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CN212077161U - A high pressure water electrolyzer - Google Patents

A high pressure water electrolyzer Download PDF

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CN212077161U
CN212077161U CN202020496444.XU CN202020496444U CN212077161U CN 212077161 U CN212077161 U CN 212077161U CN 202020496444 U CN202020496444 U CN 202020496444U CN 212077161 U CN212077161 U CN 212077161U
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cathode
anode
end cover
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membrane electrode
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范钦柏
张华农
陈宏�
高鹏然
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Shenzhen Hydrogen Fuel Cell Co ltd
Shenzhen Center Power Tech Co Ltd
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Shenzhen Center Power Tech Co Ltd
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Abstract

本实用新型涉及一种高压水电解器,属于电解器技术领域。所述高压水电解器,包括套体、上端盖、下端盖、第一弹性密封垫、第二弹性密封垫、阳极接线端子、阴极接线端子;所述阳极接线端子与所述阴极接线端子之间设置有膜电极组件及双极板;所述阳极接线端子与所述膜电极组件之间、所述阴极接线端子与所述膜电极组件之间及所述双极板与所述膜电极组件之间均设置有密封环;所述阳极接线端子、阴极接线端子及双极板均为六边形结构;所述上端盖、下端盖、第一弹性密封垫、第二弹性密封垫、膜电极组件为与所述六边形外圆大小相等的圆形结构。本实用新型的高压水电解器压降小、结构稳定好及寿命长,具有广阔的应用前景。

Figure 202020496444

The utility model relates to a high-pressure water electrolyzer, which belongs to the technical field of electrolyzers. The high-pressure water electrolyzer includes a casing, an upper end cover, a lower end cover, a first elastic gasket, a second elastic gasket, an anode connection terminal, and a cathode connection terminal; between the anode connection terminal and the cathode connection terminal A membrane electrode assembly and a bipolar plate are provided; between the anode connection terminal and the membrane electrode assembly, between the cathode connection terminal and the membrane electrode assembly, and between the bipolar plate and the membrane electrode assembly A sealing ring is arranged between them; the anode terminal, the cathode terminal and the bipolar plate are all hexagonal structures; the upper end cover, the lower end cover, the first elastic sealing gasket, the second elastic sealing gasket, the membrane electrode assembly It is a circular structure with the same size as the outer circle of the hexagon. The high-pressure water electrolyzer of the utility model has the advantages of small pressure drop, good structure stability and long service life, and has broad application prospects.

Figure 202020496444

Description

一种高压水电解器A high pressure water electrolyzer

技术领域technical field

本实用新型属于电解器技术领域,尤其涉及一种高压水电解器。The utility model belongs to the technical field of electrolyzers, in particular to a high-pressure water electrolyzer.

背景技术Background technique

随着新能源的发展日新月异,新能源汽车已经走进人们的生活,由于其“零排放”的特点,已经逐渐成为各大厂商争先发展的对象。新能源汽车通过氢气与氧气分别在化学电解质中的电解及反应产生可驱动发动机的电流,其中反应的氧气从空气中即可获取,而氢气则需要通过氢气发生器获取。With the rapid development of new energy, new energy vehicles have entered people's lives. Due to their "zero emission" characteristics, they have gradually become the target of major manufacturers. New energy vehicles generate electric current that can drive the engine through the electrolysis and reaction of hydrogen and oxygen in chemical electrolytes respectively. The reacted oxygen can be obtained from the air, while hydrogen needs to be obtained through a hydrogen generator.

目前最常用的氢气发生器为水电解器,通过水的电解产生氢气和氧气的原理从中获取氢气,然后经过干燥压缩存放在高压储气瓶中进行加氢。最近发展起来的高压电解器有望取代常压电解器,特别是没有机械压缩机,使电解加氢变成简单易行。在高压电解器中,双极板作为高压水电解器的重要元件,其结构直接关系到电解器的稳定性、产氢效率等重要因素。市面上的高压水电解器大多为圆柱形结构,圆柱形结构有利于电解器的耐高压,其双极板也为圆形结构,而圆形结构的双极板要考虑水在流道中所走的流程压降,由于圆形双极板具有弧度,其压降必定会增大,从而影响电解器的结构稳定性。At present, the most commonly used hydrogen generator is a water electrolyzer. Hydrogen is obtained from the principle of generating hydrogen and oxygen through the electrolysis of water, and then it is dried and compressed and stored in a high-pressure gas storage bottle for hydrogenation. The recently developed high-pressure electrolyzers are expected to replace atmospheric-pressure electrolyzers, especially without mechanical compressors, making electrolytic hydrogenation simple and easy. In the high-pressure electrolyzer, the bipolar plate is an important component of the high-pressure water electrolyzer, and its structure is directly related to the stability of the electrolyzer, hydrogen production efficiency and other important factors. Most of the high-pressure water electrolyzers on the market have a cylindrical structure. The cylindrical structure is beneficial to the high pressure resistance of the electrolyzer. Due to the arc of the circular bipolar plate, its pressure drop will definitely increase, thus affecting the structural stability of the electrolyzer.

实用新型内容Utility model content

本实用新型的目的在于提供一种高压水电解器,用于现场加氢,实现从电到储氢罐的直接耦合,以解决现有技术中高压水电解器由于内部结构压降大,气体和水分配不均匀,导致电解器稳定性差及寿命短等问题。The purpose of this utility model is to provide a high-pressure water electrolyzer, which is used for on-site hydrogenation, and realizes the direct coupling from electricity to the hydrogen storage tank, so as to solve the problem that the high-pressure water electrolyzer in the prior art has a large pressure drop in the internal structure, gas and The uneven distribution of water leads to problems such as poor stability and short life of the electrolyzer.

