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DE10250759A1 - Fuel cell arrangement for converting chemical to electrical energy and heat has cooling channels, bipolar plates, and feed and removal channels provided with electrically non-conducting coating - Google Patents

Fuel cell arrangement for converting chemical to electrical energy and heat has cooling channels, bipolar plates, and feed and removal channels provided with electrically non-conducting coating Download PDF

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Publication number
DE10250759A1
DE10250759A1 DE10250759A DE10250759A DE10250759A1 DE 10250759 A1 DE10250759 A1 DE 10250759A1 DE 10250759 A DE10250759 A DE 10250759A DE 10250759 A DE10250759 A DE 10250759A DE 10250759 A1 DE10250759 A1 DE 10250759A1
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Germany
Prior art keywords
channels
fuel cell
bipolar plates
feed
cell arrangement
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
DE10250759A
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German (de)
Inventor
Steffen Dr. Wieland
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Robert Bosch GmbH
Original Assignee
Buderus Heiztechnik GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Buderus Heiztechnik GmbH filed Critical Buderus Heiztechnik GmbH
Priority to DE10250759A priority Critical patent/DE10250759A1/en
Priority to DE10300581A priority patent/DE10300581A1/en
Publication of DE10250759A1 publication Critical patent/DE10250759A1/en
Ceased legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/02Details
    • H01M8/0202Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0204Non-porous and characterised by the material
    • H01M8/0223Composites
    • H01M8/0228Composites in the form of layered or coated products
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/02Details
    • H01M8/0202Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0258Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the configuration of channels, e.g. by the flow field of the reactant or coolant
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/02Details
    • H01M8/0202Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0267Collectors; Separators, e.g. bipolar separators; Interconnectors having heating or cooling means, e.g. heaters or coolant flow channels
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Composite Materials (AREA)
  • Fuel Cell (AREA)

Abstract

The fuel cell arrangement has at least one fuel cell with a polyelectrolyte membrane and bipolar plates, especially made of carbon, with fuel, air or oxygen feed channels on one side, cooling channels on the other and central feed and removal channels or connections for a gaseous or liquid coolant, fuel, combustion air or oxygen. The cooling channels, bipolar plates and feed and removal channels have an electrically non-conducting coating. The fuel cell arrangement consists of at least one individual fuel cell with a polyelectrolyte membrane and at least two associated bipolar plates (2), especially manufactured from carbon materials, with fuel, air or oxygen feed channels on one side and cooling channels (5) on the other side and central feed and removal channels (7) or connections for a gaseous or liquid coolant, fuel, combustion air or oxygen. The cooling channels, the bipolar plates and the feed and removal channels are provided with an electrically non-conducting coating (6).

Description

Die Endung betrifft eine Brennstoftzellenanordnung nach dem Oberbegriff des Patentanspruches 1.The ending relates to a fuel cell arrangement according to the preamble of the claim 1 ,

Brennstoffzellen erzeugen bei der Reaktion von Wasserstoff oder anderen kohlenwasserstoffhaltigen Brennstoffen mit Luft bzw. Sauerstoff elektrischen Strom und Wärme. Eine Brennstoffzellenanordnung besteht daher aus mindestens einer einzelnen Brennstoffzelle mit einer Polyelektrolytmembran, sowie mindestens zwei der Polyelektrolytmembran zugeordneten Bipolarplatten. Diese sind insbesondere aus gut leitenden Werkstoffen, zum Beispiel Kohlenstoff, hergestellt und besitzen auf einer Seite Brennstoff-, Luft- oder Sauerstoffzufuhrkanäle und auf der anderen Seite Kühlkanäle. Dabei können Brennstoftzellensysteme auch aus mehreren im Verbund zusammengeschalteten Einzelzellen bestehen und als sogenannte Stacks aufgebaut sein. Deshalb weist eine Brennstoffzellenanordnung zentrale Zu- und Abfuhrkanäle bzw. -anschlüsse für ein gasförmiges oder flüssiges Kühlmedium, den Brennstoff, die Verbrennungsluft oder den Sauerstoff auf.Generate fuel cells at Reaction of hydrogen or other hydrocarbonaceous Fuels with air or oxygen, electrical power and heat. A Fuel cell arrangement therefore consists of at least one individual one Fuel cell with a polyelectrolyte membrane, and at least two bipolar plates assigned to the polyelectrolyte membrane. This are especially made of highly conductive materials, for example carbon, manufactured and have on one side fuel, air or Oxygen supply channels and cooling channels on the other side. there can fuel cell systems also consist of several interconnected individual cells and be constructed as so-called stacks. Therefore, a fuel cell assembly has central supply and discharge channels or connections for a gaseous or liquid Cooling medium, the fuel, the combustion air or the oxygen.

