The automobile exhaust gas purifying silencing apparatus
[technical field]
The utility model relates to a kind of automobile exhaust gas purifying silencing apparatus, relates to a kind of automobile exhaust gas purifying silencing apparatus that adopts foaming metal as muffler material and catalyst carrier material in particular.
[background technique]
The seriousness of the environmental pollution that tail gas and exhaust sound caused of motor is well-known.To the control of the external purification and the exhaust sound of automobile exhaust, normally adopt independent of each other minute body structure of purifier and silencing apparatus, body structure not only caused engine power loss to increase in this minute, also can increase installation fee and cost of production.
In existing automobile exhaust purifier, catalyst carrier material is pottery and metal two classes.Compare shortcoming such as at present general honeycomb ceramic carrier exists temperature lower (1400 ℃ softening), element wall is thicker, preheating is slow, exhaust resistance is bigger with metallic carrier.Therefore, each state is all in the exploitation of carrying out metallic carrier.The metallic carrier wall thickness only is 1/4 of a ceramic monolith, thereby can reduce exhaust resistance.And make the catalyst carrier miniaturization become possibility; The thermal capacity of metallic carrier is little, and its pre-thermal characteristics is good, helps the enforcement that the electric preheating catalyzer is realized the zero-emission measure of HC, also has advantages such as thermal adaptability is good in addition.And the various structures that the metallic carrier of catalyzer is combined into based on the wavy metal net in the present Exhaust Gas Catalytic Converter for Automobiles, its heat shock resistance and mechanical shock performance are lower, oxidation resistance deficiency during high temperature has particularly influenced Exhaust Gas Catalytic Converter for Automobiles working life.In addition, the metallic carrier that this ripple is netted, its specific surface area is limited, and adsoption catalyst active component scarce capacity has limited the further raising of Exhaust Gas Catalytic Converter for Automobiles purification efficiency.
Existing automobile exhaust muffler system is usually based on reactive muffler, and is simple in structure because it is an all metal construction, can be high temperature resistant, corrosion-resistant, gasproof stream impacts, and the life-span is long.But the noise elimination frequency band of reactive muffler is narrower, in, low frequency noise elimination effect is better, high frequency is relatively poor.In order to remedy the defective of its high frequency noise elimination weak effect, often to need to adopt multistage combination be multistage silencing apparatus or impedance complex formula silencing apparatus etc. to high frequency noise elimination effect structure preferably, finishes the noise elimination of automobile exhaust system.Increase difficulty of processing so on the one hand, also improved the noise elimination cost on the other hand.
Existing sound-absorbing material generally adopts high temperature resistant, the corrosion resistant aluminium wire felt of energy, asbestos rope felt etc., is fixed with the pavement structure that can firmly be fixed again.This silencing apparatus is anti-to be washed away, humidity and dust-fast effect are relatively poor, and working life is shorter, and the effect of eliminating the noise simultaneously is also relatively poor, therefore also fails at present generally to be used at automotive field.
[model utility content]
The utility model provides that a kind of energy is high temperature resistant, corrosion-resistant, gasproof stream impacts, and long service life hands over cleaning of off-gas performance and acoustic attenuation performance good, simple in structure simultaneously, the easy integrated car exhaust purging muffler of processing.
The utility model comprises metal shell, the two ends of shell are connected with steam outlet pipe with suction tude respectively, be equipped with in the shell and purify and the noise elimination device, described device heart porous material is a carrier, this carrier to small part is the foaming metal material, the aperture of the foaming micropore of foaming metal material is the 50-1200 micron, and the porosity ratio of the foaming metal material ratio of material total volume (volume of air of porous material with) is 80-98%, and the foaming metal material surface is attached with catalyst coat.
Described foaming metal material can be provided with along the direction segmentation vertical with airflow direction, leaves cavity between section and the section.The foaming metal material also can be in the single or multiple lift mode with the direction setting parallel with airflow direction, between each foaming metal material layer and and outer casing inner wall between leave cavity.The thickness of described foaming metal material is the 10-40 millimeter, and the thickness of described cavity is the 10-50 millimeter.
Described foaming metal material comprises nickel, iron, copper, aluminium, titanium and the alloy thereof of the shape that foams.
Described catalyst coat component comprises metallic element, rare earth metal and small amount of precious metals, and wherein metallic element comprises one or more among calcium Ca, barium Ba, magnesium Mg, zirconium Zr, zinc Zn, the aluminium Al; Rare earth metal comprises one or more among cerium Ce, lanthanum La, praseodymium Pr, the neodymium Nu; Precious metal comprises one or more among palladium Pb, platinum Pt, rhodium Rh, the ruthenium Ru.
Also can add in gama-alumina, zirconium oxide, the cerium oxide one or more in the described catalyst coat component.
The utility model is simple in structure, process easy, long service life.In wider frequency, all has good acoustic attenuation performance; And heat shock resistance and mechanical shock, specific surface area is big, the purification efficiency height.
