CN203805319U - Additive fabrication device - Google Patents
Additive fabrication device Download PDFInfo
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- CN203805319U CN203805319U CN201320614393.6U CN201320614393U CN203805319U CN 203805319 U CN203805319 U CN 203805319U CN 201320614393 U CN201320614393 U CN 201320614393U CN 203805319 U CN203805319 U CN 203805319U
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Abstract
Description
技术领域 technical field
本实用新型属于机械设计领域。特别地,本实用新型涉及用以控制在添加制造中使用的箔的运动的有效机械装置。本实用新型提供了一种添加制造装置,其具有有效的反转机械装置以将箔引导辊的方向反转。 The utility model belongs to the field of mechanical design. In particular, the invention relates to efficient mechanical means to control the movement of foils used in additive manufacturing. The utility model provides an additive manufacturing device, which has an effective reversing mechanism to reverse the direction of the foil guiding roller. the
背景技术 Background technique
在利用可移动载体箔来盛载液体构建材料的、具有高成像分辨率(在某些情况下50微米或更高)的添加制造(additive fabrication)工艺中,需要载体箔不起皱或不过度拉伸。在某些工艺中,这特别具有挑战性,这是因为载体箔必须在当前成像位置固定同时在添加制造工艺的其他地方处移动以允许同时成像和再涂。在任何基于箔的添加制造工艺中,箔的任何起皱或意料之外的拉伸都是不期望的。 In additive fabrication processes with high imaging resolution (50 microns or higher in some cases) that utilize a removable carrier foil to hold the liquid build material, it is required that the carrier foil not wrinkle or overly stretch. In certain processes, this is particularly challenging because the carrier foil must be fixed at the current imaging location while moving elsewhere in the additive manufacturing process to allow simultaneous imaging and recoating. Any wrinkling or unintended stretching of the foil is undesirable in any foil-based additive manufacturing process. the
已知使用UV透明载体箔的添加制造工艺。例如,属于Fudim的US6,557,452使用箔来将液体构建材料输送到成像位置。液体构建材料在到达成像位置之后成像并变为固体。固体附着到有形物体先前形成的层上,然后箔被移动以将其他液体构建材料输送到成像位置来形成下一个固体层。该过程被重复以构建固体的三维物体。类似地,属于3D Systems,Inc.的US7,467,939和US7,731,887公开了基于箔的添加制造工艺。在这些工艺的各个中,在液体构建材料被成像时箔保持固定。 Additive manufacturing processes using UV transparent carrier foils are known. For example, US 6,557,452 to Fudim uses a foil to deliver liquid build material to the imaging site. The liquid build material is imaged and becomes solid after reaching the imaging site. The solid adheres to the previously formed layer of the tangible object, and the foil is then moved to deliver additional liquid build material to the imaging site to form the next solid layer. This process is repeated to build solid three-dimensional objects. Similarly, US7,467,939 and US7,731,887 to 3D Systems, Inc. disclose foil based additive manufacturing processes. In each of these processes, the foil remains fixed while the liquid build material is imaged. the
在某添加制造工艺中,液体构建材料可以在一个位置处成像,同时箔在其他位置处移动。该工艺(在属于TNO的WO2010/074566中公开)需要箔在成像位置处保持不动且无褶皱同时箔在其他地方处移动。 In an additive manufacturing process, a liquid build material can be imaged at one location while the foil is moved at another location. This process (disclosed in WO2010/074566 belonging to TNO) requires the foil to remain stationary and wrinkle-free at the imaging location while the foil moves elsewhere. the
在基于箔的添加制造工艺中,箔在成像位置处在任何方向上不移动、不起皱或者不过度拉伸是很重要的。当系统能够双向移动时,该难点更加复杂。 In foil-based additive manufacturing processes, it is important that the foil does not move, wrinkle, or stretch excessively in any direction at the imaging location. This difficulty is compounded when the system is capable of moving in both directions. the
因此,需要用于允许箔的无褶皱移动(特别是在能够双向移动的系统中)的添加制造的机械装置。 Therefore, there is a need for an additively manufactured mechanism for allowing wrinkle-free movement of foils, especially in systems capable of bi-directional movement. the
发明内容 Contents of the invention
发明了一种控制在添加制造中使用的箔的运动的有效机械装置。根据一方面,一种添加制造装置其包括往复式箔引导台(180),所述往复式箔引导台包括:能量源(90),其被布置为用于至少部分地固化可固化材料层中的交叉图案的至少一部分,所述可固化材料层布置在箔(11)上并且与有形物体接触;以及在接触面(181)的引入侧和所述接触面(181)的拖出侧上的箔引导系统,所述箔引导系统包括:柔性的箔引导辊(4);以及支承系统(1),其能够根据所述柔性的箔引导辊(4)的滚动方向(P、Q)改变和/或反转所述柔性的箔引导辊(4)的曲率,并且所述支承系统被布置成与所述柔性的箔引导辊(4)接触,所述箔引导系统用于通过所述箔引导台(180)沿着有形物体(50)的移动来将包括液体树脂层(30)的箔(11)引导至所述接触面(181)或引导出所述接触面(181)以与所述有形物体(50)接触,所述箔包括输送层和结构层,所述输送层包括聚烯烃或含氟聚合物,并且所述结构层包括半结晶热塑型聚合物,其中所述柔性的箔引导辊与所述箔的所述输送层或所述箔的所述结构层接触。 An efficient mechanical device for controlling the movement of foils used in additive manufacturing has been invented. According to an aspect, an additive manufacturing apparatus comprises a reciprocating foil guiding station (180) comprising: an energy source (90) arranged for at least partially curing a layer of curable material At least part of a cross pattern of said curable material layer disposed on the foil (11) and in contact with a tangible object; and Foil guiding system comprising: a flexible foil guiding roll (4); and a support system (1) capable of changing and and/or reverse the curvature of said flexible foil guiding roll (4) and said support system is arranged in contact with said flexible foil guiding roll (4) for guiding through said foil The movement of the stage (180) along the tangible object (50) guides the foil (11) comprising the layer of liquid resin (30) to or out of said contact surface (181) for contact with said contact surface (181). In contact with a tangible object (50), the foil includes a transport layer and a structural layer, the transport layer includes polyolefin or fluoropolymer, and the structural layer includes a semi-crystalline thermoplastic polymer, wherein the flexible foil Guide rollers are in contact with the conveying layer of the foil or the structural layer of the foil. the
在说明书的下面的部分中描述了本实用新型的具体实施例。本实用新型的这些和其他方面将通过参考下文所述的实施例阐述并且变得清楚。 Specific embodiments of the invention are described in the remainder of the specification. These and other aspects of the invention will be elucidated and apparent by reference to the embodiments described hereinafter. the
附图说明 Description of drawings
将参考附图、仅以示例的方式描述本实用新型的其他细节、方面和实施例。 Further details, aspects and embodiments of the invention will be described, by way of example only, with reference to the accompanying drawings. the
图1示意性地示出了根据本实用新型的系统的实施例的示例的截面侧视图; Fig. 1 schematically shows a cross-sectional side view of an example of an embodiment of the system according to the present invention;
图2在箔引导布局中更详细地示出了图1的实施例; Figure 2 shows the embodiment of Figure 1 in more detail in a foil-guided layout;
图3示意性地示出了另一个实施例的立体侧视图; Figure 3 schematically shows a perspective side view of another embodiment;
图4示出了图3中的实施例的细节的侧视图; Figure 4 shows a side view of a detail of the embodiment in Figure 3;