Bei gattungsgemäßen Brennstoffzellenanordnungen wird üblicherweise deionisiertes Wasser als Kühlmedium in den feingliedrigen Kühlkanälen der Bipolarplatten eingesetzt. Da alle Kühlkanäle miteinander verbunden sind, ist das deionisierte Wasser wichtig, um ein Ausgleich der jeweiligen Spannungspotentiale der Einzelzellen über das Wasser zu verhindern. Die Aufbereitung des deionisierten Wassers ist allerdings sehr aufwändig und mit einem relativ hohen Wartungsaufwand verbunden. Zudem werden bei der Deionisation spezielle Werkstoffe eingesetzt, die möglicherweise bei höheren Kühlwassertemperaturen irreversibel beschädigt werden können.With generic fuel cell arrangements is usually deionized water as cooling medium in the delicate cooling channels of the Bipolar plates used. Since all cooling channels are connected to each other, the deionized water is important in order to balance the respective To prevent voltage potential of the individual cells over the water. The treatment of the deionized water is very complex and associated with a relatively high maintenance effort. In addition, at Deionization uses special materials that may at higher Cooling water temperatures irreversibly damaged can be.

Der Erfindung liegt die Aufgabe zugrunde, eine optimierte Brennstoffzellenanordnung zu schaffen.The invention has for its object a to create optimized fuel cell arrangement.

Erfindungsgemäß wird dies mit den Merkmalen des Patentanspruches 1 gelöst. Vorteilhafte Weiterbildungen sind den Unteransprüchen zu entnehmen.According to the invention this is with the features of the claim 1 solved. Advantageous further developments can be found in the subclaims.

Die Brennstoffzellenanordnung ist dadurch gekennzeichnet, dass die Kühlkanäle der Bipolarplatten sowie die Zu- und Abfuhrkanäle mit einer elektrisch nicht leitenden Beschichtung versehen sind. Es reicht aus, wenn die Beschichtung die Oberfläche der Kühlkanäle und der Zu- und Abfuhrkanäle durchgehend bedeckt.The fuel cell assembly is characterized in that the cooling channels of the bipolar plates as well the supply and discharge channels are provided with an electrically non-conductive coating. It is sufficient if the coating runs continuously through the surface of the cooling channels and the supply and discharge channels covered.

Für einen guten Wärmeübergang aus den Bipolarplatten an das Kühlmedium sollte die Beschichtung der Kühlkanäle der Bipolarplatten eine gute Wärmeleitfähigkeit besitzen. Vorzugsweise kommt für die Beschichtung der Kühlkanäle der Bipolarplatten sowie der Zu- und Abfuhrkanäle ein keramisches Material oder ein Kunststoff zum Einsatz. Damit kann der Wärmeübergang zusätzlich positiv durch die Gestaltung der Oberfläche beeinflusst werden, wenn beispielsweise durch eine raue oder feinporige Oberflächenstruktur Turbulenzen in den oberflächennahen Bereichen des Kühlmittelstromes erzeugt werden.For good heat transfer from the bipolar plates to the cooling medium should the coating of the cooling channels of the bipolar plates good thermal conductivity have. Preferably comes for the coating of the cooling channels of the bipolar plates as well as the feed and discharge channels a ceramic material or a plastic is used. In order to can heat transfer additionally can be positively influenced by the design of the surface, for example due to a rough or fine-pored surface structure the near-surface Areas of the coolant flow be generated.

Mit der erfindungsgemäßen Anordnung wird es möglich, auf deionisiertes Wasser zur Kühlung eines Brennstoffzellensystems zu verzichten, und es ist dadurch die Trennung der unabhängigen Spannungspotentiale der Einzelzellen voneinander gewährleistet. Sämtliche Aufbereitungseinrichtungen für deionisiertes Wasser können entfallen und es wird eine größere Betriebsssicherheit bei höheren Kühlwassertemperaturen erreicht.With the arrangement according to the invention will it be possible on deionized water for cooling to do without a fuel cell system, and it is because of it the separation of the independent Voltage potentials of the individual cells guaranteed from each other. All Processing facilities for deionized water can omitted and there will be greater operational reliability at higher Cooling water temperatures reached.

