DE102005026004A1 - Cosmetic preparations containing a special aniseed extract and higher polyols - Google Patents

Abstract

Cosmetic preparation containing DOLLAR A (a) an aqueous extract from anise (Pimpinella anis fruit extract), available under the trade name Bioxilift from SILAB, St. Viance, France, (b) and one or more substances selected from the group methylpropanediol, dipropylene glycol, 1,2-hexanediol, 1,6-hexanediol, 1,2-octanediol, ethylhexylglycerol.

Description

The The present invention relates to cosmetic preparations containing an aqueous one Fruit extract from anise (Pimpinella anis fruit extract), under which Trade name Bioxilift in the company SILAB, St. Viance, France, available and one or more higher ones Polyols.

Under Cosmetics can take all measures to summarize the aesthetic establish changes on the skin and hair or for body cleansing. Cosmetics means, therefore, the external appearance too cultivate, improve and beautify, in order to be visible, tangible and smelling way to please fellow human beings as well as oneself. Thousands of years ago, man made cosmetics for this purpose applied. One dyed Lips and face, anointed with precious oils and bathed in fragrant Water.

Nice For a long time the professional world has been searching for cosmetic Preparations effective against wrinkles or cellulite.

A for the Consumers very essential, but difficult to quantitative measurable Property of cosmetic products is a particular invigorating and / or smooth skin feel as well as the smoothness of the skin after its application.

A rosy skin color (such as the stay available in fresh air is considered healthy by consumers accordingly desirable whereas a pale complexion is usually not as desirable.

task The present invention was to skin care preparations and Preparations for the care of naturally aged skin to disposal to provide, the preparations care for the body and embellish and simultaneously reduce skin wrinkles and eliminate cellulite.

It has surprisingly that a cosmetic preparation containing (a) an aqueous one Fruit extract from anise (Pimpinella anis fruit extract), under which Trade name Bioxilift in the company SILAB, St. Viance, France, available and (b) one or more substances selected from the group of methylpropanediol, 1,2-hexanediol, 1,6-hexanediol, 1,2-octanediol, dipropylene glycol, ethylhexylglycerol remedies the disadvantages of the prior art. Such a preparation has the significant advantage over preparations of the state the technique that in the aqueous Anise extract contained organic biomolecules better against chemical and microbial degradation protected are.

Furthermore has such a preparation the following additional benefits: It promotes the natural Regeneration process and Cellular metabolism of the skin, activates the skin's own protective systems and makes the skin more resistant to stressors, counteracts (first) signs of aging, reducing lines and facial lines, Refines pores and visibly firms and smoothes the complexion, Deeply activates the skin's own production of components connective tissue such as collagens, elastic fibers and proteoglycans hyaluronic acids, among others) This effectively counteracts the formation of new wrinkles through energy deposits / reserves filled and the skin / cell regeneration is improved, contributes to the rejuvenation of the inner skin structure by improving the epidermal-dermal interlocking (Papillae), which refines facial and skin contours and tightened, firming and visibly firming the skin and improving the skin Skin elasticity.

By the combination of aniseed fruit extracts with one or more Fabrics selected from the group methylpropanediol, 1,2-hexanediol, 1,6-hexanediol, 1,2-octanediol, Dipropylene glycol, ethylhexylglycerol will provide protection in aqueous Anise extract contained organic biomolecules against chemical and microbial Removal achieved so that the extracts are particularly suitable for use in cosmetic preparations and long-term stable in emulsions can be incorporated.

at Bioxilift is an aqueous fruit extract Anise (Pimpinella anis fruit extract). The extract has an amber-like Color up and has a characteristic anise smell.

Of the Extract is rich in inorganic minerals like sodium and magnesium ions, but especially of potassium ions.

The specific composition is:
Dry matter: 40-60 g / l
Mineral ashes 11-18 g / l
Total protein 12-20 g / l
pH 4.5-5.5

at During production, the aniseed fruits are solubilized in water and enzymatically hydrolyzed. The ratio of raw material to extract is ½. Soluble and insoluble Phases are separated and then filtered or afterwards sterile filtered. Bioxilift is produced by the company SILAB, France offered.

It is also advantageous in the context of the present invention, cosmetic Preparing preparations whose main purpose is not protection is sunlight, but still contains a content of other UV-protective substances contain. So z. In day creams or make-up products usually Incorporated UV-A or UV-B filter substances. Also, UV protectors, as well as antioxidants and, if desired, preservatives, effective protection of the preparations themselves against spoilage. Cheap are also cosmetic preparations in the form of a sunscreen available.

Accordingly contain the preparations for the purposes of the present invention preferably at least one further UV-A, UV-B and / or broadband filter substance. The formulations can, although not necessary, optionally also one or more organic and / or inorganic pigments as UV filter substances, which may be present in the water and / or the oil phase.

The Preparations according to the present invention Invention can furthermore advantageously also in the form of so-called oil-free cosmetic emulsions which are a water phase and at least one at room temperature liquid UV filter substance as a further phase and which in particular can also be advantageous free of other oil components.

