DE10129856A1 - Selective herbicides based on pyrimidine derivatives - Google Patents

Abstract

The invention relates to novel herbicide and synergistic combinations of active ingredients consisting of known pyrimidine derivatives, at least two other known herbicidally active compounds, and optionally additional safeners. Said combinations are especially successful when used for selective weed control in different useful plant cultures.

Description

The invention relates to new herbicidal, synergistic combinations of active ingredients consisting of at least three mixed partners, the known pyrimidine derivatives on the one hand and known, herbicidally active compounds and, if appropriate On the other hand, safeners exist and are particularly successful at selective Weed control can be used in various crops.

Pyrimidine derivatives are the subject of a number of broad-spectrum herbicides Patent applications (cf. US 4 906 285, EP-A-321 846, EP-A 658 549, US 4 248 619, US 4,427,437). The known pyrimidine derivatives, however, have a number of Impact gaps. The tolerability of these compounds Cultivated plants are also not entirely satisfactory under all conditions.

Surprisingly, it has now been found that a number of known active ingredients from the series of phenoxypyrimidine derivatives when used together with known herbicidally active compounds from various classes of substances show pronounced synergistic effects with regard to the action against weeds and particularly advantageous as a broadly effective combination preparation for selective Control of weeds in various crops such as B. in soy, Potatoes, corn or rice and especially in cereals, such as. B. barley, rye, Triticale and especially wheat, can be used.

• a) zumindest ein Phenoxypyrimidin-Derivat der allgemeinen Formel (I)
  
  
  in welcher
  R für Wasserstoff, -CH₂CH₂S(O)_nR₁ (wobei R₁ für C₁-C₄-Alkyl und n für 0, 1 oder 2 steht) oder
  
  
  steht,
  wobei
  R₂ für Wasserstoff, Halogen, Cyano, Phenyl, C₁-C₈-Alkyl, C₁-C₄- Alkoxy, C₁-C₄-Alkylthio, C₁-C₄-Alkoxycarbonyl, Mono- oder Di-C₁-C₄-Alkylaminocarbonyl, Phenyl-C₁-C₄ -Alkylaminocarbonyl steht, wobei die Phenylgruppe gegebenenfalls durch Halogen, C₁-C₂-Alkyl oder C₁-C₂-Alkoxy, Furylmethylaminocarbonyl oder Phenyl substituiert sein kann, und
  R₃ für jeweils gegebenenfalls durch Halogen, Cyano, Nitro, C₁- C₄-Alkyl, C₁-C₄-Alkoxy oder Allyloxy substituiertes Phenyl, für gegebenenfalls durch C₁-C₄-Alkyl, Phenoxy, Benzyloxy oder Acetoxy substituiertes Amino, für C₁-C₄-Alkylthio oder für die Gruppierung -COR₄ steht, wobei R₄ für C₁-C₄-Alkoxy, C₁- C₄-Alkyl, Benzyloxy oder Benzylamino steht,
  A für Chlor oder Methoxy steht und
  D und E, die gleich oder unterschiedlich sein können, für Wasserstoff, Halogen, C₁-C₈-Alkyl, C₁-C₈-Alkoxy oder durch Halogen substituiertes C₁-C₈- Alkoxy stehen,
  und/oder einem Salz einer Verbindung der Formel (I)
  ("Wirkstoffe der Gruppe 1"),
  und
• b) zumindest eine Verbindung aus einer weiteren Gruppe von Herbiziden, welche die nachstehend genannten Wirkstoffe enthält:
  Methyl-2-[[[(4,5-dihydihydro-4-methyl-5-oxo-3-propoxy-1H-1,2,4-triazol-1-yl)carbonyl]amino]sulfonyl]-benzoesäure, Natrium-Salz (Propoxycarbazonesodium) der Formel
  
  
  und
  4,5-dihydro-3-methoxy-4-methyl-5-oxo-N-[[2-(trifluoromethoxy)phenyl]sulfonyl]-1H-1,2,4-triazol-1-carboxamid, Natrium-Salz (Flucarbazone-sodium) der Formel
  
  
  ("Wirkstoffe der Gruppe 2"),
  sowie
• c) einer oder mehrerer Verbindungen aus einer weiteren Gruppe von Herbiziden, welche die nachstehend genannten Wirkstoffe enthält:
  2-Chlor-N-(ethoxymethyl)-N-(2-ethyl-6-methyl-phenyl)-acetamid (Acetochlor), 5-(2-Chlor-4-trifluormethyl-phenoxy)-2-nitro-benzoesäure-Natriumsalz (Acifluorfen-sodium), 2-Chlor-6-nitro-3-phenoxybenzenamin (Aclonifen), 2-Chlor-N-(methoxymethyl)-N-(2,6-diethyl-phenyl)-acetamid (Alachlor), N-Ethyl-N'-i-propyl-6-methylthio-1,3,5-triazin-2,4-diamin (Ametryn), 4-Amino-N-(1,1-Dimethyl-ethyl)-4,5-dihydro-3-(1-methyl-ethyl)-5-oxo-1H- 1,2,4-triazol-1-carboxamid (Amicarbazone), N-(4,6-Dimethoxy-pyrimidin-2- yl)-N'-(N-methyl-N-methylsulfonyl-sulfamoyl)-harnstoff (Amidosulfuron), 1H-1,2,4-Triazol-3-amin (Amitrole), S-[2-[(4-Chlor-phenyl)-(1-isopropyl)- amino]-2-oxo-ethyl]-O,O-dimethyl-phosphorodithioate (Anilofos), 6-Chlor-4- ethylamino-2-isopropylamino-1,3,5-triazin (Atrazin), 2-[2,4-Dichlor-5-(2- propinyloxy)-phenyl]-5,6,7,8-tetrahydro-1,2,4-triazolo-[4,3-a]-pyridin-3(2H)- on (Azafenidin), N-(4,6-Dimethoxy-pyrimidin-2-yl)-N'-[1-methyl-4-(2- methyl-2H-tetrazol-5-yl)-1H-pyrazol-5-ylsulfonyl]-harnstoff (Azimsulfuron), N-Benzyl-2-(4-fluor-3-trifluormethyl-phenoxy)-butanamid (Beflubutamid), 4- Chlor-2-oxo-3(2H)-benzthiazolessigsäure (Benazolin), N-Butyl-N-ethyl-2,6- dinitro-4-trifluormethyl-benzenamin (Benfluralin), 2,3-Dihydro-3,3-dimethyl- 5-benzofuranylethansulfonat (Benfuresate), N-(4,6-Dimethoxy-pyrimidin-2- yl)-N'-(2-methoxycarbonyl-phenylmethylsulfonyl)-harnstoff (Bensulfuronmethyl), S-[(4-Chlor-phenyl)-methyl]-diethylthiocarbamat (Benthiocarb, Thiobencarb), 2-[2-[4-(3,6-Dihydro-3-methyl-2,6-dioxo-4-trifluormethyl- 1(2H)-pyrimidinylphenoxymethyl]-5-ethyl-phenoxy-propansäure-methylester (Benzfendizone), 3-(2-Chlor-4-methylsulfonyl-benzoyl)-4-phenylthio-bicyclo-[3.2.1]-oct-3-en-2-on (Benzobicyclon), 2-[[4-(2,4-Dichlor-3-methylbenzoyl)-1,3-dimethyl-1H-pyrazol-5-yl]-oxy]-1-(4-methyl-phenyl)-ethanon (Benzofenap), Ethyl N-benzoyl-N-(3,4-dichlor-phenyl)-DL-alaninat (Benzoylprop-ethyl), 3-i-Propyl-1H-2,1,3-benzothiadiazin-4(3H)-on (Bentazon), Methyl-5-(2,4-dichlor-phenoxy)-2-nitro-benzoat (Bifenox), 5- Brom-6-methyl-3-(1-methyl-propyl)-2,4(1H,3H)pyrimidindion (Bromacil), 2- Brom-3,3-dimethyl-N-(1-methyl-1-phenyl-ethyl)-butanamid (Bromobutide), 3,5-Dibrom-4-hydroxy-benzaldehyd-O-(2,4-dinitro-phenyl)-oxim (Bromofenoxim), 3,5-Dibrom-4-hydroxy-benzonitril (Bromoxynil), N-Butoxymethyl-2- chlor-N-(2,6-diethyl-phenyl)-acetamid (Butachlor), 2-Chlor-5-(3,6-dihydro-3- methyl-2,6-dioxo-4-trifluormethyl-1(2H)-pyrimidinyl)-benzoesäure-[1,1-dimethyl-2-oxo-2-(2-propenyloxy)]-ethylester (Butafenacil-allyl), 2-(1-Ethoximino-propyl)-3-hydroxy-5-[2,4,6-trimethyl-3-(1-oxo-butyl)-phenyl]-2-cyclohexen-1-on (Butroxydim), S-Ethyl-bis-(2-methyl-propyl)-thiocarbamat (Butylate), N,N-Diethyl-3-(2,4,6-trimethyl-phenylsulfonyl)-1H-1,2,4-triazol-1- carboxamid (Cafenstrole), 2-[1-[(3-Chlor-2-propenyl)-oxy-imino]-propyl]-3- hydroxy-5-(tetrahydro-2H-pyran-4-yl)-2-cyclohexen-1-on (Caloxydim, Tepraloxydim), 2-(4-Chlor-2-fluor-5-(2-chlor-2-ethoxycarbonyl-ethyl)- phenyl)-4-difluormethyl-5-methyl-2,4-dihydro-3H-1,2,4-triazol-3-on (Carfentrazone-ethyl), 2,4-Dichlor-1-(3-methoxy-4-nitro-phenoxy)-benzol (Chlomethoxyfen), 3-Amino-2,5-dichlor-benzoesäure (Chloramben), N-(4-Chlor-6- methoxy-pyrimidin-2-yl)-N'-(2-ethoxycarbonyl-phenylsulfonyl)-harnstoff (Chlorimuron-ethyl), 1,3,5-Trichlor-2-(4-nitro-phenoxy)-benzol (Chlornitrofen), N-(4-Methoxy-6-methyl-1,3,5-triazin-2-yl)-N'-(2-chlor-phenylsulfonyl)- harnstoff (Chlorsulfuron), N'-(3-Chlor-4-methyl-phenyl)-N,N-dimethyl-harnstoff (Chlortoluron), 2-Chlor-3-[2-chlor-5-(1,3,4,5,6,7-hexahydro-1,3-dioxo- 2H-isoindol-2-yl)-phenyl]-2-propansäure-ethylester (Cinidon-ethyl), Exo-1- methyl-4-isopropyl-2-(2-methyl-phenyl-methoxy)-7-oxabicyclo-[2.2.1]- heptan (Cinmethylin), N-(4,6-Dimethoxy-1,3,5-triazin-2-yl)-N'-(2-(2-methoxy-ethoxy)-phenylsulfonyl)-harnstoff (Cinosulfuron), 2-[1-[2-(4-Chlorphenoxy)-propoxyaminobutyl]-5-(tetrahydro-2H-thiopyran-3-yl)-1,3-cyclohexandion (Clefoxydim), (E,E)-(+)-2-[1-[[(3-Chlor-2-propenyl)-oxy]-imino]- propyl]-3-hydroxy-2-cyclohexen-1-on (Clethodim), (R)-(2-Propinyl)-2-[4-(5- chlor-3-fluor-pyridin-2-yl-oxy)-phenoxy-propanoat (Clodinafop-propargyl), 2-(2,4-Dichlor-3-methyl-phenoxy)-N-phenyl-propanamid (Clomeprop), 3,6- Dichlor-pyridin-2-carbonsäure (Clopyralid), Methyl-3-chloro-2-[(5-ethoxy-7- fluor[1,2,4]triazolo[1,5-c]pyrimidin-2-yl-sulfonyl)-amino]-benzoat (Cloransulam-methyl), N-[(2-Chlor-phenyl)-methyl]-N'-(1-methyl-1-phenyl-ethyl)- harnstoff (Cumyluron), 2-Chlor-4-ethylamino-6-(1-cyano-1-methyl-ethylamino)-1,3,5-triazin (Cyanazine), N-(4,6-Dimethoxy-pyrimidin-2-yl)-N'-(2- cyclopropylcarbonyl-phenylsulfonyl)-harnstoff (Cyclosulfamuron), 2-(1- Ethoximinobutyl)-3-hydroxy-5-(tetrahydro-2H-thiopyran-3-yl)-2-cyclohexen- 1-on (Cycloxydim), (R)-2-[4-(4-Cyano-2-fluor-phenoxy)-phenoxy]-propansäure-butylester (Cyhalofop-butyl), 2,4-Dichlor-phenoxyessigsäure (2,4-D), 3,6-Dichlor-2-methoxy-benzoesäure (Dicamba), (R)-2-(2,4-Dichlor-phenoxy)-propansäure (Dichlorprop-P), Methyl-2-[4-(2,4-dichlor-phenoxy)-phenoxy]-propanoat (Diclofop-methyl), N-(2,6-Dichlor-phenyl)-5-ethoxy-7-fluor- [1,2,4]-triazolo-[1,5-c]-pyrimidin-2-sulfonamid (Diclosulam), 1,2-Dimethyl- 3,5-diphenyl-1H-pyrazolium-methylsulfat (Difenzoquat), N-(2,4-Difluorphenyl)-2-(3-trifluormethyl-phenoxy)-pyridin-3-carboxamid (Diflufenican), 2-[1-[(3,5-Difluor-phenyl)-amino-carbonyl-hydrazono]-ethyl]-pyridin-3-carbonsäure (Diflufenzopyr), S-(1-Methyl-1-phenyl-ethyl)-1-piperidin-carbothioat (Dimepiperate), 2-Chlor-N-(2,6-dimethyl-phenyl)-N-(2-methoxyethyl)-acetamid (Dimethachlor), N-(1,2-Dimethyl-propyl)-N'-ethyl-6-methylthio-1,3,5-triazin-2,4-diamin (Dimethametryn), (S-)2-Chlor-N-(2,4-dimethyl- 3-thienyl)-N-(2-methoxy-1-methyl-ethyl)-acetamid (S-) (Dimethenamid), 2- Amino-4-(1-fluor-1-methyl-ethyl)-6-(1-methyl-2-(3,5-dimethyl-phenoxy)- ethylamino)-1,3,5-triazin (Dimexyflam), N3,N3-Diethyl-2,4-dinitro-6-trifluormethyl-1,3-diamino-benzol (Dinitramine), 6,7-Dihydro-dipyrido[1,2- a:2',1'-c]pyrazindiium (Diquat), S,S-Dimethyl-2-difluormethyl-4-i-butyl-6- trifluormethyl-pyridin-3,5-dicarbothioat (Dithiopyr), N'-(3,4-Dichlorphenyl)-N,N-dimethyl-harnstoff (Diuron), N-(4-Methyl-phenyl)-N'-(1- methyl-1-phenyl-ethyl)-harnstoff (Dymron, Daimuron), 2-[2-(3-Chlorphenyl)-oxiranylmethyl]-2-ethyl-1H-inden-1,3(2H)-dion (Epropodan), S- Ethyl-dipropylthiocarbamat (EPTC), S-(Phenylmethyl)-N-ethyl-N-(1,2-dimethyl-propyl)-thiocarbamat (Esprocarb), N-Ethyl-N-(2-methyl-2-propenyl)- 2,6-dinitro-4-trifluormethyl-benzenamin (Ethalfluralin), (S)-(2-Ethoxy-1- methyl-2-oxoethyl)-2-chlor-5-(2-chlor-4-trifluormethyl-phenoxy)-benzoat (Ethoxyfen), N-(4,6-Dimethoxy-pyrimidin-2-yl)-N'-(2-ethoxy-phenoxysulfonyl)-harnstoff (Ethoxysulfuron), N-(2,3-Dichlor-phenyl)-4-ethoxymethoxybenzamid (Etobenzanid), (R)-Ethyl-2-[4-(6-chlor-benzoxazol-2-yl-oxy)-phenoxy]-propanoat (Fenoxaprop-(P)-ethyl), 4-(2-Chlor-phenyl)-N-cyclohexyl-N- ethyl-4,5-dihydro-5-oxo-1H-tetrazol-1-carboxamid (Fentrazamide), Isopropyl-N-benzoyl-N-(3-chlor-4-fluro-phenyl)-DL-alaninat (Flamprop-isopropyl), Isopropyl-N-benzoyl-N-(3-chlor-4-fluro-phenyl)-L-alaninat (Flamprop-isopropyl-L), Methyl-N-benzoyl-N-(3-chlor-4-fluor-phenoxy)-DL- alaninat (Flamprop-methyl), N-(2,6-Difluor-phenyl)-8-fluor-5-methoxy- [1,2,4]-triazolo-[1,5-c]-pyrimidin-2-sulfonamid (Florasulam), (R)-2-[4-(5-Trifluormethyl-pyridin-2-yl-oxy)-phenoxy]-propansäure-butylester (Fluazifop, -butyl, -P-butyl), 5-(4-Brom-1-methyl-5-trifluormethyl-1H-pyrazol-3-yl)-2- chlor-4-fluor-benzoesäure-i-propylester (Fluazolate), 4,5-Dihydro-3-methoxy- 4-methyl-5-oxo-N-[(2-trifluormethoxy-phenyl)-sulfonyl]-1-H-1,2,4-triazol-1- carboxamid-Natriumsalz (Flucarbazone-sodium), N-(4-Fluor-phenyl)-N-i- propyl-2-(5-trifluormethyl-1,3,4-thiadiazol-2-yl-oxy)-acetamid (Flufenacet), N-(2,6-Difluor-phenyl)-5-methyl-1,2,4-triazolo[1,5-a]-pyrimidin-2-sulfonamid (Flumetsulam), Pentyl-[2-chlor-4-fluor-5-(1,3,4,5,6,7-hexahydro-1,3-dioxo-2H-isoindol-2-yl)-phenoxy]-acetat (Flumiclorac-pentyl), 2-[7-Fluor-3,4- dihydro-3-oxo-4-(2-propinyl)-2H-1,4-benzoxazin-6-yl]-4,5,6,7-tetrahydro- 1H-isoindol-1,3-dion (Flumioxazin), 2-[4-Chlor-2-fluor-5-[(1-methyl-2-propinyl)-oxy]-phenyl]-4,5,6,7-tetrahydro-1H-isoindol-1,3(2H)-dion (Flumipropyn), 3-Chlor-4-chlormethyl-1-(3-trifluormethyl-phenyl)-2-pyrrolidinon (Fluorochloridone), 5-(2-Chlor-4-trifluormethyl-phenoxy)-2-nitro-benzoesäure-ethoxycarbonylmethylester (Fluoroglycofen-ethyl), 1-(4-Chlor-3- (2,2,3,3,3-pentafluor-propoxymethyl)-phenyl)-5-phenyl-1H-1,2,4-triazol-3- carboxamid (Flupoxam), 1-Isopropyl-2-chlor-5-(3,6-dihydro-3-methyl-2,6-dioxo-4-trifluormethyl-1(2H)-pyrimidyl)-benzoat (Flupropacil), N-(4,6-Dimethoxy-pyrimidin-2-yl)-N'-(3-methoxycarbonyl-6-trifluormethyl-pyridin-2- yl-sulfonyl)-harnstoff-Natriumsalz (Flupyrsulfuron-methyl-sodium), 9- Hydroxy-9H-fluoren-9-carbonsäure (Flurenol), (4-Amino-3,5-dichlor-6-fluorpyridin-2-yl-oxy)-essigsäure (-2-butoxy-1-methyl-ethylester, -1-methylheptylester) (Fluroxypyr, -butoxypropyl, -meptyl), 5-Methylamino-2-phenyl- 4-(3-trifluormethyl-phenyl)-3(2H)-furanon (Flurtamone), Methyl-[(2-chlor-4- fluor-5-(tetrahydro-3-oxo-1H,3H-[1,3,4]-thiadiazolo-[3,4-a]-pyridazin-1- yliden)-amino-phenyl]-thioacetat (Fluthiacet-methyl), 5-(2-Chlor-4-trifluormethyl-phenoxy)-N-methylsulfonyl-2-nitro-benzamid (Fomesafen), 2- [[[[(4,6-Dimethoxy-2-pyrimidinyl)-amino]-carbonyl]-amino]-sulfonyl]-4- formylamino-N,N-dimethyl-benzamid (Foramsulfuron), 2-Amino-4- (hydroxymethylphosphinyl)-butansäure (-ammoniumsalz) (Glufosinate (-ammonium)), N-Phosphonomethyl-glycin (-isopropylammmoniumsalz), (Glyphosate, -isopropylammonium), (R)-2-[4-(3-Chlor-5-trifluormethylpyridin-2-yl-oxy)-phenoxy]-propansäure (-methylester, -2-ethoxy-ethylester, -butylester) (Haloxyfop, -methyl, -P-methyl, -ethoxyethyl, -butyl), 3-Cyclohexyl-6-dimethylamino-1-methyl-1,3,5-triazin-2,4(1H,3H)-dion (Hexazinone), Methyl-2-(4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl)- 4-methyl-benzoat (Imazamethabenz-methyl), 2-(4,5-Dihydro-4-methyl-4-iso- propyl-5-oxo-1H-imidazol-2-yl)-5-methyl-pyridin-3-carbonsäure (Imazamethapyr), 2-(4,5-Dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl)-5- methoxymethyl-pyridin-3-carbonsäure (Imazamox), 2-(4,5-Dihydro-4- methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl)-chinolin-3-carbonsäure (Imazaquin), 2-(4,5-Dihydro-4-methyl-4-i-propyl-5-oxo-1H-imidazol-2-yl)-5-ethylpyridin-3-carbonsäure (Imazethapyr), N-(4,6-Dimethoxy-pyrimidin-2-yl)-N'- (2-chlor-imidazo[1,2-a]-pyridin-3-yl-sulfonyl)-harnstoff (Imazosuliron), N- (4-Methoxy-6-methyl-1,3,5-triazin-2-yl)-N' -(5-iod-2-methoxycarbonylphenylsulfonyl)-harnstoff-Natriumsalz (Iodosulfuron-methyl-sodium), 4- Hydroxy-3,5-diiod-benzonitril (Ioxynil), N,N-Dimethyl-N'-(4-isopropylphenyl)-harnstoff (Isoproturon), N-(3-(1-Ethyl-1-methyl-propyl)-isoxazol-5- yl)-2,6-dimethoxy-benzamid (Isoxaben), (4-Chlor-2-methylsulfonyl-phenyl)- (5-cyclopropyl-isoxazol-4-yl)-methanon (Isoxachlortole), (5-Cyclopropylisoxazol-4-yl)-(2-methylsulfonyl-4-trifluormethyl-phenyl)-methanon (Isoxaflutole), 2-[2-[4-[3,5-Dichlor-2-pyridinyl)-oxy]-phenoxy]-1-oxo-propyl]-isoxazolidin (Isoxapyrifop), (2-Ethoxy-1-methyl-2-oxo-ethyl)-5-(2-chlor-4-trifluormethyl-phenoxy)-2-nitro-benzoat (Lactofen), N'-(3,4-dichlor-phenyl)-N- methoxy-N-methyl-harnstoff (Linuron), (4-Chlor-2-methyl-phenoxy)-essigsäure (MCPA), 2-(4-Chlor-2-methyl-phenoxy)-propionsäure (Mecoprop), 2- (2-Benzthiazolyloxy)-N-methyl-N-phenyl-acetamid (Mefenacet), 2-[[[[(4,6- Dimethoxy-2-pyrimidinyl)-amino]-carbonyl]-amino]-sulfonyl]-4-[[(methylsulfonyl)-amino]methyl]-benzoesäure-methylester (Mesosulfuron), 2-(4- Methylsulfonyl-2-nitro-benzoyl)-1,3-cyclohexandion (Mesotrione), 4-Amino- 3-methyl-6-phenyl-1,2,4-triazin-5(4H)-on (Metamitron), 2-Chlor-N-(2,6-dimethyl-phenyl)-N-(1 H-pyrazol-1-yl-methyl)-acetamid (Metazachlor), N'-(4- (3,4-Dihydro-2-methoxy-2,4,4-trimethyl-2H-1-benzopyran-7-yl-oxy)- phenyl)-N-methoxy-N-methyl-harnstoff (Metobenzuron), N'-(4-Bromphenyl)-N-methoxy-N-methylharnstoff (Metobromuron), (S)-2-Chlor-N-(2- ethyl-6-methyl-phenyl)-N-(2-methoxy-1-methyl-ethyl)-acet-amid (Metolachlor, S-Metolachlor), N-(2,6-Dichlor-3-methyl-phenyl)-5,7-dimethoxy- 1,2,4-triazolo[1,5-a]-pyrimidin-2-sulfonamid (Metosulam), N'-(3-Chlor-4- methoxy-phenyl)-N,N-dimethyl-harnstoff (Metoxuron), 4-Amino-6-tertbutyl-3-methylthio-1,2,4-triazin-5(4H)-on (Metribuzin), N-(4-Methoxy-6- methyl-1,3,5-triazin-2-yl)-N'-(2-methoxycarbonyl-phenylsulfonyl)-harnstoff (Metsulfuron-methyl), S-Ethyl-hexahydro-1H-azepin-1-carbothioat (Molinate), 2-(2-Naphthyloxy)-N-phenyl-propanamid (Naproanilide), N-Butyl-N'- (3,4-dichlor-phenyl)-N-methyl-harnstoff (Neburon), N-(4,6-Dimethoxy-pyrimidin-2-yl)-N'-(3-dimethylcarbamoyl-pyridin-2-yl-sulfonyl)-harnstoff (Nicosulfuron), 4-Chlor-5-methylamino-2-(3-trifluormethyl-phenyl)-3(2H)pyridazinon (Norflurazon), S-(2-Chlor-benzyl)-N,N-diethyl-thiocarbamat (Orbencarb), 4-Dipropylamino-3,5-dinitro-benzensulfonamid (Oryzalin), 3-[2,4-Dichlor-5-(2-propinyloxy)-phenyl]-5-(t-butyl)-1,3,4-oxadiazol-2(3H)-on (Oxadiargyl), 3-[2,4-Dichlor-5-(1-methyl-ethoxy)-phenyl]-5-(t-butyl)-1,3,4-oxadiazol-2(3H)-on (Oxadiazon), N-(4,6-Dimethyl-pyrimidin-2-yl)-N'-(2-oxetan- 3-yl-oxycarbonyl-phenylsulfonyl)-harnstoff (Oxasulfuron), 3-[1-(3,5-Dichlorphenyl)-1-i-propyl]-2,3-dihydro-6-methyl-5-phenyl-4H-1,3-oxazin-4-on (Oxaziclomefone), 2-Chlor-1-(3-ethoxy-4-nitro-phenoxy)-4-trifluormethylbenzen (Oxyfluorfen), 1,1'-Dimethyl-4,4'-bipyridinium (Paraquat), 1-Amino- N-(1-ethyl-propyl)-3,4-dimethyl-2,6-dinitro-benzol (Pendimethalin), 4-(t- Butyl)-N-(1-ethyl-propyl)-2,6-dinitro-benzenamin (Pendralin), 3-(4-Chlor-5- cyclopentyloxy-2-fluor-phenyl)-5-(1-methyl-ethyliden)-2,4-oxazolidin-dion (Pentoxazone), 4-Amino-3,5,6-trichlor-pyridin-2-carbonsäure (Picloram), N- (4-Fluor-phenyl)-6-(3-trifluormethyl-phenoxy)-pyridin-2-carboxamid (Picolinafen), S-[2-(2-Methyl-1-piperidinyl)-2-oxo-ethyl]-O,O-dipropyl-phosphorodithioat (Piperophos), 2-Chlor-N-(2,6-diethyl-phenyl)-N-(2-propoxyethyl)-acetamid (Pretilachlor), N-(4,6-Bis-difluormethoxy-pyrimidin-2-yl)- N'-(2-methoxycarbonyl-phenylsulfonyl)-harnstoff (Primisulfuron-methyl), 1- Chlor-N-[2-chlor-4-fluor-5-[(6S,7aR)-6-fluor-tetrahydro-1,3-dioxo-1H- pyrrolo[1,2-c]imidazol-2(3H)-yl]-phenyl]-methansulfonamid (Profluazol), 2- Chlor-N-isopropyl-N-phenyl-acetamid (Propachlor), N-(3,4-Dichlor-phenyl)- propanamid (Propanil), (R)-[2-[[(1-Methyl-ethyliden)-amino]-oxy]-ethyl]-2- [4-(6-chlor-2-chinoxalinyloxy)-phenoxy]-propanoat (Propaquizafop), 2- Chlor-N-(2-ethyl-6-methyl-phenyl)-N-[(1-methyl-ethoxy)-methyl]-acetamid (Propisochlor), 2-[[[(4,5-Dihydro-4-methyl-5-oxo-3-propoxy-1H-1,2,4-triazol-1-yl)-carbonyl]-amino]-sulfonyl]-benzoesäure-methylester-Natriumsalz (Propoxycarbazone-sodium), S-Phenylmethyl-N,N-dipropyl-thiocarbamat (Prosulfocarb), N-(4-Methoxy-6-methyl-1,3,5-triazin-2-yl)-N'-(2-(3,3,3-trifluor-propyl)-phenylsulfonyl)-harnstoff (Prosulfuron), Ethyl-[2-Chlor-5-(4- chlor-5-difluormethoxy-1-methyl-1H-pyrazol-3-yl)-4-fluor-phenoxy]-acetat (Pyraflufen-ethyl), 1-(3-Chlor-4,5,6,7-tetrahydro-pyrazolo[1,5-a]pyridin-2- yl)-5-(methyl-2-propinylamino)-1H-pyrazol-4-carbonitril (Pyraclonil, Pyrazogyl), 4-(2,4-Dichlor-benzoyl)-1,3-dimethyl-5-(4-methyl-phenylsulfonyloxy)- pyrazol (Pyrazolate), 4-(2,4-Dichlor-benzoyl)-1,3-dimethyl-5-(phenylcarbonylmethoxy)-pyrazol (Pyrazoxyfen), N-(4,6-Dimethoxy-pyrimidin-2- yl)-N'-(4-ethoxycarbonyl-1-methyl-pyrazol-5-yl-sulfonyl)-harnstoff (Pyrazosulfuron-ethyl), Diphenylmethanon-O-[2,6-bis-(4,6-dimethoxy-pyrimidin-2- yl-oxy)-benzoyl]-oxim (Pyribenzoxim), O[3-(1,1-Dimethyl-ethyl)-phenyl]-(6- methoxy-2-pyridinyl)-methylthiocarbamat (Pyributicarb), 6-Chlor-3-phenyl- 4-pyridazinol (Pyridafol), O-(6-Chlor-3-phenyl-pyridazin-4-yl)-S-octyl-thiocarbonat (Pyridate), 6-Chlor-3-phenyl-pyridazin-4-ol (Pyridatol), 7-[(4,6-Dimethoxy-2-pyrimidinyl)-thio]-3-methyl-1(3H)-isobenzofuranon (Pyriftalid), 2-(4,6-Dimethoxy-pyrimidin-2-yl-oxy)-benzoesäure-methylester (Pyriminobac-methyl), 2-Chlor-6-(4,6-dimethoxy-pyrimidin-2-ylthio)-benzoesäure- Natriumsalz (Pyrithiobacsodium), 3,7-Dichlor-chinolin-8-carbonsäure (Quinchlorac), 7-Chlor-3-methyl-chinolin-8-carbonsäure (Quinmerac), 2-[4-(6- Chlor-2-chinoxalinyloxy)-phenoxy]-propansäure (-ethylester, -tetrahydro-2- furanyl-methylester) (Quizalofop, -ethyl, -P-ethyl, -P-tefuryl), N-(4,6-Dimethoxy-pyrimidin-2-yl)-N'-(3-ethylsulfonyl-pyridin-2-yl-sulfonyl)-harnstoff (Rimsulfuron), 2-(1-Ethoximinobutyl)-5-(2-ethylthiopropyl)-3-hydroxy-2- cyclohexen-1-on (Sethoxydim), 6-Chlor-2,4-bisethylamino-1,3,5-triazin (Simazin), 2-(2-Chlor-4-methylsulfonyl-benzoyl)-cyclohexan-1,3-dion (Sulcotrione), 2-(2,4-Dichlor-5-methylsulfonylamino-phenyl)-4-difluormethyl-5-methyl-2,4-dihydro-3H-1,2,4-triazol-3-on (Sulfentrazone), Methyl 2-[[[[(4,6-dimethyl-2-pyrimidinyl)-amino]-carbonyl]-amino]-sulfonyl]- benzoate (Sulfometuron-methyl), N-Phosphonomethyl-glycin-trimethylsulfonium (Sulfosate), N-(4,6-Dimethoxy-pyrimidin-2-yl)-N'-(2-ethylsulfonyl-imidazo[1,2-a]pyridin-3-sulfonamid (Sulfosuliron), 6-Chlor-4- ethylamino-2-tertbutylamino-1,3,5-triazin (Terbuthylazine), 2-tert-Butylamino-4-ethylamino-6-methylthio-1,3,5-triazin (Terbutryn), 2-Chlor-N-(2,6- dimethyl-phenyl)-N-(3-methoxy-2-thienyl-methyl)-acetamid (Thenylchlor), 2-Difluormethyl-5-(4,5-dihydro-thiazol-2-yl)-4-(2-methyl-propyl)-6-trifluormethyl-pyridin-3-carbonsäure-methylester (Thiazopyr), 6-(6,7-Dihydro-6,6- dimethyl-3H,5H-pyrrolo[2,1-c]-1,2,4-thiadiazol-3-ylidenamino)-7-fluor-4-(2- propinyl)-2H-1,4-benzoxazin-3(4H)-on (Thidiazimin), N-(4-Methoxy-6- methyl-1,3,5-triazin-2-yl)-N'-(2-methoxycarbonyl-thien-3-yl-sulfonyl)-harnstoff (Thifensulfuron-methyl), 2-(Ethoximino-propyl)-3-hydroxy-5-(2,4,6-trimethyl-phenyl)-2-cyclohexen-1-on (Tralkoxydim), S-(2,3,3-Trichlor-2- propenyl)-diisopropylcarbamothioat (Triallate), N-(4-Methoxy-6-methyl- 1,3,5-triazin-2-yl)-N'-[2-(2-chlor-ethoxy)-phenylsulfonyl]-harnstoff (Triasulf uron), N-Methyl-N-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-N'-(2-methoxycarbonyl-phenylsulfonyl)-harnstoff (Tribenuron-methyl), (3,5,6-Trichlor)- pyridin-2-yl-oxy-essigsäure (Triclopyr), 2-(3,5-Dichlor-phenyl)-2-(2,2,2-trichlor-ethyl)-oxiran (Tridiphane), N-[[(4,6-Dimethoxy-2-pyrimidinyl)-amino]- carbonyl]-3-(2,2,2-trifluor-ethoxy)-2-pyridinsulfonamid-Natriumsalz (Trifloxysulfuron), 1-Amino-2,6-dinitro-N,N-dipropyl-4-trifluormethyl-benzol (Trifluralin), N-[4-Dimethylamino-6-(2,2,2-trifluor-ethoxy)-1,3,5-triazin-2- yl]-N'-(2-methoxycarbonyl-phenylsulfonyl)-harnstoff (Triflusulfuronmethyl), N-(4-Methoxy-6-trifluormethoxy-1,3,5-triazin-2-yl)-N'-(2-trifluormethyl-phenylsulfonyl)-harnstoff (Tritosulfuron), N-[[(4,6-Dimethoxy-2- pyrimidinyl)-amino]-carbonyl]-3-(N-methyl-N-methylsulfonyl-amino])-2- pyridinsulfonamid, (vgl. WO-A-92/10660), 4-[4,5-Dihydro-4-methyl-5-oxo- (3-trifluormethyl)-1H-1,2,4-triazol-1-yl]-2-((ethylsulfonyl)amino]-5-fluorbenzencarbothioamid (vgl. WO-A-95/30661), Phenylcarbothiamid-,4-[4,5- dihydro-4-methyl-5-oxo-3-(trifluormethyl)-1H-1,2,4-triazol-1-yl]-2- ((ethylsulfonyl)amino]-5-fluoro- (CAS-Nummer 173980-17-1, HWH4991) und 2-Chloro-N-[1-[2,6-dichloro-4-(difluoromethyl)phenyl]-4-nitro-1H- pyrazol-5-yl]-propancarbonsäureamid (CAS-Nummer 121750-17-2; SLA5599).
  ("Wirkstoffe der Gruppe 3"),
  sowie gegebenenfalls zusätzlich
• d) zumindest eine die Kulturpflanzen-Verträglichkeit verbessernde Verbindung aus der folgenden Gruppe von Verbindungen:
  α-(1,3-Dioxolan-2-yl-methoximino)-phenylacetonitril (Oxabetrinil), α-(Cyanomethoximino)-phenylacetonitril (Cyometrinil), 4-Chlor-N-(1,3-dioxolan-2- yl-methoxy)-α-trifluor-acetophenonoxim (Fluxofenim), 4,6-Dichlor-2-phenylpyrimidin (Fenclorim), 4-Dichloracetyl-3,4-dihydro-3-methyl-2H-1,4-benzoxazin (Benoxacor), 5-Chlor-chinoxalin-8-oxy-essigsäure-(1-methyl-hexylester) (Cloquintocet), 2,2-Dichlor-N-(2-oxo-2-(2-propenylamino)-ethyl)-N- (2-propenyl)-acetamid (DKA-24), 1,8-Naphthalsäureanhydrid, 1-(2,4-Dichlor-phenyl)-5-trichlormethyl-1H-1,2,4-triazol-3-carbonsäure-ethylester (Fenchlorazol-ethyl), 2-Chlor-4-trifluormethyl-thiazol-5-carbonsäure-phenylmethylester (Flurazole), 3-Dichloracetyl-5-(2-furanyl)-2,2-dimethyl-oxazolidin (Furilazole, MON-13900), 4-Dichloracetyl-1-oxa-4-aza-spiro[4.5]-decan (AD-67), 2-Dichlormethyl-2-methyl-1,3-dioxolan (MG-191), 2,2-Dichlor-N- (1,3-dioxolan-2-yl-methyl)-N-(2-propenyl)-acetamid (PPG-1292), 2,2-Dichlor-N,N-di-2-propenyl-acetamid (Dichlormid), N-(4-Methyl-phenyl)-N'-(1- methyl-1-phenyl-ethyl)-harnstoff (Dymron), 1-Dichloracetyl-hexahydro- 3,3,8atrimethylpyrrolo[1,2-a]-pyrimidin-6(2H)-on (BAS-145138), N-(2- Methoxy-benzoyl)-4-(methylaminocarbonylamino)-benzolsulfonamid, Ethyl- 4,5-dihydro-5,5-diphenyl-3-isoxazolcarboxylat (Isoxadifen-ethyl), (4-Chlor- 2-methylphenoxy)-essigsäure (MCPA), 2-(4-Chlor-2-methylphenoxy)-propionsäure (Mecoprop), Diethyl-1-(2,4-dichlorophenyl)-4,5-dihydro-5-methyl- 1H-pyrazol-3,5-dicarboxylat (Mefenpyr-diethyl) und 2,4-Dichlorophenoxyessigsäure (2,4-D) und dessen Derivate
  ("Wirkstoffe der Gruppe 4").

