DE1002899B - Color paste for pens and stamping devices - Google Patents
Color paste for pens and stamping devicesInfo
- Publication number
- DE1002899B DE1002899B DEZ2813A DEZ0002813A DE1002899B DE 1002899 B DE1002899 B DE 1002899B DE Z2813 A DEZ2813 A DE Z2813A DE Z0002813 A DEZ0002813 A DE Z0002813A DE 1002899 B DE1002899 B DE 1002899B
- Authority
- DE
- Germany
- Prior art keywords
- color paste
- pens
- stamping devices
- color
- fats
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims description 2
- 238000009835 boiling Methods 0.000 claims description 2
- 229920000151 polyglycol Polymers 0.000 claims description 2
- 239000010695 polyglycol Substances 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 230000002378 acidificating effect Effects 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 235000014593 oils and fats Nutrition 0.000 claims 1
- 229920000515 polycarbonate Polymers 0.000 claims 1
- 239000004417 polycarbonate Substances 0.000 claims 1
- 239000003925 fat Substances 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical compound O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229920001568 phenolic resin Polymers 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- 210000004243 sweat Anatomy 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- 208000008454 Hyperhidrosis Diseases 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 150000001241 acetals Chemical class 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 230000001066 destructive effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 208000013460 sweaty Diseases 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 150000003628 tricarboxylic acids Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/16—Writing inks
- C09D11/18—Writing inks specially adapted for ball-point writing instruments
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Description
Farbpaste für Kugelschreiber und Stempelgeräte Farbpasten für Kugelschreiber und Stempelgeräte müssen rasch trocknen, gut in das Papier eindringen, ohne in die Faser auszulaufen, nicht herauslösbar und dadurch übertragbar bzw. nicht kopierbar sein. Dies gilt insbesondere bei Berührung mit Hautschweiß, Ölen, Fetten oder langkettige:n aliphatischen Carbonsäuren. Die Paste soll lichtecht und gegenüber zerstörenden Chemikalien, z. B. Chlorwasser, Wasserstoffsuperoxyd. und Salpetersäure, unangreifbar sein. Der Schriftsatz -soll auch bei verhältnismäßig geringem Druck und mit feiner Strichlinie vollständig geschlossen und ohne Abrisse sein, kleinste Schriftzeichen und neben einem normalen dicken Strich auch Haarstriche gestatten.Color paste for ballpoint pens and stamping devices Color paste for ballpoint pens and stamping devices must dry quickly, penetrate the paper well without getting into the Fiber to run out, not detachable and therefore transferable or not copiable be. This applies in particular to contact with skin sweat, oils, fats or long-chain: n aliphatic carboxylic acids. The paste is said to be lightfast and opposed to destructive Chemicals e.g. B. chlorinated water, hydrogen peroxide. and nitric acid, invulnerable be. The brief - should also with relatively little pressure and with fine The dashed line must be completely closed and without breaks, the smallest characters and allow hairlines in addition to a normal thick line.
Diese Erfordernisse werden durch die bisherigen Pasten auf der Grundlage von aliphatischer Ölsäure, Rizinusöl und Farbbasen nur genügend oder gar nicht erfüllt.These requirements are based on the past pastes aliphatic oleic acid, castor oil and color bases only sufficiently or not at all.
Die erfindungsgemäße. Farbpaste enthält eine mit schwerlöslichen aromatischen Carbon- oder Polycarbo:nsäuren stöchiometrisch durch Erhitzen in Wasser umgesetzte Farbbase, z. B. Viktoriablaubase, in hochsiedenden Lösungsmitteln geringer Flüchtigkeit, wie höheren Alkoholen bzw.. deren Polymerisationsprodukten oder ihren Estern, Äthern oder Acetalen, die weitgehend unverträglich gegen Öl, Fett oder Hautschweiß sind.The inventive. Color paste contains a color base which is stoichiometrically reacted with sparingly soluble aromatic carboxylic or polycarbonic acids by heating in water, e.g. B. Viktoriablaubase, in high-boiling solvents of low volatility, such as higher alcohols or .. their polymerization products or their esters, ethers or acetals, which are largely incompatible with oil, fat or sweat.
