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DE102009007457A1 - Screw reactor used for qualitative and quantitative identification of relevant, assessable process data for treating waste streams, comprises multiple separately controllable heating zones and experimental combustion chamber - Google Patents

Screw reactor used for qualitative and quantitative identification of relevant, assessable process data for treating waste streams, comprises multiple separately controllable heating zones and experimental combustion chamber Download PDF

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Publication number
DE102009007457A1
DE102009007457A1 DE200910007457 DE102009007457A DE102009007457A1 DE 102009007457 A1 DE102009007457 A1 DE 102009007457A1 DE 200910007457 DE200910007457 DE 200910007457 DE 102009007457 A DE102009007457 A DE 102009007457A DE 102009007457 A1 DE102009007457 A1 DE 102009007457A1
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DE
Germany
Prior art keywords
screw reactor
screw
process data
combustion chamber
reactor according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
DE200910007457
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German (de)
Inventor
Michael Prof. Dr.-Ing. Beckmann
Simon Dipl.-Ing. Unz
Marco Dr.-Ing. Klemm
Hans Prof.Dr.-Ing. Lutze
Mirco Dipl.-Ing. Thomä (BA)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BECKER UMWELTDIENSTE GmbH
Original Assignee
BECKER UMWELTDIENSTE GmbH
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Filing date
Publication date
Application filed by BECKER UMWELTDIENSTE GmbH filed Critical BECKER UMWELTDIENSTE GmbH
Priority to DE200910007457 priority Critical patent/DE102009007457A1/en
Publication of DE102009007457A1 publication Critical patent/DE102009007457A1/en
Withdrawn legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B7/00Coke ovens with mechanical conveying means for the raw material inside the oven
    • C10B7/10Coke ovens with mechanical conveying means for the raw material inside the oven with conveyor-screws
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B41/00Safety devices, e.g. signalling or controlling devices for use in the discharge of coke
    • C10B41/08Safety devices, e.g. signalling or controlling devices for use in the discharge of coke for the withdrawal of the distillation gases
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B57/00Other carbonising or coking processes; Features of destructive distillation processes in general
    • C10B57/14Features of low-temperature carbonising processes

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

A screw reactor (1) comprises multiple separately controllable heating zones (2a,2b,2c,2d,2e). Inlets (7a,7b,7c,7d,7e) in lower part of the reactor are also designed for supplying inert gases and for defining supply of reaction gas for investigation of some autothermal and autothermal reactions. A sealed product feeding screw conveyor (8), a water sluice (9) and an experimental combustion chamber (10) are also provided in the screw reactor.

Description

Es sind verschiedene großtechnische Lösungen von Anlagen zur Pyrolyse von Abfallstoffen bekannt, unter anderem Patent 10 207 056 907.8, Patent 10 207 056 905.1, Patent 10 207 056 903.5, Patent 10 207 056 904.3, Gebrauchsmuster 20 2007 016 421.1 , Gebrauchsmuster 20 2007 016 423.8 u. a.Various industrial scale solutions of waste material pyrolysis plants are known, inter alia, Patent 10 207 056 907.8, Patent 10 207 056 905.1, Patent 10 207 056 903.5, Patent 10 207 056 904.3, Utility Model 20 2007 016 421.1 . Utility Model 20 2007 016 423.8 among others

Große Schwierigkeiten bestehen darin, dass in solchen Großanlagen keine Untersuchungen zur Ermittlung der Behandlungsregime für unterschiedliche Stoffströme aufwands- und kostenarm stattfinden können.Size Difficulties are that in such large plants No studies to determine the treatment regimen for Different material flows take place with little effort and costs can.

Mit typischen Laborverfahren wie Thermowaagen und technischen Thermowaagen sind keine übertragbaren Ergebnisse für die Ermittlung von optimalen technischen Betriebsparametern erzielbar.With typical laboratory procedures such as thermo-scales and technical thermo-scales are not transferable results for the investigation achievable by optimal technical operating parameters.

Es fehlen Einrichtungen in denen mit geringstem Kostenaufwand signifikante relevante Ergebnisse für eine Vielzahl von Stoffströmen ermittelt werden können.It lack facilities in those with the least cost significant relevant results for a variety of material flows can be determined.

Diese Lücke wird durch die vorliegende Erfindung geschlossen.These Gap is closed by the present invention.

Aufgabe der im Patent dargelegten Lösung ist die schnelle und sichere Ermittlung von relevanten bewertbaren Prozessdaten zur Behandlung von Abfallströmen durch Niedertemperaturpyrolyse. Als Ergebnis werden belastbare Aussagen getroffen zu erreichbaren Pyrolysegaszusammensetzungen, zur Qualität des festen Pyrolyse-produktes, zu den Möglichkeiten des Recycling von metallischen Inhaltsstoffen, zur optimalen Behandlungstemperaturen sowie zu Verweilzeiten u. a. Außerdem sind Maßnahmen zum sicheren Brand- und Explosionsschutz ableitbar.task the solution outlined in the patent is fast and secure Determination of relevant evaluable process data for treatment of waste streams by low temperature pyrolysis. As a result reliable statements are made on achievable pyrolysis gas compositions, to the quality of the solid pyrolysis product, to the possibilities the recycling of metallic ingredients, for optimal treatment temperatures as well as to residence times u. a. In addition, measures are to safe fire and explosion protection can be derived.

