CN211856236U - Hydrogen peroxide concentration monitoring device - Google Patents
Hydrogen peroxide concentration monitoring device Download PDFInfo
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- CN211856236U CN211856236U CN201922119628.4U CN201922119628U CN211856236U CN 211856236 U CN211856236 U CN 211856236U CN 201922119628 U CN201922119628 U CN 201922119628U CN 211856236 U CN211856236 U CN 211856236U
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- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 title claims abstract description 139
- 238000012806 monitoring device Methods 0.000 title claims abstract description 34
- 238000001514 detection method Methods 0.000 claims abstract description 131
- 239000007788 liquid Substances 0.000 claims abstract description 108
- 238000006243 chemical reaction Methods 0.000 claims abstract description 49
- 238000002347 injection Methods 0.000 claims abstract description 25
- 239000007924 injection Substances 0.000 claims abstract description 25
- 239000003054 catalyst Substances 0.000 claims abstract description 19
- 238000000354 decomposition reaction Methods 0.000 claims abstract description 19
- 238000011010 flushing procedure Methods 0.000 claims description 75
- 238000005070 sampling Methods 0.000 claims description 66
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 29
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 claims description 8
- 239000007789 gas Substances 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 5
- 238000007599 discharging Methods 0.000 claims description 2
- 238000007789 sealing Methods 0.000 claims 2
- 238000012544 monitoring process Methods 0.000 abstract description 13
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 8
- 239000001301 oxygen Substances 0.000 description 8
- 229910052760 oxygen Inorganic materials 0.000 description 8
- 238000010586 diagram Methods 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 2
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000012295 chemical reaction liquid Substances 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 229910001448 ferrous ion Inorganic materials 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000002957 persistent organic pollutant Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
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Abstract
本实用新型公开了双氧水浓度监测装置,涉及浓度监测领域。该双氧水浓度监测装置包括进样管道、进样阀门、检测室、压差导流管、压差排液阀门、液位计和温度检测仪;进样管道上设有进样阀门;检测室内设有双氧水分解催化剂;压差导流管一端插入检测室的待测液体内,另一端位于检测室外,压差导流管至少有一段高于检测室内的待测液体的液面的管段,压差排液阀门设于压差导流管上;进样阀门与压差排液阀门均关闭时,将检测室封闭为气体密封检测室;压差排液阀门开启时,检测室内的待测液体在内部气压作用下由压差导流管流出;液位计用于检测液位数据;温度检测仪用于检测温度。本实用新型可用于测定待测反应池中待测液体的双氧水浓度。
The utility model discloses a hydrogen peroxide concentration monitoring device, and relates to the field of concentration monitoring. The hydrogen peroxide concentration monitoring device comprises an injection pipeline, an injection valve, a detection chamber, a pressure difference guide tube, a pressure difference drain valve, a liquid level meter and a temperature detector; the injection pipeline is provided with an injection valve; a hydrogen peroxide decomposition catalyst is provided in the detection chamber; one end of the pressure difference guide tube is inserted into the liquid to be tested in the detection chamber, and the other end is located outside the detection chamber, the pressure difference guide tube has at least one section of the pipe section higher than the liquid level of the liquid to be tested in the detection chamber, and the pressure difference drain valve is provided on the pressure difference guide tube; when the injection valve and the pressure difference drain valve are both closed, the detection chamber is sealed as a gas-sealed detection chamber; when the pressure difference drain valve is opened, the liquid to be tested in the detection chamber flows out from the pressure difference guide tube under the action of the internal air pressure; the liquid level meter is used to detect the liquid level data; and the temperature detector is used to detect the temperature. The utility model can be used to measure the hydrogen peroxide concentration of the liquid to be tested in the reaction pool to be tested.
Description
技术领域technical field
本实用新型涉及浓度监测领域,尤其涉及双氧水浓度监测装置。The utility model relates to the field of concentration monitoring, in particular to a hydrogen peroxide concentration monitoring device.
