CZ198397A3 - Fungicidal impregnation agent against micro-organisms - Google Patents
Fungicidal impregnation agent against micro-organisms Download PDFInfo
- Publication number
- CZ198397A3 CZ198397A3 CZ971983A CZ198397A CZ198397A3 CZ 198397 A3 CZ198397 A3 CZ 198397A3 CZ 971983 A CZ971983 A CZ 971983A CZ 198397 A CZ198397 A CZ 198397A CZ 198397 A3 CZ198397 A3 CZ 198397A3
- Authority
- CZ
- Czechia
- Prior art keywords
- composition according
- fungicidal
- copper
- fungi
- water
- Prior art date
Links
- 230000000855 fungicidal effect Effects 0.000 title claims abstract description 5
- 244000005700 microbiome Species 0.000 title claims description 8
- 238000005470 impregnation Methods 0.000 title 1
- 239000000839 emulsion Substances 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims abstract description 8
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 6
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 5
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000005751 Copper oxide Substances 0.000 claims abstract description 5
- 239000011449 brick Substances 0.000 claims abstract description 5
- 239000004567 concrete Substances 0.000 claims abstract description 5
- 229910000431 copper oxide Inorganic materials 0.000 claims abstract description 5
- 125000005625 siliconate group Chemical group 0.000 claims abstract description 5
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 4
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 4
- 125000002091 cationic group Chemical group 0.000 claims abstract description 4
- 235000019353 potassium silicate Nutrition 0.000 claims abstract description 4
- 229920002050 silicone resin Polymers 0.000 claims abstract description 4
- 239000004111 Potassium silicate Substances 0.000 claims abstract description 3
- 229910052909 inorganic silicate Inorganic materials 0.000 claims abstract description 3
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052913 potassium silicate Inorganic materials 0.000 claims abstract description 3
- 239000004115 Sodium Silicate Substances 0.000 claims abstract 2
- 239000003093 cationic surfactant Substances 0.000 claims abstract 2
- 229910052911 sodium silicate Inorganic materials 0.000 claims abstract 2
- 239000000203 mixture Substances 0.000 claims description 10
- 241000233866 Fungi Species 0.000 claims description 9
- 229910000365 copper sulfate Inorganic materials 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 6
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 239000004094 surface-active agent Substances 0.000 claims description 5
- 241000195493 Cryptophyta Species 0.000 claims description 4
- 239000004570 mortar (masonry) Substances 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 4
- 125000000129 anionic group Chemical group 0.000 claims description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 239000010949 copper Substances 0.000 claims description 2
- PTVDYARBVCBHSL-UHFFFAOYSA-N copper;hydrate Chemical compound O.[Cu] PTVDYARBVCBHSL-UHFFFAOYSA-N 0.000 claims description 2
- 229910021331 inorganic silicon compound Inorganic materials 0.000 claims description 2
- IJKVHSBPTUYDLN-UHFFFAOYSA-N dihydroxy(oxo)silane Chemical compound O[Si](O)=O IJKVHSBPTUYDLN-UHFFFAOYSA-N 0.000 claims 1
- JZCCFEFSEZPSOG-UHFFFAOYSA-L copper(II) sulfate pentahydrate Chemical compound O.O.O.O.O.[Cu+2].[O-]S([O-])(=O)=O JZCCFEFSEZPSOG-UHFFFAOYSA-L 0.000 abstract description 2
- 239000011505 plaster Substances 0.000 abstract description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 abstract 1
- 229940074415 potassium silicate Drugs 0.000 abstract 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 abstract 1
- 229940032158 sodium silicate Drugs 0.000 abstract 1
- 235000019794 sodium silicate Nutrition 0.000 abstract 1
- -1 captants Chemical class 0.000 description 4
- 229920001296 polysiloxane Polymers 0.000 description 4
- 229910052700 potassium Inorganic materials 0.000 description 4
- 239000011591 potassium Substances 0.000 description 4
- 150000004760 silicates Chemical class 0.000 description 3
- 231100000481 chemical toxicant Toxicity 0.000 description 2
- LELOWRISYMNNSU-UHFFFAOYSA-N hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 description 2
- 239000003440 toxic substance Substances 0.000 description 2
- RWNISPVLLBWJBU-UHFFFAOYSA-N 2-sulfonyl-1h-pyridine Chemical class O=S(=O)=C1C=CC=CN1 RWNISPVLLBWJBU-UHFFFAOYSA-N 0.000 description 1
- 241000228212 Aspergillus Species 0.000 description 1
- 208000019838 Blood disease Diseases 0.000 description 1
- 208000020084 Bone disease Diseases 0.000 description 1
- 208000012659 Joint disease Diseases 0.000 description 1
- 208000019693 Lung disease Diseases 0.000 description 1
- 208000031888 Mycoses Diseases 0.000 description 1
- 241000228143 Penicillium Species 0.000 description 1
