CR20180167A - Complejación y eliminación del mercurio de sistemas de desulfuración de gas de combustión - Google Patents
Complejación y eliminación del mercurio de sistemas de desulfuración de gas de combustiónInfo
- Publication number
- CR20180167A CR20180167A CR20180167A CR20180167A CR20180167A CR 20180167 A CR20180167 A CR 20180167A CR 20180167 A CR20180167 A CR 20180167A CR 20180167 A CR20180167 A CR 20180167A CR 20180167 A CR20180167 A CR 20180167A
- Authority
- CR
- Costa Rica
- Prior art keywords
- mercury
- hypobromite
- elimination
- capture
- completion
- Prior art date
Links
- 239000000567 combustion gas Substances 0.000 title abstract 2
- 238000006477 desulfuration reaction Methods 0.000 title abstract 2
- 230000008030 elimination Effects 0.000 title 1
- 238000003379 elimination reaction Methods 0.000 title 1
- JGJLWPGRMCADHB-UHFFFAOYSA-N hypobromite Chemical compound Br[O-] JGJLWPGRMCADHB-UHFFFAOYSA-N 0.000 abstract 6
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 abstract 4
- 229910052753 mercury Inorganic materials 0.000 abstract 4
- 239000007789 gas Substances 0.000 abstract 3
- 238000000034 method Methods 0.000 abstract 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 1
- 239000003245 coal Substances 0.000 abstract 1
- 230000023556 desulfurization Effects 0.000 abstract 1
- 239000003546 flue gas Substances 0.000 abstract 1
- 239000002803 fossil fuel Substances 0.000 abstract 1
- 239000000446 fuel Substances 0.000 abstract 1
- 230000002265 prevention Effects 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/64—Heavy metals or compounds thereof, e.g. mercury
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1493—Selection of liquid materials for use as absorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/77—Liquid phase processes
- B01D53/78—Liquid phase processes with gas-liquid contact
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/80—Semi-solid phase processes, i.e. by using slurries
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J15/00—Arrangements of devices for treating smoke or fumes
- F23J15/02—Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material
- F23J15/04—Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material using washing fluids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/10—Oxidants
- B01D2251/108—Halogens or halogen compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/30—Alkali metal compounds
- B01D2251/304—Alkali metal compounds of sodium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/40—Alkaline earth metal or magnesium compounds
- B01D2251/404—Alkaline earth metal or magnesium compounds of calcium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/50—Inorganic acids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/60—Heavy metals or heavy metal compounds
- B01D2257/602—Mercury or mercury compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/02—Other waste gases
- B01D2258/0233—Other waste gases from cement factories
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/02—Other waste gases
- B01D2258/025—Other waste gases from metallurgy plants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/02—Other waste gases
- B01D2258/0283—Flue gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/02—Other waste gases
- B01D2258/0283—Flue gases
- B01D2258/0291—Flue gases from waste incineration plants
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J2215/00—Preventing emissions
- F23J2215/60—Heavy metals; Compounds thereof
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J2219/00—Treatment devices
- F23J2219/40—Sorption with wet devices, e.g. scrubbers
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Treating Waste Gases (AREA)
Abstract