Surprisingly, it has also been found that the phenoxypyrimidine derivatives, together with other, preferably two further, known herbicidally active compounds when used together, if appropriate with the compounds (safeners / antidots) improving the crop plant tolerance described below, are particularly advantageous as broadly active combination preparations for selective control of weeds in crops such as cereals, such. B. wheat, barley, rye and rice, but can also be used in corn. The invention relates to selective herbicidal compositions, characterized by an effective content of an active ingredient combination comprising

• a) at least one phenoxypyrimidine derivative of the general formula (I)
  
  
  in which
  R is hydrogen, -CH ₂ CH ₂ S (O) _n R ₁ (where R _{1 is} C ₁ -C ₄ alkyl and n is 0, 1 or 2) or
  
  
  stands,
  in which
  R _{2 represents} hydrogen, halogen, cyano, phenyl, C ₁ -C ₈ alkyl, C ₁ -C ₄ alkoxy, C ₁ -C ₄ alkylthio, C ₁ -C ₄ alkoxycarbonyl, mono- or di-C ₁ -C ₄ -alkylaminocarbonyl, phenyl-C ₁ -C ₄ -alkylaminocarbonyl, where the phenyl group may optionally be substituted by halogen, C ₁ -C ₂ -alkyl or C ₁ -C ₂ -alkoxy, furylmethylaminocarbonyl or phenyl, and
  R ₃ for phenyl optionally substituted by halogen, cyano, nitro, C ₁ -C ₄ alkyl, C ₁ -C ₄ alkoxy or allyloxy, for amino optionally substituted by C ₁ -C ₄ alkyl, phenoxy, benzyloxy or acetoxy stands for C ₁ -C ₄ alkylthio or for the grouping -COR ₄ , where R _{4 stands} for C ₁ -C ₄ alkoxy, C ₁ - C ₄ alkyl, benzyloxy or benzylamino,
  A represents chlorine or methoxy and
  Are alkoxy, - D, which may be the same or different, is hydrogen, halogen, C ₁ -C e, ₈ alkyl, C ₁ -C ₈ alkoxy or halogen-substituted C ₁ -C ₈
  and / or a salt of a compound of formula (I)
  ("Active substances of group 1"),
  and
• b) at least one compound from a further group of herbicides which contains the active compounds mentioned below:
  Methyl 2 - [[[(4,5-dihydihydro-4-methyl-5-oxo-3-propoxy-1H-1,2,4-triazol-1-yl) carbonyl] amino] sulfonyl] benzoic acid, sodium Salt (propoxycarbazone sodium) of the formula
  
  
  and
  4,5-dihydro-3-methoxy-4-methyl-5-oxo-N - [[2- (trifluoromethoxy) phenyl] sulfonyl] -1H-1,2,4-triazole-1-carboxamide, sodium salt ( Flucarbazone-sodium) of the formula
  
