DE102006010208A1 - Drug combinations with insecticidal and acaricidal properties - Google Patents

Abstract

The new active ingredient combinations of certain cyclic ketoenols of the formula (I), $ F1 in which A, B, D, G, W, X, Y and Z have the meanings listed in the description, and / or tetronic acid derivatives of the formula (II), $ F2 in which A ', B', G ', X', Y ', Z' and n 'have the meanings listed in the description, and phthalic acid diamides of the formula (III), $ F3 in which Hal stands for chlorine, bromine or Iodine, * a carbon atom in the R or S configuration, preferably in the S configuration, indicates, have very good insecticidal and acaricidal properties.

Description

The The present invention relates to novel drug combinations which from at least one known compound from the class of tetronics or tetramic acids on the one hand and at least one other known active ingredient the class of phthalic diamides on the other hand exist and very well for the control of animal pests like insects and unwanted Acarids are suitable.

From 3-Acyl-pynolidine-2,4-diones are described above pharmaceutical properties (Suzuki, S., et al., Chem. Pharm. Bull. 15 1120 (1967)). Farther were N-phenylpyrolidine-2,4-diones from R. Schmierer and H. Mildenberger (Liebigs Ann. Chem. 1985, 1095). A biological Effectiveness of these compounds has not been described.

In EP-A-0 262 399 and GB-A-2 266 888 are similarly structured compounds (3-aryl-pyrrolidine-2,4-diones), of which, however, none herbicidal, insecticidal or acaricidal activity has become known. Known to have herbicidal, insecticidal or acaricidal activity unsubstituted, bicyclic 3-aryl-pynolidine-2,4-dione derivatives (EP-A-355 599, EP-A-415 211 and JP-A-12-053 670) as well as substituted ones monocyclic 3-aryl-pynolidine-2,4-dione derivatives (EP-A-377 893 and EP-A-442 077).

Farther polycyclic 3-arylpyrrolidine-2,4-dione derivatives are known (EP-A-442 073) and 1H-arylpyrolidinedione derivatives (EP-A-456 063, EP-A-521 334, EP-A-596 298, EP-A-613 884, EP-A-613 885, WO 95/01 997, WO 95/26 954, WO 95/20 572, EP-A-0 668 267, WO 96/25 395, WO 96/35 664, WO 97/01 535, WO 97/02 243, WO 97/36 868, WO 97/43275, WO 98/05638, WO 98/06721, WO 98/25928, WO 99/16748, WO 99/24437, WO 99/43649, WO 99/48869 and WO 99/55673, WO 01/17972, WO 01/23354, WO 01/74770, WO 03/013249, WO 04/007448, WO 04/024688, WO 04/065366, WO 04/080962, WO 04/111042, WO 05/044791, WO 05/044796, WO 05/048710, WO 05/049596, WO 05/066125, WO 05/092897.

It is known that certain substituted Δ ³ -dihydrofuran-2-one derivatives have herbicidal properties (cf DE-A-4 014 420). The synthesis of the tetronic acid derivatives used as starting compounds (such as 3- (2-methyl-phenyl) -4-hydroxy-5- (4-fluorophenyl) -Δ ³ -dihydrofuranone (2)) is also disclosed in DE-A-4014 420 described. Similarly structured compounds without indication of an insecticidal and / or acaricidal activity are known from the publication Campbell et al., J. Chem. Soc., Perkin Trans. 1, 1985, (8) 1567-76. Furthermore, 3-aryl-Δ ³ -dihydrofuranone derivatives having herbicidal, acaricidal and insecticidal properties are known from EP-A-528 156, EP-A-0 647 637, WO 95/26 345, WO 96/20 196, WO 96 / 25 395, WO 96/35 664, WO 97/01 535, WO 97/02 243, WO 97/36 868, WO 98/05638, WO 98/25928, WO 99/16748, WO 99/43649, WO 99 / 48869, WO 99/55673, WO 01/17972, WO 01/23354 and WO 01/74770, WO 03/013 249, WO 04/024 688, WO 04/080 962, WO 04/111 042. 3-Aryl-Δ ³ -dihydro-thiophenone derivatives are also known (WO 95/26 345, 96/25 395, WO 97/01 535, WO 97/02 243, WO 97/36 868, WO 98/05638, WO 98/25928, WO 99/16748, WO 99/43649, WO 99/48869, WO 99/55673, WO 01/17972, WO 01/23354, WO 01/74770, WO 03/013249, WO 04/080 962 WO 04/111 042, WO 05/092897).

Certain, in the phenyl ring unsubstituted phenyl-pyrone derivatives are already (A.M. Chirazi, T. Kappe and E. Ziegler, Arch. Pharm. 309, 558 (1976) and K.-H. Boltze and K. Heidenbluth, Chem. Ber. 91, 2849), wherein for these connections a possible Availability as pesticide is not specified. In the phenyl ring substituted phenylpyrone derivatives with herbicidal, acaricidal and insecticidal properties are in EP-A-588 137, WO 96/25 395, WO 96/35 664, WO 97/01 535, WO 97/02 243, WO 97/16 436, WO 97/19 941, WO 97/36 868, WO 98/05638, WO 99/43649, WO 99/48869, WO 99/55673, WO 01/17972, WO 01/74770, WO 03/013249, WO 04/080 962, WO 04/111 042.

Certain, in the phenyl ring unsubstituted 5-phenyl-1,3-thiazine derivatives are already known (see E. Ziegler and E. Steiner, Monatsh. 95, 147 (1964), R. Ketcham, T. Kappe and E. Ziegler, J. Heterocycl. Chem. 10, 223 (1973)), wherein for these connections a possible Application as pesticide is not specified. In the phenyl ring substituted 5-phenyl-1,3-thiazine derivatives with herbicidal, acaricidal and insecticidal activity are described in WO 94/14 785, WO 96/02 539, WO 96/35 664, WO 97/01 535, WO 97/02 243, WO 97/02 243, WO 97/36868, WO 99/05638, WO 99/43649, WO 99/48869, WO 99/55673, WO 01/17972, WO 01/74770, WO 03/013249, WO 04/080 962, WO 04/111 042.

It is known that certain substituted 2-arylcyclopentanediones possess herbicidal, insecticidal and acaricidal properties (cf., for example, US Pat. Nos. 4,283,348, 4,338,122, 4,436,666, 4,526,723, 4,551,547, 4,632,698, WO 96 / 01 798, WO 96/03 366, WO 97/14 667 and WO 98/39281, WO 99/43649, WO 99/48869, WO 99/55673, WO 01/17972, WO 01/74770, WO 03/013249, WO 04/080 962, WO 04/111 042). Besides, they are similar substituted compounds known; 3-Hydroxy-5,5-dimethyl-2-phenyl-cyclopent-2-en-1-one from the publication Micklefield et al., Tetrahedron, (1992), 7519-26 and the natural product Involutin (-) - cis-5 (3,4-dihydroxyphenyl) -3,4-dihydroxy-2- (4-hydroxyphenyl) -cyclopent-2-en-one from Edwards et al., J. Chem. Soc. S, (1967), 405-9. An insecticidal or acaricidal action is not described. In addition, 2- (2,4,6-trimethylphenyl) -1,3-indandione from the publication J. Economic Entomology, 66, (1973), 584 and the published patent application DE-A 2 361 084 is known, with indication of herbicidal and acaricidal effects.

It It is known that certain substituted 2-arylcyclohexanediones have herbicidal, insecticidal and acaricidal properties (US-4 175,135, 4,209,432, 4,256,657, 4,256,658, 4,256,659, 4,257,858, 4,283,348, 4,303,669, 4,351,666, 4,409,153, 4,436,666, 4,526,723, 4,613,617, 4,659,372, DE-A 2,813,341 and Wheeler, T.N., J. Org. Chem. 44, 4906 (1979)), WO 99/43649, WO 99/48869, WO 99/55673, WO 01/17972, WO 01/74770, WO 03/013249, WO 04/080 962, WO 04/111 042).

It It is known that certain substituted 4-aryl-pyrazolidine-3,5-diones have acaricidal, insecticidal and herbicidal properties (cf. e.g. WO 92/16510, EP-A-508 126, WO 96/11 574, WO 96/21 652, WO 99/47525, WO 01/17351, WO 01/17352, WO 01/17353, WO 01/17972, WO 01/17 973, WO 03/028 466, WO 03/062 244, WO 04/080 962, WO 04/111 042, WO 05/005428, WO 05/016873).

It It is known that certain tetrahydropyridones have herbicidal properties own: JP-A-0 832 530. Also are special 4-hydroxytetrahydropyridones with acaricidal, insecticidal and herbicidal properties: JP-A-11 152 273. Further 4-hydroxy-tetrahydropyridones were used as pesticides and herbicides in WO 01/79204.

It It is also known that certain 5,6-dihydropyrone derivatives as protease inhibitors have antiviral properties: WO 95/14012. Furthermore, this is 4-phenyl-6- (2-phenethyl) -5,6-dihydropyron from the synthesis of kawalactone derivatives Known: Kappe et al., Arch. Pharm. 309, 558-64 (1976). In addition, 5,6-dihydropyrone derivatives known as intermediates: White, J.D., Brenner, J.B., Deinsdale, M.J., J. Amer. Chem. Soc. 93, 281-2 (1971). 3-phenyl-5,6-dihydropyrone derivatives with applications as crop protection agents are described in WO 01/98288.

It it is also already known that phthalic diamides of the formula (III) have insecticidal activity. This applies to the racemic form of the compounds (EP-A 1 006 107) and in even higher Measure of the (S) -configured Enantiomers (unpublished Japanese Patent Application JP 2005-239974).

On the generic formulas and publications described in these publications Definitions as well as the individual compounds described therein is hereby expressly Referenced.

in welcher
X für Halogen, Alkyl, Alkoxy, Halogenalkyl, Halogenalkoxy oder Cyano steht,
W, Y und Z unabhängig voneinander für Wasserstoff, Halogen, Alkyl, Alkoxy, Halogenalkyl, Halogenalkoxy oder Cyano stehen,
A für Wasserstoff, jeweils gegebenenfalls durch Halogen substituiertes Alkyl, Alkoxyalkyl, gesättigtes, gegebenenfalls substituiertes Cycloalkyl steht, in welchem gegebenenfalls mindestens ein Ringatom durch ein Heteroatom ersetzt ist,
B für Wasserstoff oder Alkyl steht,
A und B gemeinsam mit dem Kohlenstoffatom an das sie gebunden sind, für einen gesättigten oder ungesättigten, gegebenenfalls mindestens ein Heteroatom enthaltenden unsubstituierten oder substituierten Cyclus stehen,
D für Wasserstoff oder einen gegebenenfalls substituierten Rest aus der Reihe Alkyl, Alkenyl, Alkoxyalkyl, gesättigtes Cycloalkyl steht, in welchem gegebenenfalls eines oder mehrere Ringglieder durch Heteroatome ersetzt sind,
A und D gemeinsam mit den Atomen an die sie gebunden sind für einen gesättigten oder ungesättigten und gegebenenfalls mindestens ein Heteroatom enthaltenden, im A,D-Teil unsubstituierten oder substituierten Cyclus stehen,
G für Wasserstoff (a) oder für eine der Gruppen

steht,
worin
E für ein Metallion oder ein Ammoniumion steht,
L für Sauerstoff oder Schwefel steht,
M für Sauerstoff oder Schwefel steht,
R¹ für jeweils gegebenenfalls durch Halogen substituiertes Alkyl, Alkenyl, Alkoxyalkyl, Alkylthioalkyl, Polyalkoxyalkyl oder gegebenenfalls durch Halogen, Alkyl oder Alkoxy substituiertes Cycloalkyl, das durch mindestens ein Heteroatom unterbrochen sein kann, jeweils gegebenenfalls substituiertes Phenyl, Phenylalkyl, Hetaryl, Phenoxyalkyl oder Hetaryloxyalkyl steht,
R² für jeweils gegebenenfalls durch Halogen substituiertes Alkyl, Alkenyl, Alkoxyalkyl, Polyalkoxyalkyl oder für jeweils gegebenenfalls substituiertes Cycloalkyl, Phenyl oder Benzyl steht,
R³ für gegebenenfalls durch Halogen substituiertes Alkyl oder gegebenenfalls substituiertes Phenyl steht,
R⁴ und R⁵ unabhängig voneinander für jeweils gegebenenfalls durch Halogen substituiertes Alkyl, Alkoxy, Alkylamino, Dialkylamino, Alkylthio, Alkenylthio, Cycloalkylthio oder für jeweils gegebenenfalls substituiertes Phenyl, Benzyl, Phenoxy oder Phenylthio stehen und
R⁶ und R⁷ unabhängig voneinander für Wasserstoff, jeweils gegebenenfalls durch Halogen substituiertes Alkyl, Cycloalkyl, Alkenyl, Alkoxy, Alkoxyalkyl, für gegebenenfalls substituiertes Phenyl, für gegebenenfalls substituiertes Benzyl oder gemeinsam mit dem N-Atom, an das sie gebunden sind, für einen gegebenenfalls durch Sauerstoff oder Schwefel unterbrochenen gegebenenfalls substituierten Ring stehen
und/oder
mindestens ein Tetronsäurederivat der Formel (II)