• • Phenylen-1,4-bis-(2-benzimidazyl)-3,3'-5,5'-tetrasulfonsäure und ihre Salze, besonders die entsprechenden Natrium-, Kalium- oder Triethanolammonium-Salze, insbesondere das Phenylen-1,4-bis-(2-benzimidazyl)-3,3'-5,5'-tetrasulfonsäure-bis-natriumsalz mit der INCI-Bezeichnung Disodium Phenyl Dibenzimidazol Tetrasulfonat (CAS-Nr.: 180898-37-7), welches beispielsweise unter der Handelsbezeichnung Neo Heliopan AP bei Symrise erhältlich ist;
• • Salze der 2-Phenylbenzimidazol-5-sulfonsäure, wie ihr Natrium-, Kalium- oder ihr Triethanolammonium-Salz sowie die Sulfonsäure selbst mit der INCI Bezeichnung Phenylbenzimidazole Sulfonsäure (CAS.-Nr. 27503-81-7), welches beispielsweise unter der Handelsbezeichnung Eusolex 232 bei Merck oder unter Neo Heliopan Hydro bei Symrise erhältlich ist;
• • 1,4-di(2-oxo-10-Sulfo-3-bornylidenmethyl)-Benzol (auch: 3,3'-(1,4-Phenylendimethylene)-bis-(7,7-dimethyl-2-oxo-bicyclo-[2.2.1]hept-1-ylmethan Sulfonsäure) und dessen Salze (besonders die entprechenden 10-Sulfato-verbindungen, insbesondere das entsprechende Natrium-, Kalium- oder Triethanolammonium-Salz), das auch als Benzol-1,4-di(2-oxo-3-bornylidenmethyl-10-sulfonsäure) bezeichnet wird. Benzol-1,4-di(2-oxo-3-bornylidenmethyl-10-sulfonsäure) hat die INCI-Bezeichnung Terephtali dene Dicampher Sulfonsäure (CAS.-Nr.: 90457-82-2) und ist beispielsweise unter dem Handelsnamen Mexoryl SX von der Fa. Chimex erhältlich;
• • Sulfonsäure-Derivate des 3-Benzylidencamphers, wie z. B. 4-(2-Oxo-3-bornylidenmethyl)benzolsulfonsäure, 2-Methyl-5-(2-oxo-3-bornylidenmethyl)sulfonsäure und deren Salze.
• • Benzoxazol-Derivate, wie z. B. das 2,4-bis-[5-1(dimethylpropyl)benzoxazol-2-yl-(4-phenyl)-imino]-6-(2-ethylhexyl)-imino-1,3,5-triazin mit der CAS Nr. 288254-16-0, welches bei 3V Sigma unter der Handelsbezeichnung Uvasorb^® K2A erhältlich ist.
• • Hydroxybenzophenone, z. B. der 2-(4-Diethylamino-2-hydoxybenzoyl)-benzoesäurehexylester (auch: Aminobenzophenon), welcher unter der Handelsbezeichnung Uvinul A Plus bei der Fa. BASF erhältlich ist.
• • Triazinderivate, wie z. B. 2,4-Bis-{[4-(2-Ethyl-hexyloxy)-2-hydroxy]-phenyl}-6-(4-methoxyphenyl)-1,3,5-triazin (INCI: Bis-Ethylhexyloxylphenol Methoxyphenyl Triazin), welches unter der Handelsbezeichnung Tinosorb^® S bei der CIBA-Chemikalien GmbH erhältlich ist; Dioctylbutylamidotriazon (INCI: Diethylhexyl Butamido Triazone), welches unter der Handelsbezeichnung UVASORB HEB bei Sigma 3V erhältlich ist; 4,4',4'-(1,3,5-Triazin-2,4,6-triyltriimino)-tris-benzoesäure-tris(2-ethylhexylester), auch: 2,4,6-Tris-[anilino-(p-carbo-2-ethyl-1-hexyloxy)]-1,3,5-triazin (INCI: Ethylhexyl Triazone), welches von der BASF Aktiengesellschaft unter der Warenbezeichnung UVINUL^® T 150 vertrieben wird; 2-[4,6-Bis(2,4-dimethylphenyl)-1,3,5-triazin-2-yl]-5-(octyloxy)phenol (CAS Nr.: 2725-22-6).
• • Benzotriazole, wie z. B. 2,2'-Methylen-bis-(6-(2H-benzotriazol-2-yl)-4-(1,1,3,3-tetramethylbutyl)-phenol) (INCI: Methylene Bis-Benztriazolyl Tetramethylbutylphenol), welches z. B. unter der Handelsbezeichnung Tinosorb^® M bei der CIBA-Chemikalien GmbH erhältlich ist.
• • 3-Benzylidencampher-Derivate, vorzugsweise 3-(4-Methylbenzyliden)campher, 3-Benzylidencampher;
• • 4-Aminobenzoesäure-Derivate, vorzugsweise 4-(Dimethylamino)-benzoesäure(2-ethylhexyl)ester, 4-(Dimethylamino)benzoesäureamylester;
• • Ester der Benzalmalonsäure, vorzugsweise 4-Methoxybenzalmalonsäuredi(2-ethylhexyl)ester;
• • Ester der Zimtsäure, vorzugsweise 4-Methoxyzimtsäure(2-ethylhexyl)ester, 4-Methoxyzimtsäureisopentylester;
• • Derivate des Benzophenons, vorzugsweise 2-Hydroxy-4-methoxybenzophenon, 2-Hydroxy-4-methoxy-4-methylbenzophenon, 2,2-Dihydroxy-4-methoxybenzophenon sowie
• • an Polymere gebundene UV-Filter
• • Ethylhexyl-2-cyano-3,3-diphenylacrylat (Octocrylen), welches von BASF unter der Bezeichnung Uvinul N 539 T erhältlich ist.

Particularly advantageous UV filter substances which are liquid at room temperature for the purposes of the present invention are homomenthylsalicylate (INCI: homosalates), 2-ethylhexyl-2-cyano-3,3-diphenylacrylate (INCI: octocrylene), 2-ethylhexyl-2-hydroxybenzoate (2 Ethylhexyl salicylate, octyl salicylate, INCI: ethylhexyl salicylate) and esters of cinnamic acid, preferably 4-methoxycinnamic acid (2-ethylhexyl) ester (2-ethylhexyl-4-methoxycinnamate, INCI: ethylhexyl methoxycinnamate) and isopentyl 4-methoxycinnamate (isopentyl-4-methoxycinnamate, INCI : isoamyl p-Methoxycinnamate), 3- (4- (2,2-bis ethoxycarbonylvinyl) phenoxy) propenyl) -methoxysiloxan / dimethylsiloxane - copolymer which is obtainable for example from Hoffmann La Roche under the trade name Parsol ^® SLX. Advantageous UV filter substances in the context of the present invention are also:

• Phenylene-1,4-bis (2-benzimidazyl) -3,3'-5,5'-tetrasulfonic acid and its salts, especially the corresponding sodium, potassium or triethanolammonium salts, especially the phenylene-1,4 bis (2-benzimidazyl) -3,3'-5,5'-tetrasulfonic acid bis-sodium salt with the INCI name Disodium Phenyl Dibenzimidazole tetrasulfonate (CAS No .: 180898-37-7), which is available, for example, under the Trade name Neo Heliopan AP available at Symrise;
• Salts of 2-phenylbenzimidazole-5-sulfonic acid, such as its sodium, potassium or triethanolammonium salt, and the sulfonic acid itself with the INCI name phenylbenzimidazole sulfonic acid (CAS No. 27503-81-7), which is available, for example, from Trade name Eusolex 232 available from Merck or Neo Heliopan Hydro from Symrise;
• 1,4-di (2-oxo-10-sulfo-3-bornylidenemethyl) benzene (also: 3,3 '- (1,4-phenylenedimethylene) -bis (7,7-dimethyl-2-oxo) bicyclo [2.2.1] hept-1-ylmethane sulfonic acid) and its salts (especially the corresponding 10-sulfato compounds, in particular the corresponding sodium, potassium or triethanolammonium salt), also known as benzene-1,4 benzene-1,4-di (2-oxo-3-bomylidenemethyl-10-sulfonic acid) has the INCI name Terephtali dene dicampher sulfonic acid (CAS. No. 90457-82-2) and is available, for example, under the trade name Mexoryl SX from Chimex;
• Sulfonic acid derivatives of 3-Benzylidencamphers, such as. B. 4- (2-oxo-3-bomylidenemethyl) benzenesulfonic acid, 2-methyl-5- (2-oxo-3-bomylidenemethyl) sulfonic acid and salts thereof.
• Benzoxazole derivatives, such as. B. the 2,4-bis- [5-1 (dimethylpropyl) benzoxazol-2-yl- (4-phenyl) -imino] -6- (2-ethylhexyl) -imino-1,3,5-triazine with the CAS No. 288254-16-0, which at 3V Sigma under the Han dels designation Uvasorb® ^® K2A is available.
• Hydroxybenzophenones, e.g. B. 2- (4-diethylamino-2-hydroxybenzoyl) -benzoesäurehexylester (also: aminobenzophenone), which is available under the trade name Uvinul A Plus in the company. BASF.
• Triazine derivatives, such as. For example, 2,4-bis - {[4- (2-ethyl-hexyloxy) -2-hydroxy] -phenyl} -6- (4-methoxyphenyl) -1,3,5-triazine (INCI: bis-ethylhexyloxy-phenol methoxyphenyl , which is available under the trade name Tinosorb ^® S from CIBA-Chemikalien GmbH triazine); Dioctylbutylamidotriazone (INCI: Diethylhexyl Butamido Triazone), which is available under the trade name UVASORB HEB from Sigma 3V; 4,4 ', 4' - (1,3,5-triazine-2,4,6-triyltriimino) tris-benzoic acid tris (2-ethylhexyl ester), also: 2,4,6-tris [anilino- (p-carbo-2-ethyl-1-hexyloxy)] - 1,3,5-triazine (INCI: ethylhexyl Triazone), which is sold by BASF Aktiengesellschaft under the trade name UVINUL T 150 ^®; 2- [4,6-bis (2,4-dimethylphenyl) -1,3,5-triazin-2-yl] -5- (octyloxy) phenol (CAS No .: 2725-22-6).
• Benzotriazoles, such as. B. 2,2'-methylene-bis- (6- (2H-benzotriazol-2-yl) -4- (1,1,3,3-tetramethylbutyl) -phenol) (INCI: Methylene bis-benztriazolyl tetramethylbutylphenol), which z. B. under the trade name Tinosorb ^® M is available from CIBA-Chemikalien GmbH.
• 3-benzylidene camphor derivatives, preferably 3- (4-methylbenzylidene) camphor, 3-benzylidene camphor;
• 4-aminobenzoic acid derivatives, preferably 2-ethylhexyl 4- (dimethylamino) benzoate, 4- (dimethylamino) benzoic acid amyl ester;
• Esters of benzalmalonic acid, preferably di-2-ethylhexyl 4-methoxybenzalmalonate;
• Esters of cinnamic acid, preferably 4-methoxycinnamic acid (2-ethylhexyl) ester, 4-methoxycinnamic acid isopentyl ester;
• Derivatives of benzophenone, preferably 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-methoxy-4-methylbenzophenone, 2,2-dihydroxy-4-methoxybenzophenone and
• • polymer-bound UV filters
• Ethylhexyl 2-cyano-3,3-diphenylacrylate (octocrylene), which is available from BASF under the name Uvinul N 539 T.

Especially advantageous preparations according to the present invention, which are characterized by a high or very high UV-A protection, contain in addition to the filter substance (s) according to the invention or preferred further UV-A and / or broadband filters, in particular Dibenzoylmethanderivate [for example 4- (tert-butyl) -4'-methoxydibenzoylmethane] and / or the 2,4-bis - {[4- (2-ethyl-hexyloxy) -2-hydroxy] -phenyl} -6- (4-methoxyphenyl) -1,3,5-triazine and / or phenylene-1,4-bis (2-benzimidazyl) -3,3'-5,5'-tetrasulfonic acid bis-sodium salt each individually or in any combination with each other.

The List of said UV filters, for the purposes of the present invention can be used Of course not limiting.

The Total amount of filter substances is from the range of 0.1 to 30 wt .-%, preferably 0.5 to 10 wt .-%, in particular 1.0 to 6.0 wt .-% - respectively based on the total weight of the preparations - chosen to cosmetic preparations to disposal to put the hair or the skin in front of the entire area protect the ultraviolet radiation.

Further it is preferred if the preparation additionally contains inorganic pigments, preferably coated titanium dioxide.

Inorganic pigments within the meaning of the invention are metal oxides and / or other sparingly water-soluble or insoluble metal compounds, in particular oxides of titanium (TiO ₂ ), zinc (ZnO), iron (eg Fe ₂ O ₃ ), zirconium (ZrO ₂ ) , Silicon (SiO ₂ ), manganese (for example MnO), aluminum (Al ₂ O ₃ ), cerium (for example Ce ₂ O ₃ ), mixed oxides of the corresponding metals and mixtures of such oxides and the sulfate of barium (BaSO ₄ ).

The Pigments can advantageous in the context of the present invention also in the form of a commercial available oily or aqueous predispersions come into use. These predispersions may advantageously dispersants and / or solubilization promoters may be added.

According to the invention, the pigments may advantageously be surface-treated ("coated"), whereby, for example, a hydrophilic, amphiphilic or hydrophobic character is to be formed or retained.This surface treatment may consist in using a thin hydrophilic and hydrophilic pigment according to methods known per se In the sense of the present invention, the various surface coatings may also contain water consist of alumina (Al ₂ O ₃ ), aluminum hydroxide Al (OH) ₃ , or alumina hydrate (also: alumina, CAS No .: 1333-84-2), sodium hexametaphosphate (NaPO ₃ ) ₆ , sodium metaphosphate (NaPO ₃ ) _n , Silica (SiO ₂ ) (also: silica, CAS No .: 7631-86-9), or iron oxide (Fe ₂ O ₃ ). These inorganic surface coatings may be present alone, in combination and / or in combination with organic coating materials.

organic surface coatings For the purposes of the present invention may consist of vegetable or animal aluminum stearate, vegetable or animal stearic acid, lauric acid, dimethylpolysiloxane (also: dimethicone), methylpolysiloxane (methicone), simethicone (a mixture of dimethylpolysiloxane with an average chain length from 200 to 350 dimethylsiloxane units and silica gel) or alginic acid.

Suitable titanium dioxide particles and predispersions of titanium dioxide particles are available from the following companies under the following trade names:

Zinc oxide particles which are suitable according to the invention and predispersions of zinc oxide particles are obtainable from the following companies under the following commercial names:

Further it is preferred if in the preparation additionally contain alpha-hydroxy acids are. Furthermore, it is preferred if in the preparation additionally glycerol is included. Furthermore, it is preferred if the preparation has a Emulsion, preferably an O / W emulsion or an O / W hydrodispersion, represents. Further, it is preferred if as coated titanium dioxide Substances with a particle diameter of 10-250 nm, preferably 10-100 nm, chosen become. Further, it is preferred if the alpha-hydroxy acid, lactic acid, citric acid, malic acid or tartaric acid is. Further, it is preferred if the preparation has a pH of 3 to 10, preferably from 4 to 8.