Damit können für eine große Anzahl von Abfallstoffen u. a. zu behandelnden Substanzen Betriebsparameter für Großanlagen sicher und aufwandsarm bzw. mit geringen Kosten ermittelt werden.In order to can for a large number of waste materials u. a. Substances to be treated Operating parameters for Large systems safe and low effort or with low costs be determined.

Erfindungsgemäß wird die dadurch erreicht, dass ein mobiler beheizbarer Schneckenreaktor (1) (Vorzugsmaße: 3 m × 2 m × 1 m, Innen⌀ des Schneckenrohres: DN = 200 mm) getrennt regelbare Beheizungszone (2) umfasst und mit mehreren getrennten je nach Untersuchungsbedarf zu und abschaltbaren Messstutzen für die Pyrolysegasentnahme (3) ausgerüstet ist. Diese Messstutzen sind mit Thermoelementen (4) und einer Messgasleitung (5), die zu einem Gasanalysator führt, ausgerüstet. Thermoelemente am Schneckenmantel (6) dienen der Überwachung des Pyrolyseverlaufes. Weiterhin befinden sich im unteren Drittel des Schneckenmantels Eintrittsöffnungen zur dosierten, örtlich bestimmten Zuführung von Inertgasen für die Gestaltung des Brand- und Explosionsschutzes (7). Diese Eintrittsöffnungen ermöglichen außerdem die Zuführung von Reaktionsgasen wie Luft für die Untersuchung von teilautothermen und autothermen Teilprozessen.According to the invention, this is achieved in that a mobile heatable screw reactor ( 1 ) (Preferred dimensions: 3 m × 2 m × 1 m, inside of the screw tube: DN = 200 mm) separately controllable heating zone ( 2 ) and with several separate test ports for the pyrolysis gas removal, which can be switched on and off according to 3 ) is equipped. These measuring sockets are equipped with thermocouples ( 4 ) and a sample gas line ( 5 ), which leads to a gas analyzer, equipped. Thermocouples on the screw shell ( 6 ) serve to monitor the pyrolysis course. Furthermore, in the lower third of the screw shell inlet openings for metered, locally determined supply of inert gases for the design of fire and explosion protection ( 7 ). These inlet openings also allow the supply of reaction gases such as air for the investigation of teilautothermen and autothermal sub-processes.

Zum gasdichten Pyrolyseguteintrag dient eine vorgeschaltete Stoffschnecke (8). Zur Sicherung des Explosionsschutzes erfolgt die Entnahme des zu beurteilenden Pyrolyseproduktes über eine Wasserbadschleuse (9).For the gastight entry of pyrolysis goods an upstream substance screw ( 8th ). To secure the explosion protection, the removal of the pyrolysis product to be assessed takes place via a water bath lock ( 9 ).

In einer direktangekoppelten Versuchsbrennkammer (10), die ebenfalls mit Thermoelementen und Messgasentnahmestutzen ausgerüstet ist, wird der Verbrennungsablauf des anfallenden Pyrolysegases untersucht. Insgesamt erfolgt die Inertisierung mit Stickstoff (11).In a directly coupled experimental combustion chamber ( 10 ), which is also equipped with thermocouples and gas sampling nozzle, the combustion process of the resulting pyrolysis gas is examined. Overall, the inertization is carried out with nitrogen ( 11 ).

Die aufwandsarm bestimmten Parameter, dienen der sicheren Einstellung der Betriebswerte von Großanlagen und ersetzen damit kostspielige Tests unter Produktionsbedingungen.The low-effort certain parameters, are used for safe adjustment the operating values of large plants and thus replace costly tests under production conditions.

11
Schneckenreaktorscrew reactor
2a bis 2e2a until 2e
Beheizungszonenheating zones
3a bis 3f3a to 3f
zu- und abschaltbare Meßstutzento- and disconnectable measuring sockets
4a bis 4f4a to 4f
Thermoelemente in den Meßgasstutzenthermocouples in the Meßgasstutzen
55
Leitung zum Gasanalysatormanagement to the gas analyzer
6a bis 6e6a to 6e
Thermoelemente am Schneckenmantelthermocouples on the snail coat
7a bis 7e7a to 7e
Eintrittsöffnungen für Inert- oder Reaktionsgasinlet openings for inert or reaction gas
88th
Stopfschneckestuffing screw
99
Wasserbadschleusewater sluice
1010
PyrolysegasversuchskammerPyrolysegasversuchskammer
1111
Stickstoff zur Inertisierungnitrogen for inerting

ZITATE ENTHALTEN IN DER BESCHREIBUNGQUOTES INCLUDE IN THE DESCRIPTION

Diese Liste der vom Anmelder aufgeführten Dokumente wurde automatisiert erzeugt und ist ausschließlich zur besseren Information des Lesers aufgenommen. Die Liste ist nicht Bestandteil der deutschen Patent- bzw. Gebrauchsmusteranmeldung. Das DPMA übernimmt keinerlei Haftung für etwaige Fehler oder Auslassungen.This list The documents listed by the applicant have been automated generated and is solely for better information recorded by the reader. The list is not part of the German Patent or utility model application. The DPMA takes over no liability for any errors or omissions.

