DE102008052053A1 - Cosmetic or pharmaceutical preparation, useful e.g. as styling wax, comprises dialkyl carbonate compound, an emulsifier, an antiperspirant/deodorant active agent, a pigment and/or a dye, an emulsifier, a surfactant and/or a wax component - Google Patents

Abstract

Cosmetic or pharmaceutical preparation comprises dialkyl carbonate compound (I). Cosmetic or pharmaceutical preparation comprises dialkyl carbonate compound of formula (R 1>O(CH 2CH 2O) n-C(=O)(OCH 2CH 2) m-OR 2>) (I). R 1>a linear 6-22C-alkyl- and/or alkenyl residue, 2-ethylhexyl-, isotridecyl- or isostearyl residue or a residue derived from polyol with 2-15C and at least two hydroxyl groups; R 2>R1 or 1-5C-alkyl residue; and n, m : 0-100.

Description

The The present invention relates to dialkyl carbonates, their use in cosmetic and / or pharmaceutical preparations, as well as cosmetic and / or pharmaceutical preparations containing dialkyl carbonates according to formula (I).

State of the art

oil twill are an essential ingredient of cosmetic and / or pharmaceutical Preparations. Despite the large number of oil bodies already available on the market, There is a continuing interest in preparations containing oil bodies Included with a variety of cosmetic ingredients can be expressed advantageous.

Description of the invention

The cosmetic and / or pharmaceutical according to the invention Preparations make light and stable cosmetic and / or pharmaceutical Preparations.

dialkyl

in der R¹ für einen linearen Alkyl- und/oder Alkenylrest mit 6 bis 22 Kohlenstoffatomen, einen 2-Ethylhexyl-, Isotridecyl- oder Isostearylrest oder einen Rest, der sich von einem Polyol mit 2 bis 15 Kohlenstoffatome und mindestens zwei Hydroxylgruppen ableitet, R² für R¹ oder einen Alkylrest mit 1 bis 5 Kohlenstoffatomen steht und n und m unabhängig voneinander 0 oder Zahlen von 1 bis 100 bedeuten.Use according to the invention dialkyl carbonates of the formula (I),

in which R ^{1 is} a linear alkyl and / or alkenyl radical having 6 to 22 carbon atoms, a 2-ethylhexyl, isotridecyl or isostearyl radical or a radical derived from a polyol having 2 to 15 carbon atoms and at least two hydroxyl groups, R ^{2 is} R ¹ or an alkyl radical having 1 to 5 carbon atoms and n and m are independently 0 or numbers from 1 to 100.

• (A) R¹ steht für einen linearen Alkylrest mit 8 bis 18 Kohlenstoffatomen oder einen 2-Ethylhexylrest und R² für R¹ oder Methyl;
• (B) R¹ steht für einen linearen Alkylrest mit 12 bis 18 Kohlenstoffatomen, R² für R¹ oder Methyl und n und m jeweils für Zahlen von 1 bis 10;
• (C) R¹ steht für einen Rest eine Polyols steht, welches ausgewählt ist aus der Gruppe, die gebildet wird von Glycerin, Alkylenglycolen, technischen Oligoglyceringemischen, Methylolverbindungen, Niedrigalkylglucosiden, Zuckeralkoholen, Zuckern und Aminozuckern, und R² für R¹, einen linearen oder verzweigten Alkylrest mit 8 bis 12 Kohlenstoffatomen oder Methyl.

The dialkyl carbonates of the formula (I) can be prepared, for example, by transesterification of dimethyl or diethyl carbonate with the said hydroxy compounds according to the processes of the prior art; an overview can be found, for example, in Chem. Rev. 96, 951 (1996) , Dialkyl carbonates of the formula (I) which are particularly suitable for the solution of the present task fulfill one of the following conditions:

• (A) R ¹ is a linear alkyl radical having 8 to 18 carbon atoms or a 2-ethylhexyl radical and R ^{2 is} R ¹ or methyl;
• (B) R ¹ is a linear alkyl group of 12 to 18 carbon atoms, R ^{2 is} R ¹ or methyl, and n and m are each numbers of 1 to 10;
• (C) R ¹ is a radical of a polyol selected from the group consisting of glycerol, alkylene glycols, technical oligoglycerol mixtures, methylol compounds, lower alkyl glucosides, sugar alcohols, sugars and amino sugars, and R ² for R ¹ , a linear one or branched alkyl having 8 to 12 carbon atoms or methyl.

typical Examples of dialkyl carbonates of the two groups (A) and (B) are complete or partial transesterification products of dimethyl and / or diethyl carbonate with caproic alcohol, caprylic alcohol, 2-ethylhexyl alcohol, capric alcohol, lauryl alcohol, isotridecyl alcohol, Myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, Isostearyl alcohol, oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, Linolyl alcohol, linolenyl alcohol, elaeostearyl alcohol, arachyl alcohol, Gadoleyl alcohol, behenyl alcohol, erucyl alcohol and brassidyl alcohol as well as their technical mixtures, the z. B. in the high-pressure hydrogenation of technical methyl esters based on fats and oils or aldehydes from Roelen's oxo synthesis and as a monomer fraction incurred in the dimerization of unsaturated fatty alcohols. Equally suitable are the transesterification products of the lower ones Carbonates with the alcohols mentioned in the form of their adducts with 1 to 100, preferably 2 to 50 and especially 5 to 20 moles of ethylene oxide. Preferably, di-n-octyl carbonate comes into question.

• • Glycerin;
• • Alkylenglycole wie beispielsweise Ethylenglycol, Diethylenglycol, Propylenglycol, Butylenglycol, Hexylenglycol sowie Polyethylenglycole mit einem durchschnittlichen Molekulargewicht von 100 bis 1.000 Dalton;
• • technische Oligoglyceringemische mit einem Eigenkondensationsgrad von 1,5 bis 10 wie etwa technische Diglyceringemische mit einem Diglyceringehalt von 40 bis 50 Gew.-%;
• • Methyolverbindungen, wie insbesondere Trimethylolethan, Trimethylolpropan, Trimethylolbutan, Pentaerythrit und Dipentaerythrit;
• • Niedrigalkylglucoside, insbesondere solche, mit 1 bis 8 Kohlenstoffen im Alkylrest wie beispielsweise Methyl- und Butylglucosid;
• • Zuckeralkohole mit 5 bis 12 Kohlenstoffatomen wie beispielsweise Sorbit oder Mannit,
• • Zucker mit 5 bis 12 Kohlenstoffatomen wie beispielsweise Glucose oder Saccharose;
• • Aminozucker wie beispielsweise Glucamin.

The carbonates of group (C) are substances which are obtained by transesterifying all or part of dimethyl and / or diethyl carbonate with polyols. Polyols which in the meaning of the invention in Be come preferably, have preferably 2 to 15 carbon atoms and at least two hydroxyl groups. Typical examples are

• • glycerin;
• Alkylene glycols such as ethylene glycol, diethylene glycol, propylene glycol, butylene glycol, hexylene glycol and polyethylene glycols having an average molecular weight of 100 to 1,000 daltons;
• Technical Oligoglyceringemische with an intrinsic degree of condensation of 1.5 to 10 such as technical Diglyceringemische with a diglycerol content of 40 to 50 wt .-%;
• Methyolverbindungen, in particular trimethylolethane, trimethylolpropane, trimethylolbutane, pentaerythritol and dipentaerythritol;
• Lower alkyl glucosides, in particular those having 1 to 8 carbons in the alkyl radical, for example methyl and butyl glucoside;
• Sugar alcohols having 5 to 12 carbon atoms, such as sorbitol or mannitol,
• • sugars with 5 to 12 carbon atoms, such as glucose or sucrose;
• • Aminosugars such as glucamine.

at Of course, this reaction can not only be exchanged a methyl or ethyl group come against a polyol, but rather a mixture is obtained in which several or even all the hydroxyl groups of the polyol are linked to carbonate groups, so that optionally even gives an oligomeric or polymeric network structure. Substances of this type are also intended according to the invention the general formula (I).

The Preparations according to the invention can the dialkyl carbonates in amounts of 0.1 to 80, preferably 5 to 50 and in particular 10 to 30 wt .-% - based on the Total weight of the cosmetic and / or pharmaceutical preparation - included.

The cosmetic and / or pharmaceutical according to the invention Preparations make light and stable cosmetic and / or pharmaceutical Preparations, this is particularly the case when they continue to contain antiperspirant / deodorant agents.

One The invention therefore relates to cosmetic and / or pharmaceutical Preparations containing dialkyl carbonates of the formula (I) and at least one antiperspirant / deodorant active ingredient.

According to the invention suitable as antiperspirant / deodorant active substance all active ingredients, The body odors counteract, cover these or eliminate. Body odors arise through the action of skin bacteria on apocrine perspiration, whereby unpleasant-smelling degradation products are formed. As antiperspirant / deodorant In particular compounds are selected from the group consisting of antiperspirants, esterase inhibitors, bactericidal or bacteriostatic agents and / or sweat-absorbing Substances.

antiperspirants

at Antiperspirants are salts of aluminum, zirconium or zinc. Such suitable antiperspirant active ingredients are z. Aluminum chloride, aluminum chlorohydrate, aluminum dichlorohydrate, Aluminum sesquichlorohydrate and their complex compounds z. B. with 1,2-propylene glycol. Aluminum hydroxyalloinate, aluminum chloride tartrate, Aluminum zirconium trichlorohydrate, aluminum zirconium tetrachlorohydrate, Aluminum zirconium pentachlorohydrate and their complex compounds z. With amino acids such as glycine. Preferably, aluminum chlorohydrate, Aluminum zirconium tetrachlorohydrate, aluminum zirconium pentachlorohydrate and their complex compounds used.

The Preparations according to the invention can the antiperspirants in amounts of 1 to 50, preferably 5 to 30 and in particular 8 to 25 wt .-% - based on the total weight the cosmetic and / or pharmaceutical preparation - included.

esterase

In the presence of sweat in the underarm area, extracellular enzymes - esterases, preferably proteases and / or lipases - are formed by bacteria, which split the esters contained in sweat and thereby release odors. Suitable esterase inhibitors are preferably trialkyl such as trimethyl citrate, tripropyl, triisopropyl, tributyl citrate and especially triethyl citrate (Hydagen® ^® CAT, Cognis GmbH, Dusseldorf / FRG). The substances inhibit the enzyme activity and thereby reduce the Ge unpleasant smells. Other substances which are suitable as esterase inhibitors are sterol sulfates or phosphates, such as lanosterol, cholesterol, campesterin, stigmasterol and sitosterol sulfate or phosphate, dicarboxylic acids and their esters, such as glutaric acid, glut arsäuremonoethylester, Glutarsäurediethylester, adipic acid , Adipinsäuremonoethylester, diethyl adipate, malonic acid and diethyl malonate, hydroxycarboxylic acids and their esters such as citric acid, malic acid, tartaric acid or diethyl tartrate and zinc glycinate.

The Preparations according to the invention can the esterase inhibitors in amounts of from 0.01 to 20, preferably 0.1 to 10 and in particular 0.3 to 5 wt .-% - related on the total weight of the cosmetic and / or pharmaceutical Preparation - included.

Bactericidal or bacteriostatic agents

Typical examples of suitable bactericidal or bacteriostatic agents are in particular chitosan and phenoxyethanol. Particularly effective are also 5-chloro-2- (2,4-dichlorophenoxy) phenol has proven that is marketed under the brand name Irgasan ^® by Ciba-Geigy, Basle / CH. As germ-inhibiting agents are basically all effective against Gram-positive bacteria substances such. For example, 4-hydroxybenzoic acid and its salts and esters, N- (4-chlorophenyl) -N '- (3,4-dichlorophenyl) urea, 2,4,4'-trichloro-2'-hydroxydiphenyl ether (triclosan), 4-chloro 3,5-dimethylphenol, 2,2'-methylenebis (6-bromo-4-chlorophenol), 3-methyl-4- (1-methylethyl) phenol, 2-benzyl-4-chlorophenol, 3- (4 -Chlorophenoxy) -1,2-propanediol, 3-iodo-2-propynyl butylcarbamate, chlorhexidine, 3,4,4'-trichlorocarbanilide (TTC), antibacterial fragrances, thymol, thyme oil, eugenol, clove oil, menthol, mint oil, farnesol, phenoxyethanol , Glycerol monocaprinate, glycerol monocaprylate, glycerol monolaurate (GML), diglycerol monocaprinate (DMC), salicylic acid N-alkylamides such as. Salicylic acid n-octylamide or salicylic acid n-decylamide.

The Preparations according to the invention can the bactericidal or bacteriostatic agents in amounts of 0.01 to 5 and preferably 0.1 to 2 wt .-% - on the total weight of the cosmetic and / or pharmaceutical Preparation - included.

Sweat absorbing substances

When sweat-absorbing substances come modified starch, such as B. Dry Flo Plus (National Starch), silicates, talc and other substances of similar modification that contribute to sweat absorption appear appropriate. The preparations according to the invention can sweat-absorbing substances in quantities from 0.1 to 30, preferably 1 to 20 and in particular 2 to 8 wt .-% - on the total weight of the cosmetic and / or pharmaceutical Preparation - included.

The cosmetic and / or pharmaceutical according to the invention Preparations make light and stable cosmetic and / or pharmaceutical Preparations, this is particularly the case when they furthermore contain at least one UV light protection filter.

One The invention therefore relates to cosmetic and / or pharmaceutical Preparations containing containing dialkyl carbonates according to formula (I), and at least at least one UV photoprotective filter.

One The invention relates preferably to cosmetic and / or pharmaceutical preparations containing 0.1 to 80% by weight of dialkyl carbonates according to formula (I) and at least one UV light protection filter.

• – 3-Benzylidencampher bzw. 3-Benzylidennorcampher (Mexoryl SDS 20) und dessen Derivate, z. B. 3-(4-Methylbenzyliden)campher wie in der EP 0693471 B1 beschrieben
• – 3-(4'-Trimethylammonium)benzyliden-bornan-2-on-methylsulfat (Mexoryl SO)
• – 3,3'-(1,4-Phenylendimethin)-bis (7,7-dimethyl-2-oxobicyclo-[2.2.1]heptan-1-methansulfonsäure) and salts (Mexoryl SX)
• – 3-(4'-Sulfo)-benzyliden-bornan-2-on and salts (Mexoryl SL)
• – Polymer von N-{(2und 4)-[2-oxoborn-3-yliden)methyl}benzyl]acrylamid (Mexoryl SW)
• – 2-(2H-Benzotriazol-2-yl)-4-methyl-6-(2-methyl-3-(1,3,3,3-tetramethyl-1-(trimethylsilyloxy)disiloxanyl)propyl)phenol (Mexoryl SL)
• – 4-Aminobenzoesäurederivate, vorzugsweise 4-(Dimethylamino)benzoesäure-2-ethylhexylester, 4-(Dimethylamino)benzoesäure-2-octylester und 4-(Dimethylamino)benzoe-säureamylester;
• – Ester der Zimtsäure, vorzugsweise 4-Methoxyzimtsäure-2-ethylhexylester, 4-Methoxyzimtsäurepropylester, 4-Methoxyzimtsäureisoamylester, 2-Cyano-3,3-phenylzimtsäure-2-ethylhexylester (Octocrylene);
• – Ester der Salicylsäure, vorzugsweise Salicylsäure-2-ethylhexylester, Salicylsäure-4-iso-propylbenzylester, Salicylsäurehomomenthylester;
• – Derivate des Benzophenons, vorzugsweise 2-Hydroxy-4-methoxybenzophenon, 2-Hydroxy-4-methoxy-4'-methylbenzophenon, 2,2'-Dihydroxy-4-methoxybenzophenon;
• – Ester der Benzalmalonsäure, vorzugsweise 4-Methoxybenzmalonsäuredi-2-ethylhexylester;
• – Triazinderivate, wie z. B. 2,4,6-Trianilino-(p-carbo-2'-ethyl-1'-hexyloxy)-1,3,5-triazin und 2,4,6-Tris[p-(2-ethylhexyl-oxycar-bonyl)anilino]-1,3,5-triazin (Uvinul T 150) wie in der EP 0818450 A1 beschrieben oder 4,4'-[(6-[4-((1,1-Dimethylethyl)aminocarbonyl)phenyl-amino]-1,3,5-triazin-2,4-diyl)diimino]bis(benzoesäure-2-ethylhexylester) (Uvasorb^® HEB);
• – 2,2(-Methylen-bis(6-(2H-benzotriazol-2-yl)-4-(1,1,3,3-tetramethyl-butyl)phenol) (Tinosorb M);
• – 2,4-Bis[4-(2-ethylhexyloxy)-2-hydroxyphenyl]-6-(4-methoxyphenyl)-1,3,5-triazin (Tinosorb S);
• – Propan-1,3-dione, wie z. B. 1-(4-tert.Butylphenyl)-3-(4'methoxyphenyl)propan-1,3-dion;
• – Ketotricyclo(5.2.1.0)decan-Derivate, wie in der EP 0694521 B1 beschrieben;
• – Dimethicodiethylbenzalmalonate (Parsol SLX).

According to the invention, liquid or crystalline organic substances (light protection filters) which are capable of absorbing ultraviolet rays and absorb the absorbed energy in the form of longer-wave radiation, eg. B. to give off heat again. UV filters can be oil-soluble or water-soluble. As typical oil-soluble UV-B filters or broad-spectrum UV A / B filters are z. To name, for example:

• - 3-Benzylidencampher or 3-Benzylidennorcampher (Mexoryl SDS 20) and its derivatives, for. B. 3- (4-methylbenzylidene) camphor as in EP 0693471 B1 described
• 3- (4'-trimethylammonium) benzylidene-bornan-2-one methylsulfate (mexoryl SO)
• 3,3 '- (1,4-phenylenedimethine) -bis (7,7-dimethyl-2-oxobicyclo [2.2.1] heptane-1-methanesulfonic acid) and salts (Mexoryl SX)
• 3- (4'-sulfo) -benzylidene-bornan-2-one and salts (Mexoryl SL)
• Polymer of N - {(2 and 4) - [2-oxoborn-3-ylidene) methyl} benzyl] acrylamide (Mexoryl SW)
• 2- (2H-Benzotriazol-2-yl) -4-methyl-6- (2-methyl-3- (1,3,3,3-tetramethyl-1- (trimethylsilyloxy) disiloxanyl) propyl) phenol (Mexoryl SL )
• 4-aminobenzoic acid derivatives, preferably 2-ethylhexyl 4- (dimethylamino) benzoate, 2-octyl 4- (dimethylamino) benzoate and 4- (dimethylamino) benzoic acid amyl ester;
• Esters of cinnamic acid, preferably 4-methoxycinnamic acid 2-ethylhexyl ester, 4-methoxycinnamic acid propyl ester, 4-methoxycinnamic acid isoamyl ester, 2-cyano-3,3-phenylcinnamic acid 2-ethylhexyl ester (octocrylene);
• Esters of salicylic acid, preferably 2-ethylhexyl salicylate, 4-isopropyl benzyl salicylate, homomenthyl salicylate;
• Derivatives of benzophenone, preferably 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-methoxy-4'-methylbenzophenone, 2,2'-dihydroxy-4-methoxybenzophenone;
• Esters of benzalmalonic acid, preferably di-2-ethylhexyl 4-methoxybenzmalonate;
• - Triazine derivatives, such as. 2,4,6-trianilino (p-carbo-2'-ethyl-1'-hexyloxy) -1,3,5-triazine and 2,4,6-tris [p- (2-ethylhexyl-oxycar -bonyl) anilino] -1,3,5-triazine (Uvinul T 150) as in EP 0818450 A1 or 4,4 '- [(6- [4- ((1,1-dimethylethyl) aminocarbonyl) phenylamino] -1,3,5-triazine-2,4-diyl) diimino] bis (benzoic acid-2 -ethylhexylester) (Uvasorb HEB ^®);
• 2,2 (-methylene bis (6- (2H-benzotriazol-2-yl) -4- (1,1,3,3-tetramethylbutyl) phenol) (Tinosorb M);
• 2,4-bis [4- (2-ethylhexyloxy) -2-hydroxyphenyl] -6- (4-methoxyphenyl) -1,3,5-triazine (Tinosorb S);
• - Propane-1,3-dione, such as. B. 1- (4-tert-butylphenyl) -3- (4'-methoxyphenyl) propane-1,3-dione;
• - Ketotricyclo (5.2.1.0) decane derivatives, as in EP 0694521 B1 described;
• Dimethicodiethylbenzalmalonate (Parsol SLX).

• – 2-Phenylbenzimidazol-5-sulfonsäure und deren Alkali-, Erdalkali-, Ammonium-, Alkylammonium-, Alkanolammonium- und Glucammoniumsalze;
• – 2,2(-(1,4-Phenylen)bis(1H-benzimidazol-4,6-disulfon-säure, Mononatriumsalz) (Neo Heliopan AP)
• – Sulfonsäurederivate von Benzophenonen, vorzugsweise 2-Hydroxy-4-methoxybenzophenon-5-sulfonsäure und ihre Salze;
• – Sulfonsäurederivate des 3-Benzylidencamphers, wie z. B. 4-(2-Oxo-3-bornylidenmethyl)benzolsulfonsäure und 2-Methyl-5-(2-oxo-3-bornyliden)sulfonsäure und deren Salze.

Suitable water-soluble UV filters are:

• 2-phenylbenzimidazole-5-sulfonic acid and its alkali metal, alkaline earth metal, ammonium, alkylammonium, alkanolammonium and glucammonium salts;
• 2,2 (- (1,4-phenylene) bis (1H-benzimidazole-4,6-disulfonic acid, monosodium salt) (Neo Heliopan AP)
• Sulfonic acid derivatives of benzophenones, preferably 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid and its salts;
• - Sulfonic acid derivatives of 3-Benzylidencamphers, such as. B. 4- (2-oxo-3-bomylidenemethyl) benzenesulfonic acid and 2-methyl-5- (2-oxo-3-bomylidene) sulfonic acid and salts thereof.

As a typical UV-A filter in particular derivatives of benzoylmethane are suitable, such as 1- (4'-tert-butylphenyl) -3- (4'-methoxyphenyl) propane-1,3-dione, 4-tert-butyl -4'-methoxydibenzoylmethane (Parsol ^® 1789), 1-phenyl-3- (4'-isopropylphenyl) propane-1,3-dione as well as enamine compounds as described in the DE 19712033 A1 (BASF) and benzoic acid, 2- [4- (diethylamino) -2-hydroxybenzoyl] -, hexyl ester (Uvinul ^® A plus).

Of course, the UV-A and UV-B filters can also be used in mixtures. Particularly favorable combinations consist of the derivatives of benzoylmethane, z. B. 4-tert-butyl-4'-methoxydibenzoylmethane (Parsol ^® 1789) and 2-cyano-3,3-phenylcinnamate-2-ethyl-hexyl ester (Octocrylene), in combination with esters of cinnamic acid, preferably 4-methoxycinnamic acid-2 ethylhexyl ester and / or 4-methoxycinnamic acid propyl ester and / or 4-methoxycinnamic acid isoamyl ester. Advantageously, such combinations with water-soluble filters such. B. 2-phenylbenzimidazole-5-sulfonic acid and their alkali, alkaline earth, ammonium, alkylammonium, alkanolammonium and glucammonium combined.

As UV light protection filters are particularly suitable in accordance with Annex VII of the Commission Directive (in the Commission Directive 2005/9 / EC of 28 January 2005 amending Council Directive 76/768 / EEC, concerning cosmetic products, for the purposes of adapting Annexes VII thereof to technical progress ) substances, which are explicitly referred to here.

In addition to the soluble substances mentioned, insoluble photoprotective pigments, namely finely dispersed metal oxides or salts, are also suitable for this purpose. Examples of suitable metal oxides are in particular zinc oxide and titanium dioxide and, in addition, oxides of iron, zirconium, silicon, manganese, aluminum and cerium and mixtures thereof. As salts silicates (talc), barium sulfate or zinc stearate can be used. The oxides and salts are used in the form of the pigments for skin-care and skin-protecting emulsions and also for decorative cosmetics. The particles should have an average diameter of less than 100 nm, preferably between 5 and 50 nm and in particular between 15 and 30 nm. They may have a spherical shape, but it is also possible to use those particles which have an ellipsoidal or otherwise deviating shape from the spherical shape. The pigments can also be surface-treated, ie hydrophilized or hydrophobized. Typical case games are coated titanium dioxides, such. As titanium dioxide T 805 (Degussa) or Eusolex ^® T, Eusolex ^® T-2000, Eusolex ^® T-Aqua, Eusolex ^® AVO, Eusolex ^® T-ECO, Eusolex ^® T-OLEO and Eusolex ^® TS (Merck). Typical examples are zinc oxides, such as. B. Zinc Oxide neutral, Zinc Oxide NDM (Symrise) or Z-Cote ^® (BASF) or SUNZnO-AS and SUNZnO NAS (Sunjun Chemical Co. Ltd.). Suitable hydrophobic coating agents are in particular silicones and in particular trialkoxyoctylsilanes or simethicones. In sunscreens, so-called micro- or nanopigments are preferably used. Preferably, micronized zinc oxide is used. Further suitable UV sunscreen filters are the overview of P.Finkel in SÖFW Journal 122, 8/1996, pp. 543-548 and Parf.Kosm. Volume 80, No. 3/1999, pp. 10 to 16 refer to.

Next the two aforementioned groups of primary photoprotective agents may also be secondary sunscreen of the type The antioxidants used are the photochemical reaction chain interrupt which is triggered when ultraviolet radiation penetrates the skin. Typical examples of this are Amino acids (eg glycine, histidine, tyrosine, tryptophan) and their derivatives, imidazoles (eg, urocanic acid) and their derivatives Derivatives, peptides such as D, L-carnosine, D-carnosine, L-carnosine and their Derivatives (eg anserine), carotenoids, carotene (eg carotene, Carotene, lycopene) and their derivatives, chlorogenic acid and their derivatives, lipoic acid and its derivatives (eg dihydrolipoic acid), Auro-thioglucose, propylthiouracil and other thiols (eg thioredoxin, Glutathione, cysteine, cystine, cystamine and their glycosyl, N-acetyl, Methyl, ethyl, propyl, amyl, butyl and lauryl, palmitoyl, Oleyl, -linoleyl, cholesteryl and glyceryl esters) and their Salts, dilauryl thiodipropionate, distearyl thiodipropionate, thiodipropionic acid and their derivatives (esters, ethers, peptides, lipids, nucleotides, nucleosides and salts) as well as sulfoximine compounds (eg buthionine sulfoximines, Homocysteine sulfoximine, butioninsulfone, penta-, hexa-, heptathionine sulfoximine) in very low tolerated dosages (eg pmol to mol / kg), furthermore (metal) chelators (for example α-hydroxy fatty acids, Palmitic acid, phytic acid, lactoferrin), α-hydroxy acids (eg, citric acid, lactic acid, malic acid), Humic acid, bile acids, bile extracts, bilirubin, Biliverdin, EDTA, EGTA and their derivatives, unsaturated Fatty acids and their derivatives (eg gamma-linolenic acid, Linoleic acid, oleic acid), folic acid and their derivatives, ubiquinone and ubiquinol and their derivatives, Vitamin C and derivatives (eg ascorbyl palmitate, Mg ascorbyl phosphate, Ascorbyl acetate), tocopherols and derivatives (eg, vitamin E acetate), Vitamin A and derivatives (vitamin A palmitate) and coniferyl benzoate Benzoin, Rutinic Acid and Derivatives, α-Glycosylrutin, Ferulic acid, furfurylidene glucitol, carnosine, butylhydroxytoluene, Butylhydroxyanisole, nordihydroguaiakolic acid, nordihydroguajaretic acid, Trihydroxybutyrophenone, uric acid and its derivatives, mannose and their derivatives, superoxide dismutase, zinc and its derivatives (eg ZnO, ZnSO4) selenium and its derivatives (eg selenium methionine), Stilbenes and their derivatives (eg stilbene oxide, trans-stilbene oxide) and the derivatives suitable according to the invention (salts, Esters, ethers, sugars, nucleotides, nucleosides, peptides and lipids) these mentioned active ingredients.

One The invention therefore relates to cosmetic and / or pharmaceutical Preparations containing 0.1 to 80% by weight of dialkyl carbonates of the formula (I) and at least one UV light protection filter selected from the group consisting of 4-methylbenzylidene camphor, benzophenone-3, Butyl methoxydibenzoylmethane, bis-ethylhexyloxyphenol methoxyphenyl Triazines, methylene bis-benzotriazolyl tetramethylbutylphenol, diethylhexyl Butamido triazone, ethylhexyl triazone and diethylamino hydroxybenzoyl Hexyl benzoates, 3- (4'-trimethylammonium) benzylidenebornan-2-one methylsulfate, 3,3 '- (1,4-phenylenedimethine) -bis (7,7-dimethyl-2-oxobicyclo [2.2.1] heptane-1-methanesulfonic acid) and their salts, 3- (4'-sulfo) -benzyliden-bornan-2-one and its salts, Polymer of N - {(2 and 4) - [2-oxoborn-3-ylidene) methyl} benzyl] acrylamide, 2- (2H-benzotriazol-2-yl) -4-methyl-6- (2-methyl-3-) (1,3,3,3-tetramethyl-1- (trimethylsilyloxy) disiloxanyl) propyl) phenol, Dimethicodiethylbenzalmalonate and their mixtures.

One The invention therefore relates to cosmetic and / or pharmaceutical Preparations containing dialkyl carbonates according to formula (I) and at least one UV photoprotective filter selected from the group consisting of 4-methylbenzylidene camphor, benzophenone-3, Butyl methoxydibenzoylmethane, bis-ethylhexyloxyphenol methoxyphenyl Triazines, methylene bis-benzotriazolyl tetramethylbutylphenol, diethylhexyl Butamido triazone, ethylhexyl triazone and diethylamino hydroxybenzoyl Hexyl benzoates, 3- (4'-trimethylammonium) benzylidene-bornan-2-one methylsulfate, 3,3 '- (1,4-phenylenedimethine) -bis (7,7-dimethyl-2-oxobicyclo- [2.2.1] heptane-1-methanesulfonic acid) and their salts, 3- (4'-sulfo) -benzyliden-bornan-2-one and its salts, Polymer of N - {(2 and 4) - [2-oxoborn-3-ylidene) methyl} benzyl] acrylamide, 2- (2H-benzotriazol-2-yl) -4-methyl-6- (2-methyl-3- (1,3,3,3-tetramethyl-1- (trimethylsilyloxy) disiloxanyl) propyl) phenol, Dimethicodiethylbenzalmalonate and their mixtures.