背景技术Background technique
目前,芬顿反应在废水处理领域有很广泛的应用,芬顿反应的无机化学反应过程为:过氧化氢与二价铁离子Fe2+的混合溶液将很多已知的有机化合物如羧酸、醇、酯类氧化为无机态。芬顿反应具有去除难降解有机污染物的高能力。过氧化氢俗称双氧水,在利用芬顿反应处理废水时,需要监测反应液中的双氧水浓度,以及时调节双氧水用量,提高芬顿反应效率。At present, the Fenton reaction is widely used in the field of wastewater treatment. The inorganic chemical reaction process of the Fenton reaction is: the mixed solution of hydrogen peroxide and ferrous ion Fe Alcohols and esters are oxidized to inorganic state. The Fenton reaction has a high ability to remove refractory organic pollutants. Hydrogen peroxide is commonly known as hydrogen peroxide. When using the Fenton reaction to treat wastewater, it is necessary to monitor the concentration of hydrogen peroxide in the reaction solution, adjust the amount of hydrogen peroxide in time, and improve the efficiency of the Fenton reaction.
但是,现有技术中,缺乏能够用于监测芬顿反应池内的双氧水浓度的装置。However, in the prior art, a device that can be used to monitor the hydrogen peroxide concentration in the Fenton reaction cell is lacking.
实用新型内容Utility model content
为了克服现有技术的不足,本实用新型的目的在于提供双氧水浓度监测装置。In order to overcome the deficiencies of the prior art, the purpose of the present invention is to provide a hydrogen peroxide concentration monitoring device.
本实用新型的目的采用如下技术方案实现:The purpose of this utility model adopts following technical scheme to realize:
双氧水浓度监测装置,包括进样管道、进样阀门、检测室、压差导流管、压差排液阀门、液位计和温度检测仪;Hydrogen peroxide concentration monitoring device, including sampling pipeline, sampling valve, detection chamber, differential pressure guide tube, differential pressure discharge valve, liquid level gauge and temperature detector;
所述进样管道上设有所述进样阀门;所述进样管道被配置为,在所述进样阀门开启时,用于将待测反应池内的待测液体送至所述检测室内;所述检测室内设有双氧水分解催化剂,所述双氧水分解催化剂用于催化所述检测室内的双氧水发生分解反应;The sampling pipeline is provided with the sampling valve; the sampling pipeline is configured to send the liquid to be tested in the reaction tank to be tested to the detection chamber when the sampling valve is opened; The detection chamber is provided with a hydrogen peroxide decomposition catalyst, and the hydrogen peroxide decomposition catalyst is used to catalyze the decomposition reaction of the hydrogen peroxide in the detection chamber;
所述压差导流管一端插入所述检测室的待测液体内,另一端位于所述检测室外,所述压差导流管至少有一段高于所述检测室内的待测液体的液面的管段,所述压差排液阀门设于所述压差导流管上;所述进样阀门与所述压差排液阀门均关闭时,将所述检测室封闭为气体密封检测室;One end of the differential pressure conduit is inserted into the liquid to be measured in the detection chamber, and the other end is located outside the detection chamber. The differential pressure conduit has at least a section higher than the liquid level of the liquid to be measured in the detection chamber. The pressure difference discharge valve is arranged on the pressure difference guide pipe; when both the sample injection valve and the pressure difference discharge valve are closed, the detection chamber is closed as a gas-tight detection chamber;
所述压差排液阀门用于当所述气体密封检测室内的内部气压高于外部大气压时开启,以使所述检测室内的待测液体在内部气压作用下由所述压差导流管流出;所述液位计用于检测所述检测室内的待测液体的液位数据;所述温度检测仪用于检测所述检测室内温度。The differential pressure discharge valve is used to open when the internal air pressure in the gas-tight detection chamber is higher than the external atmospheric pressure, so that the liquid to be tested in the detection chamber flows out from the differential pressure conduit under the action of the internal air pressure ; the liquid level meter is used to detect the liquid level data of the liquid to be tested in the detection chamber; the temperature detector is used to detect the temperature of the detection chamber.
进一步地,所述压差导流管为倒U型管,所述检测室侧壁设有开口,所述倒U型管的第一端由所述开口伸入所述检测室内;所述压差排液阀门设于所述倒U型管位于所述检测室外的管部上。Further, the differential pressure guide tube is an inverted U-shaped tube, the side wall of the detection chamber is provided with an opening, and the first end of the inverted U-shaped tube extends into the detection chamber through the opening; the pressure The differential discharge valve is arranged on the pipe portion of the inverted U-shaped pipe located outside the detection chamber.