  
  ("Active substances of group 2"),
  such as
• c) one or more compounds from a further group of herbicides which contains the active compounds mentioned below:
  2-Chloro-N- (ethoxymethyl) -N- (2-ethyl-6-methyl-phenyl) -acetamide (acetochlor), 5- (2-chloro-4-trifluoromethyl-phenoxy) -2-nitro-benzoic acid sodium salt (Acifluorfen-sodium), 2-chloro-6-nitro-3-phenoxybenzenamine (Aclonifen), 2-chloro-N- (methoxymethyl) -N- (2,6-diethyl-phenyl) -acetamide (alachlor), N- Ethyl-N'-i-propyl-6-methylthio-1,3,5-triazine-2,4-diamine (Ametryn), 4-Amino-N- (1,1-dimethyl-ethyl) -4,5- dihydro-3- (1-methyl-ethyl) -5-oxo-1H-1,2,4-triazole-1-carboxamide (amicarbazone), N- (4,6-dimethoxypyrimidin-2-yl) -N '- (N-methyl-N-methylsulfonylsulfamoyl) urea (amidosulfuron), 1H-1,2,4-triazol-3-amine (amitrole), S- [2 - [(4-chlorophenyl) - (1-isopropyl) - amino] -2-oxo-ethyl] -O, O-dimethyl-phosphorodithioate (anilofos), 6-chloro-4-ethylamino-2-isopropylamino-1,3,5-triazine (atrazine), 2- [2,4-dichloro-5- (2-propynyloxy) phenyl] -5,6,7,8-tetrahydro-1,2,4-triazolo- [4,3-a] pyridine-3 ( 2H) - one (azafenidin), N- (4,6-dimethoxypyrimidin-2-yl) -N '- [1-methyl-4- (2-methyl-2H-tetrazol-5-yl) -1H- pyrazol-5-ylsulfonyl] -harnsto ff (azimsulfuron), N-benzyl-2- (4-fluoro-3-trifluoromethyl-phenoxy) -butanamide (beflubutamide), 4-chloro-2-oxo-3 (2H) -benzthiazole acetic acid (benazoline), N-butyl- N-ethyl-2,6-dinitro-4-trifluoromethylbenzamine (benfluralin), 2,3-dihydro-3,3-dimethyl-5-benzofuranylethanesulfonate (benfuresate), N- (4,6-dimethoxypyrimidine-2 - yl) -N '- (2-methoxycarbonylphenylmethylsulfonyl) urea (bensulfuronmethyl), S - [(4-chlorophenyl) methyl] diethylthiocarbamate (benthiocarb, thiobencarb), 2- [2- [4- ( 3,6-Dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1 (2H) -pyrimidinylphenoxymethyl] -5-ethyl-phenoxypropanoic acid methyl ester (benzfendizone), 3- (2-chloro-4- methylsulfonyl-benzoyl) -4-phenylthio-bicyclo- [3.2.1] oct-3-en-2-one (benzobicyclone), 2 - [[4- (2,4-dichloro-3-methylbenzoyl) -1, 3-dimethyl-1H-pyrazol-5-yl] -oxy] -1- (4-methylphenyl) ethanone (benzofenap), ethyl N-benzoyl-N- (3,4-dichlorophenyl) -DL- alaninate (benzoylprop-ethyl), 3-i-propyl-1H-2,1,3-benzothiadiazin-4 (3H) -one (bentazone), methyl-5- (2,4-dichlorophenoxy) -2-nitro - benzoate (bifenox), 5-bromo-6-methyl-3- (1-methyl-propyl) -2.4 (1H, 3H) pyrimidinedione (bromoacil), 2-bromo-3,3-dimethyl-N- (1st -methyl-1-phenyl-ethyl) -butanamide (bromobutide), 3,5-dibromo-4-hydroxy-benzaldehyde-O- (2,4-dinitro-phenyl) -oxime (bromofenoxime), 3,5-dibromo- 4-hydroxy-benzonitrile (bromoxynil), N-butoxymethyl-2-chloro-N- (2,6-diethyl-phenyl) -acetamide (butachlor), 2-chloro-5- (3,6-dihydro-3-methyl -2,6-dioxo-4-trifluoromethyl-1 (2H) -pyrimidinyl) -benzoic acid- [1,1-dimethyl-2-oxo-2- (2-propenyloxy)] - ethyl ester (butafenacil-allyl), 2- (1-ethoximino-propyl) -3-hydroxy-5- [2,4,6-trimethyl-3- (1-oxo-butyl) phenyl] -2-cyclohexen-1-one (butroxydim), S-ethyl bis (2-methyl-propyl) -thiocarbamate (butylate), N, N-diethyl-3- (2,4,6-trimethyl-phenylsulfonyl) -1H-1,2,4-triazole-1-carboxamide ( Cafenstrole), 2- [1 - [(3-chloro-2-propenyl) oxyimino] propyl] -3-hydroxy-5- (tetrahydro-2H-pyran-4-yl) -2-cyclohexen-1 -one (caloxydim, tepraloxydim), 2- (4-chloro-2-fluoro-5- (2-chloro-2-ethoxycarbonyl-ethyl) phenyl) -4-difluoromethyl-5-methyl-2, 4-dihydro-3H-1,2,4-triazol-3-one (carfentrazone-ethyl), 2,4-dichloro-1- (3-methoxy-4-nitro-phenoxy) -benzene (chloromethoxyfen), 3- Amino-2,5-dichlorobenzoic acid (chlorambene), N- (4-chloro-6-methoxy-pyrimidin-2-yl) -N '- (2-ethoxycarbonyl-phenylsulfonyl) urea (chlorimuron-ethyl), 1 , 3,5-trichloro-2- (4-nitro-phenoxy) benzene (chloronitrofen), N- (4-methoxy-6-methyl-1,3,5-triazin-2-yl) -N '- ( 2-chlorophenylsulfonyl) urea (chlorosulfuron), N '- (3-chloro-4-methylphenyl) -N, N-dimethylurea (chlorotoluron), 2-chloro-3- [2-chloro-5 - (1,3,4,5,6,7-hexahydro-1,3-dioxo-2H-isoindol-2-yl) phenyl] -2-propanoic acid ethyl ester (cinidon-ethyl), exo-1-methyl -4-isopropyl-2- (2-methyl-phenyl-methoxy) -7-oxabicyclo- [2.2.1] heptane (cinmethylin), N- (4,6-dimethoxy-1,3,5-triazine-2 -yl) -N '- (2- (2-methoxy-ethoxy) phenylsulfonyl) urea (cinosulfuron), 2- [1- [2- (4-chlorophenoxy) propoxyaminobutyl] -5- (tetrahydro-2H- thiopyran-3-yl) -1,3-cyclohexanedione (clefoxydim), (E, E) - (+) - 2- [1 - [[(3-chloro-2-propenyl) -oxy] -imino] - propyl ] -3-hyd roxy-2-cyclohexen-1-one (clethodim), (R) - (2-propynyl) -2- [4- (5-chloro-3-fluoropyridin-2-yl-oxy) phenoxy propanoate ( Clodinafop-propargyl), 2- (2,4-dichloro-3-methyl-phenoxy) -N-phenyl-propanamide (Clomeprop), 3,6-dichloro-pyridine-2-carboxylic acid (clopyralide), methyl-3-chloro -2 - [(5-ethoxy-7-fluoro [1,2,4] triazolo [1,5-c] pyrimidin-2-yl-sulfonyl) amino] benzoate (chlorosulam-methyl), N - [( 2-chlorophenyl) methyl] -N '- (1-methyl-1-phenyl-ethyl) urea (cumyluron), 2-chloro-4-ethylamino-6- (1-cyano-1-methyl-ethylamino ) -1,3,5-triazine (cyanazines), N- (4,6-dimethoxypyrimidin-2-yl) -N '- (2-cyclopropylcarbonylphenylsulfonyl) urea (cyclosulfamuron), 2- (1- Ethoximinobutyl) -3-hydroxy-5- (tetrahydro-2H-thiopyran-3-yl) -2-cyclohexen- 1-one (cycloxydim), (R) -2- [4- (4-cyano-2-fluoro- phenoxy) -phenoxy] -propanoic acid-butyl ester (cyhalofop-butyl), 2,4-dichloro-phenoxyacetic acid (2,4-D), 3,6-dichloro-2-methoxy-benzoic acid (Dicamba), (R) -2 - (2,4-dichlorophenoxy) propanoic acid (dichloroprop-P), methyl 2- [4- (2,4-dichlorophenox y) -phenoxy] propanoate (diclofop-methyl), N- (2,6-dichlorophenyl) -5-ethoxy-7-fluoro [1,2,4] triazolo- [1,5-c] -pyrimidine-2-sulfonamide (diclosulam), 1,2-dimethyl-3,5-diphenyl-1H-pyrazolium-methylsulfate (difenzoquat), N- (2,4-difluorophenyl) -2- (3-trifluoromethyl-phenoxy) -pyridine-3-carboxamide (diflufenican), 2- [1 - [(3,5-difluoro-phenyl) -amino-carbonyl-hydrazono] -ethyl] -pyridine-3-carboxylic acid (diflufenzopyr), S- (1- Methyl 1-phenyl-ethyl) -1-piperidine-carbothioate (dimepiperate), 2-chloro-N- (2,6-dimethyl-phenyl) -N- (2-methoxyethyl) -acetamide (dimethachlor), N- ( 1,2-dimethyl-propyl) -N'-ethyl-6-methylthio-1,3,5-triazine-2,4-diamine (dimethametryn), (S-) 2-chloro-N- (2,4- dimethyl-3-thienyl) -N- (2-methoxy-1-methyl-ethyl) -acetamide (S-) (dimethenamid), 2-amino-4- (1-fluoro-1-methyl-ethyl) -6- (1-methyl-2- (3,5-dimethyl-phenoxy) ethylamino) -1,3,5-triazine (dimexyflam), N3, N3-diethyl-2,4-dinitro-6-trifluoromethyl-1,3 -diamino-benzene (dinitramine), 6,7-dihydro-dipyrido [1,2- a: 2 ', 1'-c] pyrazinediium (diquat), S, S-dimethyl-2-dif luormethyl-4-i-butyl-6-trifluoromethyl-pyridine-3,5-dicarbothioate (dithiopyr), N '- (3,4-dichlorophenyl) -N, N-dimethyl-urea (diuron), N- (4- Methyl-phenyl) -N '- (1-methyl-1-phenyl-ethyl) -urea (Dymron, Daimuron), 2- [2- (3-chlorophenyl) -oxiranylmethyl] -2-ethyl-1H-inden-1 , 3 (2H) -dione (epropodane), S-ethyl-dipropylthiocarbamate (EPTC), S- (phenylmethyl) -N-ethyl-N- (1,2-dimethyl-propyl) -thiocarbamate (Esprocarb), N-ethyl -N- (2-methyl-2-propenyl) - 2,6-dinitro-4-trifluoromethylbenzamine (ethalfluralin), (S) - (2-ethoxy-1-methyl-2-oxoethyl) -2-chloro 5- (2-chloro-4-trifluoromethylphenoxy) benzoate (ethoxyfen), N- (4,6-dimethoxypyrimidin-2-yl) -N '- (2-ethoxyphenoxysulfonyl) urea (ethoxysulfuron) , N- (2,3-dichlorophenyl) -4-ethoxymethoxybenzamide (etobenzanide), (R) -ethyl-2- [4- (6-chloro-benzoxazol-2-yl-oxy) phenoxy] propanoate ( Fenoxaprop- (P) -ethyl), 4- (2-chlorophenyl) -N-cyclohexyl-N-ethyl-4,5-dihydro-5-oxo-1H-tetrazole-1-carboxamide (fentrazamide), isopropyl- N-benzoyl-N- (3-chloro-4-fluro-phenyl) -DL-alaninate ( Flamprop-isopropyl), isopropyl-N-benzoyl-N- (3-chloro-4-fluro-phenyl) -L-alaninate (Flamprop-isopropyl-L), methyl-N-benzoyl-N- (3-chloro-4 -fluorophenoxy) -DL- alaninate (flamprop-methyl), N- (2,6-difluorophenyl) -8-fluoro-5-methoxy- [1,2,4] -triazolo- [1,5- c] pyrimidine-2-sulfonamide (florasulam), (R) -2- [4- (5-trifluoromethyl-pyridin-2-yl-oxy) phenoxy] propanoic acid butyl ester (fluazifop, butyl, -P- butyl), 5- (4-bromo-1-methyl-5-trifluoromethyl-1H-pyrazol-3-yl) -2-chloro-4-fluoro-benzoic acid i-propyl ester (fluazolates), 4,5-dihydro- 3-methoxy-4-methyl-5-oxo-N - [(2-trifluoromethoxyphenyl) sulfonyl] -1-H-1,2,4-triazole-1-carboxamide sodium salt (Flucarbazone-sodium), N - (4-Fluoro-phenyl) -nipropyl-2- (5-trifluoromethyl-1,3,4-thiadiazol-2-yl-oxy) -acetamide (Flufenacet), N- (2,6-difluorophenyl ) -5-methyl-1,2,4-triazolo [1,5-a] pyrimidine-2-sulfonamide (flumetsulam), pentyl- [2-chloro-4-fluoro-5- (1,3,4, 5,6,7-hexahydro-1,3-dioxo-2H-isoindol-2-yl) phenoxy] acetate (flumiclorac-pentyl), 2- [7-fluoro-3,4-dihydro-3-oxo 4- (2-propynyl) -2H-1,4-benzoxazin-6-yl] -4,5,6,7-tetrahydro-1H-isoindole-1,3-dione (flumioxazin), 2- [4-chloro-2-fluoro-5- [(1-methyl-2-propynyl) -oxy] phenyl] -4,5,6,7-tetrahydro-1H-isoindole-1,3 (2H) -dione (flumipropyn), 3-chloro-4-chloromethyl -1- (3-trifluoromethyl-phenyl) -2-pyrrolidinone (fluorochloridone), 5- (2-chloro-4-trifluoromethyl-phenoxy) -2-nitro-benzoic acid-ethoxycarbonylmethyl ester (fluoroglycofen-ethyl), 1- (4- Chloro-3- (2,2,3,3,3-pentafluoropropoxymethyl) phenyl) -5-phenyl-1H-1,2,4-triazole-3-carboxamide (flupoxam), 1-isopropyl-2- chloro-5- (3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1 (2H) pyrimidyl) benzoate (flupropacil), N- (4,6-dimethoxy pyrimidine-2 -yl) -N '- (3-methoxycarbonyl-6-trifluoromethyl-pyridin-2-yl-sulfonyl) urea sodium salt (flupyrsulfuron-methyl-sodium), 9-hydroxy-9H-fluoren-9-carboxylic acid (flurenol) , (4-Amino-3,5-dichloro-6-fluoropyridin-2-yl-oxy) acetic acid (-2-butoxy-1-methyl-ethyl ester, -1-methylheptyl ester) (fluroxypyr, -butoxypropyl, -meptyl) , 5-methylamino-2-phenyl-4- (3-trifluorme thylphenyl) -3 (2H) -furanone (Flurtamone), methyl - [(2-chloro-4-fluoro-5- (tetrahydro-3-oxo-1H, 3H- [1,3,4] -thiadiazolo- [3,4-a] pyridazin-1-ylidene) amino-phenyl] thioacetate (fluthiacet-methyl), 5- (2-chloro-4-trifluoromethyl-phenoxy) -N-methylsulfonyl-2-nitro-benzamide (Fomesafen), 2- [[[(4,6-dimethoxy-2-pyrimidinyl) amino] carbonyl] amino] sulfonyl] -4-formylamino-N, N-dimethyl-benzamide (foramsulfuron), 2 -Amino-4- (hydroxymethylphosphinyl) -butanoic acid (-ammonium salt) (glufosinate (-ammonium)), N-phosphonomethyl-glycine (-isopropylammmonium salt), (glyphosate, -isopropylammonium), (R) -2- [4- (3rd -Chlor-5-trifluoromethylpyridin-2-yl-oxy) -phenoxy] -propanoic acid (-methyl ester, -2-ethoxy-ethyl ester, -butyl ester) (haloxyfop, -methyl, -P-methyl, -ethoxyethyl, -butyl), 3-Cyclohexyl-6-dimethylamino-1-methyl-1,3,5-triazine-2,4 (1H, 3H) -dione (Hexazinone), methyl-2- (4,5-dihydro-4-methyl-4 -isopropyl-5-oxo-1H-imidazol-2-yl) - 4-methyl-benzoate (imazamethabenz-methyl), 2- (4,5-dihydro-4-methyl-4-isopropyl-5-oxo 1 H -imidazo l-2-yl) -5-methyl-pyridine-3-carboxylic acid (imazamethapyr), 2- (4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl) - 5-methoxymethyl-pyridine-3-carboxylic acid (imazamox), 2- (4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl) -quinoline-3-carboxylic acid (imazaquin ), 2- (4,5-Dihydro-4-methyl-4-i-propyl-5-oxo-1H-imidazol-2-yl) -5-ethylpyridine-3-carboxylic acid (imazethapyr), N- (4, 6-Dimethoxy-pyrimidin-2-yl) -N'- (2-chloro-imidazo [1,2-a] -pyridin-3-yl-sulfonyl) urea (imazosulirone), N- (4-methoxy-6 -methyl-1,3,5-triazin-2-yl) -N '- (5-iodo-2-methoxycarbonylphenylsulfonyl) urea sodium salt (iodosulfuron-methyl-sodium), 4-hydroxy-3,5-diiodo- benzonitrile (ioxynil), N, N-dimethyl-N '- (4-isopropylphenyl) urea (isoproturon), N- (3- (1-ethyl-1-methyl-propyl) -isoxazol-5-yl) -2 , 6-dimethoxy-benzamide (isoxaben), (4-chloro-2-methylsulfonyl-phenyl) - (5-cyclopropyl-isoxazol-4-yl) -methanone (isoxachlorotole), (5-cyclopropylisoxazol-4-yl) - ( 2-methylsulfonyl-4-trifluoromethylphenyl) methanone (isoxaflutole), 2- [2 - [4- [3,5-dichloro-2-pyridinyl) oxy] phenoxy] -1-oxo-propyl] isoxazolidine (isoxapyrifop), (2-ethoxy-1-methyl-2-oxo-ethyl) - 5- (2-chloro-4-trifluoromethyl-phenoxy) -2-nitro-benzoate (lactofen), N '- (3,4-dichlorophenyl) -N-methoxy-N-methyl-urea (Linuron), ( 4-chloro-2-methylphenoxy) acetic acid (MCPA), 2- (4-chloro-2-methylphenoxy) propionic acid (mecoprop), 2- (2-benzothiazolyloxy) -N-methyl-N-phenyl -acetamide (Mefenacet), 2 - [[[[(4,6-dimethoxy-2-pyrimidinyl) amino] carbonyl] amino] sulfonyl] -4 - [[(methylsulfonyl) amino] methyl] benzoic acid -methyl ester (mesosulfuron), 2- (4-methylsulfonyl-2-nitro-benzoyl) -1,3-cyclohexanedione (mesotrione), 4-amino-3-methyl-6-phenyl-1,2,4-triazine-5 (4H) -one (metamitron), 2-chloro-N- (2,6-dimethyl-phenyl) -N- (1 H-pyrazol-1-yl-methyl) -acetamide (metazachlor), N '- (4th - (3,4-Dihydro-2-methoxy-2,4,4-trimethyl-2H-1-benzopyran-7-yl-oxy) - phenyl) -N-methoxy-N-methylurea (metobenzuron), N '- (4-Bromophenyl) -N-methoxy-N-methylurea (metobromuron), (S) -2-chloro-N- (2-ethyl-6-methy l-phenyl) -N- (2-methoxy-1-methyl-ethyl) -acet-amide (metolachlor, S-metolachlor), N- (2,6-dichloro-3-methylphenyl) -5,7- dimethoxy-1,2,4-triazolo [1,5-a] pyrimidine-2-sulfonamide (metosulam), N '- (3-chloro-4-methoxy-phenyl) -N, N-dimethyl-urea (metoxuron ), 4-Amino-6-tertbutyl-3-methylthio-1,2,4-triazin-5 (4H) -one (metribuzin), N- (4-methoxy-6-methyl-1,3,5-triazine -2-yl) -N '- (2-methoxycarbonylphenylsulfonyl) urea (metsulfuron-methyl), S-ethyl-hexahydro-1H-azepine-1-carbothioate (Molinate), 2- (2-naphthyloxy) -N -phenyl-propanamide (naproanilide), N-butyl-N'- (3,4-dichlorophenyl) -N-methyl-urea (neburon), N- (4,6-dimethoxy-pyrimidin-2-yl) - N '- (3-dimethylcarbamoyl-pyridin-2-yl-sulfonyl) urea (nicosulfuron), 4-chloro-5-methylamino-2- (3-trifluoromethyl-phenyl) -3 (2H) pyridazinone (norflurazone), p - (2-Chlorobenzyl) -N, N-diethylthiocarbamate (Orbencarb), 4-dipropylamino-3,5-dinitro-benzenesulfonamide (Oryzalin), 3- [2,4-dichloro-5- (2-propynyloxy ) -phenyl] -5- (t-butyl) -1,3,4-oxadiazol-2 (3H) -one (oxadiargyl), 3 - [2,4-dichloro-5- (1-methylethoxy) phenyl] -5- (t-butyl) -1,3,4-oxadiazol-2 (3H) -one (oxadiazon), N- ( 4,6-Dimethyl-pyrimidin-2-yl) -N '- (2-oxetan-3-yl-oxycarbonyl-phenylsulfonyl) urea (oxasulfuron), 3- [1- (3,5-dichlorophenyl) -1- i-propyl] -2,3-dihydro-6-methyl-5-phenyl-4H-1,3-oxazin-4-one (oxaziclomefone), 2-chloro-1- (3-ethoxy-4-nitro-phenoxy ) -4-trifluoromethylbenzene (oxyfluorfen), 1,1'-dimethyl-4,4'-bipyridinium (paraquat), 1-amino-N- (1-ethyl-propyl) -3,4-dimethyl-2,6- dinitro-benzene (pendimethalin), 4- (t-butyl) -N- (1-ethyl-propyl) -2,6-dinitro-benzenamine (pendralin), 3- (4-chloro-5-cyclopentyloxy-2-fluorine -phenyl) -5- (1-methyl-ethylidene) -2,4-oxazolidinedione (pentoxazone), 4-amino-3,5,6-trichloropyridine-2-carboxylic acid (picloram), N- (4th -Fluorophenyl) -6- (3-trifluoromethylphenoxy) pyridine-2-carboxamide (picolinafen), S- [2- (2-methyl-1-piperidinyl) -2-oxo-ethyl] -O, O -dipropyl-phosphorodithioate (Piperophos), 2-chloro-N- (2,6-diethyl-phenyl) -N- (2-propoxyethyl) -acetamide (pretilachlor), N- (4,6-bis-difluoromethoxy-p yrimidin-2-yl) - N '- (2-methoxycarbonyl-phenylsulfonyl) urea (Primisulfuron-methyl), 1-chloro-N- [2-chloro-4-fluoro-5 - [(6S, 7aR) -6 -fluoro-tetrahydro-1,3-dioxo-1H-pyrrolo [1,2-c] imidazole-2 (3H) -yl] -phenyl] -methanesulfonamide (profluazole), 2-chloro-N-isopropyl-N-phenyl -acetamide (propachlor), N- (3,4-dichlorophenyl) propanamide (propanil), (R) - [2 - [[(1-methylethylidene) amino] oxy] ethyl] -2 - [4- (6-chloro-2-quinoxalinyloxy) phenoxy] propanoate (propaquizafop), 2-chloro-N- (2-ethyl-6-methylphenyl) -N - [(1-methyl-ethoxy) -methyl] -acetamide (propisochlor), 2 - [[[(4,5-dihydro-4-methyl-5-oxo-3-propoxy-1H-1,2,4-triazol-1-yl) carbonyl] -amino] -sulfonyl] -benzoic acid methyl ester sodium salt (propoxycarbazone-sodium), S-phenylmethyl-N, N-dipropyl-thiocarbamate (prosulfocarb), N- (4-methoxy-6-methyl-1,3,5- triazin-2-yl) -N '- (2- (3,3,3-trifluoropropyl) phenylsulfonyl) urea (prosulfuron), ethyl- [2-chloro-5- (4-chloro-5-difluoromethoxy -1-methyl-1H-pyrazol-3-yl) -4-fluoro-phenoxy] acetate (pyraflufen-ethyl), 1- (3-chloro-4,5,6 , 7-tetrahydro-pyrazolo [1,5-a] pyridin-2-yl) -5- (methyl-2-propynylamino) -1H-pyrazole-4-carbonitrile (pyraclonil, pyrazogyl), 4- (2,4- Dichlorobenzoyl) -1,3-dimethyl-5- (4-methylphenylsulfonyloxy) pyrazole (pyrazolates), 4- (2,4-dichlorobenzoyl) -1,3-dimethyl-5- (phenylcarbonylmethoxy) - pyrazole (pyrazoxyfen), N- (4,6-dimethoxy-pyrimidin-2-yl) -N '- (4-ethoxycarbonyl-1-methyl-pyrazol-5-yl-sulfonyl) urea (pyrazosulfuron-ethyl), diphenylmethanone -O- [2,6-bis- (4,6-dimethoxypyrimidin-2-yl-oxy) benzoyl] oxime (pyribenzoxime), O [3- (1,1-dimethylethyl) phenyl] - (6-methoxy-2-pyridinyl) methylthiocarbamate (pyributicarb), 6-chloro-3-phenyl-4-pyridazinol (pyridafol), O- (6-chloro-3-phenyl-pyridazin-4-yl) -S -octyl-thiocarbonate (pyridate), 6-chloro-3-phenyl-pyridazin-4-ol (pyridatol), 7 - [(4,6-dimethoxy-2-pyrimidinyl) thio] -3-methyl-1 (3H ) -Isobenzofuranone (pyriftalid), 2- (4,6-dimethoxy-pyrimidin-2-yl-oxy) -benzoic acid methyl ester (pyriminobac-methyl), 2-chloro-6- (4,6-dimethoxy-pyrimidine-2 -ylthio) -benzoic acid- sodium alz (pyrithiobacsodium), 3,7-dichloro-quinoline-8-carboxylic acid (Quinchlorac), 7-chloro-3-methyl-quinoline-8-carboxylic acid (Quinmerac), 2- [4- (6-chloro-2-quinoxalinyloxy ) -phenoxy] -propanoic acid (-ethyl ester, -tetrahydro-2-furanyl-methyl ester) (quizalofop, -ethyl, -P-ethyl, -P-tefuryl), N- (4,6-dimethoxy-pyrimidin-2-yl ) -N '- (3-ethylsulfonyl-pyridin-2-yl-sulfonyl) urea (rimsulfuron), 2- (1-ethoximinobutyl) -5- (2-ethylthiopropyl) -3-hydroxy-2-cyclohexen-1- on (Sethoxydim), 6-chloro-2,4-bisethylamino-1,3,5-triazine (simazine), 2- (2-chloro-4-methylsulfonyl-benzoyl) -cyclohexane-1,3-dione (Sulcotrione) , 2- (2,4-dichloro-5-methylsulfonylamino-phenyl) -4-difluoromethyl-5-methyl-2,4-dihydro-3H-1,2,4-triazol-3-one (sulfentrazone), methyl 2 - [[[[((4,6-dimethyl-2-pyrimidinyl) amino] carbonyl] amino] sulfonyl] benzoate (sulfometuron methyl), N-phosphonomethyl glycine trimethyl sulfonium (sulfosate), N- ( 4,6-Dimethoxypyrimidin-2-yl) -N '- (2-ethylsulfonylimidazo [1,2-a] pyridine-3-sulfonamide (sulfosulirone), 6-chloro-4-ethylam ino-2-tertbutylamino-1,3,5-triazine (terbuthylazine), 2-tert-butylamino-4-ethylamino-6-methylthio-1,3,5-triazine (terbutryn), 2-chloro-N- (2nd , 6-dimethyl-phenyl) -N- (3-methoxy-2-thienyl-methyl) -acetamide (thenylchlor), 2-difluoromethyl-5- (4,5-dihydro-thiazol-2-yl) -4- ( 2-methyl-propyl) -6-trifluoromethyl-pyridine-3-carboxylic acid methyl ester (thiazopyr), 6- (6,7-dihydro-6,6-dimethyl-3H, 5H-pyrrolo [2,1-c] - 1,2,4-thiadiazol-3-ylidenamino) -7-fluoro-4- (2-propynyl) -2H-1,4-benzoxazin-3 (4H) -one (thidiazimin), N- (4-methoxy- 6-methyl-1,3,5-triazin-2-yl) -N '- (2-methoxycarbonylthien-3-yl-sulfonyl) urea (thifensulfuron-methyl), 2- (ethoximino-propyl) -3 -hydroxy-5- (2,4,6-trimethyl-phenyl) -2-cyclohexen-1-one (tralkoxydim), S- (2,3,3-trichloro-2-propenyl) -diisopropylcarbamothioate (triallate), N - (4-methoxy-6-methyl-1,3,5-triazin-2-yl) -N '- [2- (2-chloroethoxy) phenylsulfonyl] urea (triasulfuron), N-methyl- N- (4-methoxy-6-methyl-1,3,5-triazin-2-yl) -N '- (2-methoxycarbonyl-phenylsulfonyl) urea (tribenuron-methyl), (3,5,6-trichloro) pyridin-2-yloxy acetic acid (triclopyr), 2- (3,5-dichloro-phenyl) -2- (2,2,2-trichloroethyl) oxirane (Tridiphane), N - [[(4,6-dimethoxy-2-pyrimidinyl) amino] carbonyl] -3- (2,2,2-trifluoroethoxy) -2-pyridinesulfonamide sodium salt (trifloxysulfuron), 1 -Amino-2,6-dinitro-N, N-dipropyl-4-trifluoromethyl-benzene (trifluralin), N- [4-dimethylamino-6- (2,2,2-trifluoro-ethoxy) -1,3,5 -triazin-2-yl] -N '- (2-methoxycarbonyl-phenylsulfonyl) urea (triflusulfuronmethyl), N- (4-methoxy-6-trifluoromethoxy-1,3,5-triazin-2-yl) -N' - (2-trifluoromethylphenylsulfonyl) urea (tritosulfuron), N - [[(4,6-dimethoxy-2-pyrimidinyl) amino] carbonyl] -3- (N-methyl-N-methylsulfonylamino]) -2- pyridine sulfonamide, (cf. WO-A-92/10660), 4- [4,5-dihydro-4-methyl-5-oxo (3-trifluoromethyl) -1H-1,2,4-triazol-1-yl] -2- ( (ethylsulfonyl) amino] -5-fluorobenzenecarbothioamide (see WO-A-95/30661), phenylcarbothiamide-, 4- [4,5-dihydro-4-methyl-5-oxo-3- (trifluoromethyl) -1H-1 , 2,4-triazol-1-yl] -2- ((ethylsulfonyl) amino] -5-fluoro- (CAS number 173980-17-1, HWH4991) and 2-chloro-N- [1- [2, 6-dichloro-4- (difluoromethyl) phenyl] -4-nitro-1H-pyrazol-5-yl] propanecarboxamide (CAS number 121750-17-2; SLA5599).
  ("Active substances of group 3"),
  as well as, if necessary, additionally
• d) at least one compound which improves the tolerance of crop plants from the following group of compounds:
  α- (1,3-Dioxolan-2-yl-methoximino) phenylacetonitrile (oxabetrinil), α- (cyanomethoximino) phenylacetonitrile (cyometrinil), 4-chloro-N- (1,3-dioxolan-2-yl-methoxy ) -α-trifluoro-acetophenone oxime (fluxofenim), 4,6-dichloro-2-phenylpyrimidine (Fenclorim), 4-dichloroacetyl-3,4-dihydro-3-methyl-2H-1,4-benzoxazine (Benoxacor), 5 Chloro-quinoxaline-8-oxyacetic acid (1-methyl-hexyl ester) (Cloquintocet), 2,2-dichloro-N- (2-oxo-2- (2-propenylamino) ethyl) -N- (2 -propenyl) -acetamide (DKA-24), 1,8-naphthalic anhydride, 1- (2,4-dichlorophenyl) -5-trichloromethyl-1H-1,2,4-triazole-3-carboxylic acid ethyl ester (fenchlorazole -ethyl), 2-chloro-4-trifluoromethyl-thiazole-5-carboxylic acid phenylmethyl ester (flurazole), 3-dichloroacetyl-5- (2-furanyl) -2,2-dimethyl-oxazolidine (furilazole, MON-13900), 4-dichloroacetyl-1-oxa-4-aza-spiro [4.5] decane (AD-67), 2-dichloromethyl-2-methyl-1,3-dioxolane (MG-191), 2,2-dichloro-N - (1,3-dioxolan-2-yl-methyl) -N- (2-propenyl) -acetamide (PPG-1292), 2,2-dichloro-N, N-di-2-propenyl-acetamide (dichlormid) , N- ( 4-methyl-phenyl) -N '- (1-methyl-1-phenyl-ethyl) -urea (Dymron), 1-dichloroacetyl-hexahydro-3,3,8atrimethylpyrrolo [1,2-a] pyrimidine-6 ( 2H) -one (BAS-145138), N- (2-methoxy-benzoyl) -4- (methylaminocarbonylamino) benzenesulfonamide, ethyl 4,5-dihydro-5,5-diphenyl-3-isoxazolecarboxylate (isoxadifen-ethyl) , (4-Chloro-2-methylphenoxy) acetic acid (MCPA), 2- (4-chloro-2-methylphenoxy) propionic acid (Mecoprop), diethyl-1- (2,4-dichlorophenyl) -4,5-dihydro -5-methyl-1H-pyrazole-3,5-dicarboxylate (mefenpyr-diethyl) and 2,4-dichlorophenoxyacetic acid (2,4-D) and its derivatives
  ("Active substances of group 4").