in welcher
X' für C₁-C₆-Alkyl, Halogen, C₁-C₆-Alkoxy oder C₁-C₃-Halogenalkyl steht,
Y' für Wasserstoff, C₁-C₆-Alkyl, Halogen, C₁-C₆-Alkoxy, C₁-C₃-Halogenalkyl steht,
Z' für C₁-C₆-Alkyl, Halogen, C₁-C₆-Alkoxy steht,
n' für eine Zahl von 0-3 steht,
A' für Wasserstoff oder jeweils gegebenenfalls durch Halogen substituiertes geradkettiges oder verzweigtes C₁-C₁₂-Alkyl, C₂-C₈-Alkenyl, C₂-C₈-Alkinyl, C₁-C₁₀-Alkoxy-C₁-C₈-alkyl, C₁-C₈-Polyalkoxy-C₂-C₈-alkyl, C₁-C₁₀-Alkylthio-C₂-C₈-alkyl, Cycloalkyl mit 3-8 Ringatomen, das durch Sauerstoff und/oder Schwefel unterbrochen sein kann oder jeweils gegebenenfalls durch Halogen, C₁-C₆-Alkyl, C₁-C₆-Halogenalkyl-, C₁-C₆-Alkoxy-, C₁-C₆-Halogenalkoxy, Nitro substituiertes Phenyl oder Phenyl-C₁-C₆-alkyl steht,
B' für Wasserstoff, C₁-C₆-Alkyl oder C₁-C₆-Alkoxy- C₁-C₄-alkyl steht
oder worin
A' und B' gemeinsam mit dem Kohlenstoffatom, an das sie gebunden sind einen gesättigten oder ungesättigten, gegebenenfalls durch Sauerstoff und/oder Schwefel unterbrochenen und gegebenenfalls durch Halogen, C₁-C₆-Alkyl, C₁-C₆-Alkoxy, C₁-C₄-Halogenalkyl, C₁-C₄-Halogenalkoxy, C₁-C₄-Alkylthio oder gegebenenfalls substituiertes Phenyl substituierten oder gegebenenfalls benzokondensierten 3- bis 8-gliedrigen Ring bilden,
G' für Wasserstoff (a) oder für die Gruppen

in welchen
R^1' für jeweils gegebenenfalls durch Halogen substituiertes C₁-C₂₀-Alkyl, C₂-C₂₀-Alkenyl, C₁-C₈-Alkoxy-C₁-C₈-alkyl, C₁-C₈-Alkylthio-C₁-C₈-alkyl, C₁-C₈-Polyalkoxy-C₂-C₈-alkyl oder Cycloalkyl mit 3-8 Ringatomen, das durch Sauerstoff- und/oder Schwefelatome unterbrochen sein kann, steht,
für gegebenenfalls durch Halogen, Nitro, C₁-C₆-Alkyl, C₁-C₆-Alkoxy, C₁-C₆-Halogenalkyl, C₁-C₆-Halogenalkoxy-substituiertes Phenyl steht;
für gegebenenfalls durch Halogen-, C₁-C₆-Alkyl, C₁-C₆-Alkoxy-, C₁-C₆-Halogenalkyl-, C₁-C₆-Halogenalkoxy-substituiertes Phenyl-C₁-C₆-alkyl steht,
für jeweils gegebenenfalls durch Halogen und/oder C₁-C₆-Alkyl substituiertes Pyridyl, Pyrimidyl, Thiazolyl oder Pyrazolyl steht,
für gegebenenfalls durch Halogen und/oder C₁-C₆-Alkyl-substituiertes Phenoxy-C₁-C₆-alkyl steht,
R^2' für jeweils gegebenenfalls durch Halogen substituiertes C₁-C₂₀-Alkyl, C₂-C₂₀-Alkenyl, C₁-C₈-Alkoxy-C₂-C₈-alkyl oder C₁-C₈-Polyalkoxy-C₂-C₈-alkyl steht,
für jeweils gegebenenfalls durch Halogen, Nitro, C₁-C₆-Alkyl, C₁-C₆-Alkoxy, C₁-C₆-Halogenalkyl-substituiertes Phenyl oder Benzyl steht,
R^3' für gegebenenfalls durch Halogen substituiertes C₁-C₈-Alkyl, für jeweils gegebenenfalls durch C₁-C₄-Alkyl, Halogen, C₁-C₄-Halogenalkyl, C₁-C₄-Alkoxy, C₁-C₄-Halogenalkoxy, Nitro oder Cyano substituiertes Phenyl oder Benzyl steht,
R^4' und R^5' unabhängig voneinander für jeweils gegebenenfalls durch Halogen substituiertes C₁-C₈-Alkyl, C₁-C₈-Alkoxy, C₁-C₈-Alkylamino, Di-(C₁-C₈)-Alkylamino, C₁-C₈-Alkylthio, C₂-C₅-Alkenylthio, C₂-C₅-Alkinylthio, C₃-C₇-Cycloalkylthio, für jeweils gegebenenfalls durch Halogen, Nitro, Cyano, C₁-C₄-Alkoxy, C₁-C₄-Halogenalkoxy, C₁-C₄-Alkylthio, C₁-C₄-Halogenalkylthio, C₁-C₄-Alkyl, C₁-C₄-Halogenalkyl substituiertes Phenyl, Phenoxy oder Phenylthio stehen,
R^6' und R^7' unabhängig voneinander für jeweils gegebenenfalls durch Halogen substituiertes C₁-C₁₀-Alkyl, C₁-C₁₀-Alkoxy, C₃-C₈-Alkenyl, C₁-C₈-Alkoxy-C₁-C₈-alkyl, für gegebenenfalls durch Halogen, C₁-C₆-Halogenalkyl, C₁-C₆-Alkyl oder C₁-C₆-Alkoxy substituiertes Phenyl, für gegebenenfalls durch Halogen, C₁-C₆-Alkyl, C₁-C₆-Halogenalkyl oder C₁-C₆-Alkoxy substituiertes Benzyl steht oder zusammen für einen gegebenenfalls durch Sauerstoff oder Schwefel unterbrochenen 5- bis 6-gliedrigen Ring stehen, der gegebenenfalls durch C₁-C₆-Alkyl substituiert sein kann.
und
mindestens einen Wirkstoff der Formel (III)

wobei
Hal für Chlor, Brom oder Iod steht,
* ein Kohlenstoffatom in der R- oder der S-Konfiguration, bevorzugt in der S-Konfiguration, kennzeichnet,
insektizide und/oder akarizide Wirkung aufweisen. Überraschenderweise ist die insektizide und/oder akarizide Wirkung der erfindungsgemäßen Wirkstoffkombinationen wesentlich höher als die Summe der Wirkungen der einzelnen Wirkstoffe. Es liegt also ein nicht vorhersehbarer, echter synergistischer Effekt vor und nicht nur eine Wirkungsergänzung.It has now been found that mixtures comprising at least one compound of the formula (I)

in which
X is halogen, alkyl, alkoxy, haloalkyl, haloalkoxy or cyano,
W, Y and Z independently of one another represent hydrogen, halogen, alkyl, alkoxy, haloalkyl, haloalkoxy or cyano,
A is hydrogen, in each case optionally halogen-substituted alkyl, alkoxyalkyl, saturated, optionally substituted cycloalkyl in which optionally at least one ring atom is replaced by a heteroatom,
B is hydrogen or alkyl,
A and B, together with the carbon atom to which they are attached, represent a saturated or unsaturated unsubstituted or substituted cycle, optionally containing at least one heteroatom,
D is hydrogen or an optionally substituted radical from the group consisting of alkyl, alkenyl, alkoxyalkyl, saturated cycloalkyl, in which optionally one or more ring members are replaced by heteroatoms,
A and D together with the atoms to which they are bonded represent a saturated or unsaturated and optionally at least one heteroatom-containing, unsubstituted or substituted in the A, D-part cycle,
G is hydrogen (a) or one of the groups

stands,
wherein
E is a metal ion or an ammonium ion,
L is oxygen or sulfur,
M is oxygen or sulfur,
R ^{1 is} in each case optionally halogen-substituted alkyl, alkenyl, alkoxyalkyl, alkylthioalkyl, polyalkoxyalkyl or optionally substituted by halogen, alkyl or alkoxy-substituted cycloalkyl which may be interrupted by at least one heteroatom, each optionally substituted phenyl, phenylalkyl, hetaryl, phenoxyalkyl or hetaryloxyalkyl .
R ^{2 is} in each case optionally halogen-substituted alkyl, alkenyl, alkoxyalkyl, polyalkoxyalkyl or in each case optionally substituted cycloalkyl, phenyl or benzyl,
R ^{3 is} optionally halogen-substituted alkyl or optionally substituted phenyl,
R ⁴ and R ⁵ independently of one another are each optionally halogen-substituted alkyl, alkoxy, alkylamino, dialkylamino, alkylthio, alkenylthio, cycloalkylthio or in each case optionally substituted phenyl, benzyl, phenoxy or phenylthio and
R ⁶ and R ⁷ are each independently hydrogen, in each case optionally halogen-substituted alkyl, cycloalkyl, alkenyl, alkoxy, alkoxyalkyl, optionally substituted phenyl, optionally substituted benzyl or together with the N-atom to which they are attached, for a optionally interrupted by oxygen or sulfur optionally substituted ring
and or
at least one tetronic acid derivative of the formula (II)

in which
X 'is C ₁ -C ₆ -alkyl, halogen, C ₁ -C ₆ -alkoxy or C ₁ -C ₃ -haloalkyl,
Y 'is hydrogen, C ₁ -C ₆ -alkyl, halogen, C ₁ -C ₆ -alkoxy, C ₁ -C ₃ -haloalkyl,
Z 'is C ₁ -C ₆ -alkyl, halogen, C ₁ -C ₆ -alkoxy,
n 'is a number from 0-3,
A 'is hydrogen or in each case optionally halogen-substituted straight-chain or branched C ₁ -C ₁₂ -alkyl, C ₂ -C ₈ -alkenyl, C ₂ -C ₈ -alkynyl, C ₁ -C ₁₀ -alkoxy-C ₁ -C ₈ -alkyl, C ₁ -C ₈ -polyalkoxy-C ₂ -C ₈ -alkyl, C ₁ -C ₁₀ -alkylthio-C ₂ -C ₈ -alkyl, cycloalkyl having 3-8 ring atoms, which is interrupted by oxygen and / or sulfur or may be in each case optionally substituted by halogen, C ₁ -C ₆ alkyl, C ₁ -C ₆ haloalkyl, C ₁ -C ₆ alkoxy, C ₁ -C ₆ haloalkoxy, nitro-substituted phenyl or phenyl-C ₁ -C ₆ -alkyl,
B 'is hydrogen, C ₁ -C ₆ -alkyl or C ₁ -C ₆ -alkoxy-C ₁ -C ₄ -alkyl
or in which
A 'and B' together with the carbon atom to which they are attached are a saturated or unsaturated, optionally interrupted by oxygen and / or sulfur and optionally by halogen, C ₁ -C ₆ alkyl, C ₁ -C ₆ alkoxy, C ₁ -C ₄ haloalkyl, C ₁ -C ₄ -haloalkoxy, C ₁ -C ₄ -alkylthio or optionally substituted phenyl, or substituted optionally benzo-fused 3- to 8-membered ring,
G 'for hydrogen (a) or for the groups

in which
R ^{1 'is} in each case optionally halogen-substituted C ₁ -C ₂₀ -alkyl, C ₂ -C ₂₀ -alkenyl, C ₁ -C ₈ -alkoxy-C ₁ -C ₈ -alkyl, C ₁ -C ₈ -alkylthio-C C ₁ -C ₈ -alkyl, C ₁ -C ₈ -polyalkoxy-C ₂ -C ₈ -alkyl or cycloalkyl having 3-8 ring atoms which may be interrupted by oxygen and / or sulfur atoms,
is optionally substituted by halogen, nitro, C ₁ -C ₆ alkyl, C ₁ -C ₆ alkoxy, C ₁ -C ₆ haloalkyl, C ₁ -C ₆ -haloalkoxy-substituted phenyl;
is optionally substituted by halogen, C ₁ -C ₆ alkyl, C ₁ -C ₆ alkoxy, C ₁ -C ₆ haloalkyl, C ₁ -C ₆ -haloalkoxy-substituted phenyl-C ₁ -C ₆ alkyl stands,
is in each case optionally substituted by halogen and / or C ₁ -C ₆ -alkyl-substituted pyridyl, pyrimidyl, thiazolyl or pyrazolyl,
represents phenoxy-C ₁ -C ₆ -alkyl optionally substituted by halogen and / or C ₁ -C ₆ -alkyl,
R ^{2 'is} in each case optionally halogen-substituted C ₁ -C ₂₀ -alkyl, C ₂ -C ₂₀ -alkenyl, C ₁ -C ₈ -alkoxy-C ₂ -C ₈ -alkyl or C ₁ -C ₈ -polyalkoxy-C C ₂ -C ₈ -alkyl,
is in each case optionally halogen, nitro, C ₁ -C ₆ -alkyl, C ₁ -C ₆ -alkoxy, C ₁ -C ₆ -haloalkyl-substituted phenyl or benzyl,
R ^{3 '} for optionally halogen-substituted C ₁ -C ₈ alkyl, in each case optionally by C ₁ -C ₄ -alkyl, halogen, C ₁ -C ₄ -haloalkyl, C ₁ -C ₄ -alkoxy, C ₁ -C ₄ -haloalkoxy, nitro or cyano substituted phenyl or benzyl,
R ^{4 '} and R ^5' independently of one another are each optionally halogen-substituted C ₁ -C ₈ -alkyl, C ₁ -C ₈ -alkoxy, C ₁ -C ₈ -alkylamino, di- (C ₁ -C ₈ ) -alkylamino C ₁ -C ₈ -alkylthio, C ₂ -C ₅ -alkenylthio, C ₂ -C ₅ -alkynylthio, C ₃ -C ₇ -cycloalkylthio, in each case optionally by halogen, nitro, cyano, C ₁ -C ₄ -alkoxy , C ₁ -C ₄ -haloalkoxy, C ₁ -C ₄ -alkylthio, C ₁ -C ₄ -haloalkylthio, C ₁ -C ₄ -alkyl, C ₁ -C ₄ -haloalkyl-substituted phenyl, phenoxy or phenylthio,
R ^{6 '} and R ^7' independently of one another are each optionally halogen-substituted C ₁ -C ₁₀ -alkyl, C ₁ -C ₁₀ -alkoxy, C ₃ -C ₈ -alkenyl, C ₁ -C ₈ -alkoxy-C ₁ - C ₈ -alkyl, optionally substituted by halogen, C ₁ -C ₆ haloalkyl, C ₁ -C ₆ alkyl or C ₁ -C ₆ alkoxy substituted phenyl, optionally substituted by halogen, C ₁ -C ₆ alkyl, C ₁ -C ₆ haloalkyl or C ₁ -C ₆ -alkoxy-substituted benzyl or together represent an optionally interrupted by oxygen or sulfur, 5- to 6-membered ring, which may optionally be substituted by C ₁ -C ₆ alkyl.
and
at least one active substance of the formula (III)

in which
Hal is chlorine, bromine or iodine,
* denotes a carbon atom in the R or S configuration, preferably in the S configuration,
have insecticidal and / or acaricidal activity. Surprisingly, the insecticidal and / or acaricidal activity of the active compound combinations according to the invention is substantially higher than the sum of the effects of the individual active compounds. So there is an unpredictable, true synergistic effect and not just one Addition of activities.

