DE1030671B - Method for gluing paper - Google Patents
Method for gluing paperInfo
- Publication number
- DE1030671B DE1030671B DEZ4215A DEZ0004215A DE1030671B DE 1030671 B DE1030671 B DE 1030671B DE Z4215 A DEZ4215 A DE Z4215A DE Z0004215 A DEZ0004215 A DE Z0004215A DE 1030671 B DE1030671 B DE 1030671B
- Authority
- DE
- Germany
- Prior art keywords
- acid
- paper
- reaction products
- paper stock
- added
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims description 11
- 238000004026 adhesive bonding Methods 0.000 title claims description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 21
- 238000004513 sizing Methods 0.000 claims description 9
- 239000012188 paraffin wax Substances 0.000 claims description 7
- 239000001993 wax Substances 0.000 claims description 6
- -1 aromatic carboxylic acids Chemical class 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 5
- 229930195729 fatty acid Natural products 0.000 claims description 5
- 239000000194 fatty acid Substances 0.000 claims description 5
- 150000004665 fatty acids Chemical class 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 4
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 2
- 150000001348 alkyl chlorides Chemical class 0.000 claims description 2
- 235000019253 formic acid Nutrition 0.000 claims description 2
- 229920005989 resin Polymers 0.000 claims description 2
- 239000011347 resin Substances 0.000 claims description 2
- 239000012266 salt solution Substances 0.000 claims description 2
- 239000007795 chemical reaction product Substances 0.000 claims 3
- 125000004432 carbon atom Chemical group C* 0.000 claims 2
- BTXXTMOWISPQSJ-UHFFFAOYSA-N 4,4,4-trifluorobutan-2-one Chemical compound CC(=O)CC(F)(F)F BTXXTMOWISPQSJ-UHFFFAOYSA-N 0.000 claims 1
- BQACOLQNOUYJCE-FYZZASKESA-N Abietic acid Natural products CC(C)C1=CC2=CC[C@]3(C)[C@](C)(CCC[C@@]3(C)C(=O)O)[C@H]2CC1 BQACOLQNOUYJCE-FYZZASKESA-N 0.000 claims 1
- 239000000839 emulsion Substances 0.000 claims 1
- 239000000123 paper Substances 0.000 description 14
- 239000000243 solution Substances 0.000 description 8
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- FDCJDKXCCYFOCV-UHFFFAOYSA-N 1-hexadecoxyhexadecane Chemical compound CCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCC FDCJDKXCCYFOCV-UHFFFAOYSA-N 0.000 description 2
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 2
- DCXXMTOCNZCJGO-UHFFFAOYSA-N Glycerol trioctadecanoate Natural products CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000007859 condensation product Substances 0.000 description 2
- 150000005690 diesters Chemical class 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- 229910021653 sulphate ion Inorganic materials 0.000 description 2
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 239000000834 fixative Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- UTOPWMOLSKOLTQ-UHFFFAOYSA-N octacosanoic acid Chemical class CCCCCCCCCCCCCCCCCCCCCCCCCCCC(O)=O UTOPWMOLSKOLTQ-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 150000003152 propanolamines Chemical class 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/07—Nitrogen-containing compounds
Landscapes
- Paper (AREA)
Description
Verfahren zum Leimen von Papier Es wurde gefunden, daß kationische Fettbasen, die aus Alkylolamin und Alkylchlorid bzw. aliphatischen und aromatischen Carbonsäuren bzw. Fettsäureamid herstellbar sind und die als Äther R - O - R1 - N < Ester R-COO.RI-N< bzw.Method of Sizing Paper It has been found that cationic Fatty bases made from alkylolamine and alkyl chloride or aliphatic and aromatic Carboxylic acids or fatty acid amide can be produced and which are used as ethers R - O - R1 - N <Ester R-COO.RI-N <resp.
Amidkondensationsprodukt R - C O N H - R1 - N < vorliegen, als Leimungsmittel für Papier, Pappe und Faserplatten dienen können und daß sie die Durchführung des Leimungsvorganges auch ohne die Mitverwendung der üblicherweise angewandten, sauer reagierenden Tonerdesalze gestatten.Amide condensation product R - C O N H - R1 - N <are present as Sizing agents for paper, cardboard and fibreboard can serve and that they are the Implementation of the gluing process without the use of the usual Allow applied, acidic alumina salts.
Es hat sich hierbei als zweckmäßig erwiesen, für die vorliegende Anwendungsweise Alkylolaminderivate einzusetzen, die mindestens zweifach substituiert sind. So weist beispielsweise der Monostearylester des Triäthanolamins nur eine geringe Leimungswirkung auf. Die Di- und Triester sind demgegenüber weitaus wirkungsvoller. Weiterhin ist es zweckmäßig, die Kettenlänge des Substituenten möglichst lang zu wählen (über C12). Derivate der Montansäure zeigen deutlich eine bessere Wirkung als die analog gebauten Stearinsäurekörper.It has proven to be expedient here to use alkylolamine derivatives which are at least twice substituted for the present application. For example, the monostearyl ester of triethanolamine only a slight sizing effect. The Di and Trieste In contrast, they are far more effective. It is also useful to choose the chain length of the substituent as long as possible (above C12). Derivatives of montanic acid clearly show a better effect than the stearic acid bodies built in the same way.