为实现上述目的,本实用新型通过以下技术方案实现:In order to achieve the above object, the utility model realizes through the following technical solutions:

一种高压水电解器,包括套体,设置于所述套体一端的上端盖、设置于所述上端盖内侧的第一弹性密封垫、设置于所述第一弹性密封垫内侧的阳极接线端子,设置于所述套体另一端的下端盖、设置于所述下端盖内侧的第二弹性密封垫、设置于所述第二弹性密封垫内侧的阴极接线端子,以及设置于所述阳极接线端子与所述阴极接线端子之间的多个膜电极组件及多个双极板,相邻的所述膜电极组件之间设置有所述双极板;所述阳极接线端子和所述阴极接线端子均与所述膜电极组件相邻设置;A high-pressure water electrolyzer, comprising a sleeve body, an upper end cover disposed at one end of the sleeve body, a first elastic sealing gasket disposed inside the upper end cover, and an anode terminal disposed inside the first elastic sealing gasket , a lower end cover arranged on the other end of the sleeve body, a second elastic gasket arranged on the inner side of the lower end cover, a cathode connection terminal arranged inside the second elastic gasket, and a cathode connection terminal arranged on the anode connection terminal A plurality of membrane electrode assemblies and a plurality of bipolar plates between the cathode connection terminals, the bipolar plates are arranged between the adjacent membrane electrode assemblies; the anode connection terminal and the cathode connection terminal are arranged adjacent to the membrane electrode assembly;

所述阳极接线端子与所述膜电极组件之间、所述阴极接线端子与所述膜电极组件之间以及所述双极板与所述膜电极组件之间均设置有密封环;A sealing ring is provided between the anode connection terminal and the membrane electrode assembly, between the cathode connection terminal and the membrane electrode assembly, and between the bipolar plate and the membrane electrode assembly;

所述阳极接线端子、所述阴极接线端子、及所述双极板均为正六边形结构,所述上端盖、下端盖、第一弹性密封垫、第二弹性密封垫、膜电极组件为与所述正六边形结构的外圆大小相等的圆形结构;所述密封环的直径与所述正六边形结构的内圆的直径相等。The anode terminal, the cathode terminal, and the bipolar plate are all regular hexagonal structures. The outer circle of the regular hexagonal structure is a circular structure with the same size; the diameter of the sealing ring is equal to the diameter of the inner circle of the regular hexagonal structure.

进一步地,所述圆形结构上对应周向设置有多个螺丝孔,所述螺丝孔设置于所述圆形结构与所述正六边形结构相对应的内接正六边形的外侧。Further, the circular structure is provided with a plurality of screw holes corresponding to the circumferential direction, and the screw holes are arranged on the outer side of the inscribed regular hexagon corresponding to the circular structure and the regular hexagonal structure.

进一步地,所述螺丝孔上设置有螺丝,所述上端盖、下端盖、第一弹性密封垫、第二弹性密封垫、及膜电极组件通过所述螺丝连接固定。这样设置,可以增强结构的稳定性,螺丝孔设置于所述内接正六边形的外侧,因此所述螺丝不与所述阳极接线端子、阴极接线端子及双极板接触。通过密封环将所述阳极接线端子与所述膜电极组件之间的空间、所述阴极接线端子与所述膜电极组件之间的空间、以及所述双极板与所述膜电极组件之间的空间密封起来,这样可以形成为阳极板及阴极板供水的密封空间,有效防止水及气体的泄漏。Further, the screw holes are provided with screws, and the upper end cover, the lower end cover, the first elastic sealing gasket, the second elastic sealing gasket, and the membrane electrode assembly are connected and fixed by the screws. In this way, the stability of the structure can be enhanced, and the screw holes are arranged on the outer side of the inscribed regular hexagon, so the screws do not contact the anode terminal, the cathode terminal and the bipolar plate. The space between the anode terminal and the membrane electrode assembly, the space between the cathode terminal and the membrane electrode assembly, and the space between the bipolar plate and the membrane electrode assembly are sealed by sealing rings In this way, a sealed space for supplying water to the anode plate and the cathode plate can be formed, and the leakage of water and gas can be effectively prevented.

所述阳极接线端子、阴极接线端子以及双极板设置为正六边形结构,使其在圆形结构内具有最大反应面积的同时,有利于气体和液体的均匀分配,同时减小高压水电解器的压降,增强结构的稳定性。The anode terminal, the cathode terminal and the bipolar plate are arranged in a regular hexagonal structure, so that it has the largest reaction area in the circular structure, and is conducive to the uniform distribution of gas and liquid, and at the same time reduces the high-pressure water electrolyzer. The pressure drop increases the stability of the structure.

进一步地,所述正六边形结构的端角设置为与所述套体的内壁相切的圆角结构,这样可以进一步增强整体结构的稳定性。Further, the end corners of the regular hexagonal structure are set as rounded corner structures tangent to the inner wall of the sleeve body, which can further enhance the stability of the overall structure.

进一步地,所述双极板的表面设置有氧化物涂层、贵金属涂层或氮化层等,用以增强双极板的耐腐蚀性。Further, the surface of the bipolar plate is provided with an oxide coating, a noble metal coating or a nitride layer, etc., to enhance the corrosion resistance of the bipolar plate.

