CN203270053U - Melting pool for aluminium electrolysis cell - Google Patents
Melting pool for aluminium electrolysis cell Download PDFInfo
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- CN203270053U CN203270053U CN201320222788.1U CN201320222788U CN203270053U CN 203270053 U CN203270053 U CN 203270053U CN 201320222788 U CN201320222788 U CN 201320222788U CN 203270053 U CN203270053 U CN 203270053U
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- aluminum
- electrolytic cell
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- lining
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- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 70
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 70
- 238000002844 melting Methods 0.000 title claims abstract description 11
- 230000008018 melting Effects 0.000 title claims abstract description 11
- 238000005868 electrolysis reaction Methods 0.000 title description 2
- 239000004411 aluminium Substances 0.000 title 1
- 239000000463 material Substances 0.000 claims description 6
- 239000012774 insulation material Substances 0.000 claims description 3
- 238000005260 corrosion Methods 0.000 claims description 2
- 230000007797 corrosion Effects 0.000 claims description 2
- 239000011819 refractory material Substances 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 18
- 229910052799 carbon Inorganic materials 0.000 abstract description 18
- 239000007788 liquid Substances 0.000 abstract description 14
- 238000006056 electrooxidation reaction Methods 0.000 abstract description 2
- 239000003792 electrolyte Substances 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 229910001610 cryolite Inorganic materials 0.000 description 3
- 238000003487 electrochemical reaction Methods 0.000 description 3
- 229910001338 liquidmetal Inorganic materials 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000005672 electromagnetic field Effects 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
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- Electrolytic Production Of Metals (AREA)
Abstract
本实用新型公开了一种铝电解槽熔池,克服了现有技术中垂直进出电铝电解槽内衬含有阴极炭块,炭块周围容易发生裂缝和炭块上表面容易导致铝液的波动增加电耗的问题。该铝电解槽熔池含有电解槽壳体和内衬,电解槽壳体内表面贴合内衬的外表面,所述内衬的底部至少设有1个储铝凹槽或排铝凸起。储铝凹槽为凹柱面、凹球面、凹旋转抛物面、凹椭球面、凹平面或倒人字形凹斜面。排铝凸起为凸柱面、凸球面、凸旋转抛物面、凸椭球面、凸平面或人字形凸斜面。该电解槽内衬不含阴极炭块,不产生电化学腐蚀,能够避免存在导电孔导致的漏液,内衬不容易发生裂缝,能够避免漏炉现象的发生。
The utility model discloses a melting pool of an aluminum electrolytic cell, which overcomes the problems in the prior art that the inner liner of the electric aluminum electrolytic cell vertically enters and exits contains a cathode carbon block, cracks easily occur around the carbon block and the upper surface of the carbon block easily causes the fluctuation of the aluminum liquid to increase. The problem of power consumption. The molten pool of the aluminum electrolytic cell includes an electrolytic cell shell and an inner liner, the inner surface of the electrolytic cell shell is attached to the outer surface of the inner liner, and at least one aluminum storage groove or aluminum row protrusion is provided on the bottom of the inner liner. The aluminum storage groove is a concave cylindrical surface, a concave spherical surface, a concave rotating paraboloid, a concave ellipsoid, a concave plane or an inverted herringbone concave slope. The aluminum row protrusions are convex cylinders, convex spheres, convex paraboloids of revolution, convex ellipsoids, convex planes or herringbone convex slopes. The lining of the electrolytic cell does not contain cathode carbon blocks, does not produce electrochemical corrosion, and can avoid liquid leakage caused by the existence of conductive holes. The lining is not prone to cracks, and the occurrence of furnace leakage can be avoided.
Description
技术领域 technical field
该实用新型涉及一种铝电解电解槽内衬结构技术,特别是涉及一种铝电解槽熔池。 The utility model relates to a lining structure technology of an aluminum electrolytic cell, in particular to a melting pool of an aluminum electrolytic cell.