The The invention also encompasses the use of a preparation according to the invention against wrinkles and / or to increase skin elasticity.

• • der Fettalkoholethoxylate
• • der ethoxylierten Wollwachsalkohole,
• • der Polyethylenglycolether der allgemeinen Formel R-O-(-CH₂-CH₂-O-)_n-R',
• • der Fettsäureethoxylate der allgemeinen Formel R-COO-(-CH₂-CH₂-O-)_n-H,
• • der veretherten Fettsäureethoxylate der allgemeinen Formel R-COO-(-CH₂-CH₂-O-)_n-R',
• • der veresterten Fettsäureethoxylate der allgemeinen Formel R-COO-(-CH₂-CH₂-O-)_n-C(O)-R',
• • der Polyethylenglycolglycerinfettsäureester
• • der ethoxylierten Sorbitanester
• • der Cholesterinethoxylate
• • der ethoxylierten Triglyceride
• • der Alkylethercarbonsäuren der allgemeinen Formel R-O-(-CH₂-CH₂-O-)_n-CH₂-COOH nd n eine Zahl von 5 bis 30 darstellen,
• • der Polyoxyethylensorbitolfettsäureester,
• • der Alkylethersulfate der allgemeinen Formel R-O-(-CH₂-CH₂-O-)_n-SO₃-H
• • der Fettalkoholpropoxylate der allgemeinen Formel R-O-(-CH₂-CH(CH₃)-O-)_n-H,
• • der Polypropylenglycolether der allgemeinen Formel R-O-(-CH₂-CH(CH₃)-O-)_n-R',
• • der propoxylierten Wollwachsalkohole,
• • der veretherten Fettsäurepropoxylate R-COO-(-CH₂-CH(CH₃)-O-)_n-R',
• • der veresterten Fettsäurepropoxylate der allgemeinen Formel R-COO-(-CH₂-CH(CH₃)-O-)_n-C(O)-R',
• • der Fettsäurepropoxylate der allgemeinen Formel R-COO-(-CH₂-CH(CH₃)-O-)_n-H,
• • der Polypropylenglycolglycerinfettsäureester
• • der propoxylierten Sorbitanester
• • der Cholesterinpropoxylate
• • der propoxylierten Triglyceride
• • der Alkylethercarbonsäuren der allgemeinen Formel R-O-(-CH₂-CH(CH₃)O-)_n-CH₂-COOH
• • der Alkylethersulfate bzw. die diesen Sulfaten zugrundeliegenden Säuren der allgemeinen Formel R-O-(-CH₂-CH(CH₃)-O-)_nSO₃-H
• • der Fettalkoholethoxylate/propoxylate der allgemeinen Formel R-O-X_n-Y_m-H,
• • der Polypropylenglycolether der allgemeinen Formel R-O-X_n-Y_m-R',
• • der veretherten Fettsäurepropoxylate der allgemeinen Formel R-COO-X_n-Y_m R',
• • der Fettsäureethoxylate/propoxylate der allgemeinen Formel R-COO-X_n-Y_m-H.

Preparations present as emulsions according to the present invention comprise one or more emulsifiers. For example, O / W emulsifiers can be advantageously selected from the group of polyethoxylated or polypropoxylated or polyethoxylated and polypropoxylated products, eg. B .:

• • the fatty alcohol ethoxylates
• The ethoxylated wool wax alcohols,
• The polyethylene glycol ether of the general formula RO - (- CH ₂ -CH ₂ -O-) _n -R ',
• The fatty acid ethoxylates of the general formula R-COO - (- CH ₂ -CH ₂ -O-) _n -H,
• The etherified fatty acid ethoxylates of the general formula R-COO - (- CH ₂ -CH ₂ -O-) _n -R ',
• • the esterified fatty acid ethoxylates of the general formula R-COO - (- CH ₂ -CH ₂ -O-) _n -C (O) -R ',
• • the polyethylene glycol glycerin fatty acid ester
• • the ethoxylated sorbitan ester
• • the cholesterol ethoxylates
• • the ethoxylated triglycerides
• The alkyl ether carboxylic acids of the general formula RO - (- CH ₂ -CH ₂ -O-) _n -CH ₂ -COOH nd n represent a number from 5 to 30,
• The polyoxyethylene sorbitol fatty acid ester,
• The alkyl ether sulfates of the general formula RO - (- CH ₂ -CH ₂ -O-) _n -SO ₃ -H
• The fatty alcohol propoxylates of the general formula RO - (- CH ₂ -CH (CH ₃ ) -O-) _n -H,
• The polypropylene glycol ether of the general formula RO - (- CH ₂ -CH (CH ₃ ) -O-) _n -R ',
• The propoxylated wool wax alcohols,
• • the etherified fatty acid propoxylates R-COO - (- CH ₂ -CH (CH ₃ ) -O-) _n -R ',
• The esterified fatty acid propoxylates of the general formula R-COO - (- CH ₂ -CH (CH ₃ ) -O-) _n -C (O) -R ',
• The fatty acid propoxylates of the general formula R-COO - (- CH ₂ -CH (CH ₃ ) -O-) _n -H,
• • the polypropylene glycol glycerin fatty acid ester
• • the propoxylated sorbitan ester
• • cholesterol propoxylates
• • the propoxylated triglycerides
• • the alkyl ether carboxylic acids of the general formula RO - (- CH ₂ -CH (CH ₃ ) O-) _n -CH ₂ -COOH
• The alkyl ether sulfates or the acids based on these sulfates of the general formula RO - (- CH ₂ -CH (CH ₃ ) -O-) _n SO ₃ -H
• The fatty alcohol ethoxylates / propoxylates of the general formula ROX _n -Y _m -H,
• The polypropylene glycol ether of the general formula ROX _n -Y _m -R ',
• The etherified fatty acid propoxylates of the general formula R-COO-X _n -Y _m R ',
• • the fatty acid ethoxylates / propoxylates of the general formula R-COO-X _n -Y _m -H.

Particularly according to the invention The polyethoxylated or polypropoxylated used are advantageous or polyethoxylated and polypropoxylated O / W emulsifiers selected from the group of substances with HLB values from 11 to 18, especially advantageous with HLB values of 14.5 to 15.5, provided the O / W emulsifiers saturated Radicals R and R 'have. Do the O / W emulsifiers have unsaturated Radicals R and / or R ', or are Isoalkylderivate, so the preferred HLB value such emulsifiers are also lower or higher.