进一步地,所述上端盖、下端盖、第一弹性密封垫、第二弹性密封垫、阳极接线端子、阴极接线端子、膜电极组件、以及双极板上均相对应地设置有用于进水的第一通孔和第二通孔、用于出水及输出产生的氧气的第三通孔、及用于出水及输出产生的氢气的第四通孔。Further, the upper end cap, the lower end cap, the first elastic sealing gasket, the second elastic sealing gasket, the anode terminal, the cathode terminal, the membrane electrode assembly, and the bipolar plate are all provided with corresponding water inlets. A first through hole and a second through hole, a third through hole for water outlet and output of generated oxygen, and a fourth through hole for water outlet and output of generated hydrogen.

进一步地,所述阳极接线端子在靠近所述上端盖的一侧面的几何中心设置有阳极接线柱;所述上端盖及所述第一弹性密封垫的几何中心均设置有与所述阳极接线柱相适配的第五通孔,所述阳极接线柱穿过所述第五通孔与外部电源线连接。Further, the anode terminal is provided with an anode terminal at the geometric center of one side face close to the upper end cover; the upper end cover and the geometric center of the first elastic gasket are both provided with the anode terminal. A matching fifth through hole through which the anode terminal is connected to an external power line.

进一步地,所述阴极接线端子在靠近所述下端盖的一侧面的几何中心设置有阴极接线柱;所述下端盖及所述第二弹性密封垫的几何中心均设置有与所述阴极接线柱相适配的第六通孔,所述阴极接线柱穿过所述第六通孔与外部电源线连接。Further, the cathode connection terminal is provided with a cathode connection post at the geometric center of a side face close to the lower end cover; the geometric center of the lower end cover and the second elastic sealing gasket is provided with the cathode connection post. A matching sixth through hole through which the cathode terminal is connected to an external power line.

进一步地,所述膜电极组件包括隔膜、设置于所述隔膜靠近所述阳极接线端子一侧的阳极板及设置于所述隔膜靠近所述阴极接线端子一侧的阴极板。Further, the membrane electrode assembly includes a diaphragm, an anode plate disposed on the side of the diaphragm close to the anode connection terminal, and a cathode plate disposed on the side of the diaphragm close to the cathode connection terminal.

进一步地,所述阳极接线端子与距离所述阳极接线端子最近的所述隔膜之间形成的密闭区间、以及所述双极板与距离所述双极板最近的所述隔膜之间形成的密闭区间均为阳极室,且形成所述阳极室的所述双极板与所述隔膜之间设置有阳极板;位于所述阳极室的所述第二通孔、第四通孔内设置有第一导管。所述第一导管用于将阳极室的水流及产生的氧气与第二通孔、第四通孔隔绝起来。Further, the airtight area formed between the anode connection terminal and the diaphragm closest to the anode connection terminal, and the airtight area formed between the bipolar plate and the diaphragm closest to the bipolar plate Each section is an anode chamber, and an anode plate is arranged between the bipolar plate and the diaphragm forming the anode chamber; a second through hole and a fourth through hole located in the anode chamber are arranged a conduit. The first conduit is used to isolate the water flow and the generated oxygen in the anode chamber from the second through hole and the fourth through hole.

进一步地,所述阴极接线端子与距离所述阴极接线端子最近的所述隔膜之间形成的密闭区间、以及所述双极板与距离所述双极板最近的所述隔膜之间形成的密闭区间均为阴极室,且形成所述阴极室的所述双极板与所述隔膜之间设置有阴极板;位于所述阴极室的所述第一通孔、第三通孔内设置有第二导管。所述第二导管用于将阴极室的水流及产生的氢气与第一通孔、第三通孔隔绝起来。Further, the airtight area formed between the cathode connection terminal and the diaphragm closest to the cathode connection terminal, and the airtight area formed between the bipolar plate and the diaphragm closest to the bipolar plate The intervals are all cathode chambers, and a cathode plate is arranged between the bipolar plate and the diaphragm that form the cathode chamber; a first through hole and a third through hole located in the cathode chamber are provided Two conduits. The second conduit is used to isolate the water flow in the cathode chamber and the generated hydrogen gas from the first through hole and the third through hole.

进一步地,所述第一导管和所述第二导管的外侧均设置有弹性密封圈。弹性密封圈使得所述第一导管与位于所述阳极室的所述第二通孔、所述第四通孔之间密封配合,所述第二导管与位于所述阴极室的所述第一通孔、所述第三通孔之间密封配合。这样设置使得第一导管与第二通孔、第四通孔之间,第二导管与第一通孔、第三通孔之间完全密封配合,防止水中的氢气和氧气混合到一起。Further, elastic sealing rings are provided on the outer sides of the first conduit and the second conduit. The elastic sealing ring enables the first conduit to be sealed with the second through hole and the fourth through hole in the anode chamber, and the second conduit and the first conduit in the cathode chamber. The through hole and the third through hole are in sealing cooperation. In this way, the first conduit and the second through hole and the fourth through hole and between the second conduit and the first through hole and the third through hole are completely sealed to prevent the hydrogen and oxygen in the water from being mixed together.

水流从上端盖的第一通孔流入,流经阳极室电解产生氧气,产生的氧气与水流一起从下端盖的第三通孔处流出;水流从上端盖的第二通孔流入,流经阴极室电解产生氢气,产生的氢气与水流一起从下端盖的第四通孔流出;第三通孔和第四通孔外部分别与气液分离器连接,经气液分离器分离后得到纯氢气与纯氧气。The water flows in from the first through hole of the upper end cap, and flows through the anode chamber to electrolyze to generate oxygen, and the generated oxygen flows out from the third through hole of the lower end cap together with the water flow; the water flow flows in from the second through hole of the upper end cap and flows through the cathode Hydrogen is generated by electrolysis in the chamber, and the generated hydrogen flows out from the fourth through hole of the lower end cover together with the water flow; the outside of the third through hole and the fourth through hole are respectively connected with a gas-liquid separator, and after separation by the gas-liquid separator, pure hydrogen and pure oxygen.

