DE102011078111A1 - Cleaning agent useful as antibacterial nourishing cosmetic skin cleansing agent for treating sensitive skin and/or mucous membrane, comprises carrier comprising vegetable oil, hydrocarbon derivative and ethoxylated hydrogenated castor oil - Google Patents

Abstract

Cleaning agent comprises a carrier comprising (a) at least one vegetable oil, (b) at least one hydrocarbon derivative (I), and (c) an ethoxylated hydrogenated castor oil with an average ethoxylation degree of at least 45. Cleaning agent comprises carrier comprising (a) at least one vegetable oil, (b) at least one of formula (CH 3(CH 2) 7CH=CH(CH 2) 7-C(=O)-OCH 2-CH(CH 2-(OCH 2CH 2) n-OH)-O-C(=O)-R 1>) (I) and (c) an ethoxylated hydrogenated castor oil with an average ethoxylation degree of at least 45. R 1>optionally saturated, optionally branched 8-22C alkyl; and n : 10-30.

Description

The invention is in the field of cosmetics and relates to cleaning compositions containing at least one vegetable oil and a mixture of at least two special solubilizers.

Cosmetic cleansers such as liquid soaps, shampoos, shower baths, bubble baths, shower gels and / or wash gels have long been known and are regularly adapted to the changing needs of consumers.

So in recent years, due to the increasing environmental awareness of consumers so-called combination preparations have been developed, with which the human body can be cleaned and maintained in only one application step.

These combination preparations have the advantage that they cause less packaging waste and require less water consumption, time and / or cost. The problem with the preparation of these preparations is the incorporation of hydrophobic active ingredients whose dispersion and stabilization in the cleaning agents often succeed only by the incorporation of crystalline or polymeric components.

To make matters worse, there is an increasing desire to produce aesthetically superior products, which preferably contain mild, vegetable oil components.

Vegetable oil components are difficult to disperse in conventional detergents, especially at higher levels, without stability problems and / or the required viscosity of the agents being lost.

In the examples of the published patent application WO 2010/009978 have been disclosed clear conditioning cleaners containing almond oil and a mixture of ethoxylated solubilizers in a certain weight ratio.

In the further development of o. G. However, examples have been found that increasing the vegetable oil content may decrease the foam quality of the detergents.

Furthermore, it could be observed that the stability of the detergents can decrease with decreasing pH values and that they can no longer be thickened satisfactorily with conventional electrolytes.

Accordingly, there is still the consumer desire for vegetable oil-containing stable cleaning agents with a high care effect for the human skin.

The present invention has for its object to develop a cosmetic care cleanser containing vegetable oils.

The vegetable oils should be clearly solubilizable in the cleanser and stabilizable over a long period of time. Furthermore, the detergents should have a high electrolyte tolerance.

Preferably, the detergents should be stable even at low pHs (up to about pH 3), and suitable for use as antibacterial cleansers having a skin care effect.

Furthermore, the compositions should have excellent foaming properties. The foam should develop quickly and spread well on the skin.

• a) mindestens ein pflanzliches Öl,
• b) mindestens eine Komponente der nachfolgenden Formel (I),
  
  in der R¹ für einen gesättigten oder ungesättigten, verzweigten oder unverzweigten Alkylrest mit 8 bis 22 C-Atomen, und n für eine Zahl zwischen 10 und 30 steht, und
• c) ethoxyliertes hydriertes Rizinusöl mit einem mittleren Ethoxylierungsgrad von mindestens 45 enthält.

The subject of the present application is a cleaning agent which is in a cosmetically acceptable carrier

• a) at least one vegetable oil,
• b) at least one component of the following formula (I),
  
  in which R ^{1 is} a saturated or unsaturated, branched or unbranched alkyl radical having 8 to 22 C atoms, and n is a number between 10 and 30, and
• c) containing ethoxylated hydrogenated castor oil having a mean degree of ethoxylation of at least 45.

A cosmetically acceptable carrier is preferably understood as meaning an aqueous or aqueous-alcoholic carrier.

The cosmetic carrier preferably contains at least 50% by weight of water.

Furthermore, the cosmetic carrier may contain 0.01 to 30% by weight, preferably 0.025 to 25% by weight and in particular 0.05 to 20% by weight of at least one alcohol which may be selected from ethanol, 1-propanol, 2-propanol, isopropanol, glycerol, 1-butanol, 2-butanol, 1-pentanol, 2-pentanol or mixtures of these alcohols.

Preference is given to the water-soluble alcohols.

Particularly preferred are ethanol, 1-propanol and / or glycerol.

The vegetable oil (component a)) in the cleaning agent according to the invention - based on its total weight - preferably in an amount of 0.01 to 10 wt .-%, more preferably from 0.025 to 5 wt .-%, more preferably from 0, 05 to 3 wt .-%, particularly preferably from 0.075 to 2 wt .-% and in particular from 0.1 to 1 wt .-% used.

As suitable vegetable oils, the detergents may contain triglycerides and / or mixtures of triglycerides.

Preferred vegetable oils are coconut oil, (sweet) almond oil, walnut oil, peach kernel oil, apricot kernel oil, rose hip kernel oil, sea buckthorn pulp oil, sea buckthorn seed oil, avocado oil, tea tree oil, soybean oil, sesame oil, sunflower oil, tsubaki oil, evening primrose oil, rice bran oil, palm kernel oil, mango seed oil, meadowfoam seed oil, Thistle oil, rapeseed oil, rice oil, macadamia nut oil, grapeseed oil, pomegranate seed oil, grapefruit seed oil, wild rose oil, hemp oil, amaranth seed oil, argan oil, babassu oil, cottonseed oil, borage seed oil, camelina oil, olive oil, wheat germ oil, pumpkin seed oil, peanut oil, hazelnut oil, elderflower seed oil, currant seed oil, linseed oil, corn oil, marula oil, Mallow oil, safflower oil, canola oil, sasanqua oil, jojoba oil, palm oil, evening primrose oil, rambutan oil, cocoa butter and shea butter.

Particularly preferred are (sweet) almond oil, peach kernel oil, apricot kernel oil, avocado oil, sunflower oil, grapeseed oil, argan oil, olive oil, wheat germ oil, pumpkin seed oil and / or jojoba oil.

Particularly preferred are (sweet) almond oil, avocado oil, sunflower oil, olive oil and / or jojoba oil.

The vegetable oil is solubilized in the cleaning agent according to the invention by the combination of components b) and c), whereby first transparent compositions are obtained, which can be thickened with electrolyte salts such as NaCl.

"Transparent" compositions detergent according to the invention are understood to have at 25 ° C preferably a turbidity ≤ 250 NTU (Nephelometric Turbidity Unit = Nephelometric turbidity unit), more preferably ≤ 150 NTU, more preferably ≤ 100 and in particular ≤ 50 (measured for example with a Device "2100P Turbidimeter" from Hach).

To the cleaning agents of the invention may be added other components (which will be described later in this application) without affecting their transparency.

In a preferred embodiment, cleaning agents according to the invention are therefore transparent.

For some applications, however, there may be a desire that the detergents according to the invention have a creamy consistency.

In this case, clouding agents and / or pearlescing agents can be added to the transparent cleaning agents in a further preferred embodiment.

"Viscous" compositions are understood to mean detergents according to the invention which preferably have a viscosity in the range from 3.000 to 20,000 mPas, more preferably from 4,000 to 15,000 mPas, more preferably from 5,000 to 12,500 mPas, particularly preferably from 7,500 to 10,000 mPas and in particular from 8,000 to 9,000 mPas (each measured with a Haake VT550 rotational viscometer, 20 ° C, MV measuring device, MV II spindle, 8 rpm).

As a first suitable solubilizer (component b)), the cleaning agent according to the invention preferably contains from 0.01 to 10% by weight, more preferably from 0.025 to 7.5% by weight, more preferably from 0.05 to 5% by weight, based on its total weight .-%, particularly preferably 0.1 to 3 wt .-% and in particular 0.5 to 2 wt .-% of a component according to the formula (I) described above, in which R ^{1 is} preferably a saturated or unsaturated, branched or unbranched alkyl radical having 8 to 18, more preferably 8 to 16 and in particular 8 to 14 carbon atoms, and n is preferably a number between 15 and 25, and particularly preferably a number between 17 and 20 stands.

An example of a particularly suitable solubilizer according to formula (I) is a known under the INCI name PEG-18 Glyceryl Oleate / Cocoate, and commercially - for example, under the name Antil ^® 171 - available from the company Evonik solubilizer.

As a second suitable solubilizer (component c)), the cleaning agent according to the invention contains - based on its total weight - preferably 0.01 to 10 wt .-%, more preferably 0.025 to 7.5 wt .-%, more preferably 0.05 to 5 wt %, more preferably 0.1 to 3 wt .-% and in particular 0.5 to 2 wt .-% ethoxylated hydrogenated castor oil having a mean degree of ethoxylation of at least 50, preferably of at least 55 and in particular of at least 60.

An example of a particularly suitable solubilizer c) is a known under the INCI name PEG-60 Hydrogenated Castor Oil, and commercially - for example, under the name Cremophor ^® CO 60 - available from the company Cognis solubilizer.

• a) 0,025 bis 5 Gew.-% mindestens eines pflanzlichen Öls, ausgewählt aus (süßem) Mandelöl, Pfirsichkernöl, Aprikosenkernöl, Avocadoöl, Sonnenblumenöl, Traubenkernöl, Arganöl, Olivenöl, Weizenkeimöl, Kürbiskernöl und/oder Jojobaöl,
• b) 0,025 bis 7,5 Gew.-% mindestens einer Komponente gemäß der zuvor beschriebenen Formel (I), in der R¹ bevorzugt für einen gesättigten oder ungesättigten, verzweigten oder unverzweigten Alkylrest mit 8 bis 18, mehr bevorzugt mit 8 bis 16 und insbesondere mit 8 bis 14 C-Atomen, und n bevorzugt für eine Zahl zwischen 15 und 25, und insbesondere bevorzugt für eine Zahl zwischen 17 und 20 steht, und
• c) 0,025 bis 7,5 Gew.-% ethoxyliertes hydriertes Rizinusöl mit einem mittleren Ethoxylierungsgrad von mindestens 50, bevorzugt von mindestens 55.

