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DE102005030929A1 - Core for producing metallic cast parts comprises a base material based on salt or carbon and inorganic and/or organic binders for hardening during the production and maintenance during casting - Google Patents

Core for producing metallic cast parts comprises a base material based on salt or carbon and inorganic and/or organic binders for hardening during the production and maintenance during casting Download PDF

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Publication number
DE102005030929A1
DE102005030929A1 DE102005030929A DE102005030929A DE102005030929A1 DE 102005030929 A1 DE102005030929 A1 DE 102005030929A1 DE 102005030929 A DE102005030929 A DE 102005030929A DE 102005030929 A DE102005030929 A DE 102005030929A DE 102005030929 A1 DE102005030929 A1 DE 102005030929A1
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Germany
Prior art keywords
cores according
cast cores
cast
base material
carbon
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DE102005030929A
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German (de)
Inventor
Gudrun Dipl.-Ing. Schiller
Dieter Käfer
Gisbert Dipl.-Ing. Schulze
Peter Dr. Stingl
Christos G. Prof. Dr.-Ing. Aneziris
Jana Dipl.-Ing. Hubálková
Antje Kynast
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Ceramtec GmbH
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Ceramtec GmbH
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Priority to DE102005030929A priority Critical patent/DE102005030929A1/en
Publication of DE102005030929A1 publication Critical patent/DE102005030929A1/en
Withdrawn legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/24Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B12/00Cements not provided for in groups C04B7/00 - C04B11/00
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/22Natural resins, e.g. rosin
    • C04B26/24Cellulosic waste liquor, e.g. sulfite lye
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/005Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing gelatineous or gel forming binders, e.g. gelatineous Al(OH)3, sol-gel binders
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/06Aluminous cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/10Lime cements or magnesium oxide cements
    • C04B28/105Magnesium oxide or magnesium carbonate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/30Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing magnesium cements or similar cements
    • C04B28/32Magnesium oxychloride cements, e.g. Sorel cement
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00939Uses not provided for elsewhere in C04B2111/00 for the fabrication of moulds or cores

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Molds, Cores, And Manufacturing Methods Thereof (AREA)
  • Mold Materials And Core Materials (AREA)

Abstract

Core comprises a base material based on salt or carbon and inorganic and/or organic binders for hardening during the production and maintenance during casting.

Description

Die Erfindung betrifft Gusskerne aus einem Werkstoff auf der Basis von Salz oder Kohlenstoff zur Verwendung bei der Herstellung von metallischen Gussteilen.The The invention relates to cast cores made of a material based on Salt or carbon for use in the manufacture of metallic castings.

Bei der Herstellung metallischer Gussteile ist es notwendig, in den Gussteilen vorgesehene Hohlräume in der Gießform durch Formkörper auszufüllen, die die Konturen des Hohlraums genau ausfüllen. Diese Formkörper sind die sogenannten Gusskerne, die die Funktion eines Platzhalters für den späteren Hohlraum einnehmen. Die Anforderungen, die an die Gusskerne gestellt werden, sind hoch. Sie müssen sich leicht herstellen lassen, formstabil und konturengenau sein, die für ihre Herstellung verwendeten Werkstoffe sollen weder die Umwelt belasten, noch gesundheitliche Gefährdungen verursachen und schließlich sollen nach dem Guss die Rückstände eines Kerns möglichst einfach, schnell und vollständig entfernt werden können.at In the production of metallic castings it is necessary in the Castings provided cavities in the mold through moldings fill, which exactly fill the contours of the cavity. These shaped bodies are the so-called casting cores, which serve the function of a placeholder for the later cavity taking. The requirements placed on the casting cores are high. You need to be easy to produce, dimensionally stable and contoured, the for The materials used in their production should not harm the environment burden, still cause health hazards and eventually should after casting the residues of a Kerns as possible easy, fast and complete can be removed.

Um diese Anforderungen zu erfüllen, werden auf das zu gießende Metall und das daraus resultierende Gießverfahren abgestimmte Werkstoffe für die Gusskerne verwendet, wobei den dabei verwendeten Bindemitteln eine besondere Bedeutung zukommt. Einerseits müssen die Kerne bei Gießtemperatur formstabil sein, andererseits müssen sich die Kerne nach dem Guß leicht und vollständig entfernen lassen.Around to meet these requirements will be on the to be poured Metal and the resulting casting process matched materials for the casting cores used, with the binders used a special Meaning. On the one hand, have to the cores are dimensionally stable at casting temperature on the other hand have to be the cores are easy after casting and completely have it removed.

Aufgabe der vorliegenden Erfindung ist es, Gusskerne aus einem keramischen Werkstoff vorzustellen, welche beim Gießen die notwendige Festigkeit gewährleisten und sich leicht und vollständig entfernen lassen.task The present invention is to cast cores from a ceramic To present material, which during casting the necessary strength guarantee and easy and complete have it removed.

Die Aufgabe wird durch die in den Ansprüchen beanspruchten Merkmale gelöst. Die Herstellung der erfindungsgemäßen keramischen Gusskerne erfolgt nach Verfahren, wie sie zur Herstellung von Formteilen in der keramischen Technologie bekannt sind.The The object is achieved by the features claimed in the claims solved. The production of the ceramic casting cores according to the invention takes place by processes such as those used to produce molded parts in the ceramic Technology are known.