进一步地,所述液位计为超声波液位计。Further, the liquid level gauge is an ultrasonic level gauge.
进一步地,还包括进样泵,所述进样泵与所述进样管道连接,以提供将待测反应池内的待测液体抽送至所述检测室的动力。Further, a sampling pump is also included, and the sampling pump is connected with the sampling pipeline to provide power for pumping the liquid to be tested in the reaction cell to be tested to the detection chamber.
进一步地,所述检测室内填充颗粒状的所述双氧水分解催化剂,所述双氧水分解催化剂包括二氧化锰颗粒。Further, the detection chamber is filled with the particulate hydrogen peroxide splitting catalyst, and the hydrogen peroxide splitting catalyst includes manganese dioxide particles.
进一步地,所述检测室设有用于将待测液体排出的排样口,所述滤网设于所述排样口。Further, the detection chamber is provided with a sample discharge port for discharging the liquid to be tested, and the filter screen is provided on the sample discharge port.
进一步地,还包括冲洗水箱、冲洗管道、冲洗泵和冲洗阀门;所述冲洗阀门设于所述冲洗管道;所述冲洗水箱用于盛装冲洗液,所述冲洗管道用于将所述冲洗水箱与所述检测室连通;所述冲洗泵用于提供动力,以当所述冲洗阀门开启时,通过所述冲洗管道将所述冲洗水箱内的冲洗液抽送至所述检测室内;Further, it also includes a flushing water tank, a flushing pipeline, a flushing pump and a flushing valve; the flushing valve is arranged in the flushing pipeline; the flushing water tank is used for holding flushing liquid, and the flushing pipeline is used for connecting the flushing water tank with the flushing water tank. the detection chamber is communicated; the flushing pump is used for providing power to pump the flushing liquid in the flushing water tank into the detection chamber through the flushing pipeline when the flushing valve is opened;
所述冲洗阀门、所述进样阀门和压差排液阀门均关闭时,所述检测室为气体密封检测室。When the flushing valve, the sampling valve and the differential pressure discharge valve are all closed, the detection chamber is a gas-tight detection chamber.
进一步地,所述进样泵与所述冲洗泵共用,为进样冲洗泵;所述进样冲洗泵具有进水口和出水口;Further, the sampling pump is shared with the flushing pump, and is a sampling flushing pump; the sampling flushing pump has a water inlet and a water outlet;
所述监测装置还包括连接干管,所述进样管道一端与所述待测反应池连接,另一端与所述连接干管连接;所述冲洗管道一端与所述待测反应池连接,另一端与所述连接干管连接;The monitoring device further comprises a connecting dry pipe, one end of the sampling pipe is connected to the reaction cell to be tested, and the other end is connected to the connecting dry pipe; one end of the flushing pipe is connected to the reaction cell to be tested, and the other end is connected to the reaction cell to be tested. One end is connected with the connecting trunk;
所述连接干管与所述进水口连接,所述出水口与所述检测室连接。The connecting main pipe is connected with the water inlet, and the water outlet is connected with the detection chamber.
进一步地,还包括排样管道、排样阀门和排样泵;所述检测室设有排样口;所述排样管道与所述排样口连接,所述排样阀门设于所述排样管道;所述排样泵用于提供动力,以当所述排样阀门开启时,将所述检测室内的液体通过所述排样管道排出。Further, it also includes a sample discharge pipeline, a sample discharge valve and a sample discharge pump; the detection chamber is provided with a sample discharge port; the sample discharge pipeline is connected with the sample discharge port, and the sample discharge valve is arranged in the discharge port. The sampling pipeline; the sampling pump is used for providing power to discharge the liquid in the detection chamber through the sampling pipeline when the sampling valve is opened.
进一步地,还包括用于盛装待测液体的待测反应池,所述待测反应池上侧设有开口,所述排样管道远离所述检测室的一端通过所述开口将所述检测室内的液体送至所述待测反应池。Further, it also includes a reaction pool to be tested for containing the liquid to be tested, the upper side of the reaction pool to be tested is provided with an opening, and the end of the discharge pipe away from the detection chamber passes through the opening to remove the liquid in the detection chamber. The liquid is sent to the reaction cell to be tested.
