DE10316207A1 - Clinker production unit, comprises sinter furnace, bypass system with heating unit, spray unit and separator for the removal of solidified droplets - Google Patents
Clinker production unit, comprises sinter furnace, bypass system with heating unit, spray unit and separator for the removal of solidified droplets Download PDFInfo
- Publication number
- DE10316207A1 DE10316207A1 DE10316207A DE10316207A DE10316207A1 DE 10316207 A1 DE10316207 A1 DE 10316207A1 DE 10316207 A DE10316207 A DE 10316207A DE 10316207 A DE10316207 A DE 10316207A DE 10316207 A1 DE10316207 A1 DE 10316207A1
- Authority
- DE
- Germany
- Prior art keywords
- dust
- exhaust gases
- melt
- unit
- bypass system
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000007921 spray Substances 0.000 title claims abstract description 9
- 238000010438 heat treatment Methods 0.000 title claims abstract description 5
- 238000004519 manufacturing process Methods 0.000 title claims description 8
- 239000000428 dust Substances 0.000 claims abstract description 38
- 239000007789 gas Substances 0.000 claims abstract description 30
- 239000002994 raw material Substances 0.000 claims abstract description 11
- 238000002844 melting Methods 0.000 claims abstract description 10
- 230000008018 melting Effects 0.000 claims abstract description 10
- 238000010304 firing Methods 0.000 claims abstract description 6
- 239000000155 melt Substances 0.000 claims abstract description 5
- 238000005507 spraying Methods 0.000 claims abstract description 5
- 238000009434 installation Methods 0.000 claims abstract 3
- 238000005245 sintering Methods 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 13
- 238000002485 combustion reaction Methods 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 239000000446 fuel Substances 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 239000012530 fluid Substances 0.000 claims description 2
- 238000000926 separation method Methods 0.000 description 4
- 239000004568 cement Substances 0.000 description 3
- 239000003344 environmental pollutant Substances 0.000 description 3
- 231100000719 pollutant Toxicity 0.000 description 3
- 239000000470 constituent Substances 0.000 description 2
- 235000013312 flour Nutrition 0.000 description 2
- 238000012432 intermediate storage Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000010791 quenching Methods 0.000 description 2
- 230000000171 quenching effect Effects 0.000 description 2
- 150000003464 sulfur compounds Chemical class 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 206010010774 Constipation Diseases 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- BITYAPCSNKJESK-UHFFFAOYSA-N potassiosodium Chemical class [Na].[K] BITYAPCSNKJESK-UHFFFAOYSA-N 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B7/00—Hydraulic cements
- C04B7/36—Manufacture of hydraulic cements in general
- C04B7/43—Heat treatment, e.g. precalcining, burning, melting; Cooling
- C04B7/436—Special arrangements for treating part or all of the cement kiln dust
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/10—Production of cement, e.g. improving or optimising the production methods; Cement grinding
- Y02P40/121—Energy efficiency measures, e.g. improving or optimising the production methods
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Furnace Details (AREA)
Abstract
Description
Die Erfindung betrifft eine Anlage sowie ein Verfahren zur Herstellung von Klinker mit einem Sinterofen zum Brennen von vorgewärmtem Rohmaterial sowie einem Bypasssystem zum Abzweigen eines Teils der im Sinterofen entstehenden staubhaltigen Abgase.The The invention relates to a system and a method for manufacturing from clinker with a sintering furnace for firing preheated raw material and a bypass system for branching off part of the in the sintering furnace resulting exhaust gases containing dust.
Rohmaterialen und Brennstoffe für die Zementherstellung enthalten zumeist Bestandteile von Chloriden, Alkalien (Natrium-Kalium-Verbindungen) sowie Schwefelverbindungen, insbesondere Sulphate, die bei relativ hohen Behandlungstemperaturen leicht flüchtig werden. Während des Brennprozesses im Sinterofen verdampfen die zuvor genannten leicht flüchtigen Bestandteile bzw. Verbindungen zu einem großen Teil, so dass sie mit den Verbrennungs- bzw. Behandlungsgasen im Sinterofen transportiert werden und in kälteren Bereichen des Sinterofens, einer Calcinierzone sowie eines Vorwärmers kondensieren können, wobei das zu brennende Rohmaterial weitgehend als Kondensatfläche dient. Diese kondensierten Bestandteile (Verbindungen) gelangen zusammen mit dem zu brennenden Rohmehl erneut in Sinterzone. Der Vorgang der Verdampfung und Kondensation der genannten Bestandteile setzen sich fort, sodass sich zwischen heißeren Bereichen, wie dem Sinterofen und kälteren Bereichen, wie dem Vorwärmer, ein Kreislauf aus leicht flüchtigen Bestandteilen, insbesondere also aus den Chlorid-, Alkali- und Schwefelverbindungen ausbaut, der beträchtlich anschwellen kann.raw materials and fuels for cement production mostly contains chlorides, Alkalis (sodium-potassium compounds) and sulfur compounds, especially sulphates, which are easy at relatively high treatment temperatures volatile become. While of the firing process in the sintering furnace evaporate the aforementioned volatile Components or connections to a large extent, so that they with the Combustion or treatment gases transported in the sintering furnace be and in colder Can condense areas of the sintering furnace, a calcining zone and a preheater, wherein the raw material to be burned largely serves as a condensate surface. These condensed components (compounds) come together with the raw flour to be burned again in the sintering zone. The process the evaporation and condensation of the constituents mentioned away, so that there is between hotter areas such as the sintering furnace and colder Areas, like the preheater, a cycle of volatile Ingredients, especially from the chloride, alkali and sulfur compounds expands that swell considerably can.