背景技术 Background technique
现代铝工业的主要产生设备为铝电解槽,基本生产过程是将直流电通过槽侧的立柱母线、阳极母线进入炭素阳极,在炭素阳极与冰晶石电解质熔体的界面发生电化学反应,将溶解在冰晶石电解质熔体中的氧化铝电解成为液态金属铝,沉积到电解槽底部,炭素阳极不断消耗并在阳极上释放出二氧化碳气体。直流电在流经液态金属铝、再流经其下方的炭素阴极,从电解槽的长边两侧沿等同数量的阴极钢棒流出电解槽。铝电解槽在生产过程中,槽中存在着高达高于1000℃的熔融电解质和900℃以上的铝液。电解生产过程中,电解槽熔池底部要流过数十万安培的强大电流,底部阴极炭块在电化学反应的作用下,会出现裂缝,电解质或铝水会从阴极炭块的裂缝中渗入,破坏内衬结构,最终形成电解槽漏炉。 The main production equipment in the modern aluminum industry is aluminum electrolytic cell. The basic production process is to pass direct current into the carbon anode through the column busbar and anode busbar on the side of the cell, and an electrochemical reaction occurs at the interface between the carbon anode and the cryolite electrolyte melt. The alumina in the cryolite electrolyte melt is electrolyzed into liquid metal aluminum, which is deposited at the bottom of the electrolytic cell, and the carbon anode is continuously consumed and carbon dioxide gas is released on the anode. The direct current flows through the liquid metal aluminum, then flows through the carbon cathode below it, and flows out of the electrolytic cell along the same number of cathode steel rods on both sides of the long side of the electrolytic cell. During the production process of the aluminum electrolytic cell, there are molten electrolyte above 1000°C and molten aluminum above 900°C in the cell. During the electrolytic production process, a powerful current of hundreds of thousands of amperes flows through the bottom of the molten pool of the electrolytic tank. Under the action of the electrochemical reaction, the cathode carbon block at the bottom will have cracks, and electrolyte or aluminum water will infiltrate through the cracks of the cathode carbon block. , Destroy the lining structure, and finally form the electrolytic cell leakage furnace.
经改进后,电解过程采用水平进出电方式,电解槽内衬不含阴极炭块,能够避免存在导电孔导致的漏液,内衬不容易发生裂缝,能够避免漏炉现象的发生。同时能够消除因存在阴极炭块,炭块上表面的水平构造导致阴极内衬上部的铝液在数十万安培的强大电流产生的强电磁场作用下,产生铝液磁旋流,造成铝液的波动,从而造成电解质极距的设定增高,电压设定加大导致电解铝的工艺电耗增加。当内衬底部设有储铝凹槽或排铝凸起时,生成的铝液能及时聚集在内衬的低处被抽走,能够防止过多的铝液聚集,避免铝液波动。 After the improvement, the electrolysis process adopts the horizontal power-in and out-flow method, and the lining of the electrolytic cell does not contain cathode carbon blocks, which can avoid liquid leakage caused by the existence of conductive holes, and the lining is not prone to cracks, which can avoid the occurrence of furnace leakage. At the same time, it can eliminate the existence of the cathode carbon block and the horizontal structure of the upper surface of the carbon block, which causes the aluminum liquid on the upper part of the cathode lining to generate a magnetic swirl flow of the aluminum liquid under the action of a strong electromagnetic field generated by a strong current of hundreds of thousands of amperes, causing the aluminum liquid to vortex. Fluctuations, resulting in an increase in the setting of the electrolyte pole distance, and an increase in the voltage setting leads to an increase in the power consumption of the electrolytic aluminum process. When the bottom of the inner liner is provided with aluminum storage grooves or aluminum discharge protrusions, the generated aluminum liquid can be collected in the lower part of the inner liner in time to be pumped away, which can prevent excessive aluminum liquid from accumulating and avoiding fluctuations of aluminum liquid.
实用新型内容 Utility model content
本实用新型克服了现有技术中垂直进出电铝电解槽内衬含有阴极炭块,炭块周围容易发生裂缝和炭块上表面容易导致铝液的波动增加电耗的问题,提供了一种经久耐用,内衬底部不开孔的电铝电解槽熔池。 The utility model overcomes the problems in the prior art that the inner lining of the vertically entering and exiting electric aluminum electrolytic cell contains cathode carbon blocks, cracks are likely to occur around the carbon blocks and the upper surface of the carbon blocks is likely to cause fluctuations in aluminum liquid and increase power consumption, and provides a durable Durable electric aluminum bath with no holes at the bottom of the inner substrate.
