DE102009035408A1 - Gasification of carbonaceous fuels with increased conversion rate - Google Patents
Gasification of carbonaceous fuels with increased conversion rate Download PDFInfo
- Publication number
- DE102009035408A1 DE102009035408A1 DE200910035408 DE102009035408A DE102009035408A1 DE 102009035408 A1 DE102009035408 A1 DE 102009035408A1 DE 200910035408 DE200910035408 DE 200910035408 DE 102009035408 A DE102009035408 A DE 102009035408A DE 102009035408 A1 DE102009035408 A1 DE 102009035408A1
- Authority
- DE
- Germany
- Prior art keywords
- fuel
- dust
- raw
- gasification
- gas purification
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 239000000446 fuel Substances 0.000 title claims abstract description 30
- 238000002309 gasification Methods 0.000 title claims abstract description 24
- 238000006243 chemical reaction Methods 0.000 title description 2
- 239000000428 dust Substances 0.000 claims abstract description 23
- 239000002245 particle Substances 0.000 claims abstract description 5
- 238000000034 method Methods 0.000 claims description 21
- 238000000746 purification Methods 0.000 claims description 10
- 238000001035 drying Methods 0.000 claims description 5
- 239000012065 filter cake Substances 0.000 claims description 4
- 238000000227 grinding Methods 0.000 claims description 4
- 239000012528 membrane Substances 0.000 claims description 2
- 239000003245 coal Substances 0.000 description 27
- 239000007789 gas Substances 0.000 description 18
- 239000002002 slurry Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 239000002817 coal dust Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000002006 petroleum coke Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- BUHVIAUBTBOHAG-FOYDDCNASA-N (2r,3r,4s,5r)-2-[6-[[2-(3,5-dimethoxyphenyl)-2-(2-methylphenyl)ethyl]amino]purin-9-yl]-5-(hydroxymethyl)oxolane-3,4-diol Chemical compound COC1=CC(OC)=CC(C(CNC=2C=3N=CN(C=3N=CN=2)[C@H]2[C@@H]([C@H](O)[C@@H](CO)O2)O)C=2C(=CC=CC=2)C)=C1 BUHVIAUBTBOHAG-FOYDDCNASA-N 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- RHZUVFJBSILHOK-UHFFFAOYSA-N anthracen-1-ylmethanolate Chemical compound C1=CC=C2C=C3C(C[O-])=CC=CC3=CC2=C1 RHZUVFJBSILHOK-UHFFFAOYSA-N 0.000 description 1
- 239000003830 anthracite Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/02—Dust removal
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/46—Gasification of granular or pulverulent flues in suspension
- C10J3/48—Apparatus; Plants
- C10J3/50—Fuel charging devices
- C10J3/506—Fuel charging devices for entrained flow gasifiers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2200/00—Details of gasification apparatus
- C10J2200/15—Details of feeding means
- C10J2200/156—Sluices, e.g. mechanical sluices for preventing escape of gas through the feed inlet
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0903—Feed preparation
- C10J2300/0906—Physical processes, e.g. shredding, comminuting, chopping, sorting
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0903—Feed preparation
- C10J2300/0909—Drying
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/16—Integration of gasification processes with another plant or parts within the plant
- C10J2300/1693—Integration of gasification processes with another plant or parts within the plant with storage facilities for intermediate, feed and/or product
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
- C10J2300/1807—Recycle loops, e.g. gas, solids, heating medium, water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
- C10J2300/1846—Partial oxidation, i.e. injection of air or oxygen only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/02—Dust removal
- C10K1/024—Dust removal by filtration
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/02—Dust removal
- C10K1/026—Dust removal by centrifugal forces
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Industrial Gases (AREA)
Abstract
In einer Vergasungseinrichtung wird zu Brennstaub gemahlener kohlenstoffhaltiger Rohbrennstoff zu einem reich an H und CO haltigen Rohgas vergast. Aus dem Rohgas ausgefilterte Partikel, insbesondere nicht konvertierter Brennstaub, werden dem Rohbrennstoff wieder zugemischt. Hierdurch kann eine nicht optimale Umsetzung des Brennstoffs, die auf Unzulänglichkeiten der Vergasungseinrichtung oder deren Betriebsparameter beruhen mag, verbessert werden, der Anlagenwirkungsgrad erhöht werden und der Entsorgungsaufwand minimiert werden.In a gasification device, carbonaceous raw fuel milled to give dust is gasified to a raw gas rich in H and CO. From the raw gas filtered particles, in particular unconverted fuel dust are added to the raw fuel again. As a result, a non-optimal implementation of the fuel, which may be based on shortcomings of the gasification device or its operating parameters, be improved, the system efficiency can be increased and the disposal costs are minimized.