[description of drawings]
Fig. 1 is the structural representation of first kind of mode of execution of the utility model automobile exhaust gas purifying silencing apparatus;
Fig. 2 is the structural representation of second kind of mode of execution of the utility model automobile exhaust gas purifying silencing apparatus;
Fig. 3 is that the A of Fig. 2 is to view;
Fig. 4 is the structural representation of the third mode of execution of the utility model automobile exhaust gas purifying silencing apparatus;
Fig. 5 is the structural representation of the 4th kind of mode of execution of the utility model automobile exhaust gas purifying silencing apparatus;
In conjunction with example the utility model is described in further detail with reference to the accompanying drawings:
[embodiment]
[embodiment one]
As shown in Figure 1, comprise metal shell 2, the two ends of shell 2 are connected with steam outlet pipe 4 with suction tude 2 respectively (can establish clamp flange on suction tude and the steam outlet pipe, figure does not show), and foaming metal material 3 is housed in the shell 2.The porosity ratio of foaming metal material can be between 80-98%, and the aperture can be between the 50-1200 micron, and the foaming metal material surface is attached with catalyst coat.Sound-absorbing material 3 segmentations (among the figure be two sections, can be divided into multistage in actual use) are arranged in the metal shell 2 along the direction vertical with airflow direction, leave cavity between the sound-absorbing material 3 of segmentation setting.The thickness of foaming metal material can be between the 10-40 millimeter, and the thickness of cavity can be between the 10-50 millimeter.
Above-mentioned foaming metal material can comprise: elemental metals that nickel, iron, titanium are formed or the alloy that is made of above-mentioned metal.Also can be AB type alloy, wherein component A is a kind of in nickel, iron, the titanium, and its content accounts for 55-95% (weight percentage), and component B is one or more in chromium, aluminium, cobalt, molybdenum, the zinc, and its content accounts for 5-45% (weight percentage).
Catalyst coat component attached to the foaming metal surface comprises metallic element, rare earth metal and small amount of precious metals, and wherein metallic element comprises one or more among calcium Ca, barium Ba, magnesium Mg, zirconium Zr, zinc Zn, the aluminium Al; Rare earth metal comprises one or more among cerium Ce, lanthanum La, praseodymium Pr, the neodymium Nu; Precious metal comprises one or more among palladium Pb, platinum Pt, rhodium Rh, the ruthenium Ru.
Also can add in gama-alumina, zirconium oxide, the cerium oxide one or more in the described catalyst coat component.
Foaming metal material pore size is very big to the performance impact of whole tail gas clean-up, when the aperture was 50~1200 microns, changing effect was better, when the aperture is 400~800 microns, its changing effect optimum, foaming metal material pore size has very big influence to sound absorbing capabilities simultaneously.Its acoustic absorptivity rises earlier from low to high along with the increase in aperture presents one, and downward trend from high to low can obtain best acoustically effective in the time of between 200-1200 again.Simultaneously, the foaming metal material is better than low frequency part at the acoustically effective of HFS.
Because of a little, by leaving cavity between sound-absorbing material 3, and the mode that reasonably increases the thickness of material improves the sound absorbing capabilities of silencing apparatus, especially at the sound absorbing capabilities of low frequency part.Cavity objectively also can play the effect that increases material thickness, and this is equivalent to prolong effective length capillaceous, can reduce the consumption of material thus, has reduced cost.Can also improve simultaneously the sound absorbing capabilities of sound absorbing capabilities, the especially low frequency part of material.Studies have shown that, when the thickness of foaming metal material between the 10-40 millimeter, the thickness of cavity is between the 10-50 millimeter time, just can effectively improve acoustically effective, particularly the acoustically effective of low frequency part makes the utility model can both obtain good acoustically effective in the frequency range of a broadness.
The porosity ratio of foaming metal material also has bigger influence for specific surface area, purifying property, sound absorbing capabilities and the gas-flow resistance of material attached catalyst carrier, but, if the porosity ratio of material is brought up to 98% when above, not only also relatively difficult at present at technical elements, and it is uneconomical, and can influence the mechanical strength of material, reduce its erosion resistibility.Therefore the porosity ratio of foaming metal material being defined as 80-98% is a best scope.
[embodiment two]
As shown in Figures 2 and 3, the foaming metal material adopts along modes such as the direction parallel with airflow direction are provided with, also can form air-flow path between the centre of the sound-absorbing material 3 that the foaming metal material is made and sound-absorbing material 3 and metal shell 2.Like this, littler to the exhaust resistance of motor, but acoustically effective has decline slightly.So the quantity of the foaming metal material 3 that is provided with can be one deck or multilayer.Between each foaming metal material layer and and outer casing inner wall between leave cavity.The optimum thickness of foaming metal material is between the 10-40 millimeter, and the optimum thickness of cavity is between the 10-50 millimeter.
[embodiment three]
As shown in Figure 4, in metal shell 2, preceding half section is adopted foaming metal 3 as muffler material, and the second half section is adopted the metallic carrier of wavy metal net 5 as catalyzer, and all the other are identical with embodiment one.
[embodiment four]
As shown in Figure 5, in metal shell 2, adopt foaming metal 3 and the wavy metal tennis 5 section gap settings that are attached with catalyzer, every intersegmental interval 6 that is provided with, all the other are identical with embodiment one.
The various embodiments described above of employing the utility model tail-gas purifying silencer are used for general car and detect, and tail gas clean-up effect and elimination noiseproof feature all are better than state specified standards.
The foregoing description just embodies the preferred version of the utility model basic ideas; those skilled in the art to wherein some part some changes that may make all embodied principle of the present utility model, belong within the protection domain of the present utility model.