The Compounds of the formula (I) or (II) can also be used as a function of one another by the nature of the substituents, as geometric and / or optical Isomers or mixtures of isomers, in different compositions, if necessary in the usual Way can be separated. Both the pure isomers and the isomer mixtures whose Production and use as well as agents containing them are subject matter of the present invention. The following is for the sake of simplicity but always spoken of compounds of formula (I) or (II), although both the pure compounds and possibly also mixtures meant with different proportions of isomeric compounds are.

in welchen
E für ein Metallion oder ein Ammoniumion steht,
L für Sauerstoff oder Schwefel steht und
M für Sauerstoff oder Schwefel steht,
R¹ steht bevorzugt für jeweils gegebenenfalls durch Halogen substituiertes C₁-C₁₀-Alkyl, C₂-C₁₀-Alkenyl, C₁-C₄-Alkoxy-C₁-C₄-alkyl, C₁-C₄-Alkylthio-C₁-C₄-alkyl oder gegebenenfalls durch Fluor, Chlor, C₁-C₄-Alkyl oder C₁-C₂-Alkoxy substituiertes C₃-C₆-Cycloalkyl,
für gegebenenfalls durch Fluor, Chlor, Brom, Cyano, Nitro, C₁-C₄-Alkyl, C₁-C₄-Alkoxy, Triflourmethyl oder Triflourmethoxy substituiertes Phenyl,
für jeweils gegebenenfalls durch Chlor oder Methyl substituiertes Pyridyl oder Thienyl,
R² steht bevorzugt für jeweils gegebenenfalls durch Fluor oder Chlor substituiertes C₁-C₁₀-Alkyl, C₂-C₁₀-Alkenyl, C₁-C₄-Alkoxy-C₂-C₄-alkyl,
für gegebenenfalls durch Methyl oder Methoxy substituiertes C₅-C₆-Cycloalkyl oder
für jeweils gegebenenfalls durch Fluor, Chlor, Brom, Cyano, Nitro, C₁-C₄-Alkyl, C₁-C₄-Alkoxy, Trifluormethyl oder Trifluormethoxy substituiertes Phenyl oder Benzyl,
R³ steht bevorzugt für gegebenenfalls durch Fluor substituiertes C₁-C₄-Alkyl oder für gegebenenfalls durch Fluor, Chlor, Brom, C₁-C₄-Alkyl, C₁-C₄-Alkoxy, Trifluormethyl, Trifluormethoxy, Cyano oder Nitro substituiertes Phenyl,
R⁴ steht bevorzugt unabhängig voneinander für jeweils gegebenenfalls durch Fluor oder Chlor substituiertes C₁-C₄-Alkyl, C₁-C₄-Alkoxy, C₁-C₄-Alkylamino, C₁-C₄-Alkylthio oder für jeweils gegebenenfalls durch Fluor, Chlor, Brom, Nitro, Cyano, C₁-C₄-Alkoxy, Trifluormethoxy, C₁-C₄-Alkylthio, C₁-C₄-Halogenalkylthio, C₁-C₄-Alkyl oder Trifluormethyl substituiertes Phenyl, Phenoxy oder Phenylthio,
R⁵ steht bevorzugt für C₁-C₄-Alkoxy oder C₁-C₄-Thioalkyl,
R⁶ steht bevorzugt für C₁-C₆-Alkyl, C₃-C₆-Cycloalkyl, C₁-C₆-Alkoxy, C₃-C₆-Alkenyl, C₁-C₄-Alkoxy-C₁-C₄-alkyl,
R⁷ steht bevorzugt für C₁-C₆-Alkyl, C₃-C₆-Alkenyl oder C₁-C₄-Alkoxy-C₁-C₄-alkyl,
R⁶ und R⁷ stehen zusammen bevorzugt für einen gegebenenfalls durch Methyl oder Ethyl substituierten C₃-C₆-Alkylenrest, in welchem gegebenenfalls ein Kohlenstoffatom durch Sauerstoff oder Schwefel ersetzt ist
und/oder mindestens einen Wirkstoff der Formel (II) und mindestens einen Wirkstoff der Formel (III).Preference is given to active compound combinations comprising compounds of the formula (I) in which the radicals have the following meaning:
W is preferably hydrogen, C ₁ -C ₄ -alkyl, C ₁ -C ₄ -alkoxy, chlorine, bromine or fluorine,
X is preferably C ₁ -C ₄ -alkyl, C ₁ -C ₄ -alkoxy, C ₁ -C ₄ -haloalkyl, fluorine, chlorine or bromine,
Y and Z independently of one another preferably represent hydrogen, C ₁ -C ₄ -alkyl, halogen, C ₁ -C ₄ -alkoxy or C ₁ -C ₄ -haloalkyl,
A is preferably hydrogen or in each case optionally halogen-substituted C ₁ -C ₆ -alkyl or C ₃ -C ₈ -cycloalkyl,
B is preferably hydrogen, methyl or ethyl,
A, B and the carbon atom to which they are attached are preferably saturated C ₃ -C ₆ -cycloalkyl, in which optionally one ring member is replaced by oxygen or sulfur and which is optionally mono- or disubstituted by C ₁ -C ₄ -alkyl, trifluoromethyl or C ₁ -C ₄ -alkoxy is substituted,
D is preferably hydrogen, in each case optionally fluorine- or chlorine-substituted C ₁ -C ₆ -alkyl, C ₃ -C ₄ -alkenyl or C ₃ -C ₆ -cycloalkyl,
A and D together preferably represent optionally methyl-substituted C ₃ -C ₄ alkanediyl, wherein optionally a methylene group is replaced by sulfur.
G is preferably hydrogen (a) or one of the groups

in which
E is a metal ion or an ammonium ion,
L stands for oxygen or sulfur and
M is oxygen or sulfur,
R ¹ preferably represents in each case optionally halogen-substituted C ₁ -C ₁₀ -alkyl, C ₂ -C ₁₀ -alkenyl, C ₁ -C ₄ -alkoxy-C ₁ -C ₄ -alkyl, C ₁ -C ₄ -alkylthio C ₁ -C ₄ -alkyl or C ₃ -C ₆ -cycloalkyl optionally substituted by fluorine, chlorine, C ₁ -C ₄ -alkyl or C ₁ -C ₂ -alkoxy,
optionally substituted by fluorine, chlorine, bromine, cyano, nitro, C ₁ -C ₄ alkyl, C ₁ -C ₄ alkoxy, trifluoromethyl or Triflourmethoxy substituted phenyl,
each optionally substituted by chlorine or methyl substituted pyridyl or thienyl,
R ² preferably represents in each case optionally fluorine- or chlorine-substituted C ₁ -C ₁₀ -alkyl, C ₂ -C ₁₀ -alkenyl, C ₁ -C ₄ -alkoxy-C ₂ -C ₄ -alkyl,
for optionally substituted by methyl or methoxy C ₅ -C ₆ -cycloalkyl or
in each case optionally substituted by fluorine, chlorine, bromine, cyano, nitro, C ₁ -C ₄ alkyl, C ₁ -C ₄ alkoxy, trifluoromethyl or trifluoromethoxy-substituted phenyl or benzyl,
R ³ preferably represents optionally fluorine-substituted C ₁ -C ₄ -alkyl or optionally substituted by fluorine, chlorine, bromine, C ₁ -C ₄ -alkyl, C ₁ -C ₄ -alkoxy, trifluoromethyl, trifluoromethoxy, cyano or nitro phenyl,
R ⁴ is preferably independently of one another in each case optionally substituted by fluorine or chlorine-substituted C ₁ -C ₄ -alkyl, C ₁ -C ₄ -alkoxy, C ₁ -C ₄ -alkylamino, C ₁ -C ₄ -alkylthio or in each case optionally by Fluoro, chloro, bromo, nitro, cyano, C ₁ -C ₄ alkoxy, trifluoromethoxy, C ₁ -C ₄ alkylthio, C ₁ -C ₄ haloalkylthio, C ₁ -C ₄ alkyl or trifluoromethyl-substituted phenyl, phenoxy or phenylthio,
R ⁵ is preferably C ₁ -C ₄ -alkoxy or C ₁ -C ₄ -thioalkyl,
R ⁶ is preferably C ₁ -C ₆ -alkyl, C ₃ -C ₆ -cycloalkyl, C ₁ -C ₆ -alkoxy, C ₃ -C ₆ -alkenyl, C ₁ -C ₄ -alkoxy-C ₁ -C ₄ alkyl,
R ⁷ is preferably C ₁ -C ₆ -alkyl, C ₃ -C ₆ -alkenyl or C ₁ -C ₄ -alkoxy-C ₁ -C ₄ -alkyl,
R ⁶ and R ⁷ together preferably represent an optionally substituted by methyl or ethyl C ₃ -C ₆ alkylene, in which optionally a carbon atom is replaced by oxygen or sulfur
and / or at least one active ingredient of the formula (II) and at least one active ingredient of the formula (III).

in welchen
M für Sauerstoff oder Schwefel steht,
R¹ steht besonders bevorzugt für C₁-C₈-Alkyl, C₂-C₄-Alkenyl, Methoxymethyl, Ethoxymethyl, Ethylthiomethyl, Cyclopropyl, Cyclopentyl oder Cyclohexyl,
für gegebenenfalls einfach bis zweifach durch Fluor, Chlor, Brom, Cyano, Nitro, Methyl, Ethyl, Methoxy, Trifluormethyl oder Trifluormethoxy substituiertes Phenyl,
für jeweils gegebenenfalls einfach bis zweifach durch Chlor oder Methyl substituiertes Pyridyl oder Thienyl,
R² steht besonders bevorzugt für C₁-C₈-Alkyl, C₂-C₄-Alkenyl, Methoxyethyl, Ethoxyethyl oder für Phenyl oder Benzyl,
R⁶ und R⁷ stehen unabhängig voneinander besonders bevorzugt für Methyl, Ethyl oder zusammen für einen C₅-Alkylenrest, in welchem die C₃-Methylengruppe durch Sauerstoff ersetzt ist
und/oder mindestens einen Wirkstoff der Formel (II) und mindestens einen Wirkstoff der Formel (III).Particularly preferred are combinations of active substances containing compounds of the formula (I) in which the radicals have the following meaning:
W is particularly preferably hydrogen, methyl, ethyl, chlorine, bromine or methoxy,
X is particularly preferably chlorine, bromine, methyl, ethyl, propyl, isopropyl, methoxy, ethoxy or trifluoromethyl,
Y and Z are more preferably independently of one another hydrogen, fluorine, chlorine, bromine, methyl, ethyl, propyl, isopropyl, trifluoromethyl or methoxy,
A particularly preferably represents methyl, ethyl, propyl, isopropyl, butyl, isobutyl, sec-butyl, tert-butyl, cyclopropyl, cyclopentyl or cyclohexyl,
B is particularly preferably hydrogen, methyl or ethyl,
A, B and the carbon atom to which they are attached are particularly preferably saturated C ₆ -cycloalkyl, in which optionally one ring member is replaced by oxygen and which is optionally monosubstituted by methyl, ethyl, methoxy, ethoxy, propoxy or butoxy,
D is particularly preferably hydrogen, methyl, ethyl, propyl, isopropyl, butyl, isobutyl, allyl, cyclopropyl, cyclopentyl or cyclohexyl,
A and D together are particularly preferably C ₃ -C ₄ -alkanediyl optionally substituted by methyl,
G is particularly preferably hydrogen (a) or one of the groups

in which
M is oxygen or sulfur,
R ¹ particularly preferably represents C ₁ -C ₈ -alkyl, C ₂ -C ₄ -alkenyl, methoxymethyl, ethoxymethyl, ethylthiomethyl, cyclopropyl, cyclopentyl or cyclohexyl,
optionally substituted once to twice by fluorine, chlorine, bromine, cyano, nitro, methyl, ethyl, methoxy, trifluoromethyl or trifluoromethoxy-substituted phenyl,
for each optionally mono- to disubstituted by chlorine or methyl-substituted pyridyl or thienyl,
R ² particularly preferably represents C ₁ -C ₈ -alkyl, C ₂ -C ₄ -alkenyl, methoxyethyl, ethoxyethyl or phenyl or benzyl,
R ⁶ and R ⁷ independently of one another particularly preferably represent methyl, ethyl or together represent a C ₅ -alkylene radical in which the C ₃ -methylene group is replaced by oxygen
and / or at least one active ingredient of the formula (II) and at least one active ingredient of the formula (III).