图5示出了辊组件的细节;并且 Figure 5 shows the details of the roller assembly; and
图6示出了结合在添加制造装置中的箔引导系统的实施例。 Figure 6 shows an embodiment of a foil guiding system incorporated in an additive manufacturing device. the
具体实施方式 Detailed ways
根据一方面,通过以辊的曲率可以完全反转的柔性形式来代替刚性形式而设置弯曲辊,特别是辊轴,可以适当地控制在往复式添加制造工艺中使用的箔。在一个实施例中,辊可以设置为单件杆(rod)。曲率能够利用相对小的力而改变,在某些实施例中当辊表面被调节以限定箔拖拽力时(其中箔拖拽力限定辊弯曲曲率),曲率甚至可以(仅仅)利用由箔移动拖拽力提供的力而改变。 According to an aspect, by arranging curved rollers, in particular roller shafts, instead of rigid forms in flexible forms in which the curvature of the rollers can be completely reversed, it is possible to properly control the foils used in the reciprocating additive manufacturing process. In one embodiment, the roller may be provided as a one-piece rod. The curvature can be changed with relatively small forces, and in some embodiments the curvature can even be changed (only) with The force provided by the drag force changes. the
当前所要求保护的实用新型的方面的、与外部支承相联系的柔性辊布局代替现有技术的固定辊布局。该柔性辊布局可容易地调到箔运动方向。而且,箔引导系统允许在箔无褶皱的情况下辊方向的完全反转。 The flexible roll arrangement associated with the external support of the presently claimed aspect of the utility model replaces the fixed roll arrangement of the prior art. This flexible roller arrangement can be easily adjusted to the direction of foil movement. Furthermore, the foil guiding system allows a complete reversal of the direction of the rolls without wrinkling of the foil. the
对于在金属薄片卷绕工艺(web winding process)中的箔起皱的已知解决方案是使用曲辊(参见例如,GB1019958),其中辊是柔性的并且绕非柔性弯曲轴旋转。弯曲部分的隆起指向薄片运动的方向。通过薄片与辊表面之间的摩擦,薄片在其最初接触辊的点与其离开辊的点之间沿横向方向被拉伸,并且褶皱在沿着箔运动方向从辊延伸的区域上被消除。从EP0431275可以得知另一个公开,其中示出了改变偏转角以产生期望伸展的机械装置。然而,没有预期箔方向的反转。在US3248031中,公开了一种弯曲辊,其能够通过已公开的支承系统在多个方向上弯曲。然而,现有技术还没有预期在添加制造装置中允许方向反转的多辊设备。 A known solution to foil wrinkling in a web winding process is to use curved rolls (see eg GB1019958), where the rolls are flexible and rotate around an inflexible curved axis. The bulge of the curved portion points in the direction of the sheet movement. By friction between the sheet and the roll surface, the sheet is stretched in the transverse direction between the point where it initially contacts the roll and the point where it leaves the roll, and wrinkles are eliminated over the area extending from the roll in the direction of foil motion. Another publication is known from EP0431275, which shows a mechanism for varying the deflection angle to produce the desired extension. However, no reversal of the foil orientation is expected. In US3248031 a bending roll is disclosed which can be bent in multiple directions by means of the disclosed bearing system. However, the prior art has not anticipated multi-roll equipment that allows direction reversal in an additive manufacturing setup. the
图1示意性地示出了根据本实用新型的方面的系统1的实施例的截面侧视图。从图中可以看出,外支撑支承部分以平坦表面2的形式设置,该平坦表面2可与辊4的外表面3接合。表面2在弯曲辊4的外表面3上支撑弯曲辊4。弯曲状态意味着辊在一定程度上的柔性回弹,其中辊在一定应力下被弯曲成曲线。变形可以是弹性的,这在节约能源方面是有利的,但也可以是略微非弹性的。表面2从而使引导辊4能够在弯曲状态下相对 于表面2滚动运动,使得辊可以与滚动方向P、Q相一致地在至少两个支承位置A、B之间弯曲。在第一箔输送方向P上,使辊在第一支承位置A处向上弯曲,并且在相反箔输送方向Q上,使辊以相对于第一支承位置反转的曲率B向下弯曲。如果在两个方向P、Q上施加箔速度的变化,那么可以调整支承位置并且支撑位置不需要对称。因此,支承布局1允许辊轴4的弯曲沿着在支承表面2上的路径变化。因此,一个或多个辊4被设置为具有可逆的曲率,其中当箔输送方向P、Q反转时,曲率反转。应该注意,非柔性弯曲辊的传统布局在箔输送的反转中可能引起褶皱,沿运动方向隆起的曲线在弯曲保持固定并且运动方向相对于隆起反转时、可能引起褶皱。 Figure 1 schematically shows a cross-sectional side view of an embodiment of a system 1 according to aspects of the present invention. As can be seen from the figure, the outer support bearing portion is provided in the form of a flat surface 2 engageable with the outer surface 3 of the roller 4 . The surface 2 supports the bending roll 4 on its outer surface 3 . The bent state means that the roll has a certain degree of flexible springback, wherein the roll is bent into a curve under a certain stress. The deformation can be elastic, which is advantageous in terms of energy savings, or slightly inelastic. The surface 2 thus enables a rolling movement of the guide roller 4 relative to the surface 2 in a curved state, so that the roller can bend between at least two bearing positions A, B in correspondence with the rolling directions P, Q. In the first foil conveying direction P, the roller is curved upwards at a first bearing position A, and in the opposite foil conveying direction Q, the roller is curved downwards with a curvature B reversed relative to the first bearing position. If a variation of the foil velocity is applied in both directions P, Q, the support position can be adjusted and does not need to be symmetrical. Thus, the bearing arrangement 1 allows the curvature of the roller shaft 4 to vary along the path on the bearing surface 2 . Thus, one or more rollers 4 are provided with a reversible curvature, wherein the curvature is reversed when the foil conveying directions P, Q are reversed. It should be noted that conventional layouts of non-flexible curved rollers may cause wrinkling during reversal of the foil feed, and curves that are raised in the direction of motion may cause wrinkling when the bending is held fixed and the direction of motion is reversed relative to the humping. the
图2在箔引导布局中更详细地示出了图1的实施例。这里,支撑结构5被设置为在弯曲辊4的附近支撑额外的刚性辊6。支撑结构5还提供了轴向锁定弯曲辊4的锁定结构7。 Figure 2 shows the embodiment of Figure 1 in more detail in a foil guided layout. Here, the support structure 5 is arranged to support an additional rigid roll 6 in the vicinity of the bending roll 4 . The support structure 5 also provides a locking structure 7 for axially locking the bending roll 4 . the
锁定结构7可相对于支撑结构5固定,并且可以包括轴承,该轴承被布置为随着辊4由其弯曲而导致的轴线方向的改变而能够绕该轴承的中心点扭转。轴承可以是自调心球轴承类型,其允许内圈与外圈之间的失准。因此,柔性辊4可以被锁定在轴向锁定辊4的端部锁定结构7之间。刚性辊6被形成为箔引导元件,其朝向布置在弯曲辊4一侧上(并在下面进一步解释)的接触区域引导箔(未示出)和从该接触区域引出箔。在某些实施例中,引导元件6可以是形成接触面的边缘的非可转动引导件。 The locking structure 7 may be fixed relative to the support structure 5 and may comprise a bearing arranged to be able to twist about its center point as the direction of the axis changes as the roll 4 is bent by it. The bearings may be of the self-aligning ball bearing type, which allows for misalignment between the inner and outer rings. Thus, the flexible roller 4 can be locked between the end locking structures 7 of the axially locked roller 4 . The rigid roll 6 is formed as a foil guiding element which guides a foil (not shown) towards and leads out of a contact area arranged on one side of the bending roll 4 (and explained further below) . In some embodiments, the guide element 6 may be a non-rotatable guide forming the edge of the contact surface. the
