CN203484406U - Multi-heat source shaft interval-heating thermal desorption device for repairing soil polluted by organic matter - Google Patents
Multi-heat source shaft interval-heating thermal desorption device for repairing soil polluted by organic matter Download PDFInfo
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Abstract
本实用新型涉及环保领域,旨在提供一种用于有机物污染土壤修复的多热源有轴间热式热脱附装置。该装置的间热式热脱附器为夹套式加热炉;外筒上设有土壤进料口、出土器、第一多热源入口、第一多热源出口;在内筒设有载气入口、载气出口;由外轴套和中空内轴套构成夹套式结构的中空有轴式回转轴,设有分别与外轴套或内轴套相接的第二多热源出口和第二多热源入口;本实用新型可对有机污染物污染土壤进行有效处理,特别适用于高浓度、多组分有机污染物污染土壤场地修复;对多种热源适应性良好,提高了热源的综合利用效率;单位时间土壤处理能力大,且特别适用于砂质污染土壤。对于有机污染物污染土壤,可实现99.9%以上的有机污染物去除效率。
The utility model relates to the field of environmental protection and aims to provide a multi-heat-source interaxial heat-type thermal desorption device for remediation of organic-contaminated soil. The indirect thermal desorber of the device is a jacketed heating furnace; the outer cylinder is provided with a soil feed port, an excavator, the first multi-heat source inlet, and the first multi-heat source outlet; the inner cylinder is provided with a carrier gas inlet , Carrier gas outlet; the hollow shafted rotary shaft of the jacket structure composed of the outer sleeve and the hollow inner sleeve is provided with the second multi-heat source outlet and the second multi-heat source outlet respectively connected with the outer shaft sleeve or the inner shaft sleeve Heat source inlet; the utility model can effectively treat organic pollutant-contaminated soil, and is especially suitable for site restoration of high-concentration and multi-component organic pollutant-contaminated soil; it has good adaptability to various heat sources and improves the comprehensive utilization efficiency of heat sources; The soil treatment capacity per unit time is large, and it is especially suitable for sandy polluted soil. For organic pollutant-contaminated soil, the removal efficiency of organic pollutants can reach more than 99.9%.
Description
技术领域technical field
本实用新型涉及一套有机污染物污染土壤修复装置,通过间热式热脱附系统,将土壤中有机污染物脱附出来,属环保领域。The utility model relates to a set of organic pollutant polluted soil restoration device, which desorbs organic pollutants in soil through an indirect thermal desorption system, and belongs to the field of environmental protection.
背景技术Background technique
我国有大量土壤遭受了有机污染物污染,污染物种类包括农业生产使用的杀虫剂、电力行业使用的多氯联苯、以及石油行业事故泄油等。随着公众对有机污染物环境和健康危害的逐步认识,迫切的需要经济而有效方法处理这些毒性物质。A large amount of soil in my country has been polluted by organic pollutants. The types of pollutants include pesticides used in agricultural production, polychlorinated biphenyls used in the power industry, and accidental oil spills in the oil industry. With the gradual public awareness of the environmental and health hazards of organic pollutants, there is an urgent need for economical and effective methods to deal with these toxic substances.
主要的有机污染物污染土壤的修复技术有生物修复、化学修复、物理修复等。生物修复多为原位修复,其投资小、运行成本低、操作条件温和、对环境干扰小,但生物修复周期长,且受限于植物或微生物种类,仅能处理某些特定种类的有机污染物,且只能应用于较低浓度条件下;物理修复或化学修复多为异位修复,初始投资大、运行成本较高,但修复周期短,且适用于各种类型的有机污染物以及高浓度污染场地。比较而言,物理修复或化学修复有着更广泛的适用性,特别适用于高浓度、多组分有机污染污染场地。The main remediation technologies for soil contaminated by organic pollutants include biological remediation, chemical remediation, and physical remediation. Bioremediation is mostly in-situ repair, which has small investment, low operating cost, mild operating conditions, and little environmental interference, but the bioremediation cycle is long, and it is limited by the types of plants or microorganisms, and can only deal with certain types of organic pollution. substances, and can only be applied under low concentration conditions; physical remediation or chemical remediation is mostly ectopic remediation, with large initial investment and high operating costs, but the remediation period is short, and it is suitable for various types of organic pollutants and high Concentration pollution site. In comparison, physical remediation or chemical remediation has wider applicability, especially for high-concentration, multi-component organic pollution contaminated sites.