本实用新型的技术解决方案是,提供一种具有以下结构的铝电解槽熔池:含有电解槽壳体和内衬,电解槽壳体内表面贴合内衬的外表面,所述内衬的底部至少设有1个储铝凹槽或排铝凸起。储铝凹槽为凹柱面、凹球面、凹旋转抛物面、凹椭球面、凹平面或倒人字形凹斜面。凹柱面和倒人字形凹斜面为纵向、横向或斜向排列,所述的纵向与熔池的长边平行。排铝凸起为凸柱面、凸球面、凸旋转抛物面、凸椭球面、凸平面或人字形凸斜面。凸柱面和人字形凸斜面为纵向、横向或斜向排列,所述的纵向与熔池的长边平行。内衬含有保温材料、耐火材料、抗渗材料和耐腐蚀材料。 The technical solution of the utility model is to provide an aluminum electrolytic cell melting pool with the following structure: it contains the electrolytic cell shell and the inner lining, the inner surface of the electrolytic cell shell is attached to the outer surface of the inner lining, and the bottom of the inner lining is At least one aluminum storage groove or aluminum row protrusion is provided. The aluminum storage groove is a concave cylindrical surface, a concave spherical surface, a concave rotating paraboloid, a concave ellipsoid, a concave plane or an inverted herringbone concave slope. The concave cylindrical surface and the inverted herringbone concave inclined surface are arranged vertically, horizontally or obliquely, and the longitudinal direction is parallel to the long side of the molten pool. The aluminum row protrusions are convex cylinders, convex spheres, convex paraboloids of revolution, convex ellipsoids, convex planes or herringbone convex slopes. The convex cylindrical surface and the herringbone convex inclined surface are arranged longitudinally, transversely or obliquely, and the longitudinal direction is parallel to the long side of the molten pool. The lining contains insulation materials, refractory materials, impermeable materials and corrosion-resistant materials.
与现有技术相比,本实用新型铝电解槽熔池具有以下优点:经改进后,电解槽内衬不含阴极炭块,不产生电化学腐蚀,能够避免存在导电孔导致的漏液,内衬不容易发生裂缝,能够避免漏炉现象的发生。同时能够消除阴极炭块上表面的水平构造导致阴极内衬上部的铝液在磁场作用下,产生铝液磁旋流形成铝液波动,从而大幅度提高电流效率,增加原铝产量。节省电能的同时还可以大量简化铝电解槽的母线配置,节省大量铝材。本实用新型结构简单,节省材料,使用寿命长,具有良好的社会和经济效益。 Compared with the prior art, the molten pool of the aluminum electrolytic cell of the utility model has the following advantages: after improvement, the lining of the electrolytic cell does not contain cathode carbon blocks, does not produce electrochemical corrosion, and can avoid liquid leakage caused by the existence of conductive holes. The lining is not prone to cracks, which can avoid the occurrence of furnace leakage. At the same time, it can eliminate the horizontal structure of the upper surface of the cathode carbon block, which causes the aluminum liquid on the upper part of the cathode lining to generate a magnetic swirl flow of the aluminum liquid under the action of a magnetic field, thereby greatly improving the current efficiency and increasing the output of primary aluminum. While saving electric energy, it can greatly simplify the busbar configuration of the aluminum electrolytic cell and save a lot of aluminum materials. The utility model has the advantages of simple structure, material saving, long service life and good social and economic benefits.