图3示意性的示出了本实用新型的方面的其他实施例的立体侧视图。在该实施例中,多个支承元件20、21、22限定对于辊4的支承接触。虽然图2的实施例可以设置有被动支承布局1,其中弯曲力从辊上的薄片的张力获得(如联系图5的布局所进一步阐明的),但优选地,产生曲率(的改变)的力从(例如,气动类型的)致动器8主动获得。控制器9被设置为使致动器8与滚动方向P、Q相一致地受控。辊4由锁定结构7轴向锁定,并且具有两个中途支承接触件20、22,该中途支承接触件在中央支承被致动时被动地遵循辊的弯曲运动。对于特定期望的弯曲曲率,可以沿着柔性辊设置多个致动器。 Fig. 3 schematically shows a perspective side view of other embodiments of aspects of the present invention. In this embodiment, a plurality of support elements 20 , 21 , 22 define a support contact for the roller 4 . While the embodiment of Figure 2 may be provided with a passive support arrangement 1 where the bending force is derived from the tension of the sheet on the roll (as further clarified in connection with the arrangement of Figure 5), preferably, the force that produces (the change in) the curvature It is actively obtained from an actuator 8 (eg of pneumatic type). The controller 9 is arranged to control the actuator 8 in correspondence with the rolling directions P, Q. The roller 4 is locked axially by the locking structure 7 and has two intermediate bearing contacts 20 , 22 which passively follow the bending movement of the roller when the central bearing is actuated. For a particular desired bending curvature, multiple actuators may be positioned along the flexible roller. the
图4更详细地示出了主动支承布局10。支承21经由辊210、211提供了沿着辊的部分圆周的支承接触。以这种方式,辊4被包埋在支承21中并且通过箔11的按压力被保持在由支承接触件210、211限定的固定支承位置,其中支承接触件210、211与辊4的外表面接合并且将辊4部分地包埋在支撑辊210、211之间。由于辊4嵌入在支承结构21中,主动支承致动装置9限定了辊4的弯曲运动的范围和外止动件(outer stops)。示意性地,在位置B处与移动的箔11’一起指示了辊4’,以图示由可移动支承21强制提供的辊在位置A和B之间的弯曲运动。 Figure 4 shows the active support arrangement 10 in more detail. The bearing 21 provides bearing contact via rollers 210, 211 along part of the circumference of the rollers. In this way, the roller 4 is embedded in the support 21 and is held in a fixed support position by the pressing force of the foil 11 defined by the support contacts 210, 211 which are in contact with the outer surface of the roller 4. The roller 4 is engaged and partially embedded between the support rollers 210 , 211 . Since the roller 4 is embedded in the support structure 21 , the active bearing actuation means 9 define the range of bending movement and the outer stops of the roller 4 . Schematically, the roller 4' is indicated at position B together with the moving foil 11' to illustrate the bending movement of the roller between positions A and B, forcibly provided by the movable support 21. the
因此,致动器8被布置用于使得支承元件21运动以提供辊4的在(至少)两个支承位置A、B之间的被迫弯曲运动。 Thus, the actuator 8 is arranged for moving the support element 21 to provide a forced bending movement of the roller 4 between (at least) two support positions A, B. the
虽然在理论上致动可以由任何线性的或其他致动布局来提供,但在优选实施例中,致动器8包括可旋转臂80,其使得至少一个支承元件21在至少两个支承位置A、B之间旋转。线性气动致动器81耦合到可旋转臂80,可旋转臂80承载部分地包埋柔性辊4的支承21。通过气动致动,臂80在两个支承位置A、B之间旋转,并且通过包埋布局,柔性辊4被迫在两个支承位置A、B之间弯曲,同时通过支承21允许辊4的滚动运动。在实施例中,支承21可以由球、圆柱或固定表面的适合润滑结构来提供。刚性辊结构6被支撑在支撑结构中,支撑结构具有外部支承以允许滚动运动。可旋转臂80将柔性辊4的曲率从在箔运动沿P方向向上时的上部位置A弯曲到在箔运动沿相反的Q方向向下时的下部位置B。下部位置B通过虚线示意性地示出。 Although in theory actuation may be provided by any linear or other actuation arrangement, in a preferred embodiment the actuator 8 comprises a rotatable arm 80 which enables at least one support element 21 to move between at least two support positions A , B to rotate between. A linear pneumatic actuator 81 is coupled to a rotatable arm 80 carrying the support 21 partially embedding the flexible roller 4 . By pneumatic actuation, the arm 80 is rotated between the two support positions A, B, and by the embedding arrangement the flexible roller 4 is forced to bend between the two support positions A, B, while the support 21 allows the roller 4 to flex. rolling motion. In an embodiment, the bearing 21 may be provided by a ball, a cylinder or a suitable lubricated structure of a fixed surface. The rigid roller structure 6 is supported in a support structure with external bearings to allow rolling motion. The rotatable arm 80 bends the curvature of the flexible roller 4 from an upper position A when the foil movement is upward in the P direction to a lower position B when the foil movement is downward in the opposite Q direction. The lower position B is schematically indicated by dashed lines. the
在实施例中,箔(11)中的张力和/或位移可以例如通过测量支承辊(210、211)中任一者的反作用力2100和/或支承辊210、211之间力的差值来测量。箔(11)的张力和/位移可以由控制器801响应于箔中的张力和/或位移的测量结果,例如通过经由致动器81的控制增大或减小曲率或者通过可旋转臂(80)的沿臂方向适当地向外或向内的移动800,来调节。 In an embodiment, the tension and/or displacement in the foil (11) can be determined, for example, by measuring the reaction force 2100 of any of the backup rolls (210, 211) and/or the difference in force between the backup rolls 210, 211 Measurement. The tension and/or displacement of the foil (11) may be controlled by the controller 801 in response to measurements of tension and/or displacement in the foil, for example by increasing or decreasing the curvature via control via the actuator 81 or by a rotatable arm (80 ) is adjusted by appropriate outward or inward movement 800 in the direction of the arm. the
如在图4的实施例中公开的被动辊组件22、20可以被设计为使支承21被布置在可旋转臂结构80上,而不通过致动器81主动驱动。 The passive roller assemblies 22, 20 as disclosed in the embodiment of FIG. the
图5示出了替换的被动辊组件20。被动意味着当中央支承被致动和/ 或当辊通过箔的拖拽力而弯曲时,组件顺应辊的弯曲运动。相反,主动支承布局意味着供应主动提供的力(超过拖拽力),以强制致动辊4的弯曲运动。 FIG. 5 shows an alternative driven roller assembly 20 . Passive means that the assembly follows the bending motion of the roll when the central support is actuated and/or when the roll is bent by the drag force of the foil. On the contrary, an active bearing arrangement means supplying an actively provided force (over and above the drag force) to force the bending movement of the actuating roller 4 . the
虽然适当润滑的表面2提供摩擦支承,但支承接触还可以由与引导辊4接合的布置在锁止结构213上的滚动元件(rolling element)212提供,其中锁止结构213限定辊4弯曲的弯曲范围。例如,端部锁止结构213设置在弯曲的期望范围的一端或两端,从而提供相对于支承系统20固定的锁止元件213。 While a properly lubricated surface 2 provides frictional support, bearing contact can also be provided by rolling elements 212 arranged on locking structures 213 that engage the guide rollers 4, wherein the locking structures 213 limit the curvature of the roll 4 bends. scope. For example, end locking structures 213 are provided at one or both ends of the desired range of bending, thereby providing locking member 213 that is fixed relative to support system 20 . the