Se divulga un método para la reducción y la prevención de las emisiones de mercurio en el medio ambiente de los combustibles fósiles quemados u otros gases liberados con el uso de hipobromito. El hipobromito se utiliza para la captura del mercurio de los gases de combustión resultantes utilizando un sistema de desulfuración de gases de combustión o lavador. El método utiliza hipobromito en conjunto con un lavador de gases para capturar el mercurio y reducir su emisión y/o re-emisión con los gases de chimenea. El método permite el uso de carbón como un limpiador y fuente de combustible amigable con el medio ambiente, así como la captura de mercurio de otros sistemas de procesamiento
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201562208212P | 2015-08-21 | 2015-08-21 | |
| PCT/US2016/047822 WO2017034999A1 (en) | 2015-08-21 | 2016-08-19 | Complexation and removal of mercury from flue gas desulfurization systems |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CR20180167A true CR20180167A (es) | 2018-06-14 |
Family
ID=58100714
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CR20180167A CR20180167A (es) | 2015-08-21 | 2016-08-19 | Complejación y eliminación del mercurio de sistemas de desulfuración de gas de combustión |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US9764280B2 (es) |
| BR (1) | BR112018003122B1 (es) |
| CL (1) | CL2018000418A1 (es) |
| CO (1) | CO2018001646A2 (es) |
| CR (1) | CR20180167A (es) |
| EC (1) | ECSP18012794A (es) |
| MX (1) | MX2018002172A (es) |
| NI (1) | NI201800028A (es) |
| PE (1) | PE20180374A1 (es) |
| WO (1) | WO2017034999A1 (es) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2017035003A1 (en) | 2015-08-21 | 2017-03-02 | Ecolab Usa Inc. | Complexation and removal of mercury from flue gas desulfurization systems |
| MX2018002173A (es) | 2015-08-21 | 2018-06-15 | Ecolab Usa Inc | Formacion de complejos y remocion de mercurio de los sistemas de desulfuracion de gases de combustion. |
| WO2019010163A1 (en) | 2017-07-06 | 2019-01-10 | Ecolab USA, Inc. | IMPROVED INJECTION OF MERCURY OXIDANTS |
| CN111974187A (zh) * | 2020-08-20 | 2020-11-24 | 长春净月潭供热有限公司 | 一种氧化镁作为脱硫剂的烟气脱硫方法 |
Family Cites Families (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5658467A (en) | 1993-08-05 | 1997-08-19 | Nalco Chemical Company | Method and composition for inhibiting growth of microorganisms including peracetic acid and a non-oxidizing biocide |
| US5785867A (en) | 1993-08-05 | 1998-07-28 | Nalco Chemical Company | Method and composition for inhibiting growth of microorganisms including peracetic acid and a non-oxidizing biocide |
| CA2129489C (en) | 1993-08-05 | 2000-10-10 | Judy G. Lazonby | Method and composition for inhibiting growth of microorganisms including peracetic acid and a non-oxidizing biocide |
| US5980758A (en) | 1993-08-05 | 1999-11-09 | Nalco Chemical Company | Method and composition for inhibiting growth of microorganisms including peracetic acid and a non-oxidizing biocide |
| US5733786A (en) | 1996-11-26 | 1998-03-31 | Hach Company | Mercury determination |
| US5942126A (en) | 1997-01-03 | 1999-08-24 | Nalco Chemical Company | Process to manufacture stabilized alkali or alkaline earth metal hypobromite and uses thereof in water treatment to control microbial fouling |
| US6007726A (en) | 1998-04-29 | 1999-12-28 | Nalco Chemical Company | Stable oxidizing bromine formulations, methods of manufacture thereof and methods of use for microbiofouling control |
| US6156229A (en) | 1998-06-29 | 2000-12-05 | Nalco Chemical Company | Stable oxidizing bromine formulations, method of manufacture and uses thereof for biofouling control |
| US6123870A (en) | 1998-06-29 | 2000-09-26 | Nalco Chemical Company | Stable oxidizing bromine formulations, method of manufacture and uses thereof for biofouling control |
| US6287473B1 (en) | 1998-06-29 | 2001-09-11 | Nalco Chemical Company | Stable oxidizing bromine formulations, method of manufacture and uses thereof for biofouling control |