Description
Die Erfindung betrifft ein Verfahren zur Brennstoffeinspeisung für eine Flugstromvergasungsanlage, in der Brennstaub bei einem Druck zwischen 0,1 und 1 MPa zu einem reich an H und CO haltigen Rohgas vergast wird.The The invention relates to a method for fuel feed for an entrained flow gasification plant, in the dust at a pressure between 0.1 and 1 MPa to a rich in H and CO containing crude gas is gassed.
Um
Kohle mittels Flugstromvergasung mit trockener Kohleeinspeisung
vergasen zu können ist es erforderlich, die Kohle zu trocknen
und zu mahlen sowie die Kohle einschließlich Fördergas
auf den Vergasungsdruck anzuheben. Dies geschieht nach heutigem
Stand der Technik in folgenden, wesentlichen Verfahrensschritten,
siehe
Die
Prozessschritte (
Die gesamte Prozesskette der Kohleaufbereitung von der Rohkohle bis zum Flugstromvergaser stellt einen wesentlichen Anteil des Aufwandes für eine Kohlevergasungsanlage dar. Für Kohlen mit hohem Inkohlungsgrad wie Steinkohle, Anthrazit, Petrolkoks konkurriert dieses Verfahren zudem mit der Slurryvergasung, wobei die Slurry-Vergasung bzgl. der Investitionskosten meist im Vorteil steht.The entire process chain of coal processing from raw coal to to Flugstromvergaser represents a significant proportion of the effort for a coal gasification plant. For coal with high coalification such as hard coal, anthracite, petroleum coke competes this method also with the slurry gasification, wherein the slurry gasification regarding the investment costs is usually in the advantage.
Aus
der
Der Erfindung liegt die Aufgabe zugrunde, bei einer Flugstromvergasungsanlage mit pneumatischer Brennstaubeinspeisung die Anforderungen für eine nach Möglichkeit vollständige Umsetzung des zugeführten Brennstaubs zu reduzieren.Of the Invention is based on the object in an entrainment gasification plant with pneumatic fuel dust feed the requirements for a if possible, complete implementation of the supplied To reduce fuel dust.
Die
Aufgabe wird durch ein Verfahren mit den Merkmalen des Anspruchs
1 gelöst.The
The object is achieved by a method having the features of the
Erfindungsgemäß wird der in der Rohgasreinigung anfallende Filterkuchen dem Rohbrennstoff zugeführt. Im Zuge der Partialoxidation in dem Flugstromvergaser nicht konvertierter Brennstaub wird aus dem Rohgas ausgefiltert und dem eingangsseitig zugeführten Brennstaub zugemischt. Hierdurch kann der Anlagenwirkungsgrad erhöht werden (nochmalige Vergasung von nicht umgesetztem Kohlenstoff) und der Entsorgungsaufwand minimiert werden.According to the invention the resulting in the raw gas purification filter cake fed to the raw fuel. In the course of the partial oxidation in the entrained flow gasifier unconverted Fuel dust is filtered out of the raw gas and fed to the input side Mixed with dust. This can increase the plant efficiency (repeated gasification of unreacted carbon) and the disposal costs are minimized.
Vorteilhafte Weiterbildungen der Erfindung sind in den Unteransprüchen angegeben.advantageous Further developments of the invention are in the subclaims specified.
Die Erfindung wird im Folgenden als Ausführungsbeispiel in einem zum Verständnis erforderlichen Umfang anhand von Figuren näher erläutert. Dabei zeigen:The Invention will be described below as an exemplary embodiment to an extent necessary for understanding on the basis of Figures explained in more detail. Showing:
In den Figuren bezeichnen gleiche Bezeichnungen gleiche Elemente.In the same designations denote the same elements.
Der
wesentliche Unterschied zwischen dem pneumatischen Fördersystem
(
Eine
Weiterbildung ist durch die in
Sowohl
bei der Schleusenentspannung als auch aufgrund des pneumatischen
Transportes von (
Gemäß der
in
Im Zuge der Partialoxidation in dem Flugstromvergaser nicht konvertierter Brennstaub wird aus dem Rohgas ausgefiltert und dem eingangsseitig zugeführten Brennstaub zugemischt. Die Nicht-Konversion des Brennstaubs kann auf Inhomogenitäten des Brennstoffs, wie z. B. betreffend Aufmahlungsgrad oder Mischung unterschiedlicher Brennstoffsorten, insbesondere Kohlesorten, aber auch auf vom Optimum abweichenden Betriebsparametern des Flugstromvergasers zurückzuführen sein.in the Partial oxidation in the entrained flow gasifier unconverted Fuel dust is filtered out of the raw gas and the input side added to supplied fuel dust. The non-conversion of the fuel dust can be due to inhomogeneities of the fuel, such as B. regarding Aufmahlungsgrad or mixture of different Fuel types, especially types of coal, but also on the optimum attributable to deviating operating parameters of the entrained-flow gasifier be.
