DD277829A1 - MEANS TO INCREASE THE TOLERANCE OF CULTURAL PLANTS AGAINST CHEMICAL STRESSORS - Google Patents
MEANS TO INCREASE THE TOLERANCE OF CULTURAL PLANTS AGAINST CHEMICAL STRESSORS Download PDFInfo
- Publication number
- DD277829A1 DD277829A1 DD32304788A DD32304788A DD277829A1 DD 277829 A1 DD277829 A1 DD 277829A1 DD 32304788 A DD32304788 A DD 32304788A DD 32304788 A DD32304788 A DD 32304788A DD 277829 A1 DD277829 A1 DD 277829A1
- Authority
- DD
- German Democratic Republic
- Prior art keywords
- side effects
- tolerance
- fungicides
- formula
- growth regulators
- Prior art date
Links
- 239000000126 substance Substances 0.000 title claims abstract description 12
- 230000000694 effects Effects 0.000 claims abstract description 20
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000003630 growth substance Substances 0.000 claims abstract description 14
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 13
- 239000000417 fungicide Substances 0.000 claims abstract description 11
- 239000000203 mixture Substances 0.000 claims abstract description 7
- 244000038559 crop plants Species 0.000 claims abstract description 6
- 150000002169 ethanolamines Chemical class 0.000 claims abstract description 6
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000002253 acid Substances 0.000 claims abstract description 3
- 239000004480 active ingredient Substances 0.000 claims abstract description 3
- 239000012458 free base Substances 0.000 claims abstract description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 3
- 239000011707 mineral Substances 0.000 claims abstract description 3
- 150000003839 salts Chemical class 0.000 claims abstract description 3
- JUZXDNPBRPUIOR-UHFFFAOYSA-N chlormequat Chemical compound C[N+](C)(C)CCCl JUZXDNPBRPUIOR-UHFFFAOYSA-N 0.000 claims description 12
- 150000003852 triazoles Chemical class 0.000 claims description 10
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 claims description 6
- OEYIOHPDSNJKLS-UHFFFAOYSA-N choline Chemical compound C[N+](C)(C)CCO OEYIOHPDSNJKLS-UHFFFAOYSA-N 0.000 claims description 3
- 229960001231 choline Drugs 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- -1 Chlorethylphosphonat- and triazole Chemical compound 0.000 claims description 2
- 239000005574 MCPA Substances 0.000 claims description 2
- WHKUVVPPKQRRBV-UHFFFAOYSA-N Trasan Chemical compound CC1=CC(Cl)=CC=C1OCC(O)=O WHKUVVPPKQRRBV-UHFFFAOYSA-N 0.000 claims description 2
- 230000003115 biocidal effect Effects 0.000 claims description 2
- 239000000969 carrier Substances 0.000 claims description 2
- 239000007954 growth retardant Substances 0.000 claims description 2
- 230000000116 mitigating effect Effects 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- 230000003449 preventive effect Effects 0.000 claims description 2
- 239000000654 additive Substances 0.000 claims 3
- 239000000729 antidote Substances 0.000 claims 2
- 239000000575 pesticide Substances 0.000 claims 2
- KZDCLQBOHGBWOI-UHFFFAOYSA-N 2-(2,4,6-trichlorophenoxy)acetic acid Chemical compound OC(=O)COC1=C(Cl)C=C(Cl)C=C1Cl KZDCLQBOHGBWOI-UHFFFAOYSA-N 0.000 claims 1
- 239000003638 chemical reducing agent Substances 0.000 claims 1
- UHZZMRAGKVHANO-UHFFFAOYSA-M chlormequat chloride Chemical compound [Cl-].C[N+](C)(C)CCCl UHZZMRAGKVHANO-UHFFFAOYSA-M 0.000 claims 1
- 230000008030 elimination Effects 0.000 claims 1
- 238000003379 elimination reaction Methods 0.000 claims 1
- 230000009931 harmful effect Effects 0.000 claims 1
- 239000004009 herbicide Substances 0.000 claims 1
- 239000000546 pharmaceutical excipient Substances 0.000 claims 1
- 239000000047 product Substances 0.000 claims 1
- 239000013589 supplement Substances 0.000 claims 1
- 241000209140 Triticum Species 0.000 description 8
- 235000021307 Triticum Nutrition 0.000 description 7
- UDPGUMQDCGORJQ-UHFFFAOYSA-N (2-chloroethyl)phosphonic acid Chemical compound OP(O)(=O)CCCl UDPGUMQDCGORJQ-UHFFFAOYSA-N 0.000 description 5
- 241000219310 Beta vulgaris subsp. vulgaris Species 0.000 description 5