Die verfahrensgemäß eingesetzten Basen werden als Salzlösungen angewandt. Zweckmäßigerweise verwendet man zur Salzbildung flüchtige Säuren, wie Ameisensäure oder Essigsäure, da diese sich beim Trocknen des geleimten Papiers zum Teil verflüchtigen und die hydrophobe Base hinterlassen.The bases used according to the process are used as salt solutions. It is expedient to use volatile acids such as formic acid for salt formation or acetic acid, as some of these evaporate when the sized paper dries and leave the hydrophobic base.
Die verfahrensgemäß verwendeten Körper vermögen als Lösungsvermittler für andere Stoffe, wie Paraffin, Wachse und zum Teil auch Harze, Fette und Fettsäuren, zu wirken. Zum Beispiel läßt sich eine Schmelze aus 40 Teilen Paraffin und 60 Teilen Dicetyläther des Triäthanolamins in stark verdünnter heißer Essigsäure durch einfaches Verrühren zu einer noch bei niedriger Konzentration schleimig-viskosen Flüssigkeit, die nicht den Charakter einer Paraffindispersion hat, auflösen.The bodies used according to the method can act as solubilizers for other substances such as paraffin, waxes and sometimes resins, fats and fatty acids, to act. For example, a melt of 40 parts paraffin and 60 parts Dicetyl ether of triethanolamine in very dilute hot acetic acid by simple Mixing to form a slimy-viscous liquid even at a low concentration, which does not have the character of a paraffin dispersion.
Die verfahrensgemäß angewandten Basen wirken auf viele Farbstoffe fällend. Sie üben auf die Fixierung von Füllstoffen einen günstigen Einfluß aus. Sie fällen Ligninsäuren und bieten eine Möglichkeit, diese Stoffe als Füll- und Leimstoffe mit einzusetzen.The bases used according to the process act on many dyes falling. They exert a beneficial influence on the fixation of fillers. They precipitate lignic acids and offer a way of using these substances as fillers and To use glue substances.
Die Verwendung kationischer Amide war bisher nur bei einem besonderen Verfahren bekannt, bei dem nicht dispergierte Wachse (Paraffin) mit Papierstoff bei Temperaturen über dem Schmelzpunkt des Wachses im Holländer intensiv vermischt und anschließend durch Zusatz einer Lösung von kationischen Amiden fixiert wurden. Dabei muß der gesamte Papierstoff auf ungewohnte Temperaturen erhitzt und gründlich mechanisch behandelt werden, damit eine gleichmäßige Verteilung des Wachses in der Masse erfolgt. Die kationischen Amide dienen lediglich als Fixierungsmittel für die eingesetzten Wachse. Aus diesem Verfahren ließ sich nicht voraussehen, daß durch Verwendung verdünnter Lösungen von kationischen Fettbasen auf einfache Art bei üblichen Temperaturen ein ausreichender Leimungseffekt erzielt werden kann. Beispiel 1 Der aus Triäthanolamin und Stearin gewonnene Diester [(R - C 0 0 - C2 H,), - N . C2 H4 0 HJ wird unter Zusatz von Essigsäure in heißem Wasser gelöst (Konzentration 10g/1). Mit einem Zusatz von 2,5 °j, des Esters zu einem Zellstoff im Holländer wird bei Verarbeitung des Papierstoffes ein geleimtes, praktisch neutral reagierendes Papier erhalten.The use of cationic amides has hitherto only been a particular one Process known in which undispersed waxes (paraffin) with paper stock intensively mixed in the Hollander at temperatures above the melting point of the wax and then fixed by adding a solution of cationic amides. The entire paper stock must be heated to unusual temperatures and thoroughly mechanically treated so that an even distribution of the wax in the Mass takes place. The cationic amides only serve as a fixative for the waxes used. From this process it could not be foreseen that through Use of dilute solutions of cationic fatty bases in a simple way with usual Temperatures a sufficient sizing effect can be achieved. Example 1 The Diesters obtained from triethanolamine and stearin [(R - C 0 0 - C2 H,), - N. C2 H4 0 HJ is dissolved in hot water with the addition of acetic acid (concentration 10g / 1). With an addition of 2.5 ° j, the ester to a pulp in the When processing the paper stock, Holländer becomes a sized, practically neutral got reactive paper.