In a first preferred embodiment, detergents according to the invention contain, based on their total weight,

• a) 0.025 to 5% by weight of at least one vegetable oil selected from (sweet) almond oil, peach kernel oil, apricot kernel oil, avocado oil, sunflower oil, grape seed oil, argan oil, olive oil, wheat germ oil, pumpkin seed oil and / or jojoba oil,
• b) 0.025 to 7.5 wt .-% of at least one component according to the formula (I) described above, in which R ^{1 is} preferably a saturated or unsaturated, branched or unbranched alkyl radical having 8 to 18, more preferably 8 to 16 and in particular having 8 to 14 C atoms, and n is preferably a number between 15 and 25, and particularly preferably a number between 17 and 20, and
• c) 0.025 to 7.5% by weight of ethoxylated hydrogenated castor oil having a mean degree of ethoxylation of at least 50, preferably of at least 55.

• a) 0,05 bis 3 Gew.-% mindestens eines pflanzlichen Öls, ausgewählt aus (süßem) Mandelöl, Avocadoöl, Sonnenblumenöl, Olivenöl und/oder Jojobaöl,
• b) 0,05 bis 5 Gew.-% mindestens einer der unter der INCI-Bezeichnung PEG-18 Glyceryl Oleate/Cocoate bekannten Verbindung gemäß der zuvor genannten Formel (I), und
• c) 0,05 bis 5 Gew.-% ethoxyliertes hydriertes Rizinusöl mit einem mittleren Ethoxylierungsgrad von mindestens 60 enthalten.

Within this embodiment, those cleaning agents are particularly preferred which - based on their total weight -

• a) from 0.05 to 3% by weight of at least one vegetable oil selected from (sweet) almond oil, avocado oil, sunflower oil, olive oil and / or jojoba oil,
• b) 0.05 to 5 wt .-% of at least one known under the INCI name PEG-18 Glyceryl Oleate / Cocoate compound according to the aforementioned formula (I), and
• c) 0.05 to 5 wt .-% ethoxylated hydrogenated castor oil having a mean degree of ethoxylation of at least 60.

Detergents usually contain one or more surfactants to develop their cleaning action.

Detergents according to the invention may also contain one or more surfactants, which may be selected from anionic, nonionic and / or amphoteric / zwitterionic surfactants.

In a second preferred embodiment of the invention, the cleaning agents according to the invention contain - based on their total weight - preferably 3 to 20 wt .-%, more preferably 5 to 15 wt .-% and in particular 7 to 12 wt .-% of at least one anionic surfactant.

• – lineare und verzweigte Fettsäuren mit 8 bis 30 C-Atomen (Seifen),
• – Ethercarbonsäuren der Formel R-O-(CH₂-CH₂O)_x-CH₂-COOH, in der R eine lineare oder verzweigte, gesättigte oder ungesättigte Alkylgruppe mit 8 bis 30 C-Atomen und x = 0 oder 1 bis 16 ist,
• – Acylsarcoside mit 8 bis 24 C-Atomen in der Acylgruppe,
• – Acyltauride mit 8 bis 24 C-Atomen in der Acylgruppe,
• – Acylisethionate mit 8 bis 24 C-Atomen in der Acylgruppe,
• – Sulfobernsteinsäuremono- und/oder -dialkylester mit 8 bis 24 C-Atomen in der Alkylgruppe und Sulfobernsteinsäuremono-alkylpolyoxyethylester mit 8 bis 24 C-Atomen in der Alkylgruppe und 1 bis 6 Oxyethylgruppen,
• – Alpha-Olefinsulfonate mit 8 bis 24 C-Atomen,
• – Alkylsulfat- und/oder Alkylpolyglykolethersulfatsalze der Formel R-O(CH₂-CH₂O)_x-OSO₃ ^–X⁺, in der R eine bevorzugt lineare oder verzweigte, gesättigte oder ungesättigte Alkylgruppe mit 8 bis 30 C-Atomen, x = 0 oder 1 bis 12 und X ein Alkali- oder Ammoniumion ist,
• – Sulfonate ungesättigter Fettsäuren mit 8 bis 24 C-Atomen und 1 bis 6 Doppelbindungen,
• – Ester der Weinsäure und Zitronensäure mit Alkoholen, die Anlagerungsprodukte von etwa 2–15 Molekülen Ethylenoxid und/oder Propylenoxid an Fettalkohole mit 8 bis 22 C-Atomen darstellen,
• – Alkyl- und/oder Alkenyletherphosphate der Formel,
  
  in der R¹ bevorzugt für einen aliphatischen Kohlenwasserstoffrest mit 8 bis 30 Kohlenstoffatomen, R² für Wasserstoff, einen Rest (CH₂CH₂O)_nR¹ oder X, n für Zahlen von 0 bis 10 und X für Wasserstoff, ein Alkali- oder Erdalkalimetall oder NR³R⁴R⁵R⁶, mit R³ bis R⁶ unabhängig voneinander stehend für einen C₁ bis C₄-Kohlenwasserstoffrest, steht.

Suitable anionic surfactants which can be used in the compositions according to the invention include, for example:

• - linear and branched fatty acids with 8 to 30 carbon atoms (soaps),
• Ether carboxylic acids of the formula RO- (CH ₂ -CH ₂ O) _x -CH ₂ -COOH, in which R is a linear or branched, saturated or unsaturated alkyl group having 8 to 30 C atoms and x = 0 or 1 to 16,
• Acylsarcosides having 8 to 24 C atoms in the acyl group,
• Acyltaurides having 8 to 24 carbon atoms in the acyl group,
• Acyl isethionates having 8 to 24 C atoms in the acyl group,
• Sulfosuccinic acid mono- and / or dialkyl esters having 8 to 24 C atoms in the alkyl group and sulfosuccinic acid monoalkyl polyoxyethyl esters having 8 to 24 C atoms in the alkyl group and 1 to 6 oxyethyl groups,
• Alpha-olefin sulfonates having 8 to 24 C atoms,
• - Alkyl sulfate and / or Alkylpolyglykolethersulfatsalze of the formula RO (CH ₂ -CH ₂ O) _x -OSO ₃ ^- X ⁺ , in which R is a preferably linear or branched, saturated or unsaturated alkyl group having 8 to 30 carbon atoms, x = 0 or 1 to 12 and X is an alkali or ammonium ion,
• Sulfonates of unsaturated fatty acids having 8 to 24 C atoms and 1 to 6 double bonds,
• Esters of tartaric acid and citric acid with alcohols which are adducts of about 2-15 molecules of ethylene oxide and / or propylene oxide with fatty alcohols containing 8 to 22 carbon atoms,
• Alkyl and / or alkenyl ether phosphates of the formula
  
  in the R ^{1 is} preferably an aliphatic hydrocarbon radical having 8 to 30 carbon atoms, R ^{2 is} hydrogen, a radical (CH ₂ CH ₂ O) _n R ¹ or X, n is from 0 to 10 and X is hydrogen, an alkali metal radical or alkaline earth metal or NR ³ R ⁴ R ⁵ R ⁶ , where R ³ to R ⁶ are each independently a C ₁ to C ₄ hydrocarbon radical.

Preferred anionic surfactants are ether carboxylic acids of the abovementioned formula, acylsarcosides having 8 to 24 C atoms in the acyl group, sulfosuccinic acid mono- and / or dialkyl esters having 8 to 24 C atoms in the alkyl group and sulfosuccinic acid monoalkylpolyoxyethyl esters having 8 to 24 C atoms in the alkyl group and 1 to 6 oxyethyl groups, alpha-olefin sulfonates having 8 to 24 carbon atoms and / or alkyl sulfate and / or Alkylpolyglykolethersulfatsalze the aforementioned formula.

Particularly preferred anionic surfactants are straight-chain or branched alkyl ether sulfates which contain an alkyl radical having 8 to 18 and in particular 10 to 16 C atoms and 1 to 6 and in particular 2 to 4 ethylene oxide units.

Further particularly preferred anionic surfactants are straight-chain or branched alkyl sulfonates which contain an alkyl radical having 8 to 18 and in particular 10 to 16 carbon atoms. Particular preference is given to the sodium, magnesium and / or triethanolamine salts of linear or branched lauryl, tridecyl and / or myristyl sulfates which have a degree of ethoxylation of from 2 to 4.

• a) 0,025 bis 5 Gew.-% mindestens eines pflanzlichen Öls, ausgewählt aus (süßem) Mandelöl, Pfirsichkernöl, Aprikosenkernöl, Avocadoöl, Sonnenblumenöl, Traubenkernöl, Arganöl, Olivenöl, Weizenkeimöl, Kürbiskernöl und/oder Jojobaöl,
• b) 0,025 bis 7,5 Gew.-% mindestens einer Komponente gemäß der zuvor beschriebenen Formel (I), in der R¹ bevorzugt für einen gesättigten oder ungesättigten, verzweigten oder unverzweigten Alkylrest mit 8 bis 18, mehr bevorzugt mit 8 bis 16 und insbesondere mit 8 bis 14 C-Atomen, und n bevorzugt für eine Zahl zwischen 15 und 25, und insbesondere bevorzugt für eine Zahl zwischen 17 und 20 steht,
• c) 0,025 bis 7,5 Gew.-% ethoxyliertes hydriertes Rizinusöl mit einem mittleren Ethoxylierungsgrad von mindestens 50, bevorzugt von mindestens 55, und
• d) 3 bis 20 Gew.-% mindestens eines anionischen Tensids aus der Gruppe der Ethercarbonsäuren, Acylsarcoside mit 8 bis 24 C-Atomen in der Acylgruppe, Sulfobernsteinsäuremono- und/oder -dialkylester mit 8 bis 24 C-Atomen in der Alkylgruppe und Sulfobernsteinsäuremono-alkylpolyoxyethylester mit 8 bis 24 C-Atomen in der Alkylgruppe und 1 bis 6 Oxyethylgruppen, Alpha-Olefinsulfonate mit 8 bis 24 C-Atomen und/oder Alkylsulfat- und/oder Alkylpolyglykolethersulfatsalze.

In a third preferred embodiment, detergents according to the invention contain, based on their total weight,

• a) 0.025 to 5% by weight of at least one vegetable oil selected from (sweet) almond oil, peach kernel oil, apricot kernel oil, avocado oil, sunflower oil, grape seed oil, argan oil, olive oil, wheat germ oil, pumpkin seed oil and / or jojoba oil,
• b) 0.025 to 7.5 wt .-% of at least one component according to the formula (I) described above, in which R ^{1 is} preferably a saturated or unsaturated, branched or unbranched alkyl radical having 8 to 18, more preferably 8 to 16 and in particular having 8 to 14 C atoms, and n is preferably between 15 and 25, and particularly preferably between 17 and 20,
• c) 0.025 to 7.5 wt .-% ethoxylated hydrogenated castor oil having a mean degree of ethoxylation of at least 50, preferably of at least 55, and
• d) 3 to 20 wt .-% of at least one anionic surfactant from the group of ether carboxylic acids, acylsarcosides having 8 to 24 carbon atoms in the acyl group, sulfosuccinic mono- and / or dialkyl ester having 8 to 24 carbon atoms in the alkyl group and sulfosuccinic mono Alkylpolyoxyethylester having 8 to 24 carbon atoms in the alkyl group and 1 to 6 oxyethyl groups, alpha-olefin sulfonates having 8 to 24 carbon atoms and / or alkyl sulfate and / or Alkylpolyglykolethersulfatsalze.