进一步地,所述阳极接线柱与所述阴极接线柱的外侧设置有绝缘护套,防止阳极接线柱与上端盖、阴极接线柱与下端盖之间漏电,提高了使用安全性。Further, an insulating sheath is provided on the outside of the anode terminal and the cathode terminal to prevent electric leakage between the anode terminal and the upper end cover, and the cathode terminal and the lower end cover, thereby improving the safety in use.

进一步地,所述第一弹性密封垫、第二弹性密封垫均为绝缘橡胶材质密封垫,既隔绝电流,又为电解器在受压情况下提供膨胀空间。Further, the first elastic sealing gasket and the second elastic sealing gasket are both insulating rubber material sealing gaskets, which not only isolates the current, but also provides expansion space for the electrolyzer under pressure.

本实用新型提出的技术方案中,具有以下有益效果:In the technical scheme proposed by the utility model, it has the following beneficial effects:

1.阳极接线端子、阴极接线端子与双极板均设计为六边形结构,使其在圆形结构内具有最大反应面积的同时,有利于气体和液体的均匀分配,同时减小高压水电解器的压降,增强结构的稳定性。1. The anode terminal, cathode terminal and bipolar plate are all designed in a hexagonal structure, so that it has the largest reaction area in the circular structure, and is conducive to the uniform distribution of gas and liquid, while reducing high-pressure water electrolysis reduce the pressure drop of the device and enhance the stability of the structure.

2.阳极接线端子、阴极接线端子及双极板的六边形结构的端角设置为与所述套体内壁相切的圆角结构,这样可以使得阳极接线端子、阴极接线端子和双极板的外侧圆角处与套体内壁完全贴附,进一步增强整体结构的稳定性。2. The end corners of the hexagonal structure of the anode terminal, the cathode terminal and the bipolar plate are set as the rounded structure tangent to the inner wall of the sleeve, so that the anode terminal, the cathode terminal and the bipolar plate can be formed. The outer rounded corners of the sleeve are completely attached to the inner wall of the sleeve, which further enhances the stability of the overall structure.

3.所述双极板的表面设置有氧化物涂层、贵金属涂层和氮化层等,使得双极板不易被电解质润湿,也可避免电解质流失;且通过对双极板进行涂层从而增强双极板的耐腐蚀性,可以提高高压水电解器的寿命。3. The surface of the bipolar plate is provided with an oxide coating, a precious metal coating, a nitride layer, etc., so that the bipolar plate is not easily wetted by the electrolyte, and the loss of the electrolyte can also be avoided; and by coating the bipolar plate Thereby, the corrosion resistance of the bipolar plate is enhanced, and the service life of the high-pressure water electrolyzer can be improved.

附图说明Description of drawings

图1为本实用新型一实施例的高压水电解器的结构爆炸图。1 is an exploded view of the structure of a high-pressure water electrolyzer according to an embodiment of the present invention.

具体实施方式Detailed ways

下面将结合本实用新型实施例中的附图,对本实用新型实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本实用新型的一部分实施例,而不是全部的实施例。基于本实用新型中的实施例,本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其他实施例,都属于本实用新型保护的范围。The technical solutions in the embodiments of the present utility model will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present utility model. Obviously, the described embodiments are only a part of the embodiments of the present utility model, but not all of them. Example. Based on the embodiments of the present invention, all other embodiments obtained by those of ordinary skill in the art without creative work fall within the protection scope of the present invention.

需要说明,若本实用新型实施例中有涉及方向性指示(诸如上、下、左、右、前、后、顶、底……),则该方向性指示仅用于解释在某一特定姿态(如附图所示)下各部件之间的相对位置关系、运动情况等,如果该特定姿态发生改变时,则该方向性指示也相应地随之改变。It should be noted that if there are directional indications (such as up, down, left, right, front, back, top, bottom...) involved in the embodiments of the present invention, the directional indications are only used to explain a certain posture (As shown in the attached drawings), when the relative positional relationship, movement situation, etc. between the lower components, if the specific posture changes, the directional indication also changes accordingly.

在本申请中,除非另有明确的规定和限定,术语“安装”、“相连”、“连接”、“固定”等术语应做广义理解,例如,可以是固定连接,也可以是可拆卸连接,或成一体;可以是机械连接,也可以是电连接;可以是直接相连,也可以通过中间媒介间接相连,可以是两个元件内部的连通或两个元件的相互作用关系,除非另有明确的限定。对于本领域的普通技术人员而言,可以根据具体情况理解上述术语在本申请中的具体含义。In this application, unless otherwise expressly specified and limited, the terms "installed", "connected", "connected", "fixed" and other terms should be understood in a broad sense, for example, it may be a fixed connection or a detachable connection , or integrated; it can be a mechanical connection or an electrical connection; it can be directly connected or indirectly connected through an intermediate medium, it can be the internal connection of two elements or the interaction relationship between the two elements, unless otherwise specified limit. For those of ordinary skill in the art, the specific meanings of the above terms in this application can be understood according to specific situations.

需要说明的是,当元件被称为“固定于”或“设置于”另一个元件,它可以直接在另一个元件上或者也可以存在居中的元件。当一个元件被认为是“连接”另一个元件,它可以是直接连接到另一个元件或者可能同时存在居中元件。It should be noted that when an element is referred to as being "fixed to" or "disposed on" another element, it can be directly on the other element or an intervening element may also be present. When an element is referred to as being "connected" to another element, it can be directly connected to the other element or intervening elements may also be present.

