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DE102005031224A1 - Alternative utilization variant for biogas plants - Google Patents

Alternative utilization variant for biogas plants Download PDF

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DE102005031224A1
DE102005031224A1 DE102005031224A DE102005031224A DE102005031224A1 DE 102005031224 A1 DE102005031224 A1 DE 102005031224A1 DE 102005031224 A DE102005031224 A DE 102005031224A DE 102005031224 A DE102005031224 A DE 102005031224A DE 102005031224 A1 DE102005031224 A1 DE 102005031224A1
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biogas
biogas plants
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Hans-Juergen Dopheide
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    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
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    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/09Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis
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    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M21/00Bioreactors or fermenters specially adapted for specific uses
    • C12M21/04Bioreactors or fermenters specially adapted for specific uses for producing gas, e.g. biogas
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    • C12M21/00Bioreactors or fermenters specially adapted for specific uses
    • C12M21/12Bioreactors or fermenters specially adapted for specific uses for producing fuels or solvents
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    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M23/00Constructional details, e.g. recesses, hinges
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    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M43/00Combinations of bioreactors or fermenters with other apparatus
    • C12M43/02Bioreactors or fermenters combined with devices for liquid fuel extraction; Biorefineries
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M47/00Means for after-treatment of the produced biomass or of the fermentation or metabolic products, e.g. storage of biomass
    • C12M47/18Gas cleaning, e.g. scrubbers; Separation of different gases
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12PFERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P5/00Preparation of hydrocarbons or halogenated hydrocarbons
    • C12P5/02Preparation of hydrocarbons or halogenated hydrocarbons acyclic
    • C12P5/023Methane
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel

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Abstract

Biogasanlagen für nachwachsende Rohstoffe und/oder ähnliche Substrate produzieren nach dem Stand der Technik Methangas zur Verstromung mit Blockheizkraftwerken oder zur direkten Einspeisung in das Gasleitungsnetz.
Dieses macht die Biogasanlagen abhängig vom Vorhandensein von Strom- oder Gasleitungsnetzen, von den Abnehmern für die Verlustwärmemengen des Blockheizkraftwerks und von den im Energieeinspeisegesetz jeweils festgelegten Einspeisebedingungen.
Die erfindungsgemäße alternative Nutzungsvariante für Biogasanlagen soll diese Nachteile ausgleichen, indem das gewonnene Methan an Ort und Stelle in Methanol umgewandelt und, gekoppelt an den jeweiligen Benzinpreis, vorzugssweise als Treibstoff für Kraftfahrzeuge vermarktet wird.
Biogasanlagen und ihr Betrieb erhalten auf diese Weise eine zukunftssichere, subventionsfreie und profitablere Grundlage.
Biogas plants for renewable raw materials and / or similar substrates produce according to the state of the art methane gas for power generation with combined heat and power plants or for direct feed into the gas pipeline network.
This makes the biogas plants dependent on the presence of electricity or gas networks, of the customers for the heat loss amounts of the combined heat and power plant and of the feed conditions specified in the energy supply law.
The alternative use variant according to the invention for biogas plants is intended to compensate for these disadvantages by converting the methane obtained into methanol on the spot and, preferably, coupled to the respective price of gasoline, as a fuel for motor vehicles.
Biogas plants and their operations thus receive a future-proof, subsidy-free and more profitable basis.

Figure 00000001
Figure 00000001

Description

Die Nutzung der gewonnenen Methangasmengen aus Biogasanlagen für nachwachsende Rohstoffe und/oder organische Abfälle sowie ähnliche Substrate erfolgt nach dem heutigen Stand der Technik in der Weise, dass das Methangas entweder als Treibstoff für Blockheizkraftwerke zur Erzeugung von Strom und Wärme genutzt oder zu weiterer Nutzung in das Erdgasnetz eingespeist wird.The Use of recovered methane gas from biogas plants for renewable raw materials and / or organic waste as well as similar Substrates according to the state of the art in the way that the methane gas either as fuel for combined heat and power plants to produce Electricity and heat used or fed into the natural gas grid for further use.