• a) 0,05 bis 3 Gew.-% mindestens eines pflanzlichen Öls, ausgewählt aus (süßem) Mandelöl, Avocadoöl, Sonnenblumenöl, Olivenöl und/oder Jojobaöl,
• b) 0,05 bis 5 Gew.-% mindestens einer der unter der INCI-Bezeichnung PEG-18 Glyceryl Oleate/Cocoate bekannten Verbindung gemäß der zuvor genannten Formel (I),
• c) 0,05 bis 5 Gew.-% ethoxyliertes hydriertes Rizinusöl mit einem mittleren Ethoxylierungsgrad von mindestens 60, und
• d) 5 bis 15 Gew.-% geradkettige oder verzweigte Alkylethersulfate enthalten, die einen Alkylrest mit 8 bis 18 und insbesondere mit 10 bis 16 C-Atomen sowie 1 bis 6 und insbesondere 2 bis 4 Ethylenoxideinheiten aufweisen.

Within this embodiment, it is particularly preferred if the cleaning agents according to the invention - based on their total weight -

• a) from 0.05 to 3% by weight of at least one vegetable oil selected from (sweet) almond oil, avocado oil, sunflower oil, olive oil and / or jojoba oil,
• b) 0.05 to 5% by weight of at least one compound known under the INCI name PEG-18 Glyceryl Oleate / Cocoate according to the abovementioned formula (I),
• c) 0.05 to 5 wt .-% ethoxylated hydrogenated castor oil having a mean degree of ethoxylation of at least 60, and
• d) 5 to 15 wt .-% straight-chain or branched alkyl ether containing an alkyl radical having 8 to 18 and in particular having 10 to 16 carbon atoms and 1 to 6 and in particular 2 to 4 ethylene oxide units.

For some applications (for example, for particularly sensitive, skin-care cleaning formulations), it may be advantageous if the cleaning agents according to the invention contain a particularly mild surfactant.

• a. mindestens ein anionisches Tensid und
• b. mindestens ein amphoteres und/oder zwitterionisches Tensid.

In a fourth preferred embodiment, a cleaning agent according to the invention therefore contains

• a. at least one anionic surfactant and
• b. at least one amphoteric and / or zwitterionic surfactant.

Suitable amphoteric / zwitterionic surfactants may be selected from compounds of the following formulas (i) to (v) in which the radical R is in each case a straight-chain or branched, saturated or mono- or polyunsaturated alkyl or alkenyl radical having 8 to 24 carbon atoms stands,

Particularly suitable amphoteric / zwitterionic surfactants are alkylamidoalkylbetaines and / or alkylampho (di) acetates of the abovementioned formulas (i) to (v).

Particularly suitable amphoteric / zwitterionic surfactants include the surfactants cocamidopropyl betaine and disodium cocoamphodiacetate known under the INCI name.

Amphoteric / zwitterionic surfactants may be present in the detergents according to the invention, based on their total weight, preferably in amounts of from 0.5 to 15% by weight, more preferably from 1 to 10% by weight and in particular from 2 to 7.5% by weight. be added.

• a) 0,025 bis 5 Gew.-% mindestens eines pflanzlichen Öls, ausgewählt aus (süßem) Mandelöl, Pfirsichkernöl, Aprikosenkernöl, Avocadoöl, Sonnenblumenöl, Traubenkernöl, Arganöl, Olivenöl, Weizenkeimöl, Kürbiskernöl und/oder Jojobaöl,
• b) 0,025 bis 7,5 Gew.-% mindestens einer Komponente gemäß der zuvor beschriebenen Formel (I), in der R¹ bevorzugt für einen gesättigten oder ungesättigten, verzweigten oder unverzweigten Alkylrest mit 8 bis 18, mehr bevorzugt mit 8 bis 16 und insbesondere mit 8 bis 14 C-Atomen, und n bevorzugt für eine Zahl zwischen 15 und 25, und insbesondere bevorzugt für eine Zahl zwischen 17 und 20 steht,
• c) 0,025 bis 7,5 Gew.-% ethoxyliertes hydriertes Rizinusöl mit einem mittleren Ethoxylierungsgrad von mindestens 50, bevorzugt von mindestens 55,
• d) 3 bis 20 Gew.-% mindestens eines anionischen Tensids aus der Gruppe der Ethercarbonsäuren, Acylsarcoside mit 8 bis 24 C-Atomen in der Acylgruppe, Sulfobernsteinsäuremono- und/oder -dialkylester mit 8 bis 24 C-Atomen in der Alkylgruppe und Sulfobernsteinsäuremono-alkylpolyoxyethylester mit 8 bis 24 C-Atomen in der Alkylgruppe und 1 bis 6 Oxyethylgruppen, Alpha-Olefinsulfonate mit 8 bis 24 C-Atomen und/oder Alkylsulfat- und/oder Alkylpolyglykolethersulfatsalze, und
• e) 0,5 bis 15 Gew.-% mindestens eines zwitterionischen und/oder amphoteren Tensids.

In a fifth preferred embodiment, detergents according to the invention contain, based on their total weight,

• a) 0.025 to 5% by weight of at least one vegetable oil selected from (sweet) almond oil, peach kernel oil, apricot kernel oil, avocado oil, sunflower oil, grape seed oil, argan oil, olive oil, wheat germ oil, pumpkin seed oil and / or jojoba oil,
• b) 0.025 to 7.5 wt .-% of at least one component according to the formula (I) described above, in which R ^{1 is} preferably a saturated or unsaturated, branched or unbranched alkyl radical having 8 to 18, more preferably 8 to 16 and in particular having 8 to 14 C atoms, and n is preferably between 15 and 25, and particularly preferably between 17 and 20,
• c) 0.025 to 7.5% by weight of ethoxylated hydrogenated castor oil having a mean degree of ethoxylation of at least 50, preferably of at least 55,
• d) 3 to 20 wt .-% of at least one anionic surfactant from the group of ether carboxylic acids, acylsarcosides having 8 to 24 carbon atoms in the acyl group, sulfosuccinic mono- and / or dialkyl ester having 8 to 24 carbon atoms in the alkyl group and sulfosuccinic mono alkylpolyoxyethyl esters having 8 to 24 carbon atoms in the alkyl group and 1 to 6 oxyethyl groups, alpha-olefin sulfonates having 8 to 24 carbon atoms and / or alkyl sulfate and / or alkylpolyglycol ether sulfate salts, and
• e) 0.5 to 15 wt .-% of at least one zwitterionic and / or amphoteric surfactant.

• a) 0,05 bis 3 Gew.-% mindestens eines pflanzlichen Öls, ausgewählt aus (süßem) Mandelöl, Avocadoöl, Sonnenblumenöl, Olivenöl und/oder Jojobaöl,
• b) 0,05 bis 5 Gew.-% mindestens einer der unter der INCI-Bezeichnung PEG-18 Glyceryl Oleate/Cocoate bekannten Verbindung gemäß der zuvor genannten Formel (I),
• c) 0,05 bis 5 Gew.-% ethoxyliertes hydriertes Rizinusöl mit einem mittleren Ethoxylierungsgrad von mindestens 60,
• d) 5 bis 15 Gew.-% geradkettige oder verzweigte Alkylethersulfate, die einen Alkylrest mit 8 bis 18 und insbesondere mit 10 bis 16 C-Atomen sowie 1 bis 6 und insbesondere 2 bis 4 Ethylenoxideinheiten enthalten, und
• e) 2 bis 7,5 Gew.-% mindestens eines der unter der INCI-Bezeichnung bekannten Tenside Cocamidopropylbetain und Disodium Cocoamphodiacetate enthalten.

Within this embodiment, it is particularly preferred if the cleaning agents according to the invention - based on their total weight -

• a) from 0.05 to 3% by weight of at least one vegetable oil selected from (sweet) almond oil, avocado oil, sunflower oil, olive oil and / or jojoba oil,
• b) 0.05 to 5% by weight of at least one compound known under the INCI name PEG-18 Glyceryl Oleate / Cocoate according to the abovementioned formula (I),
• c) 0.05 to 5% by weight of ethoxylated hydrogenated castor oil having a mean degree of ethoxylation of at least 60,
• d) 5 to 15% by weight of straight-chain or branched alkyl ether sulfates which contain an alkyl radical having 8 to 18 and in particular 10 to 16 C atoms and 1 to 6 and in particular 2 to 4 ethylene oxide units, and
• e) 2 to 7.5 wt .-% of at least one of the known under the INCI name surfactants cocamidopropyl betaine and disodium cocoamphodiacetates.

As already stated earlier in this application, cleaning agents according to the invention should, in a further preferred embodiment, also be stable in a more acidic pH range than conventional detergents, have a good foam quality and have outstanding cleaning and care properties.

It has been found that the detergents according to the invention meet these requirements in a preferred pH range of from 3 to 5.5.

In this pH range, the cleaning agents according to the invention are in principle also suitable for the production of nourishing detergents having an antibacterial effect, which can also be used in sensitive skin regions and / or on the mucous membrane.

In a sixth preferred embodiment, the cleaning agents according to the invention therefore additionally contain at least one antibacterial active ingredient.

in der

• – der Rest R bevorzugt ein Wasserstoffatom, ein Alkalimetallion oder eine lineare oder verzweigte C₁-C₄-Alkylgruppe, und
• – der Rest R¹ in ortho-, meta- oder para-Stellung zur -COOR-Gruppe stehen kann und bevorzugt ein Wasserstoffatom oder eine Hydroxylgruppe bedeutet.

Suitable antibacterial agents which can be added to the cleaning agents according to the invention are, for example, active compounds which fall under the following formula (II)

in the

• The radical R preferably represents a hydrogen atom, an alkali metal ion or a linear or branched C ₁ -C ₄ -alkyl group, and
• - The radical R ^{1 may be} ortho, meta or para to the -COOR group and preferably represents a hydrogen atom or a hydroxyl group.

Active compounds of the formula (II) preferred for use in the detergents according to the invention contain, as the radical R, a hydrogen atom or an alkali metal ion and, as the radical R ^1, a hydrogen atom or a hydroxyl group which is preferably ortho to the -COOR group.

Particularly preferred active compounds according to formula (II) are salicylic acid and benzoic acid and the alkali metal salts of these acids.