另外,若本实用新型实施例中有涉及“第一”、“第二”等的描述,则该“第一”、“第二”等的描述仅用于描述目的,而不能理解为指示或暗示其相对重要性或者隐含指明所指示的技术特征的数量。由此,限定有“第一”、“第二”的特征可以明示或者隐含地包括至少一个该特征。另外,各个实施例之间的技术方案可以相互结合,但是必须是以本领域普通技术人员能够实现为基础,当技术方案的结合出现相互矛盾或无法实现时应当认为这种技术方案的结合不存在,也不在本实用新型要求的保护范围之内。In addition, if there are descriptions involving "first", "second", etc. in the embodiments of the present invention, the descriptions of "first", "second", etc. are only for the purpose of description, and should not be construed as instructions or Implicit their relative importance or implicitly indicate the number of technical features indicated. Thus, a feature delimited with "first", "second" may expressly or implicitly include at least one of that feature. In addition, the technical solutions between the various embodiments can be combined with each other, but must be based on the realization by those of ordinary skill in the art. When the combination of technical solutions is contradictory or cannot be realized, it should be considered that the combination of such technical solutions does not exist. , is not within the scope of protection required by the present utility model.

为了简化结构,本实施例设置有两个膜电极组件,在其他实施例中可根据实际需要设置多个所述膜电极组件以增加阴极和阳极的反应面积,从而保证氢气及氧气的产量。In order to simplify the structure, this embodiment is provided with two membrane electrode assemblies. In other embodiments, multiple membrane electrode assemblies can be provided according to actual needs to increase the reaction area of the cathode and the anode, thereby ensuring the production of hydrogen and oxygen.

如图1所示,本实用新型提供一种高压水电解器,包括套体10,设置于所述套体10一端的上端盖20、设置于所述上端盖20内侧的第一弹性密封垫40、设置于所述第一弹性密封垫40内侧的阳极接线端子60、设置于所述套体10另一端的下端盖30、设置于所述下端盖30内侧的第二弹性密封垫50、设置于所述第二弹性密封垫50内侧的阴极接线端子70、以及设置于所述阳极接线端子60与所述阴极接线端子70之间的多个膜电极组件90及多个双极板100,相邻的所述膜电极组件90之间设置有所述双极板100,所述阳极接线端子60和所述阴极接线端子70均与所述膜电极组件相邻设置;As shown in FIG. 1 , the present invention provides a high-pressure water electrolyzer, comprising a sleeve body 10 , an upper end cover 20 disposed at one end of the sleeve body 10 , and a first elastic sealing gasket 40 disposed inside the upper end cover 20 . , the anode terminal 60 arranged on the inner side of the first elastic gasket 40, the lower end cover 30 arranged on the other end of the casing 10, the second elastic gasket 50 arranged on the inner side of the lower end cover 30, The cathode connection terminal 70 inside the second elastic sealing gasket 50, and the plurality of membrane electrode assemblies 90 and the plurality of bipolar plates 100 disposed between the anode connection terminal 60 and the cathode connection terminal 70 are adjacent to each other. The bipolar plate 100 is arranged between the membrane electrode assemblies 90, and the anode terminal 60 and the cathode terminal 70 are arranged adjacent to the membrane electrode assembly;

所述阳极接线端子60与所述膜电极组件90之间、所述阴极接线端子70与所述膜电极组件90之间以及所述双极板100与所述膜电极组件90之间均设置有密封环80;Between the anode terminal 60 and the membrane electrode assembly 90 , between the cathode terminal 70 and the membrane electrode assembly 90 , and between the bipolar plate 100 and the membrane electrode assembly 90 , sealing ring 80;

所述阳极接线端子60、阴极接线端子70和双极板100均为正六边形结构,所述上端盖20、下端盖30、第一弹性密封垫40、第二弹性密封垫50、膜电极组件90为与所述正六边形结构的外圆大小相等的圆形结构;所述密封环80的直径与所述正六边形结构的内圆的直径相等。The anode terminal 60, the cathode terminal 70 and the bipolar plate 100 are all regular hexagonal structures, the upper end cap 20, the lower end cap 30, the first elastic gasket 40, the second elastic gasket 50, the membrane electrode assembly 90 is a circular structure with the same size as the outer circle of the regular hexagonal structure; the diameter of the sealing ring 80 is equal to the diameter of the inner circle of the regular hexagonal structure.

作为优选的实施例,所述圆形结构上对应周向设置有多个螺丝孔1000,所述螺丝孔1000设置于所述圆形结构与所述正六边形结构相对应的内接正六边形的外侧。As a preferred embodiment, the circular structure is provided with a plurality of screw holes 1000 corresponding to the circumferential direction, and the screw holes 1000 are arranged in the inscribed regular hexagon corresponding to the circular structure and the regular hexagonal structure outside.

作为优选的实施例,所述螺丝孔1000上设置有螺丝(图中未标识),所述上端盖20、下端盖30、第一弹性密封垫40、第二弹性密封垫50、及膜电极组件90通过所述螺丝连接固定,这样设置可以增强结构的稳定性。螺丝孔1000设置于所述内接正六边形的外侧,因此所述螺丝不与所述阳极接线端子60、阴极接线端子70及双极板100接触。通过所述密封环80将所述阳极接线端子60与所述膜电极组件90之间的空间、所述阴极接线端子70与所述膜电极组件90之间的空间密封起来,这样可以形成为阳极板及阴极板供水的密封空间,有效防止水及气体的泄漏。As a preferred embodiment, the screw holes 1000 are provided with screws (not marked in the figure), the upper end cover 20 , the lower end cover 30 , the first elastic sealing gasket 40 , the second elastic sealing gasket 50 , and the membrane electrode assembly 90 is fixed by the screw connection, and this arrangement can enhance the stability of the structure. The screw holes 1000 are arranged on the outer side of the inscribed regular hexagon, so the screws do not contact the anode terminal 60 , the cathode terminal 70 and the bipolar plate 100 . The space between the anode connection terminal 60 and the membrane electrode assembly 90 and the space between the cathode connection terminal 70 and the membrane electrode assembly 90 are sealed by the sealing ring 80, so that an anode can be formed The sealed space for the water supply of the plate and the cathode plate can effectively prevent the leakage of water and gas.