相比现有技术,本实用新型的有益效果在于:Compared with the prior art, the beneficial effects of the present utility model are:
可用于对芬顿反应池内的液体进行抽样检测,利用双氧水在催化剂作用下发生分解反应,测定待测液体中的双氧水浓度。It can be used to sample and test the liquid in the Fenton reaction tank, and use hydrogen peroxide to decompose under the action of a catalyst to measure the concentration of hydrogen peroxide in the liquid to be tested.
附图说明Description of drawings
图1为本实用新型的双氧水浓度监测装置示意图一;Fig. 1 is the schematic diagram one of the hydrogen peroxide concentration monitoring device of the present invention;
图2为图1中的A部放大图;Fig. 2 is the enlarged view of A part in Fig. 1;
图3为本实用新型的双氧水浓度监测装置示意图二;Fig. 3 is the schematic diagram two of the hydrogen peroxide concentration monitoring device of the present invention;
图4为本实用新型的检测室的示意图。FIG. 4 is a schematic diagram of the detection chamber of the present invention.
图中:10、检测室;21、进样管道;22、进样泵;23、进样阀门;30、冲洗水箱;31、冲洗管道;32、冲洗泵;33、冲洗阀门;41、排样管道;42、排样泵;43、排样阀门;50、进样冲洗泵;61、压差导流管;62、压差排液阀门;71、液位计;72、温度检测仪;80、PLC显示端;90、待测反应池。In the figure: 10, detection room; 21, sampling pipeline; 22, sampling pump; 23, sampling valve; 30, flushing water tank; 31, flushing pipeline; 32, flushing pump; 33, flushing valve; 41, sampling Pipeline; 42. Sampling pump; 43. Sampling valve; 50. Sampling flushing pump; 61. Differential pressure diversion pipe; 62. Differential pressure discharge valve; 71. Liquid level gauge; 72. Temperature detector; 80 , PLC display terminal; 90, the reaction pool to be tested.
具体实施方式Detailed ways
下面,结合附图以及具体实施方式,对本实用新型做进一步描述,需要说明的是,在不相冲突的前提下,以下描述的各实施例之间或各技术特征之间可以任意组合形成新的实施例。Hereinafter, the present invention will be further described with reference to the accompanying drawings and specific embodiments. It should be noted that, on the premise of no conflict, the embodiments or technical features described below can be combined arbitrarily to form new implementations. example.
如图1-4所示,本实施例提供了双氧水浓度监测装置,该双氧水浓度监测装置包括进样管道21、进样阀门23、检测室10、压差导流管61、压差排液阀门 62和液位计71。As shown in Figures 1-4, the present embodiment provides a hydrogen peroxide concentration monitoring device, the hydrogen peroxide concentration monitoring device includes a
本实施例的监测装置,用于由容盛有芬顿反应液的待测反应池90内抽样监测,待测反应池90内待测液体内含有双氧水,监测装置用于监测双氧水浓度。The monitoring device of this embodiment is used for sampling monitoring from the
具体地,进样管道21用于将待测反应池90与检测室10连通;进样管道21 上设有进样阀门23;进样管道21被配置为,在进样阀门23开启时,用于将待测反应池90内的待测液体送至检测室10内;检测室10设有排样口,排样阀门 43用于封闭或开启排样口,排样阀门43开启时,检测室10内的液体可以由排样口排出,以便进行下一次监测;检测室10内设有双氧水分解催化剂,双氧水分解催化剂与双氧水接触时,用于催化检测室10内的待测液体中的双氧水发生分解反应;Specifically, the
压差导流管61一端插入检测室10的待测液体内,另一端位于检测室10外,压差导流管61至少有一段高于检测室10内的待测液体的液面的管段,压差排液阀门62设于压差导流管61上;进样阀门23、排样阀门43与压差排液阀门 62均关闭时,将检测室10封闭为气体密封检测室10;压差排液阀门62用于当气体密封检测室10内的内部气压高于外部大气压时开启,以使检测室10内的待测液体在内部气压作用下由压差导流管61的第二端流出;液位计71用于测检测室10内的待测液体的液位数据。One end of the differential
