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DE102004015800A1 - Katalysator für die Oxidation von Wasserstoff, sowie Verfahren zur Dehydrierung von Kohlenwasserstoffen - Google Patents

Katalysator für die Oxidation von Wasserstoff, sowie Verfahren zur Dehydrierung von Kohlenwasserstoffen Download PDF

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Publication number
DE102004015800A1
DE102004015800A1 DE102004015800A DE102004015800A DE102004015800A1 DE 102004015800 A1 DE102004015800 A1 DE 102004015800A1 DE 102004015800 A DE102004015800 A DE 102004015800A DE 102004015800 A DE102004015800 A DE 102004015800A DE 102004015800 A1 DE102004015800 A1 DE 102004015800A1
Authority
DE
Germany
Prior art keywords
catalyst
oxidation
dehydrogenation
hydrocarbons
hydrogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
DE102004015800A
Other languages
English (en)
Inventor
Christian Walsdorff
Falk Simon
Gerald Vorberg
Goetz-Peter Schindler
Michael Hesse
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to DE102004015800A priority Critical patent/DE102004015800A1/de
Priority to JP2007505446A priority patent/JP2007537029A/ja
Priority to US11/547,500 priority patent/US20080262281A1/en
Priority to KR1020067021400A priority patent/KR20070004845A/ko
Priority to CA002558547A priority patent/CA2558547A1/en
Priority to EP05716274A priority patent/EP1732867A1/de
Priority to RU2006137946/04A priority patent/RU2006137946A/ru
Priority to PCT/EP2005/003010 priority patent/WO2005097715A1/de
Priority to CNA2005800106306A priority patent/CN1938246A/zh
Publication of DE102004015800A1 publication Critical patent/DE102004015800A1/de
Withdrawn legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
    • B01J23/626—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with tin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/14—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of germanium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3335—Catalytic processes with metals
    • C07C5/3337—Catalytic processes with metals of the platinum group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/612—Surface area less than 10 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/56—Platinum group metals
    • C07C2523/60—Platinum group metals with zinc, cadmium or mercury

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

Die Erfindung betrifft einen Katalysator für die Oxidation von Wasserstoff in einem Verfahren zur Dehydrierung von Kohlenwasserstoffen, wobei der Katalysator, geträgert auf alpha-Aluminiumoxid, 0,01 bis 0,1 Gew.-% Platin und 0,01 bis 0,1 Gew.-% Zinn, bezogen auf das Gesamtgewicht des Katalysators, enthält, ein Verfahren zur Oxidation von Wasserstoff und ein Verfahren zur Dehydrierung von Kohlenwasserstoffen mit integriertem Oxidationsverfahren unter Verwendung des genannten Katalysators.
DE102004015800A 2004-03-29 2004-03-29 Katalysator für die Oxidation von Wasserstoff, sowie Verfahren zur Dehydrierung von Kohlenwasserstoffen Withdrawn DE102004015800A1 (de)

Priority Applications (9)

Application Number Priority Date Filing Date Title
DE102004015800A DE102004015800A1 (de) 2004-03-29 2004-03-29 Katalysator für die Oxidation von Wasserstoff, sowie Verfahren zur Dehydrierung von Kohlenwasserstoffen
JP2007505446A JP2007537029A (ja) 2004-03-29 2005-03-22 水素の酸化に使用される触媒および炭化水素を脱水素する方法
US11/547,500 US20080262281A1 (en) 2004-03-29 2005-03-22 Catalyst Used for the Oxidation of Hydrogen, and Method for the Dehydrogenation of Hydrocarbons
KR1020067021400A KR20070004845A (ko) 2004-03-29 2005-03-22 수소의 산화 반응에 사용되는 촉매, 및 탄화수소의탈수소화 방법
CA002558547A CA2558547A1 (en) 2004-03-29 2005-03-22 Catalyst used for the oxidation of hydrogen, and method for the dehydrogenation of hydrocarbons
EP05716274A EP1732867A1 (de) 2004-03-29 2005-03-22 Katalysator für die oxidation von wasserstoff, sowie verfahren zur dehydrierung von kohlenwasserstoffen
RU2006137946/04A RU2006137946A (ru) 2004-03-29 2005-03-22 Катализатор для окисления водорода, а также для дегидрирования углеводородов
PCT/EP2005/003010 WO2005097715A1 (de) 2004-03-29 2005-03-22 Katalysator für die oxidation von wasserstoff, sowie verfahren zur dehydrierung von kohlenwasserstoffen
CNA2005800106306A CN1938246A (zh) 2004-03-29 2005-03-22 用于将氢气氧化的催化剂及烃类脱氢的方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE102004015800A DE102004015800A1 (de) 2004-03-29 2004-03-29 Katalysator für die Oxidation von Wasserstoff, sowie Verfahren zur Dehydrierung von Kohlenwasserstoffen