所述阳极接线端子60、阴极接线端子70及双极板100设置为正六边形结构,使其在圆形结构内具有最大反应面积的同时,有利于气体和液体的均匀分配,同时减小高压水电解器的压降,增强结构的稳定性。The anode terminal 60, the cathode terminal 70 and the bipolar plate 100 are arranged in a regular hexagonal structure, so that it has the largest reaction area in the circular structure, is conducive to the uniform distribution of gas and liquid, and reduces high voltage at the same time. The pressure drop of the water electrolyzer enhances the stability of the structure.

作为优选的实施例,所述正六边形结构的端角处为设置为与所述套体10内壁相切的圆角结构,进一步增强整体结构的稳定性。As a preferred embodiment, the end corners of the regular hexagonal structure are rounded structures arranged to be tangent to the inner wall of the sleeve body 10, which further enhances the stability of the overall structure.

作为优选的实施例,所述双极板100的表面设置有氧化物涂层、贵金属涂层或氮化层等,用以增强双极板的耐腐蚀性。As a preferred embodiment, the surface of the bipolar plate 100 is provided with an oxide coating, a noble metal coating or a nitride layer, etc., to enhance the corrosion resistance of the bipolar plate.

在本实施例中,所述上端盖20、下端盖30、第一弹性密封垫40、第二弹性密封垫50、阳极接线端子60、阴极接线端子70、膜电极组件90、以及双极板100上均相对应地设置有用于进水的第一通孔1和第二通孔2、用于出水及输出产生的氧气的第三通孔3、及用于出水及输出产生的氢气的第四通孔4。In this embodiment, the upper end cap 20 , the lower end cap 30 , the first elastic gasket 40 , the second elastic gasket 50 , the anode terminal 60 , the cathode terminal 70 , the membrane electrode assembly 90 , and the bipolar plate 100 There are correspondingly provided first through holes 1 and second through holes 2 for water inlet, third through holes 3 for water outlet and output generated oxygen, and fourth through holes for water outlet and output generated hydrogen. Via 4.

作为优选的实施例,所述阳极接线端子60在靠近所述上端盖20的一侧面的几何中心设置有阳极接线柱61;所述上端盖20及所述第一弹性密封垫40的几何中心均设置有与所述阳极接线柱61相适配的第五通孔5,所述阳极接线柱61穿过所述第五通孔5与外部电源线(图中未画出)连接。As a preferred embodiment, the anode terminal 60 is provided with an anode terminal 61 at the geometric center of one side surface close to the upper end cover 20 ; the geometric centers of the upper end cover 20 and the first elastic gasket 40 are both A fifth through hole 5 matching the anode terminal 61 is provided, and the anode terminal 61 passes through the fifth through hole 5 and is connected to an external power line (not shown in the figure).

作为优选的实施例,所述阴极接线端子70在靠近所述下端盖30的一侧面的几何中心设置有阴极接线柱71;所述下端盖30及所述第二弹性密封垫50的几何中心均设置有与所述阴极接线柱71相适配的第六通孔6,所述阴极接线柱71穿过所述第六通孔6与外部电源线(图中未画出)连接。As a preferred embodiment, the cathode connecting terminal 70 is provided with a cathode connecting post 71 at the geometric center of one side surface of the lower end cover 30 ; the geometric centers of the lower end cover 30 and the second elastic gasket 50 are both A sixth through hole 6 matching the cathode terminal 71 is provided, and the cathode terminal 71 passes through the sixth through hole 6 and is connected to an external power line (not shown in the figure).

具体地,所述膜电极组件90包括隔膜91、设置于所述隔膜91靠近所述阳极接线端子20一侧的阳极板92及设置于所述隔膜91靠近所述阴极接线端子30一侧的阴极板93。Specifically, the membrane electrode assembly 90 includes a diaphragm 91 , an anode plate 92 disposed on the side of the diaphragm 91 close to the anode terminal 20 , and a cathode disposed on the side of the diaphragm 91 close to the cathode terminal 30 plate 93.

作为优选的实施例,所述阳极接线端子60与距离所述阳极接线端子60最近的所述隔膜91之间形成的密闭区间、及所述双极板100与距离所述双极板100最近的所述隔膜91之间形成的密闭区间均为阳极室(图中未标识),且形成所述阳极室的所述双极板100与所述隔膜91之间设置有阳极板92;位于所述阳极室200的所述第二通孔2、第四通孔4内设置有第一导管210。所述第一导管210用于将阳极室200的水流及产生的氧气与第二通孔2、第四通孔4隔绝起来。As a preferred embodiment, the sealed area formed between the anode connection terminal 60 and the diaphragm 91 closest to the anode connection terminal 60 , and the bipolar plate 100 and the closest area to the bipolar plate 100 The airtight areas formed between the diaphragms 91 are anode chambers (not marked in the figure), and an anode plate 92 is arranged between the bipolar plate 100 forming the anode chamber and the diaphragm 91; A first conduit 210 is provided in the second through hole 2 and the fourth through hole 4 of the anode chamber 200 . The first conduit 210 is used to isolate the water flow and the generated oxygen in the anode chamber 200 from the second through hole 2 and the fourth through hole 4 .