It is advantageous to choose the fatty alcohol ethoxylates from the group of ethoxylated stearyl alcohols, cetyl alcohols, cetylstearyl alcohols (cetearyl alcohols). Particularly preferred are:
Polyethylene glycol (13) stearyl ether (steareth-13), polyethylene glycol (14) stearyl ether (steareth-14), polyethylene glycol (15) stearyl ether (steareth-15), polyethylene glycol (16) stearyl ether (steareth-16), polyethylene glycol (17) stearyl ether ( Steareth-17), polyethylene glycol (18) stearyl ether (steareth-18), polyethylene glycol (19) stearyl ether (steareth-19), polyethylene glycol (20) stearyl ether (steareth-20),
Polyethylene glycol (12) isostearyl ether (isosteareth-12), polyethylene glycol (13) isostearyl ether (isosteareth-13), polyethylene glycol (14) isostearyl ether (isosteareth-14), polyethylene glycol (15) isostearyl ether (isosteareth-15), polyethylene glycol (16) isostearyl ether ( Isosteareth-16), polyethylene glycol (17) isostearyl ether (isosteareth-17), polyethylene glycol (18) isostearyl ether (isosteareth-18), polyethylene glycol (19) isostearyl ether (isosteareth-19), polyethylene glycol (20) isostearyl ether (isosteareth-20),
Polyethylene glycol (13) Cetyl ether (Ceteth-13), Polyethylene glycol (14) Cetyl ether (Ceteth-14), Polyethylene glycol (15) Cetyl ether (Ceteth-15), Polyethylene glycol (16) Cetyl ether (Ceteth-16), Polyethylene glycol (17) Cetyl ether ( Ceteth-17), polyethylene glycol (18) cetyl ether (ceteth-18), polyethylene glycol (19) cetyl ether (ceteth-19), polyethylene glycol (20) cetyl ether (ceteth-20),
Polyethylene glycol (13) isocetyl ether (isoceteth-13), polyethylene glycol (14) isocetyl ether (isoceteth-14), polyethylene glycol (15) isocetyl ether (isoceteth-15), polyethylene glycol (16) isocetyl ether (isoceteth-16), polyethylene glycol (17) isocetyl ether (Isoceteth-17), polyethylene glycol (18) isocetyl ether (isoceteth-18), polyethylene glycol (19) isocetyl ether (isoceteth-19), polyethylene glycol (20) isocetyl ether (isoceteth-20),
Polyethylene glycol (12) oleyl ether (Oleth-12), polyethylene glycol (13) oleyl ether (Oleth-13), polyethylene glycol (14) oleyl ether (Oleth-14), polyethylene glycol (15) oleyl ether (Oleth-15),
Polyethylene glycol (12) lauryl ether (Laureth-12), polyethylene glycol (12) isolauryl ether (Isolaureth-12),
Polyethylene glycol (13) cetyl stearyl ether (ceteareth-13), polyethylene glycol (14) cetyl stearyl ether (ceteareth-14), polyethylene glycol (15) cetyl stearyl ether (ceteareth-15), polyethylene glycol (16) cetyl stearyl ether (ceteareth-16), polyethylene glycol (17) cetyl stearyl ether ( Ceteareth-17), polyethylene glycol (18) cetyl stearyl ether (ceteareth-18), polyethylene glycol (19) cetyl stearyl ether (ceteareth-19), polyethylene glycol (20) cetyl stearyl ether (ceteareth-20).

It is also advantageous to choose the fatty acid ethoxylates from the following group:
Polyethylene glycol (20) stearate, polyethylene glycol (21) stearate, polyethylene glycol (22) stearate, polyethylene glycol (23) stearate, polyethylene glycol (24) stearate, polyethylene glycol (25) stearate,
Polyethylene glycol (12) isostearate, polyethylene glycol (13) isostearate, polyethylene glycol (14) isostearate, polyethylene glycol (15) isostearate, polyethylene glycol (16) isostearate, polyethylene glycol (17) isostearate, polyethylene glycol (18) isostearate, polyethylene glycol (19) isostearate, polyethylene glycol (20) isostearate, polyethylene glycol (21) isostearate, polyethylene glycol (22) isostearate, polyethylene glycol (23) isostearate, polyethylene glycol (24) isostearate, polyethylene glycol (25) isostearate,
Polyethylene glycol (12) oleate, polyethylene glycol (13) oleate, polyethylene glycol (14) oleate, polyethylene glycol (15) oleate, polyethylene glycol (16) oleate, polyethylene glycol (17) oleate, polyethylene glycol (18) oleate, polyethylene glycol (19) oleate, polyethylene glycol ( 20) oleate The ethoxylated alkyl ether carboxylic acid or its salt may advantageously be sodium laureth-11-carboxylate.

When Alkyl ether sulfate can be advantageously used sodium laureth 1-4 sulfate become.

When Ethoxylated cholesterol derivative may advantageously be polyethylene glycol (30) cholesteryl ether be used. Also, polyethylene glycol (25) sojasterol has become proven.

When ethoxylated triglycerides can Advantageously, the Polyethylene Glycol (60) Evening Primrose Glycerides is used become (Evening Primrose = evening primrose)

Farther is advantageous, the Polyethylenglycolglycerinfettsäureester from the group polyethylene glycol (20) glyceryl laurate, polyethylene glycol (21) glyceryl laurate, Polyethylene glycol (22) glyceryl laurate, Polyethylene glycol (23) glyceryl laurate, polyethylene glycol (6) glyceryl caprate / caprinate, Polyethylene glycol (20) glyceryl oleate, polyethylene glycol (20) glyceryl isostearate, Polyethylene glycol (18) glyceryl oleate / cocoate to choose.

It is also cheap the sorbitan esters from the group polyethylene glycol (20) sorbitan monolaurate, polyethylene glycol (20) sorbitan monostearate, Polyethylene glycol (20) sorbitan monoisostearate, polyethylene glycol (20) sorbitan monopalmitate, polyethylene glycol sorbitan monooleate (20) to choose.

Especially preferred O / W emulsifiers are glyceryl stearate citrate, polyglyceryl-3-methyl glucose distearate, Cetearyl glucosides, PEG-40 stearate, PEG-100 stearate, stearic acid, ceteareth-20 and steareth-21.

When advantageous W / O emulsifiers can be used: fatty alcohols having 8 to 30 carbon atoms, Monoglycerol ester saturated and / or unsaturated, branched and / or unbranched alkanecarboxylic acids of a chain length of 8 to 24, especially 12-18 C atoms, diglycerol esters saturated and / or unsaturated, branched and / or unbranched alkanecarboxylic acids of a chain length of 8 to 24, especially 12-18 C atoms, monoglycerol ether saturated and / or unsaturated, branched and / or unbranched alcohols of a chain length of 8 to 24, especially 12-18 C atoms, diglycerol ether saturated and / or unsaturated, branched and / or unbranched alcohols of a chain length of 8 to 24, especially 12-18 C atoms, propylene glycol esters saturated and / or unsaturated, branched and / or unbranched alkanecarboxylic acids of a chain length of 8 to 24, especially 12-18 C atoms and saturated sorbitan esters and / or unsaturated, branched and / or unbranched alkanecarboxylic acids of a chain length of 8 to 24, especially 12-18 C-atoms.