Claims (29)

Gusskerne zur Verwendung bei der Herstellung von metallischen Gussteilen, vorzugsweise Aluminiumformteilen, dadurch gekennzeichnet, dass sie aus Grundwerkstoffen auf der Basis von Salz oder Kohlenstoff bestehen und dass anorganische und/oder organische Bindemittel vorgesehen sind zur Verfestigung bei der Herstellung und Formerhaltung beim Gießen.Cast cores for use in the production of metallic castings, preferably aluminum moldings, characterized in that they consist of base materials based on salt or carbon and that inorganic and / or organic binders are provided for solidification in the production and shape retention during casting. Gusskerne nach Anspruch 1, dadurch gekennzeichnet, dass der Grundwerkstoff auf der Basis von Kohlenstoff Grafit ist.Cast cores according to Claim 1, characterized the base material is based on carbon graphite. Gusskerne nach Anspruch 1, dadurch gekennzeichnet, dass der Grundwerkstoff auf der Basis von Kohlenstoff Bakelitharz ist.Cast cores according to Claim 1, characterized that the base material is based on carbon bakelite resin is. Gusskerne nach Anspruch 1, dadurch gekennzeichnet, dass der Grundwerkstoff auf der Basis von Kohlenstoff Novolak oder Resol-Harze ist.Cast cores according to Claim 1, characterized that the base material is based on carbon novolac or Resole Resins is. Gusskerne nach Anspruch 1, dadurch gekennzeichnet, dass der Grundwerkstoff auf der Basis von Kohlenstoff Carbores ist.Cast cores according to Claim 1, characterized that the base material based on carbon is carbores. Gusskerne nach Anspruch 1, dadurch gekennzeichnet, dass der Grundwerkstoff auf der Basis von Kohlenstoff Epoxy-Harze sind.Cast cores according to Claim 1, characterized that the base material is based on carbon epoxy resins are. Gusskerne nach Anspruch 1, dadurch gekennzeichnet, dass der Grundwerkstoff auf der Basis von Kohlenstoff Pech ist.Cast cores according to Claim 1, characterized that the base material based on carbon is pitch. Gusskerne nach einem der Ansprüche 1 bis 7, dadurch gekennzeichnet, dass das Bindemittel hochaktive Kieselsäure, insbesondere Diatomeenerde, ist.Cast cores according to one of Claims 1 to 7, characterized the binder is highly active silicic acid, in particular diatomaceous earth. Gusskerne nach Anspruch 8, dadurch gekennzeichnet, dass der Anteil an Kieselsäure im Bereich von 0,1 % bis 10 Gew.% liegt.Cast cores according to claim 8, characterized in that that the proportion of silica in the range of 0.1% to 10% by weight. Gusskerne nach einem der Ansprüche 1 bis 7, dadurch gekennzeichnet, dass das Bindemittel nanoskaliges SiO2 ist.Cast cores according to one of claims 1 to 7, characterized in that the binder is nanoscale SiO 2 . Gusskerne nach Anspruch 10, dadurch gekennzeichnet, dass der Anteil an nanoskaligem SiO2 im Bereich von 0,1 % bis 40 Gew.% liegt.Cast cores according to claim 10, characterized in that the proportion of nanoscale SiO 2 is in the range of 0.1% to 40% by weight. Gusskerne nach einem der Ansprüche 1 bis 7, dadurch gekennzeichnet, dass das Bindemittel nanoskaliges TiO2 ist.Cast cores according to one of claims 1 to 7, characterized in that the binder is nanoscale TiO 2 . Gusskerne nach Anspruch 12, dadurch gekennzeichnet, dass der Anteil an nanoskaligem TiO2 im Bereich von 0,1 % bis 40 Gew.% liegt.Cast cores according to claim 12, characterized in that the proportion of nanoscale TiO 2 is in the range of 0.1% to 40% by weight. Gusskerne einem der Ansprüche 1 bis 7, gekennzeichnet durch eine Kombination der Bindemittel aus nanoskaligem TiO2 und SiO2.Cast cores according to one of Claims 1 to 7, characterized by a combination of the nanosize TiO 2 and SiO 2 binders. Gusskerne nach Anspruch 14, dadurch gekennzeichnet, dass der Anteil der Kombination von nanoskaligem TiO2 und SiO2 im Bereich von 0,1 % bis 60 Gew.% liegt.Cast cores according to claim 14, characterized in that the proportion of the combination of nanoscale TiO 2 and SiO 2 is in the range of 0.1% to 60% by weight. Gusskerne nach einem der Ansprüche 1 bis 7, dadurch gekennzeichnet, dass das Bindemittel Tonerdezement ist.Cast cores according to one of claims 1 to 7, characterized in that the binder Alumina cement is. Gusskerne nach Anspruch 16, dadurch gekennzeichnet, dass der Anteil an Tonerdezement im Bereich von 0,1 % bis 10 Gew.% liegt.Cast cores according to Claim 16, characterized the proportion of alumina cement ranges from 0.1% to 10% by weight lies. Gusskerne nach einem der Ansprüche 1 bis 7, dadurch gekennzeichnet, dass das Bindemittel Sorelzement ist.Cast cores according to one of Claims 1 to 7, characterized that the binder is sorrel cement. Gusskerne nach Anspruch 18, dadurch gekennzeichnet, dass der Anteil an Sorelzement im Bereich von 0,1 % bis 10 Gew.