Preferred substituents of the radicals shown in the formula (I) shown above are explained below.
R preferably represents hydrogen or


in which
R _{2 is} preferably hydrogen, chlorine, cyano, phenyl, C ₁ -C ₈ alkyl, methoxy, methylthio, C ₁ -C ₂ alkoxycarbonyl, propylaminocarbonyl, dimethylaminocarbonyl, benzylaminocarbonyl (the benzyl group being optionally substituted by chloro, methyl or methoxy ), 2'-phenylethylaminocarbonyl or furylmethylaminocarbonyl, and
R ₃ preferably represents phenyl optionally substituted by chlorine, fluorine, cyano, nitro, methyl, methoxy, ethoxy, butoxy, allyloxy, methylthio, dimethylamino, phenoxy, benzyloxy or acetoxy or -COR ₄ , where R _{4 represents} methoxy, ethoxy, Is methyl, benzyloxy or benzylamino,
A preferably represents chlorine or methoxy and
D and E, which may be the same or different, are preferably hydrogen, methoxy or ethoxy.
R ₂ particularly preferably represents hydrogen, methyl, methylthio, cyano, methoxycarbonyl or phenyl.
R ₃ particularly preferably represents phenyl optionally substituted by methyl or methoxy.
A particularly preferably represents methoxy.
D and E are particularly preferably methoxy.
R ₂ very particularly preferably represents phenyl.
R ₃ very particularly preferably represents phenyl.

Preferred mixture components from the active ingredients in group 3 are one or more compounds from a group of herbicides which contain the active ingredients mentioned below:
4-amino-N- (1,1-dimethyl-ethyl) -4,5-dihydro-3- (1-methyl-ethyl) -5-oxo-1H-1,2,4-triazole-1-carboxamide ( Amicarbazones), N- (4,6-dimethoxy-pyrimidin-2-yl) -N '- (N-methyl-N-methylsulfonylsulfamoyl) urea (amidosulfuron), N-benzyl-2- (4-fluoro- 3-trifluoromethyl-phenoxy) butanamide (beflubutamide), 3-i-propyl-1H-2,1,3-benzothiadiazin-4 (3H) -one (bentazone), methyl-5- (2,4-dichlorophenoxy) ) -2-nitrobenzoate (bifenox), 3,5-dibromo-4-hydroxy-benzonitrile (bromoxynil), 2- (4-chloro-2-fluoro-5- (2-chloro-2-ethoxycarbonyl-ethyl) -phenyl ) -4-difluoromethyl-5-methyl-2,4-dihydro-3H-1,2,4-triazol-3-one (carfentrazone-ethyl), N- (4-methoxy-6-methyl-1,3, 5- triazin-2-yl) -N '- (2-chlorophenylsulfonyl) urea (chlorosulfuron), N' - (3-chloro-4-methylphenyl) -N, N-dimethylurea (chlorotoluron) , 2-chloro-3- [2-chloro-5- (1,3,4,5,6,7-hexahydro-1,3-dioxo-2H-isoindol-2-yl) phenyl] -2-propanoic acid ethyl ester (cinidon-ethyl), (R) - (2-propynyl) -2- [4- (5-chloro-3-fluoropyridin-2-yl-oxy) phenoxy propanoate (clodinafop propargyl), 3,6-dichloro-py ridin-2-carboxylic acid (clopyralide), 2,4-dichlorophenoxyacetic acid (2,4-D), 3,6-dichloro-2-methoxybenzoic acid (Dicamba), (R) -2- (2,4- Dichlorophenoxy) propanoic acid (dichloroprop-P), methyl 2- [4- (2,4-dichlorophenoxy) phenoxy] propanoate (diclofop-methyl), 1,2-dimethyl-3,5-diphenyl -1H-pyrazolium methyl sulfate (difenzoquat), N- (2,4-difluorophenyl) -2- (3-trifluoromethylphenoxy) pyridine-3-carboxamide (diflufenican), N- (4,6-dimethoxypyrimidine) 2-yl) -N '- (2-ethoxyphenoxysulfonyl) urea (ethoxysuliron), (R) - ethyl 2- [4- (6-chloro-benzoxazol-2-yl-oxy) phenoxy] propanoate (Fenoxaprop- (P) - ethyl), 4- (2-chlorophenyl) -N-cyclohexyl-N-ethyl-4,5-dihydro-5-oxo-1H-tetrazole-1-carboxamide (fentrazamide), isopropyl -N-benzoyl-N- (3-chloro-4-fluro-phenyl) -DL- alaninate (Flamprop-isopropyl), isopropyl-N-benzoyl-N- (3-chloro-4-fluro-phenyl) -L- alaninate (flamprop-isopropyl-L), methyl-N-benzoyl-N- (3-chloro-4-fluorophenoxy) - DL-alaninate (flamprop-methyl), N- (2,6-difluorophenyl) - 8-fluoro-5-methoxy- [1,2,4] triazolo- [1,5-c] pyr imidin-2-sulfonamide (florasulam), 5- (4-bromo-1-methyl-5-trifluoromethyl-1H-pyrazol-3-yl) -2-chloro-4-fluoro-benzoic acid i-propyl ester (fluazolates), 4,5-Dihydro-3-methoxy-4-methyl-5-oxo-N - [(2-trifluoromethoxyphenyl) sulfonyl] -1- H-1,2,4-triazole-1-carboxamide sodium salt ( Flucarbazone-sodium), N- (4-fluorophenyl) -Ni-propyl-2- (5-trifluoromethyl-1,3,4-thiadiazol-2-yl-oxy) -acetamide (Flufenacet), 5- (2-chlorine -4-trifluoromethyl-phenoxy) -2-nitro-benzoic acid ethoxycarbonylmethyl ester (fluoroglycofen-ethyl), N- (4,6-dimethoxy-pyrimidin-2-yl) -N '- (3-methoxycarbonyl-6-trifluoromethyl-pyridine -2-yl-sulfonyl) urea sodium salt (flupyrsulfuron-methyl-sodium), (4-amino-3,5-dichloro-6-fluoropyridin-2-yl-oxy) acetic acid (-2-butoxy- 1-methyl-ethyl ester, -1-methyl-heptyl ester) (fluroxypyr, -butoxypropyl, -meptyl), 5-methylamino-2-phenyl-4- (3-trifluoromethyl-phenyl) -3 (2H) -furanone (flurtamone) , 2-Amino-4- (hydroxymethylphosphinyl) butanoic acid (ammonium salt) (glufosinate (ammonium)), N-phosphonomethylglycine (isopro pylammmonium salt), (glyphosate, isopropylammonium), methyl 2- (4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl) -4-methyl-benzoate (imazamethabenz- methyl), 2- (4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl) -5-methyl-pyridine-3-carboxylic acid (imazamethapyr), 2- (4th , 5-Dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl) -5-methoxymethyl-pyridine-3-carboxylic acid (imazamox), 2- (4,5-dihydro-4- methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl) -quinoline-3-carboxylic acid (imazaquin), 2- (4,5-dihydro-4-methyl-4-i-propyl-5-oxo -1H-imidazol-2-yl) -5-ethyl-pyridine-3-carboxylic acid (imazethapyr), N- (4-methoxy-6-methyl-1,3,5-triazin-2-yl) -N'- (5-iodo-2-methoxycarbonyl-phenylsulfonyl) urea sodium salt (iodosulfuron-methyl-sodium), 4-hydroxy-3,5-diiodobenzonitrile (ioxynil), N, N-dimethyl-N '- (4- isopropyl-phenyl) -urea (isoproturon), N- (3- (1-ethyl-1-methyl-propyl) -isoxazol-5-yl) -2,6-dimethoxy-benzamide (isoxaben), (4-chloro- 2-methylsulfonylphenyl) - (5-cyclopropylisoxazol-4-yl) methanone (isoxachlorotole ), (5-Cyclopropyl-isoxazol-4-yl) - (2-methylsulfonyl-4-trifluoromethyl-phenyl) -methanone (isoxaflutole), (4-chloro-2-methyl-phenoxy) -acetic acid (MCPA), 2- (4-chloro-2-methylphenoxy) propionic acid (mecoprop), 2- (2-benzothiazolyloxy) -N-methyl-N-phenyl-acetamide (mefenacet), 2 - [[[[(4,6-dimethoxy -2-pyrimidinyl) amino] carbonyl] amino] sulfonyl] -4 - [[(methylsulfonyl) amino] methyl] benzoic acid methyl ester (mesosulfuron), 4-amino-3-methyl-6-phenyl- 1,2,4-triazin-5 (4H) -one (metamitron), N- (2,6-dichloro-3-methylphenyl) -5,7-dimethoxy-1,2,4-triazolo [1, 5-a] pyrimidine-2-sulfonamide (metosulam), 4-amino-6-tert-butyl-3-methylthio-1,2,4-triazin-5 (4H) -one (metribuzin), N- (4th -Methoxy-6-methyl-1,3,5-triazin-2-yl) -N '- (2-methoxycarbonyl-phenylsulfonyl) urea (metsulfuron-methyl), 1-amino-N- (1-ethyl-propyl ) -3,4-dimethyl-2,6-dinitro-benzene (pendimethalin), N- (4-fluoro-phenyl) -6- (3-trifluoromethyl-phenoxy) -pyridine-2-carboxamide (picolinafen), N- (3,4-dichlorophenyl) propanamide (propanil), ethyl (2-chloro-5- (4-chloro 5-difluoromethoxy-1-methyl-1H-pyrazol-3-yl) -4-fluorophenoxy] acetate (pyraflufen-ethyl), 2- (2-chloro-4-methylsulfonyl-benzoyl) -cyclohexane-1,3 -dione (Sulcotrione), N-phosphonomethyl-glycine-trimethylsulfonium (sulfosate), N- (4,6-dimethoxypyrimidin-2-yl) -N '- (2-ethylsulfonyl-imidazo [1,2-a] pyridine -3-sulfonamide (sulfosulirone), N- (4-methoxy-6-methyl-1,3,5-triazin-2-yl) -N '- (2-methoxycarbonylthien-3-yl sulfonyl) urea (Thifensulfuron-methyl), 2- (ethoximino-propyl) -3-hydroxy-5- (2,4,6-trimethyl-phenyl) -2-cyclohexen-1-one (tralkoxydim), S- (2,3, 3-trichloro-2-propenyl) diisopropyl carbamothioate (triallate), N- (4-methoxy-6-methyl-1,3,5-triazin-2-yl) -N '- [2- (2-chloro-ethoxy ) -phenylsulfonyl] urea (triasulfuron), N-methyl-N- (4-methoxy-6-methyl-1,3,5-triazin-2-yl) -N '- (2-methoxycarbonyl-phenylsulfonyl) urea (Tribenuron-methyl), 1-amino-2,6-dinitro-N, N-dipropyl-4-trifluoromethyl-benzene (trifluralin), N- (4-methoxy-6-trifluoromethoxy-1,3,5-triazine 2-yl) -N '- (2-trifluoromethyl-phenylsulfonyl) urea ff (tritosulfuron), phenylcarbothiamide-, 4- [4,5-dihydro-4-methyl-5-oxo-3- (trifluoromethyl) -1H-1,2,4-triazol-1-yl] -2- [( ethylsulfonyl) amino] -5-fluoro- (CAS number 173980-17-1, HWH4991) and (2-chloro-N- [1- [2,6-dichloro-4- (difluoromethyl) phenyl] -4-nitro -1H-pyrazol-5-yl] - propanecarboxamide (CAS number 121750-17-2; SLA5599).

• a) Sulfonylharnstoffe:
  N-(4,6-Dimethoxy-pyrimidin-2-yl)-N'-(N-methyl-N-methylsulfonyl-sulfamoyl)-harnstoff (Amidosulfuron), N-(4-Methoxy-6-methyl-1,3,5-triazin-2-yl)- N'-(2-chlor-phenylsulfonyl)-harnstoff (Chlorsulfuron), N-(4,6-Dimethoxypyrimidin-2-yl)-N'-(3-methoxycarbonyl-6-trifluormethyl-pyridin-2-yl-sulfonyl)-harnstoff-Natriumsalz (Flupyrsulfuron-methyl-sodium), N-(4-Methoxy-6-methyl-1,3,5-triazin-2-yl)-N'-(5-iod-2-methoxycarbonyl-phenylsulfonyl)-harnstoff-Natriumsalz (Iodosulfuron-methyl-sodium), 2-[[[[(4,6-Dimethoxy-2-pyrimidinyl)-amino]-carbonyl]-amino]-sulfonyl]-4-[[(methylsulfonyl)-amino]methyl]-benzoesäure-methylester (Mesosulfuron), N-(4- Methoxy-6-methyl-1,3,5-triazin-2-yl)-N'-(2-methoxycarbonyl-phenylsulfonyl)-harnstoff (Metsulfuron-methyl), N-(4,6-Dimethoxy-pyrimidin-2-yl)- N'-(2-ethylsulfonyl-imidazo[1,2-a]pyridin-3-sulfonamid (Sulfosulfuron), N- (4-Methoxy-6-methyl-1,3,5-triazin-2-yl)-N'-(2-methoxycarbonyl-thien-3-ylsulfonyl)-harnstoff (Thifensulfuron-methyl), N-(4-Methoxy-6-methyl-1,3,5- triazin-2-yl)-N'-[2-(2-chlor-ethoxy)-phenylsulfonyl]-harnstoff (Triasulfuron), N-Methyl-N-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-N'-(2-methoxy- carbonyl-phenylsulfonyl)-harnstoff (Tribenuron-methyl), N-(4-Methoxy-6-trifluormethoxy-1,3,5-triazin-2-yl)-N'-(2-trifluormethyl-phenylsulfonyl)-harnstoff (Tritosulfuron),
• b) Triazolopyrimidine:
  N-(2,6-Difluor-phenyl)-8-fluor-5-methoxy-[1,2,4]-triazolo-[1,5-c]-pyrimidin- 2-sulfonamid (Florasulam), N-(2,6-Dichlor-3-methyl-phenyl)-5,7-dimethoxy- 1,2,4-triazolo[1,5-a]-pyrimidin-2-sulfonamid (Metosulam),
• c) Imidazolinone:
  Methyl-2-(4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1 H-imidazol-2-yl)-4- methyl-benzoat (Imazamethabenz-methyl), 2-(4,5-Dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl)-5-methyl-pyridin-3-carbonsäure (Imazamethapyr), 2-(4,5-Dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl)-5-methoxymethyl-pyridin-3-carbonsäure (Imazamox), 2-(4,5-Dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl)-chinolin-3-carbonsäure (Imazaquin), 2-(4,5- Dihydro-4-methyl-4-i-propyl-5-oxo-1H-imidazol-2-yl)-5-ethyl-pyridin-3- carbonsäure (Imazethapyr),
• d) Harnstoffe:
  N'-(3-Chlor-4-methyl-phenyl)-N,N-dimethyl-harnstoff (Chlortoluron), N,N- Dimethyl-N'-(4-isopropyl-phenyl)-harnstoff (Isoproturon),
• e) Triazindione:
  4-Amino-6-tert-butyl-3-methylthio-1,2,4-triazin-5(4H)-on (Metribuzin),
• f) Triketone:
  2-(2-Chlor-4-methylsulfonyl-benzoyl)-cyclohexan-1,3-dion (Sulcotrione),
• g) Triazolinone:
  2-(4-Chlor-2-fluor-5-(2-chlor-2-ethoxycarbonyl-ethyl)-phenyl)-4-difluormethyl-5-methyl-2,4-dihydro-3H-1,2,4-triazol-3-on (Carfentrazone-ethyl), Phenylcarbothiamid-,4-[4,5-dihydro-4-methyl-5-oxo-3-(trifluormethyl)-1H- 1,2,4-triazol-1-yl]-2-[(ethylsulfonyl)amino]-5-fluoro-(CAS-Nummer 173980-17-1, HWH4991),
• h) Benzonitrile:
  3,5-Dibrom-4-hydroxy-benzonitril (Bromoxynil), 4-Hydroxy-3,5-diiodbenzonitril (Ioxynil),
• i) Phenoxypropionsäurederivate:
  (R)-(2-Propinyl)-2-[4-(5-chlor-3-fluor-pyridin-2-yl-oxy)-phenoxy-propanoat (Clodinafop-propargyl), Methyl-2-[4-(2,4-dichlor-phenoxy)-phenoxy]-propanoat (Diclofop-methyl), (R)-Ethyl-2-[4-(6-chlor-benzoxazol-2-yl-oxy)-phenoxy]-propanoat (Fenoxaprop-(P)-ethyl),
• j) Dichlorphenoxysäurederivate:
  2,4-Dichlor-phenoxyessigsäure (2,4-D), (R)-2-(2,4-Dichlor-phenoxy)-propansäure (Dichlorprop-P), (4-Chlor-2-methyl-phenoxy)-essigsäure (MCPA), 2- (4-Chlor-2-methyl-phenoxy)-propionsäure (Mecoprop),
• k) Carboxamide:
  N-(2,4-Difluor-phenyl)-2-(3-trifluormethyl-phenoxy)-pyridin-3-carboxamid (Diflufenican), N-(4-Fluor-phenyl)-6-(3-trifluormethyl-phenoxy)-pyridin-2- carboxamid (Picolinafen),
• l) Oxyacetamide:
  N-(4-Fluor-phenyl)-N-i-propyl-2-(5-trifluormethyl-1,3,4-thiadiazol-2-yl- oxy)-acetamid (Flufenacet),
  (2-Chloro-N-[1-[2,6-dichl oro-4-(difluoromethyl)phenyl]-4-nitro-1H-pyrazol-5-yl]- propancarbonsäureamid (CAS-Nummer 121750-12-2; SLA5599),
  Methyl-5-(2,4-dichlor-phenoxy)-2-nitro-benzoat (Bifenox),
  2-Chlor-3-[2-chlor-5-(1,3,4,5,6,7-hexahydro-1,3-dioxo-2H-isoindol-2-yl)-phenyl]-2- propansäure-ethylester (Cinidon-ethyl),
  (4-Amino-3,5-dichlor-6-fluor-pyridin-2-yl-oxy)-essigsäure (-2-butoxy-1-methylethylester, -1-methyl-heptylester) (Fluroxypyr, -butoxypropyl, -meptyl),
  2-Amino-4-(hydroxymethylphosphinyl)-butansäure (-ammoniumsalz) (Glufosinate (-ammonium)),
  N-Phosphonomethyl-glycin (-isopropylammmoniumsalz), (Glyphosate, -isopropylammonium),
  N-Phosphonomethyl-glycin-trimethylsulfonium (Sulfosate).