辊4可以设置为金属杆,例如,钢杆。在实施例中,杆是中空的。在另一个实施例中,杆是实心的。辊的刚度足够小以允许在没有太多力的情况下弯曲,并且又足够大以限定箔的足够大的弯曲半径从而在仅有几个支承的情况下得到缓和的弯曲形状。辊4的表面40必须足够坚硬以适合作为用于柔性支承的支承表面。当仅使用几个柔性支承时,例如,各自轴向长度为几个毫米的球支承210、211,辊表面40将具有非常小的耐磨性(wear-resistant)。当使用摩擦支承2时,其中棒可以被支撑相当大的长度,该表面仍然必须是耐磨的,但现在负载条件不同了:低负载,但在较大表面上,并且接触不是滚动的而是移动的。 The rollers 4 can be provided as metal rods, eg steel rods. In an embodiment, the rod is hollow. In another embodiment, the rod is solid. The stiffness of the rollers is small enough to allow bending without too much force, yet large enough to define a large enough bend radius for the foil to get a gently bent shape with only a few supports. The surface 40 of the roller 4 must be hard enough to be suitable as a bearing surface for flexible support. When only a few flexible bearings are used, eg ball bearings 210, 211 each having an axial length of a few millimeters, the roller surface 40 will be very little wear-resistant. When using friction bearings 2, where the rod can be supported over considerable lengths, the surface must still be wear resistant, but now the load conditions are different: low load, but on a larger surface, and the contact is not rolling but mobile. the
辊表面40可以设置有处理或层或纹理(粗糙度)以提供辊4和箔材料11之间的足够高的摩擦系数,和/或使辊表面更加耐磨。 The roll surface 40 may be provided with a treatment or a layer or a texture (roughness) to provide a sufficiently high coefficient of friction between the roll 4 and the foil material 11 and/or to make the roll surface more wear resistant. the
现在参考图6,其示出了结合了在前面的示图中详细公开的柔性引导系统1的方面的添加制造系统100。系统100包括能量源90,其用于将邻接箔11的液体层30的预定区域51固化以得到有形物体50的固体层52,固体层从而具有预定形状。在箔11上,液体层30被形成为有限高度以与有形物体50接触。 Reference is now made to Fig. 6, which shows an additive manufacturing system 100 incorporating aspects of the flexible guidance system 1 disclosed in detail in the previous figures. The system 100 comprises an energy source 90 for curing a predetermined area 51 of the liquid layer 30 adjoining the foil 11 to obtain a solid layer 52 of the tangible object 50, the solid layer thus having a predetermined shape. On the foil 11 the liquid layer 30 is formed with a limited height to be in contact with the tangible object 50 . the
此外,往复式箔引导台180可以设置为具有与箔11接触的接触面181,并且在接触面181的引入侧和接触面181的拖出侧上包括一对上下箔引导件6、60,使得柔性箔引导辊4布置在这一对引导件之间,下箔引导件60限定与在箔高度H的接触面181相距高度H0的箔高度位置。图6-1图示了箔11的平面视图,其中箔11被引导通过接触面181同时被支承 布置1的弯曲辊1沿横向方向伸展。为了保持箔11不起皱,柔性引导辊作为第一引导辊4被放置在区域181的引入侧上,并且第二柔性引导辊4’被放置在拖出侧上;箔11在第一柔性引导辊4、4’两者上被牵引,并且箔11沿第一方向P运动以使得箔11保持与柔性引导辊4、4’接触,其中第一柔性引导辊和第二柔性引导辊具有第一曲率(A)。在与第一方向相反的运动方向Q上(参见图6-2),柔性引导辊4、4’具有与第一曲率A相反的第二曲率B。 Furthermore, the reciprocating foil guide table 180 may be provided with a contact surface 181 in contact with the foil 11 and includes a pair of upper and lower foil guides 6, 60 on the introduction side of the contact surface 181 and the pull-out side of the contact surface 181, such that The flexible foil guide roller 4 is arranged between this pair of guides, the lower foil guide 60 defining a foil height position at a distance H0 from the contact face 181 at foil height H. Figure 6-1 illustrates a plan view of the foil 11, wherein the foil 11 is guided through the contact surface 181 while being stretched in the transverse direction by the bending roll 1 of the supporting arrangement 1. In order to keep the foil 11 wrinkle-free, a flexible guide roll is placed as the first guide roll 4 on the lead-in side of the region 181 and a second flexible guide roll 4' is placed on the pull-out side; the foil 11 is placed on the first flexible guide The rollers 4, 4' are drawn on both and the foil 11 is moved in a first direction P such that the foil 11 remains in contact with the flexible guide rollers 4, 4', wherein the first flexible guide roller and the second flexible guide roller have a first Curvature (A). In a direction of movement Q opposite to the first direction (see Fig. 6-2), the flexible guide rollers 4, 4' have a second curvature B opposite to the first curvature A. the
因此,箔11可以被引导至接触面181或从接触面181被引导出,从而通过箔引导台180沿有形物体50的运动允许在箔上的树脂与有形物体50接触,同时在树脂层与有形物体接触期间使箔11相对于有形物体50保持固定。应该注意,在该条件下,箔相对于台180沿先前被指示为P和Q的相反方向运动。在实施例中,箔(11)的运动在两端(A和B)处被阻止。 Thus, the foil 11 can be guided to or from the contact surface 181 such that movement along the tangible object 50 by the foil guide table 180 allows the resin on the foil to come into contact with the tangible object 50 while contact between the resin layer and the tangible object 50 is achieved. The foil 11 remains fixed relative to the tangible object 50 during object contact. It should be noted that under this condition the foil moves relative to the stage 180 in opposite directions previously indicated as P and Q. In an embodiment, the movement of the foil (11) is blocked at both ends (A and B). the
在实施例中,箔包括输送层和结构层,输送层包括聚烯烃或含氟聚合物,并且结构层包括半结晶的热塑性聚合物。 In an embodiment, the foil comprises a transport layer comprising a polyolefin or a fluoropolymer and a structural layer comprising a semi-crystalline thermoplastic polymer. the
根据当前所要求的实用新型的第一方面,柔性多层衬底至少包括输送层和结构层,并且因此是多层衬底。柔性多层衬底必须具有至少两个层。在一些实施例中,柔性多层衬底具有两个层,并且在其他实施例中,柔性多层衬底具有三个或四个层。对于柔性多层衬底中层的数目没有实际的限制,只要衬底不会降低添加制造工艺的效力即可。例如,在某些情况下,太多层的添加可能降低柔性多层衬底的辐射透明度,以致不能向可辐射固化树脂传递足够的光化辐射。类似地,对柔性多层衬底的厚度没有实际的限制,只要厚度不会对三维物体的构建带来太多负面影响即可。在实施例中,柔性多层衬底具有至少20微米的厚度。在实施例中,柔性多层衬底的厚度为从约50微米到约350微米。在实施例中,柔性多层衬底的厚度为从约20微米到约250微米。在实施例中,柔性多层衬底的厚度为从约50微米到约250微米。在另一个实施例中,柔性多层衬底的厚度为从约90微米到约160微米。 According to a first aspect of the presently claimed utility model, the flexible multilayer substrate comprises at least a transport layer and a structural layer, and is thus a multilayer substrate. A flexible multilayer substrate must have at least two layers. In some embodiments, the flexible multilayer substrate has two layers, and in other embodiments, the flexible multilayer substrate has three or four layers. There is no practical limit to the number of layers in a flexible multilayer substrate, as long as the substrate does not reduce the effectiveness of the additive manufacturing process. For example, in some cases, the addition of too many layers may reduce the radiation transparency of the flexible multilayer substrate such that sufficient actinic radiation cannot be delivered to the radiation curable resin. Similarly, there is no practical limit to the thickness of flexible multilayer substrates, as long as the thickness does not bring too much negative impact on the construction of three-dimensional objects. In an embodiment, the flexible multilayer substrate has a thickness of at least 20 microns. In an embodiment, the thickness of the flexible multilayer substrate is from about 50 microns to about 350 microns. In an embodiment, the thickness of the flexible multilayer substrate is from about 20 microns to about 250 microns. In an embodiment, the thickness of the flexible multilayer substrate is from about 50 microns to about 250 microns. In another embodiment, the thickness of the flexible multilayer substrate is from about 90 microns to about 160 microns. the