These UV photoprotective filters are commercially available, for example, under the following trade names:
Neoheliopan ^® MBC (INCI: 4-Methylbenzylidene Camphor; manufacturer: Symrise); Neoheliopan ^® BB (INCI: Ben zophenone-3, manufacturer: Symrise); Parsol ^® 1789 (INCI: Butyl Methoxydibenzoylmethane, manufactured by Hoffmann-La Roche (Givaudan); Tinosorb ^® S (INCI: Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine); Tinosorb ^® M (INCI: Methylene Bis-Benzotriazolyl Tetramethylbutylphenol): Herstelller: Ciba Specialty Chemicals Corporation; Uvasorb® ^® HEB (INCI: diethylhexylbutamidotriazone Triazone, manufactured by 3V Inc.), Uvinul ^® T 150 (INCI: Ethylhexyltriazone, Manufacturer: BASF AG); Uvinul ^® A plus (INCI: diethylamino hydroxybenzoyl hexyl benzoate: Manufacturer: BASF AG; Mexoryl SO ^®: 3- (4'-trimethylammonium) benzylidene bornan-2-one methyl sulfate, INCI: Camphor benzalkonium Methosulfate; Mexoryl SX ^®: 3,3 '- (1,4-phenylenedimethine) bis (7, 7-dimethyl-2-oxobicyclo- [2.2.1] heptane-1-methanesulfonic acid), CTFA: INCI Terephthalylidene Dicamphor Sulfonic Acid; Mexory ^® SL: 3- (4'-sulfo) -benzylidenbornan-2-one, INCI Benzylidene Camphor Sulfonic Acid; Mexoryl SW ^®: polymer of N - {(2 and 4) - [2-oxoborn-3-ylidene) methyl} benzyl] acrylamide, INCI Polyacrylamidomethy Benzylidenes Camphor; Mexoryl SL ^®: 2- (2H-benzotriazole-2-yl) phenol -4-methyl-6- (2-methyl-3- (1,3,3,3-tetramethyl-1- (trimethylsilyloxy) disiloxanyl) propyl) ; INCI: DROMETRIZOLE TRISILOXANE; Parsol ^® SLX: dimethicodiethyl benzalmalonate, INCI polysilicone-15th

The Preparations according to the invention can the UV photoprotective filters in amounts of 0.5 to 30 wt .-%, preferably 2.5 to 20 wt .-%, particularly preferably 5-15 wt .-% - related on the total weight of the cosmetic and / or pharmaceutical Preparation - included.

One The invention relates to cosmetic and / or pharmaceutical Preparations containing dialkyl carbonates of the formula (I) and at least one self-tanner.

One preferred object of the invention relates to cosmetic and / or pharmaceutical preparations containing 0.1 to 80% by weight of dialkyl carbonates according to formula (I) and at least one self-tanner.

When Selbstbräuner are substances to understand which one Cause tanning of the skin. For example, be as well alpha, beta-unsubstituted aldehydes called, which with the Amino acids of the skin in the sense of a Maillard reaction too Abreact colored compounds. As active ingredients for Self-tanners continue to be natural or synthetic ketols or aldols. As suitable active ingredients exemplified by dihydroxyacetone, erythrulose, glycerolaldehyde, Alloxan, hydroxymethylglyoxal, gamma-dialdehyde, 6-aldo-D-fructose, Ninhydrin and meso-tartaric dialdehyde. As a self-tanner Particularly suitable are dihydroxyacetone and / or erythrulose.

When Particularly advantageous mixtures of o. g. drugs with each other or with mucondialdehyde and / or naphthoquinones such as z. 5-hydroxy-1,4-naphthoquinone (juglone) and 2-hydroxy-1,4-naphthoquinone proved.

The Contain compositions of the invention the self-tanner usually in concentrations from 1 to 10, in particular from 2 to 5 wt .-% - on the total weight of the cosmetic and / or pharmaceutical Preparation.

One The invention relates to cosmetic and / or pharmaceutical Preparations containing dialkyl carbonates of the formula (I) and at least at least one self-tanner and at least a UV sunscreen filter.

One preferred object of the invention relates to cosmetic and / or pharmaceutical preparations containing 0.1 to 80% by weight of dialkyl carbonates according to formula (I) and at least one self-tanner and at least one UV sunscreen filter.

The cosmetic and / or pharmaceutical according to the invention Preparations can be used, for example, as O / W or W / O care emulsions, Sunscreen formulation, AP / Deo concepts, formulations for decorative cosmetics, oily care preparations, impregnating liquids for substrates such as paper and non-wovens available. Examples include wet wipes, handkerchiefs, Diapers or hygiene products.

The dialkyl carbonates of the formula (I) and the cosmetic and / or pharmaceutical preparations according to the invention which they contain are also particularly suitable for light, sprayable applications and / or as constituents of care emulsions for tissues, papers, wipes, sponges (for example polyurethane sponges ), Patches in the field of baby hygiene, baby care, skin care, sunscreen, after-sun treatment, insect repellent, cleansing, facial cleansing and AP / deodorant application. They let themselves up Apply tissues, papers, wipes, fleece products, sponges, puffs, plasters and bandages that are used in the field of cleaning, hygiene and / or care (wet wipes for baby hygiene and baby care, cleaning wipes, face wipes, skin wipes, Wipes with active ingredients against skin aging, wipes with sunscreen formulations and insect repellents and wipes for decorative cosmetics or after-sun treatment, toilet wipes, antiperspirant wipes, diapers, handkerchiefs, wet wipes, hygiene products, self-tanning Wipes, toilet paper, refreshing towels, After -shave towels). They can be used, inter alia, in preparations for hair care, hair cleaning or hair coloring. The use of the dialkyl carbonates of the formula (I) has a positive influence on the sensory behavior during administration.

The Dialkyl carbonates according to formula (I) are suitable in particular as constituents of preparations of decorative Cosmetics, such as lipsticks, eye make-up, such as Eyeshadow, mascara, eyeliner, kohl, nail polish, etc. as well as make-up Formulations.

One The invention relates to cosmetic and / or pharmaceutical Preparations containing dialkyl carbonates of the formula (I) and at least at least one pigment and / or a dye.

One preferred object of the invention relates to cosmetic and / or pharmaceutical preparations containing 0.1 to 80% by weight of dialkyl carbonates according to formula (I) and at least one pigment and / or a dye.

Of the Term pigment includes particles of any shape that knows or colored, organic or inorganic, in the preparations are not soluble, and serve the purpose of the preparation to color. In a preferred embodiment inorganic pigments are used, are particularly preferred Metal oxides.

When inorganic pigments are exemplified: titanium dioxide, optional surface-coated, zirconium or cerium oxides and Zinc, iron (black, yellow or red) and chromium oxide, manganese violet, Ultramarine Blue, Chrome Hydroate and Iron (III) Blue, Metal Powder like aluminum powder or copper powder.

In a preferred embodiment of the invention is that Pigment selected from the inorganic pigments, preferably from the metal oxides. In a preferred embodiment the pigment is selected from the group consisting of Titanium dioxide, zinc oxide, iron oxide and mixtures thereof.

The Pigments can be present both individually and in mixtures. Preferred for the purposes of the present invention are pigment mixtures from white pigments (eg kaolin, titanium dioxide or zinc oxide) and inorganic color pigments (eg iron oxide pigments, chromium oxides), wherein the pigments are coated ("coated") or uncoated can. Among the color pigments, iron oxides are particularly preferred.

Advantageous For the purposes of the present invention, the one or more Pigments also selected from the group of effect pigments which of the cosmetic preparation is next to the pure color an additional property - such. Legs Angular dependence of the color (change, flop), gloss (not surface gloss) or texture. Such effect pigments are advantageous according to the invention in addition to one or more white and / or colored pigments used.

The most important group of effect pigments are the luster pigments to which DIN 55944: 2003-11 the metallic effect pigments and the pearlescent pigments belong. Some special effect pigments can not be assigned to these two groups, eg. As platelet graphite, platelet-shaped iron oxide and micronized titanium dioxide, wherein micronized titanium dioxide produces no gloss effect, but an angle-dependent light scattering effect. After the luster pigments after DIN 55943: 2001-10 These are predominantly platelet-shaped effect pigments. Parallel oriented luster pigments show a characteristic shine. The optical effect of luster pigments is based on the directed reflection of metallic particles (metallic effect pigments), on transparent particles with high refractive index (pearlescent pigments) or on the phenomenon of interference (interference pigments) ( DIN 55944: 2003-11 ).

Examples for commercially preferred according to the invention Effect pigments are: Timiron and # 174; from Merck, Iriodin and # 174; from Merck (pearl and color luster pigments for decorative technical Applications), Xirallic and # 174; from Merck (color intensive crystals effect pigments).

Furthermore, the preparations according to the invention may advantageously also contain organic color pigments, ie organic dyes which are practically insoluble in the preparation. To DIN 55944: 1990-04 Organic pigments can be divided into azo pigments and polycyclic pigments from a chemical point of view as well as colored or black pigments from a color point of view. Organic white pigments are of no practical importance.

The Pigments may be advantageous for the purposes of the present invention also in the form of commercially available oily or aqueous predispersions are used. The invention Preparations usually contain 0.1 to 40% by weight Pigments - based on the total weight of the cosmetic and / or pharmaceutical preparation.

It is also advantageous in the context of the present invention, when the inventive preparation one or more dyes contains.

The Dyes can be both synthetic and natural Be of origin.

A list of suitable dyes can be found in EP 1 371 359 A2 , P.8, Z. 25-57, p.9 and p.10 and p.11, Z. 1 to 54, which are hereby incorporated by reference. The preparations according to the invention usually contain 0.01 to 5, preferably 0.1 to 1.0 wt .-% dyes - based on the total weight of the cosmetic and / or pharmaceutical preparation. The preparations according to the invention usually contain a total amount of dyes and pigments in the range of 0.01 to 30 wt .-%, in particular 0.1 to 15 wt .-%, preferably 1 to 10 wt .-%, based on the total weight of the cosmetic and / or pharmaceutical preparation.

Suitable dyes and pigments are in particular the dyes and pigments approved in accordance with Annex IV of the Commission Directive (in the version: Commission Directive 2007/22 / EC of 17 April 2007 amending Council Directive 76/768 / EEC, concerning cosmetic products, for the purposes of adapting Annexes IV and VI to technical Progress ) substances, which are hereby explicitly referred to.

The cosmetic and / or pharmaceutical preparations Formulations for personal care, z. B. a body milk, Creams, lotions, sprayable emulsions, elimination products body odor, etc. The dialkyl carbonates can be also in surfactant-containing formulations such. B. foam and shower baths, Use shampoos and conditioners. Depending on the application purpose contain the cosmetic and / or pharmaceutical preparations a number of other auxiliaries and additives, such as Surfactants, other oils, emulsifiers, pearlescent waxes, Bodying agent, thickener, superfatting agent, Stabilizers, polymers, fats, waxes, lecithins, phospholipids, biogenic agents, antidandruff agents, film formers, swelling agents, Insect repellents, self-tanner, tyrosinase inhibitors (Depigmenting agent), hydrotropes, solubilizers, preservatives, Perfume oils, dyes, etc., which are exemplified below are listed.

One The invention relates to cosmetic and / or pharmaceutical Preparations containing dialkyl carbonates according to formula (I) and at least one emulsifier and / or a surfactant and / or a wax component and / or a polymer and / or another oil body.

One preferred object of the invention relates to cosmetic and / or pharmaceutical preparations containing 0.1 to 80% by weight of dialkyl carbonates according to formula (I) and at least one emulsifier and / or a surfactant and / or a wax component and / or a polymer and / or another oil body.

emulsifier

In an embodiment of the invention contain the inventive Preparations at least one emulsifier.

One The invention relates to cosmetic and / or pharmaceutical Preparations containing dialkyl carbonates of the formula (I) and at least one emulsifier.

The Contain compositions of the invention the emulsifier (s) usually in an amount of 0 to 40% by weight, preferably 0.1 to 20% by weight, preferably 0.1 to 15 wt .-% and in particular 0.1 to 10 wt .-% based on the Total weight of the composition.

Each Emulsifier becomes a so-called HLB value (a dimensionless number between 0 and 20) indicating whether a preferred one Water or oil solubility is present. Numbers below 9 are preferably oil-soluble, hydrophobic Emulsifiers, numbers over 11 water-soluble, hydrophilic Emulsifiers.

Of the HLB value says something about the balance of size and strength of the hydrophilic and lipophilic groups of a Emulsifier off.

The HLB value of an emulsifier can also be calculated from increments, with the HLB increments for the different hydrophilic and hydrophobic groups that make up a molecule. As a rule, he can work with tables (eg HP Fiedler, Encyclopedia of Pharmaceuticals, Cosmetics and Adjacent Areas, Editio Cantor Verlag, Aulendorf, 4th ed. 1996 ) or the manufacturer's instructions. The solubility of the emulsifier in the two phases practically determines the type of emulsion. If the emulsifier is better soluble in water, an O / W emulsion is obtained. On the other hand, if the emulsifier has better solubility in the oiphase, a W / O emulsion is formed under otherwise identical production conditions.

In an embodiment of the invention contains the inventive preparation more than an emulsifier. The expert sets depending on the rest Components customary emulsifier systems (such as emulsifier and co-emulsifier).

Nonionic emulsifiers

• (1) Anlagerungsprodukte von 2 bis 50 Mol Ethylenoxid und/oder 1 bis 20 Mol Propylenoxid an lineare Fettalkohole mit 8 bis 40 C-Atomen, an Fettsäuren mit 12 bis 40 C-Atomen und an Alkylphenole mit 8 bis 15 C-Atomen in der Alkylgruppe.
• (2) C₁₂-C₁₈-Fettsäuremono- und -diester von Anlagerungsprodukten von 1 bis 50 Mol Ethylenoxid an Glycerin.
• (3) Sorbitanmono- und -diester von gesättigten und ungesättigten Fettsäuren mit 6 bis 22 Kohlenstoffatomen und deren Ethylenoxidanlagerungsprodukte.
• (4) Alkylmono- und -oligoglycoside mit 8 bis 22 Kohlenstoffatomen im Alkylrest und deren ethoxylierte Analoga.
• (5) Anlagerungsprodukte von 7 bis 60 Mol Ethylenoxid an Ricinusöl und/oder gehärtetes Ricinusöl.
• (6) Polyol- und insbesondere Polyglycerinester, wie z. B. Polyolpoly-12-hydroxystearate, Polyglycerinpolyricinoleat, Polyglycerindiisostearat oder Polyglycerindimerat. Ebenfalls geeignet sind Gemische von Verbindungen aus mehreren dieser Substanzklassen.
• (7) Anlagerungsprodukte von 2 bis 15 Mol Ethylenoxid an Ricinusöl und/oder gehärtetes Ricinusöl.
• (8) Partialester auf Basis linearer, verzweigter, ungesättigter bzw. gesättigter C₆-C₂₂-Fettsäuren, Ricinolsäure sowie 12-Hydroxystearinsäure und Polyglycerin, Pentaerythrit, Dipentaerythrit, Zuckeralkohole (z. B. Sorbit), Alkylglucoside (z. B. Methylglucosid, Butylglucosid, Laurylglucosid) sowie Polyglucoside (z. B. Cellulose), oder Mischester wie z. B. Glycerylstearatcitrat und Glycerylstearatlactat.
• (9) Polysiloxan-Polyalkyl-Polyether-Copolymere bzw. entsprechende Derivate.
• (10) Mischester aus Pentaerythrit, Fettsäuren, Citronensäure und Fettalkohol und/oder Mischester von Fettsäuren mit 6 bis 22 Kohlenstoffatomen, Methylglucose und Polyolen, vorzugsweise Glycerin oder Polyglycerin.

The group of nonionic emulsifiers include, for example:

• (1) addition products of 2 to 50 moles of ethylene oxide and / or 1 to 20 moles of propylene oxide to linear fatty alcohols having 8 to 40 carbon atoms, to fatty acids having 12 to 40 carbon atoms and to alkylphenols having 8 to 15 carbon atoms in the alkyl group.
• (2) C ₁₂ -C ₁₈ fatty acid mono- and diesters of addition products of 1 to 50 moles of ethylene oxide with glycerol.
• (3) sorbitan mono- and diesters of saturated and unsaturated fatty acids having 6 to 22 carbon atoms and their ethylene oxide addition products.
• (4) Alkyl mono- and oligoglycosides having 8 to 22 carbon atoms in the alkyl group and their ethoxylated analogs.
• (5) addition products of 7 to 60 moles of ethylene oxide with castor oil and / or hydrogenated castor oil.
• (6) polyol and in particular polyglycerol esters, such as. Polyol poly-12-hydroxystearates, Polyglycerinpolyricinoleat, Polyglycerindiisostearat or Polyglycerindimerat. Also suitable are mixtures of compounds of several of these classes of substances.
• (7) addition products of 2 to 15 moles of ethylene oxide with castor oil and / or hydrogenated castor oil.
• (8) partial esters based on linear, branched, unsaturated or saturated C ₆ -C ₂₂ fatty acids, ricinoleic acid and 12-hydroxystearic acid and polyglycerol, pentaerythritol, dipentaerythritol, sugar alcohols (eg sorbitol), alkyl glucosides (eg methyl glucoside , Butyl glucoside, lauryl glucoside) as well as polyglucosides (eg cellulose), or mixed esters such. Glyceryl stearate citrate and glyceryl stearate lactate.
• (9) Polysiloxane-polyalkyl-polyether copolymers or corresponding derivatives.
• (10) mixed esters of pentaerythritol, fatty acids, citric acid and fatty alcohol and / or mixed esters of fatty acids having 6 to 22 carbon atoms, methyl glucose and polyols, preferably glycerol or polyglycerol.

The addition products of ethylene oxide and / or of propylene oxide to fatty alcohols, fatty acids, alkylphenols, glycerol mono- and diesters and sorbitan mono- and diesters of fatty acids or to castor oil are known, commercially available products. These are mixtures of homologs whose mean Alkoxylierungsgrad the ratio of the amounts of ethylene oxide and / or propylene oxide and substrate, with which the addition reaction is carried out corresponds. Depending on the degree of ethoxylation, these are W / O or O / W emulsifiers. C _12/18 fatty acid _mono- and diesters of addition products of ethylene oxide with glycerol are known as refatting agents for cosmetic preparations.

According to the invention particularly useful and mild emulsifiers are polyol poly-12-hydroxystearates and mixtures thereof which, for example, under the trademarks Dehymuls ^® PGPH "(W / O-emulsifier) or" Eumulgin ^® VL 75 "(mixture of lauryl glucoside in the weight ratio 1: 1 , O / W emulsifier) or Dehymuls® ^® SBL (W / O emulsifier) are marketed by Cognis Germany GmbH. In this connection, in particular the European Patent EP 766 661 B1 directed. The polyol component of these emulsifiers can be derived from substances which have at least two, preferably from 3 to 12 and in particular from 3 to 8 hydroxyl groups and from 2 to 12 carbon atoms.

Particularly preferred emulsifiers are z. Cetyl dimethicone copolyol (e.g., Abil EM-90), polyglyceryl-2 dipolyhydroxystearates (e.g., Dehymuls PGPH), polyglycerol-3-diisostearates (e.g., Lameform TGI), polyglyceryl-4 isostearates (e.g. Isolan GI 34), polyglyceryl-3 oleates (eg Isolan GO 33), diisostearoyl polyglyceryl-3 diisostearates (eg Isolan PDI), polyglyceryl-3 methylglucose distearates (eg Tego Care 450), Polyglyceryl-3 Beeswax (eg Cera Bellina), Polyglyceryl-4 Caprate (eg Polyglycerol Caprate T2010 / 90), Polyglyceryl-3 Cetyl Ether (eg Chimexane NL), Polyglyceryl-3 Distearate (e.g. Cremophor GS 32) and polyglyceryl polyricinoleates (e.g., Admul WOL 1403), glyceryl oleates (e.g., Monomuls 90-O 18), alkyl glucosides (e.g., Plantacare 1200, Emulgade PL 68/50, Montanov 68, Tego Care CG 90, Tego Glucoside L 55), Methyl Glucose Isostearate (eg Tego Care IS), Methyl Glucose Sesquistearate (Tego Care PS), Sodium Cocoyl Hydrolyzed Wheat Protein (eg Gluadin WK), Potassium Cetyl phosphates (eg, amphisol K, Crodaf os CKP), sodium alkyl sulfates (e.g. B. Lanette E), sucrose esters (e.g., as Crodesta F-10, F-20, F-50, F-70, F-110, F-160, SL-40, Sucro Emulgade ^®), ethoxylated and / or propoxylated fatty alcohols fatty acids, castor oils or hydrogenated castor oils (eg Eumulgin B2, B2, B3, L, HRE 40, HRE 60, RO 40, Cremophor HRE 40, HRE 60, L, WO 7, Dehymuls HRE 7, Arlacel 989), PEG-30 dipolyhydroxystearates (eg Arlacel P 135, Dehymuls LE), sorbitan esters, sorbitan esters ethoxylated and / or propoxylated and mixtures thereof. A particularly effective mixture consists of polyglyceryl-2 dipolyhydroxystearates and lauryl glucosides and glycerol (eg Eumulgin VL 75). Also suitable are Polyglyceryl-4 Diisostearate / polyhydroxystearate / sebacate (Isolan ^® GPS), Diisostearoyl Polyglyceryl-3 Diisostearate (z. B. Isolan PDI), alkali metal salts of acyl glutamates (for. Example, Eumulgin SG).

As lipophilic W / O emulsifiers are in principle suitable emulsifiers with an HLB value of 1 to 8, which are summarized in numerous tables and known in the art. Some of these emulsifiers are for example in Kirk-Othmer, "Encyclopedia of Chemical Technology", 3rd Ed., 1979, Vol. 8, page 913 , listed. For ethoxylated products, the HLB value can also be calculated according to the following formula: HLB = (100-L): 5, where L is the weight fraction of the lipophilic groups, ie the fatty alkyl or fatty acyl groups in weight percent, in the ethylene oxide adducts.

Particularly advantageous from the group of W / O emulsifiers are partial esters of polyols, especially of C ₄ -C ₆ polyols, such as partial esters of pentaerythritol or sugar esters, eg. B. sucrose distearate, sorbitan monoisostearate, sorbitan sesquiisostearate, sorbitan diisostearate, sorbitan triisostearate, sorbitan monooleate, sorbitan sesquioleate, sorbitan dioleate, sorbitan trioleate, Sorbitanmonoerucat, Sorbitansesquierucat, Sorbitandierucat, Sorbitantrierucat, Sorbitanmonoricinoleat, Sorbitansesquiricinoleat, Sorbitandiricinoleat, Sorbitantriricinoleat, Sorbitanmonohydroxystearat, Sorbitansesquihydroxystearat, sorbitan dihydroxystearate, Sorbitantrihydroxystearat, Sorbitanmonotartrat, Sorbitansesquitartrat, Sorbitan ditartrate, sorbitan tritartrate, sorbitan monocitrate, sorbitan siccitrate, sorbitan di-citrate, sorbitan tricitrate, sorbitan monomaleate, sorbitan sesquimaleate, sorbitan adipate, sorbitan trimaleate, and technical mixtures thereof. Also suitable as emulsifiers are addition products of from 1 to 30, preferably from 5 to 10, mol of ethylene oxide with the stated sorbitan esters.

Depending on the formulation, it may be advantageous additionally to use at least one emulsifier from the group of nonionic O / W emulsifiers (HLB value: 8-18) and / or solubilizers. These are, for example, the already mentioned in the introduction ethylene oxide adducts with a correspondingly high degree of ethoxylation, z. B. 10-20 ethylene oxide units for O / W emulsifiers and 20-40 ethylene oxide units for so-called solubilizers. Particularly advantageous as O / W emulsifiers according to the invention are ceteareth-12 and PEG-20 stearate. Particularly suitable solubilizers are Eumulgin ^® HRE 40 (INCI: PEG-40 Hydrogenated Castor Oil), Eumulgin ^® HRE 60 (INCI: PEG-60 Hydrogenated Castor Oil), Eumulgin ^® L (INCI: PPG-1-PEG-9 Laurylglycolether) and Eumulgin ^® SML 20 (INCI: polysorbate-20).

Nonionic emulsifiers from the group of alkyl oligoglycosides are particularly skin-friendly and therefore preferably suitable as O / W emulsifiers. C ₈ -C ₂₂ alkyl mono- and oligoglycosides, their preparation and their use are known from the prior art. They are prepared in particular by reacting glucose or oligosaccharides with primary alcohols having 8 to 22 carbon atoms. With regard to the glycoside radical, both monoglycosides in which a cyclic sugar residue is glycosidically linked to the fatty alcohol and oligomeric glycosides having a degree of oligomerization of preferably approximately 8 are suitable. The degree of oligomerization is a statistical mean, which is based on a homolog distribution typical for such technical products. Products which are available under the name Plantacare ^®, a glucosidically bonded C ₈ -C ₁₆ alkyl group containing at an oligoglucoside whose average degree of oligomerization is 1 to the second The glucamine-derived acylglucamides are also suitable as nonionic emulsifiers. According to the invention is a product which is sold under the name Emulgade® ^® PL 68/50 by Cognis Germany GmbH and a 1: 1 mixture of alkyl polyglucosides and fatty alcohols. Also advantageously usable according to the invention is a mixture from Lauryl Glucoside, polyglyceryl-2-dipolyhydroxystearate, glycerine and water which is commercially available under the name Eumulgin ^® VL 75 miles.

When Emulsifiers also come substances such as lecithins and phospholipids in question. As examples of natural lecithins are called the cephalins, which are also called phosphatidic acids and derivatives of 1,2-diacyl-sn-glycerol-3-phosphoric acids represent. The opposite is understood by phospholipids usually mono- and preferably diesters of phosphoric acid with glycerol (glycerol phosphates), which are generally considered to be the fats become. In addition, sphingosines or sphingolipids are also suitable.

bei welcher X und Y unabhängig voneinander gewählt werden aus der Gruppe H (Wasserstoff) sowie der verzweigten und unverzweigten Alkylgruppen, Acylgruppen und Alkoxygruppen mit 1-24 Kohlenstoffatomen, p eine Zahl von 0–200 darstellt, q eine Zahl von 1–40 darstellt, und r eine Zahl von 1–100 darstellt.As emulsifiers, for example, silicone emulsifiers may be included. These can be selected, for example, from the group of alkylmethicone copolyols and / or alkyl dimethicone copolyols, in particular from the group of compounds which are characterized by the following chemical structure:

in which X and Y are independently selected from the group H (hydrogen) and the branched and unbranched alkyl groups, acyl groups and alkoxy groups having 1-24 carbon atoms, p is a number from 0-200, q represents a number from 1-40, and r represents a number from 1-100.

An example of particularly advantageous for the purposes of the present invention, silicone emulsifiers to be used are dimethicone, which Evonik Goldschmidt under the trade designations AXIL ^® B 8842, ABIL ^® B 8843, ABIL ^® B 8847, ABIL ^® B 8851, ABIL ^® B 8852, ABIL ^® B 8863, ABIL ^® B 8873 and ABIL ^® B 88183 are sold.

Another example of particularly advantageous for the purposes of the present invention to use surfactants is Cetyl PEG / PPG-10/1 Dimethicone (cetyl dimethicone), which is sold by Evonik Goldschmidt under the trade name ABIL ^® EM 90th

Another example of particularly advantageous for the purposes of the present invention to use surfactants is the cyclomethicone dimethicone copolyol, which is sold by Evonik Goldschmidt under the trade name ABIL ^® EM 97 and ABIL ^® WE 09th

Further, the emulsifier Lauryl PEG / PPG-18/18 Methicone (lauryl) has been found to be particularly advantageous, which under the tradename Dow Corning ^® 5200 Formulation Aid from Dow Corning Company Ltd. is available.

One Another advantageous silicone emulsifier is octyl dimethicone ethoxy Glucoside from Wacker.

For a water-in-silicone oil emulsion according to the invention, it is possible to use all known emulsifiers used for this emulsion type. Particularly preferred water-in-silicone emulsifiers according to the invention are cetyl PEG / PPG-10/1 dimethicone and lauryl PEG / PPG-18/18 methicone [z. B. ABIL ^® EM 90 Evonik Goldschmidt), DC5200 Formulation Aid (Dow Corning)] and any mixtures of both emulsifiers.

surfactants

In an embodiment of the invention contain the inventive Preparations at least one surfactant.

Surfactants are amphiphilic substances that can dissolve organic, nonpolar substances in water. she due to their specific molecular structure with at least one hydrophilic and a hydrophobic molecule part, for a lowering of the surface tension of the water, the wetting of the skin, the facilitation of the dirt removal and -solution, a gentle rinsing and - as desired - for foam regulation.

When Surfactants are usually surface active Understood substances that have an HLB value of greater 20 have.

One The invention relates to cosmetic and / or pharmaceutical Preparations containing dialkyl carbonates of the formula (I) and at least one surfactant.

When Surfactants may be anionic, nonionic, cationic and / or amphoteric or zwitterionic surfactants be. In surfactant-containing cosmetic preparations, such as, for example, shower gels, Foam baths, shampoos etc. is preferably at least contain an anionic surfactant.