Die Zeichnung stellt ein Ausführungsbeispiel der Erfindung dar. Es zeigt eine Brennstoffzellenanordnung:The drawing represents an embodiment of the Invention shows. It shows a fuel cell arrangement:

1: in einer schematischen Gesamtdarstellung und 1 : in a schematic overall representation and

2: in einem vergrößerten Ausschnitt mit Kühlkanälen in Bipolarplatten. 2 : in an enlarged section with cooling channels in bipolar plates.

Eine Brennstoffzellenanordnung besteht im Wesentlichen aus mindestens einer Polyelektrolytmembran 1 sowie aus mindestens zwei der Polyelektrolytmembran 1 zugeordneten Bipolarplatten 2, welche auf einer Seite Zufuhrkanäle 3 für Brennstoff B oder Zufuhrkanäle 4 für Sauerstoff S, und auf der anderen Seite Kühlkanäle 5 für ein insbesondere flüssiges Kühlmedium K aufweisen.A fuel cell arrangement essentially consists of at least one polyelectrolyte membrane 1 and from at least two of the polyelectrolyte membrane 1 assigned bipolar plates 2 which have feed channels on one side 3 for fuel B or feed channels 4 for oxygen S, and on the other side cooling channels 5 for a liquid cooling medium K in particular.

Erfindungsgemäß sind die Oberflächen der Kühlkanäle 5 der Bipolarplatten 2 sowie der zentralen Zu- und Abfuhrkanäle 7 für das Kühlmedium K mit einer elektrisch nicht leitenden Beschichtung 6 versehen.According to the invention, the surfaces of the cooling channels 5 the bipolar plates 2 and the central supply and discharge channels 7 for the cooling medium K with an electrically non-conductive coating 6 Mistake.

Claims (4)

Brennstoffzellenanordnung, bestehend aus mindestens einer einzelnen Brennstoffzelle mit einer Polyelektrolytmembran, sowie mindestens zwei der Polyelektrolytmembran zugeordneten Bipolarplatten, welche insbesondere aus Kohlenstoff-Werkstoffen hergestellt, und auf einer Seite mit Brennstoff-, Luft- oder Sauerstoftzufuhrkanälen und auf der anderen Seite mit Kühlkanälen versehen sind, sowie mit zentralen Zu- und Abfuhrkanälen bzw. -anschlüssen für ein gasförmiges oder flüssiges Kühlmedium, den Brennstoff, die Verbrennungsluft oder den Sauerstoff, dadurch gekennzeichnet, dass die Kühlkanäle (5) der Bipolarplatten (2) sowie die Zu- und Abfuhrkanäle (7) mit einer elektrisch nicht leitenden Beschichtung (6) versehen sind.Fuel cell arrangement consisting of at least one individual fuel cell with a polyelectrolyte membrane, as well as at least two bipolar plates assigned to the polyelectrolyte membrane, which are made in particular from carbon materials and are provided on one side with fuel, air or oxygen supply channels and on the other side with cooling channels, and with central supply and discharge channels or connections for a gaseous or liquid cooling medium, the fuel, the combustion air or the oxygen, characterized in that the cooling channels ( 5 ) of the bipolar plates ( 2 ) and the supply and discharge channels ( 7 ) with an electrically non-conductive coating ( 6 ) are provided. Brennstoffzellenanordnung nach Anspruch 1, dadurch gekennzeichnet, dass die Beschichtung (6) der Kühlkanäle (5) der Bipolarplatten (2) sowie die Zu- und Abfuhrkanäle (7) vorzugsweise eine gute Wärmeleitfähigkeit besitzt.Fuel cell arrangement according to claim 1, characterized in that the coating ( 6 ) of the cooling channels ( 5 ) of the bipolar plates ( 2 ) and the supply and discharge channels ( 7 ) preferably has good thermal conductivity. Brennstoffzellenanordnung nach den Ansprüchen 1 oder 2, dadurch gekennzeichnet, dass die Beschichtung (6) der Kühlkanäle (5) der Bipolarplatten (2) sowie die Zu- und Abfuhrkanäle (7) vorzugsweise aus einem keramischen Material besteht.Fuel cell arrangement according to claims 1 or 2, characterized in that the coating ( 6 ) of the cooling channels ( 5 ) of the bipolar plates ( 2 ) and the supply and discharge channels ( 7 ) preferably consists of a ceramic material. Brennstoffzellenanordnung nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, dass die Beschichtung (6) der Kühlkanäle (5) der Bipolarplatten (2) sowie die Zu- und Abfuhrkanäle (7) vorzugsweise aus einem Kunststoff besteht.Fuel cell arrangement according to one of claims 1 to 3, characterized in that the coating ( 6 ) of the cooling channels ( 5 ) of the bipolar plates ( 2 ) and the supply and discharge channels ( 7 ) preferably consists of a plastic.
DE10250759A 2002-10-31 2002-10-31 Fuel cell arrangement for converting chemical to electrical energy and heat has cooling channels, bipolar plates, and feed and removal channels provided with electrically non-conducting coating Ceased DE10250759A1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
DE10250759A DE10250759A1 (en) 2002-10-31 2002-10-31 Fuel cell arrangement for converting chemical to electrical energy and heat has cooling channels, bipolar plates, and feed and removal channels provided with electrically non-conducting coating
DE10300581A DE10300581A1 (en) 2002-10-31 2003-01-10 Fuel cells have fuel and cooling channels coated with non electrically conducting fluid that hardens on heating