在众多的物理修复或化学修复技术中,热脱附是公认处理有机物污染土壤的成熟可靠技术,是最广泛的应用于有机物污染场地修复技术之一。热脱附技术对不同有机污染物种类及浓度有着良好的适应性,同时修复速度快,周期短。按照加热方式,热脱附技术可分为直热式和间热式两类。直热式技术热源和污染土壤直接接触,传热效率高,处理能力大,但产生大量需进一步处理的有害气体;间热式技术热源不和污染物料直接接触,传热效率较低,但需处理的有害气体量少,特别适用于高毒性有机物污染土壤处理。Among many physical or chemical remediation technologies, thermal desorption is recognized as a mature and reliable technology for treating organic matter-contaminated soil, and is one of the most widely used remediation technologies for organic matter-contaminated sites. Thermal desorption technology has good adaptability to different types and concentrations of organic pollutants, and at the same time, the repair speed is fast and the cycle is short. According to the heating method, thermal desorption technology can be divided into direct heating type and indirect heating type. The heat source of the direct heating technology is in direct contact with the polluted soil, which has high heat transfer efficiency and large processing capacity, but produces a large amount of harmful gas that needs further treatment; the heat source of the indirect heating technology does not directly contact the polluted material, and the heat transfer efficiency is low, but it needs to The amount of harmful gas processed is small, and it is especially suitable for the treatment of soil contaminated by highly toxic organic substances.
但是,目前的间接热脱附技术仍存在以下缺陷:热脱附器结构复杂,建造成本高,操作运行不便;传热效率低,能源利用效率低;对多种热源适应性不佳,不能充分利用低品味能源。对不同质地的土壤适应性差,热脱附过程中易发生土壤粘结现象。However, the current indirect thermal desorption technology still has the following defects: the structure of the thermal desorber is complex, the construction cost is high, and the operation is inconvenient; the heat transfer efficiency is low, and the energy utilization efficiency is low; Use low-taste energy. It has poor adaptability to soils of different textures, and soil bonding is prone to occur during thermal desorption.
实用新型内容Utility model content
本实用新型要解决的技术问题是,克服现有技术中的不足,提供一种用于有机物污染土壤修复的多热源有轴间热式热脱附装置。The technical problem to be solved by the utility model is to overcome the deficiencies in the prior art and provide a multi-heat source interaxial thermal desorption device for remediation of organic-contaminated soil.
为解决技术问题,本实用新型的解决方案是:For solving technical problems, the solution of the utility model is:
提供一种用于有机物污染土壤修复的多热源有轴间热式热脱附装置,包括热脱附器;该热脱附器是间热式热脱附器,为夹套式加热炉;Provided is a multi-heat source and axial interthermal thermal desorption device for remediation of organic-contaminated soil, including a thermal desorber; the thermal desorber is an indirect thermal desorber, which is a jacketed heating furnace;
间热式热脱附器包括水平方向布置的内筒和外筒,内筒的外壁上布置肋片用于促进传热;在外筒前端的上部设有接入至内筒中的土壤进料口、在内筒后端的下部设有出土器;在外筒后端的上部设有用于通入热量载体的第一多热源入口、在外筒前端的下部设有第一多热源出口;在内筒前端的下部设有用于通入载气的载气入口、在内筒后端的上部设有载气出口;热量载体在内筒外夹套中的流通路径与内筒中的土壤运动方向相反,载气在内筒中的流通路径均与内筒中的土壤运动方向相同;The indirect thermal desorber includes an inner cylinder and an outer cylinder arranged in a horizontal direction, and ribs are arranged on the outer wall of the inner cylinder to promote heat transfer; a soil feed port connected to the inner cylinder is provided on the upper part of the front end of the outer cylinder, The lower part of the inner cylinder rear end is provided with an excavator; the upper part of the outer cylinder rear end is provided with a first multi-heat source inlet for passing into the heat carrier, and the lower part of the outer cylinder front end is provided with a first multi-heat source outlet; the lower part of the inner cylinder front end is provided with There is a carrier gas inlet for feeding the carrier gas, and a carrier gas outlet is provided at the upper part of the rear end of the inner cylinder; the flow path of the heat carrier in the outer jacket of the inner cylinder is opposite to the movement direction of the soil in the inner cylinder, and the flow of the carrier gas in the inner cylinder The flow paths are all in the same direction as the soil movement in the inner cylinder;
在内筒的中心线上设有空心转动轴,是由外轴套和中空内轴套构成夹套式结构的中空有轴式回转轴;在空心转动轴的一端设有第二多热源出口和用于通入热量载体的第二多热源入口;第二多热源出口和第二多热源入口分别与外轴套或内轴套相接,其安装方式的选择使得热量载体在外轴套中的流向与内筒中的土壤运动方向相反。A hollow rotating shaft is provided on the center line of the inner cylinder, which is a hollow shafted rotating shaft with a jacket structure composed of an outer sleeve and a hollow inner sleeve; one end of the hollow rotating shaft is provided with a second multi-heat source outlet and The second multi-heat source inlet for passing through the heat carrier; the second multi-heat source outlet and the second multi-heat source inlet are respectively connected to the outer shaft sleeve or the inner shaft sleeve, and the selection of the installation method makes the flow direction of the heat carrier in the outer shaft sleeve Opposite to the movement of the soil in the inner barrel.