in welchen
M für Sauerstoff oder Schwefel steht,
R¹ steht ganz besonders bevorzugt für C₁-C₈-Alkyl, C₂-C₄-Alkenyl, Methoxymethyl, Ethoxymethyl, Ethylmethylthio, Cyclopropyl, Cyclopentyl, Cyclohexyl oder
für gegebenenfalls einfach durch Fluor, Chlor, Brom, Methyl, Methoxy, Trifluormethyl, Trifluormethoxy, Cyano oder Nitro substituiertes Phenyl,
für jeweils gegebenenfalls einfach durch Chlor oder Methyl substituiertes Pyridyl oder Thienyl,
R² steht ganz besonders bevorzugt für C₁-C₈-Alkyl, C₂-C₄-Alkenyl, Methoxyethyl, Ethoxyethyl, Phenyl oder Benzyl,
R⁶ und R⁷ stehen unabhängig voneinander ganz besonders bevorzugt für Methyl, Ethyl oder zusammen für einen C₅-Alkylenrest, in welchem die C₃-Methylengruppe durch Sauerstoff ersetzt istVery particular preference is given to active compound combinations comprising compounds of the formula (I) in which the radicals have the following meaning:
W is very particularly preferably hydrogen or methyl,
X very particularly preferably represents chlorine, bromine or methyl,
Y and Z are very particularly preferably each independently hydrogen, chlorine, bromine or methyl,
A, B and the carbon atom to which they are attached very particularly preferably represent saturated C ₆ -cycloalkyl in which optionally one ring member is replaced by oxygen and which is optionally monosubstituted by methyl, methoxy, ethoxy, propoxy or butoxy,
D is very particularly preferably hydrogen,
G is very particularly preferably hydrogen (a) or one of the groups

in which
M is oxygen or sulfur,
R ¹ very particularly preferably represents C ₁ -C ₈ -alkyl, C ₂ -C ₄ -alkenyl, methoxymethyl, ethoxymethyl, ethylme thylthio, cyclopropyl, cyclopentyl, cyclohexyl or
optionally substituted by fluorine, chlorine, bromine, methyl, methoxy, trifluoromethyl, trifluoromethoxy, cyano or nitro phenyl,
each optionally substituted by chlorine or methyl, pyridyl or thienyl,
R ² very particularly preferably represents C ₁ -C ₈ -alkyl, C ₂ -C ₄ -alkenyl, methoxyethyl, ethoxyethyl, phenyl or benzyl,
R ⁶ and R ⁷ independently of one another very particularly preferably represent methyl, ethyl or together represent a C ₅ -alkylene radical in which the C ₃ -methylene group has been replaced by oxygen

und/oder mindestens einen Wirkstoff der Formel (II) und mindestens einen Wirkstoff der Formel (III).Particular preference is given to mixtures comprising the compound spirotetramate (Ib-1)

and / or at least one active ingredient of the formula (II) and at least one active ingredient of the formula (III).

in welchen
R^1' für jeweils gegebenenfalls einfach bis fünffach durch Fluor oder Chlor substituiertes C₁-C₁₆-Alkyl, C₂-C₁₆-Alkenyl, C₁-C₄-Alkoxy-C₁-C₄-alkyl, C₁-C₄-Alkylthio-C₁-C₄-alkyl oder Cycloalkyl mit 3-6 Ringatomen, das durch Sauerstoff- und/oder Schwefelatome unterbrochen sein kann, steht,
für gegebenenfalls einfach bis zweifach durch Fluor, Chlor, Brom, Nitro, C₁-C₄-Alkyl, C₁-C₄-Alkoxy, C₁-C₄-Halogenalkyl, C₁-C₄-Halogenaloxy-substituiertes Phenyl steht, für gegebenenfalls einfach bis zweifach durch Fluor, Chlor, Brom, C₁-C₄-Alkyl, C₁-C₄-Alkoxy, C₁-C₄-Halogenalkyl-, C₁-C₄-Halogenalkoxy-substituiertes Benzyl steht, für jeweils gegebenenfalls einfach bis zweifach durch Chlor, Brom und/oder C₁-C₄-Alkyl substituiertes Pyridyl, Pyrimidyl, Thiazolyl oder Pyrazolyl steht,
R^2' für jeweils gegebenenfalls einfach bis fünffach Fluor oder Chlor durch substituiertes C₁-C₂₀-Alkyl, C₂-C₂₀-Alkenyl, C₁-C₆-Alkoxy-C₂-C₆-alkyl, C₁-C₆-Polyalkoxy-C₂-C₆-alkyl steht,
für jeweils gegebenenfalls einfach bis zweifach durch Fluor, Chlor, Brom, Nitro, C₁-C₆-Alkyl, C₁-C₆-Alkoxy, C₁-C₄-Halogenalkyl-substituiertes Phenyl oder Benzyl steht,
R^3' für gegebenenfalls einfach bis fünffach durch Fluor oder Chlor substituiertes C₁-C₄-Alkyl, für jeweils gegebenenfalls einfach bis zweifach durch C₁-C₄-Alkyl, Fluor, Chlor, Brom, C₁-C₄-Halogenalkyl, C₁-C₄-Alkoxy, C₁-C₄-Halogenalkoxy, Nitro oder Cyano substituiertes Phenyl oder Benzyl steht,
R^4' und R^5' unabhängig voneinander für jeweils gegebenenfalls einfach bis dreifach durch Fluor oder Chlor substituiertes C₁-C₄-Alkyl, C₁-C₄-Alkoxy, C₁-C₄-Alkylamino, Di-(C₁-C₄)-Alkylamino, C₁-C₄-Alkylthio, C₂-C₄-Alkenylthio, C₃-C₆-Cycloalkylthio, für jeweils gegebenenfalls einfach bis zweifach durch Fluor, Chlor, Brom, Nitro, Cyano, C₁-C₂-Alkoxy, C₁-C₂-Halogenalkoxy, C₁-C₂-Alkylthio, C₁-C₂-Halogenalkylthio, C₁-C₂-Alkyl, C₁-C₂-Halogenalkyl substituiertes Phenyl, Phenoxy oder Phenylthio stehen,
R^6' und R^7' unabhängig voneinander für jeweils gegebenenfalls einfach bis dreifach durch Fluor oder Chlor substituiertes C₁-C₆-Alkyl, C₁-C₆-Alkoxy, C₃-C₆-Alkenyl, C₁-C₄-Alkoxy-C₁-C₂-alkyl, für gegebenenfalls einfach bis zweifach durch Fluor, Chlor, Brom, C₁-C₂-Halogenalkyl, C₁-C₄-Alkyl oder C₁-C₄-Alkoxy substituiertes Benzyl steht oder zusammen für einen gegebenenfalls durch Sauerstoff oder Schwefel unterbrochenen 5- bis 6-gliedrigen Ring stehen, der gegebenenfalls durch C₁-C₂-Alkyl substituiert sein kann.Preference is given to active ingredient combinations containing compounds of the formula (II) in which
X 'is C ₁ -C ₄ -alkyl, chlorine, bromine, C ₁ -C ₄ -alkoxy or C ₁ -C ₃ -haloalkyl,
Y 'is hydrogen, C ₁ -C ₄ -alkyl, fluorine, chlorine, bromine, C ₁ -C ₄ -alkoxy, C ₁ -C ₃ -haloalkyl,
Z 'is C ₁ -C ₄ -alkyl, chlorine, bromine, C ₁ -C ₄ -alkoxy,
n 'is a number from 0-2,
A 'is hydrogen or in each case optionally mono- to trisubstituted by fluorine-substituted straight-chain or branched C ₁ -C ₆ -alkyl, C ₂ -C ₆ -alkenyl, C ₁ -C ₄ -alkoxy-C ₁ -C ₂ -alkyl, cycloalkyl with 3-8 ring atoms, which may optionally be interrupted by oxygen and / or sulfur, or optionally mono- to disubstituted by fluorine, chlorine, bromine, C ₁ -C ₂ alkyl, C ₁ -C ₂ haloalkyl, C ₁ -C _2- alkoxy, C ₁ -C ₂ -haloalkoxy, nitro-substituted phenyl or benzyl,
B 'is hydrogen, C ₁ -C ₂ -alkyl or C ₁ -C ₂ -alkoxy-C ₁ -C ₂ -alkyl
or in which
A 'and B' together with the carbon atom to which they are attached are a saturated or unsaturated, optionally interrupted by oxygen and / or sulfur and optionally mono- to disubstituted by fluorine, chlorine, C ₁ -C ₄ -alkyl, C ₁ -C Form _4- alkoxy, C ₁ -C ₂ -haloalkyl, C ₁ -C ₂ -haloalkoxy or C ₁ -C ₂ -alkylthio-substituted 3 to 7-membered ring,
G 'for hydrogen (a) or for the groups

in which
R ^{1 'is} in each case optionally mono- to trisubstituted by fluorine or chlorine-substituted C ₁ -C ₁₆ -alkyl, C ₂ -C ₁₆ -alkenyl, C ₁ -C ₄ -alkoxy-C ₁ -C ₄ -alkyl, C ₁ -C _4- alkylthio-C ₁ -C ₄ -alkyl or cycloalkyl having 3-6 ring atoms which may be interrupted by oxygen and / or sulfur atoms,
optionally mono- or disubstituted by fluorine, chlorine, bromine, nitro, C ₁ -C ₄ alkyl, C ₁ -C ₄ alkoxy, C ₁ -C ₄ haloalkyl, C ₁ -C ₄ -Halogenaloxy-substituted phenyl, optionally mono- or disubstituted by fluorine, chlorine, bromine, C ₁ -C ₄ alkyl, C ₁ -C ₄ alkoxy, C ₁ -C ₄ haloalkyl, C ₁ -C ₄ -haloalkoxy-substituted benzyl, represents each optionally mono- to disubstituted by chlorine, bromine and / or C ₁ -C ₄ -alkyl-substituted pyridyl, pyrimidyl, thiazolyl or pyrazolyl,
R ^{2 'is} in each case optionally mono- to quintuply fluorine or chlorine by substituted C ₁ -C ₂₀ -alkyl, C ₂ -C ₂₀ -alcohol kenyl, C ₁ -C ₆ -alkoxy-C ₂ -C ₆ -alkyl, C ₁ -C ₆ -polyalkoxy-C ₂ -C ₆ -alkyl,
in each case optionally mono- to disubstituted by fluorine, chlorine, bromine, nitro, C ₁ -C ₆ -alkyl, C ₁ -C ₆ -alkoxy, C ₁ -C ₄ -haloalkyl-substituted phenyl or benzyl,
R ^{3 'is} optionally mono- to trisubstituted by fluorine or chlorine-substituted C ₁ -C ₄ -alkyl, in each case optionally mono- to disubstituted by C ₁ -C ₄ -alkyl, fluorine, chlorine, bromine, C ₁ -C ₄ -haloalkyl, C ₁ -C ₄ alkoxy, C ₁ -C ₄ haloalkoxy, nitro or cyano substituted phenyl or benzyl,
R ^{4 '} and R ^5' independently of one another in each case optionally monosubstituted to trisubstituted by fluorine or chlorine, C ₁ -C ₄ -alkyl, C ₁ -C ₄ -alkoxy, C ₁ -C ₄ -alkylamino, di- (C ₁ - C ₄ ) -alkylamino, C ₁ -C ₄ -alkylthio, C ₂ -C ₄ -alkenylthio, C ₃ -C ₆ -cycloalkylthio, in each case optionally mono- to disubstituted by fluorine, chlorine, bromine, nitro, cyano, C ₁ - C ₂ alkoxy, C ₁ -C ₂ -haloalkoxy, C ₁ -C ₂ -alkylthio, C ₁ -C ₂ -haloalkylthio, C ₁ -C ₂ -alkyl, C ₁ -C ₂ -haloalkyl-substituted phenyl, phenoxy or phenylthio stand,
R ^{6 '} and R ^7' independently of one another in each case optionally monosubstituted to trisubstituted by fluorine or chlorine, C ₁ -C ₆ -alkyl, C ₁ -C ₆ -alkoxy, C ₃ -C ₆ -alkenyl, C ₁ -C ₄ - Alkoxy-C ₁ -C ₂ alkyl, optionally mono- to disubstituted by fluorine, chlorine, bromine, C ₁ -C ₂ -haloalkyl, C ₁ -C ₄ -alkyl or C ₁ -C ₄ -alkoxy substituted benzyl or together represent an optionally interrupted by oxygen or sulfur 5- to 6-membered ring, which may optionally be substituted by C ₁ -C ₂ alkyl.