Besonders kritisch wird es dann, wenn Schadstoffkonzentrationen erreicht sind, bei denen das Rohmaterial schlechter oder überhaupt nicht mehr fließfähig ist und es zu Anbackungen und Verstopfungen kommt.Especially it becomes critical when pollutant concentrations are reached, where the raw material is poorly or no longer flowable at all and caking and constipation occur.
Um diesen Schadstoffkreislauf zu durchbrechen werden insbesondere sogenannte Bypasssysteme vorgesehen, die einen Teil der staubhaltigen Abgase des Sinterofens ableiten. Das Bypass-Heißgas wird dann üblicherweise mittels Luft oder Wasser soweit abkühlt, dass die Schadstoffe an den Staubpartikeln kondensieren. Ist dabei die Staubkonzentration des Bypass-Heißgases zu gering, kommt es zu Ansatzproblemen. Zur Erhöhung der Staubkonzentration arbeitet man beispielsweise mit einem zusätzlichen Mehlschleier im Ofeneinlaufgehäuse.Around To break this pollutant cycle are so-called Bypass systems are provided that contain part of the dust-containing exhaust gases of the sintering furnace. The bypass hot gas is then usually cools down by means of air or water until the pollutants condense the dust particles. Here is the dust concentration of the bypass hot gas too small, there are problems with the approach. To increase the dust concentration for example, you work with an additional flour curtain in the oven inlet housing.
In einem nachgeschalteten Bypassfilter werden die Staubpartikel des Bypassstroms abgeschieden. Bei einem zu hohen Staubanteil im abgeleiteten Bypassstrom erhöht sich somit der Anteil des Bypassfilterstaubes.In a bypass filter, the dust particles of the Bypass flow separated. If there is too much dust in the bypass flow elevated thus the proportion of the bypass filter dust.
Dort, wo es sich bei dem abgeschiedenen Bypassstaub um relativ geringe Mengen handelt, kann er einer Zementmühle zugeben oder auch bei anderen mineralischen Bindemitteln verwendet werden. Bei größeren Mengen an Bypassstaub, wie es in vielen Ländern, wie beispielsweise den USA, der Fall ist, stellt der Bypassstaub ein Abfallprodukt dar, das vielfach mit entsprechend hohen Kosten deponiert werden muss.There, where the separated bypass dust is relatively low If quantities are involved, he can add them to a cement mill or to others mineral binders can be used. For larger quantities of bypass dust, as is the case in many countries, such as the United States, the case, the bypass dust is a waste product, which often has to be deposited at correspondingly high costs.
Aus
der
Der Erfindung liegt daher die Aufgabe zugrunde ein einfacheres Verfahren zur Umwandlung des Bypassstaubes anzugeben.The The invention is therefore based on the object of a simpler method to specify the conversion of the bypass dust.
Erfindungsgemäß wird diese Aufgabe durch die Merkmale des Anspruches 1 bzw. 5 gelöst.According to the invention Task solved by the features of claims 1 and 5, respectively.
Die erfindungsgemäße Anlage zur Herstellung von Klinker weist einen Sinterofen zum Brennen von vorgewärmtem Rohmaterial sowie ein Bypasssystem zum Abzweigen eines Teils der im Sinterofen entstehenden staubhaltigen Abgase auf, wobei das Bypasssystem eine Einrichtung zum Erhitzen der staubhaltigen Abgase bis zum Schmelzen des im Abgas enthaltenden Staubs, eine Einrichtung zum Versprühen der entstehenden Schmelze zu Tropfen sowie eine Einrichtung zum Abscheiden der Tropfen vorsieht.The Plant according to the invention for the production of clinker has a sintering furnace for burning preheated Raw material and a bypass system for branching off part of the Dust-containing exhaust gases arising in the sintering furnace, whereby the bypass system a device for heating the dust-containing exhaust gases until melting of the dust contained in the exhaust gas, a device for spraying the resulting melt to drops and a device for separation the drop provides.