The Contain compositions of the invention the surfactant (s) usually in an amount of 0 to 40 wt .-%, preferably 0.05 to 30 wt .-%, in particular 0.05 to 20 wt .-%, preferably 0.1 to 15 wt .-% and in particular 0.1 to 10% by weight based on the total weight of the composition.

typical Examples of nonionic surfactants are fatty alcohol polyglycol ethers, Alkylphenol polyglycol ethers, fatty acid polyglycol esters, fatty acid amide polyglycol ethers, Fatty amine polyglycol ethers, alkoxylated triglycerides, mixed ethers or mixed formals, optionally partially oxidized alk (en) yloligoglycosides or glucuronic acid derivatives, fatty acid N-alkylglucamides, Protein hydrolysates (in particular vegetable products based on wheat), Polyol fatty acid esters, sugar esters, sorbitan esters, polysorbates and amine oxides. Unless the nonionic surfactants are polyglycol ether chains These may contain a conventional, preferably however, have a narrow homolog distribution.

Zwitterionic surfactants are those surface-active compounds which carry in the molecule at least one quaternary ammonium group and at least one -COO ^(-) or -SO ₃ ^(-) group. Particularly suitable zwitterionic surfactants are the so-called betaines such as N-alkyl-N, N-dimethylammonium glycinates, for example cocoalkyldimethylammonium glycinate, N-acylaminopropyl-N, N-dimethylammonium glycinates, for example cocoacylaminopropyldimethylammonium glycinate, and 2-alkyl-3-carboxylmethyl 3-hydroxyethylimidazoline having in each case 8 to 18 carbon atoms in the alkyl or acyl group and cocoacylaminoethylhydroxyethylcarboxymethylglycinate. A preferred zwitterionic surfactant is the fatty acid amide derivative known by the INCI name Cocamidopropyl Betaine.

Also suitable, in particular as co-surfactants, are ampholytic surfactants. Ampholytic surfactants are understood as meaning those surface-active compounds which, apart from a C ₈ -C ₁₈ -alkyl or acyl group in the molecule, contain at least one free amino group and at least one -COOH or -SO ₃ H group and are capable of forming internal salts. Examples of suitable ampholytic surfactants are N-alkylglycines, N-alkylpropionic acids, N-alkylaminobutyric acids, N-alkyliminodipropionic acids, N-hydroxyethyl-N-alkylamidopropylglycines, N-alkyltaurines, N-alkylsarcosines, 2-alkylaminopropionic acids and alkylaminoacetic acids each having about 8 to 18 C Atoms in the alkyl group. Particularly preferred ampholytic surfactants are N-cocoalkylaminopropionate, cocoacylaminoethylaminopropionate and C _12-18 acylsarcosine.

typical Examples of amphoteric or zwitterionic surfactants are Alkylbetaines, alkylamidobetaines, aminopropionates, aminoglycinates, Imidazolinium betaines and sulfobetaines. For the surfactants mentioned are exclusively known compounds. As regards the structure and production of these substances, reference should be made to relevant reviews referenced in this field. Typical examples for especially suitable mild, d. H. particularly skin-friendly surfactants are fatty alcohol polyglycol ether sulfates, monoglyceride sulfates, mono- and / or dialkyl sulphosuccinates, fatty acid isethionates, fatty acid sarcosinates, Fatty acid taurides, fatty acid glutamates, α-olefinsulfonates, Ethercarbonsäuren, Alkyloligoglucoside and / or mixtures thereof with alkyl oligoglucoside carboxylates, fatty acid glucamides, Alkylamidobetaines, amphoacetals and / or protein fatty acid condensates, the latter preferably based on wheat proteins or their salts.

Anionic surfactants are characterized by a water-solubilizing, anionic group such. As a carboxylate, sulfate, sulfonate or phosphate group and a lipophilic radical. Skin-compatible anionic surfactants are known in the art in large numbers from relevant manuals and commercially available. These are, in particular, alkyl sulfates in the form of their alkali metal, ammonium or alkanolammonium salts, alkyl ether sulfates, alkyl ether carboxylates, acyl isethionates, acylsarcosinates, acyltaurines having linear alkyl or acyl groups having 12 to 18 carbon atoms, and sulfosuccinates and acylglutamates in the form of their alkali metal or ammonium salts.

typical Examples of anionic surfactants are soaps, alkylbenzenesulfonates, Alkanesulfonates, olefin sulfonates, alkyl ether sulfonates, glycerol ether sulfonates, α-methyl ester sulfonates, Sulfo fatty acids, alkyl sulfates, fatty alcohol ether sulfates, Glycerol ether sulfates, fatty acid ether sulfates, hydroxymethylene ether sulfates, Monoglyceride (ether) sulfate, fatty acid amide (ether) sulfate, Mono- and dialkylsulfosuccinates, mono- and dialkylsulfosuccinamates, Sulfotriglycerides, amide soaps, ether carboxylic acids and theirs Salts, fatty acid isethionates, fatty acid sarcosinates, Fatty acid taurides, N-acyl amino acids, such as Acyl lactylates, acyl tartrates, acyl glutamates and acyl aspartates, alkyl oligoglucoside sulfates, Protein fatty acid condensates (especially vegetable products wheat-based) and alkyl (ether) phosphates. Unless the anionic Surfactants contain polyglycol ether chains, these can be one conventional, but preferably a narrow homolog distribution exhibit.

Quaternary ammonium compounds can be used in particular as cationic surfactants. Preference is given to ammonium halides, in particular chlorides and bromides, such as alkyltrimethylammonium chlorides, dialkyldimethylammonium chlorides and trialkylmethylammonium chlorides, eg. Cetyl trimethyl ammonium chloride, stearyl trimethyl ammonium chloride, distearyl dimethyl ammonium chloride, lauryl dimethyl ammonium chloride, lauryl dimethyl benzyl ammonium chloride and tricetylmethyl ammonium chloride. Furthermore, the very readily biodegradable quaternary ester compounds, such as the sold under the trademark Stepantex ^® dialkyl ammonium methosulfates and Methylhydroxyalkyldialkoyloxyalkylammoniummethosulfate and the corresponding products of the Dehyquart ^® series, can be used as cationic surfactants. The term "esterquats" is generally understood to mean quaternized fatty acid triethanolamine ester salts. They can impart a special softness to the compositions according to the invention. These are known substances which are prepared by the relevant methods of organic chemistry. Further cationic surfactants which can be used according to the invention are the quaternized protein hydrolysates.

wax component

In an embodiment of the invention contain the inventive Preparations at least one wax component.

One The invention relates to cosmetic and / or pharmaceutical Preparations containing dialkyl carbonates of the formula (I) and at least one wax component.

The Contain compositions of the invention the wax component (s) usually in an amount from 0 to 40% by weight, especially from 0 to 20% by weight, preferably 0.1 to 15 wt .-% and in particular 0.1 to 10 wt .-% based on the total weight of the composition.

Under The term wax usually becomes all natural or artificially derived substances and mixtures with The following properties are understood: they are from solid to brittle hard consistency, coarse to fine crystalline, translucent to hazy and melt above 30 ° C without decomposition. you are already slightly above the melting point of low viscosity and not stringy and show a strong temperature-dependent Consistency and solubility. Usable according to the invention is a wax component or a mixture of wax components, which melt at 30 ° C or above.

When According to the invention, waxes can also be fats and fat-like substances of waxy consistency used as long as they have the required melting point. These include u. a. Fats (triglycerides), mono- and diglycerides, natural and synthetic waxes, fatty and wax alcohols, Fatty acids, esters of fatty alcohols and fatty acids as well as fatty acid amides or any mixtures of these substances.

Fats are triacylglycerols, ie the triple esters of fatty acids with glycerol. Preferably, they contain saturated, unbranched and unsubstituted fatty acid residues. These may also be mixed esters, ie triple esters of glycerol with different fatty acids. Usable according to the invention and particularly suitable as bodying agents are so-called hardened fats and oils which are obtained by partial hydrogenation. Herbal hardened fats and oils are preferred, e.g. As hardened castor oil, peanut oil, soybean oil, rapeseed oil, rapeseed oil, cottonseed oil, soybean oil, sunflower oil, palm oil, palm kernel l, linseed oil, almond oil, corn oil, olive oil, sesame oil, cocoa butter and coconut oil.

Suitable are u. a. the triple esters of glycerol with C12-C60 fatty acids and in particular C12-C36 fatty acids. This counts hardened castor oil, a triple ester of glycerol and a hydroxystearic acid, e.g. the term Cutina HR is on the market. Also suitable are glycerol tristearate, Glycerol tribehenate (eg Syncrowax HRC), glycerol tri-palmitate or the triglyceride mixtures known under the name Syncrowax HGLC, with the requirement that the melting point of the wax component or of the mixture is at 30 ° C or above.

When Wax components are according to the invention in particular Mono- and diglycerides or mixtures of these Partialglyceride used. To the inventively usable glyceride mixtures include those marketed by Cognis Deutschland GmbH & Co. KG Products Novata AB and Novata B (mixture of C12-C18 mono-, di- and triglycerides) as well as Cutina MD or Cutina GMS (glyceryl stearate).

To which can be used according to the invention as a wax component Fatty alcohols include the C12-C50 fatty alcohols. The fatty alcohols can be made from natural fats, oils and Waxes are obtained, such as myristyl alcohol, 1-pentadecanol, Cetyl alcohol, 1-heptadecanol, stearyl alcohol, 1-nonadecanol, arachidyl alcohol, 1-heenicosanol, behenyl alcohol, brassidyl alcohol, lignoceryl alcohol, Ceryl alcohol or myricyl alcohol. According to the invention preferred are saturated unbranched fatty alcohols. But also unsaturated, Branched or unbranched fatty alcohols can be used according to the invention as Wax component can be used as long as they meet the required melting point exhibit. Also usable according to the invention are fatty alcohol cuts, as in the reduction of naturally occurring fats and oils such. B. beef tallow, peanut oil, Rapeseed oil, cottonseed oil, soybean oil, Sunflower oil, palm kernel oil, linseed oil, castor oil, Corn oil, rapeseed oil, sesame oil, cocoa butter and coconut oil. But it can also be synthetic Alcohols, e.g. B. the linear, even-numbered fatty alcohols of the Ziegler synthesis (Alfole) or the partially branched alcohols from the oxo process (Dobanols) can be used. Particularly according to the invention C14-C22 fatty alcohols, which are for example suitable, are preferred from Cognis Deutschland GmbH under the name Lanette 18 (C18 alcohol), Lanette 16 (C16 alcohol), Lanette 14 (C14 alcohol), Lanette O (C16 / 18 alcohol) and Lanette 22 (C18 / C22 alcohol) become. Fatty alcohols give the compositions a drier Skin sensation as triglycerides and are therefore opposite the latter is preferred.

When Wax components can also contain C14-C40 fatty acids or mixtures thereof are used. These include, for example Myristic, pentadecane, palmitic, margarine, stearic, nonadecan, Arachin, beehive, lignocerin, cerotin, melissin, eruca and elaeostearic acid and substituted fatty acids, such as. B. 12-hydroxystearic acid, and the amides or monoethanolamides of fatty acids, wherein this list is exemplary and not restrictive Character has.

Usable according to the invention For example, natural vegetable waxes, such as Candelilla wax, carnauba wax, japan wax, esparto wax, cork wax, Guaruma wax, rice germ oil wax, sugar cane wax, ouricury wax, Montan wax, sunflower wax, fruit waxes such as orange waxes, lemon waxes, Grapefruit wax, bayberry wax (= Bayberrywax) and animal waxes, such as B. beeswax, shellac wax, spermaceti, wool wax and raffia fat. For the purposes of the invention, it may be advantageous to hydrogenated or use hardened waxes. To the invention usable natural waxes include the mineral waxes, such as Ceresin and ozokerite or the petrochemical waxes, such as As petrolatum, paraffin waxes and microwaxes. As a wax component are also chemically modified waxes, especially the hard waxes, such as As Montanesterwachse, Sasol waxes and hydrogenated jojoba waxes used. To the synthetic waxes which can be used according to the invention are, for example, waxy polyalkylene waxes and polyethylene glycol waxes. Vegetable waxes are preferred according to the invention.

The wax component can also be selected from the group of wax esters of saturated and / or unsaturated, branched and / or unbranched alkanecarboxylic acids and saturated and / or unsaturated, branched and / or unbranched alcohols, from the group of esters of aromatic carboxylic acids, dicarboxylic acids, tricarboxylic acids or hydroxycarboxylic acids (for example 12-hydroxystearic acid) and saturated and / or unsaturated, branched and / or unbranched alcohols, and also from the group of the lactides of long-chain hydroxycarboxylic acids. Examples of such esters are the C16-C40 alkyl stearates, C20-C40 alkyl stearates (eg Kester wax K82H), C20-C40 dialkyl esters of dimer acids, C18-C38 alkyl hydroxystearoyl stearates or C20-C40 alkyl erucates. Further, C30-C50 alkyl beeswax, tristearyl citrate, triisostearyl citrate, stearyl heptanoate, stearyl octanoate, trilauryl citrate, ethylene glycol dipalmitate, ethylene glycol distearate, ethylene glycol di (12-hydroxystearate), stearyl stearate, palmityl stearate, stearyl behenate, cetyl ester, cetea Rylbehenat and behenyl behenate used. Also Fettsäurepartialglyceride, ie technical mono- and / or diesters of glycerol with fatty acids having 12 to 18 carbon atoms such as glycerol mono / dilaurate, palmitate, myristate or stearate come into question.

When Waxes are still suitable pearlescent waxes. As pearlescent waxes, especially for use in surfactant formulations, For example: alkylene glycol esters, especially ethylene glycol distearate; Fatty acid alkanolamides, especially coconut fatty acid diethanolamide; Partial glycerides, especially stearic acid monoglyceride; ester of polybasic, optionally hydroxy-substituted carboxylic acids with fatty alcohols having 6 to 22 carbon atoms, especially long-chain Esters of tartaric acid; Fatty substances, such as fatty alcohols, Fatty ketones, fatty aldehydes, fatty ethers and fatty carbonates, in total at least 24 carbon atoms, especially laurone and distearyl ether; Fatty acids such as stearic acid, hydroxystearic acid or Behenic acid, ring-opening products of olefin epoxides with 12 to 22 carbon atoms with fatty alcohols with 12 to 22 Carbon atoms and / or polyols having 2 to 15 carbon atoms and 2 to 10 hydroxyl groups and mixtures thereof.

polymers

In an embodiment of the invention contain the inventive Preparations at least one polymer.

One The invention relates to cosmetic and / or pharmaceutical Preparations containing dialkyl carbonates according to formula (I) and at least one polymer.

The Contain compositions of the invention the polymer (s) usually in an amount of 0 to 20 wt .-%, preferably 0.1 to 15 wt .-% and in particular 0.1 to 10% by weight based on the total weight of the composition.

Suitable cationic polymers are, for example, cationic cellulose derivatives, such as. Example, a quaternized hydroxyethylcellulose obtainable under the name Polymer JR 400 ^® from Amerchol, cationic starch, copolymers of diallyl ammonium salts and acrylamides, quaternized vinylpyrrolidone / vinylimidazole polymers, such. As Luviquat ^® (BASF), condensation products of polyglycols and amines, quaternized collagen polypeptides, for example lauryldimonium hydroxypropyl hydrolyzed collagen (Lamequat® ^® L / Grunau), quaternized wheat polypeptides, polyethyleneimine, cationic silicone polymers such. B. amidomethicones, copolymers of adipic acid and Dimethylaminohydroxypropyldiethylentriamin (Cartaretine ^® / Sandoz), copolymers of acrylic acid with dimethyldiallyl ammonium chloride (Merquat ^® 550 / Chemviron), polyaminopolyamides, cationic chitin derivatives such as quaternized chitosan, optionally microcrystalline distributed, condensation products of dihaloalkylene, such as. B. dibromobutane with bis-dialkylamines, such as. B. bis-dimethylamino-1,3-propane, cationic guar gum, such as. ^Jaguar® CBS, ^Jaguar® C-17, ^Jaguar® C-16 from Celanese, quaternized ammonium salt polymers, e.g. B. Mirapol ^® A-15, Mirapol ^® AD-1, Mirapol ^® AZ-1 from Miranol.

When anionic, zwitterionic, amphoteric and nonionic polymers for example, vinyl acetate / crotonic acid copolymers, Vinylpyrrolidone / vinyl acrylate copolymers, vinyl acetate / butyl maleate / isobornyl acrylate Copolymers, methyl vinyl ether / maleic anhydride copolymers and their esters, uncrosslinked polyols crosslinked with polyols, Acrylamidopropyltrimethylammonium chloride / acrylate copolymers, octylacrylamide / methylmethacrylate / tert.butylaminoethylmethacrylate / 2-hydroxypropylmethacrylate copolymers, Polyvinylpyrrolidone, vinylpyrrolidone / vinylacetate copolymers, vinylpyrrolidone / dimethylaminoethylmethacrylate / vinylcaprolactam terpolymers and optionally derivatized cellulose ethers and silicones in question.

Also suitable as polymers are polysaccharides, especially xanthan gum, guar guar, agar agar, alginates and Tyloses and, for example, Aerosil types (hydrophilic silicas), carboxymethyl cellulose and hydroxyethyl and hydroxypropyl cellulose, polyvinyl alcohol, polyvinyl pyrrolidone and bentonites such. B. Bentone ^® Gel VS-5PC (Rheox).

Also suitable are so-called quaternary polymers, for. With the INCI name Polyquaternium-37, which correspond to the following general formula:
Alternatively, other dialkylaminoalkyl (meth) acrylates and their ammonium salts or dialkylaminoalkyl (meth) acrylamides obtainable by alkylation or protonation and also their ammonium salts obtained by alkylation or protonation can be used. Especially preferred are polymers containing MAPTAC, APTAC, MADAME, ADAMS, DMAEMA and TMAEMAC. In addition, it is also possible to use copolymers with anionic, other cationic or uncharged monomers according to the invention, in particular those which additionally (meth) acrylate and / or 2-acrylamido-2-methyl -propanesulfonic acid and / or acrylamide and / or vinylpyrrolidone and / or alkyl (meth) acrylates.

exemplary are such polymers with the INCI name Polyquaternium-11, Polyquaternium-13, Polyquaternium-14, Polyquaternium-15, Polyquaternium-28, Polyquaternium-32, Polyquaternium-43, Polyquaternium-47.

oil body

In an embodiment of the invention contain the inventive Preparations at least one oil body. Usually contain the preparations according to the invention Dialkyl carbonates of the formula (I) as an oil body. In the embodiment mentioned here as preferred the preparations thus one of the inventive Dialkycarbonates different oil body, too referred to as "another oil body".

One preferred object of the invention relates to cosmetic and / or pharmaceutical preparations containing dialkyl carbonates of the formula (I) and at least one (further) oil body.

The oil bodies (inventive dialkyl carbonates plus other oil bodies) are usually in a total amount of 0.1-90, in particular 0.1-80, in particular 0.5 to 70, preferred 1 to 60, in particular 1 to 50 wt .-%, in particular 1 to 40 wt .-%, preferably 5-25% by weight and especially 5-15 Wt .-% included. The other oil bodies are common in an amount of 0.1 to 40 wt .-% - based on the total weight the preparation - included.

Guerbet alcohols based on fatty alcohols having 6 to 18, preferably 8 to 10, carbon atoms, as well as further, additional esters such as myristyl myristate, myristyl palmitate, myristyl stearate, myristyl isostearate, myristyl oleate, myristyl behenate, myristyl erucate, cetyl myristate, cetyl palmitate, cetyl stearate, cetyl isostearate are suitable as further oil bodies , cetyl oleate, cetyl behenate, Cetylerucat, Stearylmyristat, stearyl palmitate, stearyl stearate, Stearylisostearat, stearyl oleate, stearyl behenate, Stearylerucat, isostearyl, isostearyl palmitate, Isostearylstearat, isostearyl isostearate, Isostearyloleat, isostearyl behenate, Isostearyloleat, oleyl myristate, oleyl palmitate, oleyl stearate, oleyl isostearate, oleyl oleate, Oleylbehenat, oleyl erucate, behenyl myristate , Behenyl palmitate, behenyl stearate, behenyl isostearate, behenyl oleate, behenyl behenate, behenyl erucate, erucyl myristate, erucyl palmitate, erucyl stearate, erucyl isostearate, erucyl oleate, erucyl behenate and erucyl erucate. In addition, esters of C ₁₈ -C ₃₈ -alkylhydroxycarboxylic acids with linear or branched C ₆ -C ₂₂ -fat are suitable alcohols, in particular dioctyl malates, esters of linear and / or branched fatty acids with polyhydric alcohols (such as, for example, propylene glycol, dimerdiol or trimer triol), triglycerides based on C ₆ -C ₁₀ fatty acids, liquid mono- / di- / triglyceride mixtures Base of C ₆ -C ₁₈ fatty acids, esters of C ₆ -C ₂₂ fatty alcohols and / or Guerbet alcohols with aromatic carboxylic acids, in particular benzoic acid, esters of C ₂ -C ₁₂ dicarboxylic acids with polyols having 2 to 10 carbon atoms and 2 to 6 Hydroxyl groups, vegetable oils, branched primary alcohols, substituted cyclohexanes, linear and branched C ₆ -C ₂₂ fatty alcohol carbonates, such as. B. Dicaprylyl carbonates (Cetiol ^® CC) Guerbetcarbonate based on fatty alcohols having 6 to 18, preferably 8 to 10 C atoms, esters of benzoic acid with linear and / or branched C ₆ -C ₂₂ alcohols (eg Finsolv ^® TN), linear or branched, symmetrical or asymmetrical dialkyl ethers having 6 to 22 carbon atoms per alkyl group, such as. As dicaprylyl (Cetiol ^® OE), ring-opening products of epoxidized fatty acid esters with polyols and hydrocarbons or mixtures thereof.

auszeichnen werden auch als Polydimethylsiloxan bzw. Dimethicon (INCI) bezeichnet. Dimethicon gibt es in verschiedenen Kettenlängen bzw. mit verschiedenen Molekulargewichten.As further oil body, for example, silicone oils come into question. They can be present as cyclic and / or linear silicone oils. Silicone oils are high molecular weight synthetic polymeric compounds in which silicon atoms via oxygen atoms chain and / or net-like linked and the remaining valences of silicon by hydrocarbon radicals (usually methyl, more rarely ethyl, propyl, phenyl groups, etc.) are saturated. Systematically, the silicone oils are called polyorganosiloxanes. The methyl-substituted polyorganosiloxanes, which are the quantitatively most important compounds of this group and are represented by the following structural formula

are also referred to as polydimethylsiloxane or dimethicone (INCI). Dimethicone is available in different chain lengths or with different molecular weights.

advantageous Polyorganosiloxanes in the context of the present invention are, for example Dimethylpolysiloxane [poly (dimethylsiloxane)], which, for example under the trade names Abil 10 to 10 000 at Evonik Goldschmidt are available. Also advantageous are phenylmethylpolysiloxane (INCI: phenyl dimethicone, phenyl trimethicone), cyclic silicones (Octamethylcyclotetrasiloxane or decamethylcyclopentasiloxane), which according to INCI are also referred to as cyclomethicone, amino-modified Silicones (INCI: Amodimethicone) and silicone waxes, eg. B. polysiloxane-polyalkylene copolymers (INCI: stearyl dimethicone and cetyl dimethicone) and dialkoxydimethylpolysiloxanes (Stearoxy dimethicone and behenoxy stearyl dimethicone), which as various Abil wax types available from Evonik Goldschmidt are. But other silicone oils are beneficial in the sense of the present invention, for example, cetyidimethicone, Hexamethylcyclo-trisiloxane, polydimethylsiloxane, poly (methylphenylsiloxane). Particularly preferred according to the invention silicones are dimethicone and cyclomethicone.

The Preparations according to the invention can furthermore biogenic agents, insect repellents, tyrosinase Inhibitors, preservatives, perfume oils, superfatting agents, Stabilizers and / or hydrotropes included.

One The invention relates to cosmetic and / or pharmaceutical Preparations containing dialkyl carbonates of the formula (I) and at least one biogenic active ingredient, insect repellent, Tyrosinase inhibitor, preservative, perfume oil, Stabilizer and / or hydrotrog.

One preferred object of the invention relates to cosmetic and / or pharmaceutical preparations containing dialkyl carbonates of the formula (I) and at least one biogenic active ingredient, insect repellent, Tyrosinase inhibitor, preservative, perfume oil, Stabilizer and / or hydrotrog.

Under biogenic agents are for example tocopherol, tocopherol acetate, Tocopherol palmitate, ascorbic acid, (deoxy) ribonucleic acid and their fragmentation products, β-glucans, retinol, Bisabolol, allantoin, phytantriol, panthenol, AHA acids, Amino acids, ceramides, pseudoceramides, essential oils, plant extracts, such as Aloe vera, Prunus extract, Bambaranus extract and vitamin complexes to understand.

Suitable insect repellents are N, N-diethyl-m-toluamide, 1,2-pentanediol or 3- come (Nn-butyl-N-acetyl-amino) -propionic acid ethyl ester), which under the name ^® Insect Repellent 3535 from Merck KGaA, as well as Butylacetylaminopropionate in question.

When Tyrosinhinbitoren that prevent the formation of melanin and application in depigmenting agents, for example, arbutin, Ferulic acid, kojic acid, coumaric acid and ascorbic acid (vitamin C) in question.

Suitable preservatives are, for example, phenoxyethanol, formaldehyde solution, parabens, pentanediol or sorbic acid and the silver ^complexes known under the name Surfacine®. Furthermore, are suitable as preservatives in WO 07/048757 described 1,2 alkanediols having 5 to 8 carbon atoms.

Suitable preservatives are in particular the according to Annex VI of the Commission Directive (in the Commission Directive 2007/22 / EC of 17 April 2007 amending Council Directive 76/768 / EEC, concerning cosmetic products, for the purposes of adapting Annexes IV and VI to technical Progress ) substances, which are explicitly referred to here.

When Perfume oils are called mixtures of natural and synthetic fragrances. Natural fragrances are extracts of flowers, stems and leaves, Fruits, fruit peels, roots, woods, herbs and grasses, needles and twigs, resins and balsams. Farther come from animal raw materials, such as civet and castoreum and synthetic fragrance compounds of the ester, ether, Aldehydes, ketones, alcohols and hydrocarbons in question.

When Stabilizers can be metal salts of fatty acids, such as For example, magnesium, aluminum and / or zinc stearate or ricinoleate be used.

to Improvement of the flow behavior can further Hydrotropes, such as ethanol, isopropyl alcohol, or polyols be used. Polyols, which come into consideration, own preferably 2 to 15 carbon atoms and at least two hydroxyl groups. The polyols may contain other functional groups, in particular Amino groups, or be modified with nitrogen.