Especially advantageous W / O emulsifiers are glyceryl monostearate, glyceryl monoisostearate, Glyceryl monomyristate, glyceryl monooleate, diglyceryl monostearate, Diglyceryl monoisostearate, propylene glycol monostearate, propylene glycol monoisostearate, Propylene glycol monocaprylate, propylene glycol monolaurate, sorbitan monoisostearate, Sorbitan monolaurate, sorbitan monocaprylate, sorbitan monoisooleate, Sucrose distearate, cetyl alcohol, stearyl alcohol, arachidyl alcohol, Behenyl alcohol, isobehenyl alcohol, selachyl alcohol, chimyl alcohol, Polyethylene glycol (2) stearyl ether (steareth-2), glyceryl monolaurate, Glyceryl monocaprinate, glyceryl monocaprylate.

Also can be advantageous the emulsions in the context of the present invention also hydrocolloids (also as thickener or gelling agent) containing the preparations can stabilize.

When advantageous according to the invention Hydrocolloids are agar-agar, carrageenan, tragacanth, gum arabic, Alginates, xanthan gum, pectins, polyoses, guar flour, locust bean gum, Strength, Dextrins, cellulose ethers, hydroxyethyl and propyl cellulose derivatives, Vinyl polymers, polycarboxylic acids, Polyethers, polyimines, polyamides, polysilicic acids, clay minerals, zeolites, silicas used.

Further advantageous gelling agents are, for example, copolymers of C _10-30 -alkyl acrylates and one or more monomers of acrylic acid, methacrylic acid or their esters. The INCI name for such compounds is "Acrylates / C 10-30 Alkyl Acrylate Crosspolymer". Particularly advantageous are the Pemulen ^® types TR 1, TR 2 and TRZ from. Goodrich (Noveon).

Also Carbopols are advantageous gelling agents for such preparations. Carbopols are polymers of acrylic acid, especially acrylate-alkyl acrylate copolymers. Advantageous Carbopols are for example the types 980, 981, 984 1342, 1382, 2984 and 5984. Also the ETD types 2001, 2020, 2050 and Carbopol Ultrez 10, PVM / MA Decadiene Crosspolymer (trade name Stabileze 06), polyglyceryl methacrylate and polyacrylamide, ammonium dimethyltauramide / vinylformamide copolymer, copolymer / crosspolymer comprising acryloyldimethyltaurate, polyacryloyldimethyltauramide, polyvinylpyrrolidone and copolymer thereof.

in der R ein Wasserstoff oder eine Methylgruppe darstellen kann.Hydrocolloids which are preferred according to the invention are: magnesium and / or aluminum silicates and, for example, methylcelluloses, which are referred to as the methyl ethers of cellulose. They are characterized by the following structural formula

in which R can represent a hydrogen or a methyl group.

Especially advantageous in the context of the present invention are in general also referred to as methylcelluloses cellulose mixed ethers, which in addition to a dominating content of methyl additionally 2-hydroxyethyl, 2-hydroxypropyl or 2-hydroxybutyl groups. Especially preferred are (hydroxypropyl) methylcelluloses, for example the under the trade name Methocel E4M at the Dow Chemical Comp. available.

In order to improve the water resistance of cosmetic and dermatological sunscreen preparations, it may be advantageous to incorporate film formers into the cosmetic or dermatological preparations. According to the prior art, this z. As polyurethanes (eg. As the Avalure ^® grades from Goodrich), dimethicone copolyol polyacrylates (Surface Silsoft ^® from Witco Organo Silicones Group), PVP / VA (VA = vinyl acetate) copolymer (Luviscol VA 64 Powder from BASF), C _20-40 carboxylic acid with polyethylene (Performacid 350 from New Phase Technologies) and film formers from the group of polymers based on polyvinylpyrrolidone (PVP):

Especially Copolymers of polyvinylpyrrolidone are preferably used, for example, the PVP hexadecene copolymer and the PVP eicosene copolymer, which under the trade names Antaron V216 and Antaron V220 available from GAF Chemicals Cooperation, as well as the Tricontayl PVP and the like more.

adversely is however for Such preparations containing film formers in an effective (i.e. H. the water resistance increasing) contain concentration that they the application on the skin a sticky and greasy impression leave.

Next the influence of The basis is also the ability to bind of the UV filter in or on the skin of great importance for water resistance the formulation. It is understandable, that oil-soluble UV filters better to the (lipophilic) surface the skin to be bound or are harder to wash off this than water-soluble UV filter.

The cosmetic preparations according to the invention can contain cosmetic excipients, such as those commonly used in such preparations be used, for. Preservatives, preservatives, Complexing agents, bactericides, perfumes, substances for increasing of foaming, Dyes, pigments that are a coloring Have effect, thickener, moisturizing and / or moisturizing Substances, fillers, the skin feeling improve, fats, oils, Waxes or other usual Ingredients of a cosmetic formulation such as alcohols, polyols, Polymers, foam stabilizers, electrolytes, organic solvents or silicone derivatives.

advantageous Preservatives according to the present invention are, for example Iodopropyl butyl carbamates (for example those sold under the trade names Glycacil-L, Glycacil-S available from Lonza and / or Dekaben LMB by Jan Dekker), parabens (i.e., p-hydroxybenzoic acid alkyl esters, such as methyl, ethyl, propyl and / or butylparaben), phenoxyethanol, Ethanol, benzoic acid and more. Usually comprises the preservation system according to the invention also advantageously also preservation aids, such as for example, octoxyglycerol, glycine soy etc.

advantageous Complexing agents in the sense of the present invention are, for example EDTA, [S, S] -ethylenediamine disuccinate (EDDS), which is for example available under the trade name Octaquest from the company Octel, Pentasodium ethylenediamine tetramethylene phosphonate, which z. B. available under the trade name Dequest 2046 from the company Monsanto and / or iminodisuccinic acid, which u. a. from Bayer AG under the trade name Iminodisuccinat VP OC 370 (about 30% solution) and Baypure CX 100 available is.

Especially advantageous preparations are also obtained if, as additional or agents used antioxidants. Included in the invention the preparations advantageously one or more antioxidants. As cheap, but yet optional antioxidants can all be used for cosmetic Applications suitable or common Antioxidants are used.