- 241000235527 Rhizopus Species 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 229940121363 anti-inflammatory agent Drugs 0.000 description 1
- 239000002260 anti-inflammatory agent Substances 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- 230000002925 chemical effect Effects 0.000 description 1
- 229910000366 copper(II) sulfate Inorganic materials 0.000 description 1
- 150000001896 cresols Chemical class 0.000 description 1
- 230000002498 deadly effect Effects 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 208000014951 hematologic disease Diseases 0.000 description 1
- 208000018706 hematopoietic system disease Diseases 0.000 description 1
- 210000000987 immune system Anatomy 0.000 description 1
- 210000004185 liver Anatomy 0.000 description 1
- 208000019423 liver disease Diseases 0.000 description 1
- 210000004072 lung Anatomy 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 150000003377 silicon compounds Chemical class 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000019351 sodium silicates Nutrition 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 150000003558 thiocarbamic acid derivatives Chemical class 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5076—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with masses bonded by inorganic cements
- C04B41/5089—Silica sols, alkyl, ammonium or alkali metal silicate cements
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
- A01N59/20—Copper
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04G—SCAFFOLDING; FORMS; SHUTTERING; BUILDING IMPLEMENTS OR AIDS, OR THEIR USE; HANDLING BUILDING MATERIALS ON THE SITE; REPAIRING, BREAKING-UP OR OTHER WORK ON EXISTING BUILDINGS
- E04G23/00—Working measures on existing buildings
- E04G23/002—Arrangements for cleaning building facades
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/2092—Resistance against biological degradation
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Architecture (AREA)
- Wood Science & Technology (AREA)
- Ceramic Engineering (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Plant Pathology (AREA)
- Materials Engineering (AREA)
- Civil Engineering (AREA)
- Dentistry (AREA)
- Electrochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Health & Medical Sciences (AREA)
- Mechanical Engineering (AREA)
- General Health & Medical Sciences (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Aftertreatments Of Artificial And Natural Stones (AREA)
- Paints Or Removers (AREA)
Abstract
Description
Vynález se týká f ungicidního impregnačního prostředku proti* | mikroorganismům na betonu, cihlách, maltě a omítkách, jnSofe 4i^ .The present invention relates to a phicogenic impregnating agent against an anti-inflammatory agent microorganisms on concrete, bricks, mortar and plasters, necSofe 4i ^.
v budovách a na budovách. Fungicidní impregnační prostředek | z 0 z z M z ί · ~ i podle vynalezu je v důsledků svého chemického složeni -s-eiwpeTi”™”’'’··’ účinně ničit plísně, houby a řasy, jakož i zamezovat napadení plísněmi, houbami a řasami. Podstata chemického působení prostředku podle vynálezu spočívá v kombinaci chemicko-fyzikálních vlastností, které dokládají novost prostředku podle vynálezu.in buildings and buildings. Fungicidal impregnating agent from 0 zz ί · M z ~ I of the invention is due to its chemical composition -s-eiwpeTi "™"'''··' effectively destroying fungi, algae and fungi and Prevent mildew, fungi and algae. The essence of the chemical action of the composition according to the invention lies in the combination of the chemical-physical properties which demonstrate the novelty of the composition according to the invention.
Dosavadní stav technikyBACKGROUND OF THE INVENTION
Dosavadní potírání plísní a hub je založeno na používání známých toxických chemických látek. Z těch lze jmenovat soli těžkých kovů, jako soli rtuti, olova, cínu a zinku, jakož i kresoly, fenoly, kyanovodík, kvarterní amoniové sloučeniny, sulf onylpyr.i diny, kaptany, triaziny, thiokarbamáty atd. Uvedené látky mají napomáhat k odstranění mikroorganismů o nichž je známo, že způsobují onemocnění plic, krve, jater, kostí a kloubů, z obytných domů. Zvláště nebezpečné pro lidský organismus, popřípadě pro jeho imunitní systém, jsou plísně rodu Aspergillus, Penicillium a Rhizopus, které mohou vést ke smrtelným mykozám.The current control of molds and fungi is based on the use of known toxic chemicals. These include heavy metal salts, such as mercury, lead, tin and zinc, as well as cresols, phenols, hydrogen cyanide, quaternary ammonium compounds, sulfonylpyridines, captants, triazines, thiocarbamates, etc. These substances are intended to assist in the removal of microorganisms. known to cause lung, blood, liver, bone and joint disease from residential homes. Especially dangerous to the human body or its immune system are fungi of the genera Aspergillus, Penicillium and Rhizopus, which can lead to deadly mycoses.