Publications (1)

Publication Number Publication Date
DE102004015800A1 true DE102004015800A1 (de) 2005-10-20

Family

ID=34961676

Family Applications (1)

Application Number Title Priority Date Filing Date
DE102004015800A Withdrawn DE102004015800A1 (de) 2004-03-29 2004-03-29 Katalysator für die Oxidation von Wasserstoff, sowie Verfahren zur Dehydrierung von Kohlenwasserstoffen

Country Status (9)

Country Link
US (1) US20080262281A1 (de)
EP (1) EP1732867A1 (de)
JP (1) JP2007537029A (de)
KR (1) KR20070004845A (de)
CN (1) CN1938246A (de)
CA (1) CA2558547A1 (de)
DE (1) DE102004015800A1 (de)
RU (1) RU2006137946A (de)
WO (1) WO2005097715A1 (de)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1919614A1 (de) 2005-07-22 2008-05-14 Basf Se Katalysator zur dehydrierung oder hydrierung von kohlenwasserstoffen enthaltend sekundäres katalysatormaterial
DE102005040286A1 (de) 2005-08-25 2007-03-01 Basf Ag Mechanisch stabiler Katalysator auf Basis von alpha-Aluminiumoxid
MY150227A (en) * 2006-02-15 2013-12-31 Basf Se Dehydrogenation process
CN100372819C (zh) * 2006-06-22 2008-03-05 华东理工大学 一种氢氧化制苯乙烯的反应方法
US20100310441A1 (en) * 2009-06-05 2010-12-09 Basf Corporation Catalytic Article for Removal of Volatile Organic Compounds in Low Temperature Applications
CN102247843A (zh) * 2010-05-19 2011-11-23 中国科学院大连化学物理研究所 一种用于环烷烃脱氢铂基催化剂稳定性的改进方法
CN106238045A (zh) 2010-12-17 2016-12-21 埃克森美孚化学专利公司 脱氢催化剂和方法
KR20130133008A (ko) 2011-03-28 2013-12-05 엑손모빌 케미칼 패턴츠 인코포레이티드 탈수소화 방법
US8946495B2 (en) 2011-05-22 2015-02-03 Fina Technology, Inc. Process for alkylation of toluene to form styrene and ethylbenzene
CN104667912A (zh) * 2014-07-10 2015-06-03 中国科学院福建物质结构研究所 一种co脱氢流化床反应用催化剂及其制备方法和应用
US10682628B2 (en) * 2017-11-02 2020-06-16 Uop Llc Processes for regenerating a catalyst for the selective conversion of hydrocarbons
CN110013759A (zh) * 2018-01-09 2019-07-16 中国石油化工股份有限公司 低温催化氧化处理含氢驰放气的装置及方法
CN113286653A (zh) * 2018-10-30 2021-08-20 科莱恩国际有限公司 脱氢催化剂及其制备和使用方法

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4418237A (en) * 1981-03-30 1983-11-29 Uop Inc. Dehydrogenation of dehydrogenatable hydrocarbons
US4599471A (en) * 1985-09-16 1986-07-08 Uop Inc. Method for oxygen addition to oxidative reheat zone of hydrocarbon dehydrogenation process
US4812597A (en) * 1987-09-02 1989-03-14 Uop Inc. Dehydrogenation of dehydrogenatable hydrocarbons
US4914249A (en) * 1988-12-29 1990-04-03 Uop Dehydrogenation of dehydrogenatable hydrocarbons
DE3935073A1 (de) * 1989-10-20 1991-04-25 Sued Chemie Ag Verfahren zur katalytischen dehydrierung von kohlenwasserstoffen, insbesondere von alkylaromaten
JP3860625B2 (ja) * 1996-08-19 2006-12-20 三菱化学株式会社 水素の酸化触媒、水素の選択的酸化方法、及び炭化水素の脱水素方法
DE19812468A1 (de) * 1998-03-23 1999-09-30 Basf Ag Verfahren zur Herstellung von 1,2-Dichlorethan
US6177381B1 (en) * 1998-11-03 2001-01-23 Uop Llc Layered catalyst composition and processes for preparing and using the composition
DE10009017A1 (de) * 2000-02-25 2001-09-06 Basf Ag Geformte Katalysatoren
US6858769B2 (en) * 2002-10-18 2005-02-22 Uop Llc Lithium aluminate layered catalyst and a selective oxidation process using the catalyst

Also Published As

Publication number Publication date
WO2005097715A1 (de) 2005-10-20
US20080262281A1 (en) 2008-10-23
RU2006137946A (ru) 2008-05-10
CN1938246A (zh) 2007-03-28
JP2007537029A (ja) 2007-12-20
CA2558547A1 (en) 2005-10-20
EP1732867A1 (de) 2006-12-20
KR20070004845A (ko) 2007-01-09

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