Beide Nutzungsarten engen die Flexibilität bei der Auswahl des günstigsten Standortes der Biogasanlage ein, weil diese möglichst nah am Strom- oder Gasleitungsnetz platziert sein soll, obwohl es wegen der Anfuhrkosten der Substrate besser wäre, die Anlage dort zu bauen, wo die Pflanzen wachsen.Both Usage types narrow the flexibility in choosing the cheapest Location of the biogas plant, because this as close as possible to the electricity or Gas pipeline network should be placed, although it because of the delivery costs the substrates would be better, the Plant to build where the plants grow.

Noch schwieriger wird die Auswahl des Standortes, wenn auch noch die Nähe eines Abnehmers für die bei der Verstromung durch das Blockheizkraftwerk anfallenden Wärmemengen gesucht werden muss, was oft zu einem mühsamen Spagat zwischen Einspeisepunkt und Wärmeabnehmer führt. Die für den Transport sowohl der erzeugten elektrischen als auch der thermischen Energie notwendigen Leitungen sind teuer und führen darüber hinaus zu spürbaren Verlusten.Yet the selection of the location becomes more difficult, though still the Near one Customer for the resulting from the power generation by the combined heat and power plant amounts of heat must be sought, which is often a tedious balancing act between entry point and heat consumer leads. The for the Transport of both the generated electrical and the thermal Energy necessary lines are expensive and also lead to noticeable losses.

Nachteilig ist bei der Biogasnutzung nach dem Stand der Technik auch die Tatsache, dass die Wirtschaftlichkeit der Biogasanlagen erst durch die stützende Subvention durch das Energieeinspeisegesetz gewährleistet wird, welche je nach der politischen Zielrichtung der jeweiligen Regierung ganz oder teilweise in Fortfall geraten kann.adversely in the biogas utilization of the prior art is also the fact that the profitability of the biogas plants only by the supporting subsidy guaranteed by the energy feed law, whichever is the political direction of the respective government completely or may be partially eliminated.

Es ist deshalb Ziel der Erfindung, eine alternative Nutzungsvariante zu schaffen, welche frei von den geschilderten Nachteilen ist.It is therefore the aim of the invention, an alternative use variant to create, which is free of the disadvantages described.

Dieses Ziel wird dadurch erreicht, dass das in der Biogasanlage gewonnene Biogas an Ort und Stelle zu reinem Methangas aufbereitet und in einer Cracking-Anlage zu Methanol gewandelt wird, das sich als Treibstoff etwa für Kraftfahrzeuge ohne weitere Bearbeitung einfach und gewinnbringend ohne Subventionen zu steigenden Marktpreisen verkaufen lässt.This The goal is achieved by using the biogas plant Biogas processed on site to pure methane gas and in a cracking plant is converted to methanol, which turns out to be fuel about for Motor vehicles without further processing simple and profitable sell without subsidies at rising market prices.

Die Vorteile liegen auf der Hand:

  • – Kein Blockheizkraftwerk, keine Stromeinspeisung in das Stromnetz
  • – Keine Wärmeverluste im BHKW, deshalb kein Fernwärmeverkauf
  • – Kein Transformator und keine Stromleitungen ins Netz erforderlich
  • – Keine Standortabhängigkeit vom Stromnetz oder Wärmeabnehmer
  • – Keine Energieverluste auf dem Leitungsweg bis zur Einspeisestelle
  • – Keine weiten Transportwege für die Substrate
  • – Keine Abhängigkeit von den nicht sicheren Einspeisevergütungen des EEG
  • – Kein Bonusverlust bei kovergärung mit Abfällen, da vom EEG unabhängig
  • – Keine Rückbauverpflichtung für Anlagen im Außenbereich nach 20 Jahren
The advantages are apparent:
  • - No combined heat and power plant, no electricity fed into the power grid
  • - No heat loss in the CHP, therefore no district heating sales
  • - No transformer and no power lines required in the grid
  • - No location dependency on the electricity grid or heat consumer
  • - No energy losses on the line to the feed point
  • - No long transport routes for the substrates
  • - No dependence on the non-safe feed-in tariffs of the EEG
  • - No bonus loss in co-fermentation with waste, as independent from the EEG
  • - No decommissioning obligation for outdoor facilities after 20 years

Es wird erwartet, dass die Investitions- und Betriebskosten der erfindungsgemäßen Alternativen Nutzungsvariante für Biogasanlagen deutlich unter denen der nach dem Stand der Technik errichteten und betriebenen Biogasanlagen liegen werden.It It is expected that the investment and operating costs of the alternatives of use according to the invention for biogas plants significantly below those of the state of the art and built operated biogas plants will be.