Antibacterial active ingredients which fall under the abovementioned formula (II) may, preferably more preferably in amounts of at least 0.01% by weight, preferably of at least 0.05% by weight, of the cleaning agents according to the invention-based on their total weight of at least 0.1% by weight, more preferably of at least 0.2% by weight and in particular of at least 0.3% by weight.

In a particularly preferred embodiment, detergents according to the invention, which are formulated as antibacterial skin cleansing preparations, comprise at least 0.01% by weight, preferably at least 0.05% by weight, more preferably at least 0.1% by weight, particularly preferably at least 0.2 wt .-% and in particular at least 0.3 wt .-% of at least two different active ingredients, which fall under the aforementioned formula (II).

• a) 0,025 bis 5 Gew.-% mindestens eines pflanzlichen Öls, ausgewählt aus (süßem) Mandelöl, Pfirsichkernöl, Aprikosenkernöl, Avocadoöl, Sonnenblumenöl, Traubenkernöl, Arganöl, Olivenöl, Weizenkeimöl, Kürbiskernöl und/oder Jojobaöl,
• b) 0,025 bis 7,5 Gew.-% mindestens einer Komponente gemäß der zuvor beschriebenen Formel (I), in der R¹ bevorzugt für einen gesättigten oder ungesättigten, verzweigten oder unverzweigten Alkylrest mit 8 bis 18, mehr bevorzugt mit 8 bis 16 und insbesondere mit 8 bis 14 C-Atomen, und n bevorzugt für eine Zahl zwischen 15 und 25, und insbesondere bevorzugt für eine Zahl zwischen 17 und 20 steht,
• c) 0,025 bis 7,5 Gew.-% ethoxyliertes hydriertes Rizinusöl mit einem mittleren Ethoxylierungsgrad von mindestens 50, bevorzugt von mindestens 55,
• d) 3 bis 20 Gew.-% mindestens eines anionischen Tensids aus der Gruppe der Ethercarbonsäuren, Acylsarcoside mit 8 bis 24 C-Atomen in der Acylgruppe, Sulfobernsteinsäuremono- und/oder -dialkylester mit 8 bis 24 C-Atomen in der Alkylgruppe und Sulfobernsteinsäuremono-alkylpolyoxyethylester mit 8 bis 24 C-Atomen in der Alkylgruppe und 1 bis 6 Oxyethylgruppen, Alpha-Olefinsulfonate mit 8 bis 24 C-Atomen und/oder Alkylsulfat- und/oder Alkylpolyglykolethersulfatsalze, und
• e) mindestens 0,01 Gew.-% mindestens zweier verschiedener Wirkstoffe, die unter die zuvor genannte Formel (II) fallen.

In a seventh preferred embodiment, detergents according to the invention contain, based on their total weight,

• a) 0.025 to 5% by weight of at least one vegetable oil selected from (sweet) almond oil, peach kernel oil, apricot kernel oil, avocado oil, sunflower oil, grape seed oil, argan oil, olive oil, wheat germ oil, pumpkin seed oil and / or jojoba oil,
• b) 0.025 to 7.5 wt .-% of at least one component according to the formula (I) described above, in which R ^{1 is} preferably a saturated or unsaturated, branched or unbranched alkyl radical having 8 to 18, more preferably 8 to 16 and in particular having 8 to 14 C atoms, and n is preferably between 15 and 25, and particularly preferably between 17 and 20,
• c) 0.025 to 7.5% by weight of ethoxylated hydrogenated castor oil having a mean degree of ethoxylation of at least 50, preferably of at least 55,
• d) 3 to 20 wt .-% of at least one anionic surfactant from the group of ether carboxylic acids, acylsarcosides having 8 to 24 carbon atoms in the acyl group, sulfosuccinic mono- and / or dialkyl ester having 8 to 24 carbon atoms in the alkyl group and sulfosuccinic mono alkylpolyoxyethyl esters having 8 to 24 carbon atoms in the alkyl group and 1 to 6 oxyethyl groups, alpha-olefin sulfonates having 8 to 24 carbon atoms and / or alkyl sulfate and / or alkylpolyglycol ether sulfate salts, and
• e) at least 0.01% by weight of at least two different active substances which fall under the abovementioned formula (II).

• a) 0,025 bis 5 Gew.-% mindestens eines pflanzlichen Öls, ausgewählt aus (süßem) Mandelöl, Pfirsichkernöl, Aprikosenkernöl, Avocadoöl, Sonnenblumenöl, Traubenkernöl, Arganöl, Olivenöl, Weizenkeimöl, Kürbiskernöl und/oder Jojobaöl,
• b) 0,025 bis 7,5 Gew.-% mindestens einer Komponente gemäß der zuvor beschriebenen Formel (I), in der R¹ bevorzugt für einen gesättigten oder ungesättigten, verzweigten oder unverzweigten Alkylrest mit 8 bis 18, mehr bevorzugt mit 8 bis 16 und insbesondere mit 8 bis 14 C-Atomen, und n bevorzugt für eine Zahl zwischen 15 und 25, und insbesondere bevorzugt für eine Zahl zwischen 17 und 20 steht,
• c) 0,025 bis 7,5 Gew.-% ethoxyliertes hydriertes Rizinusöl mit einem mittleren Ethoxylierungsgrad von mindestens 50, bevorzugt von mindestens 55,
• d) 3 bis 20 Gew.-% mindestens eines anionischen Tensids aus der Gruppe der Ethercarbonsäuren, Acylsarcoside mit 8 bis 24 C-Atomen in der Acylgruppe, Sulfobernsteinsäuremono- und/oder -dialkylester mit 8 bis 24 C-Atomen in der Alkylgruppe und Sulfobernsteinsäuremono-alkylpolyoxyethylester mit 8 bis 24 C-Atomen in der Alkylgruppe und 1 bis 6 Oxyethylgruppen, Alpha-Olefinsulfonate mit 8 bis 24 C-Atomen und/oder Alkylsulfat- und/oder Alkylpolyglykolethersulfatsalze,
• e) 0,5 bis 15 Gew.-% mindestens eines zwitterionischen und/oder amphoteren Tensids, und
• f) mindestens 0,01 Gew.-% mindestens zweier verschiedener Wirkstoffe enthalten, die unter die zuvor genannte Formel (II) fallen.

Within this embodiment, it is more preferable if the cleaning agents according to the invention - based on their total weight -

• a) 0.025 to 5% by weight of at least one vegetable oil selected from (sweet) almond oil, peach kernel oil, apricot kernel oil, avocado oil, sunflower oil, grape seed oil, argan oil, olive oil, wheat germ oil, pumpkin seed oil and / or jojoba oil,
• b) 0.025 to 7.5 wt .-% of at least one component according to the formula (I) described above, in which R ^{1 is} preferably a saturated or unsaturated, branched or unbranched alkyl radical having 8 to 18, more preferably 8 to 16 and in particular having 8 to 14 C atoms, and n is preferably between 15 and 25, and particularly preferably between 17 and 20,
• c) 0.025 to 7.5% by weight of ethoxylated hydrogenated castor oil having a mean degree of ethoxylation of at least 50, preferably of at least 55,
• d) 3 to 20 wt .-% of at least one anionic surfactant from the group of ether carboxylic acids, acylsarcosides having 8 to 24 carbon atoms in the acyl group, sulfosuccinic mono- and / or dialkyl ester having 8 to 24 carbon atoms in the alkyl group and sulfosuccinic mono alkylpolyoxyethyl esters having 8 to 24 carbon atoms in the alkyl group and 1 to 6 oxyethyl groups, alpha-olefin sulfonates having 8 to 24 carbon atoms and / or alkyl sulfate and / or alkyl polyglycol ether sulfate salts,
• e) 0.5 to 15 wt .-% of at least one zwitterionic and / or amphoteric surfactant, and
• f) contain at least 0.01 wt .-% of at least two different active ingredients, which fall under the aforementioned formula (II).

• a) 0,05 bis 3 Gew.-% mindestens eines pflanzlichen Öls, ausgewählt aus (süßem) Mandelöl, Avocadoöl, Sonnenblumenöl, Olivenöl und/oder Jojobaöl,
• b) 0,05 bis 5 Gew.-% mindestens einer der unter der INCI-Bezeichnung PEG-18 Glyceryl Oleate/Cocoate bekannten Verbindung gemäß der zuvor genannten Formel (I),
• c) 0,05 bis 5 Gew.-% ethoxyliertes hydriertes Rizinusöl mit einem mittleren Ethoxylierungsgrad von mindestens 60,
• d) 5 bis 15 Gew.-% geradkettige oder verzweigte Alkylethersulfate, die einen Alkylrest mit 8 bis 18 und insbesondere mit 10 bis 16 C-Atomen sowie 1 bis 6 und insbesondere 2 bis 4 Ethylenoxideinheiten enthalten,
• e) 2 bis 7,5 Gew.-% mindestens eines der unter der INCI-Bezeichnung bekannten Tenside Cocamidopropylbetain und Disodium Cocoamphodiacetate, und
• f) mindestens 0,1 Gew.-% Benzoesäure und/oder ein Alkalimetallsalz der Benzoesäure sowie Salicylsäure und/oder ein Alkalimetallsalz der Salicylsäure enthalten.

Within this embodiment, it is particularly preferred if the cleaning agents according to the invention - based on their total weight -

• a) from 0.05 to 3% by weight of at least one vegetable oil selected from (sweet) almond oil, avocado oil, sunflower oil, olive oil and / or jojoba oil,
• b) 0.05 to 5% by weight of at least one compound known under the INCI name PEG-18 Glyceryl Oleate / Cocoate according to the abovementioned formula (I),
• c) 0.05 to 5% by weight of ethoxylated hydrogenated castor oil having a mean degree of ethoxylation of at least 60,
• d) 5 to 15% by weight of straight-chain or branched alkyl ether sulfates which contain an alkyl radical having 8 to 18 and in particular 10 to 16 C atoms and 1 to 6 and in particular 2 to 4 ethylene oxide units,
• e) 2 to 7.5% by weight of at least one of the surfactants cocamidopropyl betaine and disodium cocoamphodiacetate known under the INCI name, and
• f) at least 0.1 wt .-% benzoic acid and / or an alkali metal salt of benzoic acid and salicylic acid and / or an alkali metal salt of salicylic acid.

Particularly preferred cleaning agents within this embodiment have pH values in the range of from 3 to 5.5, more preferably from 3.5 to 5, and especially from 4 to 4.5.

At earlier points in this application, it has already been stated that preferred cleaning agents according to the invention, in addition to their cleaning action, should have a high skin care effect, so that optimally only one product must be used for cleaning and care of the skin (combination preparation).

Consumers typically use a deodorant after the daily shower to prevent and / or relieve body odors caused by sweating.