For the in the preferred ranges of halogens are halogen preferred for chlorine and fluorine.

in welchen
R^1' für jeweils gegebenenfalls einfach bis dreifach durch Fluor oder Chlor substituiertes C₁-C₁₂-Alkyl, C₂-C₁₂-Alkenyl, C₁-C₄-Alkoxy-C₁-C₂-alkyl, oder Cycloalkyl mit 3-6 Ringatomen, das durch 1 bis 2 Sauerstoffatome unterbrochen sein kann, steht, für gegebenenfalls einfach durch Fluor, Chlor, Brom, Nitro, C₁-C₄-Alkyl, C₁-C₄-Alkoxy, Trifluormethyl oder Trifluormethoxy substituiertes Phenyl steht;
R^2' für C₁-C₁₂-Alkyl, C₂-C₁₂-Alkenyl, C₁-C₄-Alkoxy-C₂-C₄-alkyl, steht, für jeweils gegebenenfalls einfach durch Fluor, Chlor, Brom, Nitro, C₁-C₄-Alkyl, C₁-C₄-Alkoxy oder Trifluormethyl substituiertes Phenyl oder Benzyl steht, und mindestens einen Wirkstoff der Formel (II).Particularly preferred are combinations of active substances containing compounds of the formula (II) in which
X 'is C ₁ -C ₄ -alkyl, chlorine, bromine, C ₁ -C ₄ -alkoxy or trifluoromethyl,
Y 'is hydrogen, C ₁ -C ₄ -alkyl, chlorine, bromine, C ₁ -C ₄ -alkoxy, C ₁ -C ₂ -haloalkyl,
Z 'is C ₁ -C ₄ -alkyl, chlorine, bromine, C ₁ -C ₄ -alkoxy,
n 'is 0 or 1,
A 'and B' together with the carbon atom to which they are attached form a saturated 5- to 6-membered ring which is optionally monosubstituted by C ₁ -C ₄ -alkyl or C ₁ -C ₄ -alkoxy,
G 'for hydrogen (a) or for the groups

in which
R ^{1 'is} in each case optionally monosubstituted to trisubstituted by fluorine or chlorine, C ₁ -C ₁₂ -alkyl, C ₂ -C ₁₂ -alkenyl, C ₁ -C ₄ -alkoxy-C ₁ -C ₂ -alkyl, or cycloalkyl with 3 -6 ring atoms, which may be interrupted by 1 to 2 oxygen atoms, is optionally substituted by fluorine, chlorine, bromine, nitro, C ₁ -C ₄ alkyl, C ₁ -C ₄ alkoxy, trifluoromethyl or trifluoromethoxy substituted phenyl ;
R ^{2 'is} C ₁ -C ₁₂ -alkyl, C ₂ -C ₁₂ -alkenyl, C ₁ -C ₄ -alkoxy-C ₂ -C ₄ -alkyl, is in each case optionally simply by fluorine, chlorine, bromine, nitro , C ₁ -C ₄ alkyl, C ₁ -C ₄ alkoxy or trifluoromethyl-substituted phenyl or benzyl, and at least one active compound of the formula (II).

in welchen
R^1' für jeweils gegebenenfalls einfach bis dreifach durch Fluor oder Chlor substituiertes C₁-C₈-Alkyl, C₂-C₈-Alkenyl, C₁-C₃-Alkoxy-C₁-C₂-alkyl, oder Cycloalkyl mit 3-6 Ringatomen, das durch 1 bis 2 Sauerstoffatome unterbrochen sein kann, steht,
für gegebenenfalls einfach durch Fluor, Chlor, Brom, Methyl, Methoxy, Trifluormethyl oder Trifluormethoxy substituiertes Phenyl steht;
R^2' für C₁-C₈-Alkyl, C₂-C₈-Alkenyl, C₁-C₄-Alkoxy-C₂-C₃-alkyl, steht,
für jeweils gegebenenfalls einfach durch Fluor, Chlor, Brom, Nitro, Methyl, Methoxy oder Trifluormethyl substituiertes Phenyl oder Benzyl steht.Very particular preference is given to active ingredient combinations containing compounds of the formula (II) in which
X 'is methyl, ethyl, chlorine, bromine, methoxy, ethoxy or trifluoromethyl,
Y 'is hydrogen, methyl, ethyl, chlorine, bromine, methoxy or trifluoromethyl,
Z 'is methyl, ethyl, chlorine, bromine or methoxy,
n 'is 0 or 1,
A 'and B' together with the carbon atom to which they are attached form a saturated 5- to 6-membered ring which is optionally substituted by methyl, ethyl, propyl, methoxy, ethoxy, propoxy, butoxy or isobutoxy,
G 'for hydrogen (a) or for the groups

in which
R ^{1 'is} in each case optionally monosubstituted to trisubstituted by fluorine or chlorine, C ₁ -C ₈ -alkyl, C ₂ -C ₈ -alkenyl, C ₁ -C ₃ -alkoxy-C ₁ -C ₂ -alkyl, or cycloalkyl with 3 -6 ring atoms, which may be interrupted by 1 or 2 oxygen atoms,
optionally substituted by fluorine, chlorine, bromine, methyl, methoxy, trifluoromethyl or trifluoromethoxy phenyl;
R ^{2 'is} C ₁ -C ₈ -alkyl, C ₂ -C ₈ -alkenyl, C ₁ -C ₄ -alkoxy-C ₂ -C ₃ -alkyl,
each optionally optionally substituted by fluorine, chlorine, bromine, nitro, methyl, methoxy or trifluoromethyl substituted phenyl or benzyl.

Especially preferred are combinations of active substances containing compounds of Formula (II-b-1) or (II-b-2).

Prefers are mixtures containing at least one of the compounds (IIIa), (IIIb) or (IIIc).

The active compound combinations according to the invention contain in addition to at least one active ingredient of formula (III) in enantiomerically pure Form or as a mixture of the two enantiomers in any ratio at least a compound of formula (I) and / or of formula (II).

und mindestens einen Wirkstoff der Formel (III).The active compound combinations according to the invention preferably comprise one of the active compounds (IIIa), (IIIb) or (IIIc) and a compound of the formula (I) or a compound of the formula (II). Particular preference is given to active ingredient combinations containing the compound of the formula (II-b-1)

and at least one active ingredient of the formula (III).

und mindestens einen Wirkstoff der Formel (III).Also particularly preferred are combinations of active substances containing the compound of the formula (II-b-2)

and at least one active ingredient of the formula (III).

und mindestens einen Wirkstoff der Formel (III).Also particularly preferred are combinations of active substances containing the compound of the formula (Ib-1)

and at least one active ingredient of the formula (III).

All particularly preferred is a mixture containing the compound (IIIa) and the compound (I-b-1).

Farther very particularly preferred is a mixture containing the compound (IIIa) and the compound (II-b-1).

Farther very particularly preferred is a mixture containing the compound (IIIa) and the compound (II-b-2).

Farther very particularly preferred is a mixture containing the compound (IIIb) and the compound (I-b-1).

Farther very particularly preferred is a mixture containing the compound (IIIb) and the compound (II-b-1).

Farther very particularly preferred is a mixture containing the compound (IIIb) and the compound (II-b-2).

Farther very particularly preferred is a mixture containing the compound (IIIc) and the compound (I-b-1).

Farther very particularly preferred is a mixture containing the compound (IIIc) and the compound (II-b-1).

Farther very particularly preferred is a mixture containing the compound (IIIc) and the compound (II-b-2).

Especially preferred is a mixture containing the compound (IIIb) and the compound (I-b-1).

Farther particularly preferred is a mixture containing the compound (IIIb) and the compound (II-b-1).

Farther particularly preferred is a mixture containing the compound (IIIb) and the compound (II-b-2).

If the active ingredients in the active compound combinations according to the invention are present in certain weight ratios, the synergistic effect is particularly pronounced. However, the weight ratios of the drugs in the drug combinations can be varied in a relatively wide range. In general, the combinations according to the invention contain an active ingredient of the formula (I) or an active ingredient of the formula (II) and an active ingredient of the formula (III) in the following preferred and particularly preferred mixing ratios: Preferred mixing ratio: 125: 1 to 1: 125 Particularly preferred mixing ratio: 25: 1 to 1:25

The mixing ratios based on weight ratios. The relationship is to be understood as an active ingredient of the formula (I) or active ingredient of Formula (II): Active ingredient of the formula (III).

The active compound combinations according to the invention are suitable for good plant tolerance, favorable toxicity to warm-blooded animals and good environmental compatibility for the protection of plants and plant organs, for increasing crop yields, improving the quality of the crop and for controlling animal pests, in particular insects, arachnids, helminths, nematodes and mollusks in agriculture, horticulture, livestock, forests, gardens and recreational facilities, in the protection of materials and materials and in the hygiene sector. They can preferably be used as crop protection agents. They are effective against normally sensitive and resistant species as well as against all or individual stages of development. The above mentioned pests include:
From the order of the Anoplura (Phthiraptera) eg Damalinia spp., Haematopinus spp., Linognathus spp., Pediculus spp., Trichodectes spp.
From the class of the Arachnida eg Acarus siro, Aceria sheldoni, Aculops spp., Aculus spp., Amblyomma spp., Argas spp., Boophilus spp., Brevipalpus spp., Bryobia praetiosa, Chorioptes spp., Dermanyssus gallinae, Eotetranychus spp. Epitrimerus pyri, Eutetranychus spp., Eriophyes spp., Hemitarsonemus spp., Hyalomma spp., Ixodes spp., Latrodectus mactans, Metatetranychus spp., Oligonychus spp., Ornithodoros spp., Panonychus spp., Phyllocoptruta oleivora, Polyphagotarsonemus latus, Psoroptes spp , Rhipicephalus spp., Rhizoglyphus spp., Sarcoptes spp., Scorpio maurus, Stenotarsonemus spp., Tarsonemus spp., Tetranychus spp., Vasates lycopersici.
From the class of Bivalva eg Dreissena spp.
From the order of Chilopoda eg Geophilus spp., Scutigera spp.
From the order Coleoptera eg Acanthoscelides obtectus, Adoretus spp., Agelastica alni, Agriotes spp., Amphimallon solstitialis, Anobium punctatum, Anoplophora spp., Anthonomus spp., Anthrenus spp., Apogonia spp., Atomaria spp., Attagenus spp. Bruchidius obtectus, Bruchus spp., Ceuthorhynchus spp., Cleonus mendicus, Conoderus spp., Cosmopolites spp., Costelytra zealandica, Curculio spp., Cryptorhynchus lapathi, Dermestes spp., Diabrotica spp., Epilachna spp., Faustinus cubae, Gibbium psylloides, Heteronychus arator, Hylamorpha elegans, Hylotrupes bajulus, Hypera postica, Hypothenemus spp., Lachnosterna consanguinea, Leptinotarsa decemlineata, Lissorhoptrus oryzophilus, Lixus spp., Lyctus spp., Meligethes aeneus, Melolontha melolontha, Migdolus spp., Monochamus spp., Naupactus xanthographus, Niptus hololeucus, Oryctes rhinoceros, Oryzaephilus surinamensis, Otiorrhynchus sulcatus, Oxycetonia jucunda, Phaedon cochleariae, Phyllophaga spp., Popillia japonica, Premnotrypes spp., Psylli or chrysocephala, Ptinus spp., Rhizobius ventralis, Rhizopertha dominica, Sitophilus spp., Sphenophorus spp., Starchus spp., Symphyletes spp., Tenebrio molitor, Tribolium spp., Trogoderma spp., Tychius spp., Xylotrechus spp., Zabrus spp ,
From the order of the Collembola eg Onychiurus armatus.
From the order of the Dermaptera eg Forficula auricularia.
From the order of Diplopoda eg Blaniulus guttulatus.
From the order of Diptera eg Aedes spp., Anopheles spp., Bibio hortulanus, Calliphora erythrocephala, Ceratitis capitata, Chrysomyia spp., Cochliomyia spp., Cordylobia anthropophaga, Culex spp., Cuterebra spp., Dacus oleae, Dermatobia hominis, Drosophila spp , Fannia spp., Gastrophilus spp., Hylemyia spp., Hyppobosca spp., Hypoderma spp., Liriomyza spp. Lucilia spp., Musca spp., Nezara spp., Oestrus spp., Oscinella frit, Pegomyia hyoscyami, Phorbia spp , Stomoxys spp., Tabanus spp., Tannia spp., Tipula paludosa, Wohlfahrtia spp.
From the class Gastropoda eg Arion spp., Biomphalaria spp., Bulinus spp., Deroceras spp., Galba spp., Lymnaea spp., Oncomelania spp., Succinea spp.
From the class of helminths, for example, Ancylostoma duodenale, Ancylostoma ceylanicum, Acylostoma braziliensis, Ancylostoma spp., Ascaris lubricoides, Ascaris spp., Brugia malayi, Brugia timori, Bunostomum spp., Chabertia spp., Clonorchis spp., Cooperia spp., Dicrocoelium spp , Dictyocaulus filaria, Diphyllobothrium latum, Dracunculus medinensis, Echinococcus granulosus, Echinococcus multilocularis, Enterobius vermicularis, Faciola spp., Haemonchus spp., Heterakis spp., Hymenolepis nana, Hyostrongulus spp., Loa Loa, Nematodirus Spp., Oesophagostomum spp., Opisthorchis spp., Onchocerca volvulus, Ostertagia spp., Paragonimus spp., Schistosome spp, Strongyloides fuelleborni, Strongyloides stercoralis, Stronyloides spp., Taenia saginata, Taenia solium, Trichinella spiralis, Trichinella nativa, Trichinella britovi, Trichinella nelsoni, Trichinella pseudopsiralis, Trichostrongulus spp., Trichuris trichuria, Wuchereria bancrofti.