Examples

formulation Examples

The following formulation examples include a dialkyl carbonate according to formula (I) Di-n-octyl carbonate, which is available untder the trade name Cetiol ^® CC from Cognis. (INCI: Dicarpylylcarbonate). All-purpose cream (W / O) phase Component / trade name INCI Wt .-% I. DEHYMULS ^® E Dicocoyl Pentaerhytithyl Distearyl Citrate (and) Sorbitan Sesquioleate (and) Cera Alba (Beeswax) (and) Aluminum Stearate 3.00 DEHYMULS ^® PGPH Polyglyceryl 2 dipolyhydroxystearates 2.00 CETIOL ^® OE Dicaprylyl ether 5.00 CETIOL ^® 868 Ethylhexyl stearate 5.00 MYRITOL ^® 331 Cocoglycerides 1.00 CETIOL ^® CC 6.00 II. Glycerin 86% 5.00 MgSO ₄ × 7H ₂ O 1.00 Water, deionized 72,00 III. preservative qs

production:

• * erhältlich von Lambert-Rivière (France)

The components of Phase I were melted at 80 to 85 ° C and stirred to homogeneity. The components of phase II were heated to 80 to 85 ° C and added slowly to phase I with stirring. It was stirred for a further 5 minutes at this temperature. Thereafter, the emulsion was cooled with stirring and homogenized at 65 to 55 ° C. As soon as the emulsion appears homogeneous, it was further cooled to 30 ° C. with stirring. Thereafter, phase III components were added and stirred again. Balm for moisturizing and protecting the lips phase Component trade name INCI Wt .-% I. Cerilla Raffinée G * Candelilla (Euphorbia cerifera) Wax 7.53 CUTINA ^® LM conc. Polyglyceryl-2 Dipolyhydroxystearates and Octyldodecanol and Copernicia Cerifera (Carnauba) Wax and Euphorbia Cerifera (Candelilla) Wax and Beeswax and Cetearyl Glucosides and Cetearyl Alcohol 6.57 Colophane claire type Y Rosin 1.89 Cerauba T1 * Carnauba (Copernica cerifera) wax 1.86 Cerabeil blanche 1 * Beeswax 5.31 CETIOL ^® CC 15:57 EUTANOL ^® G octyldodecanol 21.71 Crodamol ML (Croda) Myristyl lactate 1.13 ELESTAB ^® 36 6 12:43 II. Castor oil Castor oil 35.00 III. IRWINOL ^® LS 9319 African wild mango butter 3:00

• * available from Lambert-Rivière (France)

Preparation: Phase I was melted at 85 ° C, Phase II was added and the temperature maintained at 80 ° C. Phase III was added shortly before pouring into the mold (which had been moistened with dimethicone 50 cts and preheated to 40 ° C). The mass was placed in the mold and cooled to 40 ° C. The molds were cooled in the freezer to near 0 ° C. Styling wax phase Component trade name INCI Wt .-% I. CUTINA ^® MD Glyceryl stearate 47.0 COMPERLAN ^® 100 Cocamide MEA 2.50 CUTINA ^® HR Powder Hydrogenated Castor Oil 2.50 PLANTACARE ^® 1200 UP Lauryl glucoside 5.00 LANETTE ^® O Cetearyl Alcohol 7.00 CUTINA ^® CP Cetyl palmitate 7.00 Eumulgin ^® O 20 Oleth-20 5.00 CETIOL ^® CC 23.5 Wacker silicone oil AK 350 Dimethicone 0.50

The preparation is carried out by heating all components to 80 ° C and homogenization. Moisturizing body milk phase Component trade name INCI Wt .-% EMULGADE ^® CM Cetearyl Isononanoate (and) Ceteareth-20 (and) Cetearyl Alcohol (and) Glyceryl Stearate (and) Glycerin (and) Ceteareth 5.0 Eumulgin ^® VL 75 Lauryl Glucoside (and) Polyglyceryl-2 Dipolyhydroxystearate (and) Glycerin 2.0 CETIOL ^® OE Dicaprylyl ether 4.0 CETIOL ^® J 600 Oleyl erucate 1.0 isopropyl myristate Isopropyl myristate 7.0 CETIOL ^® CC 7.0 II. Water, deionized ad 100 III. Cosmedia SP Sodium polyacrylate 0.4 IV. Hispagel ^® 200 Glycerol (and) Glyceryl Polyacrylates 20.0 V. Preservative, perfume qs pH 5.5

The preparation was carried out by mixing phase I and water at room temperature with stirring. Then, Phase III was added and stirred until a homogeneous, swollen mixture was present. Then, Phase IV was added, followed by Phase V, then the pH was adjusted. O / W soft cream phase Component trade name INCI Wt .-% I. Emulgade® ^® SE-PF Glyceryl Stearate (and) Ceteareth-20 (and) Ceteareth-12 (and) Stearyl Alcohol (and) Ceteareth-20 (and) distearyl ether 6.0 LANETTE ^® O Cetearyl Alcohol 1.0 CUTINA ^® MD Glyceryl stearate 2.0 CETIOL ^® MM Myristyl myristate 2.0 CETIOL ^® CC 8.0 Jojoba Oil Simmondsia chinensis (jojoba) Seed Oil 2.0 Copherol® ^® 1250 Tocopheryl acetate 0.5 Dimethicone 0.5 Cyclomethicone 3.0 II. water Aqua ad 100 Propylene glycol 3.0 III. Hispagel ^® 200 Glycerol (and) Glyceryl Polyacrylates 15.0 IV. preservative qs pH 5.5-6.5

This cream was prepared by heating Phase I to 80 ° C, Phase II was also heated to 80 ° C and added to Phase I with stirring. This mixture was cooled while stirring and homogenized at about 55 ° C. with a suitable dispersion apparatus (eg Ultra Turrax). Thereafter, Phase III was added with continuous stirring, Phase IV was added and the pH was adjusted. W / O cream phase Component / product name INCI Wt .-% I. MONOMULS ^® 90 O 18 Glyceryl Oleate 2.00 LAMEFORM ^® TGI Polyglyceryl 3 diisostearate 4.00 CETIOL ^® A Hexyl Laurate 12,00 CETIOL ^® CC 12,00 SIPOL ^® C 16/18 OR Cetearyl Alcohol 1.00 Zinc stearate Zinc stearate 2.00 Zinc oxides CI 77947 (or) Zinc Oxide 15.00 Magnesium sulphates Magnesium sulphates 1.00 glycerin glycerin 3.00 preservative qs Benzyl Alcohol Benzyl Alcohol 0.40 HYDAGEN ^® B bisabolol 0.50 water aqua 100.00

The first 7 components were melted at 85 ° C. Magnesium sulfates and glycerine were dissolved in the water and this mixture was heated to 85 ° C. This aqueous phase was added to the oil phase and dispersed. With continued stirring, it was cooled to 40 ° C and then benzyl alcohol and Hydagen B were mixed and added to the emulsion. With further stirring was cooled to 30 ° C and homogenized. "Body Wash" cleansing emulsion phase Component trade name INCI Wt .-% I Texapon ALS-IS Ammonium Lauryl Sulfate 30.00 TEXAPON ^® NSO Sodium Laureth Sulfate 18,00 CETIOL ^® CC 18,00 Plantacare® ^® 1200 Lauryl glucoside 8.00 II Jaguar HP 105 Hydroxypopyl guar 2.00 Euxyl K400 Methyl dibromo glutaronitrile and phenoxyethanol 0.10 water Aqua 23,90 pH-value 5.6

Table 1: O / W sunscreen emulsions

• * National Starch

Tabelle 10B: Antiperspirant Suspensionsstifte sowie Soft Solids – Mengenangaben in Gew.-% – Zusammensetzung 7 8 12-Hydroxystearinsäure 10 5 CETIOL^® CC 65 65 Dry Flo Plus* - 5 Aluminium Zirconium Tetrachlorohydrex GLY 25 25

• * National Starch

Tabelle 11: Rezepturen 1 bis 13 Komponenten INCI (Handelsname) 1 2 3 4 5 6 7 8 9 10 11 12 13 Glyceryl Stearate, Ceteareth-20, Ceteareth-12, Cetearyl Alkohol, Cetyl Palamitate (Emulgade^® SE) 10.7 5.1 Ceteareth-20 (Eumulgin^® B2) 5.8 3.4 Cetearyl Glucoside, Cetearyl Alcohol (Emulgade^® PL 68/50) 1 1 1 2 2 2 2 Polyglyceryl-2 Dipolyhydroxystearate, Lauryl Glucoside, Glycerin (Eumulgin^® VL 75) 1 1 3 2.5 Sodium Cetearyl Sulfate (Lanette^® E) 1 1 1 1 1 1 Dicaprylyl Carbonate (Cetiol^®CC) 10 9 13 3 5 8 4 6 4 8 8 14 2 Cocoglycerides (Myritol^® 331) 3 4 4 4 5 3 3 Dicaprylyl Ether (Cetiol^® OE) 5 3 2 Dibutyl Adipate (Cetiol^® B) 4 4 4 Hydrogenated Dimer Dilinoleyl/Dimethylcarbonate Copolymer (Cosmedia^® DC) 1 1 1 1 1 1.5 1.5 2 3 2 1.5 2 2 Ethyl Butylacetylaminopropionate 5 5 Tocopherol 1 1 1 1 1 1 1 1 1 1 1 1 1 Zinc oxide, nanonisiert, gecoated 5 5 5 5 5 2 5 3 Titanium dioxide, nanonisiert, Gecoated 5 5 2 3 5 2 Ethyl hexyl Methoxycinnamate 7.5 7.5 7.5 3 1 3 5 5 5 Octocrylene 9 9 9 2 1 2 1.5 Butyl Methoxydibenzoylmethane 2 2 1 2 2 4-Methylbenzylidene Camphor 2 2 Ethylhexyl Triazone 1 1 2 1 Diethylhexyl Butamido Triazone 1 1 2 1 2 Phenylbenzimidazole 13.3 Sulfonic Acid als Na-Salz, 15% wäßrige Lsg. Glycerin 3 3 3 3 3 3 3 3 3 3 3 5 5 Magnesium aluminium silicate (and) cellulose Gum 0.75 0.75 0.5 0.5 0.5 0.35 Xanthan Gum 0.25 0.25 0.5 0.5 0.5 0.35 Sodium Polyacrylate (Cosmedia^® SP) 0.1 0.1 0.2 0.1 Acrylates/C10-30 Alkyl Acrylate Crosspolymer 0.2 0.1 Wasser, Perfume, Preservatives q.s. q.s. q.s. q.s. q.s. q.s. q.s. q.s. q.s. q.s. q.s. q.s. q.s. Tabelle 12: Rezepturen 14 bis 26 Komponenten INCI (Handelsname) 14 15 16 17 18 19 20 21 22 23 24 25 26 Glyceryl Stearate, Ceteareth-20, Ceteareth-12, Cetearyl Alcohol, Cetyl Palmitate (Emulgade^® SE) 3.7 3.7 4.9 4.1 Ceteareth-12 (Eumulgin^®B1) 1.3 1.3 Ceteareth-20 (Eumulgin^®B2) 1.1 0.9 Cetearyl Glucoside, Cetearyl Alcohol (Emulgade^® PL 68/50) 5 1 1 1 1 3 Polyglyceryl-2 Dipolyhydroxystearate, Lauryl Glucoside, Glycerin (Eumulgin^® VL 75) 3 5 5 Sodium Cetearyl Sulfate (Lanette^® E) 0.25 0.25 0.25 0.25 0.25 Potassium Cetyl Phosphate 0.5 Dicaprylyl Carbonate (Cetiol^® CC) 9 5 11 8 5 8 8 10 9.5 8 14 10 10 Coco-Caprylate/Caprate (Cetiol^® LC) 1 1 1 1 1 Caprylic/Capric Triglyceride (Myritol^® 312) 1 1 1 1 1 Cocoglycerides (Myritol^® 331) 4 4 Cetearyl Isononanoate (Cetiol^® SN) 3 3 3.5 Octyldodecanol (Eutanol^® G) 3.5 2 2 Hexyldecanol (Eutanol^® G16) 1 1 1 1 1 Olus (Cegesoft^® PS6) 1.5 1.5 Passiflora Incarnata (Cegesoft^® PFO) 1.5 Dimethicone 0.5 0.5 0.5 0.5 0.5 Dimer Distearyltricarbonate (Cosmedia^® DC) 1 1.5 1.5 2,5 2,5 0.5 Triethyl Citrate (Hydagen^® C.A.T) 1.5 Tocopherol 0.5 0.5 0.5 Tocopheryl Acetate 0.5 0.5 Ethanol 5 Aluminum Chlorhydrate (Locron L) 40 Chitosan (Hydagen^® DCMF) 0.1 Glycolic Acid 0.04 Glycerin 2 2 2 3 3 3 3 3 2 2 2 3 2 Potassium Hydroxyde, 20% wäßrige Lsg. 0.3 0.2 0.1 0.4 0.3 0.5 Glycerin, Glyceryl Polyacrylate (Hispagel^® 50) 10 Carbomer 0.1 0.2 0.2 Sodium Polyacrylate (Cosmedia^® SP) 0.15 Acrylates/C10-30 Alkyl Acrylate Crosspolymer 0.15 0.05 Wasser, Perfume, Preservatives q.s q.s. q.s. q.s. q.s. q.s. q.s. q.s. q.s. q.s. q.s. q.s. Tabelle 13: Rezepturen 27 bis 33 (Formulierungen für AP/Deo) Komponenten INCI (Handelsname) 27 28 29 30 31 32 33 Glyceryl Stearate, Ceteareth-20, Ceteareth-12, Cetearyl Alcohol, Cetyl Palmitate (Emulgade^® SE) 6 4,5 6 Ceteareth-20 (Eumulgin^®B2) 1 Cetearyl Isononanoate, Glyceryl Stearate, Ceteareth-20, Ceteareth-12, Cetearyl Alcohol, Cetyl Palmitate (Emulgade^® CM) 20 Polyglyceryl-3 Diisostearate Lameform TGI 3 Cocoglycerides (Novata^® AB) 4 Stearyl alcohol (Lanette 18) 14,7 Hydrogenated Castor Oil (Cutina^® HR) 3,7 6,5 Polyglyceryl-2 Dipolyhydroxystearate, (Dehymuls^® PGPH) 1 Sodium Cetearyl Sulfate (Lanette^® E) 0,3 0,3 Behenyl Alcohol (Lanette^® 22) 2 4 Dicaprylyl Carbonate (Cetiol^® CC) 4 7 5 5 4 4 15 Dicaprylylether (Cetiol^® OE) 2 4 3 9 Cocoglycerides (Myritol^® 331) Cyclopentasiloxane 3 5 34 2 14 Cyclopentasiloxane and Dimethicone/Vinyldimethicone Crosspolymer SFE 839 (GE Bayer) 3 Dimethicone 1 Dimer Distearyltricarbonate (Cosmedia^® DC) 1 1 1 1 1 1 1 Triethyl Citrate (Hydagen^® C.A.T) 2 PEG-40 Hydrogenated Castor Oil 1 Tocopheryl Acetate 1 Aluminium Zirconium Tetrachlorohydrex GLY (Rezal 36) 30 40 22,9 30 25 Aluminum Chlorhydrate (Locron L) 10 Chitosan (Hydagen^® DCMF) 0,05 Glycolic Acid 0,02 Glycerin 5 5 Propylene Carbonate (Fluka) 0,5 Quaternium-18 Hectorite (Bentone 18) 1 Talc (Merck) 5 5 MgSO4 × 7H2O 1 Wasser Phase II 46,7 35 Wasser, Perfume, Preservatives q.s. q.s. q.s. q.s. q.s. q.s. q.s.

• 27 – Antiperspirant/Deo Crème/28 – Antiperspirant Creme (W/O)/29 – Antiperspirant/Deo Spray 30 – Antiperspirant Stift mit Vitamin E/31 – Deodorant Wipe – Formulierung/32 – Antiperspirant Creme 33 – Antiperspirant Creme «Soft Solid»

All data in% by weight. component 1 2 3 4 5 6 7 8th 9 10 11 L = lotion, C = cream, L C S L C L L C L C L Eumulgin ^® VL 75 4 4 2 Eumulgin ^® B2 2 Tween ^® 60 1 Myrj ^® 51 3 2 Cutina ^® E 24 1 1 Hostaphat ^® KL 340 N 2 Lanette ^® e 0.5 0.5 Amphisol® ^® K 1 1 0.5 1 sodium 1 2 Emulgade® ^® PL 68/50 1 5 4 Tego ^® Care 450 3 Cutina ^® MD 2 6 4 6 Lanette ^® 14 1 1 2 4 Lanette ^® O 1 6 5 2 2 Antaron V 216 1 2 2 1 Lanolin, anhydrous USP 5 myritol ^® PC 5 myritol ^® 331 5 8th 6 10 2 Finsolv ^® TN 1 1 8th Cetiol ^® CC 2 4 9 1 2 6 6 3 2 4 1 Cetiol ^® OE 3 2 3 Dow Corning DC ^® 244 4 1 5 2 2 Dow Corning DC ^® 2502 1 2 Silicone oil Wacker AK ^® 350 2 Cetiol ^® 868 2 8th 7 Cetiol ^® J 600 3 2 5 mineral oil 9 Cetiol ^® B 1 2 eutanol ^® G eutanol ^® G 16 Cetiol ^® PGL 5 5 Continuation Table 1: O / W sunscreen emulsions component 1 2 3 4 5 6 7 8th 9 10 11 almond oil 2 1 Photonyl ^® LS 2 2 panthenol 1 bisabolol 0.2 Tocopherol / tocopheryl acetate 1 Photonyl ^® LS 1 Neo Heliopan ^® Hydro (Na salt) 2 2.2 3 3 2 Neo Heliopan AP (Na salt) 2 1.5 2 2 1 1 Neo Heliopan ^® 303 3 5 9 4 Neo Heliopan ^® BB 1 2 Neo Heliopan ^® MBC 2 3 2 2 2 1 Neo Heliopan ^® OS 10 7 Neo Heliopan ^® E 1000 7.5 6 6 Neo Heliopan ^® AV 7.5 7.5 4 5 Uvinul ^® T 150 2 2.5 1 Parsol ^® 1789 1 1 2 2 2 Zinc oxide NDM 10 5 10 3 5 4 Eusolex ^® T 2000 5 3 3 4 Veegum ^® Ultra 0.75 1 1 Keltrol ^® T 12:25 0.5 0.5 Carbopol ^® 980 0.5 0.2 0.2 0.2 0.5 0.1 0.3 0.2 ethanol 10 butylene 2 4 3 2 5 2 2 glycerin 5 5 5 3 3 2 4 3 Preservative, NaOH qs water Ad 100 Table 2: O / W sunscreen emulsions component 12 13 14 15 16 17 18 19 20 21 22 L = lotion, C = cream, L L L C L C S C C L L Eumulgin ^® VL 75 4 3 4.5 3 4 Eumulgin ^® B2 1 Tween ^® 60 1 Cutina ^® E 24 2 Hostaphat ^® KL 340 N 0.5 Lanette ^® e 0.5 0.5 0.5 0.1 0.5 Amphisol® ^® K 0.5 1 1 1 sodium 1 Emulgade® ^® PL 68/50 6 4.5 1 5 Tego ^® Care 450 1 4 Cutina ^® MD 1 8th 6 1 4 1 Lanette ^® 14 2 2 1 Lanette ^® O 2 1 1 Antaron V 220 1 2 0.5 2 0.5 myritol ^® PC 5 myritol ^® 331 12 12 8th 8th 10 8th Finsolv ^® TN 5 3 3 Cetiol ^® CC 10 2 10 6 10 9 7 8th 2 1 3 Cetiol ^® OE 2 2 Dow Corning DC ^® 244 2 1 Dow Corning DC ^® 2502 1 1 Ceraphyl ^® 45 2 2 Silicone oil Wacker AK ^® 350 1 Cetiol ^® 868 2 Cetiol ^® J 600 2 Cetiol ^® B 4 4 4 eutanol ^® G 3 5 3 eutanol ^® G 16 p 10 Cetiol ^® PGL 5 2 Photonyl ^® LS 2 panthenol 1 bisabolol 0.2 Tocopherol / tocopheryl acetate 1 Neo Heliopan ^® Hydro (Na salt) 3 Neo Heliopan AP (Na salt) 2 2 2 1 Eusolex ^® OCR 6 9 5 7 9 4 7 Neo Heliopan ^® BB 1 1 1 Neo Heliopan ^® MBC 2 1 3 1 3 Neo Heliopan ^® OS 2 7 Neo Heliopan ^® E1000 4 5 Neo Heliopan ^® AV 4 7.5 5 5 4 7.5 Uvinul ^® T 150 1 1.3 1 1 Parsol ^® 1789 1 2 1 Z-Cote ^® HP 1 7 2 5 7 5 6 2 Eusolex ^® T 2000 5 2 10 10 2 Veegum ^® Ultra 1.5 1.5 1.5 1.2 1 Keltrol ^® T 0.5 0.5 0.5 0.4 0.5 Pemulen ^® TR 2 0.3 0.3 0.1 0.2 0.3 ethanol 5 8th butylene 1 3 3 8th 1 glycerin 2 4 3 3 3 3 3 5 3 Water / preservative / NaOH ad 100 / qs / qs Table 3: W / O sunscreen emulsions component 23 24 25 26 27 28 29 30 31 32 33 L = lotion; C = cream C L C L C L L L L C C Dehymuls® ^® PGPH 4 2 1 3 3 1 1 2 2 4 1 Monomuls® ^® 90-O18 2 Lame form ^® TGI 2 4 3 1 3 Abil ^® EM 90 4 Glucate ^® DO 3 Isolani ^® PDI 4 2 Arlacel ^® 83 2 Elfacos ^® ST9 2 Elfacos ^® ST37 Arlacel ^® P 135 2 Dehymuls® ^® HRE 7 zinc stearate 1 1 1 1 1 beeswax 1 2 1 1 3 2 3 Tego ^® Care CG 1 .5 Prisorine ^® 3505 1 1 1 1 1 1 Wool wax alcohol, anhydrous, USP 1 Antaron V 216 2 myritol ^® PC 3 4 myritol ^® 331 10 3 6 8th Finsolv ^® TN 5 5 Cetiol ^® CC 15 26 2 1 10 4 2 6 5 12 6 Cetiol ^® OE 4 5 4 2 Dow Corning DC ^® 244 2 Dow Corning DC ^® 2502 1 2 Prisorine ^® 3758 2 Silicone oil Wacker AK ^® 350 4 3 Cetiol ^® 868 2 eutanol ^® G 16 3 eutanol ^® G 16S Cetiol ^® J 600 4 2 Continued Table 3: W / O sunscreen emulsions component 23 24 25 26 27 28 29 30 31 32 33 Ceraphyl ^® 45 2 2 6 Cetiol ^® B 2 4 3 eutanol ^® G 3 2 8th Cetiol ^® PGL 11 2 4 9 almond oil 1 5 Photonyl ^® LS 2 1 4 panthenol 1.0 0.2 1.0 bisabolol Tocopherol / tocopheryl acetate Magnesium sulfate × 7 water 1 Neo Heliopan ^® Hydro (Na salt) 2 3 2 Neo Heliopan AP (Na salt) 2 1 2 1 2 1 Neo Heliopan ^® 303 4 6 Neo Heliopan ^® BB 4 2 2 Neo Heliopan ^® MBC 4 3 Neo Heliopan ^® OS Neo Heliopan ^® E 1000 5 Neo Heliopan ^® AV 3 6 6 7.5 7.5 5 7.5 Uvinul ^® T 150 2.5 1 2 Parsol ^® 1789 2 1 2 Zinc oxide NDM 6 Eusolex ^® T 2000 15 10 5 4 4 ethanol 8th butylene 2 6 2 5 2 glycerin 5 3 3 5 3 2 10 4 Water, preservative ad 100, qs Table 4: W / O sunscreen emulsions component 34 35 36 37 38 39 40 41 42 43 44 L = lotion; C = cream L C L L C L L L L C C Dehymuls® ^® PGPH 3 1 5 1 1 3 2 4 0.5 1 4 Monomuls® ^® 90-O18 1 Lame form ^® TGI 4 1 3 1 Abil ^® EM 90 1 2 Glucate ^® DO 3 2 Isolani ^® PDI 3 4 Arlacel ^® 83 3 Elfacos ^® ST9 2 Elfacos ^® ST37 2 Arlacel ^® P 135 3 Dehymuls® ^® HRE 7 4 zinc stearate 2 2 1 1 1 1 beeswax 1 2 2 3 2 1 1 Tego ^® Care CG isostearic 1 1 1 1 1 1 Wool wax alcohol, anhydrous Antaron V 220 0.5 2 1 1 1 myritol ^® PC myritol ^® 331 4 2 3 5 8th 5 4 Finsolv ^® TN 5 5 7 Cetiol ^® CC 5 5 3 3 2 2 4 19 3 1 16 Cetiol ^® OE 3 2 3 Dow Corning DC ^® 244 4 2 Dow Corning DC ^® 2502 1 Prisorine ^® 3578 1 Silicone oil Wacker AK ^® 350 1 Cetiol ^® 868 eutanol ^® G 16 3 eutanol ^® G 16S 7 Cetiol ^® J 600 3 Continued Table 4: W / O sunscreen emulsions component 34 35 36 37 38 39 40 41 42 43 44 Ceraphyl ^® 45 1 5 4 Cetiol ^® B 3 3 2 2 eutanol ^® G 2 4 5 Cetiol ^® PGL 5 2 almond oil 2 Photonyl ^® LS 3 2 panthenol 1.0 bisabolol 0.2 Tocopherol / tocopheryl acetate 1.0 Magnesium sulfate × 7 water 1 Neo Heliopan ^® Hydro (Na salt) 4 4 Neo Heliopan AP (Na salt) 2 1 2 1 Neo Heliopan ^® 303 6 2 6 Neo Heliopan ^® BB 2 2 2 Neo Heliopan ^® MBC 2 3 4 2 Neo Heliopan ^® OS 10 8th Neo Heliopan ^® E 1000 5 6 5 Neo Heliopan ^® AV 5 5 7.5 5 Uvinul ^® T 150 1 2 2 3 2 Parsol ^® 1789 1 1 1 0.5 Z-Cote ^® HP 1 4 10 5 5 Titanium dioxide T 805 2 3 7 4 7 ethanol 8th 10 butylene 5 1 3 3 8th 2 glycerin 6 2 5 5 3 5 Water, preservative ad 100, qs Table 5: W / O care emulsions component 45 46 47 48 49 50 51 52 53 54 55 L = lotion. C = cream C L C L C L L L C C C Dehymuls® ^® PGPH 1 3 1 2 3 1 1 2 1 1 1 Monomuls® ^® 90-O18 2 2 2 Lame form ^® TGI 4 1 3 1 4 3 3 Abil ^® EM 90 4 Isolani ^® PDI 4 Glucate ^® DO 5 Arlacel ^® 83 5 Dehymuls® ^® FCE Dehymuls® ^® HRE 7 4 1 zinc stearate 2 1 1 1 1 1 1 beeswax 2 3 1 1 1 3 2 1 Tego Care ^® CG 1 0.5 Prisorine ^® 3505 1 1 1 1 1 Dry flo ^® plus SFE 839 3 Lanolin; anhydrous USP 5 4 Cegesoft ^® C 17 3 1 myritol ^® PC 2 4 myritol ^® 331 6 2 6 2 Finsolv ^® TN 5 2 5 Cetiol ^® A 6 4 Cetiol ^® CC 3 12 2 12 12 4 4 6 3 12 6 Cetiol ^® SN 5 3 Cetiol ^® OE 3 4 2 4 2 8th Dow Corning DC ^® 244 1 2 Dow Corning DC ^® 2502 1 2 Prisorine ^® 3758 3 Silicone oil Wacker AK ^® 350 4 3 Continuation Table 5: W / O care emulsions component 45 46 47 48 49 50 51 52 53 54 55 Cetiol ^® 868 2 Cetiol ^® J 600 4 2 Ceraphyl ^® 45 2 2 6 Cetiol ^® B 2 4 3 eutanol ^® G 16 1 1 3 7 eutanol ^® G 3 1 8th Cetiol ^® PGL 4 9 almond oil 3 5 Insect Repellent ^® 3535 2 N, N-diethyl-m-toluamide 3 5 Photonyl ^® LS 2 2 panthenol 1.0 bisabolol 0.2 Tocopherol / tocopheryl acetates 1.0 Magnesium sulfate × 7 water 1 Bentone ^® 38 1 Aluminum chlorohydrate 8th propylene carbonate 0.5 ethanol 8th Butylene glycol 2 6 2 5 2 glycerin 5 3 3 5 3 2 10 4 Water, preservative ad 100, qs Table 6: W / O care emulsions component 56 57 58 59 60 61 62 63 64 65 66 L = lotion. C = cream L C L L C L L L L C C Dehymuls® ^® PGPH 3 1 5 1 1 3 3 4 1 1 1 Monomuls® ^® 90-O18 1 1 Lame form ^® TGI 4 1 3 Abil ^® EM 90 3 2 Isolani ^® PDI 3 4 Glucate ^® DO 1 Arlacel ^® 83 3 Dehymuls® ^® FCE 4 1 Dehymuls® ^® HRE 7 7 zinc stearate 2 2 1 1 1 1 1 1 beeswax 4 2 1 2 2 1 2 3 5 Tego ^® Care CG Prisorine ^® 3505 1 1 1 1 1 1 Dry flo ^® plus 1 SFE ^® 839 5 4 Emery ^® 1780 Lanolin anhydrous USP 7 3 Cegesoft ^® C 17 2 myritol ^® PC 8th myritol ^® 331 4 3 5 3 5 4 Finsolv ^® TN 5 7 Cetiol ^® A 6 Cetiol ^® CC 6 4 4 14 10 5 11 6 3 20 7 Cetiol ^® SN 5 Cetiol ^® OE 3 2 3 8th Dow Corning ^® DC 244 4 2 2 Dow Corning ^® DC 2502 1 Prisorine ^® 3758 1 Silicone oil Wacker AK ^® 350 1 1 4 Cetiol ^® 868 10 Cetiol ^® J 600 4 3 Ceraphyl ^® 45 1 5 4 Cetiol ^® B 3 3 2 2 eutanol ^® G 16 1 3 eutanol ^® G 2 2 5 Cetiol ^® PGL 10 4 6 3 almond oil 2 5 2 Photonyl ^® LS 2 2 panthenol 1.0 bisabolol 0.2 Tocopherol / tocopheryl acetate 1.0 Magnesium sulfate × 7 water 1 Bentone ^® 38 1 propylene carbonate 0.5 ethanol 8th 10 butylene 5 1 3 3 8th 2 1 glycerin 6 2 5 5 3 5 Water, preservative ad 100, qs Table 7: O / W care emulsions component 67 68 69 70 71 72 73 74 75 76 77 L = lotion, C = cream C C C L C L L C L C C Eumulgin ^® VL 75 4 Dehymuls® ^® PGPH 2 GenerolTM ^® R 1 Eumulgin ^® B2 0.8 Tween ^® 60 1 Cutina ^® E 24 0.6 2 Hostaphat ^® KL 340 N 2 Lanette ^® e 1 Amphisol® ^® K 0.5 1 1 0.5 sodium 0.5 Emulgade® ^® PL 68/50 2.5 4 Tego ^® Care CG 2 Tego ^® Care 450 5 Cutina ^® MD 1 6 5 4 6 Lanette ^® 14 1 2 4 Lanette ^® O 4.5 4 1 2 2 novata ^® FROM 1 1 Lanolin, anhydrous, USP 5 Cetiol ^® SB 45 1.5 2 Cegesoft ^® C 17 myritol ^® PC 5 myritol ^® 331 2 5 6 12 Finsolv ^® TN 2 8th Cetiol ^® CC 7 10 2 1 10 6 6 6 3 12 6 Cetiol ^® OE 7 4 3 Dow Corning DC ^® 245 2 5 1 Dow Corning DC ^® 2502 2 1 Prisorine ^® 3758 1 Silicone oil Wacker AK ^® 350 0.5 0.5 0.5 1 4 Cetiol ^® 868 2 4 Cetiol ^® J 600 2 3 3 2 5 Continued Table 7: O / W Care Emulsions component 67 68 69 70 71 72 73 74 75 76 77 Ceraphyl ^® 45 3 Cetiol ^® SN 5 Cetiol ^® B 2 eutanol ^® G 2 5 Cetiol ^® PGL 7 5 5 Dry flo ^® plus 5 1 SFE 839 5 2 almond oil 1 Insect Repellent ^® 3535 2 4 2 3 N, N-diethyl-m-toluamide 2 3 Photonyl ^® LS 2 2 2 panthenol 1 bisabolol 0.2 Tocopherol / tocopheryl acetate 1 Veegum ^® ultra 1 Keltrol ^® T 0.4 0.5 Pemulen ^® TR 2 0.3 0.3 Carbopol ^® Ultrez 10 0.3 0.2 0.2 0.1 0.3 Cosmedia SP 0.3 0.2 0.2 Aluminum Chlorohydrate 7 ethanol 10 butylene 4 3 2 5 2 glycerin 2 5 5 3 3 2 4 3 Water, preservative, NaOH ad 100, qs, pH 6.5-7.5 Table 8: O / W care emulsions component 78 79 80 81 82 83 84 85 86 87 88 L = lotion, C = cream C C L C L C L L L L C Eumulgin ^® VL 75 4 3 1 2 GenerolTM ^® R 2 Eumulgin ^® B2 2 1 Tween ^® 60 1 Cutina ^® E 24 2 Hostaphat ^® KL 340 N Lanette ^® e 0.5 1 Amphisol® ^® K 0.5 1 1 1 sodium 1 Emulgade® ^® PL 68/50 6 5 4 Tego ^® Care CG Tego ^® Care 450 4 Cutina ^® MD 3 3 8th 6 8th 4 Lanette ^® 14 2 2 1 Lanette ^® O 2 2 3 1 1 1 6 novata ^® FROM Lanolin, anhydrous, USP 4 Cetiol ^® SB 45 2 Cegesoft ^® C 17 4 myritol ^® PC 6 5 5 myritol ^® 331 5 5 7 10 3 Finsolv ^® TN 5 5 3 3 1 Cetiol ^® CC 3 4 2 1 10 2 2 6 3 12 3 Cetiol ^® OE 2 2 5 Dow Corning DC ^® 245 2 1 8th 2 Dow Corning DC ^® 2502 1 1 3 Continuation Table 8: O / W care emulsions component 78 79 80 81 82 83 84 85 86 87 88 Prisorine ^® 3758 3 2 Silicone oil Wacker AK ^® 350 1 1 Cetiol ^® 868 2 Cetiol ^® J 600 2 Ceraphyl ^® 45 3 Cetiol ^® SN Cetiol ^® B 5 5 4 3 eutanol ^® G 3 5 5 Cetiol ^® PGL 5 2 Dry flo ^® plus 1 1 SFE 839 1 1 almond oil 2 Photonyl ^® LS 2 panthenol 1 bisabolol 0.2 Tocopherol / tocopheryl acetate 1 Veegum ^® Ultra 1 Keltrol ^® T 0.5 Carbopol ^® ETD 2001 0.3 0.3 0.5 0.2 0.2 Pemulen ^® TR 2 0.3 0.3 0.5 ethanol 5 8th 10 butylene 5 2 3 3 8th glycerin 2 4 3 3 7 5 3 5 Water, preservative, NaOH ad 100, qs (pH 6.5-7.5) Table 9: Spray formulations component 89 90 91 92 93 94 95 96 97 98 99 S = body spray, S * = sunscreen spray S S S S S S * S * S * S * S * S * Emulgade® ^® SE-PF 8.9 7.5 7.5 4.3 9.8 8.2 9.9 Eumulgin ^® B2 3.1 3 4.2 Eumulgin ^® B3 4.2 3.3 Eumulgin ^® HRE 40 4.7 Cutina ^® E 24 5.9 4 Amphisol® ^® K 1 1 1 Eumulgin ^® VL 75 2 Emulgade® ^® PL 68/50 0.5 2.5 1 Cutina ^® MD 3.1 Antaron V 220 1 1 1 1 1 myritol ^® PC myritol ^® 331 3 4 3 3 3 3 Finsolv ^® TN 4 8th Cetiol ^® CC 17 5 7 12 12 7 6 9 5 4 6 Cetiol ^® OE 5 7 2 Dow Corning DC ^® 244 4 4 5 Cetiol ^® 868 3 Cetiol ^® J 600 2 2 Cetiol ^® B 2 eutanol ^® G 2 1 Photonyl ^® LS 2 2 2 2 panthenol 1 bisabolol 0.2 Tocopherol / tocopheryl acetate 1 Neo Heliopan ^® Hydro (Na salt) 2 3 Neo Heliopan AP (Na salt) 2 2 2 1 Eusolex ^® OCR 2 3 Neo Heliopan ^® BB 1 Neo Heliopan ^® MBC 2 2 2 1 1 Neo Heliopan ^® OS 5 Neo Heliopan ^® AV 6 6 2 7.5 2 Uvinul ^® T 150 1 1 1 1 Parsol ^® 1789 1 1 1 Z-Cote ^® HP 1 2 2 Eusolex ^® T 2000 2 2 Veegum ^® Ultra 1.5 Laponite ^® XLG 1.5 Keltrol ^® T 0.5 Pemulen ^® TR 2 0.2 Insect Repellent ^® 3535 1 N, N-diethyl-m-toluamide 1 ethanol butylene 1 2 1 glycerin 3 2 3 2 3 Water / preservative / NaOH ad 100 / qs / qs Table 10A: Antiperspirant suspension sticks and soft solids - Quantities in% by weight - composition 1 2 3 4 5 6 distearylether - 15 - - - - stearyl - - 15 10 14.7 - Guerbet Alcohol C36 15 - - - - - Tribehenin - - - - - 20 Hydrogenated Castor Oil - - 4 - 3.7 - CETIOL ^® CC 30 60 51 60 31.6 55 octyldodecanol 5 - - - - - dicaprylyl 5 - - - - - Hexyldecanol + hexyldecyl laurate - 10 - - - - Cyclomethicone 20 - - - 30 - Dry Flo Plus * - - 5 - - - silica - - - 2.5 - - Talc - - - 2.5 - - Aluminum zirconium tetrachlorohydrex GLY - - 25 25 - 25 Aluminum Chlorohydrate 25 15 - - 20 -