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE10250759A DE10250759A1 (en) 2002-10-31 2002-10-31 Fuel cell arrangement for converting chemical to electrical energy and heat has cooling channels, bipolar plates, and feed and removal channels provided with electrically non-conducting coating

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DE10250759A1 true DE10250759A1 (en) 2004-05-19

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006095926A3 (en) * 2005-03-10 2007-02-22 Toyota Motor Co Ltd Air-cooled fuel cell system
FR3059473A1 (en) * 2016-11-25 2018-06-01 Valeo Systemes Thermiques FUEL CELL WITH INTEGRATED COOLING CIRCUIT AND METHOD FOR MANUFACTURING THE SAME
DE102017206869A1 (en) * 2017-04-24 2018-10-25 Bayerische Motoren Werke Aktiengesellschaft Cooling channel for a fuel cell, fuel cell and method for producing a cooling channel
WO2023203111A2 (en) 2022-04-20 2023-10-26 Unicorn Energy AG Fluid distribution strip for a fuel cell, fuel cell kit and fuel cell component
DE102023112965A1 (en) 2023-05-17 2024-11-21 Schaeffler Technologies AG & Co. KG Bipolar plate for an electrochemical system and method for producing a bipolar plate

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006095926A3 (en) * 2005-03-10 2007-02-22 Toyota Motor Co Ltd Air-cooled fuel cell system
FR3059473A1 (en) * 2016-11-25 2018-06-01 Valeo Systemes Thermiques FUEL CELL WITH INTEGRATED COOLING CIRCUIT AND METHOD FOR MANUFACTURING THE SAME
DE102017206869A1 (en) * 2017-04-24 2018-10-25 Bayerische Motoren Werke Aktiengesellschaft Cooling channel for a fuel cell, fuel cell and method for producing a cooling channel
WO2023203111A2 (en) 2022-04-20 2023-10-26 Unicorn Energy AG Fluid distribution strip for a fuel cell, fuel cell kit and fuel cell component
DE102022109562A1 (en) 2022-04-20 2023-10-26 Unicorn Energy AG Fluid distribution strip for a fuel cell, fuel cell kit and fuel cell component
DE102023112965A1 (en) 2023-05-17 2024-11-21 Schaeffler Technologies AG & Co. KG Bipolar plate for an electrochemical system and method for producing a bipolar plate
DE102023112965B4 (en) 2023-05-17 2025-03-27 Schaeffler Technologies AG & Co. KG Method for producing a bipolar plate and bipolar plate

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Legal Events

Date Code Title Description
OP8 Request for examination as to paragraph 44 patent law
8127 New person/name/address of the applicant

Owner name: BBT THERMOTECHNIK GMBH, 35576 WETZLAR, DE

8127 New person/name/address of the applicant

Owner name: ROBERT BOSCH GMBH, 70469 STUTTGART, DE

8131 Rejection