% liegt.Cast cores according to Claim 18, characterized that the content of corrosive cement ranges from 0.1% to 10% by weight lies. Gusskerne nach einem der Ansprüche 1 bis 7, dadurch gekennzeichnet, dass das Bindemittel feindisperses MgO und/oder feindisperser Spinell sind.Cast cores according to one of Claims 1 to 7, characterized the binder is finely dispersed MgO and / or finely dispersed spinel. Gusskerne nach Anspruch 20, dadurch gekennzeichnet, dass der Anteil an feindispersem MgO und/oder feindispersem Spinell im Bereich von 0,1 % bis 40 Gew.% liegt.Cast cores according to Claim 20, characterized the proportion of finely dispersed MgO and / or finely dispersed spinel in the range of 0.1% to 40% by weight. Gusskerne nach einem der Ansprüche 1 bis 7, dadurch gekennzeichnet, dass das Bindemittel Lignin und/oder Ligninsulfonate sind.Cast cores according to one of Claims 1 to 7, characterized the binder is lignin and / or ligninsulfonates. Gusskerne nach Anspruch 22, dadurch gekennzeichnet, dass der Anteil an Lignin und/oder Ligninsulfonaten im Bereich von 0,1 % bis 10 Gew.% liegt.Cast cores according to Claim 22, characterized the proportion of lignin and / or ligninsulphonates is in the range of 0.1% to 10% by weight. Gusskerne nach einem der Ansprüche 1 bis 7, dadurch gekennzeichnet, dass das Bindemittel Hydroxide, vorzugsweise Aluminiumhydroxid, sind.Cast cores according to one of Claims 1 to 7, characterized that the binder hydroxides, preferably aluminum hydroxide, are. Gusskerne nach Anspruch 24, dadurch gekennzeichnet, dass der Anteil an Hydroxiden beim Grundwerkstoff Salz im Bereich von 0,1 % bis 5 Gew.% liegt.Cast cores according to Claim 24, characterized that the proportion of hydroxides in the base material salt in the range from 0.1% to 5% by weight. Gusskerne nach Anspruch 24, dadurch gekennzeichnet, dass der Anteil an Hydroxiden beim Grundwerkstoff Kohlenstoff im Bereich von 0,1 % bis 10 Gew.% liegt.Cast cores according to Claim 24, characterized that the proportion of hydroxides in the base material carbon in the Range from 0.1% to 10% by weight. Gusskerne nach einem der Ansprüche 8 bis 26, dadurch gekennzeichnet, dass das Bindersystem aus einer Kombination der in diesen Ansprüchen genannten Bindemittel besteht.Cast cores according to one of Claims 8 to 26, characterized that the binder system of a combination of those mentioned in these claims Binder exists. Gusskerne nach einem der Ansprüche 1 bis 27, dadurch gekennzeichnet, dass die Gusskerne zur Herstellung von Aluminiumformteilen verwendet werden.Cast cores according to one of Claims 1 to 27, characterized that the cores used for the production of aluminum moldings become. Gusskerne nach Anspruch 28, dadurch gekennzeichnet, dass die Gusskerne zur Herstellung von Kolben für Automobilanwendungen verwendet werden.Cast cores according to Claim 28, characterized that the cores are used to make pistons for automotive applications.
DE102005030929A 2004-07-23 2005-07-02 Core for producing metallic cast parts comprises a base material based on salt or carbon and inorganic and/or organic binders for hardening during the production and maintenance during casting Withdrawn DE102005030929A1 (en)

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DE102005030929A DE102005030929A1 (en) 2004-07-23 2005-07-02 Core for producing metallic cast parts comprises a base material based on salt or carbon and inorganic and/or organic binders for hardening during the production and maintenance during casting

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
DE102004035977 2004-07-23
DE102004035976 2004-07-23
DE102004035976.8 2004-07-23
DE102004035977.6 2004-07-23
DE102005030929A DE102005030929A1 (en) 2004-07-23 2005-07-02 Core for producing metallic cast parts comprises a base material based on salt or carbon and inorganic and/or organic binders for hardening during the production and maintenance during casting

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102006031700A1 (en) * 2006-07-08 2008-01-10 Refratechnik Holding Gmbh Process for the production of basic carbonaceous products by casting and / or molding

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102006031700A1 (en) * 2006-07-08 2008-01-10 Refratechnik Holding Gmbh Process for the production of basic carbonaceous products by casting and / or molding

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8127 New person/name/address of the applicant

Owner name: CERAMTEC AG, 73207 PLOCHINGEN, DE

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Owner name: CERAMTEC GMBH, 73207 PLOCHINGEN, DE

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