优选地,本实施例中进样管道21一端插入待测反应池90的反应液内,另一端与检测室10的上端连接;本实施例中排样口设于检测室10下端,以便于排样,在其他一些实施例中,排样口也可以位于检测室10上端。Preferably, in this embodiment, one end of the
优选地,由于待测液体中含有强氧化剂,为了保证该系统的正常工作,本实施例的进样管道21为耐腐蚀管道。Preferably, since the liquid to be tested contains a strong oxidant, in order to ensure the normal operation of the system, the
在上述结构的基础上,本实施例的进样管道21通过以下方式将待测反应池 90内的待测液体送至检测室10内:On the basis of the above structure, the
该双氧水浓度监测装置还设有进样泵22,进样泵22与进样管道21连接,进样阀门23开启时,进样泵22启动,以提供动力,将待测液体由待测反应池 90抽送至检测室10,本实施例中的进样泵22用于将定量的待测液体抽送至检测室10;本实施例中的进样管道21包括第一管道和第二管道;第一管道一端插入所述待测反应池90内,另一端与进样泵22的进水口连接;第二管道一端与进样泵22的出水口连接,另一端与检测室10的进样口连接;进样阀门23设于第二管道。在其他一些实施例中,进样泵22还可以设置于其他位置。The hydrogen peroxide concentration monitoring device is also provided with a
在其他一些实施例中,还可以通过如下方式实现将待测反应池90内的待测液体送至检测室10内:In some other embodiments, the liquid to be tested in the
将进样管道21的出液口设置为低于待测反应池90的液位高度,如低于待测反应池90;如此可利用连通器原理,通过进样管道21将待测反应池90内的反应液导送至检测室10。The liquid outlet of the
本实施例中的双氧水浓度监测装置的双氧水浓度工作流程为:The hydrogen peroxide concentration work flow of the hydrogen peroxide concentration monitoring device in the present embodiment is:
取样步骤:排样阀门43关闭,开启进样泵22、进样阀门23,待测反应池 90中一定量的待测液体经过进样管道21进入检测室10,关闭进样阀门23;Sampling step: the sampling
监测步骤:含有双氧水的待测液体与检测室10内的双氧水分解催化剂接触,在催化剂的作用下,双氧水发生分解反应,生成水和氧气;此时,由于排样阀门43、进样阀门23关闭,检测室10被封闭为气体密封检测室10,随着双氧水在触媒的作用下分解释放出氧气,检测室10内的压力升高;双氧水分解反应时间(约1-10min)结束后,打开压差排液阀门62,由于检测室10内部的气体压力高于外部大气压力,在检测室10内部气压的作用下,待测液体通过压差导流管61排到检测室10外,直至内外气压持平,液位计71用于记录液位以得到液位差值,温度检测仪72用于记录检测室10内的温度。Monitoring step: the liquid to be tested containing hydrogen peroxide is in contact with the hydrogen peroxide decomposition catalyst in the
通过测得的液位数据和室内温度值,得到双氧水浓度值的原理为:Through the measured liquid level data and indoor temperature value, the principle of obtaining the hydrogen peroxide concentration value is as follows:
如图4所示,检测室10下部的待测液体的体积为V1,上部气体体积为V2, V1+V2=V。As shown in FIG. 4 , the volume of the liquid to be tested in the lower part of the
设检测液体中双氧水的含量为x,则分解出氧气的摩尔当量:Assuming that the content of hydrogen peroxide in the detection liquid is x, the molar equivalent of oxygen is decomposed:
m=0.5ρV1x(公式1);m=0.5ρV 1 x (formula 1);
不考虑氧气在待测液体中的溶解,假设氧气完全释放到检测室10的上部空间V2,则按照氧气的范德华方程,压力值与体积满足公式2:Regardless of the dissolution of oxygen in the liquid to be tested, assuming that the oxygen is completely released into the upper space V 2 of the
P=0.5ρV1xRT/(V1-b)-a/V2(公式2);P=0.5ρV 1 xRT/(V 1 -b)-a/V 2 (Equation 2);
其中,T为温度(K),T为由温度检测仪72测得的温度值;R为气体方程常数;a为0.1378(Pa.m6.mol-2);b为3.183*10-5(m3.mol-1),a、b为氧气的范德华方程常数;Wherein, T is the temperature (K), T is the temperature value measured by the
忽略二次项,则有公式3:Ignoring the quadratic term, there is formula 3:
V=0.5ρV1xRT/P+b(公式3);V=0.5ρV 1 xRT/P+b (formula 3);
设检测室10的截面积为S,则检测室10内的液位高度Δh下降满足公式4:Assuming that the cross-sectional area of the
Δh=(0.5ρV1xRT/P+b)/S(公式4);Δh=(0.5ρV 1 xRT/P+b)/S(Formula 4);
由此可以建立液位下降高度Δh、检测室10温度T与双氧水浓度x的关系方程,从而由液位高度变化检测双氧水浓度x的变化。Thereby, the relationship equation between the liquid level drop height Δh, the temperature T of the
需要说明的是,当选定了一定尺寸的检测室10后,V值与S值可得。It should be noted that when a certain size of the
本实施例通过进样管道21的设置,可以将待测反应池90内的待测液体导入检测室10内;通过在检测室10内设置双氧水分解催化剂,使得送至的待测液体中的双氧水可以发生分解反应;通过设置进样阀门23、压差排液阀门62和排样阀门43的封闭,可以提供密封反应空间,避免双氧水分解反应产生的氧气外泄;通过压差导流管61与液位计71的设置,可以利用双氧水分解反应产生气体使得检测室10内气压增大的特性,可以通过液位计71检测得到液位差值Δh,再根据温度检测仪72测得的温度T,则可依据公式4计算得到双氧水浓度x。In this embodiment, the liquid to be tested in the
由于当压差排液阀门62开启时,若压差导流管61每一部分均位于液面下侧,根据连通器原理,即使检测室10内的气压与外部大气压相等,检测室10 内的待测液体也会沿压差导流管61流出,故而本实施例中将压差导流管61设置为至少有一段管段位于待测液体的液面上方,如此保证待测液体流出量仅与检测室10内外压差相关。Because when the differential
本实施例的监测装置,可以实现对双氧水浓度的侧顶,有利于控制芬顿反应结束后的双氧水残余量,通过设定多个监测点,调节双氧水用量与进水浓度波动一致。The monitoring device of this embodiment can realize the lateral top of the concentration of hydrogen peroxide, which is beneficial to control the residual amount of hydrogen peroxide after the Fenton reaction is completed.
本实施例中,通过在待测反应池90的出水口设置监测点,在中和脱气池设置一到两个监测点,以后者作为双氧水加药量的削减量的下限,以出水口浓度作为双氧水加药量削减量的上限,每个监测点设置一台双氧水浓度监测装置,如此可依据监测结果调节双氧水用量与进水浓度波动一致。In this embodiment, a monitoring point is set at the water outlet of the
本实施例中,压差排液阀门62的控制可以至少通过以下方式实现:第一,监测装置设置控制系统,控制系统用于接受预设的开启关闭时间,以通过控制系统控制压差排液阀门62的开启和关闭;第二,通过人工观测检测室10内的反应情况,人工控制压差排液阀门62的开启和关闭。In this embodiment, the control of the differential
为了能够得到待测液体的液体体积值V1,在一些实施例中,通过控制进样泵22的进样速度、进样阀门23的关闭时间等,从而使得进入检测室10内的待测液体体积V1为预设的体积;在另外一些实施例中,监测装置还设有体积监测组件,体积监测组件用于监测检测室10内的液位高度,并根据液位高度与检测室10尺寸,计算得到检测室10内的待测液体体积V1;在其他一些实施例中,通过在检测室10设置刻度线,直接读取待测液体体积V1实现。In order to obtain the liquid volume value V 1 of the liquid to be tested, in some embodiments, by controlling the injection speed of the
优选地,压差导流管61为倒U型管,检测室10侧壁设有开口,倒U型管的第一端由开口伸入检测室10内;倒U型管的管壁与开口之间密封连接;压差排液阀门62设于倒U型管位于检测室10外的管部上。Preferably, the differential
本实施例中,为了提高计算效率,监测装置还设置处理模块,处理模块根据液位计71数据、温度检测仪72数据和预设的液位浓度方程可计算得到双氧水浓度。本实施例中还包括PLC显示端80,用于输入预设值(a、b、R)和显示各项信息。In this embodiment, in order to improve the calculation efficiency, the monitoring device is further provided with a processing module, which can calculate the hydrogen peroxide concentration according to the data of the
优选地,检测室10内填充有颗粒状的双氧水分解催化剂,以提高待测液体与催化剂的接触面积,有利于充分分解,提高压力监测精度。Preferably, the
在上述结构的基础上,为了防止排样时催化剂流失,该监测装置还包括滤网,滤网设于排样口。On the basis of the above structure, in order to prevent the loss of catalyst during sample discharge, the monitoring device further includes a filter screen, and the filter screen is arranged at the sample discharge port.