Zitierte PatentliteraturCited patent literature

  • - DE 202007016421 U [0001] - DE 202007016421 U [0001]
  • - DE 202007016423 U [0001] - DE 202007016423 U [0001]

Claims (6)

Einschneckenreaktor zur qualitativen und quantitativen, schnellen und sicheren Ermittlung von relevanten, bewertbaren Prozessdaten für die Behandlung von Abfallströmen durch Niedertemperaturpyrolyse, dadurch gekennzeichnet, dass es sich um einen mobilen elektrisch beheizbaren Schneckenreaktor handelt, der mehrere getrennt regelbare Beheizungszonen umfasst, und mit zu- und abschaltbaren Messstutzen für die Pyrolysegasentnahme ausgerüstet ist.Single-screw reactor for the qualitative and quantitative, rapid and reliable determination of relevant, assessable process data for the treatment of waste streams by low-temperature pyrolysis, characterized in that it is a mobile electrically heated screw reactor comprising a plurality of separately controllable heating zones, and with on and off switchable Measuring nozzle is equipped for pyrolysis gas extraction. Einschneckenreaktor nach 1., dadurch gekennzeichnet, dass er Eintrittsöffnungen im unteren Drittel des Schneckenmantels zur Zuführung von Inertgasen (Explosionsschutz) und zur definierten Zuführung von Reaktionsgas für die Untersuchung von teilautothermen und autothermen Reaktionen besitzt.Single-screw reactor according to claim 1, characterized that he has inlets in the lower third of the snail shell for the supply of inert gases (explosion protection) and the defined supply of reaction gas for the Examination of partially autothermal and autothermal reactions. Einschneckenreaktor nach 1., dadurch gekennzeichnet, dass die gasdichte Produktaufgabe über eine vorgeschaltete Stopfschnecke erfolgt.Single-screw reactor according to claim 1, characterized that the gas-tight product task via an upstream Plug screw takes place. Einschneckenreaktor nach 1., dadurch gekennzeichnet, dass die gasdichte Produktentnahme über eine Wasserbadschleuse erfolgt.Single-screw reactor according to claim 1, characterized that the gas-tight product removal via a water lock he follows. Einschneckenreaktor nach 1., dadurch gekennzeichnet, dass die Versuchsbrennkammer für die Untersuchung der Verbrennung des anfallenden Pyrolysegases direkt an den Einschneckenreaktor angekoppelt ist.Single-screw reactor according to claim 1, characterized that the experimental combustion chamber for the investigation of the combustion the resulting pyrolysis gas is coupled directly to the single-screw reactor is. Einschneckenreaktor nach den Ansprüchen 1–5, dadurch gekennzeichnet, dass er für die Optimierung der Prozessdaten einer Vielzahl von unterschiedlichen Stoffströmen multivalent nutzbar ist.Single-screw reactor according to claims 1-5, characterized in that it is for the optimization of Process data of a variety of different streams multivalent usable.
DE200910007457 2009-02-04 2009-02-04 Screw reactor used for qualitative and quantitative identification of relevant, assessable process data for treating waste streams, comprises multiple separately controllable heating zones and experimental combustion chamber Withdrawn DE102009007457A1 (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102014105340A1 (en) * 2014-04-15 2015-10-15 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Plant and process for the thermocatalytic treatment of material and pyrolysis oil produced therewith
CN107459995A (en) * 2017-08-28 2017-12-12 华南理工大学云浮研究院 A kind of high temperature for chemical industry fuel crushes reaction unit

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE202007016423U1 (en) 2006-11-22 2008-02-28 Bauknecht, Maximilian Plant for the thermal treatment of waste materials
DE202007016421U1 (en) 2006-11-22 2009-04-02 Morschett, Peter Plant for the treatment and treatment of waste materials from composite materials, in particular composite cartons (tetrapacks)

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE202007016423U1 (en) 2006-11-22 2008-02-28 Bauknecht, Maximilian Plant for the thermal treatment of waste materials
DE202007016421U1 (en) 2006-11-22 2009-04-02 Morschett, Peter Plant for the treatment and treatment of waste materials from composite materials, in particular composite cartons (tetrapacks)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102014105340A1 (en) * 2014-04-15 2015-10-15 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Plant and process for the thermocatalytic treatment of material and pyrolysis oil produced therewith
US10414987B2 (en) 2014-04-15 2019-09-17 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. System and method for thermocatalytic treatment of material and pyrolysis oil produced therewith
CN107459995A (en) * 2017-08-28 2017-12-12 华南理工大学云浮研究院 A kind of high temperature for chemical industry fuel crushes reaction unit

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Effective date: 20120901