It would be desirable if a previously mentioned preparation would also have a deodorizing effect, so that cleaning, care and deodorization of the skin could be done in one application step. This could, for example, be an advantage when traveling.

In an eighth preferred embodiment, the cleaning agents according to the invention therefore additionally contain at least one deodorizing agent.

in der

• – R² bevorzugt für eine Methyl-, Ethyl-, Propyl-, Isopropyl-, Butyl-, Pentyl-, Hexyl-, Hydroxymethyl-, Hydroxyethyl-, Ethylglycol-, Hydroxypropyl- oder 1,2-Dihydroxypropylgruppe,
• – R³ bevorzugt für Wasserstoff oder eine Methyl-, Ethyl-, Propyl-, Isopropyl-, Butyl-, Pentyl-, Hexyl-, Heptyl-, Octyl-, Benzyl-, -CH₂-O-CH(C₂H₅)-CH₂CH₂CH₂CH₃-Gruppe, und
• – R⁴ bevorzugt für Wasserstoff oder eine Methyl-, Ethyl-, Propyl-, Isopropyl-, Butyl-, Benzylgruppe steht,

mit der Maßgabe, dass R³ und R⁴ nicht gleichzeitig für Wasserstoff stehen.Suitable deodorizing agents which can be added to the cleaning agents according to the invention are, for example, active ingredients which fall under the following formula (III)

in the

• R ^{2 is} preferably a methyl, ethyl, propyl, isopropyl, butyl, pentyl, hexyl, hydroxymethyl, hydroxyethyl, ethyl glycol, hydroxypropyl or 1,2-dihydroxypropyl group,
• R ^{3 is} preferably hydrogen or a methyl, ethyl, propyl, isopropyl, butyl, pentyl, hexyl, heptyl, octyl, benzyl, -CH ₂ -O-CH (C ₂ H ₅ ) -CH ₂ CH ₂ CH ₂ CH ₃ group, and
• R ⁴ preferably represents hydrogen or a methyl, ethyl, propyl, isopropyl, butyl, benzyl group,

with the proviso that R ³ and R ^{4 are} not simultaneously hydrogen.

For use in the cleaning agents according to the invention more preferred active compounds of formula (III) contain as R ² a methyl or a hydroxymethyl group, as R ^{3 is} hydrogen or an ethyl, propyl, isopropyl, butyl, pentyl, hexyl , Heptyl, benzyl, or -CH ₂ -O-CH (C ₂ H ₅ ) -CH ₂ CH ₂ CH ₂ CH ₃ - group and as R ^{4 is} hydrogen or a methyl or benzyl group, with the proviso that R ³ and R ^{4 are} not simultaneously hydrogen.

Particularly preferred active compounds of the formula (III) are selected from at least one of the following compounds: phenoxyethanol, methylbenzyl alcohol, 2-benzylheptanol, 1,2-butylene glycol, 1,2-pentanediol, 1,2-hexanediol, 1,2-hepanediol, 1 , 2-octanediol and ethylhexylglycerol.

The one or more of the abovementioned deodorizing active ingredients may be present in the cleansing compositions according to the invention, based on their total weight, preferably in an amount of at least 0.001% by weight, more preferably of at least 0.005% by weight, particularly preferably of at least 0.01 Wt .-% and in particular of at least 0.025 wt .-% are used.

• a) 0,025 bis 5 Gew.-% mindestens eines pflanzlichen Öls, ausgewählt aus (süßem) Mandelöl, Pfirsichkernöl, Aprikosenkernöl, Avocadoöl, Sonnenblumenöl, Traubenkernöl, Arganöl, Olivenöl, Weizenkeimöl, Kürbiskernöl und/oder Jojobaöl,
• b) 0,025 bis 7,5 Gew.-% mindestens einer Komponente gemäß der zuvor beschriebenen Formel (I), in der R¹ bevorzugt für einen gesättigten oder ungesättigten, verzweigten oder unverzweigten Alkylrest mit 8 bis 18, mehr bevorzugt mit 8 bis 16 und insbesondere mit 8 bis 14 C-Atomen, und n bevorzugt für eine Zahl zwischen 15 und 25, und insbesondere bevorzugt für eine Zahl zwischen 17 und 20 steht,
• c) 0,025 bis 7,5 Gew.-% ethoxyliertes hydriertes Rizinusöl mit einem mittleren Ethoxylierungsgrad von mindestens 50, bevorzugt von mindestens 55,
• d) 3 bis 20 Gew.-% mindestens eines anionischen Tensids aus der Gruppe der Ethercarbonsäuren, Acylsarcoside mit 8 bis 24 C-Atomen in der Acylgruppe, Sulfobernsteinsäuremono- und/oder -dialkylester mit 8 bis 24 C-Atomen in der Alkylgruppe und Sulfobernsteinsäuremono-alkylpolyoxyethylester mit 8 bis 24 C-Atomen in der Alkylgruppe und 1 bis 6 Oxyethylgruppen, Alpha-Olefinsulfonate mit 8 bis 24 C-Atomen und/oder Alkylsulfat- und/oder Alkylpolyglykolethersulfatsalze, und
• e) mindestens 0,001 Gew.-% mindestens eines deodorierenden Wirkstoffes, der unter die zuvor genannte Formel (III) fällt.

In a ninth preferred embodiment, detergents according to the invention contain, based on their total weight,

• a) 0.025 to 5% by weight of at least one vegetable oil selected from (sweet) almond oil, peach kernel oil, apricot kernel oil, avocado oil, sunflower oil, grape seed oil, argan oil, olive oil, wheat germ oil, pumpkin seed oil and / or jojoba oil,
• b) 0.025 to 7.5 wt .-% of at least one component according to the formula (I) described above, in which R ^{1 is} preferably a saturated or unsaturated, branched or unbranched alkyl radical having 8 to 18, more preferably 8 to 16 and in particular having 8 to 14 C atoms, and n is preferably between 15 and 25, and particularly preferably between 17 and 20,
• c) 0.025 to 7.5% by weight of ethoxylated hydrogenated castor oil having a mean degree of ethoxylation of at least 50, preferably of at least 55,
• d) 3 to 20 wt .-% of at least one anionic surfactant from the group of ether carboxylic acids, acylsarcosides having 8 to 24 carbon atoms in the acyl group, sulfosuccinic mono- and / or dialkyl ester having 8 to 24 carbon atoms in the alkyl group and sulfosuccinic mono alkylpolyoxyethyl esters having 8 to 24 carbon atoms in the alkyl group and 1 to 6 oxyethyl groups, alpha-olefin sulfonates having 8 to 24 carbon atoms and / or alkyl sulfate and / or alkylpolyglycol ether sulfate salts, and
• e) at least 0.001 wt .-% of at least one deodorant active ingredient, which falls under the aforementioned formula (III).

• a) 0,025 bis 5 Gew.-% mindestens eines pflanzlichen Öls, ausgewählt aus (süßem) Mandelöl, Pfirsichkernöl, Aprikosenkernöl, Avocadoöl, Sonnenblumenöl, Traubenkernöl, Arganöl, Olivenöl, Weizenkeimöl, Kürbiskernöl und/oder Jojobaöl,
• b) 0,025 bis 7,5 Gew.-% mindestens einer Komponente gemäß der zuvor beschriebenen Formel (I), in der R¹ bevorzugt für einen gesättigten oder ungesättigten, verzweigten oder unverzweigten Alkylrest mit 8 bis 18, mehr bevorzugt mit 8 bis 16 und insbesondere mit 8 bis 14 C-Atomen, und n bevorzugt für eine Zahl zwischen 15 und 25, und insbesondere bevorzugt für eine Zahl zwischen 17 und 20 steht,
• c) 0,025 bis 7,5 Gew.-% ethoxyliertes hydriertes Rizinusöl mit einem mittleren Ethoxylierungsgrad von mindestens 50, bevorzugt von mindestens 55,
• d) 3 bis 20 Gew.-% mindestens eines anionischen Tensids aus der Gruppe der Ethercarbonsäuren, Acylsarcoside mit 8 bis 24 C-Atomen in der Acylgruppe, Sulfobernsteinsäuremono- und/oder -dialkylester mit 8 bis 24 C-Atomen in der Alkylgruppe und Sulfobernsteinsäuremono-alkylpolyoxyethylester mit 8 bis 24 C-Atomen in der Alkylgruppe und 1 bis 6 Oxyethylgruppen, Alpha-Olefinsulfonate mit 8 bis 24 C-Atomen und/oder Alkylsulfat- und/oder Alkylpolyglykolethersulfatsalze,
• e) 0,5 bis 15 Gew.-% mindestens eines zwitterionischen und/oder amphoteren Tensids, und
• f) 0,005 Gew.-% mindestens eines deodorierenden Wirkstoffs enthalten, der unter die zuvor genannte Formel (III) fällt, in der R² bevorzugt eine Methyl- oder eine Hydroxymethylgruppe, R³ bevorzugt Wasserstoff oder eine Ethyl-, Propyl-, Isopropyl-, Butyl-, Pentyl-, Hexyl-, Heptyl-, Benzyl-, bzw. eine -CH₂-O-CH(C₂H₅)-CH₂CH₂CH₂CH₃-Gruppe, und R⁴ bevorzugt Wasserstoff oder eine Methyl- bzw. Benzylgruppe bedeutet, mit der Maßgabe, dass R³ und R⁴ nicht gleichzeitig für Wasserstoff stehen.

Within this embodiment, it is more preferable if the cleaning agents according to the invention - based on their total weight -

• a) 0.025 to 5% by weight of at least one vegetable oil selected from (sweet) almond oil, peach kernel oil, apricot kernel oil, avocado oil, sunflower oil, grape seed oil, argan oil, olive oil, wheat germ oil, pumpkin seed oil and / or jojoba oil,
• b) 0.025 to 7.5 wt .-% of at least one component according to the formula (I) described above, in which R ^{1 is} preferably a saturated or unsaturated, branched or unbranched alkyl radical having 8 to 18, more preferably 8 to 16 and in particular having 8 to 14 C atoms, and n is preferably between 15 and 25, and particularly preferably between 17 and 20,
• c) 0.025 to 7.5% by weight of ethoxylated hydrogenated castor oil having a mean degree of ethoxylation of at least 50, preferably of at least 55,
• d) 3 to 20 wt .-% of at least one anionic surfactant from the group of ether carboxylic acids, acylsarcosides having 8 to 24 carbon atoms in the acyl group, sulfosuccinic mono- and / or dialkyl ester having 8 to 24 carbon atoms in the alkyl group and sulfosuccinic mono alkylpolyoxyethyl esters having 8 to 24 carbon atoms in the alkyl group and 1 to 6 oxyethyl groups, alpha-olefin sulfonates having 8 to 24 carbon atoms and / or alkyl sulfate and / or alkyl polyglycol ether sulfate salts,
• e) 0.5 to 15 wt .-% of at least one zwitterionic and / or amphoteric surfactant, and
• f) 0.005% by weight of at least one deodorizing active ingredient which falls under the abovementioned formula (III), in which R ^{2 is} preferably a methyl or hydroxymethyl group, R ^{3 is} preferably hydrogen or an ethyl, propyl, isopropyl , Butyl, pentyl, hexyl, heptyl, benzyl, or a -CH ₂ -O-CH (C ₂ H ₅ ) -CH ₂ CH ₂ CH ₂ CH ₃ group, and R ^{4 is} preferably hydrogen or a methyl or benzyl group, with the proviso that R ³ and R ^{4 are} not simultaneously hydrogen.

