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CO5050309A1 - FUNGICIDE MIXTURES BASED ON TRIPELOXIMETER DERIVATIVES AND OTHER FUNGICIDES - Google Patents

FUNGICIDE MIXTURES BASED ON TRIPELOXIMETER DERIVATIVES AND OTHER FUNGICIDES

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Publication number
CO5050309A1
CO5050309A1 CO99017836A CO99017836A CO5050309A1 CO 5050309 A1 CO5050309 A1 CO 5050309A1 CO 99017836 A CO99017836 A CO 99017836A CO 99017836 A CO99017836 A CO 99017836A CO 5050309 A1 CO5050309 A1 CO 5050309A1
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Prior art keywords
alkyl
alkoxy
cyano
alkylthio
alkylamino
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CO99017836A
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Spanish (es)
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Thomas Grote
Sauter Hubert
Eberhard Ammermann
Gisela Lorenz
Siegfred Strathmann
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Basf Ag
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Publication of CO5050309A1 publication Critical patent/CO5050309A1/en

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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
    • A01N37/50—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids the nitrogen atom being doubly bound to the carbon skeleton
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
    • A01N25/06—Aerosols
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/12—Powders or granules
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/10—Aromatic or araliphatic carboxylic acids, or thio analogues thereof; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
    • C07C251/32—Oximes
    • C07C251/50—Oximes having oxygen atoms of oxyimino groups bound to carbon atoms of substituted hydrocarbon radicals
    • C07C251/56—Oximes having oxygen atoms of oxyimino groups bound to carbon atoms of substituted hydrocarbon radicals of hydrocarbon radicals substituted by doubly-bound oxygen atoms

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Environmental Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Zoology (AREA)
  • Plant Pathology (AREA)
  • Chemical & Material Sciences (AREA)
  • Toxicology (AREA)
  • Dispersion Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Mezcla para la protección de plantas, que contienen comocomponentes activos a) derivados de ácido fenilácetico de la fórmula I en la que los sustituyentes y el índice tienen los significados siguientes:X NOCH3 , CHOCH3 , CHCH3 ;Y O, NRR1 , R cada uno independientemente del otro, hidrógeno y C1 -C4 alquilo;R2 ciano, nitro, trifluorometilo, halógeno, C1 -C4 -alquilo y C1 -C4 -alcoxi;m 0, 1 ó 2, pudiendo los radicales R2 ser diferentes cuando m es 2;R3 hidrógeno, ciano, C1 -C4 -alquilo, C1 -C4 - halógenoalquilo, C3 -C6 -cicloalquilo;R4 , R6 cada uno independientemente del otro, hidrógeno, C1 -C10 -alquilo, C3 -C6 -cicloalquilo, C2 -C10 -alquenilo, C2 -C10 -alquinilo, C1 -C10 -alquilcarbonilo, C2 -C10 -alquenilcarbonilo, C3 -C10 -alquinilcarbonilo o C1 -C10 -alquilsulfonilo, cuyos radicales pueden estar parcialmente o completamente halogenados o llevar de uno a tres de los grupos siguientes: ciano, nitro, hidroxi, mercapto, amino, carboxilo, aminocarbonilo, aminotiocarbonilo, halógeno, C1 -C6 -alquilo, C1 -C6 -halógenoalquilo, C1 -C6 -alquilsulfonilo, C1 -C6 -alquilsulfoxilo, C1 -C6 -alcoxi, C1 -C6 -halógenoalcoxi, C1 -C6 -alcoxicarbonilo, C1 -C6 -alquiltio, C1 -C6 -alquilamino, di C1 -C6 -alquilamino, C1 -C6 -alquilaminocarbonilo, di C1 -C6 -alquilaminocarbonilo, di-C1 -C6 - alquilaminotiocarbonilo, C2 -C6 -alquenilo, C1 -C6 -alqueniloxi, C3 -C6 -cicloalquilo, C3 -C6 -cicloalquiloxi, heterociclilo, heterocicliloxi, bencilo, benciloxi, arilo, ariloxi, ariltio, hetarilo, hetariloxi y hetariltio, cuyos grupos cíclicos pueden por su parte estar parcial o completamente halogenados o llevar a uno a tres de los grupos siguientes: ciano, nitro, hidroxi, mercapto, amino, carboxilo, aminocarbonilo, 2 aminotiocarbonilo, halógeno, C1 -C6 -alquilo, C1 -C6 -halógenoalquilo, C1 -C6 -alquilsulfonilo, C1 -C6 -alquilsulfoxilo, C3 -C6 -cicloalquilo, C1 -C6 -alcoxi, C1 -C6 -halógenoalcoxi, C1 -C6 -alquiloxicarbonilo, C1 -C6 -alquiltio, C1 -C6 -alquilamino, di C1 -C6 -alquilamino, C1 -C6 -alquilaminocarbonilo, di C1 -C6 - alquilaminocarbonilo, C1 -C6 -alquilaminotiocarbonilo, di C1 -C6 - alquilaminotiocarbonilo, C2 -C6 -alquenilo, C2 -C6 -alqueniloxi, bencilo, benciloxi, arilo, ariloxi, ariltio, hetarilo, hetariloxi, hetariltio o C(=NOR7 )-An R8 ;Arilo, arilcarbonilo, arilsulfonilo, hetarilo, hetarilcarbonilo o hetarilsulfonilo, cuyos radicales pueden estar parcial o completamente halógenados o llevar de uno a tres de los grupos siguientes:Ciano, nitro, hidroxi, mercapto, amino, carboxilo,aminocarbonilo, aminotiocarbonilo, halógeno, C1 -C6 -alquilo, C1 -C6 -halógenoalquilo, C1 -C6 -alquilcarbonilo, C1 -C6 -alquilsulfonilo, C1 -C6 -alquilsulfoloxi, C3 -C6 -cicloalquilo, C1 -C6 -alcoxi, C1 -C6 -halógenoalcoxi, C1 -C6 -alcoxi, C1 -C6 -halógenoalcoxi, C1 -C6 -alquiloxicarbonilo, C1 -C6 -alquiltio, C1 -C6 -alquilamino, di C1 -C6 -alquilamino, C1 -C6 -alquilaminocarbonilo, di C1 -C6 -alquilaminocarbinilo, C1 -C6 - alquilaminotiocarbonilo, di C1 -C6 - alquilaminotiocarbonilo, C2 -C6 -alquenilo, C2 -C6 -alqueniloxi, bencilo, benciloxi, arilo, ariloxi, hetarilo, hetariloxi o C( =NOR7 ) -An -R8 ;R5 hidrógeno,C1 -C6 -alquilo, C2 -C6 -alquenilo, C2 -C6 -alquinilo, pudiendo los radicales hidrocarburo de estos grupos estar parcial o completamente halogenados o llevar de uno a tres de los radicales siguientes: ciano, nitro, hidroxi, mercapto, amino, carboxilo, aminocarbonilo, aminotiocarbonilo, halógeno, C1 -C6 - alquilaminocarbonilo, di C1 -C6 - alquilaminocarbonilo, C1 -C6 -alquilaminotiocarbonilo, di