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CN203839391U - Solar Photovoltaic Photothermal Composite Module - Google Patents

Solar Photovoltaic Photothermal Composite Module Download PDF

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Publication number
CN203839391U
CN203839391U CN201420290448.7U CN201420290448U CN203839391U CN 203839391 U CN203839391 U CN 203839391U CN 201420290448 U CN201420290448 U CN 201420290448U CN 203839391 U CN203839391 U CN 203839391U
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photovoltaic
thermal
heat
photo
assembly
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苑进社
高向明
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Chongqing Normal University
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Chongqing Normal University
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/60Thermal-PV hybrids

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Abstract

The utility model discloses a solar photovoltaic and photo-thermal composite assembly. The solar photovoltaic and photo-thermal composite assembly comprises a photovoltaic assembly and a photo-thermal assembly. The photovoltaic assembly includes solar photovoltaic cells, and an EVA film layer and a transparent resin protective layer that are successively bonded to the upper surfaces of the solar photovoltaic cells. An ETFE film layer and a heat conduction base plate are successively bonded to the lower surfaces of the solar photovoltaic cells. A flexible graphite plate is disposed between the ETFE film layer and the heat conduction base plate. The service life of the solar photovoltaic assembly and the photo-thermal assembly is prolonged. The solar photovoltaic and photo-thermal composite assembly is a photovoltaic and photo-thermal integrated assembly that has a simple structure, is convenient to mount and is low in cost. The photovoltaic and photo-thermal integrated assembly enables the conversion efficiency of photovoltaic cells to be increased, the photo-thermal and photovoltaic conversion performance to be improved and the solar utilization efficiency to be increased, allows solar power generation and hot water supplying to be achieved by the same body at the same time, and helps to save space resources.

Description

太阳能光伏光热复合组件Solar Photovoltaic Photothermal Composite Module

技术领域technical field

本实用新型涉及太阳能发电技术领域,特别涉及太阳能光伏光热复合组件。The utility model relates to the technical field of solar power generation, in particular to a solar photovoltaic photothermal composite assembly.