Die
Rohgasreinigung (
Die Rückführung der ausgefilterten Partikel aus dem Rohgas und die Zumischung zu dem zu vergasenden Brennstaub kann kontinuierlich oder zyklisch erfolgen.The Return of the filtered particles from the Crude gas and the admixture to the fuel to be gasified continuously or cyclically.
BezugszeichenlisteLIST OF REFERENCE NUMBERS
- 11
- RohkohlefördertechnikRohkohlefördertechnik
- 22
- RohkohlesiloRohkohlesilo
- 33
- Trocknung und Mahlung der Kohle (kombiniert oder separat)desiccation and grinding the coal (combined or separately)
- 44
- Staubfilterdust filter
- 55
- KohlestaubsiloKohlestaubsilo
- 66
- Pneumatisches Fördersystempneumatic conveyor system
- 77
- Zwischenbunkerintermediate bunker
- 88th
- Schleusensystemlock system
- 99
- Einspeisebehälterfeed tank
- 1010
- Kohlevergasungcoal gasification
- 6*6 *
- Schleusensystem mit integrierter pneumatischer Förderung oder Staubpumpelock system with integrated pneumatic conveying or dust pump
ZITATE ENTHALTEN IN DER BESCHREIBUNGQUOTES INCLUDE IN THE DESCRIPTION
Diese Liste der vom Anmelder aufgeführten Dokumente wurde automatisiert erzeugt und ist ausschließlich zur besseren Information des Lesers aufgenommen. Die Liste ist nicht Bestandteil der deutschen Patent- bzw. Gebrauchsmusteranmeldung. Das DPMA übernimmt keinerlei Haftung für etwaige Fehler oder Auslassungen.This list The documents listed by the applicant have been automated generated and is solely for better information recorded by the reader. The list is not part of the German Patent or utility model application. The DPMA takes over no liability for any errors or omissions.
Zitierte PatentliteraturCited patent literature
- - US 4465496 [0005] US 4465496 [0005]
Claims (8)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE200910035408 DE102009035408A1 (en) | 2009-07-31 | 2009-07-31 | Gasification of carbonaceous fuels with increased conversion rate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE200910035408 DE102009035408A1 (en) | 2009-07-31 | 2009-07-31 | Gasification of carbonaceous fuels with increased conversion rate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE102009035408A1 true DE102009035408A1 (en) | 2011-02-03 |
Family
ID=43402587
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE200910035408 Ceased DE102009035408A1 (en) | 2009-07-31 | 2009-07-31 | Gasification of carbonaceous fuels with increased conversion rate |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE102009035408A1 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102012217890A1 (en) | 2012-10-01 | 2014-04-03 | Siemens Aktiengesellschaft | Combination of pressure charging and metering for continuous delivery of fuel dust into an entrainment gasification reactor over long distances |
| DE102013203739A1 (en) | 2013-03-05 | 2014-09-11 | Siemens Aktiengesellschaft | Combination of pressure charging and metering for continuous delivery of fuel dust into an entrainment gasification reactor over long distances |
| DE102013216948A1 (en) | 2013-08-26 | 2015-03-12 | Siemens Aktiengesellschaft | Device for measuring pressure and differential pressure in dust conveyor lines |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4465496A (en) | 1983-01-10 | 1984-08-14 | Texaco Development Corporation | Removal of sour water from coal gasification slag |
-
2009
- 2009-07-31 DE DE200910035408 patent/DE102009035408A1/en not_active Ceased
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4465496A (en) | 1983-01-10 | 1984-08-14 | Texaco Development Corporation | Removal of sour water from coal gasification slag |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102012217890A1 (en) | 2012-10-01 | 2014-04-03 | Siemens Aktiengesellschaft | Combination of pressure charging and metering for continuous delivery of fuel dust into an entrainment gasification reactor over long distances |
| DE102012217890B4 (en) * | 2012-10-01 | 2015-02-12 | Siemens Aktiengesellschaft | Combination of pressure charging and metering for continuous delivery of fuel dust into an entrainment gasification reactor over long distances |
| US9939152B2 (en) | 2012-10-01 | 2018-04-10 | Siemens Aktiengesellschaft | Combination of pressure charging and metering for continuously supplying pulverized fuel into an entrained-flow gasifying reactor with long conveying distances |
| DE102013203739A1 (en) | 2013-03-05 | 2014-09-11 | Siemens Aktiengesellschaft | Combination of pressure charging and metering for continuous delivery of fuel dust into an entrainment gasification reactor over long distances |
| DE102013216948A1 (en) | 2013-08-26 | 2015-03-12 | Siemens Aktiengesellschaft | Device for measuring pressure and differential pressure in dust conveyor lines |
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Effective date: 20120128 |