• * National Starch

Table 10B: Antiperspirant suspension sticks and soft solids - Quantities in% by weight - composition 7 8th 12-hydroxystearic acid 10 5 CETIOL ^® CC 65 65 Dry Flo Plus * - 5 Aluminum zirconium tetrachlorohydrex GLY 25 25

• * National Starch

Table 11: Recipes 1 to 13 Components INCI (trade name) 1 2 3 4 5 6 7 8th 9 10 11 12 13 Glyceryl Stearate, Ceteareth-20, Ceteareth-12, Cetearyl Alcohol, Cetyl Palamitate (Emulgade ^® SE) 10.7 5.1 Ceteareth-20 (Eumulgin ^® B2) 5.8 3.4 Cetearyl Glucoside, Cetearyl Alcohol (Emulgade ^® PL 68/50) 1 1 1 2 2 2 2 Polyglyceryl-2 dipolyhydroxystearates, lauryl glucosides, glycerin (Eumulgin ^® VL 75) 1 1 3 2.5 Sodium Cetearyl Sulfate (Lanette ^® e) 1 1 1 1 1 1 Dicaprylyl carbonates (Cetiol ^® CC) 10 9 13 3 5 8th 4 6 4 8th 8th 14 2 Cocoglycerides (Myritol ^® 331) 3 4 4 4 5 3 3 Dicaprylyl ether (Cetiol ^® OE) 5 3 2 Dibutyl adipate (Cetiol ^® B) 4 4 4 Hydrogenated dimer dilinoleyl / dimethyl carbonate copolymer (Cosmedia ^® DC) 1 1 1 1 1 1.5 1.5 2 3 2 1.5 2 2 Ethyl butylacetylaminopropionate 5 5 tocopherol 1 1 1 1 1 1 1 1 1 1 1 1 1 Zinc oxide, nanonized, coated 5 5 5 5 5 2 5 3 Titanium dioxide, nanonized, coated 5 5 2 3 5 2 Ethyl hexyl methoxycinnamate 7.5 7.5 7.5 3 1 3 5 5 5 Octocrylene 9 9 9 2 1 2 1.5 Butyl methoxydibenzoylmethane 2 2 1 2 2 4-methylbenzylidene camphor 2 2 Ethylhexyl triazone 1 1 2 1 Diethylhexyl butamido triazone 1 1 2 1 2 Phenylbenzimidazolesulphonic 13.3 Sulfonic acid as Na salt, 15% aqueous sol. glycerin 3 3 3 3 3 3 3 3 3 3 3 5 5 Magnesium aluminum silicate (and) cellulose Gum 0.75 0.75 0.5 0.5 0.5 12:35 Xanthan gum 12:25 12:25 0.5 0.5 0.5 12:35 Sodium polyacrylate (Cosmedia ^® SP) 0.1 0.1 0.2 0.1 Acrylates / C10-30 Alkyl Acrylate Crosspolymer 0.2 0.1 Water, Perfume, Preservatives qs qs qs qs qs qs qs qs qs qs qs qs qs Table 12: Formulations 14 to 26 Components INCI (trade name) 14 15 16 17 18 19 20 21 22 23 24 25 26 Glyceryl Stearate, Ceteareth-20, Ceteareth-12, Cetearyl Alcohol, Cetyl Palmitate (Emulgade ^® SE) 3.7 3.7 4.9 4.1 Ceteareth-12 (Eumulgin ^® B1) 1.3 1.3 Ceteareth-20 (Eumulgin ^® B2) 1.1 0.9 Cetearyl Glucoside, Cetearyl Alcohol (Emulgade ^® PL 68/50) 5 1 1 1 1 3 Polyglyceryl-2 dipolyhydroxystearates, lauryl glucosides, glycerin (Eumulgin ^® VL 75) 3 5 5 Sodium Cetearyl Sulfate (Lanette ^® e) 12:25 12:25 12:25 12:25 12:25 Potassium Cetyl Phosphate 0.5 Dicaprylyl carbonates (Cetiol ^® CC) 9 5 11 8th 5 8th 8th 10 9.5 8th 14 10 10 Coco-Caprylate / Caprate (Cetiol ^® LC) 1 1 1 1 1 Caprylic / Capric triglycerides (Myritol ^® 312) 1 1 1 1 1 Cocoglycerides (Myritol ^® 331) 4 4 Cetearyl Isononanoate (Cetiol ^® SN) 3 3 3.5 Octyldodecanol (Eutanol ^® G) 3.5 2 2 Hexyldecanol (Eutanol ^® G16) 1 1 1 1 1 Olus (Cegesoft ^® PS6) 1.5 1.5 Passiflora Incarnata (Cegesoft ^® PFO) 1.5 Dimethicone 0.5 0.5 0.5 0.5 0.5 Dimer distearyl tricarbonate (Cosmedia ^® DC) 1 1.5 1.5 2.5 2.5 0.5 Triethyl Citrate (Hydages ^® CAT) 1.5 tocopherol 0.5 0.5 0.5 Tocopheryl acetate 0.5 0.5 ethanol 5 Aluminum Chlorhydrates (Locron L) 40 Chitosan (Hydagen ^® DCMF) 0.1 Glycolic Acid 12:04 glycerin 2 2 2 3 3 3 3 3 2 2 2 3 2 Potassium hydroxides, 20% aqueous sol. 0.3 0.2 0.1 0.4 0.3 0.5 Glycerin, Glyceryl Polyacrylates (Hispagel ^® 50) 10 Carbomer 0.1 0.2 0.2 Sodium polyacrylate (Cosmedia ^® SP) 12:15 Acrylates / C10-30 Alkyl Acrylate Crosspolymer 12:15 12:05 Water, Perfume, Preservatives qs qs qs qs qs qs qs qs qs qs qs qs Table 13: Formulations 27 to 33 (formulations for AP / Deo) Components INCI (trade name) 27 28 29 30 31 32 33 Glyceryl Stearate, Ceteareth-20, Ceteareth-12, Cetearyl Alcohol, Cetyl Palmitate (Emulgade ^® SE) 6 4.5 6 Ceteareth-20 (Eumulgin ^® B2) 1 Cetearyl Isononanoate, Glyceryl Stearate, Ceteareth-20, Ceteareth-12, Cetearyl Alcohol, Cetyl Palmitate (Emulgade ^® CM) 20 Polyglyceryl-3 diisostearate Lameform TGI 3 Cocoglycerides (Novata ^® FROM) 4 Stearyl alcohol (Lanette 18) 14.7 Hydrogenated Castor Oil (Cutina ^® MR) 3.7 6.5 Polyglyceryl-2 dipolyhydroxystearates, (Dehymuls ^® PGPH) 1 Sodium Cetearyl Sulfate (Lanette ^® e) 0.3 0.3 Behenyl Alcohol (Lanette ^® 22) 2 4 Dicaprylyl carbonates (Cetiol ^® CC) 4 7 5 5 4 4 15 Dicaprylyl ether (Cetiol ^® OE) 2 4 3 9 Cocoglycerides (Myritol ^® 331) Cyclopentasiloxane 3 5 34 2 14 Cyclopentasiloxane and Dimethicone / Vinyldimethicone Crosspolymer SFE 839 (GE Bayer) 3 Dimethicone 1 Dimer distearyl tricarbonate (Cosmedia ^® DC) 1 1 1 1 1 1 1 Triethyl Citrate (Hydages ^® CAT) 2 PEG-40 Hydrogenated Castor Oil 1 Tocopheryl acetate 1 Aluminum Zirconium Tetrachlorohydrex GLY (Rezal 36) 30 40 22.9 30 25 Aluminum Chlorhydrates (Locron L) 10 Chitosan (Hydagen ^® DCMF) 0.05 Glycolic Acid 0.02 glycerin 5 5 Propylene Carbonates (Fluka) 0.5 Quaternium-18 hectorite (Bentone 18) 1 Talc (Merck) 5 5 MgSO4 × 7H2O 1 Water phase II 46.7 35 Water, Perfume, Preservatives qs qs qs qs qs qs qs

• 27 - Antiperspirant / Deodorant Cream / 28 - Antiperspirant Cream (W / O) / 29 - Antiperspirant / Deodorant Spray 30 - Antiperspirant Pen with Vitamin E / 31 - Deodorant Wipe - Formulation / 32 - Antiperspirant Cream 33 - Antiperspirant Cream «Soft Solid»

Table 14 describes sunscreen formulations of the O / W type; Table 15 describes care emulsions. The use of the dialkyl carbonates according to the invention has a positive influence on the sensory behavior during administration. The quantities are in each case based on% by weight of the commercial substances in the overall composition. Table 14: O / W sunscreen emulsions component 12 13 14 15 16 17 18 19 20 21 22 L = lotion, C = cream, S = spray L C L C L C S C C L L Eumulgin ^® VL 75 2 3 1 Eumulgin ^® B2 2 1 Tween ^® 60 1 Cutina ^® E 24 0.5 Hostaphat ^® KL 340 N 0.5 Eumulgin ^® SG 0.5 0.5 0.3 0.1 Lanette ^® E 0.1 0.5 Amphisol ^® K 0.5 1 sodium 1 Emulgade® ^® PL 68/50 2 1 3 Tego ^® Care 450 2 2 Cutina ^® MD 2 1 3 1 Lanette ^® 14 1 Lanette ^® O 2 2 1 1 Cutina ^® PES 1 1 2 1 Allianz ^® OPT 1 1 1 2 2 Cosmedia ^® DC 1.5 2 1.5 2 1.5 1.5 Lanolin, anhydrous, USP 1 1 Myritol ^® PC 5 Myritol ^® 331 6 4 5 8th 10 8th Finsolv ^® TN 5 3 3 Cetiol ^® CC 12 2 10 7 3 12 11 6 4 4 5 Cetiol ^® OE 2 2 Dow Corning ^DC® 244 2 1 Dow Corning ^DC® 2502 1 1 3 Ceraphyl ^® 45 2 2 Silicone oil Wacker AK ^® 350 1 Cetiol ^® 868 2 Cetiol ^® J 600 2 Cetiol ^® B 4 4 4 Eutanol ^® G 3 3 Eutanol ^® G 16 S 3 Cetiol ^® PGL 1 1 2 Photonyl ^® LS 2 panthenol 1 bisabolol 0.2 Tocopherol / tocopheryl acetate 1 Neo Heliopan Hydro ^® (Na salt) 3 Eusolex ^® OCR 6 9 5 7 9 4 7 Neo Heliopan ^® AP (Na salt) 0.5 1 Neo Heliopan ^® BB 1 1 1 Neo Heliopan ^® MBC 2 1 3 1 3 Neo Heliopan ^® OS 2 7 Neo Heliopan ^® E1000 4 5 Neo Heliopan ^® AV 4 7.5 5 5 4 7.5 Uvinul ^® A PLUS 1 2 Uvinul ^® T 150 1 1.3 1 1 Tinosorb ^® M 2 2 2 Tinosorb ^® S 1 2 2 Parsol ^® 1789 1 2 1 Z- ^Cote® HP 1 7 2 5 7 5 6 2 Eusolex ^® T 2000 5 2 10 10 2 Veegum ^® Ultra 1.5 1.5 1.5 1.2 1 Keltrol ^® T 0.5 0.5 0.5 0.4 0.5 Cosmedia ^® SP 0.2 0.3 0.1 0.2 Pemulen ^® TR 2 0.3 0.3 0.2 0.3 ethanol 5 8th butylene 1 3 3 8th 1 glycerin 2 4 3 3 3 3 3 5 3 Water / preservative / NaOH ad 100 / qs / qs Table 15: O / W care emulsions component 34 35 36 37 38 39 40 41 42 43 44 L = lotion, C = cream C C L C L C L L L L C Eumulgin ^® VL 75 5 4 2 Generol ^® R 2 Eumulgin ^® B2 1 Tween ^® 60 1 Cutina ^® E 24 0.5 Eumulgin ^® SG 0.1 0.5 0.4 0.2 0.1 Lanette ^® E 0.5 Amphisol ^® K 0.5 0.5 sodium 1 Emulgade® ^® PL 68/50 2 2 3 4 Tego ^® Care 450 1 1 Cutina ^® MD 2 1 1 1 5 2 Lanette ^® 14 1 2 1 Lanette ^® O 2 2 1 3 1 1 1 3 Cutina ^® PES 1 2 3 1 3 Novata ^® AB 1 1 Lanolin, anhydrous, USP 4 Cosmedia ^® DC 2 1.5 1 1 Cetiol ^® SB 45 2 Cegesoft ^® C 17 2 Myritol ^® PC 6 5 Myritol ^® 331 2 5 2 3 Finsolv ^® TN 3 5 3 3 1 Cetiol ^® CC 5 5 4 7 3 4 9 7 5 10 2 Cetiol ^® OE 2 2 5 Dow Corning ^DC® 245 2 1 4 8th 2 Dow Corning ^DC® 2502 1 1 3 Prisorine ^® 3758 3 2 Silicone oil Wacker AK ^® 350 1 1 Cetiol ^® 868 2 Cetiol ^® J 600 2 2 Ceraphyl ^® 45 3 Cetiol ^® SN 5 Cetiol ^® B 5 5 4 3 Eutanol ^® G 3 5 5 Cetiol ^® PGL 5 2 Dry Flo ^® Plus 1 1 SFE 839 1 1 almond oil 2 Photonyl ^® LS 2 panthenol 1 bisabolol 0.2 Tocopherol / tocopheryl acetate 1 Veegum ^® Ultra 1 Keltrol ^® T 0.5 Cosmedia ^® SP 0.5 0.5 0.5 0.2 0.5 Carbopol ^® ETD 2001 0.3 0.3 Pemulen ^® TR 2 0.3 0.3 ethanol 5 8th 10 butylene 5 2 3 3 8th glycerin 2 4 3 3 7 5 3 5 Water, preservative, NaOH ad 100, qs (pH 6.5-7.5)

• Ratio propellant/other (3.34:1); Valve: RK 150P RA 634/5/8 (Vapor Phase); Button: V04.776