Furthermore, protozoa, such as Eimeria, can be combated.
From the order of the Heteroptera eg Anasa tristis, Antestiopsis spp., Blissus spp., Calocoris spp., Campylomma livida, Cavelerius spp., Cimex spp., Creontiades dilutus, Dasynus piperis, Dichelops furcatus, Diconocoris hewetti, Dysdercus spp., Euschistus spp , Eurygaster spp., Heliopeltis spp., Horcias nobilellus, Leptocorisa spp., Leptoglossus phyllopus, Lygus spp., Macropes excavatus, Miridae, Nezara spp., Oebalus spp., Pentomidae, Piesma quadrata, Piezodorus spp., Psallus seriatus, Pseudacysta persea, Rhodnius spp., Sahlbergella singularis, Scotinophora spp., Stephanitis nashi, Tibraca spp., Triatoma spp.
From the order of Homoptera eg Acyrthosipon spp., Aeneolamia spp., Agonoscena spp., Aleurodes spp., Aleurolobus barodensis, Aleurothrixus spp., Amrasca spp., Anuraphis cardui, Aonidiella spp., Aphanostigma piri, Aphis spp., Arboridia apicalis, Aspidiella spp., Aspidiotus spp., Atanus spp., Aulacorthum solani, Bemisia spp., Brachycaudus helichrysii, Brachycolus spp., Brevicoryne brassicae, Calligypona marginata, Carneocephala fulgida, Ceratovacuna lanigera, Cercopidae, Ceroplastes spp., Chaetosiphon fragaefolii, Chionetis tegalensis, Chlorita onukii, Chromaphis juglandicola, Chrysomphalus ficus, Cicadulina mbila, Coccomytilus halli, Coccus spp., Cryptomyzus ribis, Dalbulus spp., Dialeurodes spp., Diaphorina spp., Diaspis spp., Doralis spp., Drosicha spp., Dysaphis spp. Dysmicoccus spp., Empoasca spp., Eriosoma spp., Erythroneura spp., Euscelis bilobatus, Geococcus coffeae, Homalodisca coagulata, Hyalopterus arundinis, Icerya spp., Idiocerus spp., Idioscopus spp., Laodelphax striatel lucid, Lecanium spp., Lepidosaphes spp., Lipaphis erysimi, Macrosiphum spp., Mahanarva fimbriolata, Melanaphis sacchari, Metcalfiella spp., Metopolophium dirhodum, Monellia costalis, Monelliopsis pecanis, Myzus spp., Nasonovia ribisnigri, Nephotettix spp., Nilaparvata lugens, Oncometopia spp., Orthezia praelonga, Parabemisia myricae, Paratrioza spp., Parlatoria spp., Pemphigus spp., Peregrinus maidis, Phenacoccus spp., Phloeomyzus passerinii, Phorodon humuli, Phylloxera spp., Pinnaspis aspidistrae, Planococcus spp., Protopulvinaria pyriformis, Pseudaulacaspis pentagona, Pseudococcus spp., Psylla spp., Pteromalus spp., Pyrilla spp., Quadraspidiotus spp., Quesada gigas, Rastrococcus spp., Rhopalosiphum spp., Saissetia spp., Scaphoides titanus, Schizaphis graminum, Selenaspidus articulatus, Sogata spp. Sogatella furcifera, Sogatodes spp., Stictocephala festina, Tenalaphara malayensis, Tinocallis caryaefoliae, Tomaspis spp., Toxoptera spp., Trialeurodes vaporariorum, Trioza spp., Typhlocyba spp., Unaspis spp., Viteus vitifolii.
From the order of Hymenoptera eg Diprion spp., Hoplocampa spp., Lasius spp., Monomorium pharaonis, Vespa spp.
From the order of the Isopoda eg Armadillidium vulgare, Oniscus asellus, Porcellio scaber.
From the order of the Isoptera eg Reticulitermes spp., Odontotermes spp.
From the order of Lepidoptera, for example, Acronicta major, Aedia leucomelas, Agrotis spp., Alabama argillacea, Anticarsia spp., Barathra brassicae, Bucculatrix thurberiella, Bupalus piniarius, Cacoecia podana, Capua reticulana, Carpocapsa pomonella, Cheimatobia brumata, Chilo spp., Choristoneura fumiferana , Clysia ambiguella, Cnaphalocerus spp., Earias insulana, Ephestia kuehniella, Euproctis chrysorrhoea, Euxoa spp., Feltia spp., Galleria mellonella, Helicoverpa spp., Heliothis spp., Hofmannophila pseudospretella, Homona magnanima, Hyponomeuta padella, Laphygma spp., Lithocolletis blancardella, Lithophane antennata, Loxagrotis albicosta, Lymantria spp., Malacosoma neustria, Mamestra brassicae, Mocis repanda, Mythimna separata, Oria spp., Oulema oryzae, Panolis flammea, Pectinophora gossypiella, Phyllocnistis citrella, Pieris spp., Plutella xylostella, Prodenia spp. , Pseudaletia spp., Pseudoplusia includens, Pyrausta nubilalis, Spodoptera spp., Thermesia gemmatalis, Tinea pellionella, Tineola bisselliella, Tortrix viridana, Trichoplusia spp.
From the order of the Orthoptera eg Acheta domesticus, Blatta orientalis, Blattella germanica, Gryllotalpa spp., Leucophaea maderae, Locusta spp., Melanoplus spp., Periplaneta americana, Schistocerca gregaria.
From the order of Siphonaptera eg Ceratophyllus spp., Xenopsylla cheopis.
From the order of Symphyla eg Scutigerella immaculata.
From the order of the Thysanoptera eg Baliothrips biformis, Enneothrips flavens, Frankliniella spp., Heliothrips spp., Hercinothrips femoralis, Kakothrips spp., Rhipiphorothrips cruentatus, Scirtothrips spp., Taeniothrips cardamoni, Thrips spp.
From the order of Thysanura eg Lepisma saccharina.

To the plant parasite Nematodes belong e.g. Anguina spp., Aphelenchoides spp., Belonoaimus spp., Bursaphelenchus spp., Ditylenchus dipsaci, Globodera spp., Heliocotylenchus spp., Heterodera spp., Longidorus spp., Meloidogyne spp., Pratylenchus spp., Radopholus similis, Rotylenchus spp., Trichodorus spp., Tylenchorhynchus spp., Tylenchulus spp., Tylenchulus semipenetrans, Xiphinema spp.

The active compound combinations according to the invention are distinguished in particular by their strong action versus...

The active compound combinations according to the invention can optionally in certain concentrations or application rates also as herbicides, safeners, growth regulators or agents for Improvement of plant properties, or as microbicides, for example as fungicides, antimycotics, bactericides, viricides (including agents against viroids) or as an agent against MLO (Mycoplasma-like-organism) and RLO (Rickettsia-like-organism). They leave optionally also as intermediates or precursors for the synthesis use other active ingredients.

According to the invention, all Plants and parts of plants are treated. Among plants are here understood all plants and plant populations, as desired and undesirable Wild plants or crops (including naturally occurring crops). Crops can Be plants by conventional breeding and optimization methods or by biotechnological and genetic engineering methods or Combinations of these methods can be obtained, including transgenic ones Plants and including protected by plant variety rights or non-protectable plant varieties. Under plant parts are all above ground and underground Parts and organs of plants, such as shoot, leaf, flower and root By way of example, leaves, needles, stems, stems, flowers, fruiting bodies, fruits and Seeds and roots, tubers and rhizomes are listed. Part of the plant parts also harvested material as well as vegetative and generative propagation material, For example, cuttings, tubers, rhizomes, offshoots and seeds.

The Treatment according to the invention the plants and plant parts are carried out with the active ingredient combinations directly or by acting on their environment, habitat or Storage room after the usual Treatment methods, e.g. by dipping, spraying, evaporating, misting, Spreading, spreading, injecting and propagating material, in particular in seed, still by single or multi-layer wrapping.

The Drug combinations can in the usual Formulations are transferred, like solutions, emulsions, Spray powder, water and oil based Suspensions, powders, dusts, Pastes, soluble Powder, soluble Granules, granules, suspension emulsion concentrates, drug-impregnated Natural products, drug-impregnated synthetic substances, fertilizers as well as finest encapsulations in polymeric materials.

These Formulations are prepared in a known manner, e.g. by Mixing the active ingredients with extenders, ie liquid solvents and / or solid carriers, optionally using surface-active agents, ie emulsifiers and / or dispersants and / or foam-forming agents. The Preparation of the formulations is carried out either in suitable plants or even before or during the application.

When Excipients can find substances that are suitable to the agent itself or and / or preparations derived therefrom (for example spray liquor, seed dressing) to give special properties, such as certain technical properties and / or special biological properties. As typical Additives are suitable: extenders, solvents and carriers.

When Extenders are suitable, e.g. Water, polar and nonpolar organic chemical liquids e.g. from the classes of aromatic and non-aromatic hydrocarbons (such as paraffins, alkylbenzenes, alkylnaphthalenes, chlorobenzenes), the Alcohols and polyols (which may also be substituted, etherified and / or esterified could be), ketones (such as acetone, cyclohexanone), esters (including fats and oils) and (poly) ethers, the simple and substituted amines, amides, lactams (such as N-alkylpyrrolidones) and lactones, the sulfones and sulfoxides (such as dimethylsulfoxide).

in the Traps of using water as diluent may be e.g. also organic solvents as auxiliary solvent be used. As liquid solvent are essentially in question: aromatics, such as xylene, toluene, or Alkylnaphthalenes, chlorinated aromatics and chlorinated aliphatic Hydrocarbons, such as chlorobenzenes, chloroethylenes or methylene chloride, aliphatic hydrocarbons, such as cyclohexane or paraffins, e.g. Petroleum fractions, mineral and vegetable oils, Alcohols such as butanol or glycol and their ethers and esters, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents, such as dimethylsulfoxide, as well as water.

Suitable solid carriers are:
for example, ammonium salts and ground natural minerals, such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth, and ground synthetic minerals, such as finely divided silica, aluminum umoxid and silicates, as solid carriers for granules are: for example, broken and fractionated natural rocks such as calcite, marble, pumice, sepiolite, dolomite and synthetic granules of inorganic and organic flours and granules of organic material such as paper, sawdust, coconut shells, corncobs and tobacco stems; suitable emulsifiers and / or foam formers are: for example nonionic and anionic emulsifiers, such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers, for example alkylaryl polyglycol ethers, alkylsulfonates, alkyl sulfates, arylsulfonates and protein hydrolysates; suitable dispersants are nonionic and / or ionic substances, for example from the classes of alcohol POE and / or POP ethers, acid and / or POP-POE esters, alkyl-aryl and / or POP POE ethers, fatty and / or POP-POE adducts, POE and / or POP polyol derivatives, POE and / or POP sorbitol or sugar adducts, alkyl or aryl sulfates, sulfonates and phosphates or the corresponding PO-ether adducts. Further suitable oligo- or polymers, for example starting from vinylic monomers, from acrylic acid, from EO and / or PO alone or in combination with, for example, (poly) alcohols or (poly) amines. Furthermore, find use lignin and its sulfonic acid derivatives, simple and modified celluloses, aromatic and / or aliphatic sulfonic acids and their adducts with formaldehyde.

It can in the formulations adhesives such as carboxymethylcellulose, natural and synthetic powdery, granular or latex-shaped Polymers such as gum arabic, polyvinyl alcohol, Polyvinyl acetate, as well as natural Phospholipids such as cephalins and lecithins and synthetic phospholipids.

It can Dyes such as inorganic pigments, e.g. Iron oxide, titanium oxide, Ferrocyan blue and organic dyes such as alizarin, azo and Metal phthalocyanine dyes and trace nutrients such as salts of iron, Manganese, boron, copper, cobalt, molybdenum and zinc are used.

Further Additives can Fragrances, mineral or vegetable optionally modified oils, waxes and nutrients (also trace nutrients), such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc be.

Farther may be included Stabilizers such as cold stabilizers, Preservatives, antioxidants, light stabilizers or other chemical and / or physical stability improving agents.

The Formulations generally contain between 0.01 and 98% by weight Active ingredient, preferably between 0.5 and 90%.

The active compound combinations according to the invention can in commercial Formulations and in those prepared from these formulations Forms of use mixed with other active substances, such as insecticides, Attractants, sterilants, bactericides, acaricides, nematicides, Fungicides, growth regulators or herbicides. To the insecticides count For example, phosphoric acid esters, carbamates, Carbonsäureester, chlorinated hydrocarbons, phenylureas, by microorganisms Fabrics u.a.

Also a mixture with other known active substances, such as herbicides or with fertilizers and growth regulators is possible.

The active compound combinations according to the invention can also when used as insecticides in their commercial Formulations and in those prepared from these formulations Application forms in mixture with synergists are present. synergists are compounds that increase the effect of the active ingredients without the added synergist itself being active got to.

Of the Active substance content prepared from the commercial formulations Application forms can vary widely. The drug concentration of the application forms can be from 0.00000001 up to 95% by weight of active ingredient, preferably between 0.00001 and 1% by weight.

The Application is done in a custom forms adapted to the applications Wise.

As already mentioned above, according to the invention all plants and their parts can be treated. In a preferred embodiment, wild-type or plant species obtained by conventional biological breeding methods, such as crossing or protoplast fusion, and plant cultivars and their parts are treated. In a further preferred embodiment, transgenic plants and plant cultivars which are obtained by genetic engineering, if appropriate in combination with conventional methods were received (Genetically Modified Organisms) and treated their parts. The terms "parts" or "parts of plants" or "plant parts" have been explained above.

Especially plants according to the invention are preferred the respective commercial or plant varieties in use. Among plant varieties one understands plants with new characteristics ("Traits"), which by both conventional breeding, by mutagenesis or by recombinant DNA techniques are. This can Be varieties, biotypes and genotypes.

ever according to plant species or plant varieties, their location and growth conditions (Floors, Climate, vegetation period, nutrition) can by the treatment according to the invention also superadditives ("synergistic") effects occur. For example, reduced application rates and / or expansions of the Spectrum of action and / or an increase in the effect of the invention can be used Substances and agents, better plant growth, increased tolerance across from high or low temperatures, increased tolerance to dryness or against water or soil salt content, increased flowering efficiency, easier harvest, Acceleration of maturity, higher Crop yields, higher quality and / or higher Nutritional value of Harvested products, higher Shelf life and / or workability of the harvested products possible, beyond the actually expected Go beyond effects.