背景技术Background technique

太阳能电池组件主要以半导体材料为基础制作,基本结构包括框体及设置于框体内的组件结构。其中,组件结构包括透光的前表面玻璃基片、透明密封件(如EVA胶)、电池片及背封薄膜(后表面保护部件,如PVF聚氟乙烯、TPT/TPE)等。工作原理是太阳光透过基片照射在光电产生器件上,光电产生器件通过光电效应直接将光能转换为电能,经与电池组件配套使用的光伏接线盒,将电能输出后使用。太阳能电池在将光能转换成电能的过程中,并不是将全部的光能的都转换成电能。理论研究表明,单极单晶硅材料的太阳能电池在0℃时的转换效率的理论物理极限为30%。在光强一定的条件下,当硅电池自身温度升高时输出功率将下降。在实际应用中,标准条件下,晶体硅电池平均效率在15%上下。也就是说,太阳能电池只能将15%的光能转换成可用电能,其余的85%都被转化为热能。在转换过程中,随着热能的增加,电池温度不断升高,除了光电转换效率大大降低外,太阳能电池的使用寿命也将缩短。为使太阳能电池组件能长久地正常工作,现有技术中,在框体外加设散热装置(类似于水冷、气冷等散热系统,通过循环水或循环气吸热,达到散热目的)。但热能亦是太阳能电池组件吸收太阳辐射能源的一部分,若能将该部分能源取出并收集,加以利用,而非将其视为需消散的有害热量,便能达到充分利用能源的目的,且拓宽了太阳能电池组件的使用功能。为尽可能使电池效率保持在较高水平,充分利用吸收的太阳辐射能源,同时避免热量对组件光电转换效率的影响,延长电池组件的使用寿命,可以通过在太阳能电池组件上设置导热层,将光电转换过程中产生的热能吸收传导,并由其连接的导热元件导出组件结构,由外界取热管路收集,提供给后续热能设备使用。根据其布置的位置在太阳能组件密封件内或密封件外,导热层选择绝缘材料或是高导热材料制成。导热元件可以是具有高导热能力的金属类元件,或是导热能力高于金属类元件的热管等。The solar cell module is mainly made on the basis of semiconductor materials, and its basic structure includes a frame body and a module structure arranged in the frame body. Among them, the module structure includes a light-transmitting front surface glass substrate, a transparent seal (such as EVA glue), a battery sheet and a back-sealing film (rear surface protection components, such as PVF polyvinyl fluoride, TPT/TPE), etc. The working principle is that sunlight shines on the photoelectric generating device through the substrate, and the photoelectric generating device directly converts light energy into electrical energy through the photoelectric effect, and outputs the electrical energy through the photovoltaic junction box used with the battery module for use. In the process of converting light energy into electrical energy, solar cells do not convert all light energy into electrical energy. Theoretical studies have shown that the theoretical physical limit of the conversion efficiency of solar cells made of unipolar single crystal silicon at 0°C is 30%. Under the condition of a certain light intensity, the output power will decrease when the temperature of the silicon cell itself rises. In practical applications, under standard conditions, the average efficiency of crystalline silicon cells is around 15%. In other words, solar cells can only convert 15% of light energy into usable electrical energy, and the remaining 85% are converted into heat energy. During the conversion process, with the increase of heat energy, the temperature of the battery will continue to rise. In addition to the greatly reduced photoelectric conversion efficiency, the service life of the solar battery will also be shortened. In order to make the solar cell module work normally for a long time, in the prior art, a heat dissipation device (similar to water cooling, air cooling and other heat dissipation systems, absorbing heat through circulating water or circulating air to achieve the purpose of heat dissipation) is added outside the frame. However, thermal energy is also a part of the solar radiation energy absorbed by solar cell components. If this part of energy can be taken out and collected, and used instead of being regarded as harmful heat that needs to be dissipated, the purpose of making full use of energy can be achieved and broadened function of the solar cell module. In order to keep the battery efficiency at a high level as much as possible, make full use of the absorbed solar radiation energy, avoid the influence of heat on the photoelectric conversion efficiency of the module, and prolong the service life of the battery module, it is possible to set a heat-conducting layer on the solar battery module, which will The heat energy generated during the photoelectric conversion process is absorbed and conducted, and is exported to the component structure by the connected heat-conducting element, collected by the external heat-taking pipeline, and provided to the subsequent heat energy equipment for use. According to its arrangement position inside or outside the sealing member of the solar module, the heat conduction layer is made of insulating material or high heat conduction material. The heat conduction element may be a metal element with high heat conductivity, or a heat pipe with a higher heat conductivity than the metal element.

太阳能光伏光热综合利用的复合组件目前也有研究,大多是将集热管用超声波焊到集热板上,集热板与太阳能光伏组件相贴合,或者将集热管固定连接在太阳能光伏组件的背光面,再在集热管下面安装隔热保温板构成。集热管是固定设置在光伏组件背面,与光伏组件和隔热保温板是硬接触。由于太阳能光伏光热组件一般都在户外使用,而且在运输和安装过程中集热管或集热板与光伏组件及集热管与隔热保温背板之间是硬接触,电池片易被碰碎,而且光伏组件被光面不是完全平整的,与集热板的接触不好,影响传热效率。Composite components for comprehensive utilization of solar photovoltaic light and heat are currently being studied, most of which are to weld the heat collecting tube to the heat collecting plate with ultrasonic waves, and the heat collecting plate is attached to the solar photovoltaic module, or the heat collecting tube is fixedly connected to the backlight of the solar photovoltaic module. surface, and then install heat insulation boards under the heat collecting tubes to form. The heat collecting tube is fixed on the back of the photovoltaic module, and is in hard contact with the photovoltaic module and the heat insulation board. Since solar photovoltaic photothermal components are generally used outdoors, and during transportation and installation, the heat collector tube or plate is in hard contact with the photovoltaic module, heat collector tube and heat insulation backplane, and the cells are easily broken. Moreover, the glazed surface of the photovoltaic module is not completely flat, and the contact with the heat collecting plate is not good, which affects the heat transfer efficiency.