Especially For the purposes of the present invention, water-soluble antioxidants may be advantageous are used, such as vitamins.

preferred Antioxidants are also vitamin C and its derivatives, vitamin E and its derivatives as well as vitamin A and its derivatives.

The Amount of antioxidants (one or more compounds) in the Preparations is preferably from 0.001 to 30% by weight, particularly preferably from 0.05 to 20 Wt .-%, in particular 0.1 to 10 wt .-%, based on the total weight the preparation.

Provided Vitamin E and / or derivatives thereof are the antioxidant (s), is advantageous, their respective concentrations from the field from 0.001 to 10% by weight, based on the total weight of the formulation, to choose.

Provided Vitamin A or vitamin A derivatives or carotenes or their derivatives the one or more antioxidants are advantageous, their respective Concentrations from the range of 0.001 to 10 wt .-%, based on the total weight of the formulation to choose.

Further active ingredients to be used in the context of the present invention are those which have a positive effect on the condition of the skin, in particular active ingredients for positively influencing the aging skin, which reduce the development of wrinkles or even existing wrinkles. Particularly advantageous are biochinones, in particular ubiquinone (Q10) and ubiquinol, folic acid and its derivatives (in particular tetrahydrofolic acid and dihydrofolic acid), niacin and its derivatives (especially niacinamide), creatine and creatinine, carnitine, biotin, isoflavonoids, lipoic acid, ginkgo extracts, hops and hops malt extracts. Also agents that promote the restructuring of connective tissue, such as natural and / or synthetic isoflavonoids and isoflavonoid-containing plant extracts - such. As soy and clover extracts - can be used very well in the formulations of the invention. It also appears that the formulations are particularly suitable as active ingredients for supporting the skin functions on dry skin (such as, for example, vitamin C, biotin, carnitine, propionic acid, green tea extracts, eucalyptus oil, urea and mineral salts (such as, for example, NaCl, Marine minerals) as well as osmolytes (such as inositol, betaine, quaternary ammonium compounds)). Similarly, the incorporation of drugs to alleviate or positively affect irritative skin conditions, whether sensitive skin in general or noxa-irritated skin (UV light, chemicals), has been found to be beneficial. Here are agents such as sericosides, various Extracts of licorice, licochalcone, especially licochalcone A, dexpanthenol, inhibitors of prostaglandin metabolism, in particular cyclooxygenase and leukotriene metabolism, in particular 5-lipoxygenase, but also the 5-lipoxevase inhibitor protein, FLAP. In particular, creatine and creatinine are suitable active ingredients to create and / or renew an (energy) depot and to activate the repair of various cellular structures, in particular the DNA. The incorporation of modulators of pigmentation also proved to be advantageous. Here are agents that reduce the pigmentation of the skin and thus lead to a cosmetically desired lightening of the skin and / or reduce the occurrence of age spots and / or lighten existing age spots. Examples include tyrosine sulfate, dioic acid (8-hexadecene-1,16-dicarboxylic acid) and various extracts of licorice, arbutin, alpha-arbutin, deoxyarbutin, fruit acids, especially alpha-hydroxy acids (AHAs), Bearberry (Uvae ursi), Ursolic acid, ascorbic acid, pyridoxamine, niacinamide, formulations according to the invention, which z. B. known anti-wrinkle active ingredients such as flavone glycosides (especially α-glycosyl rutin), coenzyme Q10, vitamin C and / or derivatives, vitamin E and / or derivatives and the like, are particularly advantageous for the prophylaxis and treatment of cosmetic or dermatological skin lesions, as z. Skin aging (such as dryness, roughness, dryness wrinkles, itching, decreased refatting (eg, after washing), visible vascular dilation (telangiectasia, cuperosis), slackness and wrinkle and wrinkle formation, localized hypersensitivity). , Hypo and false pigmentation (eg, age spots), increased susceptibility to mechanical stress (eg, cracking), and the like). Furthermore, they are advantageously suitable against the appearance of dry or rough skin.

When Moisturizers are substances or mixtures of substances, which give cosmetic properties the property after application or distributing on the skin surface the moisture release of the Horn layer (also called transepidermal water loss (TEWL)) to reduce and / or to positively influence the hydration of the horny layer.

All in all normalizes the skin's barrier function, which becomes skin noticeable refreshes and invigorates, and the skin appears smoother. By the Deep-acting increase in moisture, swelling and dark circles Visibly reduced, the formation of skin's own lipids is stimulated and the natural ones anti-aging functions of the skin as well as the efficiency the skin overall are stimulated.

advantageous Moisturizers for the purposes of the present invention are, for example Glycerol, lactic acid and / or Lactates, in particular sodium lactate, butylene glycol, propylene glycol, Biosaccaride gum-1, glycine soy, ethylhexyloxyglycerol, pyrrolidonecarboxylic acid, panthenol and urea.

The oil phase of Preparations in the context of the present invention contains advantageous contain nonpolar, for example, those which are chosen from the group of branched and unbranched hydrocarbons and waxes, in particular mineral oil, Vaseline (petrolatum), paraffin oil, squalane, Polyolefins, hydrogenated polyisobutenes and isohexadecane. Under Polydefins are the preferred substances for polyolefins.

It is particularly advantageous in the context of the present invention, if the content of polar oils with a polarity of less than 20 mN / m (interfacial tension against water) less than 5 wt .-% - based on the total weight the preparation - is chosen.

Advantageous can the oil phase also have a content of cyclic or linear silicone oils or Completely from such oils although it is preferred, except the silicone oil or silicone oils additional Content of other oil phase components to use.

werden auch als Polydimethylsiloxan bzw. Dimethicon (INCI) bezeichnet. Dimethicone gibt es in verschiedenen Kettenlängen bzw. mit verschiedenen Molekulargewichten.Silicone oils are synthetic compounds in which silicon atoms via oxygen atoms chain and / or net-like linked and the remaining valences of silicon by hydrocarbon radicals (usually methyl, more rarely ethyl, propyl, phenyl groups, etc.) are saturated , Systematically, the silicone oils are called polyorganosiloxanes. The methyl-substituted polyorganosiloxanes, which are the quantitatively most important compounds of this group and are characterized by the following structural formula

are also referred to as polydimethylsiloxane or dimethicone (INCI). Dimethicones are available in different chain lengths or with different molecular weights.

According to the invention advantageous is to use cyclomethicone (octamethylcyclotetrasiloxane) as a silicone oil. But also other silicone oils are advantageous for the purposes of the present invention to use for example, hexamethylcyclotrisiloxane, polydimethylsiloxane, poly (methylphenylsiloxane).