| US6669904B1 (en) | 1999-03-31 | 2003-12-30 | Ondeo Nalco Company | Stabilized bromine solutions, method of making and uses thereof for biofouling control |
| US6270722B1 (en) | 1999-03-31 | 2001-08-07 | Nalco Chemical Company | Stabilized bromine solutions, method of manufacture and uses thereof for biofouling control |
| US6245729B1 (en) | 1999-07-27 | 2001-06-12 | Ecolab, Inc. | Peracid forming system, peracid forming composition, and methods for making and using |
| US6942840B1 (en) * | 2001-09-24 | 2005-09-13 | Ada Technologies, Inc. | Method for removal and stabilization of mercury in mercury-containing gas streams |
| US6808692B2 (en) | 2002-02-14 | 2004-10-26 | Oehr Klaus H | Enhanced mercury control in coal-fired power plants |
| US8668779B2 (en) * | 2002-04-30 | 2014-03-11 | Nalco Company | Method of simultaneously cleaning and disinfecting industrial water systems |
| CN1826175B (zh) | 2003-04-23 | 2015-07-01 | 能源及环境研究中心基金会 | 用过的吸附剂的再生工艺 |
| PT1872054T (pt) * | 2005-03-17 | 2018-12-14 | Nox Ii Int Ltd | Redução das emissões de mercúrio da queima de carvão |
| WO2006099611A1 (en) | 2005-03-17 | 2006-09-21 | Nox Ii International, Ltd. | Reducing mercury emissions from the burning of coal |
| CN1864813A (zh) | 2006-04-20 | 2006-11-22 | 上海交通大学 | 燃煤烟气中单质汞与氮氧化物的同时净化方法 |
| WO2007149867A1 (en) | 2006-06-19 | 2007-12-27 | Higgins Brian S | Method and apparatus for enhanced mercury removal |
| US8110163B2 (en) | 2007-12-07 | 2012-02-07 | Nalco Company | Complexation and removal of heavy metals from flue gas desulfurization systems |
| CN1962034A (zh) | 2006-10-25 | 2007-05-16 | 华北电力大学 | 锅炉烟气同时脱硫脱硝脱汞的方法及装置 |
| CN102741157B (zh) | 2009-08-03 | 2016-01-20 | Fmc有限公司 | 用催化剂对活性化合物进行活化 |
| AU2011237443B2 (en) | 2010-04-07 | 2014-02-20 | Calgon Carbon Corporation | Methods for removal of mercury from flue gas |
| ES2676187T3 (es) | 2010-12-29 | 2018-07-17 | Ecolab Usa Inc. | Generación de ácidos peroxcarboxílicos a pH alcalino y su uso como agentes blanqueantes textiles y antimicrobianos |
| WO2012090124A2 (en) | 2010-12-29 | 2012-07-05 | Ecolab Usa Inc. | IN SITU GENERATION OF PEROXYCARBOXYLIC ACIDS AT ALKALINE pH, AND METHODS OF USE THEREOF |
| BR112014016319A8 (pt) | 2011-12-30 | 2017-07-04 | Chevron Usa Inc | processo, método, e sistema para remover metais pesados de fluidos |
| CN104334692A (zh) | 2012-05-16 | 2015-02-04 | 雪佛龙美国公司 | 从流体中去除重金属的工艺、方法和系统 |
| US20130330257A1 (en) | 2012-06-11 | 2013-12-12 | Calgon Carbon Corporation | Sorbents for removal of mercury |
| US9308518B2 (en) * | 2013-02-14 | 2016-04-12 | Calgon Carbon Corporation | Enhanced sorbent formulation for removal of mercury from flue gas |
-
2016
- 2016-08-19 US US15/241,207 patent/US9764280B2/en active Active
- 2016-08-19 CR CR20180167A patent/CR20180167A/es unknown
- 2016-08-19 BR BR112018003122-4A patent/BR112018003122B1/pt active IP Right Grant
- 2016-08-19 WO PCT/US2016/047822 patent/WO2017034999A1/en not_active Ceased
- 2016-08-19 MX MX2018002172A patent/MX2018002172A/es unknown
- 2016-08-19 PE PE2018000219A patent/PE20180374A1/es unknown
-
2018
- 2018-02-15 CL CL2018000418A patent/CL2018000418A1/es unknown
- 2018-02-20 CO CONC2018/0001646A patent/CO2018001646A2/es unknown
- 2018-02-20 EC ECIEPI201812794A patent/ECSP18012794A/es unknown
- 2018-02-21 NI NI201800028A patent/NI201800028A/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| WO2017034999A1 (en) | 2017-03-02 |
| MX2018002172A (es) | 2018-06-15 |
| ECSP18012794A (es) | 2018-10-31 |
| US20170050145A1 (en) | 2017-02-23 |
| CO2018001646A2 (es) | 2018-05-10 |
| BR112018003122B1 (pt) | 2022-09-13 |
| CL2018000418A1 (es) | 2018-07-06 |
| PE20180374A1 (es) | 2018-02-22 |
| US9764280B2 (en) | 2017-09-19 |
| NI201800028A (es) | 2018-08-09 |
| BR112018003122A2 (pt) | 2018-09-25 |
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