实用新型内容Utility model content

为了解决上述技术问题,本实用新型提供一种太阳能光伏光热复合组件,提高光伏组件的使用寿命,提供一种结构简单、安装方便、成本较低的光伏光热一体化组件,该光伏光热一体化组件可以增加光伏电池的转换效率,增加单位面积上太阳能转换效率。In order to solve the above technical problems, the utility model provides a solar photovoltaic photothermal composite assembly, which improves the service life of the photovoltaic assembly, and provides a photovoltaic photothermal integrated assembly with simple structure, convenient installation and low cost. Integrated components can increase the conversion efficiency of photovoltaic cells and increase the conversion efficiency of solar energy per unit area.

本实用新型的太阳能光伏光热复合组件,包括光伏组件和光热组件,所述光伏组件包括太阳能光伏电池片以及其上表面依次粘接设置的EVA膜层和透明树脂防护层,其下表面依次粘接设置有四氟乙烯ETFE膜层和导热底板,所述四氟乙烯ETFE膜层与导热底板之间设置柔性石墨板;The solar photovoltaic photothermal composite assembly of the utility model includes a photovoltaic assembly and a photothermal assembly. The photovoltaic assembly includes a solar photovoltaic battery sheet and an EVA film layer and a transparent resin protective layer that are sequentially bonded on the upper surface of the solar photovoltaic assembly. A tetrafluoroethylene ETFE film layer and a heat-conducting bottom plate are bonded, and a flexible graphite plate is arranged between the tetrafluoroethylene ETFE film layer and the heat-conducting bottom plate;

进一步,所述光热组件包括设置于导热底板背面的集热管,所述热器外侧设置有隔热保温背板,所述集热管与隔热保温背板之间设置橡塑保温层;Further, the photothermal assembly includes a heat collecting tube arranged on the back of the heat conducting bottom plate, a heat insulating back plate is set outside the heater, and a rubber and plastic insulation layer is set between the heat collecting tube and the heat insulating back plate;

进一步,所述橡塑保温层设置有用于与集热管外表面相配合固定的凹槽;Further, the rubber and plastic insulation layer is provided with a groove for matching and fixing with the outer surface of the heat collecting tube;

进一步,所述集热管为多根以相互平行的方式固定于导热底板的空心铜管;Further, the heat collecting tubes are a plurality of hollow copper tubes fixed to the heat conduction bottom plate in a parallel manner;

进一步,所述集热管为蛇形盘管;Further, the heat collecting tube is a serpentine coil;

进一步,所述空心铜管焊接固定于导热底板,所述导热底板为铝板;Further, the hollow copper tube is welded and fixed to the heat conduction bottom plate, and the heat conduction bottom plate is an aluminum plate;

进一步,透明树脂防护层为钢化玻璃盖板;Further, the transparent resin protective layer is a tempered glass cover plate;

进一步,所述钢化玻璃盖板与导热底板之间的距离为25mm;Further, the distance between the tempered glass cover plate and the heat conduction bottom plate is 25mm;

进一步,所述空心铜管的管间距离与其管径的比为6.25。Further, the ratio of the distance between the hollow copper tubes to the tube diameter is 6.25.

本实用新型的有益效果:本实用新型的太阳能光伏光热复合组件,提高太阳能光伏组件和光热组件的使用寿命,结构简单、安装方便、成本较低的光伏光热一体化组件,该光伏光热一体化组件可以增加光伏电池的转换效率,以及光热与光电的转换性能,增加单位面积上太阳能转换效率,增加太阳能利用效率,实现太阳能发电热水同体同步,节省空间资源。Beneficial effects of the utility model: the solar photovoltaic photothermal composite component of the utility model improves the service life of the solar photovoltaic component and the photothermal component, and is a photovoltaic photothermal integrated component with simple structure, convenient installation and low cost. Thermally integrated components can increase the conversion efficiency of photovoltaic cells, as well as the conversion performance of photothermal and photoelectricity, increase the conversion efficiency of solar energy per unit area, increase the efficiency of solar energy utilization, realize the synchronization of solar power generation and hot water, and save space resources.

