DE102005052918A1 - Cold-formable Ti alloy - Google Patents
Cold-formable Ti alloy Download PDFInfo
- Publication number
- DE102005052918A1 DE102005052918A1 DE200510052918 DE102005052918A DE102005052918A1 DE 102005052918 A1 DE102005052918 A1 DE 102005052918A1 DE 200510052918 DE200510052918 DE 200510052918 DE 102005052918 A DE102005052918 A DE 102005052918A DE 102005052918 A1 DE102005052918 A1 DE 102005052918A1
- Authority
- DE
- Germany
- Prior art keywords
- titanium alloy
- beta
- temperature
- cold
- transus
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 229910001069 Ti alloy Inorganic materials 0.000 title abstract 5
- 238000000137 annealing Methods 0.000 abstract 3
- 238000000034 method Methods 0.000 abstract 2
- 230000007704 transition Effects 0.000 abstract 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 abstract 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract 1
- 229910045601 alloy Inorganic materials 0.000 abstract 1
- 239000000956 alloy Substances 0.000 abstract 1
- 238000005275 alloying Methods 0.000 abstract 1
- 229910021535 alpha-beta titanium Inorganic materials 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 229910052750 molybdenum Inorganic materials 0.000 abstract 1
- 239000011733 molybdenum Substances 0.000 abstract 1
- 229910052720 vanadium Inorganic materials 0.000 abstract 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052726 zirconium Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C14/00—Alloys based on titanium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/16—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of other metals or alloys based thereon
- C22F1/18—High-melting or refractory metals or alloys based thereon
- C22F1/183—High-melting or refractory metals or alloys based thereon of titanium or alloys based thereon
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Forging (AREA)
Abstract
Die Erfindung ermöglicht es, Werkstücke aus Titanlegierungen in einem kostengünstigen Kaltverformungsverfahren zu fertigen. Dies wird erreicht mittels einer (alpha + beta)-Titanlegierung mit etwa 2-4,0 Gew.-% Aluminium, etwa 4-5,5 Gew.-% Vanadium und etwa 4,5-6,0 Gew.-% Molybdän, die durch die zusätzlichen Legierungsanteile von etwa 0,5-1,5 Gew.-% Zirkon und etwa 0,5-1,5 Gew.-% Zinn eine Kaltverformbarkeit bei ausreichender Festigkeit des gefertigten Werkstücks erlangt. Weiterhin wird die Kaltverformbarkeit erfindungsgemäß mittels eines Wärmebehandlungsverfahrens erzielt, mit den Schritten: Glühen der Titanlegierung bei einer unteren Glühtemperatur, welche zwischen 160 DEG bis 230 DEG unterhalb der Umwandlungstemperatur (beta-transus) liegt, und Abkühlen der Titanlegierung auf Umgebungstemperatur. Die Titanlegierung wird vorzugsweise zuvor bei einer oberen Glühtemperatur geglüht, welche 50 DEG und 100 DEG unterhalb der Umwandlungstemperatur (beta-transus) liegt.The invention makes it possible to manufacture workpieces of titanium alloys in a cost-effective cold forming process. This is achieved by using an alpha-beta titanium alloy containing about 2-4.0 wt% aluminum, about 4-5.5 wt% vanadium, and about 4.5-6.0 wt% molybdenum which, due to the additional alloying proportions of about 0.5-1.5% by weight of zirconium and about 0.5-1.5% by weight of tin, achieves cold workability with sufficient strength of the finished workpiece. Furthermore, the cold workability is achieved according to the invention by means of a heat treatment process, comprising the steps of: annealing the titanium alloy at a lower annealing temperature which is between 160 ° and 230 ° below the transition temperature (beta-transus), and cooling the titanium alloy to ambient temperature. The titanium alloy is preferably preliminarily annealed at an upper annealing temperature which is 50 ° and 100 ° below the transition temperature (beta-transus).