• a) 0,05 bis 3 Gew.-% mindestens eines pflanzlichen Öls, ausgewählt aus (süßem) Mandelöl, Avocadoöl, Sonnenblumenöl, Olivenöl und/oder Jojobaöl,
• b) 0,05 bis 5 Gew.-% mindestens einer der unter der INCI-Bezeichnung PEG-18 Glyceryl Oleate/Cocoate bekannten Verbindung gemäß der zuvor genannten Formel (I),
• c) 0,05 bis 5 Gew.-% ethoxyliertes hydriertes Rizinusöl mit einem mittleren Ethoxylierungsgrad von mindestens 60,
• d) 5 bis 15 Gew.-% geradkettige oder verzweigte Alkylethersulfate, die einen Alkylrest mit 8 bis 18 und insbesondere mit 10 bis 16 C-Atomen sowie 1 bis 6 und insbesondere 2 bis 4 Ethylenoxideinheiten enthalten,
• e) 2 bis 7,5 Gew.-% mindestens eines der unter der INCI-Bezeichnung bekannten Tenside Cocamidopropylbetain und Disodium Cocoamphodiacetate, und
• f) mindestens 0,01 Gew.-% mindestens einer der folgenden Verbindungen enthalten: Phenoxyethanol, Methylbenzylalkohol, 2-Benzylheptanol, 1,2-Butylenglycol, 1,2-Pentandiol, 1,2-Hexandiol, 1,2-Hepandiol, 1,2-Octandiol und/oder Ethylhexylglycerin.

Within this embodiment, it is particularly preferred if the cleaning agents according to the invention - based on their total weight -

• a) from 0.05 to 3% by weight of at least one vegetable oil selected from (sweet) almond oil, avocado oil, sunflower oil, olive oil and / or jojoba oil,
• b) 0.05 to 5% by weight of at least one compound known under the INCI name PEG-18 Glyceryl Oleate / Cocoate according to the abovementioned formula (I),
• c) 0.05 to 5% by weight of ethoxylated hydrogenated castor oil having a mean degree of ethoxylation of at least 60,
• d) 5 to 15% by weight of straight-chain or branched alkyl ether sulfates which contain an alkyl radical having 8 to 18 and in particular 10 to 16 C atoms and 1 to 6 and in particular 2 to 4 ethylene oxide units,
• e) 2 to 7.5% by weight of at least one of the surfactants cocamidopropyl betaine and disodium cocoamphodiacetate known under the INCI name, and
• f) at least 0.01% by weight of at least one of the following compounds: phenoxyethanol, methylbenzyl alcohol, 2-benzylheptanol, 1,2-butylene glycol, 1,2-pentanediol, 1,2-hexanediol, 1,2-hepanediol, 1 , 2-octanediol and / or ethylhexylglycerol.

• a) 0,05 bis 3 Gew.-% mindestens eines pflanzlichen Öls, ausgewählt aus (süßem) Mandelöl, Avocadoöl, Sonnenblumenöl, Olivenöl und/oder Jojobaöl,
• b) 0,05 bis 5 Gew.-% mindestens einer der unter der INCI-Bezeichnung PEG-18 Glyceryl Oleate/Cocoate bekannten Verbindung gemäß der zuvor genannten Formel (I),
• c) 0,05 bis 5 Gew.-% ethoxyliertes hydriertes Rizinusöl mit einem mittleren Ethoxylierungsgrad von mindestens 60,
• d) 5 bis 15 Gew.-% geradkettige oder verzweigte Alkylethersulfate, die einen Alkylrest mit 8 bis 18 und insbesondere mit 10 bis 16 C-Atomen sowie 1 bis 6 und insbesondere 2 bis 4 Ethylenoxideinheiten enthalten,
• e) 2 bis 7,5 Gew.-% mindestens eines der unter der INCI-Bezeichnung bekannten Tenside Cocamidopropylbetain und Disodium Cocoamphodiacetate,
• f) mindestens 0,1 Gew.-% Benzoesäure und/oder ein Alkalimetallsalz der Benzoesäure sowie Salicylsäure und/oder ein Alkalimetallsalz der Salicylsäure, und
• g) mindestens 0,01 Gew.-% mindestens einer der folgenden Verbindungen enthalten: Phenoxyethanol, Methylbenzylalkohol, 2-Benzylheptanol, 1,2-Butylenglycol, 1,2-Pentandiol, 1,2-Hexandiol, 1,2-Hepandiol, 1,2-Octandiol und/oder Ethylhexylglycerin.

Within this embodiment, it is particularly preferred if the cleaning agents according to the invention - based on their total weight -

• a) from 0.05 to 3% by weight of at least one vegetable oil selected from (sweet) almond oil, avocado oil, sunflower oil, olive oil and / or jojoba oil,
• b) 0.05 to 5% by weight of at least one compound known under the INCI name PEG-18 Glyceryl Oleate / Cocoate according to the abovementioned formula (I),
• c) 0.05 to 5% by weight of ethoxylated hydrogenated castor oil having a mean degree of ethoxylation of at least 60,
• d) 5 to 15% by weight of straight-chain or branched alkyl ether sulfates which contain an alkyl radical having 8 to 18 and in particular 10 to 16 C atoms and 1 to 6 and in particular 2 to 4 ethylene oxide units,
• e) 2 to 7.5% by weight of at least one of the surfactants cocamidopropyl betaine and disodium cocoamphodiacetate known under the INCI name,
• f) at least 0.1 wt .-% benzoic acid and / or an alkali metal salt of benzoic acid and salicylic acid and / or an alkali metal salt of salicylic acid, and
• g) at least 0.01% by weight of at least one of the following compounds: phenoxyethanol, methylbenzyl alcohol, 2-benzylheptanol, 1,2-butylene glycol, 1,2-pentanediol, 1,2-hexanediol, 1,2-hepanediol, 1 , 2-octanediol and / or ethylhexylglycerol.

• – nichtionische Tenside und/oder nichtionische Emulgatoren, die in den Reinigungsmitteln (bezogen auf ihr Gesamtgewicht) bevorzugt in einer Menge von 0,1 bis 7,5 Gew.-%, besonders bevorzugt von 0,25 bis 5 Gew.-% und insbesondere von 0,5 bis 3 Gew.-% eingesetzt werden können, und
• – kationische Polymere, die in den Reinigungsmitteln (bezogen auf ihr Gesamtgewicht) bevorzugt in einer Menge von 0,01 bis 5 Gew.-%, besonders bevorzugt von 0,05 bis 3 Gew.-% und insbesondere von 0,1 bis 2 Gew.-% eingesetzt werden können.

In addition to the aforementioned active ingredients, the detergents of the invention may also contain a number of other active ingredients which impart advantageous properties to them. The preferred optional active substances that can be used in the cleaning agents according to the invention include, for example:

• - Nonionic surfactants and / or nonionic emulsifiers, in the detergents (based on their total weight) preferably in an amount of 0.1 to 7.5 wt .-%, particularly preferably from 0.25 to 5 wt .-% and in particular from 0.5 to 3 wt .-% can be used, and
• Cationic polymers which are in the cleaning agents (based on their total weight) preferably in an amount of 0.01 to 5 wt .-%, particularly preferably from 0.05 to 3 wt .-% and in particular from 0.1 to 2 wt .-% can be used.

• – C₈-C₃₀-Fettsäuremono- und -diester von Anlagerungsprodukten von 1 bis 30 Mol Ethylenoxid an Glycerin,
• – Aminoxide,
• – Anlagerungsprodukte von 2 bis 50 Mol Ethylenoxid und/oder 0 bis 5 Mol Propylenoxid an lineare und verzweigte Fettalkohole mit 8 bis 30 C-Atomen, an Fettsäuren mit 8 bis 30 C-Atomen und an Alkylphenole mit 8 bis 15 C-Atomen in der Alkylgruppe,
• – Sorbitanfettsäureester und Anlagerungeprodukte von Ethylenoxid an Sorbitanfettsäureester wie beispielsweise Polysorbate,
• – Zuckerfettsäureester und Anlagerungsprodukte von Ethylenoxid an Zuckerfettsäureester,
• – Fettsäurealkanolamide,
• – Anlagerungsprodukte von Ethylenoxid an Fettamine und/oder
• – Alkylpolyglucoside.

Examples of suitable nonionic surfactants / emulsifiers include

• C ₈ -C ₃₀ -fatty acid mono- and diesters of addition products of 1 to 30 mol of ethylene oxide with glycerol,
• - amine oxides,
• - Addition products of 2 to 50 moles of ethylene oxide and / or 0 to 5 moles of propylene oxide to linear and branched fatty alcohols having 8 to 30 carbon atoms, to fatty acids having 8 to 30 carbon atoms and to alkylphenols having 8 to 15 carbon atoms in the alkyl group,
• Sorbitan fatty acid esters and adducts of ethylene oxide with sorbitan fatty acid esters such as polysorbates,
• Sugar fatty acid esters and addition products of ethylene oxide with sugar fatty acid esters,
• Fatty acid alkanolamides,
• - Addition products of ethylene oxide with fatty amines and / or
• - Alkyl polyglucosides.

Particularly suitable nonionic surfactants are alkyl oligoglucosides, in particular alkyl oligoglucosides based on hydrogenated C _12/14 cocoalcohol having a DP of 1-3, as are commercially available, for example, under the INCI name "Coco-Glucoside", and fatty acid alkanolamides, in particular C ₈ -C ₂₄ fatty acid (di) ethanolamides.

Further preferred nonionic surfactants are the C ₈ -C ₃₀ fatty acid mono- and diesters of addition products of 1 to 30 moles of ethylene oxide with glycerol. Particularly preferred are the C ₁₀ -C ₁₆ -Fetsäuremono- and diesters of addition products of 1 to 10 moles of ethylene oxide to glycerol. Especially preferred is the PEG-7 glyceryl cocoate known under the INCI name.