• Die Zubereitungen gemäß der vorliegenden Erfindung können ferner vorteilhaft eine oder mehrere Substanzen aus der folgenden Gruppe der Siloxanelastomere enthalten, beispielsweise um die Wasserfestigkeit und/oder den Lichtschutzfaktor der Produkte zu steigern:
• (a) Siloxanelastomere, welche die Einheiten R₂SiO und RSiO_1,5 und/oder R₃SiO_0,5 und/oder SiO₂ enthalten, wobei die einzelnen Reste R jeweils unabhängig voneinander Wasserstoff, C_1-24-Alkyl (wie beispielsweise Methyl, Ethyl, Propyl) oder Aryl (wie beispielsweise Phenyl oder Tolyl), Alkenyl (wie beispielsweise Vinyl) bedeuten und das Gewichtsverhältnis der Einheiten R₂SiO zu RSiO_1,5 aus dem Bereich von 1 : 1 bis 30 : 1 gewählt wird;
• (b) Siloxanelastomere, welche in Silikonöl unlöslich und quellfähig sind, die durch die Additionsreaktion eines Organopolysiloxans (1), das siliciumbebundenen Wasserstoff enthält, mit einem Organopolysiloxan (2), das ungesättigte aliphatische Gruppen enthält, erhältlich sind, wobei die verwendeten Mengenateile so gewählt werden, daß die Menge des Wasserstoffes des Organopolysiloxans (1) oder der ungesättigten aliphatischen Gruppen des Organopolysiloxans (2) • im Bereich von 1 bis 20 mol-% liegt, wenn das Organopolysiloxan nicht cyclisch ist und • im Bereich von 1 bis 50 mol-% liegt, wenn das Organopolysiloxan cyclisch ist.

Particularly advantageous polyorganosiloxanes in the context of the present invention are, for example, dimethylpolysiloxanes [poly (dimethylsiloxane)], which are obtainable, for example, under the trade names Abil 10 to 10 000 from Th. Goldschmidt. Also advantageous are phenylmethylpolysiloxanes (INCI: phenyl dimethicone, phenyl trimethicone), cyclic silicones (octamethylcyclotetrasiloxane or decamethylcyclopentasiloxane), which are also referred to as cyclomethicones according to INCI, amino-modified silicones (INCI: amodimethicones) and silicone waxes, eg. As polysiloxane-polyalkylene copolymers (INCI: stearyl dimethicone and cetyl dimethicone) and dialkoxydimethylpolysiloxanes (stearoxy dimethicones and behenoxy stearyl dimethicone), which are available as various Abil-Wax types from Th. Goldschmidt. However, other silicone oils are also advantageous for the purposes of the present invention, for example cetyl dimethicone, hexamethylcyclotrisiloxane, polydimethylsiloxane, poly (methylphenylsiloxane).

• The preparations according to the present invention may also advantageously contain one or more substances from the following group of siloxane elastomers, for example in order to increase the water resistance and / or the sun protection factor of the products:
• (A) siloxane elastomers containing the units R ₂ SiO and RSiO _1.5 and / or R ₃ SiO _0.5 and / or SiO ₂ , wherein the individual radicals R are each independently hydrogen, C _1-24 alkyl (as for example, methyl, ethyl, propyl) or aryl (such as phenyl or tolyl), alkenyl (such as vinyl) and the weight ratio of the units R ₂ SiO to RSiO _{1.5 is selected} from the range of 1: 1 to 30: 1 ;
• (b) Siloxane elastomers which are insoluble and swellable in silicone oil obtainable by the addition reaction of an organopolysiloxane (1) containing silicon-bonded hydrogen with an organopolysiloxane (2) containing unsaturated aliphatic groups, the proportions used being such in that the amount of hydrogen of the organopolysiloxane (1) or of the unsaturated aliphatic groups of the organopolysiloxane (2) is in the range from 1 to 20 mol%, if the organopolysiloxane is not cyclic, and in the range from 1 to 50 mol% % is when the organopolysiloxane is cyclic.

Advantageous For the purposes of the present invention, the siloxane elastomer (s) are present in the form of spherical Powder or in the form of gels.

According to the invention advantageous in the form of spherical Powder present siloxane elastomers are those with the INCI name Dimethicone / Vinyl Dimethicone Crosspolymer, for example that of DOW CORNING under the trade designations DOW CORNING 9506 Powder available.

Especially it is preferred if the siloxane elastomer in combination with oils Hydrocarbons of animal and / or vegetable origin, synthetic oils, synthetic Esters, synthetic ethers or mixtures thereof is used.

All it is particularly preferred if the siloxane elastomer in combination with unbranched at room temperature liquid or pasty silicone oils or cyclic silicone oils or mixtures thereof is used. Particularly advantageous Organopolysiloxane elastomers with the INCI name Dimethicone / Polysilicone-11, especially those available from Grant Industries Inc. Gransil types GCM, GCM-5, DMG-6, CSE gel, PM gel, LTX, ININ gel, AM-18 Gel and / or DMCM-5.

All exceptionally preferred it is when the siloxane elastomer is in the form of a gel of siloxane elastomer and a lipid phase, wherein the content of the siloxane elastomer in which gel is 1 to 80% by weight, preferably 0.1 to 60% by weight, respectively based on the total weight of the gel.

It is advantageous in the context of the present invention, the total amount the siloxane elastomers (active content) from the range of 0.01 to 10 wt .-%, advantageously from 0.1 to 5 wt .-%, each based on the total weight of the formulation to choose.

The following examples are intended to illustrate the present invention without limiting it. The numerical values in the examples are by weight, based on the total weight of the respec gene preparations.

When Pimpinella anis fruit extract was used in Bioxylift.

O / W Cream - Example 1

O / W Day Cream - Example 2

Sunscreen Cream - Example 3

After Sun Gel - Example 4

After Shave Gel - Example 5

O / W Cream - Example 6

O / W Cream - Example 7

O / W Cream - Example 8

Example 9: W / O cream

Example 10 Microemulsion

Examples of W / O pins

Claims (7)

Contains cosmetic preparation (a) one aqueous Fruit extract from anise (Pimpinella anis fruit extract), under which Trade name Bioxilift in the company SILAB, St. Viance, France, available (B) and one or more substances selected from the group of methylpropanediol, Dipropylene glycol, 1,2-hexanediol, 1,6-hexanediol, 1,2-octanediol, ethylhexylglycerol. Preparation according to one of the preceding claims characterized that they additionally inorganic pigments, preferably coated titanium dioxide. Preparation according to one of the preceding claims characterized in that it is an emulsion, preferably an O / W emulsion or an O / W hydrodispersion, represents. Preparation according to one of the preceding claims characterized characterized in that as coated titanium dioxide substances with a Particle diameter of 10-250 nm, preferably 10-100 nm, chosen become. Preparation according to one of the preceding claims characterized characterized in that it has a pH of 3 to 10, preferably from 4 to 8, has. Use of a preparation according to one of the preceding claims against wrinkles. Use of a preparation according to one of the preceding claims to increase skin elasticity.