C1 -C6 -alquilaminotiocarbonilo, C1 -C6 - alquilsulfonilo, C1 -C6 -alquilsulfoxilo, C1 -C6 -alcoxi, C1 -C6 -halógenoalcoxi, C1 -C6 -alcoxicarbonilo, C1 -C6 -alquiltio, C1 -C6 -alquilamino, di C1 -C6 -alquilamino, C2 -C6 -alqueniloxi, C3 -C6 -cicloalquilo, C3 -C6 -cicloalquiloxi, heterociclilo, heterocicliloxi, arilo, ariloxi, aril C1 -C4 -alcoxi, ariltio, aril C1 -C4 -alquiltio, hetarilo, hetariloxi,hetaril C1 -C4 -alcoxi, hetariltio, hetaril C1 -C4 - alquiltio, cuyos radicales cíclicos pueden por su parte estar parcial o completamente halógenados y/o llevar de uno a tres de los grupos siguientes: ciano, nitro, hidroxi, mercapto, amino, carboxilo, aminocarbonilo, aminotiocarbonilo, C1 -C6 - alquilo, C1 -C6 -halógenoalquilo, C1 -C6 - alquilsulfonilo, C1 -C6 -alquilsulfoxilo, C3 -C6 cicloalquilo, C1 -C6 -alcoxi, C1 -C6 halógenoalcoxi, C1 -C6 -alcoxicarbonilo, C1 -C6 - alquiltio, C1 -C6 -alquilamino, di C1 -C6 -alquilamino, C1 -C6 -alquilaminocarbonilo, di C1 -C6 alquilaminocarbonilo, C1 -C6 - alquilaminotiocarbonilo, di C1 -C6 - alquilaminotiocarbonilo, C2 -C6 -alquenilo, C2 -C6 -alqueniloxi, bencilo, benciloxi, arilo, ariloxi, ariltio, hetarilo, hetariloxi, hetariltio y C(=NOR7 )-An -R8 ;C3 C6 -cicloalquilo, C3 -C6 -cicloalquenilo, heterociclico, arilo, hetarilo, cuyos radicales cíclicos pueden estar parcial o completamente halógenados o llevar de uno a tres de los grupos siguientes: ciano, nitro, hidroxi, mercapto, amino, carboxilo, aminocarbonilo, aminotiocarbonilo, halógeno, C1 -C6 -alquilo, C1 -C6 -halógenoalquilo, C1 -C6 alquilsulfonilo, C1 -C6 -alquilsulfoxilo, C3 -C6 -cicloalquilo, C1 -C6 -alcoxi, C1 -C6 - halógenoalcoxi, C1 -C6 alcoxicarbonilo, C1 -C6 - alquiltio, C1 -C6 -alquilamino, di C1 -C6 -alquilamino, C1 -C6 alquilaminocarbonilo, di C1 -C6 - alquilaminocarbonilo, C1 -C6 -alquilaminotiocarbonilo, di C1 -C6 -alquilaminotiocarbonilo, C2 -C6 -alquenilo, C2 -C6 -alqueniloxi, bencilo, benciloxi, arilo, ariloxi, hetarilo, hetariloxi;SignificandoA oxígeno, azufre o nitrógeno y llevando el nitrógeno hidrógeno o C1 -C6 -alquilo;n 0 ó 1;R7 hidrógeno o C1 -C6 -alquilo yR8 hidrógeno o C1 -C6 -alquilo,así como sus sales, y 3 b) como mínimo, un compuesto de las fórmulas II a Vteniendo los sustituyentes los significados siguientes:A C3 -C6 -cicloalquilo, que puede llevar de uno a tres sustituyentes seleccionados del grupo que contiene halógeno y C1 -C3 -alquilo;R9 C1 -C6 -alquilo o C2 -C6 -alquenilo, cuyos radicales pueden estar parcial o completamente halógenados y/o llevar uno o dos de los grupos siguientes: C1 -C4 -alcoxi C1 -C4 -halógenoalcoxi, C1 -C4 -alquiltio, C1 -C4 -alcoxicarbonilo, C3 -C6 -cicloalquilo y fenilo, pudiendo el fenilo estar parcial o completamente halogenado y/o llevar de uno a tres de los radicales siguientes; nitro, ciano, C1 -C4 -alquilo, C1 -C4 halógenoalquilo, C1 -C4 -alcoxi, C1 -C4 -halógenoalcoxi, C1 -C4 -alquiltio, C3 -C6 cicloalquil o heterocíclico;R10 , R11 , R12 hidrógeno o, independiente, uno de los significados del radical R9 ;n 0 ó 1;Y ciano o halógeno;W fenilo, naftilo o heteroarilo, cuyos radicales pueden llevar de uno a tres de los grupos siguientes: nitro, halógeno, ciano, C1 -C4 -alquilo, C1 -C4 -halógenoalquilo, C1 -C4 -alcoxi, C1 -C4 -halógeno alcoxi, C1 -C4 -alquiltio, C3 -C6 cicloalquilo y C1 -C4 -alcoxicarbonilo,R13 C6 -C15 bicicloalquilo o C7 -C15 - bicicloalquenilo, cuyos radicales pueden estar completamente halógenados y, siempre que no estén completamente halógenados, dos átomos de carbono de estos radicales pueden formar junto con un grupo C3 -C5 -alquilideno un anillo carboxíclico saturado de cinco a seis miembros y/o llevar uno o, cada uno independiente del otro, dos, tres, cuatro o cinco de los grupos siguientes: ciano, C1 -C4 -alquilo, C1 -C4 -halógenoalquilo, C1 -C4 -alcoxi, C1 -C4 - halógenoalcoxi y arilo, pudiendo el arilo estar parcial o completamente halógenado y/o llevar, cada uno independiente del otro, dos o tres de los sustituyentes siguientes: nitro, ciano, C1 -C4 - alquilo, C1 -C4 -halógenoalquilo, C1 -C4 -alcoxi, C1 -C4 -halógenoalcoxi y C1 -C4 -alquiltio;R14 , R15 , R16 cada uno independientemente del otro, hidrógeno, C1 -C8 -alquilo, que puede estar parcial o completamente halógenado y/o llevar uno o dos grupos siguientes: C1 -C4 -alcoxi, C1 -C4 - halógenoalcoxi, C1 -C4 -alquiltio, C3 -C7 -cicloalquilo, C5 -C7 -cicloalquenilo, pudiendo los grupos cíclicos por su parte llevar uno o, independientemente, dos o tres átomos de halógeno, grupos C1 -C3 -alquilo y/o C1 -C3 -alcoxi y arilo, pudiendo el arilo estar parcial o completamente halógenado y/o llevar uno o, cada vez independientemente, dos o tres de los sustituyentes siguientes: nitro, ciano, C1 -C4 -alquilo, C1 -C4 -halógenoalquilo, C1 -C4 -alcoxi, C1 -C4 halógenoalcoxi y C1 -C4 -alquiltio o C3 -C6 -cicloalquilo, C3 -C6 -cicloalquenilo o heterociclico, cuyos radicales pueden estar parcial o completamente halogenados y/o llevar, independientemente, dos o tres de los grupos siguientes: ciano, C1 -C6 -alquilo, C1 -C6 - halógenoalquilo, C2 -C6 -alquenilo, C1 -C6 -alcoxi y C1 -C6 -alquiltio;Ar arilo o heteroarilo, cuyos radicales pueden llevar uno o, cada uno independientemente del otro, dos o tres de los grupos siguientes: halógeno, ciano, C1 -C4 -alquilo, C1 -C4 -alcoxialquilo, C1 -C4 -halógenoalquilo, C1 -C4 -alcoxi, C1 -C4 halógenoalcoxi, C1 -C4 -alquiltio, C1 -C4 alcoxicarbonilo, arilo, ariloxi, en cuyos grupos los anillos pueden a su vez llevar uno o, cada uno independientemente del otro, dos o tres de los sustituyentes siguientes: halógeno, ciano, C1 -C4 -alquilo, C1 -C4 -alcoxialquilo, C1 -C4 -halógenoalquilo, C1 -C4 -alcoxi, C1 -C4 -halógenoalcoxi, C1 C4 -alquiltio y C1 -C4 alcoxicarbonilo, en una porción en peso del compuesto I y el compuesto II hasta V de 2500:1 a 