- 241000209219 Hordeum Species 0.000 description 5
- 235000007340 Hordeum vulgare Nutrition 0.000 description 5
- 235000013339 cereals Nutrition 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 235000021536 Sugar beet Nutrition 0.000 description 4
- 238000004690 coupled electron pair approximation Methods 0.000 description 4
- 239000005822 Propiconazole Substances 0.000 description 3
- STJLVHWMYQXCPB-UHFFFAOYSA-N propiconazole Chemical compound O1C(CCC)COC1(C=1C(=CC(Cl)=CC=1)Cl)CN1N=CN=C1 STJLVHWMYQXCPB-UHFFFAOYSA-N 0.000 description 3
- 239000002028 Biomass Substances 0.000 description 2
- TWFZGCMQGLPBSX-UHFFFAOYSA-N Carbendazim Natural products C1=CC=C2NC(NC(=O)OC)=NC2=C1 TWFZGCMQGLPBSX-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000006013 carbendazim Substances 0.000 description 2
- JNPZQRQPIHJYNM-UHFFFAOYSA-N carbendazim Chemical compound C1=C[CH]C2=NC(NC(=O)OC)=NC2=C1 JNPZQRQPIHJYNM-UHFFFAOYSA-N 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- WHTVZRBIWZFKQO-AWEZNQCLSA-N (S)-chloroquine Chemical compound ClC1=CC=C2C(N[C@@H](C)CCCN(CC)CC)=CC=NC2=C1 WHTVZRBIWZFKQO-AWEZNQCLSA-N 0.000 description 1
- ANHAEBWRQNIPEV-UHFFFAOYSA-N 2-chloroethyl dihydrogen phosphate Chemical compound OP(O)(=O)OCCCl ANHAEBWRQNIPEV-UHFFFAOYSA-N 0.000 description 1
- 241001504630 Alcedo Species 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000002238 attenuated effect Effects 0.000 description 1
- 229960003677 chloroquine Drugs 0.000 description 1
- WHTVZRBIWZFKQO-UHFFFAOYSA-N chloroquine Natural products ClC1=CC=C2C(NC(C)CCCN(CC)CC)=CC=NC2=C1 WHTVZRBIWZFKQO-UHFFFAOYSA-N 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000002538 fungal effect Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Die Erfindung betrifft Mittel zur Erhoehung der Toleranz von Kulturpflanzen gegenueber chemischen Stressoren, vor allem aber gegenueber unguenstigen Nebenwirkungen bekannter Wachstumsregulatoren und Fungizide. Als Wirkstoffe enthalten diese Mittel ein Ethanolamin der allgemeinen Formel I, wobei R1 und R2H, R1H und R2CH3 resp. R1 und R2CH3 bedeuten koennen oder ein Gemisch aus Mono-, Di- und Triethanolamin der Formeln II a bis II c. Die Ethanolamine koennen in den erfindungsgemaessen Mitteln als freie Base oder als Salz einer Mineralsaeure vorliegen. Formeln I, II a, II b, II cThe invention relates to agents for increasing the tolerance of crop plants to chemical stressors, but especially to unfavorable side effects of known growth regulators and fungicides. As active ingredients, these agents contain an ethanolamine of the general formula I, where R1 and R2H, R1H and R2CH3, respectively. R 1 and R 2 CH 3 may mean or a mixture of mono-, di- and triethanolamine of the formulas II a to II c. The ethanolamines can be present in the inventive compositions as the free base or as the salt of a mineral acid. Formulas I, IIa, IIb, IIc
Description
Z.öl der Erfindung ist es, Mittel zur Erhöhung der Toleranz von Kulturpflanzen gegenüber chemischen Stressoren, vor allem abür Mittel zur Abschwächung von ungünstigen Nebenwirkungen bekannter Wachstumsregulatoren und Fungizids zu schaffen. Das Ziel der Erfindung ist insbesondere darauf gerichtet, Mittel zur vorbeugenden Toleranzerhchung gegenüber chemischen Streß, verursacht durch Wachstumsretardantien auf Chlorcholin-, Chlorethylphosphat und Triazolbasis so· vie durch Benzimidazol und Triazolfungizide in Gegenwart von unphysiologischen Temperaturen und/oder Wassermangel, zu entwickeln.Z.öl the invention is to provide means for increasing the tolerance of crops to chemical stressors, especially for providing means for mitigating adverse side effects of known growth regulators and fungicides. The object of the invention is particularly directed to developing means for the preventive tolerance to chemical stress caused by growth retardants on chloro choline, chloroethyl phosphate and triazole basis, as well as by benzimidazole and triazole fungicides in the presence of unphysiological temperatures and / or water deficiency.