本实用新型中,所述出土器的下端设置输送器,输送器的上方设增湿器。In the utility model, a conveyor is arranged at the lower end of the excavator, and a humidifier is arranged above the conveyor.
本实用新型中,所述多热源入口接至燃油高温烟气出口、余热锅炉废气出口或电厂锅炉废气出口。In the utility model, the multi-heat source inlet is connected to the high-temperature flue gas outlet of the fuel oil, the exhaust gas outlet of the waste heat boiler or the exhaust gas outlet of the power plant boiler.
与现有技术相比,本实用新型的有益效果在于:Compared with the prior art, the utility model has the beneficial effects of:
本实用新型的用于有机物污染土壤修复的多热源有轴间热式热脱附装置,通过间接加热对土壤进行热脱附,可对有机污染物污染土壤进行有效处理,特别适用于高浓度、多组分有机污染物污染土壤场地修复;对多种热源适应性良好,且可根据目标有机污染物的理化性质,选择适宜的热源,提高了热源的综合利用效率;采用间热式热脱附装置,减少了需处理的烟气量;采用具有肋片的内筒外壁结构设计,同时多热源与土壤异向运动,促进了多热源和土壤的换热,增加了传热效率;采用有轴式旋转轴,单位时间土壤处理能力大,且特别适用于砂质污染土壤。对于有机污染物污染土壤,本装置可实现99.9%以上的有机污染物去除效率。本实用新型的有机物污染土壤修复的多热源有轴间热式热脱附装置,其需处理烟气量少、有机污染物去除彻底、运行成本较焚烧等技术低30~60%,能经济有效的处理有机污染物污染土壤。The multi-heat source interaxial thermal desorption device for the remediation of organic polluted soil of the utility model can perform thermal desorption on the soil through indirect heating, and can effectively treat the soil polluted by organic pollutants, and is especially suitable for high concentration, Remediation of soil contaminated by multi-component organic pollutants; good adaptability to various heat sources, and the appropriate heat source can be selected according to the physical and chemical properties of the target organic pollutants, which improves the comprehensive utilization efficiency of heat sources; adopts indirect thermal desorption The device reduces the amount of flue gas to be treated; the design of the outer wall of the inner cylinder with fins is adopted, and at the same time, multiple heat sources and soil move in opposite directions, which promotes the heat exchange between multiple heat sources and soil and increases the heat transfer efficiency; The rotary shaft has a large soil treatment capacity per unit time, and is especially suitable for sandy polluted soil. For soil polluted by organic pollutants, this device can achieve a removal efficiency of more than 99.9% of organic pollutants. The multi-heat source for the remediation of organic-contaminated soil of the utility model has an inter-axial thermal desorption device, which requires less flue gas treatment, complete removal of organic pollutants, and lower operating costs by 30-60% compared with incineration and other technologies, which is economical and effective The treatment of organic pollutants polluted soil.
附图说明Description of drawings
图1是本实用新型的工艺流程示意图。Fig. 1 is the technological process schematic diagram of the present utility model.
图中附图标记:1土壤进料口,2外筒,3内筒,4电机,5空心转动轴,6第一多热源入口,7第一多热源出口,8载气入口,9载气出口,10出土器,11输送器,12增湿器,13肋片,14第二多热源入口,15第二多热源出口。Reference signs in the figure: 1 soil feed inlet, 2 outer cylinder, 3 inner cylinder, 4 motor, 5 hollow rotating shaft, 6 first multi-heat source inlet, 7 first multi-heat source outlet, 8 carrier gas inlet, 9 carrier gas Exit, 10 excavators, 11 conveyors, 12 humidifiers, 13 fins, 14 second multi-heat source inlets, 15 second multi-heat source outlets.