Rich Hair conditioner/Haar Conditioner Phase Handelsname INCI Bezeichnung Gew.-% I. Dehyquart^®L80 Dicocoylethyl Hydroxyethylmonium Methosulfat (und) Propylene Glycol 2 Lanette^®O Cetearyl Alcohol 5 Cutina^®GMS Glyceryl Stearate 1 CETIOL^® CC 0,3 Cetiol^®J 600 Oleyl Erucate 0,5 Plantacare^®1200 UP Lauryl Glucoside 2 II. Glycerol 2 Wasser, entionisiert 50 III. Hydroxyethylcellulose Hydroxyethylcellulose 0,4 Wasser, deionisiert Ad 100 IV. Aloe vera Gel 0,1 Konservierungsmittel q.s. Parfum q.s. >> pH Wert 4–4,5 >> Viskosität mPas Ca. 8000 Water-in-Oil Formulations for Sunscreen and Skin Care In Table 16, W / O emulsion type sunscreen formulations are described; in Table 17, care emulsions are described. The use of dialkyl carbonates positively influences the sensory behavior during application. The quantities are in each case based on% by weight of the commercial substances in the overall composition. Table 16: W / O sunscreen formulations Ingredient 1 2 3 4 5 6 7 8th 9 10 11 L = lotion; C = cream C L C L C L L L L C C Dehymuls® ^® PGPH 4 2 1 3 3 1 1 2 2 4 1 Monomuls ^® 90-O18 2 Lame form TGI ^® 2 4 3 1 3 Abil ^® EM 90 4 Isolani ^® PDI 4 2 zinc stearate 1 1 1 1 1 beeswax 1 5 1 5 7 5 Tego ^® Care CG 1 0.5 Prisorine ^® 3505 1 1 1 1 Cosmedia DC 3 4 2 1 1 2 2 2 3 1 1 Myritol ^® 331 2 3 6 3 Finsolv ^® TN 5 2 Cetiol ^® CC 10 4 6 3 6 6 3 4 4 6 10 Tegosoft DEC 4 3 5 5 Cetiol ^® OE 4 5 4 2 Dow ^Corning® DC 244 3 2 2 4 Dow ^Corning® DC 2502 1 1 2 1 1 Silicone oil Wacker AK 350 1 4 3 Cetiol ^® PGL 3 2 4 Cophero ^® F 1300 1 Magnesium sulfate × 7 H ₂ O 1 Neo Heliopan Hydro ^® (Na salt) 2 2.2 3 3 1 2 Neo Heliopan ^® 303 5 4 4 Uvasorb ^® HEB 1 1 1 2 Neo Heliopan ^® MBC 2 2 2 2 Uvinul ^® A plus 2 3 3 Neo Heliopan ^® AP (Na salt) 2 2 1 1 6 Neo Heliopan ^® AV 3 4 6 4 7.5 4 5 1 Uvinul ^® T 150 1 1 2.5 1 Parsol ^® 1789 2 1 2 2 2 Zinc oxide NDM 10 3 4 Tinosorb ^® M 3 3 2 2 Tinosorb ^® S 3 3 2 2 Eusolex ^® T Aqua 8th 5 Eusolex ^® T 2000 5 3 3 4 ethanol 8th glycerin 5 3 3 3 5 3 2 3 10 4 3 Water, preservative ad 100, qs Table 17: W / O care emulsions component 55 56 57 58 59 60 61 62 63 64 65 L = lotion. C = cream C L C L C L L L C C C Dehymuls® ^® PGPH 1 3 1 2 3 1 1 2 1 1 1 Monomuls ^® 90-O18 2 2 2 Lame form TGI ^® 4 1 3 1 4 3 3 Abil ^® EM 90 4 Isolani ^® PDI 4 Glucate ^® DO 5 Arlacel ^® 83 5 Dehymuls ^® FCE Dehymuls ^® HRE 7 4 1 zinc stearate 2 1 1 1 1 1 1 beeswax 4 1 1 4 7 Tego ^Care® CG 1 0.5 Prisorine ^® 3505 1 1 1 1 1 Dry Flo ^® Plus SFE 839 3 Lanolin; anhydrous USP 5 4 Cegesoft ^® C 17 3 1 Myritol ^® PC 2 4 Myritol ^® 331 6 2 6 2 8th Finsolv ^® TN 5 2 5 Cetiol ^® A 6 4 Cetiol ^® CC 3 12 2 12 12 4 4 6 3 12 6 Cetiol ^® SN 5 3 Cetiol ^® OE 3 4 2 4 2 Dow Corning ^DC® 244 1 2 Dow Corning ^DC® 2502 1 2 Prisorine ^® 3758 3 Silicone oil Wacker AK ^® 350 4 3 Cetiol ^® 868 2 7 Cetiol ^® J 600 4 2 Ceraphyl ^® 45 2 2 6 Cetiol ^® B 2 4 3 Eutanol ^® G 16 1 3 Eutanol ^® G 3 8th Cetiol ^® PGL 4 9 almond oil 1 5 Insect Repellent ^® 3535 2 N, N-diethyl-m-toluamide 3 5 Photonyl ^® LS 2 2 panthenol 1.0 bisabolol 0.2 Tocopherol / tocopheryl acetates 1.0 Magnesium sulfate × 7 water 1 Bentone ^® 38 1 propylene carbonate 0.5 ethanol 8th Butylene glycol 2 6 2 5 2 glycerin 5 3 3 5 3 2 10 4 Water, preservative Ad 100, qs Table 18 component 1 2 3 4 5 6 7 ethanol 4.00 3.00 4.50 Water that. (add to) 100 100 100 100 100 100 100 Phenonip 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Glycerol 99% 3.00 3.00 3.00 3.00 3.00 3.00 3.00 Ultrogel ^® 300 (Polyquaternium-37) 0.8 1.00 1.50 0.90 2.00 1.50 0.75 Eumulgin ^® VL 75 (Lauryl Glucoside (and) Polyglyceryl-2 Dipolyhydroxystearate (and) Glycerin) 1.80 - 0.80 - - - - Emulgade® ^® PL 68/50 (cetearyl glucosides (and Cetearyl Alcohol) - - - - - 3.00 - Eumulgin ^® SG (Sodium Stearylglutamate) 0.10 0.12 0.30 0.10 - 0.08 Cutina ^® PES (Pentaerythrityl Distearate) 2.50 3.50 1.70 4.00 2.00 4.00 5.00 Cetiol ^® J600 (Oleyl Erucate) 2.00 - 5.00 - - 1.00 3.00 Cetiol ^® CC (Dicaprylyl Carbonate) 6.50 3.00 9.00 6.00 9.50 8.00 7.00 Cetiol ^® PGL (hexyldecanol (and) Hexyldecyl laurate) - 2.00 - 4.00 5.00 5.00 1.00 Tegosoft DEC ^® (Diethylhexyl Carbonate) - - - 2.50 - - 3.00 ^DC® 345 (cyclopentasiloxane) 4.00 - - - 2.00 - - Cetiol ^® B (Dibutyl Adipate) 5.00 3.5 5.00 2.00 Myritol ^® 331 (Cocoglycerides) 3.00 - - - - 4.00 4.50 DHA (dihydroxyacetone) 2.00 1.00 2.50 1.00 2.00 2.00 3.50 Uvinul ^® T 150 (Ethylhexyl Triazone) - 1.00 - - - - Tinosorb ^® M (methylene bis-Benzotriazoyl Tetramethylbutylphenol) - 1.00 1.00 - - - - Tinosorb ^® S (bis-ethylhexyloxyphenol methoxyphenyl triazines) - 2.00 - - 0.50 - - Uvasorb HEB ^® (Diethylhexyl Butamino Triazone) - - - - 1.00 - - Neo Heliopan ^® AV (ethylhexyl methoxycinnamate - 5:00 5.00 - 3.00 - - Parsol ^® 1789 (Butyl methoxydibenzoylmethane) - 3:00 3.00 - 2.00 - - Neo Heliopan 303 ^® (Octocrylene) - 3.50 2.00 - - - - Sprayable W / O emulsion (SPF 20) phase component INCI Wt .-% I Dehymuls ^® LE PEG-30 dipolyhydroxystearates 3:00 DC 245 Cyclopentasiloxane 5:00 Cetiol ^® A Hexyl Laurate 5:00 Cetiol ^® CC Dicaprylyl carbonates 3.0 Cosmedia ^® Gel CC Dicaprylyl Carbonate (and) Stearalkonium Hectorite (and) Propylene Carbonate 4:00 Cetiol ^® Sun Titanium Dioxide Dispersion 8:00 pm II Deionized Water Aqua qs 100 Butylene glycol Butylene glycol 3:00 Ajidew N50 Sodium PCA 2:00 Magnesium sulphates Magnesium sulphates 12:50 EDTA 4 Na Tetrasodium EDTA 12:05 Preservative qs III Perfume qs Viscosity, Brook. RVT, 20 ° C, Sp 4, 5 rpm 2700 mPas Sprayable W / O emulsion (SPF 20) phase component INCI Wt .-% I Dehymuls ^® LE PEG-30 dipolyhydroxystearates 4:00 Dehymuls® ^® PGPH Polyglyceryl-2 dipolyhydroxystearates 4:00 Cetiol ^® 868 Ethylhexyl stearate 7:00 Cetiol ^® CC Dicaprylyl carbonates 5.40 Cosmedia ^® Gel CC Dicaprylyl Carbonate (and) Stearalkonium Hectorite (and) Propylene Carbonate 3:00 Cetiol ^® OE Dicaprylyl ether 5:00 Zincum N 29 Zinc oxides 2:00 II Cetiol ^® Sun Titanium Dioxide Dispersion 8:00 pm III Deionized Water Aqua qs 100.00 glycerin glycerin 5:00 Sodium Chloride Sodium Chloride 12:50 Magnesium sulphates Magnesium sulphates 12:50 Preservative qs IV Perfume qs Viscosity: Brookfield. RVT, 20 ° C, Sp 5, 10 rpm 10400 mPas Sunscreen Spray (SPF 6) phase component INCI Wt .-% I Deionized Water Aqua qs 100 Butylene glycol Butylene glycol 3:00 II Veegum Ultra Magnesium Aluminum Silicate 12:50 Keltrol T. Xanthan gum 12:30 III Eumulgin ^® VL 75 Lauryl Glucoside (and) Polyglyceryl-2-Dipolyhydroxystearate (and) Glycerin 6:00 am Cetiol ^® CC Dicaprylyl carbonates 7.00 Cetiol ^® AB C12-15 alkyl benzoates 7:00 Cetiol ^® Sun Titanium Dioxide Dispersion 10:00 Preservative qs Perfume qs Viscosity: Brook. RVT, 20 ° C, Sp 4, 5 rpm 3500 mPas pH = 6.5 Sun Lotion (SPF 20) component INCI Wt .-% I Myritol ^® 331 Cocoglycerides 2:00 Cetiol ^® SB 45 Shea butter 1:00 Cosmedia Gel CC Dicaprylyl Carbonate (and) Stearalkonium Hectorite 2:00 Uvasorb ^® HEB Dioctyl butamido triazone 3:00 CETIOL ^® CC 2.00 Neo Heliopan ^® AV Ethylhexyl methoxycinnamate 4:00 Neo Heliopan ^® E1000 Isoamyl p-methoxycinnamate 4:00 Neo Heliopan ^® 303 Octocrylene 3:00 Copherol® ^® 1250 C Tocopheryl acetate 12:25 Cosmedia ^® DC Hydrogenated dimer dilinoleyl / dimethyl carbonate copolymer 2:00 II Cetiol ^® Sun Titanium Dioxide Dispersion 6:00 am Satiaxane CX 91 Xanthan gum 0.30 Eumulgin ^® VL75 Lauryl Glucoside (and) Polyglyceryl-2-Dipolyhydroxystearate (and) Glycerin 3.13 III Deionized Water Water 58.22 2 NaEDTA Disodium EDTA 12:10 Liponic EG-1 Glycereth-26 3:00 IV Tinosorb M Methylenebisbenzotriazolyltetramethylbutylphenol 3:00 Water Water 3:00 Preservative qs Perfume qs Viscosity Brook. RVT, 20 ° C, spindle 5, 10 rpm 2560 mPas pH = 6.70 Sun Lotion (SPF 50+) component INCI Wt .-% I Cetiol ^® B Bibutyl Adipate 2:00 Cosmedia ^® DC Hydrogenated dimer dilinoleyl / dimethyl carbonate copolymer 1:00 CETIOL ^® CC 2:00 II Neo Heliopan ^® OS Ethyl hexyl salicylates 3:00 Tinosorb ^® S Bis-ethylhexyloxyphenol Methoxyphenyl triazines 2:50 Neo Heliopan ^® AV Ethylhexyl methoxycinnamate 6:00 am Neo Heliopan ^® 303 Octocrylene 8:00 Neo Heliopan ^® 357 Butyl methoxydibenzoylmethane 2:50 III Cosmedia ^® Gel CC Dicaprylyl Carbonate (and) Stercalcium Hectorite (and) Propylene Carbonate 2:00 IV Emulgade® ^® PL 6850 Cetearyl Glucoside (and) Cetearyl Alcohol 2:50 Eumulgin ^® VL 75 Lauryl Glucoside (and) Polyglyceryl-2-Dipolyhydroxystearate (and) Glycerin 3:00 V Cetiol ^® Sun Titanium Dioxide Dispersion 10:00 VI Deionized Water Aqua qs 100 2 NaEDTA Disodium EDTA 12:10 Preservative qs Liponic EG-1 Glycereth-26 3:00 Keltrol ^® T Xanthan gum 0.60 Veegum Ultra Magnesium Aluminum Silicate 2:00 VII Dry Flo Plus Aluminum Starch Octenylsuccinate 2:00 VIII Tinosorb ^® M Methylene bis-benzotriazolyl tetramethylbutylphenol 5:00 IX Perfume qs Viscosity Brookfield Helipath 20 ° C, TB, 10 rpm 16200 mPas pH = 6.7 Anti-aging sunscreen (SPF 30) component INCI Wt .-% I Myritol ^® 331 Cocoglycerides 2:00 Cetiol ^® B Bibutyl Adipate 3:00 CETIOL ^® CC 2:00 Uvinul A plus Diethylamino hydroxybenzoyl hexyl benzoate 5:00 Uvinul T 150 Ethylhexyl triazone 2:50 Cosmedia ^® Gel CC Dicaprylyl Carbonate (and) Stearalkonium Hectorite 2:00 Cosmedia ^® DC Hydrogenated dimer dilinoleyl / dimethyl carbonate copolymer 2:00 II Cetiol ^® Sun Titanium Dioxide Dispersion 10:00 Satiaxane CX 91 Xanthan gum 12:40 Eumulgin ^® VL75 Lauryl Glucoside (and) Polyglyceryl-2-Dipolyhydroxystearate (and) Glycerin 3:50 III Deionized Water Aqua 49.60 2NaEDTA Disodium EDTA 12:10 glycerin glycerin 3:00 Preservative qs IV Photonyl ^® LS Arginine (and) Disodium Adenosine Triphosphate (and) Mannitol (and) Pyridoxine HCl (and) RNA (and) Histidine HCl (and) Phenylalanine (and) Tyrosine 2:00 Water 12:00 V Copherol® ^® 1250 C Tocopheryl acetate 12:50 Perfume qs Viscosity: Brook. RVT, 20 ° C, spindle 5, 10 rpm 3560 mPas pH = 6.50 Anti wrinkle cream component INCI Wt .-% I Eumulgin ^® BA 25 Beheneth-25 3.30 Lame form TGI ^® Polyglyceryl-3 diisostearate 0.70 Cutina ^® PES Pentaerythrityl distearate 2:00 Cetiol ^® CC Dicaprylyl carbonates 3.30 Cetiol ^® AB C12-C15 alkyl benzoates 5:00 Cetiol ^® LC Coco-caprylate / caprate 3:00 Cetiol ^® Sun Titanium Dioxide Dispersion 6:00 am Phenonip Phenoxyethanol (and) parabens 0.80 II Deionized Water Aqua 61.85 4NaEDTA Tetrasodium EDTA 12:05 glycerin glycerin 3:00 Butylene glycol Butylene glycol 2:00 III Veegum Ultra Magnessium Aluminum Silicate 3:00 Keltrol T. Xanthan gum 12:30 IV Perfume Waterfresh 12:50 Coviox ^® P70 C tocopherol 12:10 V Deionized Water Aqua 1:00 Plantactiv ^® Aesculus escin 12:10 Viscosity, Brookfield, RVT, 20 ° C, spindle 5, 5 rpm 11500 mPas pH = 6.2-6.7 Sunscreen lotion SPF 30 component INCI Wt .-% I Myritol ^® 331 Cocoglycerides 2:00 Cetiol ^® CC Dicaprylyl carbonates 2:00 Cetiol ^® B Bibutyl Adipate 2:00 Neo Heliopan ^® MBC 4-methylbenzilidene camphor 3:50 Neo Heliopan ^® AV Ethylhexyl methoxycinnamate 6:00 am Neo Heliopan ^® E1000 Isoamyl p-methoxycinnamate 6:00 am Neo Heliopan ^® 357 Butyl methoxydibenzoylmethane 1:00 Cosmedia ^® DC Hydrogenated dimer dilinoleyl / dimethyl carbonate copolymer 1:00 II Cetiol ^® Sun Titanium Dioxide Dispersion 14:00 Satiaxane CX 91 Xanthan gum 12:10 Cosmedia ^® SP Sodium polyacrylate 12:40 Eumulgin ^® VL75 Lauryl Glucoside (and) Polyglyceryl-2-Dipolyhydroxystearate (and) Glycerin 3.75 III Deionized Water Aqua qs 100.00 Neo Heliopan ^® Hydro Phenylbenzimidazole sulfonic acid 2:00 Trometamine Trometamine 1.60 Phenonip qs Viscosity: Brookfield, RVT, 20 ° C, spindle 5, 10 rpm 2240 mPas pH = 7.35 Sunscreen SPF 50+ component INCI Wt .-% I Myritol ^® 331 Cocoglycerides 2:00 Cetiol ^® CC Dicaprylyl carbonates 2:00 Cetiol ^® B Bibutyl Adipate 2:00 Neo Heliopan ^® MBC 4-methylbenzilidene camphor 3:50 Neo Heliopan ^® AV Ethylhexyl methoxycinnamate 6:00 am Neo Heliopan ^® E1000 Isoamyl p-methoxycinnamate 6:00 am Neo Heliopan ^® 357 Butyl methoxydibenzoylmethane 1:00 Cosmedia ^® DC Hydrogenated dimer dilinoleyl / dimethyl carbonate copolymer 2:00 Emulgade® ^® PL 6850 Cetearyl Glucoside (and) Cetearyl Alcohol 4:50 Lanette ^® E Sodium Cetearyl Sulfate 1.0 II Cetiol ^® Sun Titanium Dioxide Dispersion 14:00 III Deionized Water Aqua qs 100.00 Neo Heliopan ^® Hydro Phenylbenzimidazole sulfonic acid 2:00 NaOH 50% Sodium hydroxides 0.6 Preservative qs Perfume qs Viscosity: Brookfield, Helipath 20 ° C, TE, 4 rpm, 195,000 mPas pH = 7.5 AP / deodorant in aerosol form (% by weight) component INCI A B IPM Isopropyl myristate 10.8 10.8 Cetiol ^® CC Dicaprylyl carbonates 7:00 7:00 Cosmedia ^® Gel CC Dicaprylyl Carbonate (and) Stearalkonium Hectorite (and) Propylene Carbonate - 2:00 Caprylic capric triglyceride (and) stearalkonium hectorite (and) propylene carbonate 2:00 - Locron® ^® P Aluminum chlorohydrate 3:00 3:00 Hydagen® ^® CAT Triethyl citrate 1:00 1:00 Perfume Perfume 1.20 1.20 Propane 75.00 75.00 Foundation or sunscreen containing titanium dioxide Ingredients INCI name Wt .-% Cetiol ^® CC Dicaprylyl carbonates 94.00 Cosmedia ^® Gel CC Dicaprylyl Carbonate (and) Stearalkonium Hectorite (and) Propylene Carbonate 1:00 Titanium dioxide 5:00 Sunscreen spray SPF 40 (% by weight) Ingredient INCI A B I Eumulgin ^® VL 75 Lauryl Glucoside (and) Polyglyceryl-2 Dipolyhydroxystearate (and) Glycerin 6.0 6.0 Generol ^® R Brassica Campestris (Rapeseed) 1.0 1.0 Cegesoft ^® SH Cosmedia ^® Gel CC Sterols Shorea Stenoptera Dicaprylyl Carbonate (and) Stearalkonium Hectorite (and) Propylene Carbonate 1.0 2.0 1.0 Eusolex 2292 Ethylhexylmethoxycinnamate 7.5 7.5 Tinosorb ^® S Until ethylhexyloxyphenolmethoxyphenyltriazine 2.0 2.0 Cetiol ^® CC Dicaprylyl carbonate 3.0 1.5 Cetiol ^® AB C12-15 alkyl benzoates 4.0 4.0 Cosmedia ^® DC Hydrogenated dimer dilinoleyl / dimethyl carbonate copolymer 1:00 1:00 II Water 61.45 63.45 EDTA 4Na (Prolabo) Tetrasodium EDTA 0.05 12:05 Elestab 50J Chlorphenesin & Methylparaben 0.60 III Cosmedia ^® SP Sodium polyacrylate 12:40 12:40 IV Tinsorb ^® M Methylenebis benzotriazolyl tetramethylbutylphenol 10.0 10.0 Viscosity, Brookfield. RVT, 23 ° C, spindle 2.5 rpm, pH: 6 3500 mPas 700 mPas Spray SPF 40 component INCI A B I Eumulgin ^® VL75 Lauryl Glucoside (and) Polyglyceryl-2 Dipolyhydroxystearate (and) Glycerin 6.0 6.0 Generol ^® Brassica campestris (Rapeseed) sterols 1.0 1.0 Cegesoft ^® SH Shorea Stenoptera 1.0 1.0 Cosmedia ^® Gel CC Dicaprylyl Carbonate (and) Stearalkonium Hectorite (and) Propylene Carbonate 3.0 - Eusolex 2292 Ethylhexylmethoxycinnamate 7.5 7.5 Tinsorb S Bis-ethylhexyloxyphenol methoxyphenyltriazine 2.13 4.74 Cetiol ^® CC Dicaprylyl carbonates 4.0 4.0 Cetiol ^® AB C12-15 alkyl benzoates 4.0 4.0 II Water 62.32 62.71 EDTA 4Na Tetrasodium EDTA 12:05 12:05 Elestab 50J Chlorphenesin & Methylparaben 0.60 0.60 III Cosmedia ^® SP Sodium polyacrylate 12:40 12:40 IV Tinsorb M Methylenebis benzotriazolyl tetramethylbutylphenol 10:00 10:00 Viscosity Book. RVT, 23 ° C, spindle 2.5 rpm, pH: 6 A: 4020 mPas B: 730 mPas Moisturizing sunscreen lotion W / O SPF 20 component INCI A B 1 Dehymuls ^® PEG-30 dipolyhydroxystearates 3:00 3:00 DC 245 Cyclopentasiloxane 5:00 5:00 Cetiol ^® OE Dicaprylyl ether 4:00 4:00 Cetiol ^® A Hexyl Laurate 5:00 5:00 Cetiol ^® CC Dicaprylyl carbonates 3:00 3:00 II Cosmedia ^® Gel CC Dicaprylyl Carbonate (and) Stearalkonium Hectorite (and) Propylene Carbonate 4:00 III Cetiol ^® SUN Titanium dioxide (and) Alumina (and) Dimethicone and) Stearic acid (and) Dicaprylyl Carbonate (and) Polyhydroxystearic acid 8:00 pm 8:00 pm IV Deionized water Aqua 49.55 53.55 Butylene glycol Butylene glycol 3:00 3:00 Ajidew N50 Sodium PCA 2:00 2:00 Mg SO4 Magnesium sulphates 12:50 12:50 EDTA, 4 Na Tetrasodium EDTA 12:05 12:05 Phenonip Phenoxyethanol (and) Parabens 12:50 12:50 V Perfume Solole / L27 8319 / C Floressence 12:40 12:40 Viscosity, Brook. RVT, spindle 4, speed 5 [mPas] 2000 5000 Spray SPF 40 (in% by weight) component INCI A B I Eumulgin ^® VL 75 Lauryl Glucoside (and) Polyglyceryl-2 Dipolyhydroxystearate (and) Glycerin 6.0 6.0 Generol ^® R Brassica campestris (Rapeseed) sterols 1.0 1.0 Cegesoft ^® SH Shorea Stenoptera 1.0 1.0 Cosmedia ^® Gel CC Dicaprylyl Carbonate (and) Stearalkonium Hectorite (and) Propylene Carbonate 2.0 Eusolex 2292 Ethylhexylmethoxycinnamate 7.5 7.5 Tinosorb S Bis-ethylhexyloxyphenol methoxyphenyltriazine 2.0 2.0 Cetiol ^® CC Dicaprylyl carbonate 3.0 3.0 Cetiol ^® AB C12-15 alkyl benzoates 4.0 4.0 Cosmedia ^® DC Hydrogenated dimer dilinoleyl / dimethyl carbonate copolymer 1.0 1:00 II Water 61.45 63.45 EDTA 4Na Tetrasodium EDTA 12:05 12:05 Elestab 50J Chlorphenesin & Methylparaben 0.60 0.60 III Cosmedia ^® SP Sodium polyacrylate 12:40 12:40 IV Tinosorb M Methylenebis benzotriazolyl tetramethylbutylphenol 10.0 10.0 Viscosity, Brook. RVT, 23 ° C, spindle 2, 5 rpm, pH: 6 [mPas] A: 3500, B: 700 Mat finish fluid foundation component INCI Wt .-% I Lame form TGI ^® Polyglyceryl-3 diisostearate 1:50 Eumulgin ^® BA25 Beheneth-25 3:50 Cetiol ^® CC Dicaprylyl carbonates 6:00 am Myritol ^® 331 Cocoglycerides 2:00 Fitoderm ^® Squalane 3:00 Cutina ^® PES Pentaerythiryl distearate 1:00 Cegesoft ^® SH Shorea Stenoptera 1:00 Phenonip Phenoxyethanol (and) Parabens 0.80 KF 96, 100 cs Dimethicone 3:00 Cetiol ^® OE Dicaprylyl ether 3:00 II Sun Croma C47-051 Titanium dioxides 6:00 am SunPuro Yellow Iron Oxide C33-9001 Iron Oxide CI 77492 1.30 SunPuro Red Iron Oxide C33-8001 Iron Oxide CI 77491 0.60 SunPuro Black Iron Oxide C33-7001 Iron Oxide CI 77499 12:20 III Deionized Water Aqua 52.50 glycerin glycerin 3:00 Butylene glycol Butylene glycol 2:00 IV Veegum Ultra Magnesium Aluminum Silicate 1:00 Keltrol T. Xanthan gum 12:40 V Cosmedia ^® Gel CC Dicaprylyl Carbonate (and) Stearalkonium Hectorite (and) Propylene Carbonate 3:00 VI Cosmedia ^® PMMA V12 polymethyl methacrylates 2:00 VII Mirasil CDPDM Cyclomethicone (and) diphenyldimethicone 3:00 VIII Perfume Caresse 12:20 Viscosity, Brook. RVT, spindle 3, speed 5, 8400 mPas pH: 6.7 Ultra protective spray SPF 40 0 / W component INCI Wt .-% I Eumulgin ^® VL 75 Lauryl Glucoside (and) Polyglyceryl-2 Dipolyhydroxystearate (and) Glycerin 7:00 Generol ^® R Brassica campestris (Rapeseed) sterols 1:00 Cosmedia ^® DC Hydrogenated dimer dilinoleyl / dimethyl carbonate copolymer 1:00 Eusolex 2292 Ethylhexylmethoxycinnamate 7:50 Tinosorb S Bis-ethylhexyloxyphenol methoxyphenyltriazine 2:00 Cetiol ^® CC Dicaprylyl carbonate 4:00 Cetiol ^® AB C12-15 alkyl benzoate 4.00 4:00 Cegesoft ^® VP Olus & Hydrogenated Vegetable Oil & Candelilla Cera 2:50 Myritol ^® 331 Cocoglycerides 2:00 Cosmedia ^® Gel CC Sodium polyacrylate Carbonates (and) Stearalkonium Hectorites (and) Propylene Carbonates 4:00 II Water qsp 100 55.15 EDTA 4Na Tetrasodium EDTA 0.05 12:05 Elestab 50J Chlorphenesin & Methylparaben 0.60 III Keltrol T. Xanthan gum 12:20 IV Tinosorb M Methylenebis benzotriazolyl tetramethylbutylphenol 10:00 Viscosity, Brook. RVT, 23 ° C, spindle 2.5 rpm, 2500 mPas pH: 6.4 Soft moisture gel cream component INCI Wt .-% I Deionized Water Aqua 65.35 Glycerine glycerin 3:00 Phenonip Phenoxyethanol (and) Parabens 0.60 II Cosmedia ^® SP Sodium polyacrylate 1.20 III Cegesoft ^® PFO Passiflora Incarnata 2:00 Eusolex 2292 Ethylhexyl methoxycinnamate 2:00 KF 96,100 cs Dimethicone 2.00 2:00 IV Cetiol ^® CC Dicaprylyl carbonates 5:00 Eutanol ^® G octyldodecanol 4.0 Eusolex 4360 Benzophenone-3 12:10 Cegesoft ^® SBE Butyrospermum Parkii 1:50 V Cosmedia ^® Gel CC Dicaprylyl Carbonate (and) Stearalkonium Hectorite (and) Propylene Carbonate 5:00 VI Deionized Water Aqua 5:00 Osmhydran ^® LS 8453 Mannitol (and) Arginine (and) Serine (and) Sucrose (and) PCA (and) Citrulline (and) Glycogen (and) Histidine HCI (and) Alanine (and) Threonine (and) Glutamic Acid (and) Lysine HCI 2:00 VII Vegeseryl ^® LP LS 9058 Hydrolyzed soy protein 1:00 VIII Coviox ^® T70C tocopherol 12:10 Perfume Raphaelle 12:15 Viscosity, Brook. RVT, Helipath TE, speed 4, 101 000 mPas pH: 5.5 Velvety cleaning mask component INCI Wt .-% I Emulgade® ^® SE-PF Glyceryl Stearate (and) Ceteareth-20 (and) Ceteareth-12 (and) Cetearyl Alcohol (and) Cetyl Palmitate 8:00 Lanette ^® O Cetearyl Alcohol 2:00 Cegesoft ^® PS6 Olus 5:00 Cetiol ^® CC Dicaprylyl carbonates 4:00 Cutina ^® PES Pentaerythrityl distearate 3:00 II Cosmedia ^® Gel CC Dicaprylyl Carbonate (and) Stearalkonium Hectorite (and) Propylene Carbonate 5:00 III Deionized Water Aqua 45.00 Glycerine glycerin 10:00 EDTA, 4Na Tetrasodium EDTA 12:10 Elestab ^® 50J Chlorphenesin (and) Methylparaben 12:40 IV Dry Flo AF Corn Starch Modified0 1:00 Propylene glycol Propylene glycol 3:00 V kaolin kaolin 10:00 VI Perfume Concombre 12:20 Coviox ^® T70C tocopherol 12:10 VII Purisoft ^® LS 9602 Glycerin (and) Moringa Pterygosperma 2:00 VIII Green Covasol W7035 (as 0.1%) CI 42090 (and) CI19140 3.20 Viscosity, Brook. RVT, Helipath TE, Speed 4, 254 000 mPas pH: 6.3 Luxurious body butter component INCI Wt .-% I Deionized water Aqua 61.50 Glycerine glycerin 5:00 Butylene glycol Butylene glycol 2:00 EDTA, 4 Na Tetrasodium EDTA 12:10 Phenonip Phenoxyethanol (and) Parabens 0.80 II Cosmedia ^® SP Sodium polyacrylate 1:50 III Eumulgin ^® BA 25 Beheneth-25 3.00 3:00 Lanette ^® O Cetearyl Alcohol 4:00 Cetiol ^® SN Cetearyl Isononanoate 3:00 Cetiol ^® SB45 Butyrospermum Parkii 5:00 Cetiol ^® CC Dicaprylyl carbonates 1:00 KF 96, 100 cs Dimethicone 1:00 Generol ^® R Brassica campestris (Rapeseed) sterols 12:50 IV Cosmedia ^® Gel CC Dicaprylyl Carbonate (and) Stearalkonium Hectorite (and) Propylene Carbonate 5:00 V Cosmedia ^® PMMA V12 polymethyl methacrylates 2:00 Deionized water Aqua 4:00 VI Coviox ^® T70C tocopherol 12:10 Perfume Pétale 139012E 12:50 Viscosity, Brook. RVT Helipath TE, speed4, 800 000 mPas pH: 7 Happy deodorant crap component INCI Wt .-% IPM Isopropyl palmitate 6:50 Cetiol ^® Sensoft Propylheptyl Caprylate 6:50 Cosmedia ^® Gel CC Caprylic / Capric Triglycerides (and) Stearalkonium Hectorites (and) Propylene Carbonates 2:00 CETIOL ^® CC 2:00 Locron P Aluminum Clorohydrate 5:00 Perfume Deo Talco Perfume 12:30 Propellant 77.7

• Ratio propellant / other (3.34: 1); Valve: RK 150P RA 634/5/8 (vapor phase); Button: V04.776

Rich Hair Conditioner / Hair Conditioner phase trade name INCI name Wt .-% I. Dehyquart® ^® L80 Dicocoylethyl hydroxyethylmonium methosulfate (and) propylene glycol 2 Lanette ^® O Cetearyl Alcohol 5 Cutina ^® GMS Glyceryl stearate 1 CETIOL ^® CC 0.3 Cetiol ^® J 600 Oleyl erucate 0.5 Plantacare ^® 1200 UP Lauryl glucoside 2 II. glycerol 2 Water, deionized 50 III. hydroxyethyl hydroxyethyl 0.4 Water, deionized Ad 100 IV. Aloe vera gel 0.1 preservative qs Perfume qs >> PH value 4-4,5 >> Viscosity mPas Approximately 8000

Preparation: Phases I and II were heated to 85 ° C, Phase II was added at 85 ° C and the temperature was kept stirring until complete homogeneity. The emulsion was cooled with stirring and the polymer previously dissolved in water (phase III) was added. Thereafter, the remaining additives (phase IV) were added and the pH adjusted (eg with citric acid). Hair-Rinse & Coloring / Hair Rinse and Coloring phase trade name INCI name Wt .-% I. Dehyquart® ^® F75 Distearoylethyl Hydroxyethylmonium Methosulfate (and) Cetearyl Alcohol 2 Eumulgin ^® B2 Ceteareth-20 0.5 Lanette ^® O Cetearyl Alcohol 4 CETIOL ^® CC 1.5 II. Water, deionized Ad 100 III. Sol. 5% Arianor Mahogany Color 10 IV. preservative qs >> PH value 3.76

Preparation: Melting of Phase I at 80-85 ° C. Heat phase II to 80-85 ° C and stir in phase I. Stir at this temperature until complete homogeneity. Cool with stirring to 40 ° C. Adding preservatives and, if necessary, heat-sensitive additives. Cool while stirring to 30 ° C. Adjusting the pH, z. With citric acid. Add the Arianor solution at below 40 ° C. Styling gel type "Out of bed" phase trade name INCI name Wt .-% I. Alcool 96% (Prolabo) Alcohol 96% 12 Luviskol ^® VA 64 (BASF) PVP / VA 4.5 Polyox ^® WSR-301 PEG-90M 0.25 Methocel ^® E4M Premium EP (Dow) Hydroxypropyl methyl cellulose 0.6 Dehyquart® ^® L80 Dicocoylethyl Hydroxyethylmonium Methosulfate (and) Propylene Glycol 0.6 II. Eumulgin ^® HRE 40 PEG-40 Hydrogenated Castor Oil 1 CETIOL ^® CC 1.5 III. Water, deionized ad IV Hispagel ^® 200 Glycerin (and) Glyceryl Polyacrylates 36.7 V Preservative, perfume qs >> PH value 6.8 >> Viscosity (mPas) Brookfield RVT 23 ° C spindle 5, 10 rpm 220000

Preparation: 1. Add Phase I at room temperature gradually to the alcohol. 2. Mix Phase II to homogeneity and add to Phase I, 3. Add Phase III slowly to Phase I and II, 4. Add Phase IV slowly to Phase I-III, 5. Add Phase V if necessary. Sprayable Hair-Care Conditioner with Gluadin ^® WQTM phase trade name INCI Wt .-% I Monomuls® ^® 60-35C Powder Hydrogenated Palm Glycerides 1.24 Eumulgin ^® B1 Ceteareth-12 2.76 Cetiol ^® OE Dicaprylyl ether 5 CETIOL ^® CC 4 Dow ^Corning® 345 Cyclomethicone 2 II. Glycerine (86%) 2 water 16 III. Gluadin® ^® WQTM Hydroxypropyltrimonium hydrolyzed wheat protein 2.85 Plantacare ^® 2000 UP Decyl glucosides 1 water Ad 100 preservative qs PH value 5.5 Viscosity mPas <100

Preparation: 1. Heat the components of Phase I to 85 ° C, 2. Heat the components of Phase II also to 85 ° C and add Phase II by stirring in Phase I, 3. Add Phase III cold and stir until cools to room temperature. Conditioner with Dehyquart ^® C 4046 phase trade name INCI Wt .-% I. Dehyquart® ^® C 4046 Cetearyl Alcohol (and) Dipalmitoylethyl Hydroxyethylmonium Methosulfate (and) Ceteareth-20 4 Eutanol ^® G octyldodecanol 1 CETIOL ^® CC 0.5 II. Water, deionized Ad 100 Perfume qs preservative qs >> PH value 3.5 >> Viscosity (mPas) Brookfield RVF, 23 ° C, spindle 4, 10 rpm 10300

Preparation: Melting of Phase I at 80-85 ° C. Heat phase II to 80-85 ° C and stir in phase I. Stir at this temperature for five minutes. Cool to 40 ° C while stirring. Add the preservative and, if necessary, heat-sensitive additives. Cool to 30 ° C while stirring. Adjusting the pH, z. With citric acid. Conditioner with Dehyquart ^® C 4046 phase trade name INCI Wt .-% I. Dehyquart® ^® C 4046 Cetearyl Alcohol (and) Dipalmitoylethyl Hydroxyethylmonium Methosulfate (and) Ceteareth-20 4 CETIOL ^® CC 1 II. Water, deionized Ad 100 III. Perfume qs preservative qs >> PH value 3.5 >> Viscosity (mPas) Brookfield RVF, 23 ° C, spindle 4, 10 rpm 2060

Preparation: Melting of Phase I at 80-85 ° C. Heat Phase II to 80-85 ° C and stir in Phase I. Stir at this temperature for five minutes. Cool to 40 ° C while stirring. Add the preservative and, if necessary, heat-sensitive additives. Cool to 30 ° C while stirring. Adjusting the pH, z. With citric acid. Hair Polish Glossing Spray - Japan Hair Oil sprayable trade name INCI Wt .-% Dow ^Corning® 345 Fluid (Dow Corning) Cyclomethicone 85 Cetiol ^® CC Dicaprylyl carbonates 9.2 Cetiol ^® ISL Isostearyl lactates 3 Neo Heliopan AV (Haarmann & Reimer) Ethylhexyl methoxycinnamate 1.5 Wacker PDM 1000 Trimethylsiloxyphenyl dimethicone 0.5 preservative qs Perfume qs Water, deionized Ad 100

Production: Add all ingredients in the order as listed. Mix at room temperature. Hair gloss finishing serum trade name INCI Wt .-% ^DC® 1501 (Dow Corning) Cyclopentasiloxanes (and) dimethiconol 70 Cetiol ^® CC Dicaprylyl carbonate 27.7 Myritol ^® 318 Caprylic / Capric triglyceride 0.5 Neo Heliopan E 1000 (Haarmann & Reimer) Isoamyl p-methoxycinnamate 1 Phenonip (SIPCA) Phenoxyethanol (and) parabens 0.5 Perfume 0.3 dye qs

Preparation: Add the ingredients as shown. Mix at room temperature. Note: The dye and the perfume used must be oil-soluble (the perfume is also compatible with dimethiconol to prevent cloudiness). Hair gloss gelatin for very damaged and dull hair trade name INCI Wt .-% Cetiol ^® CC Dicaprylyl carbonates 43.6 Myritol ^® 318 Caprylic / Capric triglyceride 43.6 Wacker HDK H 20 (Wacker) Silica dimethyl silylates 12.5 Perfume 0.3 PH value N / A Viscosity at 20 ° C, Helipath, spindle E, 5 rpm (mPas) 500000

Preparation: Mix the ingredients in the order given. Glossy light hair cream phase trade name INCI Wt .-% I. Dehyquart ^® F 75 Distearoylethyl hydroxyethylmonium methosulfate (and) cetearyl alcohol 0.8 Dehyquart ^® L 80 Dicocoylethyl hydroxyethylmonium methosulfate (and) propylene glycol 1.8 Lanette ^® O Cetearyl Alcohol 5 Cetiol ^® CC Dicaprylyl carbonates 5 II. Water, deionized 87.4 III. preservative qs Perfume qs >> PH value 3.3 Viscosity at 20 ° C, Brookfield RVT, spindle 4, 10 rpm (mPas) 8600