附图说明Description of drawings

下面结合附图和实施例对本实用新型作进一步描述:Below in conjunction with accompanying drawing and embodiment the utility model is further described:

图1为本实用新型的结构示意图。Fig. 1 is the structural representation of the utility model.

具体实施方式Detailed ways

图1为本实用新型的结构示意图,如图所示:本实用新型的太阳能光伏光热复合组件,包括光伏组件和光热组件,所述光伏组件包括太阳能光伏电池片1以及其上表面依次粘接设置的EVA膜层2和透明树脂防护层3;其下表面依次粘接设置有四氟乙烯ETFE膜层4和导热底板6,所述四氟乙烯ETFE膜层4与导热底板6之间设置柔性石墨板5;透明树脂防护层3设置于最上层用于吸收太阳光,ETFE膜层4其透光性和耐候性好,具有表面不容易存留附着物,透明度高,轻量化,反粘性强,耐穿透等机械强度优异 耐放射线性良,,能够有效地提高抗老化性、耐腐蚀性和环保的目的,从而延长了抗老化型太阳能电池组件的使用寿命,提高抗老化型太阳能电池组件的工作效率;柔性石墨板5用于导热并起缓冲作用,避免太阳能光伏电池片1与导热底板6的硬性接触而产生磨损或损坏,同时提高密封性能,还可避免导热底板6的温度过高以提高光电转化。该结构从上到下依次为透明树脂防护层3、EVA膜层2、太阳能光伏电池片1、ETFE膜层4、柔性石墨板5、导热底板6,且通过粘接剂粘合或者是通过热合而成。Fig. 1 is a structural schematic diagram of the present utility model, as shown in the figure: the solar photovoltaic photothermal composite assembly of the present utility model includes a photovoltaic assembly and a photothermal assembly, and the photovoltaic assembly includes a solar photovoltaic battery sheet 1 and its upper surface is sequentially bonded The EVA film layer 2 and the transparent resin protective layer 3 that are arranged next to each other; its lower surface is bonded with a tetrafluoroethylene ETFE film layer 4 and a heat-conducting base plate 6 in sequence, and the tetrafluoroethylene ETFE film layer 4 and the heat-conducting base plate 6 are arranged between Flexible graphite plate 5; the transparent resin protective layer 3 is arranged on the uppermost layer to absorb sunlight, and the ETFE film layer 4 has good light transmittance and weather resistance, is not easy to retain attachments on the surface, has high transparency, light weight, and strong anti-stickiness , Excellent mechanical strength such as penetration resistance, good radiation resistance, can effectively improve aging resistance, corrosion resistance and environmental protection, thereby prolonging the service life of anti-aging solar cell components and improving anti-aging solar cell components The working efficiency is high; the flexible graphite plate 5 is used for heat conduction and plays a buffer role to avoid abrasion or damage caused by the hard contact between the solar photovoltaic cells 1 and the heat conduction base plate 6, and at the same time improve the sealing performance and avoid the temperature of the heat conduction base plate 6 from being too high to improve photoelectric conversion. From top to bottom, the structure consists of transparent resin protective layer 3, EVA film layer 2, solar photovoltaic cell sheet 1, ETFE film layer 4, flexible graphite plate 5, and heat-conducting bottom plate 6, which are bonded by adhesive or heat-sealed. made.