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE200510052918 DE102005052918A1 (en) | 2005-11-03 | 2005-11-03 | Cold-formable Ti alloy |
| EP06806675A EP1945827B1 (en) | 2005-11-03 | 2006-11-03 | Cold-workable ti alloy |
| PCT/EP2006/010569 WO2007051637A1 (en) | 2005-11-03 | 2006-11-03 | Cold-workable ti alloy |
| ES06806675T ES2387684T3 (en) | 2005-11-03 | 2006-11-03 | Cold deformable Ti alloy |
| JP2008539310A JP5210874B2 (en) | 2005-11-03 | 2006-11-03 | Cold workable titanium alloy |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE200510052918 DE102005052918A1 (en) | 2005-11-03 | 2005-11-03 | Cold-formable Ti alloy |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE102005052918A1 true DE102005052918A1 (en) | 2007-05-16 |
Family
ID=37556272
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE200510052918 Withdrawn DE102005052918A1 (en) | 2005-11-03 | 2005-11-03 | Cold-formable Ti alloy |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP1945827B1 (en) |
| JP (1) | JP5210874B2 (en) |
| DE (1) | DE102005052918A1 (en) |
| ES (1) | ES2387684T3 (en) |
| WO (1) | WO2007051637A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102007040132A1 (en) * | 2007-08-24 | 2009-02-26 | Gfe Fremat Gmbh | Process for producing tapes or films of TiAl6V4 |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011058594A (en) * | 2009-09-14 | 2011-03-24 | Beta Titanium:Kk | Wheel fastening part |
| CN108893631B (en) * | 2018-08-03 | 2020-11-13 | 燕山大学 | High-strength titanium alloy and preparation method thereof |
| CN110396622A (en) * | 2019-07-30 | 2019-11-01 | 中国船舶重工集团公司第七二五研究所 | A kind of medium-strength and ultra-high toughness titanium alloy and preparation method thereof |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1142445B (en) * | 1953-11-26 | 1963-01-17 | Crucible Steel International S | Use of titanium alloys to make parts that remain ductile after welding |
| DE2635188A1 (en) * | 1976-08-05 | 1978-02-09 | Bosch Gmbh Robert | High tensile, cold headed bolts, screws etc. - made from patented rod or wire and then tempered |
| US4842652A (en) * | 1987-11-19 | 1989-06-27 | United Technologies Corporation | Method for improving fracture toughness of high strength titanium alloy |
| RU1584408C (en) * | 1988-04-12 | 1994-10-15 | Всероссийский научно-исследовательский институт авиационных материалов | Titanium-based alloy |
| DE69024418T2 (en) * | 1989-07-10 | 1996-05-15 | Nippon Kokan Kk | Titanium-based alloy and process for its superplastic shaping |
| US5679183A (en) * | 1994-12-05 | 1997-10-21 | Nkk Corporation | Method for making α+β titanium alloy |
| DE69414529T2 (en) * | 1993-12-07 | 1999-07-15 | Hitachi Metals, Ltd., Tokio/Tokyo | Fe-based superalloy |
| RU2211873C2 (en) * | 2001-11-22 | 2003-09-10 | ОАО Верхнесалдинское металлургическое производственное объединение | METASTABLE β-TITANIUM ALLOY |
| DE69905963T2 (en) * | 1998-04-21 | 2004-01-22 | Kabushiki Kaisha Kobe Seiko Sho Also Known As Kobe Steel Ltd. | Wire rod or steel bars with good cold formability and machine parts made from them |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61106758A (en) * | 1984-10-30 | 1986-05-24 | Sumitomo Metal Ind Ltd | Heat treatment method for α+β type titanium alloy |
| JP2536673B2 (en) * | 1989-08-29 | 1996-09-18 | 日本鋼管株式会社 | Heat treatment method for titanium alloy material for cold working |
| JPH0841565A (en) * | 1994-07-29 | 1996-02-13 | Mitsubishi Materials Corp | Ti alloy castings with high strength and high toughness |
| JPH08134615A (en) * | 1994-11-10 | 1996-05-28 | Kobe Steel Ltd | Production of high strength titanium alloy excellent in characteristic of balance of mechanical property |
| US5697183A (en) | 1995-07-07 | 1997-12-16 | Sound Inventions, Inc. | Fishing rod holding device |