Dar Erfindung liegt die Aufgabe zugrunde. Mittfei zur Erhöhung der Toleranz von Kulturpflanzen gegenüber chemischen Stressoron, vor ullem aber Mittel zur Abschwächung von ungünstigen Nebenwirkungen bekannter Wachstumsregulatoren, insbesondere auf Chlorcholin·, Chlorethylphosphonat- und Triazolbasis, sowie zur Abschwächung ungünstiger Nebenwirkungen von Fungiziden, insbesondere auf Benzimidazol- und Triazolbdsis, zu entwickeln, bei deren Anwendung unter unphysiologischen Temperaturen und/oder Wassermangel Einschränkungen in der biologischen Stoffproduktion vermieden werden. Diese toleranzorhöhenden Mittel sollten selbst keine bioziden Nebenwirkungen aufweisen, kostengünstig herstellbar und toxikologisch unbedenklich sein.The invention is based on the object. Mittfei to increase the tolerance of crops to chemical stressorone, but ullem means to mitigate unfavorable side effects of known growth regulators, especially chlorocholine ·, Chlorethylphosphonat- and triazole-based, as well as to mitigate unfavorable side effects of fungicides, in particular to benzimidazole and Triazolbdsis to develop which, when used under non-physiological temperatures and / or lack of water, limits biological production. These tolerance-increasing agents should themselves have no biocidal side effects, be inexpensive to produce and toxicologically safe.
Die Aufgabe wird erfindungsgemäß dadurch gelöst, daß Mittel zur Erhöhung der Toleranz von Kulturpflanzen gegenüber chemischen Stressoren, vor allem aber gegenüber ungünstigen Nebenwirkungen bekannter Wachstumsregulatoren, insbesondere auf Chlorcholin-, Chlorethylphosphonat· und Triazolbasis, sowie gegenüber ungünstiger. Nebenwirkungen von Tungiz'den, insbesondere auf Benzimidazol- und Triazolbasis neben üblichen Hills- und Trägerstoffen als Wirkstoff ein Ethanolamin der allgemeinen Formel I,The object is achieved in that means for increasing the tolerance of crops against chemical stressors, but especially against unfavorable side effects of known growth regulators, in particular on chlorocholine, Chlorethylphosphonat · and triazole, and unfavorable. Side effects of Tungiz'den, in particular on benzimidazole and triazole basis in addition to conventional Hills and carriers as active ingredient an ethanolamine of the general formula I,
HO - CH0 - CH0 - N (Formell)HO - CH 0 - CH 0 - N (Formal)
wobei R, und R2 = H, R, = H und R2 = CH3 where R, and R 2 = H, R, = H and R 2 = CH 3
resp. R, und R2 = CH3 bedeuten können,respectively. R and R 2 = CH 3 ,
oder ein Gemisch aus Mono-, Di- und Triethanolamin der Formeln Ha bis licor a mixture of mono-, di- and triethanolamine of the formulas Ha to lic
HO-CH2-CH2-NH2 (Formel Ha',HO-CH 2 -CH 2 -NH 2 (formula Ha ',
HO-CH2-CH2-N-HHO-CH 2 -CH 2 -NH
- CH2 - OH (Formel Hb)- CH 2 - OH (formula Hb)
CH2 - CH2 - OH I HO - CH2 - CH2 - NCH 2 - CH 2 --OH I HO - CH 2 - CH 2 - N
' (Forme! lic)'(Form! Lic)
CH2 - CH2 - OHCH 2 - CH 2 --OH
enthalten.contain.
Die Ethanolamine können in den erfindungsgemäßen Mitteln als freie Base oder als Salz einer Mineralsäure vorliegen.The ethanolamines can be present in the compositions according to the invention as free base or as salt of a mineral acid.