The preferred plants or plant varieties to be treated according to the invention to be treated include all plants which, as a result of the genetic engineering modification, obtained genetic material which gives these plants particularly advantageous valuable properties ("traits"). Examples of such properties are better plant growth, increased tolerance to high or low temperatures, increased tolerance to dryness or to bottoms salt, increased flowering, easier harvesting, acceleration of ripeness, higher crop yields, higher quality and / or higher nutritional value of the harvested products , higher shelf life and / or workability of the harvested products. Further and particularly emphasized examples of such properties are an increased defense of the plants against animal and microbial pests, as against insects, mites, phytopathogenic fungi, bacteria and / or viruses as well as an increased tolerance of the plants to certain herbicidal active substances. Examples of transgenic plants are the important crops such as cereals (wheat, rice), corn, soybeans, potatoes, sugar beets, tomatoes, peas and other vegetables, cotton, tobacco, oilseed rape and fruit plants (with the fruits apples, pears, citrus fruits and Grapes), with special emphasis on maize, soya, potato, cotton, tobacco and oilseed rape. Traits which are particularly emphasized are the increased defense of the plants against insects, arachnids, nematodes and snails by toxins which are formed in the plants, in particular those which are produced by the genetic material from Bacillus thuringiensis (for example by the genes CryIA (a) , CryIA (b), CryIA (c), CryIIA, CryIIIA, CryIIIB2, Cry9c Cry2Ab, Cry3Bb and CryIF and their combinations) in the plants (hereinafter "Bt plants"). Traits also highlight the increased resistance of plants to fungi, bacteria and viruses by systemic acquired resistance (SAR), systemin, phytoalexins, elicitors and resistance genes and correspondingly expressed proteins and toxins. Traits which are furthermore particularly emphasized are the increased tolerance of the plants to certain herbicidally active compounds, for example imidazolinones, sulfonylureas, glyphosate or phosphinotricin (eg "PAT" gene). The genes which confer the desired properties ("traits") can also occur in combinations with one another in the transgenic plants. Examples of "Bt plants" are maize varieties, cotton varieties, soya bean varieties and potato varieties which are sold under the trade names YIELD GARD ^® (for example maize, cotton, soybean), Knockout ^® (for example maize), StarLink ^® (for example maize), Bollgard ^® ( cotton), NuCOTN ^® (cotton) and NewLeaf ^® (potato). Examples of herbicide-tolerant plants are maize varieties, cotton varieties and soybean varieties may be mentioned, under the trade names Roundup Ready ^® (tolerance to glyphosate, for example maize, cotton, soya bean), Liberty Link ^® (tolerance to phosphinotricin, for example oilseed rape), IMI ^® (tolerance against imidazolinone) and ^STS® (tolerance to sulfonylureas eg corn). As herbicide-resistant (conventionally grown on herbicide tolerance) plants are also sold under the name Clearfield ^® varieties (eg corn). Of course, these statements also apply to future or future marketed plant varieties with these or future developed genetic traits.

The listed Plants can particularly advantageous with the active compound combinations according to the invention be treated. The specified in the drug combinations above Preferential ranges also apply to the treatment of these plants. Particularly emphasized is the Plant treatment with the active compound combinations specifically mentioned in the present text.

The active compound combinations according to the invention not only act against plant, hygiene and Vor rat pests, but also in the veterinary sector against animal parasites (ectoparas and endoparasites) such as ticks, leather ticks, mange mites, running mites, flies (stinging and licking), parasitic fly larvae, lice, hair pieces, featherlings and fleas. These parasites include:
From the order of the Anoplurida eg Haematopinus spp., Linognathus spp., Pediculus spp., Phtirus spp., Solenopotes spp.
From the order of Mallophagida and the suborders Amblycerina and Ischnocerina eg Trimenopon spp., Menopon spp., Trinoton spp., Bovicola spp., Werneckiella spp., Lepikentron spp., Damalina spp., Trichodectes spp., Felicola spp.
From the order Diptera and the suborders Nematocerina and Brachycerina eg Aedes spp., Anopheles spp., Culex spp., Simulium spp., Eusimulium spp., Phlebotomus spp., Lutzomyia spp., Culicoides spp., Chrysops spp., Hybomitra spp. , Atylotus spp., Tabanus spp., Haematopota spp., Philipomyia spp., Braula spp., Musca spp., Hydrotaea spp., Stomoxys spp., Haematobia spp., Morellia spp., Fannia spp., Glossina spp., Calliphora Spp., Lucilia spp., Chrysomyia spp., Wohlfahrtia spp., Sarcophaga spp., Oestrus spp., Hypoderma spp., Gasterophilus spp., Hippobosca spp., Lipoptena spp., Melophagus spp.
From the order of the siphon adapter eg Pulex spp., Ctenocephalides spp., Xenopsylla spp., Ceratophyllus spp.
From the order of the Heteropterida eg Cimex spp., Triatoma spp., Rhodnius spp., Panstrongylus spp.
From the order Blattarida eg Blatta orientalis, Periplaneta americana, Blattela germanica, Supella spp.
From the subclass of Acari (Acarina) and the orders of meta and mesostigmata eg Argas spp., Ornithodorus spp., Otobius spp., Ixodes spp., Amblyomma spp., Boophilus spp., Dermacentor spp., Haemophysalis spp., Hyalomma Spp., Rhipicephalus spp., Dermanyssus spp., Raillietia spp., Pneumonyssus spp., Sternostoma spp., Varroa spp.
From the order of Actinedida (Prostigmata) and Acaridida (Astigmata) eg Acarapis spp., Cheyletiella spp., Ornithocheyletia spp., Myobia spp., Psorergates spp., Demodex spp., Trombicula spp., Listrophorus spp., Acarus spp. Tyrophagus spp., Caloglyphus spp., Hypodectes spp., Pterolichus spp., Psoroptes spp., Chorioptes spp., Otodectes spp., Sarcoptes spp., Notoedres spp., Knemidocoptes spp., Cytodites spp., Laminosioptes spp.

The active compound combinations according to the invention are also suitable for fighting of arthropods, farm animals, e.g. Bovine, Sheep, goats, horses, pigs, donkeys, camels, buffalo, rabbits, Chicken, Turkeys, ducks, geese, Bees, other pets such as e.g. Dogs, cats, caged birds, aquarium fish and so-called experimental animals, e.g. Hamster, guinea pig, Rats and mice affected. By fighting These arthropods are said to be deaths and reductions in performance (in the case of meat, milk, wool, hides, eggs, Honey, etc.) are reduced, so that through the use of the active compound combinations according to the invention a more economical and easier animal husbandry is possible.

The Application of the active compound combinations according to the invention happens in the veterinary sector and in animal husbandry in a known manner by enteral administration in the form of, for example, tablets, capsules, potions, drenches, Granules, pastes, boluses, the feed-through process, suppositories, by parenteral administration, as by injections (intramuscular, subcutaneous, intravenous, intraperitoneal, etc.), Implants, by nasal application, by dermal application in Form for example of diving or bathing (dipping), spraying (spray), infusing (Pour-on and spot-on), washing, powdering and with help of active substance-containing moldings, like collars, Ear tags, tail tags, limb bands, halters, marking devices etc.

at the application for Livestock, poultry, Pets etc. can be the drug combinations as formulations (For example, powders, emulsions, flowable agents) containing the active ingredients in an amount of 1 to 80 wt .-%, directly or after 100 up to 10 000-fold dilution apply or use as a chemical bath.

It was also found that the active compound combinations according to the invention show a high insecticidal activity against insects, the technical Destroy materials.

By way of example and preferably without limiting however, the following insects are mentioned:
Beetles such as Hylotrupes bajulus, Chlorophorus pilosis, Anobium punctatum, Xestobium rufovillosum, Ptilinus pecticornis, Dendrobium pertinex, Ernobius mollis, Priobium carpini, Lyctus brunneus, Lyctus africanus, Lyctus planicollis, Lyctus linearis, Lyctus pubescens, Trogoxylon aequale, Minthes rugicollis, Xyleborus spec. Tryptodendron spec. Apate monachus, Bostrychus capucins, Heterobostrychus brunneus, Sinoxylon spec. Dinoderus minutus;
Hymenoptera such as Sirex juvencus, Urocerus gigas, Urocerus gigas taignus, Urocerus augur;
Termites such as Kalotermes flavicollis, Cryptotermes brevis, Heterotermes indicola, Reticulitermes flavipes, Reticulitermes santonensis, Reticulitermes lucifugus, Mastotermes darwiniensis, Zootermopsis nevadensis, Coptotermes formosanus;
Bristle tails like Lepisma saccharina.

Under technical materials are non-living in the present context Materials, such as preferably plastics, adhesives, Glues, papers and cartons, leather, wood, woodworking products and paints.

The ready to use means optionally further insecticides and optionally also contain one or more fungicides.

Regarding potential additional Zumischpartner be on the above insecticides and fungicides directed.

at the same time can the active compound combinations according to the invention for protection against the growth of objects, in particular hulls, sieves, Nets, structures, wharves and signal systems connected with sea or brackish water are used.

Further can the active compound combinations according to the invention alone or in combination with other active ingredients as antifouling agent be used.

The active substance combinations are also suitable for controlling animal pests in household, hygiene and storage protection, in particular of insects, arachnids and mites, which are used in enclosed spaces, such as, for example, apartments, factory halls, offices, vehicle cabins and the like. occurrence. They can be used to control these pests, alone or in combination with other active ingredients and adjuvants in household insecticide products. They are effective against sensitive and resistant species and against all stages of development. These pests include:
From the order of Scorpionidea eg Buthus occitanus.
From the order of the Acarina eg Argas persicus, Argas reflexus, Bryobia ssp., Dermanyssus gallinae, Glyciphagus domesticus, Ornithodorus moubat, Rhipicephalus sanguineus, Trombicula alfreddugesi, Neutrombicula autumnalis, Dermatophagoides pteronissimus, Dermatophagoides forinae.
From the order of the Araneae eg Aviculariidae, Araneidae.
From the order of the Opiliones eg Pseudoscorpiones chelifer, Pseudoscorpiones cheiridium, Opiliones phalangium.
From the order of the Isopoda eg Oniscus asellus, Porcellio scaber.
From the order of the Diplopoda eg Blaniulus guttulatus, Polydesmus spp.
From the order of Chilopoda eg Geophilus spp.
From the order of Zygentoma eg Ctenolepisma spp., Lepisma saccharina, Lepismodes inquilinus.
From the order of the Blattaria eg Blatta orientalies, Blattella germanica, Blattella asahinai, Leucophaea maderae, Panchlora spp., Parcoblatta spp., Periplaneta australasiae, Periplaneta americana, Periplaneta brunnea, Periplaneta fuliginosa, Supella longipalpa.
From the order of Saltatoria eg Acheta domesticus.
From the order of the Dermaptera eg Forficula auricularia.
From the order of the Isoptera eg Kalotermes spp., Reticulitermes spp.
From the order of Psocoptera eg Lepinatus spp., Liposcelis spp.
From the order of Coleoptera, for example, Anthrenus spp., Attagenus spp., Dermestes spp., Latheticus oryzae, Necrobia spp., Ptinus spp., Rhizopertha dominica, Sitophilus granarius, Sitophilus oryzae, Sitophilus zeamais, Stegobium paniceum.
From the order of Diptera eg Aedes aegypti, Aedes albopictus, Aedes taeniorhynchus, Anopheles spp., Calliphora erythrocephala, Chrysozona pluvialis, Culex quinquefasciatus, Culex pipiens, Culex tarsalis, Drosophila spp., Fannia canicularis, Musca domestica, Phlebotomus spp., Sarcophaga carnaria , Simulium spp., Stomoxys calcitrans, Tipula paludosa.
From the order of Lepidoptera eg Achroia grisella, Galleria mellonella, Plodia interpunctella, Tinea cloacella, Tinea pellionella, Tineola bisselliella.
From the order of the Siphonaptera, for example, Ctenocephalides canis, Ctenocephalides felis, Pulex irritans, Tunga penetrans, Xenopsylla cheopis.
From the order of the Hymenoptera, for example, Camponotus herculeanus, Lasius fuliginosus, Lasius niger, Lasius umbratus, Monomorium pharaonis, Paravespula spp., Tetramorium caespitum.
From the order of the Anoplura eg Pediculus humanus capitis, Pediculus humanus corporis, Pemphigus spp. Phylloera vastatrix, Phthirus pubis.
From the order of Heteroptera eg Cimex hemipterus, Cimex lectularius, Rhodinus prolixus, Triatoma infestans.

The Application in the field of household insecticides takes place alone or in combination with other suitable active substances, such as phosphoric esters, Carbamates, pyrethroids, neonicotinoids, growth regulators or agents from other known classes of insecticides.

The Application is in aerosols, non-pressurized sprays, e.g. Pump and atomizer sprays, Fog machines, foggers, foams, Gels, evaporator products with evaporator plates made of cellulose or plastic, liquid evaporators, Gel and membrane evaporators, propeller-driven evaporators, energy-free or passive evaporation systems, moth papers, moth bags and Moth gels, as granules or dusts, in straw baits or Bait stations.

The good insecticidal and / or acaricidal action of the active compound combinations according to the invention is apparent from the examples below. While the individual active ingredients weaknesses in effect show the combinations have an effect over a simple effect summation goes beyond.

One synergistic effect is always with insecticides and acaricides then if the effect of the drug combinations is greater as the sum of the effects of the individually applied active ingredients.