附图说明 Description of drawings
图1是本实用新型铝电解槽熔池实施例一的俯视图; Fig. 1 is the plan view of Embodiment 1 of molten pool of aluminum electrolytic cell of the present invention;
图2是本实用新型铝电解槽熔池实施例一俯视图中A-Aˊ的剖面图; Fig. 2 is the sectional view of A-A' in the top view of the utility model aluminum electrolytic tank molten pool embodiment one;
图3是本实用新型铝电解槽熔池实施例一俯视图中B-Bˊ的剖面图; Fig. 3 is a cross-sectional view of B-B' in the top view of the first embodiment of the aluminum electrolytic cell molten pool of the present invention;
图4是本实用新型铝电解槽熔池实施例二的俯视图; Fig. 4 is the plan view of Embodiment 2 of the melting pool of the aluminum electrolytic cell of the present invention;
图5是本实用新型铝电解槽熔池实施例二俯视图中A-Aˊ的剖面图; Fig. 5 is a sectional view of A-A' in the plan view of Embodiment 2 of the molten pool of the aluminum electrolytic cell of the present invention;
图6是本实用新型铝电解槽熔池实施例二俯视图中B-Bˊ的剖面图; Fig. 6 is a cross-sectional view of B-B' in the top view of Embodiment 2 of the molten pool of the aluminum electrolytic cell of the present invention;
图7是本实用新型铝电解槽熔池实施例三的俯视图; Fig. 7 is a top view of Embodiment 3 of the melting pool of the aluminum electrolytic cell of the present invention;
图8是本实用新型铝电解槽熔池实施例三俯视图中A-Aˊ的剖面图; Fig. 8 is a cross-sectional view of A-A' in the top view of the third embodiment of the molten pool of the aluminum electrolytic cell of the present invention;
图9是本实用新型铝电解槽熔池实施例三俯视图中B-Bˊ的剖面图; Fig. 9 is a cross-sectional view of B-B' in the top view of Embodiment 3 of the molten pool of the aluminum electrolytic cell of the present invention;
图10是本实用新型铝电解槽熔池实施例四的俯视图; Fig. 10 is a top view of Embodiment 4 of the molten pool of the aluminum electrolytic cell of the present invention;
图11是本实用新型铝电解槽熔池实施例四俯视图中A-Aˊ的剖面图; Fig. 11 is a cross-sectional view of A-A' in the top view of Embodiment 4 of the molten pool of the aluminum electrolytic cell of the present invention;
图12是本实用新型铝电解槽熔池实施例四俯视图中B-Bˊ的剖面图。 Fig. 12 is a cross-sectional view of B-B' in the top view of Embodiment 4 of the molten pool of the aluminum electrolytic cell of the present invention.
具体实施方式 Detailed ways
附图说明中标号1是电解槽壳体,2是保温材料,3是内衬,4是储铝凹槽,5是排铝凸起。 In the description of the drawings, the number 1 is the shell of the electrolytic cell, the number 2 is the insulation material, the number 3 is the lining, the number 4 is the aluminum storage groove, and the number 5 is the aluminum row protrusion.
下面结合附图和具体实施方式对本实用新型铝电解槽熔池作进一步说明:如图所示,当采用水平进出电的方式后,直流电通过碳素电极后,电解质熔体的界面发生电化学反应,将溶解在冰晶石电解质熔体中的氧化铝电解成为液态金属铝,沉积到电解槽底部,在底部设有的储铝凹槽或排铝凸起,能够将铝液方便地汇集到内衬的较低处,最后由真空抬包快速吸出。 The molten pool of the aluminum electrolytic cell of the utility model will be further described below in conjunction with the accompanying drawings and specific embodiments: As shown in the figure, when the electricity is fed in and out horizontally, after the direct current passes through the carbon electrodes, an electrochemical reaction occurs at the interface of the electrolyte melt , the aluminum oxide dissolved in the cryolite electrolyte melt is electrolyzed into liquid metal aluminum, which is deposited to the bottom of the electrolytic cell, and the aluminum storage groove or aluminum row protrusion is provided at the bottom, which can conveniently collect the aluminum liquid to the inner lining The lower part is finally sucked out quickly by the vacuum ladle. the
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104451774A (en) * | 2014-12-29 | 2015-03-25 | 云南铝业股份有限公司 | Zero allowance cell shutting polymorph high roasting method |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104451774A (en) * | 2014-12-29 | 2015-03-25 | 云南铝业股份有限公司 | Zero allowance cell shutting polymorph high roasting method |
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Address after: 450000 Henan Province, Zhengzhou high tech District, long road, No. Y03, building 1, unit 1, building 11 Patentee after: ZHENGZHOU LIGHT METAL TECHNOLOGY CO.,LTD. Address before: 450002, Fortune Plaza 32, three road, Jinshui District, Henan, Zhengzhou, 1304 Patentee before: Zhengzhou Light Metal Technology Co.,Ltd. |
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Granted publication date: 20131106 |