Podstata vynálezuSUMMARY OF THE INVENTION
Podstata předloženého vynálezu spočívá kromě jiného a na rozdíl od dosavadního stavu techniky nikoli v toxickém chemickém učinku impregnace betonu, cihel, malty a omítky, nýbrž v použití ekologicky šetrné a dokonce z velké části biologicky odbouratelné chemické směsi, ve které jsou přítomny tensidy, které však co do účinku vůči mikroorganismům mají spíše podřadnou úlohu. Kromě toho, na rozdíl od čistě chemického učinku, působí jakožto prostředek proti škůdcům nikoli tensidicky, nýbrž snižováníir^aovrchového napětí na fyzikálním podkladu v důsledku použití sloučenin křemíku, jako jsou silikony, silikonát.y, silikáty,The essence of the present invention lies inter alia and in contrast to the prior art not in the toxic chemical effect of impregnating concrete, brick, mortar and plaster, but in using an environmentally friendly and even largely biodegradable chemical composition in which surfactants are present but which they have a rather minor role in the action against microorganisms. In addition, unlike a purely chemical agent, it acts as a pest control agent not tensidically but rather to reduce the surface tension and stress on the physical substrate due to the use of silicon compounds such as silicones, silicones, silicates,
které citlivě narušují vlhké životní prostředí mikroorganismů. K této ekologické skutečnosti, která je podstatná i pro lidi, popřípadě obyvatele domů, přispívá ještě výběr sloučenin solí kovů šetrných vůči potravinám, jako je například síran měďnatý (CuSO^. 5 t^O) a skýtá tak chemicko-fyzikální synergismus.which sensitively disturbs the humid environment of microorganisms. The choice of food-friendly metal salt compounds, such as copper sulphate (CuSO 5 .5 t ^ O), contributes to this ecological fact, which is also essential for people and / or occupants of homes, thus providing chemical-physical synergism.
Předmětem vynálezu je fungicidní impregnační prostředek proti mikroorganismům, jako jsou například plísně, houby, řasy, na betonu, cihlách, maltě a omítkách v budovách a na budovách, sestávající výhodně z organických a anorganických sloučenin křemíku, popřípadě také spolu s dalšími organickými látkami, jako jsou například akryláty, t.ensidy anionického či kationického původu v kombinaci se solemi kovů, jako například s modrou skalicí rozpuštěnou ve vodě, který spočívá v t.om, že obsahuje 0,1 až 80 % hmotn. anorganických silikátů, 0,1 až 70 % hmotn. silikonátů, 0,1 až 80 % hmotn. silikonových emulzí nebo emulzí akrylátové pryskyřice, 0,1 až 5 % hmotn. tensidů, 0,1 až 10 % hmotn. síranu měďnatého, 0,1 až 15 % hmotn. oxidů mědi a vodu.The present invention provides a fungicidal impregnating agent against microorganisms, such as fungi, fungi, algae, on concrete, bricks, mortar and plasters in and on buildings, preferably consisting of organic and inorganic silicon compounds, optionally also together with other organic substances, such as are, for example, acrylates, surfactants of anionic or cationic origin in combination with metal salts, such as, for example, blue vitriol dissolved in water, which comprises 0.1 to 80 wt. % of inorganic silicates, 0.1 to 70 wt. % of siliconates, 0.1 to 80 wt. % silicone emulsions or acrylate resin emulsions, 0.1 to 5 wt. % surfactants, 0.1 to 10 wt. % copper sulfate, 0.1 to 15 wt. copper oxide and water.
Jako silikátů se přitom výhodně používá natrium- nebo kaliumsilikát.u a jako silikonátu se výhodně používá methylsilikonátu.The silicates used are preferably sodium or potassium silicates, and the silicates are preferably methyl silicates.
Příklady provedení vynálezuDETAILED DESCRIPTION OF THE INVENTION
Složení prostředku podle vynálezu blíže ilustrují následující příklady:The following examples illustrate the compositions of the present invention:
Příklad 1Example 1
Příklad 2Example 2
ίί
Příklad 3Example 3
0,25 % hmotn. síranu měďnatého 39,45 % hmotn. vody.0.25 wt. % copper sulfate 39.45 wt. water.