1:500.Mixture for the protection of plants, which contain as active components a) derivatives of phenylacetic acid of the formula I in which the substituents and the index have the following meanings: X NOCH3, CHOCH3, CHCH3; YO, NRR1, R each independently of other, hydrogen and C1-C4 alkyl; R2 cyano, nitro, trifluoromethyl, halogen, C1-C4-alkyl and C1-C4-alkoxy; m 0, 1 or 2, the radicals R2 being different when m is 2; R3 hydrogen , cyano, C1-C4-alkyl, C1-C4-halogenoalkyl, C3-C6 -cycloalkyl; R4, R6 each independently of the other, hydrogen, C1-C10-alkyl, C3-C6 -cycloalkyl, C2-C10-alkenyl, C2-C10 -alkynyl, C1-C10 -alkylcarbonyl, C2 -C10 -alkenylcarbonyl, C3 -C10 -alkynylcarbonyl or C1-C10 -alkylsulfonyl, whose radicals may be partially or completely halogenated or carry from one to three of the following groups: cyano , nitro, hydroxy, mercapto, amino, carboxyl, aminocarbonyl, aminothiocarbonyl, ha halogen, C1-C6 -alkyl, C1-C6 -haloalkyl, C1-C6 -alkylsulfonyl, C1-C6 -alkylsulfoxyl, C1-C6 -alkoxy, C1-C6 -haloalkoxy, C1-C6 -alkoxycarbonyl, C1-C6 -alkylthio, C1-C6-alkylamino, di-C1-C6-alkylamino, C1-C6-alkylaminocarbonyl, di C1-C6-alkylaminocarbonyl, di-C1-C6-alkylamino-thiocarbonyl, C2-C6-alkenyl, C1-C6-alkenyloxy, C3-C6 - cycloalkyl, C3-C6-cycloalkyloxy, heterocyclyl, heterocyclyloxy, benzyl, benzyloxy, aryl, aryloxy, arylthio, hetaryl, heteroyloxy and hetarylthio, whose cyclic groups can in turn be partially or completely halogenated or lead to one to three of the following groups : cyano, nitro, hydroxy, mercapto, amino, carboxyl, aminocarbonyl, 2 aminothiocarbonyl, halogen, C1-C6 -alkyl, C1-C6 -haloalkyl, C1-C6 -alkylsulfonyl, C1-C6 -alkylsulfoxyl, C3-C6 -cycloalkyl, C1-C6 -alkoxy, C1-C6 -haloalkoxy, C1-C6 -alkyloxycarbonyl, C1-C6 -alkylthio, C1-C6 -alkylamino, di C1 -C6 -alq uylamino, C1-C6-alkylaminocarbonyl, di-C1-C6-alkylaminocarbonyl, C1-C6-alkylaminothiocarbonyl, di C1-C6-alkylamino-thiocarbonyl, C2-C6-alkenyl, C2-C6-alkenyloxy, benzyl, benzyloxy, aryl, aryloxy, aryloxy Hetaryl, heteroyloxy, hetarylthio or C (= NOR7) -An R8; Aryl, arylcarbonyl, arylsulfonyl, hetaryl, heteroarylcarbonyl or hetarylsulfonyl, whose radicals can be partially or completely halogenated or carry from one to three of the following groups: Cyano, nitro, hydroxy, mercapto, amino, carboxyl, aminocarbonyl, aminothiocarbonyl, halogen, C1-C6 -alkyl, C1-C6 -haloalkyl, C1-C6-alkylcarbonyl, C1-C6 -alkylsulfonyl, C1-C6 -alkylsulfoloxy, C3-C6 -cycloalkyl, C1-C6 -alkoxy, C1-C6 -haloalkoxy, C1-C6 -alkoxy, C1-C6 -haloalkoxy, C1-C6 -alkyloxycarbonyl, C1-C6 -alkylthio, C1-C6 -alkylamino, di C1 -C6 -alkylamino, C1 -C6 -alkylaminocarbonyl, di-C1-C6-alkylaminocarbinyl, C1-C6-alkylaminothiocarbonyl, di-C1-C6-al quilaminothiocarbonyl, C2-C6-alkenyl, C2-C6-alkenyloxy, benzyl, benzyloxy, aryl, aryloxy, hetaryl, heteroyloxy or C (= NOR7) -An-R8; R5 hydrogen, C1-C6-alkyl, C2-C6-alkenyl , C2-C6 -alkynyl, the