在实施例中,柔性多层衬底的各个层至少有10微米厚。在实施例 中,柔性多层衬底的各个层至少有20微米厚。在实施例中,输送层为从10到100微米厚,并且结构层为10到250微米厚。在实施例中,输送层为从10到250微米厚,并且结构层为30到200微米厚。 In an embodiment, each layer of the flexible multilayer substrate is at least 10 microns thick. In an embodiment, each layer of the flexible multilayer substrate is at least 20 microns thick. In an embodiment, the transport layer is from 10 to 100 microns thick and the structural layer is 10 to 250 microns thick. In an embodiment, the transport layer is from 10 to 250 microns thick and the structural layer is 30 to 200 microns thick. the
柔性多层衬底包括输送层和结构层。输送层用于接触可辐射固化树脂。因此,输送层应该具有用于接触可辐射固化树脂的期望性能,并且具有允许从可辐射固化树脂的刚固化的层期望分离的性能。结构层提供结构完整性。例如,结构层与输送层的物理性能相比具有某些改善的物理性能。输送层因此用于接触可辐射固化树脂,并且结构层用于提供结构完整性,结构层和输送层彼此固定到一起。例如,输送层可以直接固定到结构层,或者可以固定到中间项目,其中中间项目固定到结构层。 The flexible multilayer substrate includes a transport layer and a structural layer. The transport layer is used to contact the radiation curable resin. Thus, the delivery layer should have the desired properties for contacting the radiation curable resin and have properties that allow the desired separation from the as-cured layer of the radiation curable resin. Structural layers provide structural integrity. For example, the structural layer has certain improved physical properties compared to the physical properties of the transport layer. The transport layer is thus used to contact the radiation curable resin, and the structural layer is used to provide structural integrity, the structural and transport layers being secured to each other. For example, a transport layer can be pinned directly to a structural layer, or it can be pinned to an intermediate item that is pinned to a structural layer. the
柔性多层衬底的输送层和结构层以及其他层(如果需要)可以使用诸如共挤、层压和热合等本领域已知的方法来固定。可以使用任何可行的方法来固定层,只要该方法与为柔性多层衬底的各个层所选择的材料兼容并且能够形成将容许经由添加制造工艺来构件三维物体的柔性多层衬底即可。所使用的固定方法必须实现具有基本均匀的厚度且很少或没有褶皱的柔性多层衬底。柔性多层衬底应该具有低内部应力以避免柔性多层衬底的翘曲,并且应该是基本平坦的以允许三维物体的精确构件。层压需要使用胶黏剂或其他物质来固定层。热合包含将柔性多层衬底的层加热到适当的温度然后将该层按压到柔性多层彻底的另一个层以固定层。 The transport and structural layers and other layers (if desired) of the flexible multilayer substrate can be secured using methods known in the art such as coextrusion, lamination, and heat sealing. Any feasible method can be used to fix the layers, as long as the method is compatible with the materials chosen for the various layers of the flexible multilayer substrate and is capable of forming a flexible multilayer substrate that will allow three-dimensional objects to be built via additive manufacturing processes. The fixation method used must result in a flexible multilayer substrate of substantially uniform thickness with little or no wrinkling. The flexible multilayer substrate should have low internal stress to avoid warping of the flexible multilayer substrate, and should be substantially flat to allow precise construction of three-dimensional objects. Lamination requires the use of adhesives or other substances to hold the layers in place. Heat sealing involves heating a layer of the flexible multilayer substrate to an appropriate temperature and then pressing the layer to another layer over the flexible multilayer substrate to secure the layers. the
形成柔性多层衬底的共挤方法可能需要使用配合层(tie-layer)。配合层是将被共挤的层固定在一起的薄材料。用于配合层的适当材料是与马来酸酐接枝的聚烯烃,诸如来自的或者ExxelorTM。配合层应该被选择为确保足够的粘附力以防止在添加制造工艺期间两个层分层,并且对组合衬底的辐射透射性能没有任何显著的影响。 Coextrusion methods to form flexible multilayer substrates may require the use of tie-layers. The mating layer is the thin material that holds the coextruded layers together. A suitable material for the mating layer is a polyolefin grafted with maleic anhydride, such as from of Or Exxelor( TM) . The mating layer should be chosen to ensure sufficient adhesion to prevent delamination of the two layers during the additive manufacturing process, and without any significant impact on the radiation transmission properties of the combined substrate.
对于形成柔性多层衬底的层压方法,可能需要表面处理以将柔性多层衬底的层彼此充分固定。为了获得柔性多层衬底的层之间的良好的粘附力,可能需要表面处理以在柔性多层衬底的表面上引入反应基,从而使柔性多层衬底的层彼此充分固定。 For lamination methods to form flexible multilayer substrates, surface treatments may be required to adequately secure the layers of the flexible multilayer substrate to each other. In order to obtain good adhesion between the layers of the flexible multilayer substrate, surface treatments may be required to introduce reactive groups on the surface of the flexible multilayer substrate so that the layers of the flexible multilayer substrate are sufficiently fixed to each other. the
在实施例中,在粘着之前对柔性多层衬底的层执行电晕处理(corona treatment)或其他等离子体处理。电晕处理是使用低温电晕放电等离子体对表面的性能进行改变的表面改性技术。电晕等离子体是通过对尖锐的电极尖端施加高压而产生的,其中尖锐的电极尖端在尖锐尖端的端部处形成等离子体。通常使用电极的线性阵列来形成电晕等离子体幕(curtain of corona plasma)。在另一个实施例中,在衬底的层被固定到衬底的另一个层之前对该衬底的层进行化学处理。可以仅对输送层的第层、或者而对输送层和结构层两者的接触侧面、或者柔性多层衬底的其他不同层进行表面处理。 In an embodiment, corona treatment or other plasma treatment is performed on the layers of the flexible multilayer substrate prior to adhesion. Corona treatment is a surface modification technique that uses low-temperature corona discharge plasma to change the properties of the surface. Corona plasma is generated by applying a high voltage to a sharpened electrode tip that forms a plasma at the end of the sharpened tip. A linear array of electrodes is typically used to form a curtain of corona plasma. In another embodiment, the layer of the substrate is chemically treated before the layer of the substrate is fixed to another layer of the substrate. The surface treatment may be performed on only the first layer of the transport layer, or on the contacting sides of both the transport layer and the structural layer, or other different layers of the flexible multilayer substrate. the