Allenfalls erforderliche Verdickungsmittel, wie Phenolformaldehydkondensationsprodukte, werden beigefügt, um die richtige Viskosität zu sichern.Any necessary thickeners, such as phenol-formaldehyde condensation products, are included to ensure proper viscosity.
Beispiel 15 Gewichtsteile eines aus Viktoriablaubase mit Benzoesäure durch Erhitzen in Wasser erhaltenen Umsetzungsproduktes werden in 50 Gewichtsteilen Polyglykol unter Zusatz von 30 Gewichtsteilen. PhenolformaIdehydkondensat in der Hitze unter Rühren gelöst. Die erforderliche Viskosität wird durch Zugabe von etwa 5 % Dimethylacetamid eingestellt.Example 15 parts by weight of one made from Victoria fab base with benzoic acid reaction product obtained by heating in water are in 50 parts by weight Polyglycol with the addition of 30 parts by weight. Phenolformaldehyde condensate in the Heat dissolved with stirring. The required viscosity is achieved by adding about 5% dimethylacetamide adjusted.
Man kann auch mit Salicylsiäure, Phthalsäure oder einer Tricarbonsäure umgesetzte Farbbasen verwenden.One can also use salicylic acid, phthalic acid or a tricarboxylic acid use converted color bases.
Die Farbpaste nach der Erfindung dringt gut in das Papier ein, ohne in die Faser auszufließen. Sie kann nicht durch schweißige Finger oder Handballen übertragen werden, desgleichen nicht durch Öle oder Fette. Auch die bekannte Übertragung mittels eines hartgekochten Eies, wie es bei normalen Stempelfarben, durchaus möglich ist, gelingt nicht. Der Strich ist sofort trocken und wischfest. Die Schrift bleibt auch bei intensiver Bestrahlung voll erhalten, während bei bekannten Kugelschreiberpasten die Schrift bereits völlig verbl.aßt bzw. ganz verschwunden ist.The color paste according to the invention penetrates well into the paper without to flow out into the fiber. You can't get through sweaty fingers or the ball of your hand transferred, likewise not through oils or fats. Also the well-known transmission using a hard-boiled egg, as is the case with normal stamp inks, is quite possible is, does not succeed. The line is immediately dry and smudge-proof. The writing remains fully preserved even with intensive irradiation, while with known ballpoint pen pastes the writing has already completely faded or has completely disappeared.
Claims (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEZ2813A DE1002899B (en) | 1952-07-15 | 1952-07-15 | Color paste for pens and stamping devices |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEZ2813A DE1002899B (en) | 1952-07-15 | 1952-07-15 | Color paste for pens and stamping devices |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1002899B true DE1002899B (en) | 1957-02-21 |
Family
ID=7618653
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DEZ2813A Pending DE1002899B (en) | 1952-07-15 | 1952-07-15 | Color paste for pens and stamping devices |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE1002899B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1266719B (en) * | 1962-03-29 | 1968-04-25 | Basf Ag | Stable, highly concentrated solutions of basic dyes |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE356120C (en) * | 1917-09-19 | 1922-07-17 | Carlo Molar Dr | Process for the production of a concentrated liquid ink |
| US2141965A (en) * | 1938-11-01 | 1938-12-27 | Aronberg Lester | Marking material |
| GB621847A (en) * | 1945-07-28 | 1949-04-21 | Henry George Martin | A new or improved writing or marking fluid |
-
1952
- 1952-07-15 DE DEZ2813A patent/DE1002899B/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE356120C (en) * | 1917-09-19 | 1922-07-17 | Carlo Molar Dr | Process for the production of a concentrated liquid ink |
| US2141965A (en) * | 1938-11-01 | 1938-12-27 | Aronberg Lester | Marking material |
| GB621847A (en) * | 1945-07-28 | 1949-04-21 | Henry George Martin | A new or improved writing or marking fluid |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1266719B (en) * | 1962-03-29 | 1968-04-25 | Basf Ag | Stable, highly concentrated solutions of basic dyes |
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