优选地,双氧水分解催化剂颗粒包括二氧化锰颗粒或双氧水分解催化剂颗粒的主要成分为二氧化锰。Preferably, the hydrogen peroxide splitting catalyst particles comprise manganese dioxide particles or the main component of the hydrogen peroxide splitting catalyst particles is manganese dioxide.
优选地,检测室10上部侧壁设有进样口,进样管道21与进样口连接。Preferably, the upper side wall of the
优选地,为了便于重复抽样检测,该监测装置还包括冲洗水箱30、冲洗管道31、冲洗泵32和冲洗阀门33;冲洗阀门33设于冲洗管道31;冲洗水箱30 用于盛装冲洗液,冲洗管道31一端的端口位于冲洗液内,冲洗管道31另一端与检测室10连接;冲洗泵32用于提供动力,以当冲洗阀门33开启时,通过冲洗管道31将冲洗水箱30内的冲洗液抽送至检测室10内;如此,当检测室10 内的检测完成,为了保证下一次检测数据的准确性,通过冲洗泵32抽吸冲洗液进入检测室10内,可冲洗检测室10内的残余待测液体,冲洗完成后液体由排样口排出。Preferably, in order to facilitate repeated sampling detection, the monitoring device further includes a flushing
在一些实施例中,还可以设置冲洗花洒或喷头,提高冲洗效果。In some embodiments, a flushing shower or spray head may also be provided to improve flushing effect.
在本实施例中,冲洗阀门33、进样阀门23、压差排液阀门62和排样阀门 43均关闭时,检测室10为气体密封检测室10。In this embodiment, when the flushing
如图1所示,在一些实施例中,进样管路与冲洗管路相互独立,需要单独设置进样泵22和冲洗泵32。As shown in FIG. 1 , in some embodiments, the sampling pipeline and the flushing pipeline are independent of each other, and the
如图2所示,在其他一些实施例中,为了降低成本或便于安装,进样泵22 与冲洗泵32共用,为进样冲洗泵50;进样冲洗泵50具有进水口和出水口;监测装置还包括连接干管,进样管道21一端与待测反应池90连接,另一端与连接干管连接;冲洗管道31一端与待测反应池90连接,另一端与连接干管连接;连接干管与进水口连接,出水口与检测室10连接。As shown in FIG. 2 , in some other embodiments, in order to reduce costs or facilitate installation, the
优选地,为了加快排样效率,监测装置还包括排样管道41、排样阀门43和排样泵42,排样管道41与排样口连接,排样阀门43设于排样管道41;排样泵 42用于提供动力,以当排样阀门43开启时,将检测室10内的液体通过排样管道41排出。Preferably, in order to speed up the sampling efficiency, the monitoring device further comprises a
优选地,由于待测液体在检测室10内仅发生双氧水的分解反应,待测液体中未混入其他杂质,为了将待测液体回收利用,待测反应池90上侧设有开口,排样管道41远离检测室10的一端设于待测液体上方,以通过开口将检测室10 内的液体送至待测反应池90。Preferably, since the liquid to be tested only undergoes a decomposition reaction of hydrogen peroxide in the
本实施例通过控制系统控制所有阀门和泵。This embodiment controls all valves and pumps through the control system.
上述实施方式仅为本实用新型的优选实施方式,不能以此来限定本实用新型保护的范围,本领域的技术人员在本实用新型的基础上所做的任何非实质性的变化及替换均属于本实用新型所要求保护的范围。The above-mentioned embodiments are only the preferred embodiments of the present invention, and the scope of protection of the present invention cannot be limited by this. Any insubstantial changes and replacements made by those skilled in the art on the basis of the present invention belong to the scope of the present invention. The scope of protection of the utility model.
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