hydrocarbon radicals of these groups being able to be partially or completely halogenated or carry one to three of the following radicals: cyano, nitro, hydroxy, mercapto, amino, carboxyl, aminocarbonyl, aminothiocarbonyl, halogen, C1 - C6-alkylaminocarbonyl, di-C1-C6-alkylaminocarbonyl, C1-C6-alkylamino-thiocarbonyl, di-C1-C6-alkylaminothiocarbonyl, C1-C6-alkylsulfonyl, C1-C6-alkylsulfoxyl, C1-C6-alkoxy, C1-C6 -haloalkoxy, C1 - C6 -alkoxycarbonyl, C1-C6 -alkylthio, C1-C6 -alkylamino, di C1 -C6 -alkylamino, C2 -C6 -alkenyloxy, C3 -C6 -cycloalkyl, C3-C6 -cycloalkyloxy, heterocyclyl, heterocyclyloxy, aryl, aryloxy, aryloxy C1-C4 -alkoxy, arylthio, aryl C1 -C4 -alkylthio, hetaryl, hetaryloxy, C1-C4 -alkoxy hetaryl, hetarylthio, hetar C1-C4-alkylthio, whose cyclic radicals can be partially or completely halogenated and / or carry from one to three of the following groups: cyano, nitro, hydroxy, mercapto, amino, carboxyl, aminocarbonyl, aminothiocarbonyl, C1- C6-alkyl, C1-C6-halogenoalkyl, C1-C6-alkylsulfonyl, C1-C6-alkyl-alkylfoxyl, C3-C6 cycloalkyl, C1-C6-alkoxy, C1-C6 halogenoalkoxy, C1-C6-alkoxycarbonyl, C1-C6-alkylthio, C1-C6-alkylamino, di-C1-C6-alkylamino, C1-C6-alkylaminocarbonyl, di C1-C6 alkylaminocarbonyl, C1-C6-alkylamino-thiocarbonyl, di-C1-C6-alkylaminothiocarbonyl, C2-C6-alkenyl, C2-C6-alkenyloxy benzyl, benzyloxy, aryl, aryloxy, arylthio, heteroaryl, hetaryloxy, hetarylthio and C (= NOR7) -An -R8; C3 C6 -cycloalkyl, C3-C6 -cycloalkenyl, heterocyclic, aryl, heteroaryl, whose cyclic radicals may be partial or completely halogenated or carry from one to three of the following groups: cyano, nitro, hydroxy, mercapto, amino, carboxyl, aminocarbonyl, aminothiocarbonyl, halogen, C1-C6-alkyl, C1-C6 -haloalkyl, C1-C6 alkylsulfonyl, C1-C6-alkylsulfoxyl, C3-C6 -cycloalkyl, C1-C6-alkoxy, C1-C6-halogenoalkoxy , C1-C6 alkoxycarbonyl, C1-C6-alkylthio, C1-C6-alkylamino, di-C1-C6-alkylamino, C1-C6 alkylaminocarbonyl, di C1-C6-alkylaminocarbonyl, C1-C6-alkylamino thiocarbonyl, di C1-C6 -alkylaminothiocarbonyl, C2-C6-alkenyl, C2-C6-alkenyloxy, benzyl, benzyloxy, aryl, aryloxy, hetaryl, hetaryloxy; meaning oxygen, sulfur or nitrogen and carrying hydrogen hydrogen or C1-C6-alkyl; n 0 or 1; R7 hydrogen or C 1 -C 6 -alkyl and R 8 hydrogen or C 1 -C 6 -alkyl, as well as its salts, and at least 3 b), a compound of the formulas II to Substituents having the following meanings: A C 3 -C 6 -cycloalkyl, which may carry from one to three substituents selected from the group containing halogen and C1-C3 -alkyl; R9 C1 -C6 -alkyl or C 2-C6 -alkenyl, whose radicals can be partially or completely halogenated and / or carry one or two of the following groups: C1-C4 -alkoxy C1 -C4 -haloalkoxy, C1-C4 -alkylthio, C1-C4 -alkoxycarbonyl, C3 -C6 -cycloalkyl and phenyl, the phenyl may be partially or completely halogenated and / or carry one to three of the following