Herbicides from the class of sulfonylureas, triazolopyrimidines, imidazolinones, ureas, triazinediones, triketones, triazolinones, benzonitriles, phenoxypropionic acid derivatives, dichlorophenoxyacid derivatives, carboxamides, oxyacetamides, and other herbicidal active compounds are listed as particular herbicides and other herbicidal active ingredients as well as further herbicidal active compounds become:

• a) Sulfonylureas:
  N- (4,6-Dimethoxy-pyrimidin-2-yl) -N '- (N-methyl-N-methylsulfonylsulfamoyl) urea (amidosulfuron), N- (4-methoxy-6-methyl-1,3 , 5-triazin-2-yl) - N '- (2-chlorophenylsulfonyl) urea (chlorosulfuron), N- (4,6-dimethoxypyrimidin-2-yl) -N' - (3-methoxycarbonyl-6- trifluoromethyl-pyridin-2-yl-sulfonyl) urea sodium salt (flupyrsulfuron-methyl-sodium), N- (4-methoxy-6-methyl-1,3,5-triazin-2-yl) -N '- ( 5-iodo-2-methoxycarbonyl-phenylsulfonyl) urea sodium salt (iodosulfuron-methyl-sodium), 2 - [[[[(4,6-dimethoxy-2-pyrimidinyl) amino] carbonyl] amino] sulfonyl ] -4 - [[(methylsulfonyl) amino] methyl] benzoic acid methyl ester (mesosulfuron), N- (4-methoxy-6-methyl-1,3,5-triazin-2-yl) -N '- ( 2-methoxycarbonyl-phenylsulfonyl) urea (metsulfuron-methyl), N- (4,6-dimethoxypyrimidin-2-yl) - N '- (2-ethylsulfonyl-imidazo [1,2-a] pyridine-3- sulfonamide (sulfosulfuron), N- (4-methoxy-6-methyl-1,3,5-triazin-2-yl) -N '- (2-methoxycarbonylthien-3-ylsulfonyl) urea (thifensulfuron-methyl) , N- (4-methoxy-6-methyl-1,3,5- t riazin-2-yl) -N '- [2- (2-chloroethoxy) phenylsulfonyl] urea (triasulfuron), N-methyl-N- (4-methoxy-6-methyl-1,3,5- triazin-2-yl) -N '- (2-methoxycarbonylphenylsulfonyl) urea (tribenuron-methyl), N- (4-methoxy-6-trifluoromethoxy-1,3,5-triazin-2-yl) -N '- (2-trifluoromethyl-phenylsulfonyl) urea (tritosulfuron),
• b) Triazolopyrimidines:
  N- (2,6-difluorophenyl) -8-fluoro-5-methoxy- [1,2,4] triazolo- [1,5-c] pyrimidine- 2-sulfonamide (florasulam), N- ( 2,6-dichloro-3-methylphenyl) -5,7-dimethoxy-1,2,4-triazolo [1,5-a] pyrimidine-2-sulfonamide (metosulam),
• c) Imidazolinones:
  Methyl 2- (4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1 H -imidazol-2-yl) -4-methyl-benzoate (imazamethabenz-methyl), 2- (4.5 Dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl) -5-methyl-pyridine-3-carboxylic acid (imazamethapyr), 2- (4,5-dihydro-4-methyl- 4-isopropyl-5-oxo-1H-imidazol-2-yl) -5-methoxymethyl-pyridine-3-carboxylic acid (imazamox), 2- (4,5-dihydro-4-methyl-4-isopropyl-5-oxo -1H-imidazol-2-yl) -quinolin-3-carboxylic acid (imazaquin), 2- (4,5-dihydro-4-methyl-4-i-propyl-5-oxo-1H-imidazol-2-yl) -5-ethyl-pyridine-3-carboxylic acid (imazethapyr),
• d) ureas:
  N '- (3-chloro-4-methyl-phenyl) -N, N-dimethyl-urea (chlorotoluron), N, N-dimethyl-N' - (4-isopropyl-phenyl) -urea (isoproturon),
• e) Triazinediones:
  4-amino-6-tert-butyl-3-methylthio-1,2,4-triazin-5 (4H) -one (metribuzin),
• f) Triketones:
  2- (2-chloro-4-methylsulfonyl-benzoyl) cyclohexane-1,3-dione (sulcotrione),
• g) triazolinones:
  2- (4-chloro-2-fluoro-5- (2-chloro-2-ethoxycarbonyl-ethyl) -phenyl) -4-difluoromethyl-5-methyl-2,4-dihydro-3H-1,2,4- triazol-3-one (carfentrazone-ethyl), phenylcarbothiamid-, 4- [4,5-dihydro-4-methyl-5-oxo-3- (trifluoromethyl) -1H-1,2,4-triazol-1-yl ] -2 - [(ethylsulfonyl) amino] -5-fluoro- (CAS number 173980-17-1, HWH4991),
• h) Benzonitrile:
  3,5-dibromo-4-hydroxy-benzonitrile (bromoxynil), 4-hydroxy-3,5-diiodobenzonitrile (ioxynil),
• i) Phenoxypropionic acid derivatives:
  (R) - (2-propynyl) -2- [4- (5-chloro-3-fluoropyridin-2-yl-oxy) phenoxypropanoate (clodinafop-propargyl), methyl 2- [4- ( 2,4-dichlorophenoxy) phenoxy] propanoate (diclofop-methyl), (R) -ethyl-2- [4- (6-chloro-benzoxazol-2-yl-oxy) phenoxy] propanoate (fenoxaprop - (P) -ethyl),
• j) dichlorophenoxyacid derivatives:
  2,4-dichlorophenoxyacetic acid (2,4-D), (R) -2- (2,4-dichlorophenoxy) propanoic acid (dichloroprop-P), (4-chloro-2-methylphenoxy) - acetic acid (MCPA), 2- (4-chloro-2-methylphenoxy) propionic acid (mecoprop),
• k) carboxamides:
  N- (2,4-difluorophenyl) -2- (3-trifluoromethylphenoxy) pyridine-3-carboxamide (diflufenican), N- (4-fluorophenyl) -6- (3-trifluoromethylphenoxy) -pyridine-2-carboxamide (picolinafen),
• l) oxyacetamides:
  N- (4-fluoro-phenyl) -Ni-propyl-2- (5-trifluoromethyl-1,3,4-thiadiazol-2-yl-oxy) -acetamide (flufenacet),
  (2-Chloro-N- [1- [2,6-dichloro-4- (difluoromethyl) phenyl] -4-nitro-1H-pyrazol-5-yl] propane carboxamide (CAS number 121750-12-2; SLA5599),
  Methyl 5- (2,4-dichlorophenoxy) -2-nitro-benzoate (bifenox),
  2-chloro-3- [2-chloro-5- (1,3,4,5,6,7-hexahydro-1,3-dioxo-2H-isoindol-2-yl) phenyl] -2-propanoic acid - ethyl ester (cinidon-ethyl),
  (4-Amino-3,5-dichloro-6-fluoropyridin-2-yl-oxy) acetic acid (-2-butoxy-1-methylethyl ester, -1-methyl-heptyl ester) (fluroxypyr, butoxypropyl, meptyl )
  2-amino-4- (hydroxymethylphosphinyl) butanoic acid (ammonium salt) (glufosinate (ammonium)),
  N-phosphonomethyl-glycine (-isopropylammmonium salt), (glyphosate, -isopropylammonium),
  N-phosphonomethyl-glycine trimethyl sulfonium (sulfosate).

The following are particularly emphasized as components of the group 4 active ingredients:
5-chloro-quinoxaline-8-oxyacetic acid (1-methylhexyl ester) (cloquintocet), 1- (2,4-dichlorophenyl) -5-trichloromethyl-1H-1,2,4-triazole-3-carboxylic acid ethyl ester (fenchlorazole-ethyl), ethyl 4,5-dihydro-5,5-diphenyl-3-isoxazolecarboxylate (isoxadifen-ethyl), (4-chloro-2-methylphenoxy) acetic acid (MCPA), 2- (4th - Chloro-2-methylphenoxy) propionic acid (mecoprop), diethyl 1- (2,4-dichlorophenyl) -4,5-dihydro-5-methyl-1H-pyrazole-3,5-dicarboxylate (mefenpyr-diethyl) and 2,4-dichlorophenoxyacetic acid (2,4-D) and its derivatives.

• a) mindestens ein Phenoxypyrimidin-Derivat aus der folgenden Gruppe von Verbindungen:
  2,6-Bis[(4,6-dimethoxy-2-pyrimidinyl)oxy]-benzoat (Natrium), (Bispyribacsodium, KIH 2023) der Formel
  
  
  oder
  Diphenyl-methanon-O-[2,6-bis[(4,6-dimethoxy-2-pyrimidinyl)oxy]benzoyl]- oxim (Pyribenzoxim) der Formel
  
  
  
• b) der Verbindung Methyl-2-[[[(4,5-dihydro-4-methyl-5-oxo-3-propoxy-1H- 1,2,4-triazol-1-yl) carbonyl]amino]sulfonyl]-benzoesäure, Natrium-Salz (Propoxycarbazone-sodium) der Formel
  
  
  sowie
• c) zumindest einen der vorstehend genannten Wirkstoffe der Gruppe 3,
  sowie gegebenenfalls
• d) zumindest eine der vorstehend genannten, die Kulturpflanzen-Verträglichkeit verbessernden Verbindung der Gruppe 4, wobei solche Verbindungen bevorzugt sind, die vorstehend in bevorzugten Bereichen genannt wurden.

According to the invention, the above-mentioned selective herbicidal compositions which are characterized by a content of an active compound combination are very particularly preferred

• a) at least one phenoxypyrimidine derivative from the following group of compounds:
  2,6-bis [(4,6-dimethoxy-2-pyrimidinyl) oxy] benzoate (sodium), (bispyribacsodium, KIH 2023) of the formula
  
  
  or
  Diphenylmethanone-O- [2,6-bis [(4,6-dimethoxy-2-pyrimidinyl) oxy] benzoyl] oxime (pyribenzoxime) of the formula
  
  
  
• b) the compound methyl-2 - [[[(4,5-dihydro-4-methyl-5-oxo-3-propoxy-1H-1,2,4-triazol-1-yl) carbonyl] amino] sulfonyl] -benzoic acid, sodium salt (Propoxycarbazone-sodium) of the formula
  
  
  such as
• c) at least one of the above-mentioned active ingredients of group 3,
  and if necessary
• d) at least one of the above-mentioned compounds of group 4 which improve crop plant tolerance, preference being given to those compounds which have been mentioned above in preferred ranges.

• a) 2,6-Bis[(4,6-dimethoxy-2-pyrimidinyl)oxy)-benzoat (Natrium), (Bispyribacsodium) der Formel
  
  
  und
• b) Methyl-2-[[[(4,5-dihydro-4-methyl-5-oxo-3-propoxy-1H-1,2,4-triazol-1-yl) carbonyl]amino)sulfonyl]-benzoesäure, Natrium-Salz (Propoxycarbazonesodium) der Formel
  
  
  sowie
• c) zumindest eine weitere Verbindung ausgewählt aus den folgenden Wirkstoffen der Gruppe 3:
  • a) Sulfonylharnstoffe:
    N-(4,6-Dimethoxy-pyrimidin-2-yl)-N'-(N-methyl-N-methylsulfonyl-sulfamoyl)-harnstoff (Amidosulfuron), N-(4-Methoxy-6-methyl-1,3,5-triazin-2-yl)- N'-(2-methoxycarbonyl-phenylsulfonyl)-harnstoff (Metsulfuron-methyl), N- Methyl-N-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-N'-(2-methoxycarbonylphenylsulfonyl)-harnstoff (Tribenuron-methyl), N-(4-Methoxy-6-trifluormethoxy-1,3,5-triazin-2-yl)-N'-(2-trifluormethyl-phenylsulfonyl)-harnstoff (Tritosulfuron),
  • b) Triazolopyrimidine:
    N-(2,6-Difluor-phenyl)-8-fluor-5-methoxy-[1,2,4]-triazolo-[1,5-c]-pyrimidin- 2-sulfonamid (Florasulam), N-(2,6-Dichlor-3-methyl-phenyl)-5,7-dimethoxy- 1,2,4-triazolo[1,5-a]-pyrimidin-2-sulfonamid (Metosulam),
  • c) Imidazolinone:
    2-(4,5-Dihydro-4-methyl-4-isopropyl-5-oxo-1 H-imidazol-2-yl)-5-methoxymethyl-pyridin-3-carbonsäure (Imazamox),
  • d) Harnstoffe:
    N,N-Dimethyl-N'-(4-isopropyl-phenyl)-harnstoff (Isoproturon),
  • e) Triazindione:
    4-Amino-6-tert-butyl-3-methylthio-1,2,4-triazin-5(4H)-on (Metribuzin),
  • f) Triketone:
    2-(2-Chlor-4-methylsulfonyl-benzoyl)-cyclohexan-1,3-dion (Sulcotrione),
  • g) Triazolinone:
    Benzenecarbothiamid-,4-[4,5-dihydro-4-methyl-5-oxo-3-(trifluormethyl)-1H- 1,2,4-triazol-1-yl]-2-[(ethylsulfonyl)amino]-5-fluoro- (CAS 173980-17-1, HWH4991),
  (2-Chloro-N-[1-[2,6-dichloro-4-(difluoromethyl)phenyl]-4-nitro-1H-pyrazol-5-yl]- propancarbonsäureamid (CAS-Nummer 121750-17-2; SLA 5599),
  Methyl-5-(2,4-dichlor-phenoxy)-2-nitro-benzoat (Bifenox), und
  (4-Amino-3,5-dichlor-6-fluor-pyridin-2-yl-oxy)-essigsäure (-2-butoxy-1-methylethylester, -1-methyl-heptylester) (Fluroxypyr, -butoxypropyl, -meptyl),
  sowie gegebenenfalls
• d) zumindest eine der vorstehend genannten, die Kulturpflanzen-Verträglichkeit verbessernden Verbindung der Gruppe 4, wobei solche Verbindungen bevorzugt sind, die vorstehend in bevorzugten Bereichen genannt wurden.

Most preferred according to the invention are selective herbicidal compositions which are characterized by a content of an active ingredient combination comprising

• a) 2,6-bis [(4,6-dimethoxy-2-pyrimidinyl) oxy) benzoate (sodium), (bispyribacsodium) of the formula
  
  
  and
• b) Methyl-2 - [[[(4,5-dihydro-4-methyl-5-oxo-3-propoxy-1H-1,2,4-triazol-1-yl) carbonyl] amino) sulfonyl] benzoic acid , Sodium salt (propoxycarbazone sodium) of the formula
  
  
  such as
• c) at least one further compound selected from the following active ingredients of group 3:
  • a) Sulfonylureas:
    N- (4,6-Dimethoxy-pyrimidin-2-yl) -N '- (N-methyl-N-methylsulfonylsulfamoyl) urea (amidosulfuron), N- (4-methoxy-6-methyl-1,3 , 5-triazin-2-yl) - N '- (2-methoxycarbonyl-phenylsulfonyl) urea (metsulfuron-methyl), N-methyl-N- (4-methoxy-6-methyl-1,3,5-triazine -2-yl) -N '- (2-methoxycarbonylphenylsulfonyl) urea (tribenuron-methyl), N- (4-methoxy-6-trifluoromethoxy-1,3,5-triazin-2-yl) -N' - ( 2-trifluoromethyl-phenylsulfonyl) urea (tritosulfuron),
  • b) Triazolopyrimidines:
    N- (2,6-difluorophenyl) -8-fluoro-5-methoxy- [1,2,4] triazolo- [1,5-c] pyrimidine- 2-sulfonamide (florasulam), N- ( 2,6-dichloro-3-methylphenyl) -5,7-dimethoxy-1,2,4-triazolo [1,5-a] pyrimidine-2-sulfonamide (metosulam),
  • c) Imidazolinones:
    2- (4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1 H -imidazol-2-yl) -5-methoxymethyl-pyridine-3-carboxylic acid (imazamox),
  • d) ureas:
    N, N-dimethyl-N '- (4-isopropylphenyl) urea (isoproturon),
  • e) Triazinediones:
    4-amino-6-tert-butyl-3-methylthio-1,2,4-triazin-5 (4H) -one (metribuzin),
  • f) Triketones:
    2- (2-chloro-4-methylsulfonyl-benzoyl) cyclohexane-1,3-dione (sulcotrione),
  • g) triazolinones:
    Benzenecarbothiamid-, 4- [4,5-dihydro-4-methyl-5-oxo-3- (trifluoromethyl) -1H- 1,2,4-triazol-1-yl] -2 - [(ethylsulfonyl) amino] - 5-fluoro- (CAS 173980-17-1, HWH4991),
  (2-Chloro-N- [1- [2,6-dichloro-4- (difluoromethyl) phenyl] -4-nitro-1H-pyrazol-5-yl] propane carboxamide (CAS number 121750-17-2; SLA 5599),
  Methyl 5- (2,4-dichlorophenoxy) -2-nitro-benzoate (bifenox), and
  (4-Amino-3,5-dichloro-6-fluoropyridin-2-yl-oxy) acetic acid (-2-butoxy-1-methylethyl ester, -1-methyl-heptyl ester) (fluroxypyr, butoxypropyl, meptyl )
  and if necessary
• d) at least one of the above-mentioned compounds of group 4 which improve crop plant tolerance, preference being given to those compounds which have been mentioned above in preferred ranges.

It has now surprisingly been found that those defined above Active ingredient combinations of the phenoxypyrimidine derivatives of the formula (I) and the active ingredient of Group 2 in combination with active ingredients of group 3, optionally in Combinations with active ingredients of group 4 with very good crop tolerance have a particularly high herbicidal activity and in different Crop crops such as B. in soy, potatoes, corn or rice and especially in Cereals such as B. barley, rye, triticale and especially wheat for selective Weed control can be used.

Surprisingly, the herbicidal activity of the invention Active ingredient combinations of compounds from groups 1, 2 and 3 listed above considerably higher than the sum of the effects of the individual active ingredients.

There is therefore an unforeseeable synergistic effect and not just one Addition of activities. The new combinations of active ingredients are good in many cultures tolerated, whereby the new active substance combinations are otherwise difficult to fight Control weeds well. The new combinations of active ingredients therefore represent one valuable enrichment of selective herbicides.

It was also surprisingly found that those defined above Active ingredient combinations of phenoxypyrimidine derivatives of the formula (I) or their salts and one Safener / antidote ("active substances of group 4") in combination with one or more the group 2 and group 3 active ingredients listed above with very good Crop crop tolerance has a particularly high herbicidal activity and in different cultures, especially in cereals, especially wheat, but also used in soy, potatoes, corn and rice for selective weed control can be.

Surprisingly, it was also found that the herbicidal Substance MCPA and the substance 2,4-dichlorophenoxyacetic acid (2,4-D) and their Derivatives can take over the safener task described above.

A preferred embodiment is therefore also a mixture containing one Compound of formula (I) and / or its salts on the one hand and 2,4-D and / or its Derivatives, on the other hand, in combination with one or more of the above Active ingredients listed in groups 2 and 3. Typical derivatives of 2,4-D are e.g. B. their esters.

A preferred embodiment is also a mixture containing one Compound of formula (I) and / or their salts on the one hand and MCPA on the other hand in Combination with the above-mentioned active ingredient of group 2 and one or several Group 3 compounds.

The compounds diethyl-1- (2,4-dichlorophenyl) -4,5-dihydro-5-methyl-1H-pyrazole- 3,5-dicarboxylates (mefenpyr-diethyl), (1-methylhexyl) - [(5-chloro-8-quinolinyl) oxy] - acetate (Cloquintocet-mexyl) and ethyl 1- (2,4-dichlorophenyl) -5- (trichloromethyl) - 1H-1,2,4-triazole-3-carboxylate (fenchlorazole-ethyl) are in the following Patent applications described: DE-A-39 39 503, EP-A-191 736 and DE-A-35 25 205. 2,4-D is a well-known herbicide. (4-Chloro-2-methylphenoxy) acetic acid (MCPA) also a well known herbicide.

It is also to be regarded as surprising that from a large number of known Safeners or antidotes that are capable of the harmful effects of a herbicide to antagonize the crops, just the compounds of the above Group 4 are suitable, the damaging effect of compounds of formula (I) and their salts in combination with one or more of the above Active ingredients listed in groups 2 and 3, approximate to the crop plants completely repeal without the herbicidal activity against the To affect weeds.

The active substance combinations according to the invention can, for. B. can be used in the following plants:
Dicotyledon weeds of the genera: Sinapis, Lepidium, Galium, Stellaria, Matricaria, Anthemis, Galinsoga, Chenopodium, Urtica, Senecio, Amaranthus, Portulaca, Xanthium, Convolvulus, Ipomoea, Polygonum, Sesbania, Ambrosia, Cirsium, Carduippum, Sonuanum , Rotala, Lindernia, Lamium, Veronica, Abutilon, Emex, Datura, Viola, Galeopsis, Papaver, Centaurea, Trifolium, Ranunculus, Taraxacum.
Dicotyledon cultures of the genera: Gossypium, Glycine, Beta, Daucus, Phaseolus, Pisum, Solanum, Linum, Ipomoea, Vicia, Nicotiana, Lycopersicon, Arachis, Brassica, Lactuca, Cucumis, Cuburbita.
Monocotyledonous weeds of the genera: Echinochloa, Setaria, Panicum, Digitaria, Phleum, Poa, Festuca, Eleusine, Brachiaria, Lolium, Bromus, Avena, Cyperus, Sorghum, Agropyron, Cynodon, Monochoria, Fimbristylis, Sagittaria, Iochasumirumum, Scalumum, Scalumumum , Sphenoclea, Dactyloctenium, Agrostis, Alopecurus, Apera, Phalaris.
Monocot cultures of the genera: Oryza, Zea, Triticum, Hordeum, Avena, Secale, Sorghum, Panicum, Saccharum, Pineapple, Asparagus, Allium.

However, the use of the active compound combinations according to the invention is by no means limited to these genres, but extends in the same way other plants.

According to the invention, all plants and parts of plants can be treated. Under Plants are understood here as all plants and plant populations desired and undesirable wild plants or crops (including naturally occurring crops). Cultivated plants can be plants that by conventional breeding and optimization methods or by biotechnological and genetic engineering methods or combinations of these methods can be obtained, including and including the transgenic plants plant varieties that can or cannot be protected by plant breeders' rights. Plant parts should include all above-ground and underground parts and organs of plants, such as sprout, leaf, flower and root are understood, whereby for example leaves, needles, stems, stems, flowers, fruiting bodies, fruits and seeds as well as roots, tubers and rhizomes. To the plant parts also includes crops and vegetative and generative propagation material, for example cuttings, tubers, rhizomes, cuttings and seeds.