作为优选的实施例,所述阴极接线端子70与距离所述阴极接线端子70最近的所述隔膜91之间形成的密闭区间、及所述双极板100与距离所述双极板100最近的所述隔膜91之间形成的密闭区间均为阴极室(图中未标识),且形成所述阴极室的所述双极板100与所述隔膜91之间设置有阴极板93;位于所述阴极室300的所述第一通孔1、第三通孔3内设置有第二导管310。所述第二导管310用于将阴极室300的水流及产生的氢气与第一通孔1、第三通孔3隔绝起来。As a preferred embodiment, the airtight area formed between the cathode connection terminal 70 and the diaphragm 91 closest to the cathode connection terminal 70 , and the bipolar plate 100 and the closest area to the bipolar plate 100 The airtight sections formed between the diaphragms 91 are all cathode chambers (not marked in the figure), and a cathode plate 93 is arranged between the bipolar plate 100 and the diaphragm 91 forming the cathode chamber; A second conduit 310 is provided in the first through hole 1 and the third through hole 3 of the cathode chamber 300 . The second conduit 310 is used to isolate the water flow in the cathode chamber 300 and the generated hydrogen gas from the first through hole 1 and the third through hole 3 .

作为优选的实施例,所述第一导管210和所述第二导管310的外侧均设置有密封包裹的弹性密封圈(图中未标识),所述弹性密封圈使得所述第一导管210与位于所述阳极室200的所述第二通孔2、所述第四通孔4之间密封配合,所述第二导管310与位于所述阴极室300的所述第一通孔1、所述第三通孔3之间密封配合。这样设置使得第一导管210与第二通孔2、第四通孔4之间,第二导管310与第一通孔1、第三通孔3之间完全密封配合,防止水中的氢气和氧气混合到一起。As a preferred embodiment, the outer sides of the first conduit 210 and the second conduit 310 are provided with elastic sealing rings (not marked in the figure) that are sealed and wrapped, and the elastic sealing rings make the first conduit 210 and the The second through hole 2 and the fourth through hole 4 located in the anode chamber 200 are in sealing cooperation, and the second conduit 310 and the first through hole 1 and the fourth through hole located in the cathode chamber 300 The third through holes 3 are sealed and matched. In this way, the first conduit 210 and the second through hole 2 and the fourth through hole 4 and the second conduit 310 and the first through hole 1 and the third through hole 3 are completely sealed to prevent hydrogen and oxygen in the water. Mix together.

作为优选的实施例,所述阳极接线柱61与所述阴极接线柱71的外侧包裹设置有绝缘护套(图中未标识)。防止阳极接线柱61与上端盖20、阴极接线柱71与下端盖之间30漏电。As a preferred embodiment, an insulating sheath (not marked in the figure) is wrapped on the outer side of the anode terminal 61 and the cathode terminal 71 . Electric leakage between the anode terminal 61 and the upper end cap 20 and the cathode terminal 71 and the lower end cap 30 is prevented.

进一步地,所述第一弹性密封垫40、第二弹性密封垫50均为绝缘橡胶材质密封垫,既隔绝电流,又为电解器在受压情况下提供膨胀空间。Further, the first elastic sealing gasket 40 and the second elastic sealing gasket 50 are both insulating rubber material sealing gaskets, which not only isolates the current, but also provides expansion space for the electrolyzer under pressure.

需要说明的是,本实施例中双极板100可以用石墨双极板或金属双极板,其中,金属双极板可为镍基材料、钛基材料、不锈钢材料等;密封圈、密封垫等绝缘密封结构为高分子材料、硅胶材料、橡胶材料中的一种或多种组合。It should be noted that the bipolar plate 100 in this embodiment can be a graphite bipolar plate or a metal bipolar plate, wherein the metal bipolar plate can be a nickel-based material, a titanium-based material, a stainless steel material, etc.; a sealing ring, a gasket The iso-insulating sealing structure is one or more combinations of polymer materials, silicone materials, and rubber materials.

本实施例在制造工艺流程中需保持每个结构的平整,从而提高其耐腐蚀性和气液流动均匀性。In this embodiment, each structure needs to be kept flat during the manufacturing process, so as to improve its corrosion resistance and gas-liquid flow uniformity.

水流从上端盖20的第一通孔1流入,流经阳极室200电解产生氧气,产生的氧气与水流一起从下端盖30的第三通孔3处流出;水流从上端盖20的第二通孔2流入,流经阴极室300电解产生氢气,产生的氢气与水流一起从下端盖30的第四通孔4流出;第三通孔3和第四通孔4外部分别与气液分离器(图中为标识)连接,经气液分离器分离后得到纯氢气与纯氧气。The water flow flows in from the first through hole 1 of the upper end cover 20, and flows through the anode chamber 200 for electrolysis to generate oxygen, and the generated oxygen flows out from the third through hole 3 of the lower end cover 30 together with the water flow; The hole 2 flows in, flows through the cathode chamber 300 electrolysis to generate hydrogen, and the generated hydrogen flows out from the fourth through hole 4 of the lower end cover 30 together with the water flow; the third through hole 3 and the fourth through hole 4 are respectively connected to the gas-liquid separator ( In the figure, the symbol is connected, and pure hydrogen and pure oxygen are obtained after being separated by a gas-liquid separator.

以上所述仅为本实用新型的优选实施例,并非因此限制本实用新型的专利范围,凡是在本实用新型的实用新型构思下,利用本实用新型说明书及附图内容所作的等效结构变换,或直接/间接运用在其他相关的技术领域均包括在本实用新型的专利保护范围内。The above are only preferred embodiments of the present utility model, and are not intended to limit the scope of the present utility model patent. Under the concept of the utility model of the present utility model, the equivalent structure transformations made by using the contents of the present utility model description and accompanying drawings, Or directly/indirectly applied in other related technical fields are included in the scope of patent protection of the present invention.