对于形成柔性多层衬底的层压方法,必须使用胶黏剂来固定输送层和结构层。输送层和结构层可以使用对组合的柔性多层衬底的辐射透射性能没有任何显著影响的胶黏剂来固定。用于层压的适当胶黏剂通常是两组分聚氨酯胶黏剂(two component polyurethane adhesives)。然而,并不限于使用聚氨酯。其他可行的胶黏剂的示例是马来酸酐改性聚乙烯、丙烯酸树脂或者双组分环氧(水或溶剂型)以及其他。 For lamination methods to form flexible multilayer substrates, adhesives must be used to secure the transport and structural layers. The transport and structural layers can be fixed using adhesives that do not have any significant effect on the radiation transmissive properties of the combined flexible multilayer substrate. Suitable adhesives for lamination are usually two component polyurethane adhesives. However, the use of polyurethane is not limited. Examples of other possible adhesives are maleic anhydride modified polyethylene, acrylic resins or two-component epoxies (water or solvent based) among others. the
通常,通过在第二材料上涂覆第一材料来形成柔性多层衬底是不期望的。涂覆可能由于涂覆材料的固化或干燥上的差异而产生在尺寸上或一致性上不均匀的表面。此外,涂覆可能对刮擦或划蹭的抵抗力较差,并且与包括聚烯烃或含氟聚合物输送层和半结晶热塑性聚合物的结构层的柔性多层衬底相比、随时间推移更有可能磨损。 In general, it is not desirable to form a flexible multilayer substrate by coating a first material on a second material. Coating may result in a surface that is not uniform in size or consistency due to differences in curing or drying of the coating material. In addition, coatings may be less resistant to scratching or scuffing and, compared to flexible multilayer substrates that include polyolefin or fluoropolymer transport layers and structural layers of semi-crystalline thermoplastic polymers, tend to more likely to wear out. the
此外,已经发现,包含由涂覆工艺形成的输送层的柔性多层衬底与包括聚烯烃或含氟聚合物输送层的多层衬底相比、耐用性大幅降低。在涂覆衬底的测试期间,发现在PET结构层上涂覆的硅胶层(silicone layer)并不耐用,这是因为在构建仅几百天之后就观察到固化的可辐射固化树脂到柔性多层衬底的粘附。因此已经发现固定输送层和结构层的共挤和层压方法提供更稳健的柔性多层衬底。 Furthermore, it has been found that flexible multilayer substrates comprising a delivery layer formed by a coating process have substantially reduced durability compared to multilayer substrates comprising polyolefin or fluoropolymer delivery layers. During testing of coated substrates, it was found that the silicone layer coated on top of the PET structure layer was not durable, as the cured radiation curable resin was observed to be much more flexible after only a few hundred days of construction. Adhesion to the substrate. It has thus been found that coextrusion and lamination methods of securing the transport and structural layers provide more robust flexible multilayer substrates. the
根据当前所要求实用新型的第一方面,柔性多层衬底包括聚烯烃或含氟聚合物输送层。输送层具有如下性能,该性能允许可辐射固化树脂的可接受的涂覆和刚固化的层的剥离。输送层不得在涂覆于输送层上的可辐射固化树脂被固化之前、不会导致可辐射固化树脂的任何实质上的去湿。输 送层不得粘着到新固化的层,以使得分离新固化的层和衬底的步骤不会呈现出粘着破坏(cohesive failure)。此外,使用输送层能够使辐射固化树脂免受结构层的破坏,并且依赖于该结构层使结构层免受辐射固化树脂的破坏。某些聚合物结构层可能包含大量的水分。在可包括结构层的某些聚合物(例如聚酰胺和聚酯)中的水分可能导致在某些可辐射固化树脂固化时产生的强酸促进衬底的水解作用。通过在衬底中使用聚烯烃或含氟聚合物输送层,由于酸不可能接触到结构层,从而消除了这种反应。 According to a first aspect of the presently claimed invention, the flexible multilayer substrate comprises a polyolefin or fluoropolymer transport layer. The delivery layer has properties that allow for acceptable application of the radiation curable resin and release of the freshly cured layer. The transfer layer must not result in any substantial dewetting of the radiation curable resin before the radiation curable resin applied on the transfer layer is cured. The transfer layer must not adhere to the newly cured layer so that the step of separating the newly cured layer from the substrate does not exhibit cohesive failure. Furthermore, the use of the delivery layer enables the radiation curable resin to be protected from damage by the structural layer, and the structural layer is relied upon to protect the structural layer from damage to the radiation curable resin. Some polymeric construction layers may contain significant amounts of moisture. Moisture in certain polymers that may comprise structural layers, such as polyamides and polyesters, may cause strong acids that are generated upon curing of certain radiation curable resins to promote hydrolysis of the substrate. By using a polyolefin or fluoropolymer transport layer in the substrate, this reaction is eliminated since it is impossible for the acid to reach the structural layer. the
在实施例中,输送层为聚烯烃。在其它实施例中,输送层为支化低密度聚乙烯(LDPE)、线性低密度聚乙烯(LLPE或LLDPE)、高密度聚乙烯(HDPE)、高度支化聚乙烯或者分子量通常高于1×106g/mol的超高分子量聚乙烯(UHMWPE)。在其它实施例中,输送层为塑料,诸如乙烯和辛烯的共聚物以及聚甲基戊烯等。在其它实施例中,输送层为乙烯、丙烯、丁烯、己烯、辛烯、降冰片烯、苯乙烯聚合物或者其共聚物和混合物。在实施例中,输送层为高乙烯级的乙烯基降冰片烯(ethylene-norborene)共聚物,诸如TOPAS等。 In an embodiment, the transport layer is polyolefin. In other embodiments, the transport layer is branched low density polyethylene (LDPE), linear low density polyethylene (LLPE or LLDPE), high density polyethylene (HDPE), highly branched polyethylene, or a molecular weight typically higher than 1× 10 6 g/mol of ultra-high molecular weight polyethylene (UHMWPE). In other embodiments, the transport layer is a plastic, such as a copolymer of ethylene and octene, polymethylpentene, and the like. In other embodiments, the transport layer is a polymer of ethylene, propylene, butene, hexene, octene, norbornene, styrene, or copolymers and mixtures thereof. In an embodiment, the transport layer is a high ethylene grade vinyl norbornene copolymer, such as TOPAS or the like.
由于某些可辐射固化树脂尤其是混合固化液体可辐射固化树脂的去湿性,如果添加制造工艺太慢,则在含氟聚合物的表面上,可辐射固化树脂可能会在对可辐射固化树脂进行固化之前已经去湿。通常,与含氟聚合物相比聚烯烃使树脂去湿的可能性较小,因此取决于添加制造工艺是优选的。 Due to the dehumidification properties of some radiation curable resins, especially hybrid curable liquid radiation curable resins, if the additive manufacturing process is too slow, on the surface of the fluoropolymer, the radiation curable resin may be exposed to the radiation curable resin. Dehumidified before curing. In general, polyolefins are less likely to dewet the resin than fluoropolymers and are therefore preferred depending on the additive manufacturing process. the
含氟聚合物也可取决于添加制造工艺的工艺速度形成有用的输送层。在实施例中,输送层为含氟聚合物。在某些实施例中,输送层为聚四氟乙烯(PTFE)。在其它实施例中,输送层为四氟乙烯和乙烯的共聚物(ETFE,)。在实施例中,输送层为氟化乙丙烯共聚物(FEP)。在实施例中,输送层为AF,即四氟乙烯和二(三氟甲基)-4,5-二氟-1,3-间二氧杂环戊烯(tetrafluoroethylene and2,2-bis-4,5-difluoro-1,3-dioxole)。在其它实施例中,输送层为聚氟乙烯(PVF),并且在其它实施例中为聚偏二氟乙烯(PVDF)。 Fluoropolymers may also form useful transport layers depending on the process speed of the additive manufacturing process. In an embodiment, the transport layer is a fluoropolymer. In certain embodiments, the transport layer is polytetrafluoroethylene (PTFE). In other embodiments, the transport layer is a copolymer of tetrafluoroethylene and ethylene (ETFE, ). In an embodiment, the transport layer is a fluorinated ethylene propylene copolymer ( FEP). In an embodiment, the transport layer is AF, tetrafluoroethylene and bis(trifluoromethyl)-4,5-difluoro-1,3-dioxole (tetrafluoroethylene and2,2-bis-4,5-difluoro-1,3 -dioxole). In other embodiments, the transport layer is polyvinyl fluoride (PVF), and in other embodiments polyvinylidene fluoride (PVDF).