本实施例中,所述光热组件包括设置于导热底板6背面的集热管7,所述集热管7外侧设置有隔热保温背板9,所述集热管7与隔热保温背板9之间设置橡塑保温层8;隔热保温背板9用于支撑集热管7,橡塑保温层8起到衬垫的作用,避免集热管7与隔热保温背板9的硬性接触而损伤,同时橡塑保温层8可起到进一步加强隔热保温的作用。集热管7外侧是指集热管7下表面。In this embodiment, the photothermal assembly includes a heat collecting tube 7 arranged on the back of the heat conducting bottom plate 6, and a heat insulating back plate 9 is arranged on the outside of the heat collecting tube 7, and the connection between the heat collecting tube 7 and the heat insulating back plate 9 A rubber-plastic insulation layer 8 is arranged between them; the heat-insulating backboard 9 is used to support the heat-collecting tube 7, and the rubber-plastic insulation layer 8 plays the role of a liner to avoid damage to the heat-collecting tube 7 and the heat-insulating backboard 9 due to rigid contact. Simultaneously the rubber-plastic insulation layer 8 can play the effect of further strengthening heat insulation. The outside of the heat collecting tube 7 refers to the lower surface of the heat collecting tube 7 .

本实施例中,所述橡塑保温层8设置有用于与集热管7外表面相配合固定的凹槽;集热管7的外表面与凹槽结构内表面贴合,或者是该凹槽结构也可以为波纹面结构;便于集热管7的固定,提高集热管7的稳定性和牢固性,进一步加强保温作用。In this embodiment, the rubber and plastic insulation layer 8 is provided with a groove for cooperating with the outer surface of the heat collecting tube 7; the outer surface of the heat collecting tube 7 is attached to the inner surface of the groove structure, or the groove structure can also be It is a corrugated surface structure; it is convenient for fixing the heat collecting tube 7, improves the stability and firmness of the heat collecting tube 7, and further strengthens the heat preservation effect.

本实施例中,所述集热管7为多根以相互平行的方式固定于导热底板6的空心铜管;可采用焊接固定的方式或其他同样能实现本发明目的固定方式固定集热管7,空心铜管最好为16根,平均热效率和电效率最大。In this embodiment, the heat collecting tube 7 is a plurality of hollow copper tubes fixed to the heat conduction bottom plate 6 in a parallel manner; the heat collecting tube 7 can be fixed by welding or other fixing methods that can also achieve the purpose of the present invention. The number of copper tubes is preferably 16, and the average thermal efficiency and electrical efficiency are the largest.

本实施例中,所述集热管7为蛇形盘管;结构简单,紧凑性好,通水量大。In this embodiment, the heat collecting pipe 7 is a serpentine coil; the structure is simple, the compactness is good, and the water flow is large.

本实施例中,所述空心铜管焊接固定于导热底板6,所述导热底板6为铝板;结构强度高,导热性好。In this embodiment, the hollow copper tube is welded and fixed to the heat conduction bottom plate 6, and the heat conduction bottom plate 6 is an aluminum plate; the structure has high strength and good thermal conductivity.

本实施例中,透明树脂防护层3为钢化玻璃盖板;结构强度大,光的透射性好。In this embodiment, the transparent resin protective layer 3 is a toughened glass cover plate; the structure has high strength and good light transmission.

本实施例中,所述钢化玻璃盖板与导热底板6之间的距离为25mm;有利于提高光热与光电的转换性能,最大限度的提高光热和光电转换率,提高热效率和电效率。In this embodiment, the distance between the tempered glass cover plate and the heat-conducting bottom plate 6 is 25mm; it is beneficial to improve the conversion performance of light-to-heat and light, maximize the increase in light-to-heat and light-to-light conversion rate, and improve thermal efficiency and electrical efficiency.

本实施例中,所述空心铜管的管间距离与其管径的比为6.25;采用窄条流道,同样有利于提高光热与光电的转换性能,最大限度的提高光热和光电转换率,提高热效率和电效率。In this embodiment, the ratio of the distance between the hollow copper tubes to the diameter of the tubes is 6.25; the use of narrow flow channels is also conducive to improving the conversion performance of photothermal and photoelectricity, and maximizing the conversion rate of photothermal and photoelectricity , improve thermal efficiency and electrical efficiency.