The treatment of the plants and plant parts according to the invention with the Active substances take place directly or by influencing their environment, habitat or Storage room according to the usual treatment methods, e.g. B. by diving, spraying, Evaporation, atomization, scattering, spreading and in the case of propagation material, especially in the case of seeds, further by single or multi-layer coating.

As already mentioned above, according to the invention all plants and their parts can be treated. In a preferred embodiment, go wild existing or by conventional organic breeding methods, such as crossing or protoplast fusion obtained plant species and plant varieties and their Parts treated. In a further preferred embodiment, transgenes are Plants and plant varieties, if necessary by genetic engineering methods in combination with conventional methods (Genetically Modified Organisms) and their parts. The term "parts" or "parts of." Plants "or" parts of plants "was explained above.

Plants of the commercially available in each case are particularly preferred according to the invention or plant varieties in use. Among plant varieties is understood to mean plants with certain properties ("traits") that are characterized by both conventional breeding, by mutagenesis or by recombinant DNA techniques have been obtained. These can be varieties, bio and genotypes.

Among the preferred transgenes to be treated according to the invention (Genetically preserved) plants or plant varieties include all plants that received genetic material through the genetic modification, which gives these plants particular beneficial properties ("traits"). Examples of such properties are better plant growth, increased Tolerance to high or low temperatures, increased tolerance to Dryness or against water or soil salt content, increased flowering performance, easier harvesting, acceleration of ripening, higher crop yields, higher quality and / or higher nutritional value of the enite products, higher shelf life and / or Machinability of crop products. Further and particularly highlighted examples for such properties are an increased defense of the plants against animal and microbial pests, such as insects, mites, phytopathogenic fungi, Bacteria and / or viruses and an increased tolerance of the plants to certain herbicidal active ingredients. The important ones are examples of transgenic plants Crops, such as cereals (wheat, rice), corn, soybeans, potatoes, cotton, Rapeseed and fruit plants (with the fruits apples, pears, citrus fruits and Grapes) mentioned, especially corn, soybeans, potatoes, cotton and rapeseed be highlighted. As properties ("traits") become special highlighted the increased defense of plants against insects by in the Plant-derived toxins, especially those caused by the genetic material from Bacillus thuringiensis (e.g. through the genes CryIA (a), CryIA (b), CryIA (c), CryIIA, CryIIIA, CryIIIB2, Cry9c, Cry2Ab, Cry3Bb and CryIF as well as their Combinations) are generated in the plants (hereinafter "Bt plants"). As Properties ("traits") are also particularly emphasized the increased defense of plants against fungi, bacteria and viruses by systemic acquirers Resistance (SAR), systemin, phytoalexins, elicitors and resistance genes and appropriately expressed proteins and toxins. As traits further emphasized the increased tolerance of plants certain herbicidal active ingredients, for example imidazolinones, Sulfonylureas, glyphosate or phosphinothricin (e.g. "PAT" gene). The each the desired properties ("traits") conferring genes can also in Combinations with each other occur in the transgenic plants. As examples for "Bt plants" are maize varieties, cotton varieties, soy varieties and potato varieties under the trade names YIELD GARD® (e.g. maize, Cotton, soy), KnockOut® (e.g. maize), StarLink® (e.g. maize), Bollgard® (Cotton), Nucoton® (cotton) and NewLeaf® (potato). Examples of herbicide-tolerant plants are maize, cotton and Soybeans known as Roundup Ready® (Tolerance to glyphosates e.g. corn, cotton, soy), Liberty Link® (tolerance against phosphinotricin, e.g. Rape), IMI® (tolerance to imidazolinones) and STS® (Tolerance to sulfonylureas e.g. maize). As a herbicide resistant (conventionally grown to herbicide tolerance) plants are also the varieties sold under the name Clearfield® (e.g. maize). Of course, these statements also apply to future developed or future plant varieties with these or in the future developed genetic traits.

The synergistic effect of the active substance combinations according to the invention is at certain concentration ratios particularly pronounced. However, they can Weight ratios of the active ingredients in the active ingredient combinations in relatively large Ranges can be varied. In general, 1 part by weight of the active ingredient Formula (I) 0.001 to 1000 parts by weight each, preferably 0.005 to 200 parts by weight Parts by weight and particularly preferably 0.01 to 100 parts by weight of active ingredient of groups 2 and 3. In particular, 1 part by weight of group 1 accounts for 0.1 each up to 1 part by weight of the active ingredients in groups 2 and 3.

The advantageous effect of the crop plant tolerance of the invention Active ingredient combinations is also available at certain concentration ratios particularly pronounced. However, the weight ratios of the active ingredients in the Drug combinations can be varied in relatively large areas. In general account for 1 part by weight of active ingredient of the formula (I), its salts or its Mixtures with active ingredients of groups 2 and 3 0.001 to 1000 parts by weight, preferably 0.01 to 100 parts by weight and particularly preferably 0.1 to 10 Parts by weight of one of the crops tolerated above under (d) improving compounds (antidots / safeners).

The active substance combinations can be converted into the customary formulations such as solutions, emulsions, wettable powders, suspensions, powders, dusts, Pastes, soluble powders, granules, suspension emulsion concentrates, Active ingredient-impregnated natural and synthetic substances as well as very fine encapsulation in polymers Substances.

These formulations are prepared in a known manner, e.g. B. by mixing of the active ingredients with extenders, i.e. liquid solvents and / or solid Carriers, if appropriate using surface-active agents, that is Emulsifiers and / or dispersants and / or foaming agents.

In the case of the use of water as an extender, e.g. B. also organic Solvents are used as auxiliary solvents. As a liquid solvent essentially come into question: aromatics, such as xylene, toluene, or alkylnaphthalenes, chlorinated aromatics and chlorinated aliphatic hydrocarbons, such as chlorobenzenes, Chlorethylene or methylene chloride, aliphatic hydrocarbons such as cyclohexane or paraffins, e.g. B. petroleum fractions, mineral and vegetable oils, alcohols, such as Butanol or glycol and their ethers and esters, ketones such as acetone, Methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents, such as Dimethylformamide and dimethyl sulfoxide, as well as water.

The following are suitable as solid carriers:
z. B. ammonium salts and natural rock powders, such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth and synthetic rock powders, such as highly disperse silica, aluminum oxide and silicates, are suitable as solid carriers for granules: z. B. broken and fractionated natural rocks such as calcite, marble, pumice, sepiolite, dolomite and synthetic granules from inorganic and organic flours as well as granules from organic material such as sawdust, coconut shells, corn cobs and tobacco stems; as emulsifying and / or foam-generating agents come into question: z. B. nonionic and anionic emulsifiers, such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers, e.g. B. alkylaryl polyglycol ethers, alkyl sulfonates, alkyl sulfates, aryl sulfonates and protein hydrolyzates; as dispersants come into question: z. B. lignin sulfite and methyl cellulose.

In the formulations, adhesives such as carboxymethyl cellulose, natural and synthetic powdery, granular or latex-shaped polymers can be used, such as Gum arabic, polyvinyl alcohol, polyvinyl acetate, and natural phospholipids, such as cephalins and lecithins and synthetic phospholipids. Other additives can mineral and vegetable oils.

Dyes such as inorganic pigments, e.g. B. iron oxide, titanium oxide, Ferrocyan blue and organic dyes such as alizarin, azo and Metal phthalocyanine dyes and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, Molybdenum and zinc can be used.

The formulations generally contain between 0.1 and 95 percent by weight of active substances, including the safe active substances, preferably between 0.5 and 90%.

The active compound combinations according to the invention are generally in the form of Ready formulations applied. The one in the drug combinations Active ingredients contained can also be used in individual formulations mixed, d. H. be used in the form of tank mixes.

The new drug combinations can be used as such or in their formulations continue to be used in a mixture with other known herbicides, ready formulations or tank mixes are possible. Also one Mixture with other known active ingredients, such as fungicides, insecticides, Acaricides, nematicides, bird repellants, growth substances, Plant nutrients and soil structure improvers are possible. For certain Applications, especially in the post-emergence process, it can also be advantageous in the Formulations as additional additives plant-compatible mineral or vegetable oils or ammonium salts such as B. ammonium sulfate or Absorb ammonium rhodanide.

The new active substance combinations can be used as such, in the form of their formulations or the use forms prepared therefrom by further dilution, such as ready-to-use solutions, suspensions, emulsions, powders, pastes and granules be applied. The application happens in the usual way, e.g. B. by casting, Spraying, spraying, dusting or sprinkling.

The active substance combinations according to the invention can be used before and after emergence of the plants are applied, i.e. pre-emergence and post-emergence. she can also be worked into the soil before sowing.

A herbicide always has a synergistic effect if the herbicide Effect of the combination of active ingredients is greater than that of the individual applied Agents.

The expected effect for a given combination of two herbicides can be calculated as follows (cf. COLBY, SR: "Calculating synergistic and antagonistic responses of herbicide combinations", Weeds 15, pages 20-22, 1967):

If X =% damage from herbicide A (active ingredient of group 1) at p kg / ha application rate
and Y =% damage by herbicide B (active ingredient of group 2) at q kg / ha application rate
and Z =% damage by herbicide C (active ingredient of group 3) at an application rate of r kg / ha
and E = the expected damage to the herbicides AB and C at p, q and r kg / ha,
then

If the actual damage is greater than calculated, the combination is in its Effect over additive, that is, it shows a synergistic effect.

Claims (14)

1. Herbicidal agents, characterized by comprising an effective content of an active ingredient combination a) at least one phenoxypyrimidine derivative of the general formula (I)


in which
R is hydrogen, -CH ₂ CH ₂ S (O) _n R ₁ (where R _{1 is} C ₁ -C ₄ alkyl and n is 0, 1 or 2) or


stands,
in which
R _{2 represents} hydrogen, halogen, cyano, phenyl, C ₁ -C ₈ alkyl, C ₁ -C ₄ alkoxy, C ₁ -C ₄ alkylthio, C ₁ -C ₄ alkoxycarbonyl, mono- or di-C ₁ -C ₄ -alkylaminocarbonyl, phenyl-C ₁ -C ₄ -alkylaminocarbonyl, where the phenyl group may optionally be substituted by halogen, C ₁ -C ₂ -alkyl or C ₁ -C ₂ -alkoxy, furylmethylaminocarbonyl or phenyl, and
R ₃ for phenyl optionally substituted by halogen, cyano, nitro, C ₁ -C ₄ alkyl, C ₁ -C ₄ alkoxy or allyloxy, for amino optionally substituted by C ₁ -C ₄ alkyl, phenoxy, benzyloxy or acetoxy stands for C ₁ -C ₄ alkylthio or for the grouping -COR ₄ , where R _{4 stands} for C ₁ -C ₄ alkoxy, C ₁ - C ₄ alkyl, benzyloxy or benzylamino,
A represents chlorine or methoxy and
D and E, which may be the same or different, represent hydrogen, halogen, C ₁ -C ₈ alkyl, C ₁ -C ₈ alkoxy or C ₁ -C ₈ alkoxy substituted by halogen,
and / or a salt of a compound of formula (I)
("Active substances of group 1"),
and b) at least one compound from a further group of herbicides which contains the active compounds mentioned below:
Methyl 2 - [[[(4,5-dihydihydro-4-methyl-5-oxo-3-propoxy-1H-1,2,4-triazol-1-yl) carbonyl] amino] sulfonyl] benzoic acid, sodium Salt (Propoxycarbazone-sodium) of the formula


and
4,5-dihydro-3-methoxy-4-methyl-5-oxo-N - [[2- (trifluoromethoxy) phenyl] sulfonyl] -1H-1,2,4-triazole-1-carboxamide, sodium salt (Flucarbazone-sodium) of the formula