Claims (10)

1. A high pressure water electrolyzer characterized by: the bipolar plate comprises a sleeve body, an upper end cover arranged at one end of the sleeve body, a first elastic sealing gasket arranged at the inner side of the upper end cover, an anode connecting terminal arranged at the inner side of the first elastic sealing gasket, a lower end cover arranged at the other end of the sleeve body, a second elastic sealing gasket arranged at the inner side of the lower end cover, a cathode connecting terminal arranged at the inner side of the second elastic sealing gasket, a plurality of membrane electrode assemblies and a plurality of bipolar plates arranged between the anode connecting terminal and the cathode connecting terminal, wherein the bipolar plates are arranged between the adjacent membrane electrode assemblies; the anode connecting terminal and the cathode connecting terminal are both arranged adjacent to the membrane electrode assembly;
sealing rings are arranged between the anode connecting terminal and the membrane electrode assembly, between the cathode connecting terminal and the membrane electrode assembly and between the bipolar plate and the membrane electrode assembly;
the anode connecting terminal, the cathode connecting terminal and the bipolar plate are all in a regular hexagon structure, and the upper end cover, the lower end cover, the first elastic sealing gasket, the second elastic sealing gasket and the membrane electrode assembly are in a circular structure with the same size as the excircle of the regular hexagon structure; the diameter of the sealing ring is equal to the diameter of the inner circle of the regular hexagon structure.
2. The high pressure water electrolyzer of claim 1 characterized in that: a plurality of screw holes are arranged on the circular structure in a corresponding circumferential direction, and the screw holes are arranged on the outer sides of the circular structure and the inscribed regular hexagon corresponding to the regular hexagon; the membrane electrode assembly is characterized in that screws are arranged on the screw holes, and the upper end cover, the lower end cover, the first elastic sealing gasket, the second elastic sealing gasket and the membrane electrode assembly are fixedly connected through the screws.
3. The high pressure water electrolyzer of claim 2 characterized in that: the end angle of the regular hexagon structure is a circular angle structure tangent to the inner wall of the sleeve body.
4. The high pressure water electrolyzer of claim 1 characterized in that: the surface of the bipolar plate is provided with an oxide coating, a noble metal coating or a nitride layer.
5. The high pressure water electrolyzer of claim 1 characterized in that: the upper end cover, the lower end cover, the first elastic sealing gasket, the second elastic sealing gasket, the anode wiring terminal, the cathode wiring terminal, the membrane electrode assembly and the bipolar plate are respectively and correspondingly provided with a first through hole, a second through hole, a third through hole and a fourth through hole.
6. The high pressure water electrolyzer of claim 5 characterized in that: an anode binding post is arranged at the geometric center of one side surface of the anode binding post close to the upper end cover; the geometric centers of the upper end cover and the first elastic sealing gasket are provided with fifth through holes matched with the anode wiring terminal, and the anode wiring terminal penetrates through the fifth through holes to be connected with an external power line; the cathode wiring terminal is provided with a cathode wiring terminal at the geometric center of one side surface close to the lower end cover; the geometric centers of the lower end cover and the second elastic sealing gasket are provided with sixth through holes matched with the cathode wiring terminal, and the cathode wiring terminal penetrates through the sixth through holes to be connected with an external power line; and insulating sheaths are arranged on the outer sides of the anode binding post and the cathode binding post.
7. The high pressure water electrolyzer of claim 6 characterized in that: the membrane electrode assembly comprises a diaphragm, an anode plate and a cathode plate, wherein the anode plate is arranged on one side, close to the anode wiring terminal, of the diaphragm, and the cathode plate is arranged on one side, close to the cathode wiring terminal, of the diaphragm.
8. The high pressure water electrolyzer of claim 7 characterized in that: a sealed interval formed between the anode terminal and the diaphragm nearest to the anode terminal and a sealed interval formed between the bipolar plate and the diaphragm nearest to the bipolar plate are both anode chambers, and an anode plate is arranged between the bipolar plate forming the anode chamber and the diaphragm; and first guide pipes are arranged in the second through hole and the fourth through hole of the anode chamber.
9. The high pressure water electrolyzer of claim 8 characterized in that: a sealed interval formed between the cathode terminal and the membrane nearest to the cathode terminal and a sealed interval formed between the bipolar plate and the membrane nearest to the bipolar plate are cathode chambers, and a cathode plate is arranged between the bipolar plate forming the cathode chambers and the membrane; second guide pipes are arranged in the first through hole and the third through hole of the cathode chamber; and elastic sealing rings are arranged on the outer sides of the first guide pipe and the second guide pipe.
10. The high pressure water electrolyzer of claim 1 characterized in that: the first elastic sealing gasket and the second elastic sealing gasket are both insulating rubber sealing gaskets.
CN202020496444.XU 2020-04-07 2020-04-07 A high pressure water electrolyzer Active CN212077161U (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114672833A (en) * 2022-04-20 2022-06-28 广东卡沃罗氢科技有限公司 Anti-blocking electrolytic tank and hydrogen machine comprising same

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114672833A (en) * 2022-04-20 2022-06-28 广东卡沃罗氢科技有限公司 Anti-blocking electrolytic tank and hydrogen machine comprising same
CN114672833B (en) * 2022-04-20 2024-04-02 广东卡沃罗氢科技有限公司 Anti-blocking electrolytic tank and hydrogen machine comprising same

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