• – quaternisierte Cellulose-Derivate, wie sie unter den Bezeichnungen Celquat^® und Polymer JR^® im Handel erhältlich sind,
• – hydrophob modifizierte Cellulosederivate, beispielsweise die unter dem Handelsnamen SoftCat^® vertriebenen kationischen Polymere,
• – kationische Alkylpolyglycoside,
• – kationiserter Honig, beispielsweise das Handelsprodukt Honeyquat^® 50,
• – kationische Guar-Derivate, wie insbesondere die unter den Handelsnamen Cosmedia^® Guar N-Hance^® und Jaguar^® vertriebenen Produkte,
• – polymere Dimethyldiallylammoniumsalze und deren Copolymere mit Estern und Amiden von Acrylsäure und Methacrylsäure. Die unter den Bezeichnungen Merquat^® 100 (Poly(dimethyldiallylammoniumchlorid)) und Merquat^® 550 (Dimethyldiallylammoniumchlorid-Acrylamid-Copolymer) im Handel erhältlichen Produkte sind Beispiele für solche kationischen Polymere,
• – Copolymere des Vinylpyrrolidons mit quaternierten Derivaten des Dialkylaminoalkylacrylats und -methacrylats, wie beispielsweise mit Diethylsulfat quaternierte Vinylpyrrolidon-Dimethylaminoethylmethacrylat-Copolymere. Solche Verbindungen sind unter den Bezeichnungen Gafquat^® 734 und Gafquat^® 755 im Handel erhältlich,
• – Vinylpyrrolidon-Vinylimidazoliummethochlorid-Copolymere, wie sie unter den Bezeichnungen Luviquat^® FC 370, FC 550, FC 905 und HM 552 angeboten werden,
• – quaternierter Polyvinylalkohol, sowie die unter den Bezeichnungen
• – Polyquaternium 2, Polyquaternium 17, Polyquaternium 18, Polyquaternium-24, Polyquaternium 27, Polyquaternium-32, Polyquaternium-37, Polyquaternium 74 und Polyquaternium 89 bekannten Polymere.

Suitable cationic polymers are, for example:

• - quaternized cellulose derivatives, such as are available under the names of Celquat ^® and Polymer JR ^® commercially
• - hydrophobically modified cellulose derivatives, for example those sold under the trade name SOFTCAT ^® cationic polymers,
• Cationic alkyl polyglycosides,
• - cationized honey, for example the commercial product Honeyquat ^® 50,
• - cationic guar derivatives, such as in particular the products sold under the trade names Cosmedia® ^® guar N-Hance ^® and Jaguar ^®,
• - Dimethyldiallylammoniumsalze polymeric and their copolymers with esters and amides of acrylic acid and methacrylic acid. Under the names Merquat ^® 100 (Poly (dimethyldiallylammonium chloride)) and Merquat ^® 550 (dimethyldiallylammonium chloride-acrylamide copolymer) are examples of such cationic polymers,
• - Copolymers of vinylpyrrolidone with quaternized derivatives of dialkylaminoalkyl acrylate and methacrylate, such as diethyl sulfate quaternized vinylpyrrolidone-dimethylaminoethyl methacrylate copolymers. Such compounds are sold under the names Gafquat ^® 734 and Gafquat ^® 755 commercially,
• - vinylpyrrolidone vinylimidazoliummethochloride copolymers, such as those offered under the names Luviquat.RTM ^® FC 370, FC 550, FC 905 and HM 552,
• - Quaternized polyvinyl alcohol, as well as those under the names
• Polyquaternium 2, Polyquaternium 17, Polyquaternium 18, Polyquaternium-24, Polyquaternium 27, Polyquaternium-32, Polyquaternium-37, Polyquaternium 74 and Polyquaternium 89 known polymers.

Preferred cationic polymers are quaternized cellulose polymers, cationic guar derivatives and / or cationic polymers based on acrylic acid (derivative), which are particularly preferably selected from the polymers known by the INCI names Guar Hydroxypropyltrimonium Chloride, Polyquaternium-6, Polyquaternium-7, Polyquaternium-10 , Polyquaternium-37 and / or Polyquaternium-67.

Particularly preferred for use in the cleaning agents according to the invention is a cationic polymer known under the INCI name Polyquaternium-7.

• – Vitamine, Vitaminderivate und/oder Vitaminvorstufen und/oder
• – Pflanzenextrakte.

Other optional components that may be used in the detergents of the invention include, for example

• - Vitamins, vitamin derivatives and / or vitamin precursors and / or
• - Plant extracts.

• • Vitamin B₁ (Thiamin)
• • Vitamin B₂ (Riboflavin)
• • Vitamin B₃. Unter dieser Bezeichnung werden häufig die Verbindungen Nicotinsäure und Nicotinsäureamid (Niacinamid) geführt.
• • Vitamin B₅ (Pantothensäure und Panthenol). Im Rahmen dieser Gruppe wird bevorzugt das Panthenol eingesetzt. Einsetzbare Derivate des Panthenols sind insbesondere die Ester und Ether des Panthenols sowie kationisch derivatisierte Panthenole. Einzelne Vertreter sind beispielsweise das Panthenoltriacetat, der Panthenolmonoethylether und dessen Monoacetat sowie kationische Panthenolderivate.
• • Vitamin B₆ (Pyridoxin sowie Pyridoxamin und Pyridoxal).

Vitamin C (Ascorbinsäure): die Verwendung in Form des Palmitinsäureesters, der Glucoside oder Phosphate kann bevorzugt sein. Die Verwendung in Kombination mit Tocopherolen kann ebenfalls bevorzugt sein.
Vitamin E (Tocopherole, insbesondere α-Tocopherol).
Vitamin F: unter dem Begriff ”Vitamin F” werden üblicherweise essentielle Fettsäuren, insbesondere Linolsäure, Linolensäure und Arachidonsäure, verstanden.
Vitamin H: Als Vitamin H wird die Verbindung (3aS,4S,6aR)-2-Oxohexahydrothienol[3,4-d]-imidazol-4-valeriansäure bezeichnet, für die sich aber zwischenzeitlich der Trivialname Biotin durchgesetzt hat.Suitable vitamins are preferably the following vitamins, provitamins and vitamin precursors and their derivatives:
Vitamin A: the group of substances called vitamin A includes retinol (vitamin A ₁ ) and 3,4-didehydroretinol (vitamin A ₂ ). The β-carotene is the provitamin of retinol. As vitamin A component, for example, vitamin A acid and its esters, vitamin A aldehyde and vitamin A alcohol and its esters such as palmitate and acetate into consideration.
Vitamin B: belong to the vitamin B group or to the vitamin B complex among others

• • Vitamin B ₁ (thiamine)
• • Vitamin B ₂ (riboflavin)
• • Vitamin B ₃ . Under this name, the compounds nicotinic acid and nicotinamide (niacinamide) are often performed.
• • Vitamin B ₅ (pantothenic acid and panthenol). Within this group the panthenol is preferred. Useful derivatives of panthenol are, in particular, the esters and ethers of panthenol, as well as cationically derivatized panthenols. Individual representatives are, for example, panthenol triacetate, panthenol monoethyl ether and its monoacetate, as well as cationic panthenol derivatives.
• • Vitamin B ₆ (pyridoxine and pyridoxamine and pyridoxal).

Vitamin C (ascorbic acid): use in the form of palmitic acid ester, glucosides or phosphates may be preferred. The use in combination with tocopherols may also be preferred.
Vitamin E (tocopherols, especially α-tocopherol).
Vitamin F: the term "vitamin F" is usually understood as meaning essential fatty acids, in particular linoleic acid, linolenic acid and arachidonic acid.
Vitamin H: Vitamin H is the compound (3aS, 4S, 6aR) -2-oxohexahydrothienol [3,4-d] -imidazole-4-valeric acid, for which, in the meantime, the trivial name biotin has prevailed.

The cleaning agents according to the invention may preferably contain vitamins, provitamins and vitamin precursors from groups A, B, E and H.

Particularly preferred are nicotinic acid amide, biotin, pantolactone and / or panthenol.

Vitamins, vitamin derivatives and / or vitamin precursors may be present in the cleansing compositions (based on their total weight) preferably in an amount of from 0.001 to 10% by weight, more preferably from 0.005 to 7.5% by weight and in particular from 0.01 to 5 % By weight.

Suitable plant extracts are extracts that can be made from any part of a plant.

Usually these extracts are produced by extraction of the whole plant. However, in individual cases it may also be preferred to prepare the extracts exclusively from flowers and / or leaves of the plant.

Particularly suitable are the extracts of green tea, oak bark, stinging nettle, witch hazel, hops, chamomile, burdock root, horsetail, linden, lychee, almond, aloe vera, spruce needle, horse chestnut, sandalwood, juniper, coconut, mango, apricot, lime , Wheat, Kiwi, Melon, Orange, Grapefruit, Sage, Rosemary, Birch, Mallow, Meadowfoam, Quendel, Yarrow, Thyme, Melissa, Hominy, Coltsfoot, Marshmallow, Ginseng, Ginger root, Echinacea purpurea, Olea europea, Boerhavia diffusa roots, Foeniculum vulgaris and Apim graveolens.

Particularly preferred for use in the detergents according to the invention are the extracts of green tea, stinging nettle, witch hazel, chamomile, aloe vera, ginseng, Echinacea purpurea, Olea europea and / or Boerhavia diffusa roots.

As extraction agent for the preparation of said plant extracts water, alcohols and mixtures thereof can be used. Among the alcohols are lower alcohols such as ethanol and isopropanol, but especially polyhydric alcohols such as ethylene glycol and propylene glycol, both as the sole extractant and in admixture with water, are preferred. Plant extracts based on water / propylene glycol in a ratio of 1:10 to 10: 1 have proven to be particularly suitable.

The plant extracts can be used both in pure and in diluted form. If they are used in diluted form, they usually contain about 2-80 wt .-% of active substance and as a solvent used in their extraction agent or extractant mixture.

The plant extracts may be present in the inventive compositions (based on their total weight) preferably in an amount of from 0.01 to 10% by weight, more preferably from 0.05 to 7.5% by weight and in particular from 0.1 to 5 % By weight.