("Active substances of group 2"),
such as c) one or more compounds from a further group of herbicides which contains the active compounds mentioned below:
2-Chloro-N- (ethoxymethyl) -N- (2-ethyl-6-methyl-phenyl) -acetamide (acetochlor), 5- (2-chloro-4-trifluoromethyl-phenoxy) -2-nitro-benzoic acid sodium salt (Acifluorfen-sodium), 2-chloro-6-nitro-3-phenoxybenzenamine (Aclonifen), 2-chloro-N- (methoxymethyl) -N- (2,6-diethylphenyl) -acetamide (alachlor), N-ethyl- N'-i-propyl-6-methylthio-1,3,5-triazine-2,4-diamine (ametryn), 4-amino-N- (1,1-dimethyl-ethyl) -4,5-dihydro- 3- (1-methyl-ethyl) -5-oxo-1H-1,2,4-triazole-1-carboxamide (amicarbazone), N- (4,6-dimethoxypyrimidin-2-yl) -N'- (N-methyl-N-methylsulfonylsulfamoyl) urea (amidosulfuron), 1H-1,2,4-triazol-3-amine (amitrole), S- [2 - [(4-chlorophenyl) - (1 -isopropyl) -amino] - 2-oxo-ethyl] -O, O-dimethyl-phosphorodithioate (anilofos), 6-chloro-4-ethylamino-2-isopropylamino-1,3,5-triazine (atrazine), 2- [2,4-dichloro-5- (2-propynyloxy) phenyl] -5,6,7,8-tetrahydro-1,2,4-triazolo- [4,3-a] pyridine-3 (2H) -one (azafenidin), N- (4,6-dimethoxypyrimidin-2-yl) - N '- [1-methyl-4- (2-methyl-2H-tetrazol-5-yl) -1H-pyrazole- 5-ylsulfonyl] harnstof f (azimsulfuron), N-benzyl-2- (4-fluoro-3-trifluoromethyl-phenoxy) -butanamide (beflubutamide), 4-chloro-2-oxo-3 (2H) -benzthiazole acetic acid (benazoline), N-butyl- N-ethyl-2,6-dinitro-4-trifluoromethylbenzenamine (benfluralin), 2,3-dihydro-3,3-dimethyl-5-benzofuranylethanesulfonate (benfuresate), N- (4,6-dimethoxypyrimidin-2-yl ) -N'- (2-methoxycarbonylphenylmethylsulfonyl) urea (bensulfuronmethyl), S - [(4-chlorophenyl) methyl] diethylthiocarbamate (benthiocarb, thiobencarb), 2- [2- [4- (3, 6-Dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1 (2H) -pyrimidinylphenoxymethyl] -5-ethyl-phenoxypropanoic acid methyl ester (benzfendizone), 3- (2-chloro-4-methylsulfonylbenzoyl) -4-phenylthio-bicyclo- [3.2.1] oct-3-en-2-one (benzobicyclone), 2 - [[4- (2,4-dichloro-3-methylbenzoyl) -1,3-dimethyl- 1H-pyrazol-5-yl] - oxy] -1- (4-methylphenyl) ethanone (benzofenap), ethyl N-benzoyl-N- (3,4-dichlorophenyl) -DL-alaninate (benzoylprop- ethyl), 3-i-propyl-1H-2,1,3-benzothiadiazin-4 (3H) -one (bentazone), methyl-5- (2,4-dichlorophenoxy) -2-nitro-benzo at (bifenox), 5-bromo-6-methyl-3- (1-methylpropyl) -2.4 (1H, 3H) pyrimidinedione (bromoacil), 2-bromo-3,3-dimethyl-N- (1-methyl -1-phenyl-ethyl) -butanamide (bromobutide), 3,5-dibromo-4-hydroxy-benzaldehyde-O- (2,4-dinitro-phenyl) -oxime (bromofenoxime), 3,5-dibromo-4- hydroxy-benzonitrile (bromoxynil), N-butoxymethyl-2-chloro-N- (2,6-diethyl-phenyl) -acetamide (butachlor), 2-chloro-5- (3,6-dihydro-3-methyl-2 , 6-dioxo-4-trifluoromethyl-1 (2H) -pyrimidinyl) -benzoic acid- [1,1-dimethyl-2-oxo-2- (2-propenyloxy)] - ethyl ester (butafenacil-allyl), 2- (1 -Ethoximino-propyl) -3-hydroxy-5- [2,4,6-trimethyl-3- (1-oxo-butyl) phenyl] -2-cyclohexen-1-one (butroxydim), S-ethyl-bis - (2-methyl-propyl) -thiocarbamate (butylate), N, N-diethyl-3- (2,4,6-trimethyl-phenylsulfonyl) -1H-1,2,4-triazole-1-carboxamide (cafenstrole) , 2- [1 - [(3-chloro-2-propenyl) oxyimino] propyl] -3-hydroxy-5- (tetrahydro-2H-pyran-4-yl) -2-cyclohexen-1-one (Caloxydim, tepraloxydim), 2- (4-chloro-2-fluoro-5- (2-chloro-2-ethoxycarbonylethyl) phenyl) -4-difluoromethyl-5-methyl-2,4-dihydro -3H-1,2,4-triazol-3-one (carfentrazone-ethyl), 2,4-dichloro-1- (3-methoxy-4-nitrophenoxy) benzene (chloromethoxyfen), 3-amino-2,5 -dichlorobenzoic acid (chlorambene), N- (4-chloro-6-methoxy-pyrimidin-2-yl) -N '- (2-ethoxycarbonyl-phenylsulfonyl) -urea (chlorimuron-ethyl), 1,3,5- Trichloro-2- (4-nitro-phenoxy) benzene (chloronitrofen), N- (4-methoxy-6-methyl-1,3,5-triazin-2-yl) -N '- (2-chlorophenylsulfonyl ) urea (chlorosulfuron), N '- (3-chloro-4-methylphenyl) -N, N-dimethylurea (chlorotoluron), 2-chloro-3- [2-chloro-5- (1.3 , 4,5,6,7-hexahydro-1,3-dioxo-2H-isoindol-2-yl) phenyl] -2-propanoic acid, ethyl ester (cinidonethyl), exo-1-methyl-4-isopropyl-2- (2-methyl-phenyl-methoxy) -7-oxabicyclo- [2.2.1] -heptane (cinmethylin), N- (4,6-dimethoxy-1,3,5-triazin-2-yl) -N'- (2- (2-methoxyethoxy) phenylsulfonyl) urea (cinosulirone), 2- [1- [2- (4-chlorophenoxy) propoxyaminobutyl] -5- (tetrahydro-2H-thiopyran-3-yl) - 1,3-cyclohexanedione (Clefoxydim), (E, E) - (+) - 2- [1 - [[(3-chloro-2-propenyl) -oxy] imino] propyl] -3-hydroxy-2 - cycl ohexen-1-one (clethodim), (R) - (2-propynyl) -2- [4- (5-chloro-3-fluoropyridin-2-yl-oxy) phenoxy propanoate (clodinafop propargyl), 2 - (2,4-dichloro-3-methyl-phenoxy) -N-phenyl-propanamide (Clomeprop), 3,6-dichloro-pyridine-2-carboxylic acid (clopyralide), methyl-3-chloro-2 - [(5 - ethoxy-7-fluoro [1,2,4] triazolo [1,5-c] pyrimidin-2-yl-sulfonyl) -amino] - benzoate (chlorosulam-methyl), N - [(2-chlorophenyl) -methyl] -N '- (1-methyl-1-phenyl-ethyl) -urea (cumyluron), 2-chloro-4-ethylamino-6- (1-cyano-1-methyl-ethylamino) -1,3, 5-triazine (cyanazine), N- (4,6-dimethoxypyrimidin-2-yl) -N '- (2-cyclopropylcarbonylphenylsulfonyl) urea (cyclosulfamuron), 2- (1-ethoximinobutyl) -3-hydroxy -5- (tetrahydro-2H-thiopyran-3-yl) -2-cyclohexen-1-one (cycloxydim), (R) -2- [4- (4-cyano-2-fluorophenoxy) phenoxy] - butanoic acid propyl (cyhalofop-butyl), 2,4-dichlorophenoxyacetic acid (2,4-D), 3,6-dichloro-2-methoxybenzoic acid (Dicamba), (R) -2- (2,4- Dichlorophenoxy) propanoic acid (dichloroprop-P), methyl 2- [4- (2,4-dichlorophenoxy) phenoxy ] propanoate (diclofop-methyl), N- (2,6-dichlorophenyl) -5-ethoxy-7-fluoro [1,2,4] triazolo [1,5-c] pyrimidine-2 - sulfonamide (diclosulam), 1,2-dimethyl-3,5-diphenyl-1H-pyrazolium methyl sulfate (difenzoquat), N- (2,4-difluorophenyl) -2- (3-trifluoromethylphenoxy) pyridine-3 carboxamide (diflufenican), 2- [1 - [(3,5-difluorophenyl) amino carbonyl hydrazono] ethyl] pyridine-3-carboxylic acid (diflufenzopyr), S- (1-methyl-1- phenyl-ethyl) -1-piperidine-carbothioate (dimepiperate), 2-chloro-N- (2,6-dimethyl-phenyl) -N- (2-methoxy-ethyl) -acetamide (dimethachlor), N- (1, 2-dimethyl-propyl) -N'-ethyl-6-methylthio-1,3,5-triazine-2,4-diamine (dimethametryn), (S-) 2-chloro-N- (2,4-dimethyl- 3-thienyl) -N- (2-methoxy-1-methyl-ethyl) -acetamide (S-) (dimethenamid), 2-amino-4- (1-fluoro-1-methyl-ethyl) -6- (1 - methyl-2- (3,5-dimethyl-phenoxy) -ethylamino) -1,3,5-triazine (dimexyflam), N3, N3-diethyl-2,4-dinitro-6-trifluoromethyl-1,3-diamino -benzene (dinitramine), 6,7-dihydro-dipyrido [1,2-a: 2 ', 1'-c] pyrazinediium (diquat), S, S-dimethyl-2-difluoromethyl -4-i-butyl-6-trifluoromethylpyridine-3,5-dicarbothioate (dithiopyr), N '- (3,4-dichlorophenyl) -N, N-dimethyl-urea (diuron), N- (4-methyl -phenyl) -N '- (1-methyl-1-phenyl-ethyl) -urea (Dymron, Daimuron), 2- [2- (3-chlorophenyl) - oxiranylmethyl] -2-ethyl-1H-inden- 1,3 (2H) -dione (epropodane), S-ethyl-dipropylthiocarbamate (EPTC), S- (phenylmethyl) -N-ethyl-N- (1,2-dimethyl-propyl) -thiocarbamate (Esprocarb), N- Ethyl-N- (2-methyl-2-propenyl) -2,6-dinitro-4-trifluoromethyl-benzenamine (ethalfluralin), (S) - (2-ethoxy-1-methyl-2-oxoethyl) -2-chloro -5- (2-chloro-4-trifluoromethylphenoxy) benzoate (ethoxyfen), N- (4,6-dimethoxypyrimidin-2-yl) -N '- (2-ethoxyphenoxysulfonyl) urea (ethoxysulfuron), N- (2,3-dichlorophenyl) -4-ethoxymethoxybenzamide (etobenzanide), (R) -ethyl-2- [4- (6-chloro-benzoxazol-2-yl-oxy) phenoxy] propanoate (fenoxaprop - (P) -ethyl), 4- (2-chlorophenyl) -N-cyclohexyl-N-ethyl-4,5-dihydro-5-oxo-1H-tetrazole-1-carboxamide (fentrazamide), isopropyl-N -benzoyl-N- (3-chloro-4-fluro-phenyl) -DL-alaninate (Flamprop -isopropyl), isopropyl-N-benzoyl-N- (3-chloro-4-fluro-phenyl) -L-alaninate (Flamprop-isopropyl-L), methyl-N-benzoyl-N- (3-chloro-4- fluorophenoxy) -DL-alaninate (Flamprop-methyl), N- (2,6-difluorophenyl) -8-fluoro-5-methoxy- [1,2,4] -triazolo- [1,5-c] - butyl pyrimidin-2-sulfonamide (Florasulam), (R) -2- [4- (5-trifluoromethyl-pyridin-2-yloxy) phenoxy] propanoic acid (fluazifop, butyl, -P-butyl), 5- (4-Bromo-1-methyl-5-trifluoromethyl-1H-pyrazol-3-yl) -2-chloro-4-fluorobenzoic acid i-propyl ester (fluazolates), 4,5-dihydro-3-methoxy-4 - methyl-5-oxo-N - [(2-trifluoromethoxyphenyl) sulfonyl] -1-H-1,2,4-triazole-1-carboxamide sodium salt (Flucarbazone-sodium), N- (4-fluor -phenyl) -Ni-propyl-2- (5-trifluoromethyl-1,3,4-thiadiazol-2-yloxy) acetamide (Flufenacet), N- (2,6-difluorophenyl) -5-methyl-1 , 2,4-triazolo [1,5-a] pyrimidine-2-sulfonamide (flumetsulam), pentyl- [2-chloro-4-fluoro-5- (1, 3, 4,5,6,7-hexahydro -1,3-dioxo-2H-isoindol-2-yl) phenoxy] acetate (flumiclorac-pentyl), 2- [7-fluoro-3,4-dihydro-3-oxo 4- (2-propynyl) -2H- 1,4-benzoxazin-6-yl] -4,5,6,7-tetrahydro-1H-isoindole-1,3-dione (flumioxazin), 2- [4-chloro-2-fluoro-5- [ (1-methyl-2-propynyl) -oxy] -phenyl] -4,5,6,7-tetrahydro-1H-isoindole-1,3 (2H) -dione (flumipropyn), 3-chloro-4-chloromethyl- 1- (3-trifluoromethyl-phenyl) -2-pyrrolidinone (fluorochloridone), 5- (2-chloro-4-trifluoromethylphenoxy) -2-nitro-benzoic acid-ethoxycarbonylmethyl ester (fluoroglycofen-ethyl), 1- (4-chloro-3 - (2,2,3,3,3-pentafluoropropoxymethyl) phenyl) -5-phenyl-1H-1,2,4-triazole-3-carboxamide (flupoxam), 1-isopropyl-2-chloro-5 - (3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1 (2H) pyrimidyl) benzoate (flupropacil), N- (4,6-dimethoxypyrimidin-2-yl) -N '- (3-methoxycarbonyl-6-trifluoromethyl-pyridin-2-ylsulfonyl) urea sodium salt (flupyrsulfuron-methyl-sodium), 9-hydroxy-9H-fluoren-9-carboxylic acid (flurenol), (4-amino-3 , 5-dichloro-6-fluoropyridin-2-yl-oxy) -acetic acid (-2-butoxy-1-methyl-ethyl ester, -1-methyl-heptyl ester) (fluroxypyr, -butoxypropyl, -meptyl), 5- methylamino-2-phenyl-4- (3-trifluormethy l-phenyl) -3 (2H) -furanone (Flurtamone), methyl - [(2-chloro-4-fluoro-5- (tetrahydro-3-oxo-1H, 3H- [1,3,4] -thiadiazolo- [3,4-a] pyridazin-1-ylidene) aminophenyl] thioacetate (fluthiacet-methyl), 5- (2-chloro-4-trifluoromethylphenoxy) -N-methylsulfonyl-2-nitro-benzamide (Fomesafen), 2 - [[[((4,6-Dimethoxy-2-pyrimidinyl) amino] carbonyl] amino] sulfonyl] -4-formylamino-N, N-dimethyl-benzamide (foramsulfuron), 2 -Amino-4- (hydroxymethylphosphinyl) butanoic acid (ammonium salt) (glufosinate (ammonium)), N-phosphonomethylglycine (isopropylammmonium salt), (glyphosate, isopropylammonium), (R) -2- [4- (3rd -Chlor-5-trifluoromethyl-pyridin-2-yl-oxy) -phenoxy] -propanoic acid (-methyl ester, -2-ethoxy-ethyl ester, -butyl ester) (haloxyfop, -methyl, -P-methyl, -ethoxyethyl, -butyl ), 3-Cyclohexyl-6-dimethylamino-1-methyl-1,3,5-triazine-2,4 (1H, 3H) -dione (Hexazinone), methyl-2- (4,5-dihydro-4-methyl -4-isopropyl-5-oxo-1H-imidazol-2-yl) -4-methyl-benzoate (imazamethabenz-methyl), 2- (4,5-dihydro-4-methyl-4-isopropyl-5-oxo 1H-imidazole 2-yl) -5-methyl-pyridine-3-carboxylic acid (imazamethapyr), 2- (4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl) - 5- methoxymethyl-pyridine-3-carboxylic acid (imazamox), 2- (4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl) -quinoline-3-carboxylic acid (imazaquine), 2- (4,5-dihydro-4-methyl-4-i-propyl-5-oxo-1H-imidazol-2-yl) -5-ethyl-pyridine-3-carboxylic acid (imazethapyr), N- (4, 6- Dimethoxy-pyrimidin-2-yl) -N '- (2-chloro-imidazo [1,2-a] -pyridin-3-yl-sulfonyl) -urea (imazosulfuron), N- (4-methoxy-6 -methyl-1,3,5-triazin-2-yl) -N '- (5-iodo-2-methoxycarbonyl-phenylsulfonyl) urea sodium salt (iodosulfuron-methyl-sodium), 4-hydroxy-3,5- diiodobenzonitrile (ioxynil), N, N-dimethyl-N '- (4-isopropyl-phenyl) -urea (isoproturon), N- (3- (1-ethyl-1-methyl-propyl) -isoxazol-5-yl) - 2,6-dimethoxy-benzamide (isoxaben), (4-chloro-2-methylsulfonylphenyl) - (5-cyclopropyl-isoxazol-4-yl) -methanone (isoxachlorotole), (5-cyclopropyl-isoxazol-4-yl) - (2-methylsulfonyl-4-trifluoromethylphenyl) methanone (isoxaflutole), 2- [2- [4- [3,5-dichloro-2-pyridinyl) oxy] phenoxy] -1-oxo-propyl] isoxazolidine (isoxapyrifop), (2-ethoxy-1-methyl-2-oxo-ethyl) ) -5- (2-chloro-4-trifluoromethylphenoxy) -2-nitrobenzoate (lactofen), N '- (3,4-dichlorophenyl) -N-methoxy-N-methylurea (Linuron), (4- Chloro-2-methylphenoxy) acetic acid (MCPA), 2- (4-chloro-2-methylphenoxy) propionic acid (mecoprop), 2- (2-benzothiazolyloxy) -N-methyl-N-phenyl-acetamide (Mefenacet), 2 - [[[[(4,6-dimethoxy-2-pyrimidinyl) amino] carbonyl] amino] sulfonyl] -4- [[(methylsulfonyl) amino] methyl] benzoic acid methyl ester (Mesosulfuron), 2- (4-methylsulfonyl-2-nitro-benzoyl) -1,3-cyclohexanedione (mesotrione), 4-amino-3-methyl-6-phenyl-1,2,4-triazine-5 (4H ) -one (metamitron), 2-chloro-N- (2,6-dimethyl-phenyl) -N- (1H-pyrazol-1-yl-methyl) -acetamide (metazachlor), N '- (4- (3rd , 4-dihydro-2-methoxy-2,4,4-trimethyl-2H-1-benzopyran-7-yl-oxy) phenyl) -N-methoxy-N-methylurea (metobenzuron), N '- (4- Bromophenyl) -N-methoxy-Nmethylurea (metobromuron), (S) -2-chloro-N- (2-ethyl-6-methylph enyl) -N- (2-methoxy-1-methyl-ethyl) -acet-amide (metolachlor, S-metolachlor), N- (2,6-dichloro-3-methylphenyl) -5,7-dimethoxy- 1,2,4-triazolo [1,5-a] pyrimidine-2-sulfonamide (metosulam), N '- (3-chloro-4-methoxyphenyl) -N, N-dimethyl-urea (metoxuron), 4-Amino-6-tert-butyl-3-methylthio-1,2,4-triazine-5 (4H) -one (metribuzin), N- (4-methoxy-6-methyl-1,3,5-triazine -2-yl) -N '- (2-methoxycarbonyl-phenylsulfonyl) urea (metsulfuron-methyl), S-ethyl-hexahydro-1H-azepine-1-carbothioate (Molinate), 2- (2-naphthyloxy) -N -phenyl-propanamide (naproanilide), N-butyl-N '- (3,4-dichlorophenyl) -N-methyl-urea (neburon), N- (4,6-dimethoxy-pyrimidin-2-yl) - N '- (3-dimethylcarbamoyl-pyridin-2-yl-sulfonyl) urea (nicosulfuron), 4-chloro-5-methylamino-2- (3-trifluoromethyl-phenyl) -3 (2H) pyridazinone (norflurazone), p - (2-Chloro-benzyl) -N, N-diethylthiocarbamate (Orbencarb), 4-dipropylamino-3,5-dinitro-benzenesulfonamide (Oryzalin), 3- [2,4-dichloro-5- (2-propynyloxy ) -phenyl] -5- (t-butyl) -1,3,4-oxadiazol-2 (3H) -one (oxadiargyl), 3- [2,4-dichloro-5- (1-methylethoxy) phenyl-5- (t-butyl) - 1,3,4-oxadiazol-2 (3H) -one (oxadiazon), N- ( 4,6-Dimethyl-pyrimidin-2-yl) -N '- (2-oxetan-3-yl-oxycarbonyl-phenylsulfonyl) -urea (oxasulfuron), 3- [1- (3,5-dichlorophenyl) - 1-i-propyl] -2,3-dihydro-6-methyl-5-phenyl-4H-1,3-oxazin-4-one (oxaziclomefone), 2-chloro-1- (3-ethoxy-4-nitro -phenoxy) -4-trifluoromethyl-benzene (oxyfluorfen), 1,1'-dimethyl-4,4'-bipyridinium (paraquat), 1-amino-N- (1-ethylpropyl) -3,4-dimethyl-2, 6-dinitro-benzene (pendimethalin), 4- (t-butyl) - N- (1-ethyl-propyl) -2,6-dinitro-benzenamine (pendralin), 3- (4-chloro-5-cyclopentyloxy-2 -fluorophenyl) -5- (1-methylethylidene) -2,4-oxazolidinedione (pentoxazone), 4-amino-3,5,6-trichloropyridine-2-carboxylic acid (picloram), N- (4-fluorophenyl) -6- (3-trifluoromethylphenoxy) pyridine-2-carboxamide (picolinafen), S- [2- (2-methyl-1-piperidinyl) -2-oxoethyl] -O, O -dipropyl-phosphorodithioate (Piperophos), 2-chloro-N- (2,6-diethyl-phenyl) -N- (2-propoxyethyl) -acetamide (pretilachlor), N- (4,6-bis-difluorometho xy-pyrimidin-2-yl) -N '- (2-methoxycarbonyl-phenylsulfonyl) urea (Primisulfuron-methyl), 1-chloro-N- [2-chloro-4-fluoro-5 - [(6S, 7aR) -6-fluoro-tetrahydro-1,3-dioxo-1 H-pyrrolo [1,2-c] imidazole-2 (3H) -yl] phenyl] methanesulfonamide (profluazole), 2-chloro-N-isopropyl -N-phenyl-acetamide (propachlor), N- (3,4-dichlorophenyl) propanamide (propanil), (R) - [2 - [[(1-methylethylidene) - amino] -oxy] -ethyl] -2- [4- (6-chloro-2-quinoxalinyloxy) phenoxy] propanoate (propaquizafop), 2-chloro-N- (2-ethyl-6-methylphenyl) -N - [(1-methyl- ethoxy) methyl] acetamide (propisochlor), 2 - [[[(4,5-dihydro-4-methyl-5-oxo-3-propoxy-1H-1,2,4-triazol-1-yl) - carbonyl] amino] sulfonyl] benzoic acid methyl ester sodium salt (propoxycarbazone sodium), S-phenylmethyl-N, N-dipropyl thiocarbamate (prosulfocarb), N- (4-methoxy-6-methyl-1,3,5- triazin-2-yl) -N '- (2- (3,3,3-trifluoropropyl) phenylsulfonyl) urea (prosulirone), ethyl [2-chloro-5- (4-chloro-5-difluoromethoxy-1 -methyl-1H-pyrazol-3-yl) -4-fluoro-phenoxy] - acetate (pyraflufen-ethyl), 1- (3-chloro-4, 5,6,7-tetrahydro-pyrazolo [1,5-a] pyridin-2-yl) -5- (methyl-2-propynylamino) -1H-pyrazole-4-carbonitrile (pyraclonil, pyrazogyl), 4- (2nd , 4-dichlorobenzoyl) -1,3-dimethyl-5- (4-methylphenylsulfonyloxy) pyrazole (pyrazolates), 4- (2,4-dichlorobenzoyl) -1,3-dimethyl-5- (phenylcarbonylmethoxy) -pyrazole (pyrazoxyfen), N- (4,6-dimethoxy-pyrimidin-2-yl) -N '- (4-ethoxycarbonyl-1-methyl-pyrazol-5-yl-sulfonyl) urea (pyrazosulfuron-ethyl), Diphenylmethanone-O- [2,6-bis- (4,6-dimethoxypyrimidin-2-yloxy) benzoyl] oxime (pyribenzoxime), O [3- (1,1-dimethylethyl) phenyl ] - (6-methoxy-2-pyridinyl) methylthiocarbamate (pyributicarb), 6-chloro-3-phenyl-4-pyridazinol (pyridafol), O- (6-chloro-3-phenyl-pyridazin-4-yl) - S-octyl-thiocarbonate (pyridate), 6-chloro-3-phenyl-pyridazin-4-ol (pyridatol), 7 - [(4,6-dimethoxy-2-pyrimidinyl) thio] -3-methyl-1 ( 3H) -isobenzofuranone (pyrifialide), 2- (4,6-dimethoxy-pyrimidin-2-yl-oxy) -benzoic acid methyl ester (pyriminobac-methyl), 2-chloro-6- (4,6-dimethoxy-pyrimidine- 2-ylthio) benzoic acid Natr Ium salt (pyrithiobacsodium), 3,7-dichloro-quinoline-8-carboxylic acid (Quinchlorac), 7-chloro-3-methyl-quinoline-8-carboxylic acid (Quimnerac), 2- [4- (6-chloro-2-quinoxalinyloxy ) -phenoxy] -propanoic acid (-ethyl ester, -tetrahydro-2-furanyl-methyl ester) (quizalofop, -ethyl, -P-ethyl, -P-tefuryl), N- (4,6-dimethoxy-pyrimidin-2-yl ) -N '- (3-ethylsulfonyl-pyridin-2-yl-sulfonyl) urea (rimsulfuron), 2- (1-ethoximinobutyl) -5- (2-ethylthiopropyl) -3-hydroxy-2-cyclohexen-1- on (Sethoxydim), 6-chloro-2,4-bisethylamino-1,3,5-triazine (simazine), 2- (2-chloro-4-methylsulfonylbenzoyl) -cyclohexane-1,3-dione (Sulcotrione), 2 - (2,4-dichloro-5-methylsulfonylamino-phenyl) -4-difluoromethyl-5-methyl-2,4-dihydro-3H-1,2,4-triazol-3-one (sulfentrazone), methyl 2- [ [[[((4,6-dimethyl-2-pyrimidinyl) amino] carbonyl] amino] sulfonyl] benzoates (sulfometuronmethyl), N-phosphonomethylglycine trimethyl sulfonium (sulfosates), N- (4,6- Dimethoxy-pyrimidin-2-yl) -N '- (2-ethylsulfonyl-imidazo [1,2-a] pyridine-3-sulfonamide (sulfosulfuron), 6-chloro-4-eth ylamino-2-tertbutylamino-1,3,5-triazine (terbuthylazine), 2-tert-butylamino-4-ethylamino-6-methylthio-1,3,5-triazine (terbutryn), 2-chloro-N- (2nd , 6-dimethyl-phenyl) -N- (3-methoxy-2-thienyl-methyl) -acetamide (thenylchlor), 2-difluoromethyl-5- (4,5-dihydro-thiazol-2-yl) -4- ( 2-methylpropyl) -6-trifluoromethyl-pyridine-3-carboxylic acid methyl ester (thiazopyr), 6- (6,7-dihydro-6,6-dimethyl-3H, 5H-pyrrolo [2,1-c] -1, 2,4-thiadiazol-3-ylidenamino) -7-fluoro-4- (2-propynyl) -2H-1,4-benzoxazin-3 (4H) - one (thidiazimin), N- (4-methoxy-6- methyl-1,3,5-triazin-2-yl) -N '- (2-methoxycarbonylthien-3-yl-sulfonyl) urea (thifensulfuronmethyl), 2- (ethoximino-propyl) -3-hydroxy-5 - (2,4,6-trimethylphenyl) -2-cyclohexen-1-one (tralkoxydim), S- (2,3,3-trichloro-2-propenyl) diisopropylcarbamothioate (triallate), N- (4-methoxy- 6-methyl-1,3,5-triazin-2-yl) -N '- [2- (2-chloroethoxy) phenylsulfonyl] urea (triasulfuron), N-methyl-N- (4-methoxy- 6-methyl-1,3,5-triazin-2-yl) -N '- (2-methoxycarbonylphenylsulfonyl) urea (tribenuron-methyl), (3,5,6-trichloro) pyridin-2-yloxy acetic acid (triclopyr), 2- (3,5-dichloro-phenyl) -2- (2,2,2-trichloroethyl) oxirane (Tridiphane), N - [[(4,6-dimethoxy-2-pyrimidinyl) amino] carbonyl] -3- (2,2,2-trifluoroethoxy) -2-pyridinesulfonamide sodium salt (trifloxysulfuron), 1 -Amino-2,6-dinitro-N, N-dipropyl-4-trifluoromethyl-benzene (trifluralin), N- [4-dimethylamino-6- (2,2,2-trifluoro-ethoxy) -1,3,5 - triazin-2-yl] -N '- (2-methoxycarbonylphenylsulfonyl) urea (triflusulfuron-methyl), N- (4-methoxy-6-trifluoromethoxy-1,3,5-triazin-2-yl) - N '- (2-trifluoromethyl-phenylsulfonyl) urea (tritosulfuron), N- [[(4,6-dimethoxy-2-pyrimidinyl) amino] carbonyl] -3- (N-methyl-N-methylsulfonylamino ]) - 2-pyridine sulfonamide, (cf. WO-A-92/10660), 4- [4,5-dihydro-4-methyl-5-oxo (3-trifluoromethyl) -1H-1,2,4-triazol-1-yl] -2- [ (ethylsulfonyl) amino] -5-fluorobenzenecarbothioamide (see WO-A-95/30661), phenylcarbothiamide-, 4- [4,5-dihydro-4-methyl-5-oxo-3- (trifluoromethyl) -1H-1 , 2,4-triazol-1-yl] -2 - [(ethylsulfonyl) amino] -5- fluoro- (CAS number 173980-17-1, HWH4991) and 2-chloro-N- [1- [2, 6-dichloro-4- (difluoromethyl) phenyl] -4-nitro-1H-pyrazol-5-yl] propanecarboxamide (CAS number 121750-17-2; SLA5599).
("Active substances of group 3"),
as well as, if necessary, additionally d) at least one compound which improves the tolerance of crop plants from the following group of compounds:
α- (1,3-Dioxolan-2-yl-methoximino) phenylacetonitrile (oxabetrinil), α- (cyanomethoximino) phenylacetonitrile (cyometrinil), 4-chloro-N- (1,3-dioxolan-2-yl-methoxy ) -α-trifluoro-acetophenone oxime (fluxofenim), 4,6-dichloro-2-phenylpyrimidine (fenclorim), 4-dichloroacetyl-3,4-dihydro-3-methyl-2H-1,4-benzoxazine (benoxacor), 5 Chloroquinoxaline-8-oxyacetic acid (1-methylhexyl ester) (Cloquintocet), 2,2-dichloro-N- (2-oxo-2- (2-propenylamino) ethyl) -N- (2-propenyl ) - acetamide (DKA-24), 1,8-naphthalic anhydride, 1- (2,4-dichlorophenyl) -5-trichloromethyl-1H-1,2,4-triazole-3-carboxylic acid ethyl ester (fenchlorazole-ethyl), 2-chloro-4-trifluoromethyl-thiazole-5-carboxylic acid phenylmethyl ester (flurazole), 3-dichloroacetyl-5- (2-furanyl) -2,2-dimethyl-oxazolidine (furilazole, MON-13900), 4-dichloroacetyl-1- oxa-4-aza-spiro [4.5] decane (AD-67), 2-dichloromethyl-2-methyl-1,3-dioxolane (MG-191), 2,2-dichloro-N- (1,3- dioxolan-2-yl-methyl) -N- (2-propenyl) -acetamide (PPG-1292), 2,2-dichloro-N, N-di-2-propenyl-acetamide (dichlormid), N - (4-methyl-phenyl) -N '- (1-methyl-1-phenylethyl) urea (Dymron), 1-dichloroacetyl-hexahydro-3,3,8-trimethylpyrrolo [1,2-a] pyrimidine - 6 (2H) -one (BAS-145138), N- (2-methoxy-benzoyl) -4- (methylaminocarbonylamino) benzenesulfonamide, ethyl 4,5-dihydro-5,5-diphenyl-3-isoxazolecarboxylate (isoxadifenethyl) , (4-Chloro-2-methylphenoxy) acetic acid (MCPA), 2- (4-chloro-2-methylphenoxy) propionic acid (Mecoprop), diethyl-1- (2,4-dichlorophenyl) -4,5-dihydro -5-methyl-1 H-pyrazole-3,5-dicarboxylate (mefenpyr-diethyl) and 2,4-dichlorophenoxyacetic acid (2,4-D) and its derivatives
("Active substances of group 4"). 2. Herbicidal compositions according to claim 1, characterized in that they contain a compound of the formula (I) as active ingredients in group 1,
in which
R for hydrogen or