| JP3310155B2 (en) * | 1996-02-26 | 2002-07-29 | 新日本製鐵株式会社 | Manufacturing method of seamless pipe of α + β type titanium alloy with excellent fracture toughness |
| US6284070B1 (en) * | 1999-08-27 | 2001-09-04 | General Electric Company | Heat treatment for improved properties of alpha-beta titanium-base alloys |
| JP4019668B2 (en) * | 2001-09-05 | 2007-12-12 | Jfeスチール株式会社 | High toughness titanium alloy material and manufacturing method thereof |
| JP4216497B2 (en) * | 2001-10-17 | 2009-01-28 | 株式会社田中 | Titanium alloy screw part manufacturing method and titanium alloy screw part using the same |
| JP2003201530A (en) * | 2001-10-22 | 2003-07-18 | Kobe Steel Ltd | High-strength titanium alloy with excellent hot workability |
| DE10329899B8 (en) * | 2003-07-03 | 2005-05-19 | Deutsche Titan Gmbh | Beta titanium alloy, process for producing a hot rolled product from such alloy and its uses |
| DE602004010138T2 (en) * | 2003-08-05 | 2008-08-28 | Dynamet Holdings Inc., Wilmington | METHOD FOR PRODUCING PARTS FROM TITANIUM OR A TITANIUM ALLOY |
| DE102004022458B4 (en) * | 2004-04-29 | 2006-01-19 | Leibniz-Institut Für Festkörper- Und Werkstoffforschung Dresden E.V. | Cold-formable titanium-based alloy bodies and process for their production |
-
2005
- 2005-11-03 DE DE200510052918 patent/DE102005052918A1/en not_active Withdrawn
-
2006
- 2006-11-03 WO PCT/EP2006/010569 patent/WO2007051637A1/en not_active Ceased
- 2006-11-03 JP JP2008539310A patent/JP5210874B2/en not_active Expired - Fee Related
- 2006-11-03 ES ES06806675T patent/ES2387684T3/en active Active
- 2006-11-03 EP EP06806675A patent/EP1945827B1/en not_active Not-in-force
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1142445B (en) * | 1953-11-26 | 1963-01-17 | Crucible Steel International S | Use of titanium alloys to make parts that remain ductile after welding |
| DE2635188A1 (en) * | 1976-08-05 | 1978-02-09 | Bosch Gmbh Robert | High tensile, cold headed bolts, screws etc. - made from patented rod or wire and then tempered |
| US4842652A (en) * | 1987-11-19 | 1989-06-27 | United Technologies Corporation | Method for improving fracture toughness of high strength titanium alloy |
| RU1584408C (en) * | 1988-04-12 | 1994-10-15 | Всероссийский научно-исследовательский институт авиационных материалов | Titanium-based alloy |
| DE69024418T2 (en) * | 1989-07-10 | 1996-05-15 | Nippon Kokan Kk | Titanium-based alloy and process for its superplastic shaping |
| DE69414529T2 (en) * | 1993-12-07 | 1999-07-15 | Hitachi Metals, Ltd., Tokio/Tokyo | Fe-based superalloy |
| US5679183A (en) * | 1994-12-05 | 1997-10-21 | Nkk Corporation | Method for making α+β titanium alloy |
| DE69905963T2 (en) * | 1998-04-21 | 2004-01-22 | Kabushiki Kaisha Kobe Seiko Sho Also Known As Kobe Steel Ltd. | Wire rod or steel bars with good cold formability and machine parts made from them |
| RU2211873C2 (en) * | 2001-11-22 | 2003-09-10 | ОАО Верхнесалдинское металлургическое производственное объединение | METASTABLE β-TITANIUM ALLOY |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102007040132A1 (en) * | 2007-08-24 | 2009-02-26 | Gfe Fremat Gmbh | Process for producing tapes or films of TiAl6V4 |
| US7976649B2 (en) | 2007-08-24 | 2011-07-12 | Gfe Fremat Gmbh | Method of fabricating strips or foils, respectively, from TiAl6V4 |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2007051637A1 (en) | 2007-05-10 |
| EP1945827B1 (en) | 2012-05-30 |
| EP1945827A1 (en) | 2008-07-23 |
| JP2009515047A (en) | 2009-04-09 |
| ES2387684T3 (en) | 2012-09-28 |
| JP5210874B2 (en) | 2013-06-12 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OP8 | Request for examination as to paragraph 44 patent law | ||
| R016 | Response to examination communication | ||
| R119 | Application deemed withdrawn, or ip right lapsed, due to non-payment of renewal fee |
Effective date: 20130601 |