radicals; nitro, cyano, C1-C4-alkyl, C1-C4 halogenoalkyl, C1-C4 -alkoxy, C1-C4 -haloalkoxy, C1-C4-alkylthio, C3-C6 cycloalkyl or heterocyclic; R10, R11, R12 hydrogen or, independent, one of the meanings of the radical R9; n 0 or 1; Y cyano or halogen; W phenyl, naphthyl or heteroaryl, whose radicals can carry from one to three of the following groups: nitro, halogen, cyano, C1-C4-alkyl, C1-C4-halogenalkyl, C1-C4 -alkoxy, C1-C4 -halogen alkoxy, C1-C4 -alkylthio, C3-C6 cycloalkyl and C1-C4 -alkoxycarbonyl, R13 C6-C15 bicycloalkyl or C7 -C15 - bicycloalkenyl, whose radicals they can be completely halogenated and, provided they are not completely halogenated, two carbon atoms of these radicals can form together with a C3-C5-alkylidene group a saturated carboxylic ring of five to six members and / or carry one or, each independent on the other, two, three, four or five of the following groups: cyano, C1-C4 -alkyl, C1 -C4 -ha halogenoalkyl, C1-C4 -alkoxy, C1-C4-halogenoalkoxy and aryl, the aryl being able to be partially or completely halogenated and / or carry, each independent of the other, two or three of the following substituents: nitro, cyano, C1-C4 - alkyl, C1-C4-halogenoalkyl, C1-C4 -alkoxy, C1-C4 -haloalkoxy and C1-C4 -alkylthio; R14, R15, R16 each independently of the other, hydrogen, C1-C8 -alkyl, which may be partial or completely halogenated and / or carry one or two of the following groups: C1-C4 -alkoxy, C1-C4-halogenoalkoxy, C1-C4 -alkylthio, C3-C7 -cycloalkyl, C5 -C7 -cycloalkenyl, being able to cyclic groups carrying one or, independently, two or three halogen atoms, C1-C3-alkyl and / or C1-C3 -alkoxy and aryl groups, the aryl being able to be partially or completely halogenated and / or carry one or, each time independently, two or three of the following substituents: nitro, cyano, C1-C4-alkyl, C1-C4-halogenoalkyl, C1-C4 -alkoxy, C1-C4 halogenoalkoxy and C1-C4-alkylthio or C3-C6 -cycloalkyl, C3-C6 -cycloalkenyl or heterocyclic, the radicals of which may be partially or completely halogenated and / or independently carry two or three of the following groups: cyano, C 1 -C 6 -alkyl, C 1 -C 6 -haloalkyl, C 2 -C 6 -alkenyl, C 1 -C 6 -alkoxy and C 1 -C 6 -alkyl; Ar aryl or heteroaryl, the radicals of which can carry one or, each independently of the other, two or Three of the following groups: halogen, cyano, C1-C4 -alkyl, C1-C4 -alkoxyalkyl, C1-C4 -haloalkyl, C1-C4 -alkoxy, C1-C4 halogenoalkoxy, C1-C4 -alkylthio, C1-C4 alkoxycarbonyl, aryl, aryloxy, in whose groups the rings may in turn carry one or, each independently of the other, two or three of the following substituents: halogen, cyano, C1-C4-alkyl, C1-C4-alkoxyalkyl, C1-C4 -haloalkyl, C1-C4 -alkoxy, C1-C4 -haloalkoxy, C1 C4 -alkylthio and C1-C4 alkoxycarbonyl, in a portion by weight of the compound I and compound II up to V from 2500: 1 to 1: 500.

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