stands where
R _{2 is} preferably hydrogen, chlorine, cyano, phenyl, C ₁ -C ₈ alkyl, methoxy, methylthio, C ₁ -C ₂ alkoxycarbonyl, propylaminocarbonyl, dimethylaminocarbonyl, benzylaminocarbonyl (the benzyl group being optionally substituted by chloro, methyl or methoxy ), 2'-phenylethylaminocarbonyl or furylmethylaminocarbonyl, and
R ₃ preferably represents phenyl optionally substituted by chlorine, fluorine, cyano, nitro, methyl, methoxy, ethoxy, butoxy, allyloxy, methylthio, dimethylamino, phenoxy, benzyloxy or acetoxy or -COR ₄ , where R _{4 represents} methoxy, ethoxy, Is methyl, benzyloxy or benzylamino,
A preferably represents chlorine or methoxy and
D and E, which may be the same or different, are preferably hydrogen, methoxy or ethoxy.
R ₂ particularly preferably represents hydrogen, methyl, methylthio, cyano, methoxycarbonyl or phenyl.
R ₃ particularly preferably represents phenyl optionally substituted by methyl or methoxy.
A particularly preferably represents methoxy.
D and E are particularly preferably methoxy.
R ₂ very particularly preferably represents phenyl.
R ₃ very particularly preferably represents phenyl. 3. Herbicidal composition according to claim 1 or 2, characterized in that it contains, as an active ingredient in group 3, one or more active ingredients from the following group of active ingredients:
4-amino-N- (1,1-dimethyl-ethyl) -4,5-dihydro-3- (1-methyl-ethyl) -5-oxo-1H-1,2,4-triazole-1-carboxamide ( Amicarbazones), N- (4,6-dimethoxypyrimidin-2-yl) -N '- (N-methyl-N-methylsulfonylsulfamoyl) urea (amidosulfuron), N-benzyl-2- (4-fluoro- 3-trifluoromethylphenoxy) butanamide (beflubutamide), 3-i-propyl-1H-2,1,3-benzothiadiazin-4 (3H) -one (bentazone), methyl-5- (2,4-dichlorophenoxy) ) -2-nitro-benzoate (bifenox), 3,5-dibromo-4-hydroxy-benzonitrile (bromoxynil), 2- (4-chloro-2-fluoro-5- (2-chloro-2-ethoxycarbonyl-ethyl) -phenyl) -4-difluoromethyl-5-methyl-2,4-dihydro-3H-1,2,4-triazol-3-one (Carfentrazone-ethyl), N- (4-methoxy-6-methyl-1, 3,5-triazin-2-yl) -N '- (2-chlorophenylsulfonyl) urea (chlorosulfuron), N' - (3-chloro-4-methylphenyl) -N, N-dimethylurea ( Chlorotoluron), 2-chloro-3- [2-chloro-5- (1,3,4,5,6,7-hexahydro-1,3-dioxo-2H-isoindol-2-yl) phenyl] -2 -propanoic acid ethyl ester (cinidon-ethyl), (R) - (2-propynyl) -2- [4- (5-chloro-3-fluoropyridin-2-yl-oxy) -phenoxy-propanoate (clodinafop-propargyl ), 3,6-dichloropyride in-2-carboxylic acid (clopyralide), 2,4-dichlorophenoxyacetic acid (2,4-D), 3,6-dichloro-2-methoxybenzoic acid (Dicamba), (R) -2- (2,4-dichloro- phenoxy) propanoic acid (dichloroprop-P), methyl 2- [4- (2,4-dichlorophenoxy) phenoxy] propanoate (diclofopmethyl), 1,2-dimethyl-3,5-diphenyl-1H-pyrazolium -methyl sulfate (difenzoquat), N- (2,4-difluorophenyl) -2- (3-trifluoromethyl-phenoxy) -pyridine-3-carboxamide (diflufenican), N- (4,6-dimethoxy-pyrimidine-2- yl) -N '- (2-ethoxy-phenoxysulfonyl) urea (ethoxysulfuron), (R) -ethyl-2- [4- (6-chloro-benzoxazol-2-yl-oxy) phenoxy] propanoate (fenoxaprop - (P) -ethyl), 4- (2-chlorophenyl) -N-cyclohexyl-N-ethyl-4,5-dihydro-5-oxo-1H-tetrazole-1-carboxamide (fentrazamide), isopropyl-N -benzoyl-N- (3-chloro-4-fluro-phenyl) -DL-alaninate (Flamprop-isopropyl), isopropyl-N-benzoyl-N- (3-chloro-4-fluro-phenyl) -L-alaninate ( Flamprop-isopropyl-L), methyl-N-benzoyl-N- (3-chloro-4-fluorophenoxy) - DL-alaninate (Flamprop-methyl), N- (2,6-difluorophenyl) -8- fluoro-5-methoxy- [1,2,4] triazolo- [1,5-c] pyrimidine-2 -sulfonamide (florasulam), 5- (4-bromo-1-methyl-5-trifluoromethyl-1H-pyrazol-3-yl) -2-chloro-4-fluoro-benzoic acid i-propyl ester (fluazolates), 4.5 -Dihydro-3-methoxy-4-methyl-5-oxo-N - [(2-trifluoromethoxyphenyl) sulfonyl] -1-H-1,2,4-triazole-1-carboxamide sodium salt (Flucarbazone-sodium ), N- (4-fluorophenyl) -Ni-propyl-2- (5-trifluoromethyl-1,3,4-thiadiazol-2-yl-oxy) -acetamide (flufenacet), 5- (2-chloro 4-trifluoromethylphenoxy) -2-nitro-benzoic acid ethoxycarbonylmethyl ester (fluoroglycofenethyl), N- (4,6-dimethoxy-pyrimidin-2-yl) -N '- (3-methoxycarbonyl-6-trifluoromethyl-pyridin-2-yl- sulfonyl) urea sodium salt (flupyrsulfuron-methylsodium), (4-amino-3,5-dichloro-6-fluoropyridin-2-yl-oxy) -acetic acid (-2-butoxy-1-methyl-ethyl ester, - 1-methyl-heptyl ester) (fluroxypyr, -butoxypropyl, -meptyl), 5-methylamino-2-phenyl-4- (3-trifluoromethyl-phenyl) -3 (2H) - furanone (flurtamone), 2-amino-4- (hydroxymethylphosphinyl) butanoic acid (ammonium salt) (glufosinate (ammonium)), N-phosphonomethylglycine (isopropylammmon ium salt), (glyphosate, isopropylammonium), methyl 2- (4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl) -4-methyl-benzoate (imazamethabenz- methyl), 2- (4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl) -5-methyl-pyridine-3-carboxylic acid (imazamethapyr), 2- (4th , 5-Dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl) -5-methoxymethylpyridine-3-carboxylic acid (imazamox), 2- (4,5-dihydro-4-methyl- 4-isopropyl-5-oxo-1H-imidazol-2-yl) -quinoline-3-carboxylic acid (imazaquine), 2- (4,5-dihydro-4-methyl-4-i-propyl-5-oxo-1H -imidazol-2-yl) -5-ethyl-pyridine-3-carboxylic acid (imazethapyr), N- (4-methoxy-6-methyl-1,3,5-triazin-2-yl) -N '- (5 -iodo-2-methoxycarbonyl-phenylsulfonyl) urea sodium salt (iodosulfuronmethyl-sodium), 4-hydroxy-3,5-diiodobenzonitrile (ioxynil), N, N-dimethyl-N '- (4-isopropylphenyl) urea (isoproturon), N- (3- (1-ethyl-1-methylpropyl) isoxazol-5-yl) -2,6-dimethoxybenzamide (isoxaben), (4-chloro-2-methylsulfonylphenyl) - (5-cyclopropyl-isoxazol-4-yl) -methanone (isoxachlorotole), (5-cy clopropyl-isoxazol-4-yl) - (2-methylsulfonyl-4-trifluoromethylphenyl) methanone (isoxaflutole), (4-chloro-2-methylphenoxy) acetic acid (MCPA), 2- (4-chloro-2- methyl-phenoxy) -propionic acid (mecoprop), 2- (2-benzothiazolyloxy) -N-methyl-N-phenyl-acetamide (Mefenacet), 2 - [[[((4,6-dimethoxy-2-pyrimidinyl) amino ] -carbonyl] -amino] -sulfonyl] -4 - [[(methylsulfonyl) -amino] methyl] -benzoic acid methyl ester (mesosulfuron), 4-amino-3-methyl-6-phenyl-1,2,4-triazine -5 (4H) -one (metamitron), N- (2,6-dichloro-3-methylphenyl) -5,7-dimethoxy-1,2,4-triazolo [1,5-a] pyrimidine - 2-sulfonamide (metosulam), 4-amino-6-tert-butyl-3-methylthio-1,2,4-triazin-5 (4H) -one (metribuzin), N- (4-methoxy-6-methyl- 1,3,5-triazin-2-yl) -N '- (2-methoxycarbonylphenylsulfonyl) urea (metsulfuron-methyl), 1-amino-N- (1-ethyl-propyl) -3,4-dimethyl -2,6-dinitro-benzene (pendimethalin), N- (4-fluorophenyl) -6- (3-trifluoromethyl-phenoxy) -pyridine-2-carboxamide (picolinafen), N- (3,4-dichlorophenyl) -propanamide (propanil), ethyl- [2-chloro-5- (4-chloro-5-difluorom ethoxy-1-methyl-1H-pyrazol-3-yl) -4-fluorophenoxy] acetate (pyraflufen-ethyl), 2- (2-chloro-4-methylsulfonyl-benzoyl) cyclohexane-1,3-dione (Sulcotrione), N-phosphonomethyl-glycine trimethylsulfonium (sulfosate), N- (4,6-dimethoxypyrimidin-2-yl) -N '- (2-ethylsulfonylimidazo [1,2-a] pyridine-3 -sulfonamide (sulfosulfuron), N- (4-methoxy-6-methyl-1,3,5-triazin-2-yl) -N'- (2-methoxycarbonylthien-3-yl-sulfonyl) urea (thifensulfuron -methyl), 2- (ethoximino-propyl) -3-hydroxy-5- (2,4,6-trimethyl-phenyl) -2-cyclohexen- 1-one (tralkoxydim), S- (2,3,3- Trichloro-2-propenyl) diisopropyl carbamothioate (triallate), N- (4-methoxy-6-methyl-1,3,5-triazin-2-yl) -N '- [2- (2-chloroethoxy) phenylsulfonyl] urea (triasulfuron), N-methyl-N- (4-methoxy-6-methyl-1,3,5-triazin-2-yl) -N '- (2-methoxycarbonyl-phenylsulfonyl) urea (tribenuron-methyl ), 1-Amino-2,6-dinitro-N, N-dipropyl-4-trifluoromethylbenzene (trifluralin), N- (4-methoxy-6-trifluoromethoxy-1,3,5-triazin-2-yl) -N '- (2-trifluoromethyl-phenylsulfonyl) urea (Tritos sulfuron), phenylcarbothiamide-, 4- [4,5-dihydro-4-methyl-5-oxo-3- (trifluoromethyl) -1H-1,2,4-triazol-1-yl] -2 - [(ethylsulfonyl) amino] -5-fluoro- (CAS number 173980-17-1, HWH4991) and (2-chloro-N- [1- [2,6-dichloro-4- (difluoromethyl) phenyl] -4-nitro-1H -pyrazol-5-yl] -propane carboxamide (CAS number 121750-17-2; SLA5599). 4. Herbicidal composition according to one of claims 1 to 3, characterized in that it contains, as active ingredient of group 3, one or more active ingredients from one or more of the following groups of active ingredients: a) Sulfonylureas:
N- (4,6-Dimethoxypyrimidin-2-yl) -N '- (N-methyl-N-methylsulfonylsulfamoyl) urea (amidosulfuron), N- (4-methoxy-6-methyl-1,3,5 - triazin-2-yl) -N '- (2-chlorophenylsulfonyl) urea (chlorosulfuron), N- (4,6-dimethoxypyrimidin-2-yl) -N' - (3-methoxycarbonyl-6- trifluoromethyl-pyridin-2-yl-sulfonyl) urea sodium salt (flupyrsulfitronmethyl-sodium), N- (4-methoxy-6-methyl-1,3,5-triazin-2-yl) -N '- (5- iodo-2-methoxycarbonyl-phenylsulfonyl) urea sodium salt (iodosulfuron-methyl-sodium), 2 - [[[[((4,6-dimethoxy-2-pyrimidinyl) - amino] carbonyl] amino] sulfonyl] - 4 - [[(methylsulfonyl) amino] methyl] benzoic acid methyl ester (mesosulfuron), N- (4-methoxy-6-methyl-1,3,5-triazin-2-yl) -N '- (2nd -methoxycarbonyl-phenylsulfonyl) - urea (metsulfuron-methyl), N- (4,6-dimethoxy-pyrimidin-2-yl) - N '- (2-ethylsulfonyl-imidazo [1,2-a] pyridine-3-sulfonamide (Sulfosulfuron), N- (4-methoxy-6-methyl-1,3,5-triazin-2-yl) -N '- (2-methoxycarbonylthien-3-yl-sulfonyl) urea (thifensulfuron- methyl), N- (4-methoxy-6-methyl-1 , 3,5-triazin-2-yl) -N '- [2- (2-chloroethoxy) phenylsulfonyl] urea (triasulfuron), N-methyl-N- (4-methoxy-6-methyl-1 , 3,5-triazin-2-yl) -N '- (2-methoxycarbonyl-phenylsulfonyl) urea (tribenuron-methyl), N- (4-methoxy-6-trifluoromethoxy-1,3,5-triazin-2 -yl) -N '- (2-trifluoromethyl-phenylsulfonyl) urea (tritosulfuron), b) Triazolopyrimidines:
N- (2,6-difluorophenyl) -8-fluoro-5-methoxy- [1,2,4] -triazolo- [1,5-c] pyrimidine-2-sulfonamide (florasulam), N- ( 2,6-dichloro-3-methylphenyl) -5,7-dimethoxy-1,2,4-triazolo [1,5-a] pyrimidine-2-sulfonamide (metosulam), c) Imidazolinones:
Methyl 2- (4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl) -4-methyl-benzoate (imazamethabenz-methyl), 2- (4,5- Dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl) -5-methyl-pyridine-3-carboxylic acid (imazamethapyr), 2- (4,5-dihydro-4-methyl-4 -isopropyl-5-oxo-1H-imidazol-2-yl) -5-methoxymethyl-pyridine-3-carboxylic acid (imazamox), 2- (4,5-dihydro-4-methyl-4-isopropyl-5-oxo 1H-imidazol-2-yl) -quinolin-3-carboxylic acid (imazaquin), 2- (4,5-dihydro-4-methyl-4-i-propyl-5-oxo-1H-imidazol-2-yl) - 5-ethyl-pyridine-3-carboxylic acid (imazethapyr), d) ureas:
N '- (3-chloro-4-methyl-phenyl) -N, N-dimethyl-urea (chlorotoluron), N, N-dimethyl-N' - (4-isopropyl-phenyl) -urea (isoproturon), e) Triazinediones:
4-amino-6-tert-butyl-3-methylthio-1,2,4-triazin-5 (4H) -one (metribuzin), f) Triketones:
2- (2-chloro-4-methylsulfonyl-benzoyl) cyclohexane-1,3-dione (sulcotrione), g) triazolinones:
2- (4-chloro-2-fluoro-5- (2-chloro-2-ethoxycarbonyl-ethyl) -phenyl) -4-difluoromethyl-5-methyl-2,4-dihydro-3H-1,2,4- triazol-3-one (carfentrazone-ethyl), phenylcarbothiamid-, 4- [4,5-dihydro-4-methyl-5-oxo-3- (trifluoromethyl) -1H-1,2,4-triazol-1-yl ] -2 - [(ethylsulfonyl) amino] -5- fluoro- (CAS number 173980-17-1, HWH4991), h) Benzonitrile:
3,5-dibromo-4-hydroxy-benzonitrile (bromoxynil), 4-hydroxy-3,5-diiodobenzonitrile (ioxynil), i) Phenoxypropionic acid derivatives:
(R) - (2-propynyl) -2- [4- (5-chloro-3-fluoropyridin-2-yl-oxy) phenoxypropanoate (clodinafop-propargyl), methyl 2- [4- ( 2,4-dichlorophenoxy) phenoxy] propanoate (diclofop-methyl), (R) -ethyl-2- [4- (6-chloro-benzoxazol-2-yl-oxy) phenoxy] propanoate (fenoxaprop - (P) -ethyl), j) dichlorophenoxyacid derivatives:
2,4-dichlorophenoxyacetic acid (2,4-D), (®2- (2,4-dichlorophenoxy) propanoic acid (dichloroprop-P), (4-chloro-2-methylphenoxy) acetic acid ( MCPA), 2- (4-chloro-2-methylphenoxy) propionic acid (mecoprop), k) carboxamides:
N- (2,4-difluorophenyl) -2- (3-trifluoromethylphenoxy) pyridine-3-carboxamide (diflufenican), N- (4-fluorophenyl) -6- (3-trifluoromethylphenoxy) -pyridine-2-carboxamide (picolinafen), l) oxyacetamides:
N- (4-fluoro-phenyl) -Ni-propyl-2- (5-trifluoromethyl-1,3,4-thiadiazol-2-yl-oxy) -acetamide (flufenacet),
(2-Chloro-N- [1- [2,6-dichloro-4- (difluoromethyl) phenyl] -4-nitro-1H-pyrazol-5-yl] propane carboxamide (CAS number 121750-12-2; SLA5599 )
Methyl 5- (2,4-dichlorophenoxy) -2-nitro-benzoate (bifenox),
2-chloro-3- [2-chloro-5- (1,3,4,5,6,7-hexahydro-1,3-dioxo-2H-isoindol-2-yl) phenyl] -2-propanoic acid ethyl ester (cinidon-ethyl),
(4-amino-3,5-dichloro-6-fluoropyridin-2-yl-oxy) -acetic acid (-2-butoxy-1-methyl-ethyl ester, -1-methyl-heptyl ester) (fluroxypyr, -butoxypropyl, -meptyl), 2-amino-4- (hydroxymethylphosphinyl) -butanoic acid (-ammonium salt) (glufosinate (-ammonium)), N-phosphonomethyl-glycine (-isopropylammmonium salt), (glyphosate, -isopropylammonium) or N-phosphonomethyl-glycine- trimethylsulfonium (sulfosates). 5. Herbicidal composition according to one of claims 1 to 4, characterized in that it contains, as active ingredient in group 4, one or more active ingredients in the following group of active ingredients:
5-chloro-quinoxaline-8-oxyacetic acid (1-methylhexyl ester) (cloquintocet), 1- (2,4-dichlorophenyl) -5-trichloromethyl-1H-1,2,4-triazole-3-carboxylic acid ethyl ester (fenchlorazole-ethyl), ethyl 4,5-dihydro-5,5-diphenyl-3-isoxazolecarboxylate (isoxadifen-ethyl), (4-chloro-2-methylphenoxy) acetic acid (MCPA), 2- (4th Chloro-2-methylphenoxy) propionic acid (mecoprop), diethyl 1- (2,4-dichlorophenyl) -4,5-dihydro-5-methyl-1H-pyrazole-3,5-dicarboxylate (mefenpyrdiethyl) and 2, 4-dichlorophenoxyacetic acid (2,4-D) and its derivatives. 6. Herbicidal compositions according to one of claims 1 to 5, characterized in that they a) at least one phenoxypyrimidine derivative from the following group of compounds
2,6-bis [(4,6-dimethoxy-2-pyrimidinyl) oxy] benzoate (sodium), (bispyribac-sodium, KIH 2023) of the formula


or
Diphenylmethanone-O- [2,6-bis [(4,6-dimethoxy-2-pyrimidinyl) oxy] benzoyl] oxime (pyribenzoxime) of the formula


b) the compound methyl-2 - [[((4,5-dihydro-4-methyl-5-oxo-3-propoxy-1H-1,2,4-triazol-1-yl) carbonyl] amino] sulfonyl] -benzoic acid, sodium salt (Propoxycarbazone-sodium) of the formula


such as c) at least one active ingredient of group 3 according to one of claims 1 to 4,
and if necessary d) comprise at least one compound of group 4 according to claim 1 or 5 which improves the tolerance of crop plants. 7. Herbicidal agent according to one of claims 1 to 6, characterized in that it a) 2,6-bis [(4,6-dimethoxy-2-pyrimidinyl) oxy) benzoate (sodium), (bispyribac-sodium) of the formula


and b) Methyl 2 - [[[(4,5-dihydro-4-methyl-5-oxo-3-propoxy-1H-1,2,4-triazol-1-yl) carbonyl] amino] sulfonyl] benzoic acid , Sodium salt (Propoxycarbazone-sodium) of the formula


such as c) at least one further compound selected from the following group of compounds (“active substances of group 3”): a) Sulfonylureas:
N- (4,6-Dimethoxypyrimidin-2-yl) -N '- (N-methyl-N-methylsulfonylsulfamoyl) urea (amidosulfuron), N- (4-methoxy-6-methyl-1,3,5 - triazin-2-yl) -N '- (2-methoxycarbonyl-phenylsulfonyl) urea (metsulfuron-methyl), N-methyl-N- (4-methoxy-6-methyl-1,3,5-triazin-2 - yl) -N '- (2-methoxycarbonylphenylsulfonyl) urea (tribenuronmethyl), N- (4-methoxy-6-trifluoromethoxy-1,3,5-triazin-2-yl) -N' - (2- trifluoromethyl-phenylsulfonyl) urea (tritosulfuron), b) Triazolopyrimidines:
N- (2,6-difluorophenyl) -8-fluoro-5-methoxy- [1,2,4] -triazolo- [1,5-c] pyrimidine-2-sulfonamide (florasulam), N- ( 2,6-dichloro-3-methylphenyl) -5,7-dimethoxy-1,2,4-triazolo [1,5-a] pyrimidine-2-sulfonamide (metosulam), c) Imidazolinones:
2- (4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1 H -imidazol-2-yl) -5-methoxymethyl-pyridine-3-carboxylic acid (imazamox), d) ureas:
N, N-dimethyl-N '- (4-isopropylphenyl) urea (isoproturon), e) Triazinediones:
4-amino-6-tert-butyl-3-methylthio-1,2,4-triazin-5 (4H) -one (metribuzin), f) Triketones:
2- (2-chloro-4-methylsulfonyl-benzoyl) cyclohexane-1,3-dione (sulcotrione), g) triazolinones:
Benzenecarbothiamid-, 4- [4,5-dihydro-4-methyl-5-oxo-3- (trifluoromethyl) -1H-1,2,4-triazol-1-yl] -2 - [(ethylsulfonyl) amino] - 5-fluoro- (CAS 173980-17-1, HWH4991), (2-Chloro-N- [1- [2,6-dichloro-4- (difluoromethyl) phenyl] -4-nitro-1H-pyrazol-5-yl] propane carboxamide (CAS number 121750-17-2; SLA 5599),
Methyl 5- (2,4-dichlorophenoxy) -2-nitro-benzoate (bifenox), and
(4-amino-3,5-dichloro-6-fluoropyridin-2-yl-oxy) -acetic acid (-2-butoxy-1-methyl-ethyl ester, -1-methyl-heptyl ester) (fluroxypyr, -butoxypropyl, -meptyl)
and if necessary d) at least one of the group 4 compounds which improve crop plant tolerance and are mentioned in claim 1 or 5 include. 8. Herbicidal agent according to one of claims 1 to 7, characterized in that they are active as group 4 MCPA or Contain 2,4-dichlorophenoxyacetic acid (2,4-D) and its derivatives. 9. Herbicidal composition according to one of claims 1 to 8, characterized in that it is an active ingredient in group 1
2,6-bis [4,6-dimethoxy-2-pyrimidinyl) oxy] benzoate (sodium) (bispyribacsodium)
contain. 10. Herbicidal agent according to one of claims 1 to 9, characterized in that it is an active ingredient of group 2
Methyl 2 - [[[(4,5-dihydihydro-4-methyl-5-oxo-3-propoxy-1H-1,2,4-triazol-1-yl) carbonyl] amino] sulfonyl] benzoic acid, sodium Salt (propoxycarbazone sodium
contain. 11. Herbicidal agent according to one of claims 1 to 8, characterized characterized that 1 part by weight of active ingredient of group 1 or its Salts 0.001 to 1000 parts by weight of the active ingredients of group 2 and 3 omitted. 12. Herbicidal agents according to one of claims 1 to 8, characterized characterized that 1 part by weight of active ingredient of group 1 or its Salts 0.1 to 1 part by weight of the active ingredients of groups 2 and 3 eliminated. 13. Use of an agent according to one of claims 1 to 12 for Control of unwanted plants. 14. Process for combating undesirable plants, thereby characterized in that agents according to any one of claims 1 to 12 unwanted plants and / or their habitat can act.