Preparation: 1. Heat Phase I to 80-85 ° C, 2. Heat Phase II to 80-85 ° C and add via Phase I. Approx. Stir at the same temperature for 30 minutes. 3. Allow to cool with gentle stirring. 4. If the temperature is below 40 ° C, add Phase III in the order given, 5. Adjust the pH if necessary. Deep hair care cream with wild mango butter phase trade name INCI Wt .-% I. Structure XL (National Starch) Hydroxypropyl Starch Phosphate 5 Water, deionized 86.3 II. Dehyquart L 80 Dicocoylethyl hydroxyethylmonium methosulfate (and) propylene glycol 2.6 CETIOL ^® CC 1 Irwinol ^® LS 9319 Octyldodecanol (and) Irvingia gabonensis (and) Hydrogenated Coco Glycerides 0.1 Lame Soft ^® TM Benz Glycol distearate (and) Coco Glucoside (and) Glyceryl Oleate (and) Glyceryl Stearate 4 Gluadin® ^® WLM Hydrolyzed Wheat Protein 0.5 Nutrilan® ^® MILK Hydrolyzed Milk Protein 0.5 III. preservative qs Perfume qs >> PH value 3.8 >> Viscosity (mPas), Brookfield RVT, 20 ° C, spindle 4, 10 rpm 10000

Preparation: 1. Dissolve Structure XL in water and stir until complete homogeneity, 2. Adjust pH to 3.5-4.0 with citric acid, dilute, 3. Add remaining ingredients in the order listed while stirring ( Irwinol must be melted before adding) Hair Cream gloss & Conditioning phase trade name INCI Wt .-% I. Dehyquart ^® F 75 Distearoylethyl hydroxyethylmonium methosulfate (and) cetearyl alcohol 2 Lanette ^® O Cetearyl Alcohol 3 CETIOL ^® CC 1 Dehyquart ^® L 80 Dicocoylethyl hydroxyethylmonium methosulfate (and) propylene glycol 2 Cocoa butter (Nederland) Theobroma cacao seed butter 0.5 Structure XL (National Starch) Hydroxypropyl Starch Phosphate 5 II. Water, deionized 86.02 glycerin 0.48 III. preservative qs Perfume qs >> PH value 4.3 >> Viscosity (mPas) Brookfield RVT, 20 ° C spindle 5, 10 rpm 47600

Preparation: 1. Melt the ingredients of Phase I at 80-85 ° C, 2. Add the water at the same temperature while stirring. Hold this temperature and stir for 30 minutes, 3. cool with slow stirring, 4. adjust the pH if necessary with citric acid, 5. add the preservative and perfume at below 40 ° C. Deep penetrating Hair Reconstructor phase trade name INCI Wt .-% I. Dehyquart ^® L 80 Dicocoylethyl hydroxyethylmonium methosulfate (and) propylene glycol 2 CETIOL ^® CC 1 DC 949 (Dow Corning) Amodimethicone (and) Cetrimonium Chloride (and) Trideceth-12 1 Gluadin® ^® WLM Hydrolyzed Wheat Protein 2 Perfume qs preservative qs II. Lamesoft ^® PW 45 Cetyl palmitate (and) Beheneth-10 (and) Hydrogenated Castor Oil (and) Glyceryl Stearate 4 Water, deionized 37,75 III. Rheocare ^® CTH (E) (Cosmetic Rheologies) Polyquaternium-37 (and) propylene glycol dicaprylate / dicaprate (and) PPG-1 trideceth-6 2.25 Water, deionized 50 >> PH value 4 Viscosity (mPas) Brookfield RVT, 20 ° C spindle 4, 10 rpm 10500

Production: 1. Mix the components of phase I until completely homogeneous, the second dissolving lamesoft ^® PW 45 in water and add to phase 1, 3. Resolving Rheocare polymer in deionized water until a homogeneous cream 4. Add from Phase I + II via Phase III, 5. Adjust the pH value if necessary. Hair Conditioner Classic Care phase trade name INCI Wt .-% I. Lanette ^® O Cetearyl Alcohol 4.5 Dehyquart ^® F 75 Distearoylethyl hydroxyethylmonium methosulfate (and) cetearyl alcohol 1.4 Cutina ^® GMS V Glyceryl stearate 0.5 CETIOL ^® CC 0.2 DC 200-1000 (Dow Corning) Dimethicone 0.2 II. Dehyquart® ^® A-CA Cetrimonium chlorides 2 Water, deionized 91.2 III. preservative qs Perfume qs PH value 3.9 Viscosity (mPas) Brookfield RVT, 20 ° C spindle 4, 10 rpm 19700

Preparation: 1. Mix Phase I at 80-85 ° C to homogeneity, 2. Add Phase II over Phase I at the same temperature (80-85 ° C) and stir. Continue stirring for 30 minutes, 3. Cool with slow stirring and add Phase III at a temperature of less than 40 ° C, 4. Adjust the pH if necessary (pH value = 3.5-4.5). Hair shine mist ("crap") trade name INCI Wt .-% Cetiol ^® CC Dicaprylyl carbonate 95 Dow ^Corning® 200 Fluid (Dow Corning) Dimethicone 2.7 ^Neo® Heliopan AV (Haarmann & Reimer) Ethylhexyl methoxycinnamate 1.5 Wacker PDM 1000 Trimethylsiloxyphenyl dimethicone 0.5 Perfume 0.3 PH value N / A Viscosity at 20 ° C (mPas) <100

Preparation: Mix ingredients in the order given Sprayable Hair Conditioner, leave-on phase trade name INCI Wt .-% I. Monomuls ^® 60 35 C Hydrogenated Palm Glycerides 1.24 Eumulgin ^® B1 Ceteareth-12 2.76 Cetiol ^® S Dioctylcyclohexane 9 Cetiol ^® OE Dicaprylyl ether 9 CETIOL ^® CC 2 II. water 56.2 Gluadin® ^® WQ Laurdimonium hydroxypropyl hydrolyzed wheat protein 2.85 Plantacare ^® 1200 UP Lauryl glucoside 1 preservative qs Perfume qs Viscosity mPas

Preparation: 1. Heat Phase I to 85 ° C and stir until homogeneous. 2. Heat Phase II to 85 ° C and add slowly to Phase I while stirring, 3. Add Phase III (cold) at 78 ° C to Phase I / II while stirring, 4. Allow the emulsion to cool during stirring, which keeps the emulsion constantly in motion. Avoiding trapped air. Add Phase IV at 30 ° C. Cream to Powder Foundation Component INCI name (trade name, manufacturer) Wt .-% A Diisostearyl malate (Corum 5015, Corum) 7.7 Titanium dioxide (HD-0748, Lubrizol / Noveon) 12.6 Iron oxides (HD-3170, Lubrizol / Noveon) 1.25 Iron oxides (HD-3511, Lubrizol / Noveon) 0.2 B Dimethicone (and) Dimethicone Crosspolymer (DC 9041 Sillcone Elastomer Blend, Dow Corning) 8th CETIOL ^® CC 5 Ethylhexyl isononanoate (Corum 5021, Corum) 6 Pentaerythritol tetraisostearate (Corum 5041, Corum) 7 Polyisobutane (and) C _15-19 alkane (and) C _12-14 isoparaffin (Permethyl 284C, Presperse) 3 Cholesteryl hydroxystearate (Corum 5-89, Corum) 0.5 Carnauba wax 4 Cetyl Palmitate (Corum 5000, Corum) 0.6 Myristyl myristate (Corum 5028, Corum) 0.6 Tribehenine (Corum 5094, Corum) 0.5 Microcrystalline wax 1.5 Methyl methacrylate crosspolymer (Glanzpearl GMX 0610, ISP) 5.5 Boron nilinde (Soltouch CC6059, Momantive) 1 Talc (and) methicone (Corum 5901, Corum) 11.67 Mica (and) methicone (and) Paraffin liquidum (mineral) oil (Sericite SL012P, Nikko) 10 Lauroyl lysine (Corum 5106, Corum) 6 C Pentaerythritol tetraisostearate (and) paraffinium liquidum (mineral) oil (and) disteardimonium hectorite (and) propylene carbonate (and) palmitoyl tripeptide (Corum 9913, Corum) 3 Pentaerythritol tetraisostearate (and) paraffinium liquidum (mineral) oil (and) disteardimonium hectorite (and) propylene carbonate (and) palmitoyl oligopeptide (Corum 8616, Corum) 3 Phenoxyethenol (and) methylparaben (and) butylparaben (and) ethylparaben (and) propylparaben (Paragon MEPB, Molmyre) 1 Perfume 0.06

Preparation: Prepare premix of A, add B to A and heat to 90 ° C, mix well, adjust heat and add C. Makeup foundation Component INCI name (trade name, manufacturer) Wt .-% water 78.2 glycerin 1.89 Triethanolamine 99% 0.75 Methylparaben (Nipagin M. Nipa) 0.19 Xanthan gum (Keltrol SP, CP Kelco) 0.28 Titanium dioxide (Softex Titanium dioxide, C47-7756, Sun Chemical) 8.75 Brown iron oxide (SunChroma Brown iron oxide, C33-315 Sun Chroma, Sun Chemical) 1.08 Red iron oxides (SunChroma red iron oxide, C33-124 Sun Chroma, Sun Chemical) 0.17 Phenyl trimethicone (DC 556 cosmetic fluid, Dow Corning) 3.41 CETIOL ^® CC 1 Stearic acid, 94% 1.33 Cetyl stearyl alcohol (Lanette O, Cognis) 2.84 Propylparaben (Nipasol, M. Nipa) 0.1 "Skin Corrector" Component INCI name (trade name, manufacturer) Wt .-% Synthetic wax (Cirebelle 108, Cirebella) 2.9 CETIOL ^® CC 19.51 Synthetic wax (Cirebelle 303, Cirebella) 2.33 Titanium dioxide wax dispersion (CWD-8906, Sun Chemical) 65.12 Yellow iron oxides wax dispersion (CWD-8942, Sun Chemical) 4.18 Red iron oxide wax dispersion (CWD-8801, Sun Chemical) 1.91 Black Iron Oxide Wax Dispersion (CWD-9921, Sun Chemical) 0.05 Alumina (and) titanium dioxide (SpectraFlex Focus White C88-1001, Sun Chemical) 4 Matte Antiaging Foundation phase Component INCI name (trade name, manufacturer) Wt .-% A Cyclopentasiloxanes (and) dimethicone copolyol (DC 5225C, Dow Corning) 12 CETIOL ^® CC 10 Titanium dioxide (BTD-401, Kobo) 9 Yellow Iron Oxide (BYO-12, Kobo) 0.8 Red iron oxide (BRO-12, Kobo 0.07 Black iron oxides (BRO-12, Kobo) 0.034 Methylmethacrylate crosspolymer (Sepimat SB, Seppic) 1 Methylmethacrylate crosspolymer (Sepimat HB V, Seppic) 1 Phenoxyethanol (and) methylparaben (and) ethylparaben (and) propylparaben (and) butylparaben (Sepicide HB, Seppic) 17.296 Perfume 0.3 B Dipalmitoyl hydroxyproline (Sepilift DPHP, Seppic) 0.5 Palmitoyl praline (and) magnesium palmitoyl glutamate (and) sodium palmitoyl sarcosinate (Sepiflel One, Seppic) 05, Undecylenoyl phenylalanine (Sepiwhite MSH, Seppic) 0.1 C Sodium hydroxide, 48% solution 0.2 glycerin 5 Sodium chloride 2 Imidazolidinyl urea (Sepicide Cl, Seppic) 0.2 D water 40

Preparation: Phase A is prepared by dispersing the powders in the silicones and the n-undecane / n-tridecane with stirring, comminuting in a ball mill. Phases B, C and D are prepared separately and each heated to 80 ° C. Phase D is added to Phase C, this mixture is then added to B. Homogenize for a few minutes, cool with moderate stirring. This mixture is then added to Phase A with vigorous stirring and the resulting emulsion is homogenized. Super Matte Foundation phase Component INCI name (trade name, manufacturer) Wt .-% A water 54.72 Disodium EDTA 0.1 Water (and) montmorillonite (and) cetyl alcohol (and) glycerol (and) pentylene glycol (and) sucrose stearate (and) aderoglucan (Matte Lite Concentrate 269, MMP) 20 B Sucrose distearate (Sistearna SP30-C, MMP / Sisterna) 0.75 C Titanium dioxide 6 Red iron oxides 0.5 Yellow iron oxides 1.25 Black iron oxides 0.13 Nylon 12 0.25 D Dimethicone (and) dimethicone / vinyl dimethicone crosspolymer (Clearocast 200, MMP) 5 CETIOL ^® CC 1 Isododecane (and) isononyl isononanoate (Clearocast 550, MMP) 10 e preservative 0.3 "Chocolate Mousse" phase Component INCI name (trade name, manufacturer) Wt .-% A Cl 77891 dimethicone (SAT-T-47051, US cosmetics) 0.528 Cl 77491 dimethicone (SAT-R-33128, US cosmetics) 0.456 Cl 77492 dimethicone (SAT-Y-33873, US cosmetics) 0.732 Cl 77499 dimethicone (SAT-B-33134, US cosmetics) 0,284 B Dimethicone / vinyl dimethicone crosspolymer (and) silica (Dow Coming 9701 Cosmetic Powder, Dow Corning) 23 Zinc oxide (and) dimethicone (Z-cote HP-1, BASF) 6 C water 4 Water (and) propylene glycol (and) Helianthus annuus (sunflower) seed oil (and) Theobroma cacao extract (and) sclarolum gum (Cocoa phytolate, Alban Muller) 1 Dimethicone (Dow Coming 200 Fluid, 5 cSt, Dow Corning) 22,75 CETIOL ^® CC 22,75 Cyclopentasiloxanes (and) dimethiconol (Dow Coming 1501 Fluid, Dow Corning) 5 Cyclopentasiloxanes (and) dimethicone crosspolymer (and) dimethiconol (Dow Corning 9546 Silicone Elastomer Blend, Dow Corning) 5 Theobroma cacao seed butter (Cocoa Butter, Alban Muller) 1 Cocos nucifera (coconut) oil (and) Gardenia tahitensis flower extract (Monoi de Tahip butter frangaced, Pacific Sud Cosmédtique) 1 Tocopherol acetate (di-alpha-tocopherol acetate, DSM) 0.5 Polysilicone-15 (Parsol-SLX, DSM) 5 D Perfume (Chocolat Crème 0310585, Expressions Perfumdées) 1

Preparation: A is ground and B is added and stirred. Phase C is introduced and heated with stirring and to 45 ° C. Then AB is added in small portions and finally D is added. Fresh Foundation Emulsion Mousse phase Component INCI name (trade name, manufacturer) Wt .-% A Ceteareth-25 (and) PEG-2 stearate (and) Paraffinium liquidum (mineral) oil (and) hydrogenated coconut oil (and) cetyl alcohol (and) sodium stearate (Base O / W 097, LCW) 5 Caprylic / capric triglycerides 15 CETIOL ^® CC 1 B water 59 preservative 0.3 glycerin 2 Algas extract (and) sorbitol (Fucosorb, LCW) 2 C Cl 77499 (and) silica (Unipure Black LC 989 EM, LCW) 0.1 Cl 77492 (and) silica (Unipure Yellow LC 162 EM, LCW) 0.75 Cl 77491 (and) silica (Unipure Red LC 361 EM, LCW) 0.18 Cl 77891 (and) silica (Unipure white LC 981 EM, LCW) 2.95 Mica (Submica FL, LCW) 1 Methylmethacrylate crosspolymer (and) silica (Covabeed PMMA 2MUSL, LCW) 1 Mica (Mica 8 R2041, LCW) 4 Talc (Talc LCW, LCW) 4 Sodium plyacrylate (Covacryl MV50, LCW) 1 Silica dimethyl silyata (Covasilic 15, LCW) 0.5

Preparation: A and B are prepared separately and each heated to 70 ° C. B is added to A with stirring. Phase C was prepared separately and thoroughly mixed with a powder mixer and then added with stirring to the mixture of A and B. Mattifying Fluid Foundation phase Component INCI name (trade name, manufacturer) Wt .-% A water 20 Butylene glycol 4 PEG-400 4 Dimethicone copolyol PEG-7 phosphate (Pecostil PS 100, Pheonix) 1 B Titanium dioxide 10 talc 2 Iron oxide yellow 0.9 Iron oxide red 0.3 Iron oxide black 0.05 Titanium dioxide (Cl 77891) (and) iron oxide (Cl 77491) (and) mica (and) triethoxy caprylylsilane 3 C C _20-22 alkyl phosphate (and) C _20-22 alcohols (Sensanov WR, Seppic) 1 C _14-22 alcohol (and) C _12-20 alkyl glucosides (Montanov L, Seppic) 2 Isostearyl isostearate 8th CETIOL ^® CC 1 Ethylhexyl palmitate 9 Vegetable oil (and) palm alcohol (and) lecithin (and) vegetable stearyl esters (Sensactive Veg. Chemyunion) 2 D water qs to 100 Xanthan gum 0.15 e tromethamine qs Tetrasodium EDTA 0.05 Polymethyl methacrylate (Micropearl M100, Seppic) 3 F Sodium acrylate / acryloyldimethyl laurate copolymer (and) isohexadecane (and) polysorbane (Simulgel EG, Seppic) 0.5 G Phenoxyethanol (and) methylparaben (and) ethylparaben (and) propylparaben (and) butylparaben (Chemynoi, Chemyunion) 0.1 Perfume qs Ultra gloss lipsticks Component INCI name (trade name, manufacturer) Wt .-% Polyglyceryl-10 hydroxystearate / stearate / eicosadioate (and) dextrin palmitate (Nikkol Nikkowax LM, Nikko) 5 Copernicia cerifera (carnauba) wax 10 Cera alba (beeswax) 15 Cetyl alcohol 5 Ricinus communis (castor) seed oil 63 CETIOL ^® CC 2

Preparation: Heat the mixture and melt at 80 ° C and pour into the mold. Maximum shine pencils phase Component INCI name (trade name, manufacturer) Wt .-% A D & C Red No. 6 Barium Lake (Red 6 Lake, Emerald Nilton Davis) 0.7 Iron Oxides (CC33-5136 Russet Iron Oxide, Sun Chemical) 2.5 Iron Oxides (CC33-135 Black Iron Oxide, Sun Chemical) 0.25 Ricinus communis (castor) seed oil (Crystal O, CasChem) 3 B Ricinus communis (castor) seed oil (Crystal O, CasChem) 35.75 Copernica cerifera (carnauba) wax (Carnauba No. 1, Ray & Pitsch) 1.1 Euphorbia cerifera (candelilla) wax (Candelilla Pure, Ray & Pitsch) 5 Ozokerite (Ozokerite Wax 1700, Frank B, Ross Company) 2.5 CETIOL ^® CC 1 Microcrystalline wax (Microwax SP 19, Strahl & Pitsch) 2 Diisostearyl malata (Schercamol DISM Ester, Lubrizol / Noveon) 24 Trisostearyl citrate (Schercomol TISC Ester, Lubrizol / Noveon) 16.85 methylparaben 0.2 Propylparaben 0.1 C Mica (and) iron oxides (Colorona Copper, EMD chemicals) 5 D Ascorblalmitate 0.05 Ultra lasting lip color phase Component INCI name (trade name, manufacturer) Wt .-% A D & C Red No. 7 Calcium Lake (31-DA-3707, Emerald Hilton Davis) 0.6 D & C Red no. 6 Barium Lake (31-DA-3006, Emerald Nilton Davis) 1.5 Iron Oxides (CC33-5138 Russet Iron Oxide, Sun Chemical) 4.5 Titanium dioxide 0.5 Ricinus communis (castor) seed oil (Crystal O, CasChem) 8.3 B Ricinus communis (castor) seed oil (Crystal O, CasChem) 21.65 Copernica cerifera (carnauba) wax (Carnauba No. 1, Ray & Pitsch) 1.5 Euphorbia cerifera (candelilla) wax (Candelilla Pure, Ray & Pitsch) 6 Ozokerite (Ozokerite Wax 1700, Frank B. Ross Company) 2.5 Microcrystalline wax (Microwax SP 19, Strahl & Pitsch) 3.5 Triisostearyl polyglyceryl-3 dimer diinoleate (Schercemol PTTD ester, Lubrizol / Noveon) 10 Trisostearyl citrate (Schercomol TISC Ester, Lubrizol / Noveon) 22 Isopropyl Isostearate (Schercamol 316 Ester, Lubrizol / Noveon) 4 CETIOL ^® CC 1 methylparaben 0.2 Propylparaben 0.1 C Mica (and) Titanium dioxide (Flamenco Red, Engelhard) 12 D Ascorbyl palmitate (ascorbyl palmitate, DSM) 0.05 Long lasting shine lip gloss phase Component INCI name (trade name, manufacturer) Wt .-% A octyldodecanol 47.93 B Ethylcellulose (Ethocel 100FP, Amerchol) 5 C CETIOL ^® CC 18 bis-biglyceryl polyacladipate-2 15 Octyl methoxycinnamate 7.5 polyethylenes 2 D Red No. 7 aluminum lake (Sun Chemical) 0.58 Iron oxides (Cl 77491, Sun Chemical) 0.52 Iron oxides (Cl 77492, Sun Chemical) 0.48 Iron oxides (Cl 77499, Sun Chemical) 0.09 e Mica (and) Titanium Dioxide (Prepearis Shining Salin, Prespense) 1.9 Dimethicone crosspolymer / silica (DC 7901 Powder, Dow Corning) 1 High-shine lipstick component Wt .-% A Hydrogenated polydecenes (and) ethylene propylene / styrene copolymer (and) butylene / ethylene / styrene copolymer (Versagel MG 750, Penreco) 25.89 Petrolatum (and) ethylene / propylene / styrene copolymer (and) butylene / ethylene / styrene copolymer (Versagel P100, Penreco) 10.38 Euphorbia cerifera (candelilla) wax (Candelilla wax refined, Ross) 8.8 Cera alba (beeswax) (White Bleached Beeswax, Ross) 5.18 Lanolin wax 4.14 Lanolin oil 4.14 Octyldodecanol (Eutanol ^® G, Cognis) 4.14 CETIOL ^® CC 3.63 Copernicia cerifera (carnauba) wax (Carnauba wax, Ross) 3.11 Octyldodecyl stearoyl stearate (Ceraphyl 647, ISP) 3.11 Tridecyl trimellitate (Liponate TDTM, Lipo) 3.11 Propylparaben 0.1 Butylated hydroxytoluene 0.1 B Butyrospermum parkii (shea butter) (shea butter, ultra refined, biochemica) 5.18 Jojoba esters (Floraesters 30, Floratech) 2.07 Theobroma grandiflorum seed butter (Cupuacu butter, Beraca / Ross) 2.07 C Iron oxides (and) synthetic fluorophlogopites (Sunshine Super Russet, Sun Chemical) 8.29 Iron Oxides (Soft-Tex Russet Iron Oxide, Sun Chemical) 5.18 Red No. 7 Lake 1.04 Yellow No. 6 Lake 0.38 Elegant lipstick Component INCI Name (Manufacturer) Wt .-% Dipentaerythrityl hexacaprylate / hexacaprate (and) tridecyl trimellitate (and) tri-decyl stearate (and) neopentyl glycol dicaprylate / dicaprate (Lipovol MOS-350, Lipo) 72.2 Synthetic beeswax (Lipobee 102, Lipo) 8th Copernicia cerifera (carnauba) wax 4 Euphorbia cerifera (candelilla) wax 4 CETIOL ^® CC 1 Propylparaben 0.2 Mica (and) boron nitride (Lipomic 501 BN, Lipo) 1 Tocopherol (Vitamin E Acetate, Ruger Chemical) 0.5 Titanium dioxide (Cl 77891) (and) dipentaerythrityl hexacaprylate / hexacaprate (and) tridecyl trimellitate (and) tridecyl stearate (and) neopentyl glycol dicaprylate / dicaprate (titanium dioxide, 60% in Lipovol MOS-350, Lipo) 2.8 Iron oxide (Cl 77489) (and) dipentaerythrityl hexacaprylate / hexacaprate (and) tridecyl trimellitate (and) tridecyl stearate (and) neopentyl glycol dicaprylate / dicaprate (iron oxide Red, 60% in Lipovol MOS-350, Lipo) 4.7 Iron oxide (Cl 77489) (and) dipentaerythrityl hexacaprylate / hexacaprate (and) tridecyl trimellitate (and) tridecyl stearate (and) neopentyl glycol dicaprylate / dicaprate (iron oxide Yellow, 60% in Lipovol MOS-350, Lipo) 0.8 Iron oxide (Cl 77489) (and) dipentaerythrityl hexacaprylate / hexacaprate (and) tridecyl trimellitate (and) tridecyl stearate (and) neopentyl glycol dicaprylate / dicaprate (iron oxide black, 60% in Lipovol MOS-350, Lipo) 0.8

Preparation: All ingredients are heated to 80-85 ° C with stirring. The batch is cooled to 70-75 ° C and filled into a mold. Lip gloss Component INCI Name (Manufacturer) Wt .-% A CETIOL ^® CC 2 C _4-24 alkyl dimethicone / divinyl dimethicone crosspolymer dimethicone (NuLastic Silk MA, DM, Alzo) 15 Methylheptyldiisostearate (Beantree, Alzo) 10 C _4-24 alkyl dimethicone / divinyl dimethicone crosspolymer dimethicone (NuLastic Silk MA, DM-6, Alzo) qs to 100 Tocopherol (vitamin E, BASF) 0.2 preservative qs Perfume (Peach Nectar 6104085, Bell Flavors & Fragances) 0.2 B Calcium Sodium Borosilicate (and) Iron Oxide (Reflecks Dimensions Shiny Bronze G25000000, BASF) 1 Mica (and) Titanium dioxide (Flamenco Winter Sparide 1300000 5 Hydrogenated polyisobutenes (Luvitol Lite, BASF) 10

Preparation: Phases A and B are each homogenized in separate vessels, then becomes phase B is added to phase A and mixed until the product is homogeneous. Creamy Sheer Lip Color Component INCI Wt .-% A Sesamum indicum (sesame) seed oil 21.28 Octyldodecanol (Jarcol I-20, Jarchem) 15.47 Euphorbia cerifera (candelilla) wax (SP75, Ray & Pitsch) 12 Isohexyl caprate 10.07 Bis-diglyceryl polyaryladipate-2 (Softisan 649, Sasol) 9.95 Polyisobutenes (Permethyl 104A, Presperse) 9.67 CETIOL ^® CC 2.89 Polyethylene (Performing PL Polyethylene, New Phrase) 2.5 Microcrystalline Wax (Be Square 195, New Phrase) 2.5 B Synthetic wax and titanium dioxide (and) Isopropyl Titanium triisostearate (SW65U, Kobo) 4.24 Synthetic wax and iron oxide (and) Isopropyl Titanium triisostearate (SW60ER, Kobo) 1.41 Synthetic wax and D & C Red No. 6 Barium Lake (and) Isopropyl Titanium triisostearate (SW40R6E, Kobo) 1.41 Synthetic wax and Blue No.1 Lake (and) Isopropyl Titanium triisostearate (SW30B1A, Kobo) 0.71 Mica (and) titanium dioxide (KTZ Classic White, Kobo) 0.96 C Vitis vinifera (grape) seed oil 4.84 Vitamin E acetata 0.1 Lip volume booster INCI name (trade name, manufacturer) Wt .-% A Ricinus communis (castor) oil 39.7 Hydrogenated coco-glycerides (Softisan 100, Sasol) 8th Candelilla cera (and) Paraffin (Cenilla G, Barlocher) 9 Bis-diglyceryl polyacyl adipate-1 (Softisan 645, Sasol) 8th Cera alba (Cerabell White, Barlocher) 3 Cera carnauba wax (Cernauba T1, Barlocher) 2 Tricaprylin (Trivant OC-G, Trivant Chemical) 20 Tocopheryl acetate (D-alpha tocopheryl acetate, DSM / Roche) 0.5 CETIOL ^® CC 1 Propylparaben (Nipasol M. Nipa) 0.1 BHT (butylhydroxytoluene) 0.05 B Ricinus communis (castor) oil (and) Cl 15850 (and) BHT (COD 8001, Sun Chemical) 0.8 Calcium aluminum borosilicate (and) Cl 77891 (and) silica (and) tin oxide (Fionastar Noble Sparks, Merck) 1 Mica (and) Cl 77891 (and) Cl 77491 (Timiron MP29 Sun Gold Sparkle, Merck) 2 Mica (and) Cl 77891 (Timiron MP 149 Diamond Cluster, Merck) 2 C Glycerin (and) palmitoyl tripeptide-3 (Syn-Coll, Pentapharm) 2.5 Alkyl methacrylate crosspolymer (Poly-Pore E200, Amcol HBS) 0.35

Preparation: Heat all components of phase A to 80 ° C, add phase B to A, mix phase C and add to AB just before homogenization. Plumping effect lipstick Components INCI Name (trade name, manufacturer) Wt .-% A D & C Red No. 7 Ca Lake (CI 15850: 1) (HD-3007, Noveon) 0.4 Red iron oxide (Cl 77491) (HD-3511, Noveon) 0.4 Titanium dioxide Cl 77891 (HD-0748, Noveon) 1.2 Paraffinum liquidum (mineral) oil (and) disteardimonium hectorite (and) propylene carbonate (Gentone Gel MO V, Elementis Specialties) 1.5 Diisostearyl maleate (Corum 5015, Corum) 10.5 Mica (and) titanium dioxide (and) tin oxide (Prestige Sparkling blue, Eckart) 1.5 B Pentaerythrityl tetraisostearate (Corum 5041, Corum) 15 Cholesteryl hydroxystearate (Corum 5069, corum) 1 Hydrogenated polydecene (Nexbase 2006FG, Fortum) 15 CETIOL ^® CC 10 Isostearyl isostearate (corum 5088, Corum) 19.9 Phenyltrimethicones (DC 556, Dow Corning) 2 PEG-8 beeswax (Corum 2680, Corum) 2 ceresin 9 Euphorbia cerifera (candelilla) wax 2 Cera alba (beeswax) 2 Copernicia cerifera (carnauba) wax 3 Jojoba ester (Floraester-70, Floratech) 1 Pentaerythrityl tetraisostearate (and) paraffin liquidum (mineral) oil (and) disteardimonium hectorite (and) propyl carbonate (and) palmitoyl oligopeptide (Corum 8813, Corum) 2 C Vanilyl butyl ether (Corum 9235, Corum) 0.4 Flavor 0.2