在实施例中,柔性多层衬底为各向同性的。各向同性能够利用非取向 或双轴取向的衬底来实现。在实施例中,输送层为非取向的。在另一实施例中,输送层为(x-y平面内的)双轴取向的。在其它实施例中,结构层为非取向的,并且在实施例中,结构层为双轴取向的。在实施例中,各向同性的结构层由多个取向层形成。在实施例中,例如利用钢丝绒通过人工蚀刻法使输送层产生磨砂面,以对输送层的可辐射固化树脂接触侧进行表面抛光。 In an embodiment, the flexible multilayer substrate is isotropic. Isotropy can be achieved with non-oriented or biaxially oriented substrates. In an embodiment, the transport layer is non-oriented. In another embodiment, the transport layer is biaxially oriented (in the x-y plane). In other embodiments, the structural layer is non-oriented, and in embodiments, the structural layer is biaxially oriented. In an embodiment, the isotropic structural layer is formed from a plurality of alignment layers. In an embodiment, the radiation curable resin contacting side of the delivery layer is surface polished, eg, by hand etching the delivery layer with steel wool to create a frosted surface. the
根据当前所要求的实用新型的第一方面,柔性多层衬底包括半结晶热塑性结构层。结构层相对于输送层具备改进的物理性能。例如,结构层可提供改进的抗撕裂性、耐温性、机械性能(例如,拉伸强度或屈服应力)或者其它性能。如果添加制造工艺或设备被布置为通过衬底透射光化辐射,则结构层也必须具备高的辐射透射性。 According to a first aspect of the presently claimed utility model, the flexible multilayer substrate comprises a semi-crystalline thermoplastic structural layer. The structural layer has improved physical properties relative to the transport layer. For example, structural layers may provide improved tear resistance, temperature resistance, mechanical properties (eg, tensile strength or yield stress), or other properties. If the additive manufacturing process or device is arranged to transmit actinic radiation through the substrate, the structural layers must also be highly radiation transmissive. the
结构层包括半结晶热塑性聚合物。在实施例中,半结晶热塑性聚合物为聚酰胺。在其它实施例中,结构层为聚酰胺-6、聚酰胺-6,6、聚酰胺-4,10、聚酰胺-4,6、聚酰胺-11、聚酰胺-12、聚酰胺-6T、聚酰胺-4T、聚内酰胺及其共聚物。在其它实施例中,结构层为聚酯。在其它实施例中,结构层为聚对苯二甲酸乙二醇酯、聚对苯二甲酸丁二醇酯、(polypropyleneterephthalate)或其乙交酯的共聚物。在其它实施例中,结构层为聚乳酸、聚乙醇酸、聚羟基脂肪酸酯、聚内酯、聚萘二甲酸乙二醇酯(PEN)、聚萘二酸丁醇酯(PBN)及其共聚物。在其它实施例中,结构层为聚醚。在其它实施例中,结构层为聚甲醛、聚亚烷基氧化物及其共聚物。在实施例中,结构层在处理期间被双轴延展,从而产生双轴取向。 The structural layer includes a semi-crystalline thermoplastic polymer. In an embodiment, the semicrystalline thermoplastic polymer is polyamide. In other embodiments, the structural layer is polyamide-6, polyamide-6,6, polyamide-4,10, polyamide-4,6, polyamide-11, polyamide-12, polyamide-6T, Polyamide-4T, polylactam and its copolymers. In other embodiments, the structural layer is polyester. In other embodiments, the structural layer is polyethylene terephthalate, polybutylene terephthalate, (polypropyleneterephthalate) or a copolymer of glycolide thereof. In other embodiments, the structural layer is polylactic acid, polyglycolic acid, polyhydroxyalkanoate, polylactone, polyethylene naphthalate (PEN), polybutylene naphthalate (PBN) and the like. copolymer. In other embodiments, the structural layer is polyether. In other embodiments, the structural layer is polyoxymethylene, polyalkylene oxide, and copolymers thereof. In an embodiment, the structural layer is biaxially stretched during processing, thereby creating a biaxial orientation. the
在其它实施例中,结构层为加强半结晶热塑性聚合物。该聚合物可通过例如纤维或颗粒来加强。在实施例中,颗粒为矿物填料,诸如云母、化石、碳酸钙、硫酸钡等。在另一实施例中,颗粒为亚微米大小的颗粒,例如纳米粘土和纳米二氧化硅。亚微米大小的颗粒具有这样的优点,它们可以基本上不影响衬底的光透射的方式扩散。当利用加强聚合物时,必须密切监控衬底的UV透射,并且基本上辐射透明的加强剂是优选的加强。在实施例中,结构层包括聚酰胺纳米复合材料。 In other embodiments, the structural layer is a reinforced semi-crystalline thermoplastic polymer. The polymer can be reinforced by, for example, fibers or particles. In embodiments, the particles are mineral fillers such as mica, fossil, calcium carbonate, barium sulfate, and the like. In another embodiment, the particles are submicron sized particles, such as nanoclay and nanosilica. Submicron sized particles have the advantage that they can be diffused in a manner that does not substantially affect the light transmission of the substrate. When utilizing reinforcing polymers, the UV transmission of the substrate must be closely monitored, and substantially radiation transparent reinforcing agents are the preferred reinforcing. In an embodiment, the structural layer comprises a polyamide nanocomposite. the
相对于非晶态材料,采用了半结晶热塑性聚合物结构层,这是因为半 结晶热塑性聚合物与非晶态材料相比不易碎而且具有改进的抗裂性。此外,半结晶热塑性聚合物与非晶态材料相比具有改进的抗龟裂性。龟裂在UV光曝光下会加重。为了在某些方面中提供最佳工艺条件,希望使箔11在接触面181上尽可能保持平坦。为此,接触面181可以被特殊地设计为例如具有抽吸或夹持装置以沿纵长方向夹持箔;此外,可以设置机械结构以在预定拉力下保持箔的长度。最佳拉力取决于箔的类型和厚度,但可以通常是大约每cm箔宽度为10N(对于50cm的箔宽度为500N)。该拉力可以使箔11在具有接触高度H的接触区域181上保持平坦。纵长拉力足够使得箔在该整个区域上保持平坦(包括其边缘),并且在其边缘上不需要夹具或其他拉力装置。 Structural layers of semi-crystalline thermoplastic polymers are employed relative to amorphous materials because semi-crystalline thermoplastic polymers are less brittle and have improved crack resistance compared to amorphous materials. In addition, semi-crystalline thermoplastic polymers have improved resistance to cracking compared to amorphous materials. Cracks are exacerbated by exposure to UV light. In order to provide optimum process conditions in some respects, it is desirable to keep the foil 11 as flat as possible on the contact surface 181 . To this end, the contact surface 181 can be specially designed, for example with suction or clamping means to clamp the foil in lengthwise direction; moreover, mechanical structures can be provided to maintain the length of the foil under a predetermined tension. The optimum tension depends on the type and thickness of the foil, but may typically be around 10N per cm foil width (500N for a 50cm foil width). This tension makes it possible to keep the foil 11 flat on the contact area 181 with the contact height H. FIG. The lengthwise tension is sufficient to keep the foil flat over its entire area, including its edges, and no clamps or other tensioning devices are required on its edges. the
在本发明的另一个实施例中,存在通常具有较低弹性模量的其他类型的箔,其中纵长拉力可能不足以使箔在整个相关区域181上保持平坦。在箔11的特定边缘会出现向上或向下移动的趋势或者从期望平面起皱。为此,柔性辊布局1设置为使弯曲辊4根据箔相对于承载台180的运动方向而弯曲,这至少在由接触面181所限定的较短区域上显著地减少了任何起皱。 In another embodiment of the invention, there are other types of foils that generally have a lower modulus of elasticity, where the longitudinal tension may not be sufficient to keep the foil flat across the relevant area 181 . At certain edges of the foil 11 there will be a tendency to move up or down or to wrinkle from the desired plane. To this end, the flexible roll arrangement 1 is arranged such that the bending roll 4 bends according to the direction of movement of the foil relative to the carrier table 180 , which significantly reduces any wrinkling at least over the short area defined by the contact surface 181 . the
在该实施例中,系统100可以包括液体树脂上涂装置200,该上涂装置200在所示示例中填充有树脂液体30。可替代地,树脂层可以以预制造的薄片形式提供。在实施例中,上涂装置200是一个或多个滚花辊的形式。 In this embodiment, the system 100 may include a liquid resin applicator 200 filled with a resin liquid 30 in the example shown. Alternatively, the resin layer may be provided as a prefabricated sheet. In an embodiment, applicator 200 is in the form of one or more knurled rolls. the
能量源90可以被布置为当液体层30在区域51与有形物体50接触时穿过箔11投影图案。特别地,能量源90可以被布置用于在液体层中、在交叉图案的至少一部分中至少部分地固化(curing)。为了使得能量源90的光或其他辐射能够使液体层30固化,箔11优选地对于该辐射基本透明。 Energy source 90 may be arranged to project a pattern through foil 11 when liquid layer 30 is in contact with tangible object 50 at region 51 . In particular, the energy source 90 may be arranged for at least partial curing in at least a part of the cross pattern in the liquid layer. In order to enable light or other radiation from the energy source 90 to cure the liquid layer 30, the foil 11 is preferably substantially transparent to the radiation. the