最后说明的是,以上实施例仅用以说明本实用新型的技术方案而非限制,尽管参照较佳实施例对本实用新型进行了详细说明,本领域的普通技术人员应当理解,可以对本实用新型的技术方案进行修改或者等同替换,而不脱离本实用新型技术方案的宗旨和范围,其均应涵盖在本实用新型的权利要求范围当中。Finally, it is noted that the above embodiments are only used to illustrate the technical solutions of the present utility model without limitation. Although the utility model has been described in detail with reference to the preferred embodiments, those of ordinary skill in the art should understand that the utility model can be Modifications or equivalent replacements of the technical solutions without departing from the purpose and scope of the technical solutions of the utility model shall be covered by the claims of the utility model.

Claims (9)

1. a photovoltaic and photothermal solar composite component, it is characterized in that: comprise photovoltaic module and photo-thermal assembly, described photovoltaic module comprises solar-energy photo-voltaic cell sheet and surface EVA rete and the transparent resin overcoat of bonding setting successively thereon, its lower surface is bonding tetrafluoroethene ETFE rete and the conductive sole plate of being provided with successively, between described tetrafluoroethene ETFE rete and conductive sole plate, flexible graphite plate is set.
2. photovoltaic and photothermal solar composite component according to claim 1, it is characterized in that: described photo-thermal assembly comprises the thermal-collecting tube that is arranged at the conductive sole plate back side, described thermal-collecting tube arranged outside has heat-insulation and heat-preservation backboard, between described thermal-collecting tube and heat-insulation and heat-preservation backboard, rubber and plastic heat-insulation layer is set.
3. photovoltaic and photothermal solar composite component according to claim 2, is characterized in that: described rubber and plastic heat-insulation layer is provided with for the fixing groove that matches with thermal-collecting tube outer surface.
4. photovoltaic and photothermal solar composite component according to claim 3, is characterized in that: described thermal-collecting tube is the many hollow copper tubings that are fixed on conductive sole plate in the mode being parallel to each other.
5. photovoltaic and photothermal solar composite component according to claim 4, is characterized in that: described thermal-collecting tube is serpentine coil.
6. photovoltaic and photothermal solar composite component according to claim 5, is characterized in that: described hollow copper tubing is fixedly welded on conductive sole plate, described conductive sole plate is aluminium sheet.
7. photovoltaic and photothermal solar composite component according to claim 6, is characterized in that: transparent resin overcoat is toughened glass cover plate.
8. photovoltaic and photothermal solar composite component according to claim 7, is characterized in that: the distance between described toughened glass cover plate and conductive sole plate is 25mm.
9. photovoltaic and photothermal solar composite component according to claim 8, is characterized in that: the tube pitch of described hollow copper tubing from the ratio of its caliber be 6.25.
CN201420290448.7U 2014-06-03 2014-06-03 Solar Photovoltaic Photothermal Composite Module Expired - Fee Related CN203839391U (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104467661A (en) * 2014-11-03 2015-03-25 山东希格斯新能源有限责任公司 Solar electric heating integrated device
CN105490638A (en) * 2015-12-06 2016-04-13 上海博阳新能源科技有限公司 High-thermal conductivity photoelectric and photothermal board
CN106016415A (en) * 2016-05-23 2016-10-12 苏州铭冠软件科技有限公司 Solar power generating and heat supplying system
CN113395039A (en) * 2021-07-06 2021-09-14 浙江科隼新能源有限公司 Photovoltaic and photo-thermal integrated plate and manufacturing method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104467661A (en) * 2014-11-03 2015-03-25 山东希格斯新能源有限责任公司 Solar electric heating integrated device
CN105490638A (en) * 2015-12-06 2016-04-13 上海博阳新能源科技有限公司 High-thermal conductivity photoelectric and photothermal board
CN106016415A (en) * 2016-05-23 2016-10-12 苏州铭冠软件科技有限公司 Solar power generating and heat supplying system
CN113395039A (en) * 2021-07-06 2021-09-14 浙江科隼新能源有限公司 Photovoltaic and photo-thermal integrated plate and manufacturing method thereof

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