Claims (4)

Alternative Nutzungsvariante für Biogasanlagen, dadurch gekennzeichnet, dass das in einer Biogasanlage (1 bis 3) gewonnene Methangas (CH4) vorzugsweise an Ort und Stelle und von einer direkt an die Biogasanlage angebundenen Cracking-Anlage (5) zu Methanol (CH3OH) umgewandelt wird.Alternative utilization variant for biogas plants, characterized in that in a biogas plant ( 1 to 3 ) obtained methane gas (CH 4 ) preferably in place and from a directly connected to the biogas plant cracking plant ( 5 ) is converted to methanol (CH 3 OH). Alternative Nutzungsvariante für Biogasanlagen nach Anspruch 1, dadurch gekennzeichnet, dass das in einer Biogasanlage (1 bis 3) gewonnene Gasgemisch aus Methan, Kohlendioxyd, Schwefelsäure, Ammoniak, Wasserdampf und anderen Bestandteilen in einer der Cracking-Anlage nach Anspruch 1 (5) vorgeschalteten, vorzugsweise als Aktivkohlereinigungsanlage ausgebildeten Biogasaufbereitungsanlage (4) vorzugsweise unter Anwendung verschiedener Temperaturen und Drücke und weiterer Reinigungsprozesse aufbereitet und als praktisch reines Methangas isoliert und der Cracking-Anlage nach Anspruch 1 (5) zugeführt wird.Alternative utilization variant for biogas plants according to claim 1, characterized in that in a biogas plant ( 1 to 3 ) obtained gas mixture of methane, carbon dioxide, sulfuric acid, ammonia, water vapor and other constituents in one of the cracking system according to claim 1 ( 5 ) upstream, preferably designed as an activated carbon cleaning plant biogas upgrading plant ( 4 ) is preferably treated using various temperatures and pressures and further purification processes and isolated as practically pure methane gas and the cracking system according to claim 1 ( 5 ) is supplied. Alternative Nutzungsvariante für Biogasanlagen nach Anspruch 1 und 2, dadurch gekennzeichnet, dass in der Cracking-Anlage nach Anspruch 1 (5) die Methan-Moleküle vorzugsweise unter Hinzufügung von Wasser-Molekülen bei hoher Temperatur und hohem Druck mit Hilfe eines geeigneten Katalysators zu Methanol (CH3OH) und reinem Wasserstoff (H2) umgewandelt werden.Alternative utilization variant for biogas plants according to claim 1 and 2, characterized in that in the cracking system according to claim 1 ( 5 ) the methane molecules preferably with the addition of water molecules at high temperature and high pressure with the aid of a suitable catalyst to methanol (CH 3 OH) and pure hydrogen (H 2 ) to be converted. Alternative Nutzungsvariante für Biogasanlagen nach Anspruch 1, 2 und 3, dadurch gekennzeichnet, dass der in der Cracking-Anlage nach Anspruch 1 (5) gewonnene reine Wasserstoff nicht mit dem gewonnenen, flüssigen Methanol in den Methanol-Lagertank (5) geleitet, sondern zurück in die Fermenter (1 und 2) geführt, wird, wo er den Anaerobbakterien als Futter für die Produktion von weiterem Methangas dient.Alternative utilization variant for biogas plants according to claim 1, 2 and 3, characterized in that in the cracking system according to claim 1 ( 5 ) recovered pure hydrogen not with the recovered, liquid methanol in the methanol storage tank ( 5 ), but back into the Fermenter ( 1 and 2 ), where it serves the anaerobic bacteria as feed for the production of further methane gas.
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009021710A2 (en) 2007-08-16 2009-02-19 Dge Dr.-Ing. Günther Engineering Gmbh Method and system for the production of synthethic gas made from biogas

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009021710A2 (en) 2007-08-16 2009-02-19 Dge Dr.-Ing. Günther Engineering Gmbh Method and system for the production of synthethic gas made from biogas
WO2009021710A3 (en) * 2007-08-16 2009-05-14 Dge Dr Ing Guenther Engineerin Method and system for the production of synthethic gas made from biogas
US8187568B2 (en) 2007-08-16 2012-05-29 DGE Dr. Ing. Guenther Engineering GmbH Method and plant for the production of synthesis gas from biogas

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