Beim erfindungsgemäßen Verfahren zur Herstellung von Klinker durch Brennen von vorgewärmtem Rohmaterial wird ein Teil der dabei entstehenden staubhaltigen Abgase in ein Bypasssystem abgezweigt, wo die staubhaltigen Abgase soweit erhitzt werden, bis der im Abgas enthaltende Staub schmelzflüssig wird, die entstehende Schmelze mittels eines Fluids zu Tropfen versprüht wird, die abkühlen, erstarren und dabei Klinker bilden und schließlich abgeschieden werden.At the method according to the invention for the production of clinker by firing preheated raw material part of the resulting dust-containing exhaust gases becomes Bypass system branched off, where the dust-containing exhaust gases heated up so far until the dust contained in the exhaust gas becomes molten, the resulting melt is sprayed into drops using a fluid, who cool, solidify and form clinker and finally be separated.
Die erfindungsgemäße Anlage sowie das Verfahren wandelt den Bypassstaub direkt, ohne Quenche und Zwischenlagerung der Stäube, in Klinker um.The Plant according to the invention and the process converts the bypass dust directly without quenches and intermediate storage of the dusts, into clinker.
Weitere Ausgestaltungen der Erfindung sind Gegenstand der Unteransprüche.Further Embodiments of the invention are the subject of the dependent claims.
In einen bevorzugten Ausführungsbeispiel wird als Sprühmedium Luft und/oder Wasser verwendet. Die Abscheidung der erstarrten Tropfen erfolgt zweckmäßigerweise in einem Zyklon.In becomes a preferred embodiment as a spray medium Air and / or water used. The separation of the solidified drops expediently takes place in a cyclone.
Weitere Vorteile und Ausgestaltungen der Erfindung werden im Folgenden anhand der Beschreibung eines Ausführungsbeispieles näher erläutet.Further Advantages and refinements of the invention are described below the description of an embodiment explained in more detail.
Die Zeichnung zeigt eine schematische Darstellung einer erfindungsgemäßen Anlage mit Bypasssystem.The Drawing shows a schematic representation of a system according to the invention with bypass system.
Die
in der Zeichnung dargestellte Anlage zur Herstellung von Klinker
besteht im Wesentlichen aus einem mehrstufigen Zyklonvorwärmer
Ein
Teil der staubhaltigem Abgase des Sinterofens
Die
entstehende Schmelze wird nach unten aus dem Schmelzzyklon herausgeführt und
gelangt in eine Einrichtung
Die
dabei gleichzeitig auch gekühlten
Tropfen gelangen über
eine Leitung
Das
in der Abscheideeinrichtung
Das oben beschriebene Verfahren zeichnet sich durch einen minimalen Anteil an Abfallstoffen (Salze) aus.The The method described above is characterized by a minimal Share of waste materials (salts).
Claims (10)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10316207A DE10316207A1 (en) | 2003-04-09 | 2003-04-09 | Clinker production unit, comprises sinter furnace, bypass system with heating unit, spray unit and separator for the removal of solidified droplets |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10316207A DE10316207A1 (en) | 2003-04-09 | 2003-04-09 | Clinker production unit, comprises sinter furnace, bypass system with heating unit, spray unit and separator for the removal of solidified droplets |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE10316207A1 true DE10316207A1 (en) | 2004-10-28 |
Family
ID=33038957
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE10316207A Withdrawn DE10316207A1 (en) | 2003-04-09 | 2003-04-09 | Clinker production unit, comprises sinter furnace, bypass system with heating unit, spray unit and separator for the removal of solidified droplets |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE10316207A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006086810A1 (en) * | 2005-02-17 | 2006-08-24 | Patco Engineering Gmbh | Method for treating cement kiln dust |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3705892A1 (en) * | 1987-02-24 | 1988-09-01 | Krupp Polysius Ag | Process and system for the further processing of bypass dust in cement production |
| DE4002876A1 (en) * | 1990-02-01 | 1991-08-08 | Kloeckner Humboldt Deutz Ag | Cyclone smelting process esp. for ore concentrates - using carrier gas to transport solids and enhance vortex in cyclone |
-
2003
- 2003-04-09 DE DE10316207A patent/DE10316207A1/en not_active Withdrawn
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3705892A1 (en) * | 1987-02-24 | 1988-09-01 | Krupp Polysius Ag | Process and system for the further processing of bypass dust in cement production |
| DE4002876A1 (en) * | 1990-02-01 | 1991-08-08 | Kloeckner Humboldt Deutz Ag | Cyclone smelting process esp. for ore concentrates - using carrier gas to transport solids and enhance vortex in cyclone |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006086810A1 (en) * | 2005-02-17 | 2006-08-24 | Patco Engineering Gmbh | Method for treating cement kiln dust |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OM8 | Search report available as to paragraph 43 lit. 1 sentence 1 patent law | ||
| 8139 | Disposal/non-payment of the annual fee |