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DE10195284D2 - Reformeranlage mit Wärmeschild - Google Patents

Reformeranlage mit Wärmeschild

Info

Publication number
DE10195284D2
DE10195284D2 DE10195284T DE10195284T DE10195284D2 DE 10195284 D2 DE10195284 D2 DE 10195284D2 DE 10195284 T DE10195284 T DE 10195284T DE 10195284 T DE10195284 T DE 10195284T DE 10195284 D2 DE10195284 D2 DE 10195284D2
Authority
DE
Germany
Prior art keywords
heat shield
reformer system
reformer
shield
heat
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE10195284T
Other languages
English (en)
Other versions
DE10195284B4 (de
Inventor
Rolf Brueck
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Vitesco Technologies Lohmar Verwaltungs GmbH
Original Assignee
Emitec Gesellschaft fuer Emissionstechnologie mbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Emitec Gesellschaft fuer Emissionstechnologie mbH filed Critical Emitec Gesellschaft fuer Emissionstechnologie mbH
Priority to DE10195284T priority Critical patent/DE10195284B4/de
Publication of DE10195284D2 publication Critical patent/DE10195284D2/de
Application granted granted Critical
Publication of DE10195284B4 publication Critical patent/DE10195284B4/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/386Catalytic partial combustion
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24Stationary reactors without moving elements inside
    • B01J19/248Reactors comprising multiple separated flow channels
    • B01J19/2485Monolithic reactors
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/32Packing elements in the form of grids or built-up elements for forming a unit or module inside the apparatus for mass or heat transfer
    • B01J19/325Attachment devices therefor, e.g. hooks, consoles, brackets
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/36Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using oxygen or mixtures containing oxygen as gasifying agents
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/36Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using oxygen or mixtures containing oxygen as gasifying agents
    • C01B3/363Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using oxygen or mixtures containing oxygen as gasifying agents characterised by the burner used
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00051Controlling the temperature
    • B01J2219/00074Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/00094Jackets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00051Controlling the temperature
    • B01J2219/00132Controlling the temperature using electric heating or cooling elements
    • B01J2219/00135Electric resistance heaters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00051Controlling the temperature
    • B01J2219/0015Controlling the temperature by thermal insulation means
    • B01J2219/00153Vacuum spaces
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00051Controlling the temperature
    • B01J2219/0015Controlling the temperature by thermal insulation means
    • B01J2219/00155Controlling the temperature by thermal insulation means using insulating materials or refractories
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/18Details relating to the spatial orientation of the reactor
    • B01J2219/182Details relating to the spatial orientation of the reactor horizontal
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/32Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
    • B01J2219/322Basic shape of the elements
    • B01J2219/32203Sheets
    • B01J2219/3221Corrugated sheets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/32Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
    • B01J2219/322Basic shape of the elements
    • B01J2219/32203Sheets
    • B01J2219/32213Plurality of essentially parallel sheets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/32Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
    • B01J2219/322Basic shape of the elements
    • B01J2219/32203Sheets
    • B01J2219/32275Mounting or joining of the blocks or sheets within the column or vessel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/32Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
    • B01J2219/322Basic shape of the elements
    • B01J2219/32296Honeycombs
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0205Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0244Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0283Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06Integration with other chemical processes
    • C01B2203/066Integration with other chemical processes with fuel cells
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08Methods of heating or cooling
    • C01B2203/0805Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0838Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
    • C01B2203/0844Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08Methods of heating or cooling
    • C01B2203/0805Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/085Methods of heating the process for making hydrogen or synthesis gas by electric heating
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14Details of the flowsheet
    • C01B2203/142At least two reforming, decomposition or partial oxidation steps in series
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/16Controlling the process
    • C01B2203/1604Starting up the process
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/82Several process steps of C01B2203/02 - C01B2203/08 integrated into a single apparatus

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Hydrogen, Water And Hydrids (AREA)
DE10195284T 2000-12-08 2001-12-07 Reformeranlage mit Wärmeschild Expired - Fee Related DE10195284B4 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DE10195284T DE10195284B4 (de) 2000-12-08 2001-12-07 Reformeranlage mit Wärmeschild

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DE10061084A DE10061084A1 (de) 2000-12-08 2000-12-08 Reformeranlage mit Wärmeschild
DE10061084.6 2000-12-08
DE10195284T DE10195284B4 (de) 2000-12-08 2001-12-07 Reformeranlage mit Wärmeschild
PCT/EP2001/014416 WO2002046094A2 (de) 2000-12-08 2001-12-07 Reformeranlage mit wärmeschild

Publications (2)

Publication Number Publication Date
DE10195284D2 true DE10195284D2 (de) 2003-11-06
DE10195284B4 DE10195284B4 (de) 2011-03-24

Family

ID=7666298

Family Applications (2)

Application Number Title Priority Date Filing Date
DE10061084A Withdrawn DE10061084A1 (de) 2000-12-08 2000-12-08 Reformeranlage mit Wärmeschild
DE10195284T Expired - Fee Related DE10195284B4 (de) 2000-12-08 2001-12-07 Reformeranlage mit Wärmeschild

Family Applications Before (1)

Application Number Title Priority Date Filing Date
DE10061084A Withdrawn DE10061084A1 (de) 2000-12-08 2000-12-08 Reformeranlage mit Wärmeschild