在所示示例实施例中,能量源90在箔引导元件19之间被放置在可移动箔引导台18上,以通过箔11暴露未固化材料层。或者,能量源相对于往复式箔引导台180是可移动的。 In the example embodiment shown, energy source 90 is placed on movable foil guiding table 18 between foil guiding elements 19 to expose the layer of uncured material through foil 11 . Alternatively, the energy source is movable relative to the reciprocating foil guide table 180 . the
可移动z台140在新的可固化材料层被提供到有形物体50之前可沿z 方向移动。每当新的层固化和分离之后,承载板(z台)150连同其上附着有固化层52的有形物体50一起向上移动。 The movable z-stage 140 is movable in the z-direction before a new layer of curable material is provided to the tangible object 50. Each time a new layer is cured and separated, the carrier plate (z-stage) 150 moves upward together with the tangible object 50 with the cured layer 52 attached thereon. the
z方向意指从布置在箔11上的可固化材料层51的平面方向向外的方向。z台140在箔引导台180不移动时可以上升。在该实施例中,滚动元件170使z台140能够移动。有形物体50连接到z台140,并且在各个方法循环中,新的层从下方层叠。为了清楚,可固化材料的层以夸张的厚度示出。 The z-direction means the direction outwards from the planar direction of the curable material layer 51 arranged on the foil 11 . The z stage 140 can be raised while the foil guide stage 180 is not moving. In this embodiment, rolling elements 170 enable movement of z-stage 140 . The tangible object 50 is connected to the z-stage 140 and in each method cycle a new layer is laminated from below. Layers of curable material are shown with exaggerated thickness for clarity. the
箔11和箔引导台180可相独立地运动。在一个操作模式中,在第一步骤中,箔11被移动以将可固化材料层设置在有形物体50的下方。此时,可固化材料还没有与有形物体50接触。在第二步骤中,箔引导台180沿着有形物体50移动以将可固化材料层51施加到有形物体50、曝光可固化材料51并且移除未固化材料。在第二步骤中,箔11相对于有形物体50基本不沿垂直于z方向移动。为了缩短台180的长度方向,曝光单元90通常被限制为沿承载台移动方向例如对于约50cm的工作区域仅有利用2×2mm2的元件(‘像素’,各个像素具有LED+微透镜)实现的约6cm长度,并且仍然提供每毫米工作区域宽度为约15个像素的高分辨率。该布置的细节在PCT/NL2009/050783中公开,该申请通过引用整体结合于此。 The foil 11 and the foil guide table 180 are movable independently of each other. In one mode of operation, the foil 11 is moved to place a layer of curable material underneath the tangible object 50 in a first step. At this point, the curable material is not yet in contact with the tangible object 50 . In a second step, foil guide table 180 is moved along tangible object 50 to apply curable material layer 51 to tangible object 50, expose curable material 51 and remove uncured material. In the second step, the foil 11 is substantially not moved relative to the tangible object 50 in the direction perpendicular to z. In order to shorten the length direction of the stage 180, the exposure unit 90 is usually limited to only 2 ×2mm elements (‘pixels’, each pixel has LED+microlens) for a working area of about 50 cm along the moving direction of the carrier stage. 6 cm in length and still provide a high resolution of about 15 pixels per mm of working area width. Details of this arrangement are disclosed in PCT/NL2009/050783, which application is hereby incorporated by reference in its entirety.
如这里所使用的,术语“可固化材料”包括可通过例如UV光、激光、离子辐射(包括但不限于电子束、伽马射线或x射线)或者前面任意项的组合等固化(即,可被聚合和/或交联)的任何材料。术语“可固化材料”还应该理解为包括可固化和不可固化材料的复合材料,诸如混合了纤维和/或填充物的树脂等。 As used herein, the term "curable material" includes materials that are curable by, for example, UV light, lasers, ionizing radiation (including but not limited to electron beams, gamma rays, or x-rays), or combinations of any of the foregoing, etc. (i.e., curable polymerized and/or crosslinked) any material. The term "curable material" should also be understood to include composite materials of curable and non-curable materials, such as resins mixed with fibers and/or fillers, and the like. the
部分固化包括固化到这样的程度,即,在从交叉图案以外的层去除未固化材料时交叉图案保持稳定。可固化材料没有被完全固化,而是仅仅固化到这样的程度,即材料足够稳定以使得在去除交叉图案以外的未固化材料的步骤期间该材料不会与未固化材料一起被去除。 Partial curing includes curing to the extent that the crossing pattern remains stable upon removal of uncured material from layers other than the crossing pattern. The curable material is not fully cured, but only cured to the extent that the material is sufficiently stable that it is not removed along with the uncured material during the step of removing the uncured material outside the cross pattern. the
完全固化交叉图案需要一定的曝光时间。部分固化交叉图案意味着将图案固化到较低的程度。当能量源以与完成完全固化使用的功率相同的功 率操作时,曝光可以短一些并且RM和RP工艺的速度增大。 A certain exposure time is required to fully cure the cross pattern. Partially curing the cross pattern means curing the pattern to a lesser extent. When the energy source is operated at the same power as that used to complete a full cure, the exposure can be shorter and the speed of the RM and RP processes increased. the
在前面的实施例中所述的支承布局可以包括单个柔性辊。此外,支承布局可以包括多个柔性箔引导辊和多个支承系统,特别地:放置在中心线的第一侧上的第一柔性箔引导辊和第一支承系统,以及放置在中心线的第二侧上的第二柔性箔引导辊和第二支承系统。 The support arrangement described in the previous embodiments may comprise a single flexible roller. Furthermore, the support arrangement may comprise a plurality of flexible foil guide rollers and a plurality of support systems, in particular: a first flexible foil guide roller and a first support system placed on a first side of the centerline, and a first flexible foil guide roller and a first support system placed on the centerline. Second flexible foil guide rollers on both sides and a second support system. the
给出的详细附图、具体示例和特定的构想仅用作说明的目的。虽然这里描述和示出的装置100的具体实施例涉及从上向下构建模型50,但本实用新型的教导也可以应用于直立向上或呈角度构建模型的装置。在前面的说明书中,已经参考本实用新型的实施例的具体示例描述了本实用新型。然而,明显的,在不脱离如所附权利要求所述的本实用新型的较宽精神和范围的情况下,可以做出各种修改和改变。此外,物体可以具有任何适合的尺寸和形状。此外,设备可以物理地分布在多个装置上,但功能上作为单个设备操作。而且,功能上形成单独设备的设备可以集成在单个物理设备上。然而,其他修改、变体和替换也是可以的。因此,说明书和附图认为是说明性的而不是限制性意义的。虽然特定的实施例详细描述了特定可选特征作为本实用新型的进一步的方面,但该描述的含义是包含,并具体公开了除特别指明或物理上不可实现以外的这些特征的全部组合。 The detailed drawings, specific examples, and specific concepts have been presented for purposes of illustration only. While the specific embodiment of the device 100 described and illustrated herein relates to building the model 50 from the top down, the teachings of the present invention can also be applied to devices that build the model upright or at an angle. In the foregoing specification, the invention has been described with reference to specific examples of embodiments of the invention. It will, however, be evident that various modifications and changes can be made without departing from the broader spirit and scope of the invention as set forth in the appended claims. Additionally, objects may be of any suitable size and shape. Furthermore, a device may be physically distributed across multiple devices, yet functionally operate as a single device. Also, devices that functionally form separate devices may be integrated on a single physical device. However, other modifications, variations and substitutions are also possible. Accordingly, the specification and drawings are to be regarded in an illustrative rather than a restrictive sense. Although certain embodiments detail certain optional features as further aspects of the present invention, this description is meant to encompass and specifically disclose all combinations of these features unless otherwise specified or physically impossible. the
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106003712A (en) * | 2016-05-18 | 2016-10-12 | 太原科技大学 | Rolling device for additive manufacturing |
| US11993092B2 (en) | 2019-02-04 | 2024-05-28 | NFSC Holdings, LLC | UV/LED printing and finishing process |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106003712A (en) * | 2016-05-18 | 2016-10-12 | 太原科技大学 | Rolling device for additive manufacturing |
| CN106003712B (en) * | 2016-05-18 | 2017-12-12 | 太原科技大学 | A kind of rolling device for increasing material manufacturing |
| US11993092B2 (en) | 2019-02-04 | 2024-05-28 | NFSC Holdings, LLC | UV/LED printing and finishing process |
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