In analoger Weise wirken auch Ester der Propanolamine. Beispiel 2 Ein mit Kreide (Ca C 03) gefüllter Papierstoff wird im Holländer mit der verdünnten angesäuerten Lösung einer aus 2 Mol Stearinsäure, Harnstoff und 1 Mol Triäthanolamin hergestellten Base, die vermutlich als Amidkondensationsprodukt vorliegt, versetzt und ohne Mitverwendung von Tonerdesulfat verarbeitet. Das erhaltene Papier ist bei einem Zusatz von 2 bis 3 °/o Base tintenfest. Beispiel 3 Ein chloriertes Paraffin, das noch unsubstituierte Paraffine enthält, wird mit Diäthanolamin veräthert und mit Essigsäure in Lösung gebracht. Die erhaltene trübe, etwas flockig aufrahmende Lösung wird als Leimungsmittel dem Papierstoff bei normalen Arbeitstemperaturen, die etwa zwischen 10 und 30°C liegen, zugesetzt.Esters of propanolamines also have an analogous effect. Example 2 A paper stock filled with chalk (Ca C 03) is diluted with the Hollander acidified solution of 2 moles of stearic acid, urea and 1 mole of triethanolamine produced base, which is presumably present as an amide condensation product, added and processed without the use of alumina sulphate. The received paper is with an addition of 2 to 3% base is ink-resistant. Example 3 A chlorinated paraffin, which still contains unsubstituted paraffins is etherified with diethanolamine and brought into solution with acetic acid. The obtained cloudy, somewhat flaky creaming Solution is used as a sizing agent for the paper stock at normal working temperatures, between 10 and 30 ° C are added.
Beispiel 4 Ein aus 284 g Stearin, 100 g Kolophonium und 90 g Triäthanolamin erhaltener Mischester dient in der nach den Beispielen 1 bis 3 beschriebenen Weise als Leimungsmittel für Papierstoff.Example 4 One made from 284 g of stearin, 100 g of rosin and 90 g of triethanolamine mixed ester obtained is used in the manner described in Examples 1 to 3 as a sizing agent for paper stock.
Beispiel 5 Einer Papierstreichfarbe, die aus Chinaclay, Weißpigmenten und Stärkelösung besteht, wird 30/, des Diesters nach Beispiell in Form seiner essigsauren Lösung zugesetzt. Nach Trocknung zeigt der erhaltene Strich gute Leimung, Geschmeidigkeit und Druckfähigkeit.EXAMPLE 5 To a paper coating slip consisting of china clay, white pigments and starch solution, 30 % of the diester according to example is added in the form of its acetic acid solution. After drying, the coating obtained shows good sizing, suppleness and printability.
Beispiel 6 Man setzt im Holländer zu einem Papierstoff, dessen Temperatur etwa 20°C beträgt, eine verdünnte essigsaure Lösung von 60 Teilen Dicetyläther des Triäthanolamins und 40 Teilen Paraffin, wobei die Menge des gesamten Leimungsmittels etwa 3 °/o des Papierstoffes beträgt. Der Papierstoff, der mit 1 °/o Tonerdesulfat versetzt ist, wird in üblicher Weise weiterverarbeitet.Example 6 A paper stock is set in the Hollander, its temperature is about 20 ° C, a dilute acetic acid solution of 60 parts of dicetyl ether des Triethanolamine and 40 parts paraffin, the amount of the total sizing agent is about 3% of the stock. The paper stock made with 1% alumina sulphate is offset, is further processed in the usual way.
Claims (3)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEZ4215A DE1030671B (en) | 1954-05-26 | 1954-05-26 | Method for gluing paper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEZ4215A DE1030671B (en) | 1954-05-26 | 1954-05-26 | Method for gluing paper |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1030671B true DE1030671B (en) | 1958-05-22 |
Family
ID=7619055
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEZ4215A Pending DE1030671B (en) | 1954-05-26 | 1954-05-26 | Method for gluing paper |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE1030671B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1171724B (en) | 1959-12-24 | 1964-06-04 | Hercules Powder Co Ltd | Process for gluing or waterproofing paper products |
| EP0005201A1 (en) * | 1978-04-29 | 1979-11-14 | Bayer Ag | Paper sizing agent |
| EP0096654A3 (en) * | 1982-05-28 | 1984-11-14 | Ciba-Geigy Ag | Process for sizing paper with anionic, hydrophobic sizing agents and cationic retention agents |
| WO1998000606A1 (en) * | 1996-06-28 | 1998-01-08 | Betzdearborn Inc. | Paper sizing composition and process |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR931212A (en) * | 1945-05-10 | 1948-02-17 | Nat Oil Prod Co | Paper sizing process |
-
1954
- 1954-05-26 DE DEZ4215A patent/DE1030671B/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR931212A (en) * | 1945-05-10 | 1948-02-17 | Nat Oil Prod Co | Paper sizing process |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1171724B (en) | 1959-12-24 | 1964-06-04 | Hercules Powder Co Ltd | Process for gluing or waterproofing paper products |
| EP0005201A1 (en) * | 1978-04-29 | 1979-11-14 | Bayer Ag | Paper sizing agent |
| EP0096654A3 (en) * | 1982-05-28 | 1984-11-14 | Ciba-Geigy Ag | Process for sizing paper with anionic, hydrophobic sizing agents and cationic retention agents |
| WO1998000606A1 (en) * | 1996-06-28 | 1998-01-08 | Betzdearborn Inc. | Paper sizing composition and process |
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