具体实施方式Detailed ways
参照上述附图,对本实用新型的技术内容做一详细说明。With reference to the above-mentioned accompanying drawings, the technical content of the present utility model is described in detail.
用于有机物污染土壤修复的多热源有轴间热式热脱附装置,包括热脱附器;该热脱附器是间热式热脱附器,为夹套式加热炉;The multi-heat sources used for remediation of organic-contaminated soil include an interaxial thermal desorption device, including a thermal desorber; the thermal desorber is an indirect thermal desorber, which is a jacketed heating furnace;
间热式热脱附器包括水平方向布置的内筒3和外筒2,内筒3的外壁上布置肋片13用于促进传热;在外筒2前端的上部设有接入至内筒3中的土壤进料口1、在外筒2后端的下部设有出土器10;出土器10的下端设置输送器11,输送器11的上方设增湿器12。The indirect thermal desorber includes an inner cylinder 3 and an outer cylinder 2 arranged in a horizontal direction.
在外筒2后端的上部设有用于通入热量载体的第一多热源入口6、在外筒2前端的下部设有第一多热源出口7;在内筒3前端的下部设有用于通入载气的载气入口8、在内筒3后端的上部设有载气出口9;热量载体在内筒3外夹套中的流通路径与内筒3中的土壤运动方向相反,载气在内筒3中的流通路径与内筒3中的土壤运动方向相同。The upper part of the outer cylinder 2 rear end is provided with the first multi-heat source inlet 6 for passing into the heat carrier, and the first
在内筒3的中心线上设有空心转动轴5,是由外轴套和中空内轴套构成夹套式结构的中空有轴式回转轴;在空心转动轴5的一端设有第二多热源出口15和用于通入热量载体的第二多热源入口14;第二多热源出口15和第二多热源入口14分别与外轴套或内轴套相接,其安装方式的选择使得热量载体在外轴套中的流向与内筒中的土壤运动方向相反。A hollow rotating
第一多热源入口6和第二多热源入口14分别接至燃油高温烟气出口、余热锅炉废气出口或电厂锅炉废气出口。The first multi-heat source inlet 6 and the second
本实用新型中,利用前述装置实现有机物污染土壤修复的方法,包括以下步骤:In the present utility model, utilize aforementioned device to realize the method for remediation of organic matter polluted soil, comprise the following steps:
有机物污染土壤从土壤进料口1以固定速率进入内筒3;Organic matter polluted soil enters the inner cylinder 3 at a fixed rate from the soil feed port 1;
自多热源入口6引入300~1300℃的高温烟气、余热锅炉废气或电厂锅炉废气至内筒3和外筒2之间的夹套中,热量载体在夹套中的流通路径与内筒3中的土壤运动方向相反;从载气入口8引入惰性气体进入内筒3,载气在内筒3中的流通路径与内筒3中的土壤运动方向相同;自第二多热源入口14引入300~1300℃的高温烟气、余热锅炉废气或电厂锅炉废气至空心转动轴5中,热量载体在外轴套中的流向与内筒中的土壤运动方向相反;Introduce high-temperature flue gas at 300-1300°C, waste heat boiler exhaust gas or power plant boiler exhaust gas from the multi-heat source inlet 6 into the jacket between the inner cylinder 3 and the outer cylinder 2, the flow path of the heat carrier in the jacket and the inner cylinder 3 The soil movement direction in the inner cylinder is opposite; the inert gas is introduced into the inner cylinder 3 from the carrier gas inlet 8, and the flow path of the carrier gas in the inner cylinder 3 is the same as the soil movement direction in the inner cylinder 3; the second
土壤在内筒3中被加热至220~600℃,所含有机污染物被脱附出来并由惰性气体携带;经热脱附处理后,99.9%以上的有机污染物被脱附出来,清洁的土壤由出土器10排出,并经增湿器12喷水增湿后由输送器11排放;The soil is heated to 220-600°C in the inner cylinder 3, and the organic pollutants are desorbed and carried by the inert gas; after thermal desorption treatment, more than 99.9% of the organic pollutants are desorbed, and the clean The soil is discharged by the
热量载体离开多热源有轴间热式热脱附装置后,进入余热利用装置回收余热或直接排放;携带着有机污染物的惰性气体进入尾气处理设施进行处理;After the heat carrier leaves the multi-heat source interaxial thermal desorption device, it enters the waste heat utilization device to recover waste heat or discharge it directly; the inert gas carrying organic pollutants enters the tail gas treatment facility for treatment;
所述第一多热源、第二多热源分别是300~1300℃的高温烟气、余热锅炉废气或电厂锅炉废气中的任意一种;第一多热源和第二多热源消耗量的总和与土壤处理量之间的关系用下述公式表示:The first multi-heat source and the second multi-heat source are respectively any one of high-temperature flue gas at 300-1300°C, waste heat boiler exhaust gas or power plant boiler exhaust gas; the sum of the consumption of the first multi-heat source and the second multi-heat source and the soil The relationship between the processing volumes is expressed by the following formula:
其中,M多热源为第一多热源和第二多热源的每小时消耗量,M土为每小时多热源无轴间热式热脱附装置处理土壤量,C土为土壤比热容,ΔT土为土壤在间热式热脱附装置内升高的温度值,Q多热源为每千克多热源的热值,η热为多热源向土壤的综合传热效率。Among them, M multi-heat source is the hourly consumption of the first multi-heat source and the second multi-heat source, M soil is the amount of soil processed by the multi-heat source non-axial interthermal thermal desorption device per hour, C soil is the specific heat capacity of soil, and ΔT soil is The temperature value of soil rising in the reciprocal thermal desorption device, Q multi-heat source is the calorific value of multi-heat source per kilogram, and η heat is the comprehensive heat transfer efficiency of multi-heat source to soil.
经以上过程后,土壤中有机污染物均得到有效控制,达到良好的土壤修复效果。After the above process, the organic pollutants in the soil are effectively controlled, and a good soil restoration effect is achieved.
最后,还需注意的是,以上列举的仅是本实用新型的一个具体实施例。显然,本明不限于以上实施例,还可以有很多变形。本领域的普通技术人员能从本实用新型公开的内容直接导出或联想出的所有变形,均应认为是本实用新型的保护范围。Finally, it should also be noted that what is listed above is only a specific embodiment of the present invention. Obviously, the present invention is not limited to the above embodiments, and many modifications are possible. All deformations that a person skilled in the art can directly derive or associate from the content disclosed in the utility model shall be considered as the protection scope of the utility model.
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103506378A (en) * | 2013-09-25 | 2014-01-15 | 浙江大学 | Multi-heat source and shaft intervallic heating type thermal desorption device for organic pollutant contaminated soil repair |
| CN104353663A (en) * | 2014-09-30 | 2015-02-18 | 杭州大地环保工程有限公司 | Soil thermal desorption treatment system with discharge dust removal function |
| WO2016173448A1 (en) * | 2015-04-27 | 2016-11-03 | 沈逍江 | Two-section auger indirect thermal desorption device |
| CN108585406A (en) * | 2018-05-22 | 2018-09-28 | 德州隆科石油装备有限公司 | A kind of sludge treatment method and device |
| CN116538512A (en) * | 2023-05-06 | 2023-08-04 | 浙江浙能电力股份有限公司台州发电厂 | System and method for blending and burning oil sludge for coal-fired boiler |
-
2013
- 2013-09-25 CN CN201320599444.2U patent/CN203484406U/en not_active Expired - Lifetime
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103506378A (en) * | 2013-09-25 | 2014-01-15 | 浙江大学 | Multi-heat source and shaft intervallic heating type thermal desorption device for organic pollutant contaminated soil repair |
| CN103506378B (en) * | 2013-09-25 | 2016-01-13 | 浙江大学 | Multi-heat source interaxial thermal thermal desorption device for remediation of organic matter-contaminated soil |
| CN104353663A (en) * | 2014-09-30 | 2015-02-18 | 杭州大地环保工程有限公司 | Soil thermal desorption treatment system with discharge dust removal function |
| WO2016173448A1 (en) * | 2015-04-27 | 2016-11-03 | 沈逍江 | Two-section auger indirect thermal desorption device |
| CN108585406A (en) * | 2018-05-22 | 2018-09-28 | 德州隆科石油装备有限公司 | A kind of sludge treatment method and device |
| CN116538512A (en) * | 2023-05-06 | 2023-08-04 | 浙江浙能电力股份有限公司台州发电厂 | System and method for blending and burning oil sludge for coal-fired boiler |
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