• – UV-Filter,
• – Verdickungsmittel wie Gelatine oder Pflanzengumme, beispielsweise Agar-Agar, Guar-Gum, Alginate, Xanthan-Gum, Gummi arabicum, Karaya-Gummi, Johannisbrotkernmehl, Leinsamengummen, Dextrane, Cellulose-Derivate, z. B. Methylcellulose, Hydroxyalkylcellulose und Carboxymethylcellulose, Stärke-Fraktionen und Derivate wie Amylose, Amylopektin und Dextrine, Tone und Schichtsilikate wie z. B. Bentonit oder vollsynthetische Hydrokolloide wie z. B. Polyvinylalkohol, die Ca-, Mg- oder Zn-Seifen,
• – Strukturanten wie Maleinsäure und Milchsäure,
• – Farbstoffe zum Anfärben des Mittels,
• – Substanzen zur Einstellung des pH-Wertes, beispielsweise α- und β-Hydroxycarbonsäuren wie Citronensäure, Milchsäure, Äpfelsäure, Glycolsäure,
• – Wirkstoffe wie Bisabolol,
• – Komplexbildner wie EDTA, NTA, β-Alanindiessigsäure und Phosphonsäuren,
• – Ceramide. Unter Ceramiden werden N-Acylsphingosin (Fettsäureamide des Sphingosins) oder synthetische Analogen solcher Lipide (sogenannte Pseudo-Ceramide) verstanden,
• – Treibmittel wie Propan-Butan-Gemische, N₂O, Dimethylether, CO₂ und Luft,
• – Antioxidantien,
• – Perlglanzmittel wie EGDS oder PEG-3 Distearate,
• – Trübungsmittel wie die unter der INCI-Bezeichnung Styrene/Acrylates-Copolymer bekannten Verbindungen,
• – Viskositätsregler wie Elektrolytsalze (NaCl).

Other active ingredients, auxiliaries and additives which can be used in the cleaning agents according to the invention are, for example:

• - UV filters,
• Thickeners such as gelatin or vegetable gums, for example agar-agar, guar gum, alginates, xanthan gum, gum arabic, karaya gum, locust bean gum, linseed gums, dextrans, cellulose derivatives, e.g. As methylcellulose, hydroxyalkylcellulose and carboxymethylcellulose, starch fractions and derivatives such as amylose, amylopectin and dextrins, clays and phyllosilicates such. As bentonite or fully synthetic hydrocolloids such. As polyvinyl alcohol, the Ca, Mg or Zn soaps,
• - structurants such as maleic acid and lactic acid,
• Dyes for staining the agent,
• Substances for adjusting the pH, for example α- and β-hydroxycarboxylic acids such as citric acid, lactic acid, malic acid, glycolic acid,
• - active substances such as bisabolol,
• Complexing agents such as EDTA, NTA, β-alaninediacetic acid and phosphonic acids,
• - Ceramides. Ceramides are understood as meaning N-acylsphingosine (fatty acid amides of sphingosine) or synthetic analogues of such lipids (so-called pseudo-ceramides),
• Propellants such as propane-butane mixtures, N ₂ O, dimethyl ether, CO ₂ and air,
• - antioxidants,
• Pearlescing agents such as EGDS or PEG-3 distearates,
• Opacifiers, such as the compounds known under the INCI name styrene / acrylates copolymer,
• - Viscosity regulator such as electrolyte salts (NaCl).

The cleaning agents of the invention have excellent properties in the application to the skin.

In addition to cleaning, they care for the skin and dry it less than commercial cleaners that contain no vegetable oil components.

The cleansing agents have excellent foaming properties: they quickly foam up, spread well over the skin and leave the skin feeling pleasant after the rinse.

The cleaning agents according to the invention can be stabilized over a long period even at low pH values (up to about pH 3) and thickened with customary electrolytes, such as sodium chloride.

As a result, it is also possible to produce acidic, antibacterial, nourishing skin cleansers which are suitable for the treatment of sensitive skin areas and / or the treatment of the mucous membrane. Another advantage of the cleaning agents according to the invention is that they are suitable for the incorporation of further hydrophobic components (such as Deowirkstoffen or perfume oils) without loss of stability. The production of 3in1 products is therefore possible.

A second object of the invention is the use of the cleaning agent according to the invention as a nourishing antibacterial cosmetic skin cleanser.

Examples

The following table contains examples of cleaning compositions according to the invention (shower gel compositions). Formulation Examples 3 and 4 relate to deodorant shower gels.

Unless stated otherwise, the quantities in the table refer to% by weight. 1 2 3 4 Sodium laureth sulfate (2EO, 70%) 12 12 15 15 Cocamidopropylbetaine (40%) 10 12 12.5 12.5 sodium benzoate 0.5 0.45 0.4 0.4 sodium salicylate 0.2 0.25 0.23 0.23 Polyquaternium-7 (clear solution, AS about 9%) 1.5 1.5 1.5 1.5 Cremophor CO 60 ^®1 1.5 1.5 1.25 1.05 Almond oil, sweet 0.4 0.7 0.5 0.5 Antil ^®2 171 1 1.5 1.2 1.2 Perfume 1 1 1 1 citric acid 0.5 0.7 0.3 0.3 Electrolyte (eg NaCl for setting a viscosity of 8,000 to 9,000 mPas *) qs qs qs qs 174917 Protectate ^®3 Mod 3 - - 0.1 0.1 phenoxyethanol - - 0.25 - Sensiva ^®4 SC 50 - - 0.05 0.05 water ad 100 ad 100 ad 100 ad 100 * The respective viscosity was determined using a Haake VT550 rotational viscometer at a temperature of 20 ° C .; Measuring device MV; Spindle MV II; 8 rpm.

The cleaning agents 1 to 4 have an excellent foam development and a very good spreadability of the foam. They leave behind the rinsing on the skin a pleasant, neat feeling.

Shower gels 3 and 4 also have a deodorant effect. The deodorant effect on the skin lasts up to 24 hours.

• 1 INCI-Bezeichnung: PEG-60 Hydrogenated Castor Oil; BASF
• 2 INCI-Bezeichnung: PEG-18 Glyceryl Oleate/Cocoate; Goldschmidt
• 3 INCI-Bezeichnung: 2-Benzylheptanol, Phenoxyethanol, Heliotropine; Symrise
• 4 INCI-Bezeichnung: Ethylhexyloxaglycerin; Schülke & Mayr

The following commercial products were used:

• 1 INCI name: PEG-60 Hydrogenated Castor Oil; BASF
• 2 INCI name: PEG-18 Glyceryl Oleate / Cocoate; Goldschmidt
• 3 INCI name: 2-benzylheptanol, phenoxyethanol, heliotropins; Symrise
• 4 INCI name: ethylhexyloxaglycerin; Schülke & Mayr

QUOTES INCLUDE IN THE DESCRIPTION

This list of the documents listed by the applicant has been generated automatically and is included solely for the better information of the reader. The list is not part of the German patent or utility model application. The DPMA assumes no liability for any errors or omissions.

Cited patent literature

• WO 2010/009978 [0007]

Claims (10)

Detergent containing in a cosmetically acceptable carrier a) at least one vegetable oil, b) at least one component of the following formula (I),

in which R ^{1 is} a saturated or unsaturated, branched or unbranched alkyl radical having 8 to 22 C atoms, and n is a number between 10 and 30, and c) ethoxylated hydrogenated castor oil having a mean degree of ethoxylation of at least 45. Cleaning agent according to claim 1, characterized in that it - based on its total weight - 0.01 to 10 wt .-%, preferably 0.025 to 5 wt .-%, more preferably 0.05 to 3 wt .-%, particularly preferably 0.075 to 2 wt .-% and in particular 0.1 to 1 wt .-% of at least one vegetable oil. Cleaning agent according to one of claims 1 or 2, characterized in that it - based on its total weight - 0.01 to 10 wt .-%, preferably 0.025 to 7.5 wt .-%, more preferably 0.05 to 5 wt. -%, particularly preferably 0.1 to 3 wt .-% and in particular 0.5 to 2 wt .-% of at least one component of formula (I), in which R ^{1 is} a saturated or unsaturated, branched or unbranched alkyl radical 8 to 18, preferably having 8 to 16 and in particular having 8 to 14 carbon atoms, and n is a number between 15 and 25, preferably between 17 and 20. Cleaning agent according to one of claims 1 to 3, characterized in that it - based on its total weight - 0.01 to 10 wt .-%, preferably 0.025 to 7.5 wt .-%, more preferably 0.05 to 5 wt. %, more preferably 0.1 to 3 wt .-% and in particular 0.5 to 2 wt .-% ethoxylated hydrogenated castor oil having a mean degree of ethoxylation of at least 50, preferably of at least 55 and in particular of at least 60 contains. Cleaning agent according to one of claims 1 to 4, characterized in that it - based on its total weight - at least 0.01 wt .-%, preferably at least 0.05 wt .-%, more preferably at least 0.1 wt .-%, particularly preferably contains at least 0.2 wt .-% and in particular at least 0.3 wt .-% of at least two different components which correspond to the following formula (II)

and in which - the radical R is a hydrogen atom, an alkali metal ion or a linear or branched C ₁ -C ₄ alkyl group, and - the radical R ^{1 can be} ortho, meta or para to the -COOR group and a Represents hydrogen atom or a hydroxyl group. Detergent according to claim 5, characterized in that it contains a combination of benzoic acid and / or an alkali metal salt of benzoic acid and salicylic acid and / or an alkali metal salt of salicylic acid. Cleaning agent according to one of claims 1 to 6, characterized in that it has a pH in the range of 3 to 5.5, preferably 3.5 to 5 and in particular from 4 to 4.5. Detergent according to one of claims 1 to 7, characterized in that it - based on its total weight - at least 0.001 wt .-%, preferably at least 0.005 wt .-%, particularly preferably at least 0.01 wt .-% and in particular at least 0.025 wt .-% of at least one compound of the following formula (III),

in which - R ^{2 is} a methyl, ethyl, propyl, isopropyl, butyl, pentyl, hexyl, hydroxymethyl, hydroxyethyl, ethyl glycol, hydroxypropyl or 1,2-dihydroxypropyl group, - R ^{3 is} Hydrogen or a methyl, ethyl, propyl, isopropyl, butyl, pentyl, hexyl, heptyl, octyl, benzyl, -CH ₂ -O-CH (C ₂ H ₅ ) -CH ₂ CH ₂ CH ₂ CH ₃ group, and - R ^{4 is} hydrogen or a methyl, ethyl, propyl, isopropyl, butyl, benzyl group, provided that R ³ and R ^{4 are} not simultaneously hydrogen. Detergent according to one of Claims 1 to 8, characterized in that it contains phenoxyethanol, methylbenzyl alcohol, 2-benzylheptanol, 1,2-butylene glycol, 1,2-pentanediol, 1,2-hexanediol, 1,2-hepanediol, 1,2- Octanediol and / or ethylhexylglycerol contains. Use of a cleaning agent according to any one of claims 1 to 9 as a nourishing antibacterial cosmetic skin cleanser.