Příklad 4 % hmotn. emulze akrylové pryskyřice 20 % hmotn. kaliummethylsilikonátu 10 % hmotn. kaliumsilikátuExample 4 wt. % acrylic resin emulsion 20 wt. % of potassium methyl siliconate 10 wt. potassium silicate
0,1 % síranu měďnatého 59,9 % hmotn. vody.0.1% copper sulfate 59.9 wt. water.
i Průmyslová využitelnost rf s Využití prostředku podle vynálezu přichází v uvahu zvláště při ochraně budov vůči napadení mikroorganismy.Industrial Applicability RF s The use of the composition according to the invention comes into consideration in particular in protecting buildings against attack by microorganisms.
Claims (5)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT0111296A AT403235B (en) | 1996-06-24 | 1996-06-24 | IMPREGNANT AGAINST MOLD, MUSHROOM AND ALGAE |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CZ198397A3 true CZ198397A3 (en) | 1998-01-14 |
Family
ID=3506844
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CZ971983A CZ198397A3 (en) | 1996-06-24 | 1997-06-23 | Fungicidal impregnation agent against micro-organisms |
Country Status (6)
| Country | Link |
|---|---|
| AT (1) | AT403235B (en) |
| CZ (1) | CZ198397A3 (en) |
| DE (1) | DE19703705A1 (en) |
| HU (1) | HUP9701091A2 (en) |
| PL (1) | PL320721A1 (en) |
| SK (1) | SK80797A3 (en) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6649569B2 (en) | 2001-01-12 | 2003-11-18 | Jacques Vionnet | Composition intended for the protection of a solid substrate and its use |
| EP1223200A1 (en) * | 2001-01-12 | 2002-07-17 | Vionnet, Jacques | Composition for protecting a solid substrate and its use |
| EP1253178A1 (en) * | 2001-04-17 | 2002-10-30 | Vionnet, Jacques | Aqueous composition for the hydrophobisation of substrates |
| DE10219191A1 (en) * | 2002-04-29 | 2003-12-11 | Ransmann Ursula | Objects with antifouling protection, e.g. house wrap, tents and building materials, coated with material which becomes alkaline, with fungicidal and-or antibacterial activity, when exposed to environmental moisture |
| WO2003104159A1 (en) * | 2002-06-06 | 2003-12-18 | Radi Al-Rashed | An aqueous chemical mixture to mitigate water associated problems in concrete pavements |
| DE102004028941B4 (en) * | 2004-06-15 | 2006-05-04 | Reul, Horst, Dr. | Use of lithium ion containing aqueous solution (e.g. lithium hydroxide solution) for treating and preventing the growth of algae (e.g. green and red algae) and fungi on building surfaces, sculptures, gravestone (e.g. on the frontages) |
| CZ23591U1 (en) * | 2011-11-10 | 2012-03-26 | Effmert@Vilém | Concrete mixture, concrete and concrete product exhibiting increased resistance to formation of moss and/or lichen |
| FR3065861B1 (en) * | 2017-05-04 | 2020-03-13 | Hbco Herbals And Bio Chemicals Outsourcing | USE OF MONOMETHYLSILANETRIOL AND / OR ITS SALTS TO PROTECT CROPS |
| CN112534001A (en) | 2018-08-14 | 2021-03-19 | 巴斯夫欧洲公司 | Process for preparing silicone-in-water emulsions |
| DE102021107923A1 (en) | 2020-11-04 | 2022-05-05 | Mslsolutions Gmbh | Coating against algae and fungal attack |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SG47493A1 (en) * | 1991-10-17 | 1998-04-17 | Sheen Biotechnology Pty Ltd | Pesticide and fungicide |
| US5421867A (en) * | 1993-10-18 | 1995-06-06 | Cucorp, Inc. | Composition and process of combining a grout or mortar mix with copper-8-quinolinolate to form an antimicrobial composition |
-
1996
- 1996-06-24 AT AT0111296A patent/AT403235B/en not_active IP Right Cessation
-
1997
- 1997-01-21 DE DE19703705A patent/DE19703705A1/en not_active Ceased
- 1997-06-19 SK SK807-97A patent/SK80797A3/en unknown
- 1997-06-23 HU HU9701091A patent/HUP9701091A2/en unknown
- 1997-06-23 PL PL97320721A patent/PL320721A1/en unknown
- 1997-06-23 CZ CZ971983A patent/CZ198397A3/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| SK80797A3 (en) | 1998-01-14 |
| ATA111296A (en) | 1997-05-15 |
| HUP9701091A2 (en) | 1998-04-28 |
| HU9701091D0 (en) | 1997-08-28 |
| AT403235B (en) | 1997-12-29 |
| PL320721A1 (en) | 1998-01-05 |
| DE19703705A1 (en) | 1998-01-02 |
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