Preparation: Phase A is mixed to homogeneity, Phase B is added and heated to 90 ° C and mixed well. The heat is stopped and added to Phase C, then mixed well. lipstick Components INCI Name (trade name, manufacturer) Wt .-% A Propylene glycol dicaprylate / dicaprate (and) bis-diglyceryl polyacyl adipate-1 (and) bis-diglyceryl polyadipate-2 (softisan gel, Sasol) 9 Stearalkonium hectorite (and) propylene carbonate (Softisan 649, Sasol) 6 Hydrogenated coco-glycerides (Softisan 100, Sasol) 22.5 Hydrogenated palm oil (Softisan 154, Sasol) 3 C _12-10 alkyl octanoate (Cosmacol EDI, Sasol) 5 Petrolsturm (Mercury Vaseline 773, Merkur) 11 Cera alba (beeswax) 7 Cyclomethicone (Beisli CM 040, Wacker Chemie) 3 CETIOL ^® CC 4 Ricinus communis (castor) oil 6 paraffin 14 antioxidant qs B Titanium dioxide (Cl 77891) (Timiron Splendid Red, Merck) 3.5 Mica (and) Titanium dioxide (Cl 77891) (Timiron Starlusler MP-115, Merck) 2.5 Mica (and) Titanium dioxide (Cl 77891) (Timiron Super Silver Fine, Merck) 3 C Perfume qs Tocopheryl acetate 0.5 Volumizing mascara Components INCI Name (trade name, manufacturer) Wt .-% A Cera alba (Beeswax) (White Beeswax SP422P, Ray & Pitsch) 2.76 Glyceryl stearate 2.3 Copernicia cerifera (carnauba) wax (Carnauba wax SP63, Ray & Pitsch) 1.98 Stearic acid 3 Ethylcellulose (Ethocel Standard 100FP Premium, Amerchol) 3 CETIOL ^® CC 1 octyldodecanol 7 Premised chitosan PCA, 2.5% (Kytamer PCA polymer, Amerchol) 15 B Iron oxide (Black Iron Oxide, Sun Chemical) 6 water 55.45 C Triethanolamine 99% 1.5 D Propylene glycol (and) diazolidinyl ure (and) methylparaben (and) propylparaben (NiPaguard, Clariant) 1 Eyeshadow pen (Eye shadow stick) Components INCI Name (trade name, manufacturer) Wt .-% A CETIOL ^® CC 1 Ocryldodacyl neopentanoate (Elefac I-205, Alzo) qs. to 100 Calcium sodium borosilicate (and) silica (and) titanium dioxide (Refleck's MultiDimensions Varying Violet G58000000, BASF) 14 Mica (and) Titanium dioxide (and) iron oxides (Gemtone Moonstone G004, BASF) 1 B Butylene glycol 3.13 Acetylated glycol stearate (Unitwax, Guardian, ISP) 22 Silica (Cab-o-Sil M5, Cabot) 1.5 C Simmondsia chinensis (jojoba) seed oil (Lipovol J. Lipo) 7.5 Stearic acid (Emersol 132, Cognis) 3.6 preservative qs antioxidant qs

Phase B is melted and mixed, then added to Premixed Phase A. AB are heated with stirring to 80-05 ° C and then phase C is added slowly. Metallic silver shine mascara Components INCI Name (trade name, manufacturer) Wt .-% A water 56.25 Xanthan gum (Keltrol T, CP Kelco) 0.15 Magnesium aluminum silicate (Veegum HV, RT Vandervilt) 0.55 Carbon black (and) water (MBD 201 20% dispersion, geotech) 5 B Disodium EDTA (Edeta BD, BASF) 0.05 Methyl paraben (methyl 4-hydroxybenzoates H 5501, Sigma Aldrich) 0.3 Triethanolamine 0.5 Propylene glycol 2 C Aluminum powder (and) silica (Visionaire Bright Silver sea, Eckart) 3 D CETIOL ^® CC 5 Cyclopentasiloxanes (and) PEG / PPG-18/18 dimethicones (Dow Corning 5225C Formulation Aid, Dow Corning) 1 Cera alba (beeswax) (Ewacers 12, Wagner) 10 Stearic acid (Kortacid 1695, Akzo Nobel) 2 Glyceryl stearate (Imwitor 960K, Sasol Wax) 2 Stearyl alcohol (Lanette 18, Cognis) 2 Polyisobutenes (Permethyl-104A, Chesham Chemicals) 1 Phenoxyethanol (and) methylparaben (and) butylparaben (and) ethylparaben (and) propylparaben (and) isobutylparaben (Phenonip, Clariant) 1.2 PVP polyvinylpyrrolidone (Luviskol K30 Powder, BASF) 4 Carnauba wax (Ewacera 34, Wagner) 4

Preparation: A is mixed, B is mixed and added to A, C is added to AB and heated to 75 ° C. D is premixed separately and heated to 75 ° C and added to ABC, while cooling is stirred. Creamy Shadow Stick Components INCI Name (trade name, manufacturer) Wt .-% A CETIOL ^® CC 38.5 PPG-3 myristyl ether (Varonic APM, Evonik, Degussa) 7.0 Polyglyceryl-4-isostearate (and) cetyl PEG-PPG-10/1 dimethicone (and) hexyl laurate (Abil WE 09, Evonik, Degussa) 1.0 Dimethicone, 10 mPas 2.5 Cera alba (bees wax) 4.5 Copernicia cerifera (carnauba) wax 4.0 Ethylene / VA copolymer (AC copolymer 400, Honeywell) 2.5 ozocerites 5.8 C16-C36 acid triglycerides 2.0 Isobutylparaben (and) isopropylparaben (and) butylparaben (Liquipar Oil, From Nature with Love) 0.5 B Nylon-12 (egolon 12-10, Evonik, Degussa 2.0 Titanium dioxide 5.0 Chromium oxide green 10.00 CI 77491 (and) aluminum powder (and) silica 5.0 CI 77891 (and) CI 77288 (and) mica 10.0 Waterproof mascara Components INCI Name (trade name, manufacturer) Wt .-% A water 32.84 Magnesium aluminum silicate (Veegum HV, RT Vanderbilt) 0.10 Xanthan gum (Keltrol 1000, Kelco Corp.) 0.20 methylparaben 0.25 Trisodium EDTA (Protacid Na3 EDTA, Protameen) 0.01 Premixed sodium acrylates / acrylnitrogens copolymer (Hydrilien 9, 2.5% gel Lio - see below) 15.00 B Glycerol (and) polyester 5 (Lipo PE Base G-55, Lipo) 12,00 Talc (Rose Talc, Prespersa) 3.00 Iron oxide (CI 77499) (Iron Oxide Black, Ultra Chemical) 9.00 C Triethanolamine, 99% 1.00 D Synthetic bees wax (Lipobee 102, Lipo) 10.00 Copernicia cerifera (carnauba) wax 4.50 CETIOL ^® CC 5.50 C12-C16 alkyl benzoate (Liponate NEB, Lipo) 1.00 Stearic acid (Lipo Stearic Acid, Lipo) 3.00 Sorbitan sesquioleate (Liposorb SQO, Lipo) 1.30 Propylparaben 0.20 e Water (aqua) 1.00 Imidazolidine urea (Leposerve IU, Lipo 0.10

production: The ingredients of phase A are mixed and heated to 70 ° C heated, phase A is ground in a colloid mill, the Phase B ingredients are added in the order given while constantly grinding until the pigment is even is dispersed, then phase C is added. The parts of C are mixed and mixed at 80-84 ° C (and vented). Phase D is given as an approach and emulsified, the batch is cooled to 35 ° C and the premixed phase E is added. At 30 ° C the batch is filled into suitable containers.

Sodium acrylates / acrylnitrogens copolymer premix: 97.50% by weight of water and 2.5% by weight of sodium acrylate / acrylonitrile copolymer are mixed and heated to 78-80 ° C. with stirring. It is run for 15 to 20 minutes until the solution is clear and homogeneous. Thereafter, it is cooled to room temperature. Sebum resistant eyeshadow Components INCI Name (trade name, manufacturer) Wt .-% A Stearyl dimethicone (DC 2503 Cosmetic Wax, Dow Corning) 10.00 C30-C45 alkyl methicone (and) C30-C45 olefin (DC AMS-C30 Cosmetic Wax, Dow Corning) 5.00 Isododecane (and) arcylates / polytrimethylsiloxymethacrylate (DC FA 4002 ID Silicaone Acrylate, Dow Corning) 10.00 Cyclopentasiloxanes (and) trimethylsiloxymethacrylates (DC 749 Fluid, Dow Corning) 51.00 B Cyclopentasiloxane (and) dimethicone crosspolymers (DC 9040 Silcone Elastomer Blend, Dow Corning) 5.00 CETIOL ^® CC 3 C Silica silylates (DC VM-2270 Airgel Fine Particles, Dow Corning) 1.00 Mica 15.00

Preparation: The components of phase A are mixed and heated to 80 ° C, cooled with stirring. Phase B is mixed and added with stirring to phase A, C is added with slow stirring. lipstick ingredient INCI name Wt .-% I cerilla Candellila wax 9:00 Cerewax Microcristallina wax 3:50 Cerozo Ozokerite wax 2:50 Cerauba Carnauba wax 2:50 Cetiol MM Myristyl Mysristate 5:00 Eutanol ^® G octyldodecanol 10:00 Myritol ^® 331 Cocoglycerides 5:00 Cetiol ^® CC Dicaprylyl carbonates 8:00 Cetiol ^® J600 Oleyl erucate 1:00 Nipasol M Propyl paraben 12:50 Lame Soft ^® TGI Polyglyceryl-3 diisostearate 3:00 Cetiol ^® Sensoft Propylheptyl Caprylate 6:00 am II COD 8008 CI 77981 2.70 COD 8001 CI 15850 12.90 COD 8010 CI 15985 2.80 COD 8002 CI 15850 1:40 COD 8007 CI 42090 12:20 Ricinus Oil Codex Ricinus Communis 20.60 III Fragance Astral 112 445 B 12:40 Irwinol ^® LS 9319 Octyldodecanol & Irvingia Gabonesis & Hydrogenated Coco-Glycerides 2:50 Coviox ^® T70C tocopherol 12:50 lip care ingredient INCI name Wt .-% I Polybutenes M100 polybutenes 53.50 Cetiol ^® Sensoft Propylheptyl Caprylate 10:00 CETIOL ^® CC 5:00 Isopropyl palmitate Isopropyl palmitate 8:00 pm Cosmedia ^® DC Hydrogenated Dimer Dilinoleyl Dimethyl Carbonate Copolymer 5:00 Red 28 Lake Red 28 Lake 12:05 Perfume Fruits Rouges 12:30 Coviox ^® T70C tocopherol 12:10 Nipasol M Propylparaben 12:50 II Aerosil R972 Silica dimethyl silylates 30.5 III Ronastar Noble Spars Calcium Aluminum Borosilicate (and) Silica (and) Titanium Dioxide 12:25 Viscosity (mPa · s): Brookfield RVT, Spindle 5, Speed 10 11 000 O / W Liquid Foundation ingredient INCI name Wt .-% I Deionized Water Aqua 50.50 Butylene glycol Butylene glycol 2:00 glycerin glycerin 3:00 II Veegum Ultra Magnesium Aluminum Silicate 1:00 Keltrol T. Xanthan gum 12:40 111 Lame form TGI ^® Polyglyceryl-3 diisostearate 1:50 Eumulgin ^® B2 Ceteareth-20 3:50 Cutina ^® PES Pentaerythrityl distearate 1:00 Cegesoft ^® SH Shorea Stenoptera 1:00 Cetiol ^® CC Dicaprylyl carbonates 6:00 am Myritol ^® 331 Cocoglycerides 4:00 Fitoderm ^® Squalane 3:00 Cetiol ^® Sensoft Propylheptyl Caprylate 5:00 Phenonip Phenoxyethanol (and) Parabens 0.80 IV Sun Croma C47-051 Titanium dioxides 6:00 am SunPuro Yellow Iron Oxide C33-9001 Iron Oxide CI 77492 1.30 SunPuro Red Iron Oxide C33-8001 Iron Oxide CI 77491 0.60 SunPuro Black Iron Oxide C33-7001 Iron Oxide CI 77499 12:20 V Cosmedia ^® Gel CC Dicaprylyl Carbonate (and) Stearalkonium Hectorite (and) Propylene Carbonate 3:00 VI Micropearl M100 polymethyl methacrylates 2:00 VII Mirasil CDPDM Cyclomethicone (and) diphenyldimethicone 3:00 VIII Perfume Caresse 12:20 Viscosity (mPa · s): Brk. RVT spindle 5, speed 10 5 500, pH 7.3 attachment 1) Abil ^® EM 90 INCI: Carbomer INCI: cetyl dimethicone copolyol Manufacturer: Noveon, Inc. Manufacturer: Tego Cosmetics (Goldschmidt) 12) Carbopol ^® Ultrez 10 INCI: Carbomer 2) Allianz ^® OPT Manufacturer: Noveon, Inc. INCI: Acrylates / C12-22 alkyl Methacrylate copolymer 13) Cegesoft ^® C 17 Manufacturer: Rohm and Haas INCI: myristyl lactate Manufacturer: Cognis Germany 3) Amphisol ^® K GmbH, Grünau INCI: Potassium Cetyl Phosphate Manufacturer: Hoffmann La Roche 14) Cegesoft ^® PFO INCI: Passiflora Incarnata (EU) 4) Antaron V 220 ^® Manufacturer: Cognis Germany INCI: PVP / eicosene copolymer GmbH Manufacturer: GAF General Anilin Firm Corp. (IPS Global) 15) Cegesoft ^® PS 6 INCI: Olus 5) Antaron V 216 ^® Manufacturer: Cognis Germany INCI: PVP / hexadecenes copolymer GmbH Manufacturer: GAF General Aniline Firm Corp. (IPS Global) 16) Ceraphyl ^® 45 INCI: diethylhexyl malate 6) Arlacel ^® 83 Manufacturer: International Specialty INCI: Sorbitan Sesquioleate Products Manufacturer: Uniqema (ICI Surfacants) 17) Cetiol ^® 868 7) Arlacel ^® P 135 INCI: ethylhexyl stearate INCI: PEG-30 dipolyhydroxystearates Manufacturer: Cognis Germany Manufacturer: Uniqema (ICI Surfacants) GmbH 8) Bentone ^® 38 18) Cetiol ^® A INCI: Quaternium-18 hectorite INCI: Hexyl Laurate Manufacturer: Rheox (Elementis Manufacturer: Cognis Germany Specialties) GmbH 9) Carbopol ^® 980 19) Cetiol ^® B INCI: Carbomer INCI: dibutyl adipate Manufacturer: Goodrich Manufacturer: Cognis Germany GmbH 10) Carbopol ^® 2984 INCI: Carbomer 20) Cetiol ^® CC Manufacturer: Noveon, Inc. INCI: dicaprylyl carbonates Manufacturer: Cognis Germany 11) Carbopol ^® ETD 2001 GmbH 21) Cetiol ^® J 600 30) Cosmedia® ^® DC INCI: Oleyl Erucate INCI: Hydrogenated Dimer Manufacturer: Cognis Germany Dilinoleyl / dimethyl carbonates GmbH copolymer Manufacturer: Cognis Germany 22) Cetiol ^® LC GmbH INCI: Coco-Caprylate / Caprate Manufacturer: Cognis Germany 31) Cosmedia ^® SP GmbH INCI: sodium polyacrylate Manufacturer: Cognis Germany 23) Cetiol OE ^® GmbH INCI: dicaprylyl ether Manufacturer: Cognis Germany 32) Cutina ^® E 24 GmbH INCI: PEG-20 Glyceryl Stearate Manufacturer: Cognis Germany 24) Cetiol ^® PGL GmbH INCI: hexyldecanol, hexyldecyl Laurate 33) Cutina ^® HR Manufacturer: Cognis Germany INCI: Hydrogenated Castor Oil GmbH Manufacturer: Cognis Germany GmbH 25) Cetiol ^® S INCI: Diethylhexylcyclohexanes 34) Cutina ^® MD Manufacturer: Cognis Germany INCI: Glyceryl Stearate GmbH Manufacturer: Cognis Germany GmbH 26) Cetiol ^® SB 45 INCI: Shea Butter Butyrospermum Parkii (Linne) 35) Cuitina ^® PES Manufacturer: Cognis Germany INCI: pentaerythrityl distearate GmbH Manufacturer: Cognis Germany GmbH 27) Cetiol ^® SN INCI: Cetearyl Isononanoate 36) Dehymuls FCE ^® Manufacturer: Cognis Germany INCI: dicocoyl pentaerythrityl GmbH Distearyl citrate Manufacturer: Cognis Germany 28) Copherol ^® F 1300 C GmbH INCI: tocopherol Manufacturer: Cognis Germany 37) Dehymuls ^® HRE 7 GmbH INCI: PEG-7 Hydrogenated Castor Oil 29) Copherol 1250C Manufacturer: Cognis Germany INCI: tocopheryl acetate GmbH Manufacturer: Cognis Germany GmbH 38) Dehymuls ^® PGPH INCI: polyglyceryl-2 Dipolyhydroxystearate Manufacturer: Cognis Germany 48) Emulgade SE-PF ^® GmbH INCI: Glyceryl Stearate (and) Ceteareth-20 (and) Ceteareth-12 39) Dow ^Corning® 244 Fluid (and) cetearyl alcohol (and) cetyl INCI: Cyclomethicone Palmitate Manufacturer: Dow Corning Manufacturer: Cognis Germany GmbH 40) Dow ^Corning® 246 Fluid INCI: Cyclopentasiloxane 49) Emulgade ^® Sucro Manufacturer: Dow Corning INCI: sucrose polystearate (and) Hydrogenated polyisobutenes 41) Dow ^Corning® 2502 Manufacturer: Cognis Germany INCI: cetyl dimethicone GmbH Manufacturer: Dow Corning 50) Eumulgin ^® B1 42) Dry Flo Plus INCI: Ceteareth-12 INCI: Aluminum Starch Manufacturer: Cognis Germany G Octenylsuccinate mbH Manufacturer: National Starch 51) Eumulgin ^® B 2 43) Elfacos ^® ST 37 INCI: Ceteareth-20 INCI: PEG-22 dodecyl glycol Manufacturer: Cognis Germany copolymer GmbH Manufacturer: Akzo-Nobel 52) Eumulgin ^® HRE 40 44) Elfacos ST 9 ^® INCI: PEG-40 Hydrogenated Castor INCI: PEG-45 dodecyl glycol Oil copolymer Manufacturer: Cognis Germany Manufacturer: Akzo-Nobel GmbH 45) ^Emery® 1780 53) Eumulgin ^® SG INCI: Lanolin Alcohol INCI: Sodium Stearoyl Glutamate Manufacturer: Cognis Corporation Manufacturer: Cognis Germany (Emery) GmbH 46) Emulgade CM ^® 54) Eumulgin ^® VL 75 INCI: Cetearyl Isononanoate and INCI: Lauryl Glucoside (and) Ceteareth-20 and Cetearyl Polyglyceryl-2 Alcohol and Glyceryl Stearate Dipolyhydroxystearates (and) and glycerol and ceteareth-12 glycerin and Cetyl Palmitate Manufacturer: Cognis Germany Manufacturer: Cognis Germany GmbH GmbH 55) Eusolex ^® OCR 47) Emulgade PL 68/50 ^® INCI: Octocrylene INCI: Cetearyl Glucoside, Cetearyl Manufacturer: Merck Alcohol Manufacturer: Cognis Germany 56) Eusolex ^® T 2000 GmbH INCI: Titanium Dioxide, Alumina, 65) Hostaphat KL 340 N ^® simethicone INCI: Trilaureth-4 Phosphates Manufacturer: Merck Manufacturer: Clariant 57) Eusolex ^® T AQUA 66) Hydagen CAT ^® INCI: Water and Titanium Dioxide INCI Triethyl Citrate and Alumina and Sodium Manufacturer: Cognis Germany Metaphosphates and GmbH Phenoxyethanol and Sodium methylparaben 67) Hydagen ^® DCMF Manufacturer: Merck INCI: Chitosan Manufacturer: Cognis Germany 58) Eutanol ^® G GmbH INCI: octyl dodecanol Manufacturer: Cognis Germany 68) ^® Insect Repellent 3535 GmbH INCI: Ethyl Butylacetylaminopropionate 59) Eutanol ^® G 16 Manufacturer: EMD Chemicals Inc INCI: hexyldecanol Manufacturer: Cognis Germany 69) Isolani ^® PDI GmbH INCI: Diisostearoyl polyglyceryl-3 Diisostearate 60) Eutanol ^® G 16 S Manufacturer: Goldschmidt AG INCI: hexyldecyl stearate Manufacturer: Cognis Germany 70) Keltrol ^® T GmbH INCI: Xanthan gum Manufacturer: CP Kelco 61) Finsolv TN ^® INCI: C 12/15 alkyl benzoates 71) Lameform ^® TGI Manufacturer: Findex INCI: polyglyceryl-3 diisostearate (Nordmann / Rassmann) Manufacturer: Cognis Germany GmbH 62) Generol ^® R INCI: Brassica Campestris (Rapeseed) 72) Lanette ^® 14 Sterols INCI: myristyl alcohol Manufacturer: Cognis Germany Manufacturer: Cognis Germany GmbH GmbH 63) Glucate DO ^® 73) Lanette 18 INCI: Methyl glucose dioleate INCI: stearyl alcohol Manufacturer: NRC Manufacturer: Cognis Germany Nordmann / Rassmann GmbH 64) Hispagel 200 ^® 74) Lanette ^® 22 INCI: glycerine, glyceryl INCI: Behenyl Alcohol polyacrylates Manufacturer: Cognis Germany Manufacturer: Cognis Germany GmbH GmbH 75) Lanette ^® E INCI: Disodium phenyl INCI: Sodium Cetearyl Sulfate Dibenzimidazole tetrasulfonates Manufacturer: Cognis Germany Manufacturer: Symrise GmbH 86) Neo Heliopa ^® AV 76) Lanette ^® O INCI: ethylhexyl methoxycinnamate INCI: Cetearyl Alcohol Manufacturer: Symrise Manufacturer: Cognis Germany GmbH 87) Neo Heliopan ^® BB INCI: Benzophenone-3 77) Locron ^® L Manufacturer: Symrise INCI: Aluminum Chlorhydrates Manufacturer: Clariant 88) Neo Heliopan ^® E 1000 INCI: isoamyl-p-methoxycinnamate 78) Lucentite SAN ^® Manufacturer: Symrise INCI: Quaternium-18 hectorite Manufacturer: Co-Op Chemical Co., Ltd. 89) Neo Heliopan ^® Hydro INCI: phenylbenzimidazole sulfonic 79) Monomuls 90-O ^® 18 acid INCI: Glyceryl Oleate Manufacturer: Symrise Manufacturer: Cognis Germany GmbH 90) Neo Heliopan ^® MBC INCI: 4-methylbenzylidene camphor 80) Myrj ^® 51 Manufacturer: Symrise INCI: PEG-30 Sterates Manufacturer: Uniqema 91) Neo Heliopan OS ^® INCI: ethylhexyl salicylates 81) Myritol ^® 312 Manufacturer: Symrise INCI: Caprylic / Capric Triglycerides Manufacturer: Cognis Germany 92) Novata ^® AB GmbH INCI: Cocoglycerides Manufacturer: Cognis Germany 82) myritol ^® 331 GmbH INCI: Cocoglycerides Manufacturer: Cognis Germany 93) Parsol ^® 1789 GmbH INCI: Butyl methoxydibenzoylmethane 83) Myritol ^® PC Manufacturer: Hoffmann-La Roche INCI: Propylene glycol (Givaudan) Dicaprylate / dicaprate Manufacturer: Cognis Germany 94) Pemulen ^® TR-2 Polymer GmbH INCI: Acrylates / C10-30 Alkyl acrylate crosspolymer 84) Neo Heliopan ^® 303 Manufacturer: Noveon, Inc. INCI: Octocrylene Manufacturer: Symrise 95) Photonyl ^® LS INCI: arginine, disodium adenosine 85) Neo Heliopan ^® AP Triphosphates, mannitol, pyridoxines HCL, phenylalanine, tyrosine Manufacturer: Laboratoires Manufacturer: Ciba Specialty Chemicals Serobiologiques (Cognis) Corporation 96) Prisorine 3505 ^® 106) Tween ^® 60 INCI: Isostearic Acid INCI: Polysorbate 60 Manufacturer: Uniqema Manufacturer: Uniqema (ICI Surfactants) 97) Prisorine ^® 3758 107) Uvasorb HEB ^® INCI: Hydrogenated polyisobutenes INCI: diethylhexyl butamido Manufacturer: Uniqema Triazone Manufacturer: 3V Inc. 98) Rezal 36G INCI: Aluminum zirconium 108) Unirep ^® U-18 Tetrachlorohydrex GLY INCI: Dimethyl Phthalate and Manufacturer: Reheis, Inc Diethyl Toluamides and Ethyl Hexanediol 99) SFE ^® 839 Manufacturer: Induchem AG INCI: Cyclopentasiloxanes and Dimethicone / Vinyl Dimethicone 109) Uvinul ^® T 150 Crosspolymer INCI: ethylhexyl triazone Manufacturer: GE Silicones Manufacturer: BASF 100) Silicone oil Wacker AK ^® 350 110) Uvinul ^® A plus INCI: Dimethicone INCI: diethylamino hydroxybenzoyl Manufacturer: Wacker Hexyl benzoates Manufacturer: BASF 101) Tego ^® Care 450 INCI: polyglyceryl-3 methylglucose 111) Veegum ^® Ultra Distearate INCI: magnesium aluminum Manufacturer: Tego Cosmetics Silicate (Goldschmidt) Manufacturer: RT Vanderbilt Company, Inc 102) Tego ^® Care CG 90 INCI: Cetearyl Glucosides 112) Veegum ^® Plus Manufacturer: Goldschmidt INCI: Magnesium Aluminum Silicates and cellulose gum 103) Tegosoft ^® DEC Manufacturer: RT Vanderbilt INCI: diethylhexyl carbonates Company, Inc Manufacturer: Goldschmidt 113) Z- ^Cote® HP 1 104) Tinosorb ^® S INCI: zinc oxide and triethoxy INCI: bis-ethylhexyloxyphenol caprylylsilane Methoxyphenyl triazines Manufacturer: BASF Manufacturer: Ciba Specialty Chemicals Corporation 114) Zinc oxides NDM INCI: Zinc Oxide 105) Tinosorb M ^® Hersteler: Symrise INCI: Methylene bis-benzotriazolyl Tetramethylbutylphenol

QUOTES INCLUDE IN THE DESCRIPTION

This list The documents listed by the applicant have been automated generated and is solely for better information recorded by the reader. The list is not part of the German Patent or utility model application. The DPMA takes over no liability for any errors or omissions.

Cited patent literature

• EP 0693471 B1 [0023]
• EP 0818450 A1 [0023]
• EP 0694521 B1 [0023]
• - DE 19712033 A1 [0025]
• - EP 1371359 A2 [0057]
• - EP 766661 B1 [0071]
• WO 07/048757 [0131]

Cited non-patent literature

• Chem. Rev. 96, 951 (1996) [0005]
• - version Commission Directive 2005/9 / EC of 28 January 2005 amending Council Directive 76/768 / EEC, concerning cosmetic products, for the purposes of adapting Annexes VII thereof to technical progress [0027]
• P.Finkel in SÖFW Journal 122, 8/1996, pp. 543-548 and Parf.Kosm. Volume 80, No. 3/1999, pp. 10 to 16 [0028]
• - DIN 55944: 2003-11 [0051]
• - DIN 55943: 2001-10 [0051]
• - DIN 55944: 2003-11 [0051]
• - DIN 55944: 1990-04 [0053]
• - Commission Directive 2007/22 / EC of 17 April 2007 amending Council Directive 76/768 / EEC, concerning cosmetic products, for the purposes of adapting Annexes IV and VI to technical progress [0058]
• - HP Fiedler, Encyclopedia of excipients for pharmacy, cosmetics and related fields, Editio Cantor Verlag, Aulendorf, 4th edition 1996 [0067]
• Kirk-Othmer, "Encyclopedia of Chemical Technology", 3rd Ed., 1979, Volume 8, page 913 [0073]
• - Version Commission Directive 2007/22 / EC of 17 April 2007 amending Council Directive 76/768 / EEC, concerning cosmetic products, for the purposes of adapting Annexes IV and VI to technical progress [0132]

Claims (7)

Cosmetic and / or pharmaceutical preparations containing dialkyl carbonates of the formula (I),

in which R ^{1 is} a linear alkyl and / or alkenyl radical having 6 to 22 carbon atoms, a 2-ethylhexyl, isotridecyl or isostearyl radical or a radical derived from a polyol having 2 to 15 carbon atoms and at least two hydroxyl groups, R ^{2 is} R ¹ or an alkyl radical having 1 to 5 carbon atoms and n and m are independently 0 or numbers from 1 to 100. Cosmetic and / or pharmaceutical preparation according to claim 1, containing at least one antiperspirant / deodorant Active ingredient. Cosmetic and / or pharmaceutical preparation according to one of claims 1 and / or 2, containing at least a UV sunscreen filter. Cosmetic and / or pharmaceutical preparations according to any one of claims 1 to 3, containing at least a self-tanner. Cosmetic and / or pharmaceutical preparations according to any one of claims 1 to 4, containing at least a pigment and / or dye. Cosmetic and / or pharmaceutical preparations according to any one of claims 1 to 5, containing at least an emulsifier and / or a surfactant and / or a wax component and / or a polymer and / or another oil body. Cosmetic and / or pharmaceutical preparations according to one of claims 1 to 6, characterized that they contain as dialkyl carbonate di-n-octyl carbonate.