The expected effect for a given combination of two drugs may be according to S.R. Colby, Weeds 15 (1967), 20-22 are calculated as follows:

If
X means the degree of killing, expressed in% of the untreated control, when using the active ingredient A at a rate of mg / ha or in a concentration of m ppm,
Y means the degree of killing, expressed in% of the untreated control, when using the active substance B in an application rate of ng / ha or in a concentration of n ppm, and
E means the degree of killing, expressed in% of the untreated control, when using the active compounds A and B at application rates of m and ng / ha or in a concentration of m and n ppm,
then

is the actual insecticidal or acaricidal degree of killing greater than calculated, the combination is over-additive in its kill, i. it lies synergistic effect. In this case, the actually observed kill rate to be taller as the one from the above Formula calculated value for the expected kill rate (E).

Example A Aphis gossypii test Solvent: 7 parts by weight of dimethylformamide emulsifier: 2 parts by weight of alkylaryl polyglycol ether

to Preparation of a suitable preparation of active ingredient 1 part by weight of active compound is mixed with the stated amounts solvent and emulsifier and diluted concentrate with emulsifier-containing water to the desired concentration.

Cotton leaves (Gossypium herbaceum), which is strongly affected by the cotton aphid (Aphis gossypii) are infested by dipping in the preparation of active compound the desired Concentration treated.

To the desired Time will be the killing determined in%. 100% means that all aphids have been killed; 0% means no aphids killed were. The determined mortality values are charged one after the Colby formula (see sheet 1).

• * gef. = gefundene Wirkung
• ** ber. = nach der Colby-Formel berechnete Wirkung

Beispiel B Myzus persicae – Test Lösungsmittel: 7 Gewichtsteile Dimethylformamid Emulgator: 2 Gewichtsteile Alkylarylpolyglykolether In this test, z. B. the following combination of active ingredients according to the present application, a synergistically enhanced efficacy compared to the individually applied agents: (IIIb) and spirotetramat. Table A Plant damaging insects Aphis gossypii test

• * gef. = found effect
• ** calc. = calculated according to the Colby formula

Example B Myzus persicae test Solvent: 7 parts by weight of dimethylformamide emulsifier: 2 parts by weight of alkylaryl polyglycol ether

to Preparation of a suitable preparation of active ingredient 1 part by weight of active compound is mixed with the stated amounts solvent and emulsifier and diluted concentrate with emulsifier-containing water to the desired concentration.

Cabbage leaves (Brassica oleracea), which is strongly affected by the green Peach aphid (Myzus persicae) are attacked by dipping treated in the active compound preparation of the desired concentration.

To the desired Time will be the killing determined in%. 100% means that all aphids have been killed; 0% means no aphids killed were. The determined mortality values are charged one after the Colby formula (see sheet 1).

• * gef. = gefundene Wirkung
• ** ber. = nach der Colby-Formel berechnete Wirkung

Beispiel C Phaedon cochleariae – Larven-Test Lösungsmittel: 7 Gewichtsteile Dimethylformamid Emulgator: 2 Gewichtsteile Alkylarylpolyglykolether In this test, z. B. the following combination of active ingredients according to the present application a synergistically enhanced efficacy compared to the individually applied agents: (IIIb) and Spirodic Lofen. Table B Plant Harmful Insects Myzus persicae - Test

• * gef. = found effect
• ** calc. = calculated according to the Colby formula

Example C Phaedon cochleariae larval test Solvent: 7 parts by weight of dimethylformamide emulsifier: 2 parts by weight of alkylaryl polyglycol ether

to Preparation of a suitable preparation of active ingredient 1 part by weight of active compound is mixed with the stated amounts solvent and emulsifier and diluted concentrate with emulsifier-containing water to the desired concentration.

Cabbage leaves (Brassica oleracea) are dipped in the preparation of active compound of the desired concentration treated and with larvae of the honeybee leaf beetle (Phaedon cochleariae) occupied as long as the leaves are still wet.

To the desired Time will be the killing determined in%. 100% means that all beetle larvae have been killed; 0% means that no beetle larvae killed were. The determined kill values billed according to the Colby formula (see sheet 1).

• * gef. = gefundene Wirkung
• ** ber. = nach der Colby-Formel berechnete Wirkung

In this test, the following active ingredient combination according to the present application showed a synergistically enhanced efficacy compared to the individually applied active ingredients: (IIIb) and spirodiclofen, (IIIb) and spiromesifen. Table C Plant Harmful Insects Phaedon cochleariae larval test

• * gef. = found effect
• ** calc. = calculated according to the Colby formula

Claims (11)

Composition containing a mixture (a) of at least one compound of the formula (I)

in which X is halogen, alkyl, alkoxy, haloalkyl, haloalkoxy or cyano, W, Y and Z independently of one another are hydrogen, halogen, alkyl, alkoxy, haloalkyl, haloalkoxy or cyano, A is hydrogen, in each case optionally halogen-substituted alkyl , Alkoxyalkyl, saturated, optionally substituted cycloalkyl in which optionally at least one ring atom is replaced by a heteroatom, B is hydrogen or alkyl, A and B together with the carbon atom to which they are bonded, a saturated or unsaturated, optionally at least a heteroatom-containing unsubstituted or substituted cycle, D represents hydrogen or an optionally substituted radical from the series alkyl, alkenyl, alkoxyalkyl, saturated cycloalkyl, in which optionally one or more ring members are replaced by heteroatoms, A and D together with the atoms they are bound for one saturated or unsaturated and optionally containing at least one heteroatom, in the A, D-unsubstituted or unsubstituted cycle, G is hydrogen (a) or one of the groups

where E is a metal ion or an ammonium ion, L is oxygen or sulfur, M is oxygen or sulfur, R ^{1 is} each optionally halogen-substituted alkyl, alkenyl, alkoxyalkyl, alkylthioalkyl, polyalkoxyalkyl or optionally halogen, alkyl or Alkoxy-substituted cycloalkyl which may be interrupted by at least one heteroatom, in each case optionally substituted phenyl, phenylalkyl, hetaryl, phenoxyalkyl or hetaryloxyalkyl, R ^{2 is} in each case optionally halogen-substituted alkyl, alkenyl, alkoxyalkyl, polyalkoxyalkyl or in each case optionally substituted cycloalkyl, phenyl or benzyl, R ^{3 is} optionally halogen-substituted alkyl or optionally substituted phenyl, R ⁴ and R ⁵ are each independently optionally halogen-substituted alkyl, alkoxy, alkylamino, dialkylamino, alkylthio, alkenylthio, cycloalkylthio or for each s are optionally substituted phenyl, benzyl, phenoxy or phenylthio and R ⁶ and R ^{7 are} independently hydrogen, in each case optionally halogen-substituted alkyl, cycloalkyl, alkenyl, alkoxy, alkoxyalkyl, optionally substituted phenyl, optionally substituted benzyl or together with the N atom to which they are attached represent an optionally substituted by oxygen or sulfur interrupted optionally substituted ring, and / or (b) at least one compound of formula (II)

in which X 'is C ₁ -C ₆ -alkyl, halogen, C ₁ -C ₆ -alkoxy or C ₁ -C ₃ -haloalkyl, Y' is hydrogen, C ₁ -C ₆ -alkyl, halogen, C ₁ - C ₆ alkoxy, C ₁ -C ₃ haloalkyl, Z 'is C ₁ -C ₆ alkyl, halogen, C ₁ -C ₆ alkoxy, n' is a number from 0-3, A 'is Hydrogen or in each case optionally halogen-substituted straight-chain or branched C ₁ -C ₁₂ -alkyl, C ₂ -C ₈ -alkenyl, C ₂ -C ₈ -alkynyl, C ₁ -C ₁₀ -alkoxy-C ₁ -C ₈ -alkyl, C ₁ -C ₈ -polyalkoxy-C ₂ -C ₈ -alkyl, C ₁ -C ₁₀ -alkylthio-C ₂ -C ₈ -alkyl, cycloalkyl having 3-8 ring atoms, which may be interrupted by oxygen and / or sulfur, or each optionally substituted by halogen, C ₁ -C ₆ alkyl, C ₁ -C ₆ haloalkyl, C ₁ -C ₆ alkoxy, C ₁ -C ₆ haloalkoxy, nitro substituted phenyl or phenyl-C ₁ -C ₆ -alkyl, B 'is hydrogen, C ₁ -C ₆ alkyl or C ₁ -C ₆ alkoxy-C ₁ -C ₄ alkyl or wherein A' and B 'together with the carbon atom to which they are attached are a saturated or unsaturated, optionally interrupted by oxygen and / or sulfur and optionally by halogen, C ₁ -C ₆ -alkyl, C ₁ -C ₆ -alkoxy, C ₁ -C ₄ -haloalkyl, C ₁ -C ₄ -haloalkoxy , C ₁ -C ₄ -alkylthio or optionally substituted phenyl substituted or optionally benzo-fused 3- to 8-membered ring, G 'for hydrogen (a) or for the groups

in which R ^{1 'is} in each case optionally halogen-substituted C ₁ -C ₂₀ -alkyl, C ₂ -C ₂₀ -alkenyl, C ₁ -C ₈ -alkoxy-C ₁ -C ₈ -alkyl, C ₁ -C ₈ -Alkylthio-C ₁ -C ₈ -alkyl, C ₁ -C ₈ -polyalkoxy-C ₂ -C ₈ -alkyl or cycloalkyl having 3-8 ring atoms, which may be interrupted by oxygen and / or sulfur atoms, is, if appropriate is halogen, nitro, C ₁ -C ₆ alkyl, C ₁ -C ₆ alkoxy, C ₁ -C ₆ haloalkyl, C ₁ -C ₆ -haloalkoxy-substituted phenyl; is optionally substituted by halogen, C ₁ -C ₆ alkyl, C ₁ -C ₆ alkoxy, C ₁ -C ₆ haloalkyl, C ₁ -C ₆ -haloalkoxy-substituted phenyl-C ₁ -C ₆ alkyl each represents optionally substituted by halogen and / or C ₁ -C ₆ alkyl pyridyl, pyrimidyl, thiazolyl or pyrazolyl, optionally substituted by halogen and / or C ₁ -C ₆ alkyl-substituted phenoxy-C ₁ -C ₆ R ^{2 'is} in each case optionally halogen-substituted C ₁ -C ₂₀ -alkyl, C ₂ -C ₂₀ -alkenyl, C ₁ -C ₈ -alkoxy-C ₂ -C ₈ -alkyl or C ₁ -C ₈ Is polyalkoxy-C ₂ -C ₈ -alkyl, each of which is optionally substituted by halogen, nitro, C ₁ -C ₆ -alkyl, C ₁ -C ₆ -alkoxy, C ₁ -C ₆ -haloalkyl-substituted phenyl or benzyl, R ^{3 '} for optionally halogen-substituted C ₁ -C ₈ alkyl, in each case optionally by C ₁ -C ₄ -alkyl, halogen, C ₁ -C ₄ -haloalkyl, C ₁ -C ₄ -alkoxy, C ₁ -C ₄ -haloalkoxy, nitro or cyano substituted phenyl or benzyl, R ^{4 '} and R ^{5 '} independently of one another are each optionally halogen-substituted C ₁ -C ₈ -alkyl, C ₁ -C ₈ -alkoxy, C ₁ -C ₈ -alkylamino, di- (C ₁ -C ₈ ) -alkylamino, C ₁ - C ₈ -alkylthio, C ₂ -C ₅ -alkenylthio, C ₂ -C ₅ -alkynylthio, C ₃ -C ₇ -cycloalkylthio, in each case optionally by halogen, nitro, cyano, C ₁ -C ₄ -alkoxy, C ₁ - C ₄ -haloalkoxy, C ₁ -C ₄ alkylthio, C ₁ -C ₄ haloalkylthio, C ₁ -C ₄ alkyl, C ₁ -C ₄ -halogenoalkyl-substituted phenyl, phenoxy or phenylthio; R ^{6 '} and R ^7' independently of one another are each optionally halogen-substituted C ₁ -C ₁₀ -alkyl, C ₁ -C ₁₀ -alkoxy, C ₃ -C ₈ -alkenyl, C ₁ -C ₈ -alkoxy-C ₁ - C ₈ -alkyl, optionally substituted by halogen, C ₁ -C ₆ haloalkyl, C ₁ -C ₆ alkyl or C ₁ -C ₆ alkoxy substituieres phenyl, optionally substituted by halogen, C ₁ -C ₆ alkyl, C ₁ -C ₆ haloalkyl or C ₁ -C ₆ -alkoxy-substituted benzyl or together represent an optionally interrupted by oxygen or sulfur, 5- to 6-membered ring which may optionally be substituted by C ₁ -C ₆ alkyl, and (c) at least one active substance of the formula (III)

wherein Hal represents chlorine, bromine or iodine, * denotes a carbon atom in the R or S configuration. A composition according to claim 1, wherein the component of the formula (I) is spirotetramate. A composition according to claim 1 or 2, wherein the components of formula (II) are selected from spirodiclofen and spiromesifen. A composition according to one or more of claims 1 to 3, wherein the compound of formula (III) (S) is 3-chloro-N ¹ - {2-methyl-4- [1,2,2,2-tetrafluoro-1- ( trifluoromethyl) ethyl] phenyl} -N ² - (1-methyl-2-methylsulfonylethyl) phthalamide. Use of compositions as in claims 1 to 4 defined, to combat animal pests. Use of a composition according to one or more of the claims 1 to 4 for the treatment of seeds. Use of compositions according to one or more of the claims 1 to 4 for the treatment of transgenic plants. Use of compositions according to one or more of the claims 1 to 4 for the treatment of seeds of transgenic plants. Seed having a composition according to a or more of the claims 1 to 4 was treated. Method of combating unwanted animal pests, characterized in that one composition according to a or more of the claims 1 to 4 on the unwanted animal pests and / or their habitat and / or seed. Process for the preparation of insecticidal and acaricidal Means, characterized in that compositions, such as in the claims 1 to 4, with extenders and / or surfactants mixed.