Country Status (5)

Country Link
US (1) US7547331B2 (de)
JP (1) JP4365090B2 (de)
AU (1) AU2002229635A1 (de)
DE (2) DE10061084A1 (de)
WO (1) WO2002046094A2 (de)

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Publication number Priority date Publication date Assignee Title
JP2003089504A (ja) * 2001-07-09 2003-03-28 Mitsubishi Heavy Ind Ltd 燃料改質装置
JP4169316B2 (ja) * 2002-01-31 2008-10-22 アイシン精機株式会社 燃料改質装置
CN100393854C (zh) * 2003-01-13 2008-06-11 弗劳尔公司 用于变换转化的改进配置和方法
US20050132648A1 (en) * 2003-11-27 2005-06-23 Kyocera Corporation Fuel reformer housing container and fuel reforming apparatus
DE102005006133B4 (de) * 2004-02-10 2009-01-15 Kyocera Corp. Brennstoffreformer-Unterbringungsbehälter und Brennstoffreformiervorrichtung
JP3872491B2 (ja) * 2005-02-01 2007-01-24 学校法人慶應義塾 燃料電池用の改質器および燃料電池システム
DE102005026783A1 (de) * 2005-06-10 2006-12-21 Bayerische Motoren Werke Ag Reformersystem mit einer Abkühleinrichtung
DE102005040052B4 (de) * 2005-06-10 2014-03-20 Bayerische Motoren Werke Aktiengesellschaft Kraftfahrzeug mit einem Reformersystem mit einer Abkühleinrichtung
KR101282578B1 (ko) * 2006-04-14 2013-07-04 삼성에스디아이 주식회사 복수의 가열수단을 구비한 개질기 및 이를 이용한 연료전지시스템
DE102006039933A1 (de) * 2006-08-25 2008-02-28 Enerday Gmbh Reformer zum Umsetzen von gasförmigem Brennstoff und Oxidationsmittel zu Reformat
JP5605157B2 (ja) * 2010-10-19 2014-10-15 パナソニック株式会社 水素生成装置
DE102011100417A1 (de) * 2011-05-04 2012-11-08 Vaillant Gmbh Reformer
WO2014042800A1 (en) * 2012-09-17 2014-03-20 Board Of Regents, The University Of Texas System Catalytic plate reactors
JP6796758B2 (ja) * 2018-02-14 2020-12-09 パナソニックIpマネジメント株式会社 水素生成装置
KR102787291B1 (ko) * 2019-01-15 2025-03-27 사빅 글로벌 테크놀러지스 비.브이. 화학 물질의 생성에서 간헐적 에너지의 사용

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DE2046324A1 (de) * 1970-09-19 1972-03-23 Berger, Heinz, 3470 Höxter Vorrichtung zur Vernichtung der schädlichen Anteile der Abgase von Verbrennungsmotoren
US3958951A (en) 1974-04-09 1976-05-25 Stone & Webster Engineering Corporation Convective power reformer equipment and system
EP0025308B1 (de) * 1979-09-06 1984-07-11 Imperial Chemical Industries Plc Verfahren und Vorrichtung für den katalytischen Umsatz von Wasserdampf mit Kohlenwasserstoffen unter endothermen Bedingungen
US4844837A (en) * 1982-09-30 1989-07-04 Engelhard Corporation Catalytic partial oxidation process
US4804580A (en) 1988-07-07 1989-02-14 International Fuel Cells Corporation Catalytic reformer housing insulation and method of making same
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DE4230583A1 (de) * 1992-09-12 1994-03-17 Bayerische Motoren Werke Ag Elektrische Speicherbatterie, insbesondere für einen Fahrzeug-Antrieb
GB9225188D0 (en) * 1992-12-02 1993-01-20 Rolls Royce & Ass Combined reformer and shift reactor
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DE4307217C2 (de) * 1993-03-08 2000-08-31 Schuemann Sasol Gmbh & Co Kg Latentwärmespeicher für ein Kraftfahrzeug
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DE19639150C2 (de) * 1996-09-24 1998-07-02 Daimler Benz Ag Zentrale Heizvorrichtung für ein Gaserzeugungssystem
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US6576203B2 (en) * 1998-06-29 2003-06-10 Ngk Insulators, Ltd. Reformer
US6203764B1 (en) * 1999-01-15 2001-03-20 Midwest Research Institute Vacuum-insulated catalytic converter
DE19909935A1 (de) * 1999-03-06 2000-09-07 Daimler Chrysler Ag Reaktoreinheit, insbesondere autothermer Primärreformer
JP2001295707A (ja) * 1999-06-03 2001-10-26 Toyota Motor Corp 車両搭載用の燃料改質装置

Also Published As

Publication number Publication date
AU2002229635A1 (en) 2002-06-18
JP2004515434A (ja) 2004-05-27
US7547331B2 (en) 2009-06-16
WO2002046094A2 (de) 2002-06-13
DE10061084A1 (de) 2002-07-04
US20040033174A1 (en) 2004-02-19
WO2002046094A3 (de) 2002-09-19
JP4365090B2 (ja) 2009-11-18
DE10195284B4 (de) 2011-03-24

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Effective date: 20110810

R119 Application deemed withdrawn, or ip right lapsed, due to non-payment of renewal fee

Effective date: 20130702