Die Prüfung der erfindungsgemäßen Mittel erfolgte im Rahmen von Feldversuchen auf Standorten mit begronzter Bodenwasserbereitstel'ung an Winterweizen (cv. Arkos und cv. Alcedo), Zuckerrüben (cv. Ponemo) und Sommergersto (cv. Lada und cv. Salome). Die Versuchsdurchführung erfolgte nach Standardvorschriften für Feldversuche (Parzellengröße 20m?, 4 Wiederholungen je Prüfgüod). Die Pflanzenbestände waren während der Vegetationszeit starkem Trockenstreß und überoptimalon Temperaturen ausgesetzt. Darüber hinaus traten unmittelbar nach der Applikation im DC-Stadium 31 Temperaturan · 0 C auf. In keiner Getreideversuchsparzelle trat Lager infolge mangelnder Halmfestigkeit auf. Die erf indurnjsgemäßen Mittel wurden entweder gemeinsam mit bekannten Wachstumsregulatoren applizicrt oder 3 bis 5 Tage nach der Reguiatorenapplikation angewendet (Blattapplikation).The testing of the agents according to the invention was carried out in field trials on sites with vegetated soil water preparation on winter wheat (cv.Arkos and cv.Alcedo), sugar beets (cv.Ponemo) and summer gersto (cv.Lada and cv.Salome). The experiment was carried out according to standard regulations for field trials (parcel size 20m ? , 4 repetitions per Prüfgüod). The crops were exposed to severe dry stress and overexpansion temperatures during the growing season. In addition, immediately after the application in the DC stage occurred 31 Temperaturan · 0 C. In none of the cereal trial plots did storage occur due to lack of straw strength. The medicaments according to the invention were either applied together with known growth regulators or applied 3 to 5 days after administration of the reguiator (foliar application).
Die Untersuchungen ergaben (Tabellen 1 und 2), daß die erfindungsgemäßen Mittel die ungünstigen Nebenwirkungen von bekannten Wachstumsregulatoren auf Wachstum und F.rtragsbiläung abschwächten. Dabei ist zu vc-rmorken, daß chemischer Streß durch bokannte Wachstumsregulatoren vor allem dann nachgewiesen werden konnte, wenn beispielsweise durch Trockenheit kein Lagern dos Getreides auftrat und durch Wassermangel bereits die Halmverkürzung einen physiologisch kritischen Wert erreichte.The investigations showed (Tables 1 and 2) that the agents according to the invention attenuated the unfavorable side effects of known growth regulators on growth and production. It is to vc-rmorken that chemical stress could be detected by bokannte growth regulators especially if, for example, by dryness no storage dos cereal occurred and reached by water shortage already Halmverkürzung a physiologically critical value.
Die Versuchsdurchführung entsprach den Angaben gemäß Beispiel 1. Unter den vorherrschenden Versuchsbedingungen tratThe experiment was as described in Example 1. Under the prevailing experimental conditions occurred
kein wesentlicher Pilzbefall auf.no significant fungal attack on.
Den Resultaten der Tabelle 3 zufolge haben die erfindungsgemäßen Mittel die Streßeffekte von Carbendazim- und Propiconazoi-Fungiziden auf Standorten mit ausgeprägtem Wassermangel auf.According to the results of Table 3, the agents of the invention have the stress effects of carbendazim and propiconazoic fungicides on sites of severe water deficiency.
Tabelle 1: Einfluß der erfindungsgemäßen Mittel auf die Toleranz von Weizenpflanzen gegenüber ungünstigen Nebenwirkungen von Wachstumsregulatoren auf Chlorcholin(CCC)- und TriazolbasisTable 1: Influence of the agents according to the invention on the tolerance of wheat plants to unfavorable side effects of growth regulators based on chlorocholine (CCC) and triazole
al Befuysvariantezu ta) I)) Bc?u(jsvariantG2u · b) ♦) bedeutet bei α · 0,05 signifikant 1) cholinhaltiges CCC 2) RSW 0411: Triazolethanola)). Choline-containing CCC 2) RSW 0411: triazole ethanol
Tabelle 2: Einfluß der erfindungsgemäßen Mittel auf die Toleranz von Weizen und Zuckerrübenpflanzen gegenüber ungünstigen Nebenwirkungen von Wachstumsregulatoren auf Chlorcholin (CCC-, Triazol- und ChlorethylphosphonatfCEPAIBasisTable 2: Influence of the agents of the invention on the tolerance of wheat and sugar beet plants against unfavorable side effects of growth regulators on chlorocholine (CCC, triazole and ChlorethylphosphonatfCEPAIBasis
a) erfindungsgemäß Ethanolamine (gem. Formel Ha-) lic)a) according to the invention ethanolamines (according to formula Ha-) lic)
(3 kg/ha) Ethanolamine (gem. Formel Halle) (3kg/hai(3 kg / ha) ethanolamine (according to formula hall) (3kg / hai
CEPA (0,3 kg/ha) (plusTemperatur- «treß)CEPA (0.3 kg / ha) (plus temperature)
ohnechem. Stessor (plus Temperaturstreß)ohnechem. Stessor (plus temperature stress)
Zuckerrübon (Biotrockenmasse)Sugar beet (bio dry mass)
Zuckerrüben (Biotrockenmasse)Sugar beets (dry biomass)
163' 167'163 '167'
* signifikante Unterschiede hei α < 0,05 gegenüber Variante mit themischen Stressor, aber ohne erfindungsgemaßes Mittel* significant differences hot α <0.05 versus variant with stressor but without means according to the invention
TabelleS: Einfluß der erfindunrjsgemäßcn Mittal auf dio Fmöhung der Toleranz von Winterweizen und Sommergerste gsgenüber ungünstigen Nebenwirkungen von Fungiziden auf Benzimidazol- und TriazolbasisTable 1: Influence of the invention on the determination of the tolerance of winter wheat and spring barley over unfavorable side effects of benzimidazole and triazole based fungicides
Signifikanter Unletschied bei aO.06 gegenüber Variante mit chemischem Sticssor. aber ohne eifindungsgemaßn MittelSignificant difference in aO.06 versus variant with chemical sticssor. but without any means
Claims (1)
resp. Ri und R2 = CH3 bedeuten können, ·
oder ein Gemisch aus Mono-, Di- und Triethanolamin der Formeln Ha bis Hcwherein R 1 and R 2 = H, R, = H and R 2 = CH 3
respectively. Ri and R 2 = CH 3 ,
or a mixture of mono-, di- and triethanolamine of the formulas Ha to Hc
I
HO-CH2-CH2-N (Formel lic)CH 2 -OH 2 -OH
I
HO-CH 2 -CH 2 -N (formula lic)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DD32304788A DD277829A1 (en) | 1988-12-13 | 1988-12-13 | MEANS TO INCREASE THE TOLERANCE OF CULTURAL PLANTS AGAINST CHEMICAL STRESSORS |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DD32304788A DD277829A1 (en) | 1988-12-13 | 1988-12-13 | MEANS TO INCREASE THE TOLERANCE OF CULTURAL PLANTS AGAINST CHEMICAL STRESSORS |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DD277829A1 true DD277829A1 (en) | 1990-04-18 |
Family
ID=5604942
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DD32304788A DD277829A1 (en) | 1988-12-13 | 1988-12-13 | MEANS TO INCREASE THE TOLERANCE OF CULTURAL PLANTS AGAINST CHEMICAL STRESSORS |
Country Status (1)
| Country | Link |
|---|---|
| DD (1) | DD277829A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006040016A1 (en) * | 2004-10-08 | 2006-04-20 | Bayer Cropscience Aktiengesellschaft | Fungicidal combinations of active ingredients |
| WO2008106466A3 (en) * | 2007-02-26 | 2009-04-30 | Stepan Co | Adjuvant and dispersant formulations for pesticidal applications |
-
1988
- 1988-12-13 DD DD32304788A patent/DD277829A1/en not_active IP Right Cessation
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006040016A1 (en) * | 2004-10-08 | 2006-04-20 | Bayer Cropscience Aktiengesellschaft | Fungicidal combinations of active ingredients |
| EA013075B1 (en) * | 2004-10-08 | 2010-02-26 | Байер Кропсайенс Актиенгезельшафт | Safeners used to increase herbicidal action of fungicides and fungicidal agent |
| US9155312B2 (en) | 2004-10-08 | 2015-10-13 | Bayer Intellectual Property Gmbh | Fungicidal combinations of active ingredients |
| US10244755B2 (en) | 2004-10-08 | 2019-04-02 | Bayer Cropscience Aktiengesellschaft | Fungicidal active compound combinations |
| WO2008106466A3 (en) * | 2007-02-26 | 2009-04-30 | Stepan Co | Adjuvant and dispersant formulations for pesticidal applications |
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