CN203173971U - Glass plate manufacturing device - Google Patents
Glass plate manufacturing device Download PDFInfo
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- CN203173971U CN203173971U CN2011900005560U CN201190000556U CN203173971U CN 203173971 U CN203173971 U CN 203173971U CN 2011900005560 U CN2011900005560 U CN 2011900005560U CN 201190000556 U CN201190000556 U CN 201190000556U CN 203173971 U CN203173971 U CN 203173971U
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B17/00—Forming molten glass by flowing-out, pushing-out, extruding or drawing downwardly or laterally from forming slits or by overflowing over lips
- C03B17/06—Forming glass sheets
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B17/00—Forming molten glass by flowing-out, pushing-out, extruding or drawing downwardly or laterally from forming slits or by overflowing over lips
- C03B17/06—Forming glass sheets
- C03B17/067—Forming glass sheets combined with thermal conditioning of the sheets
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B18/00—Shaping glass in contact with the surface of a liquid
- C03B18/02—Forming sheets
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B18/00—Shaping glass in contact with the surface of a liquid
- C03B18/02—Forming sheets
- C03B18/18—Controlling or regulating the temperature of the float bath; Composition or purification of the float bath
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/50—Glass production, e.g. reusing waste heat during processing or shaping
- Y02P40/57—Improving the yield, e-g- reduction of reject rates
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- Re-Forming, After-Treatment, Cutting And Transporting Of Glass Products (AREA)
Abstract
Description
技术领域 technical field
本实用新型涉及一种玻璃板制造装置。 The utility model relates to a glass plate manufacturing device. the
背景技术 Background technique
先前,作为玻璃板的制造方法之一而采用有熔融法。熔融法是使流入成形体中的熔融玻璃自成形体溢流而制造玻璃板。自成形体溢流的熔融玻璃于沿成形体流下之后,在成形体的下端部合流,其后自成形体脱离而成为玻璃板。玻璃板藉由炉内的环境而冷却,自黏性区域经过黏弹性区域向弹性区域变化。此处,为了防止应于玻璃的黏弹性区域均匀地冷却的玻璃板的范围因在炉内产生的对流而被不均匀地冷却的情形,例如专利文献1(日本特开平2-225326号公报)所示,提出有于玻璃板的两侧设置板状构件的技术。 Conventionally, a fusion method has been used as one of the methods of manufacturing a glass plate. In the melting method, molten glass flowing into a molded body is overflowed from the molded body to produce a glass plate. The molten glass overflowing from the forming body flows down along the forming body, joins at the lower end of the forming body, and then detaches from the forming body to become a glass plate. The glass sheet is cooled by the environment in the furnace, changing from the viscous region through the viscoelastic region to the elastic region. Here, in order to prevent the range of the glass plate that should be cooled uniformly in the viscoelastic region of the glass from being unevenly cooled by convection generated in the furnace, for example, Patent Document 1 (Japanese Patent Application Laid-Open No. 2-225326 ) As shown, a technique of providing plate-shaped members on both sides of a glass plate has been proposed. the
实用新型内容 Utility model content
[实用新型所要解决的问题] [The problem to be solved by the utility model]
伴随近年来的玻璃基板的需求增加,需要提高玻璃板的生产量。然而,于采用先前的技术的情形时,难以充分控制玻璃板的冷却速度,故无法充分期待生产量的提高。 With the increase in demand for glass substrates in recent years, it is necessary to increase the throughput of glass plates. However, in the case of employing the conventional technique, it is difficult to sufficiently control the cooling rate of the glass sheet, and thus a sufficient improvement in throughput cannot be expected. the
因此,本实用新型的课题在于提供一种能够调整玻璃板的冷却速度的玻璃板制造装置。 Therefore, an object of this invention is to provide the glass plate manufacturing apparatus which can adjust the cooling rate of a glass plate. the
[解决问题的技术手段] [Technical means to solve the problem]
本实用新型的玻璃板制造装置是于使自成形体溢流的熔融玻璃沿成形体的两侧面流下后,在成形体的下端部附近合流而制造玻璃板者,其具备多个冷却调整板、及温度控制单元。多个冷却调整板于较熔融玻璃的合流点更靠下方处沿熔融玻璃的流动方向并列配置,对玻璃板的冷却速度进行调整。温度控制单元与各冷却调整板对应而设置,对各冷却调整板的温度进行控制。 The glass plate manufacturing device of the present invention is to make the molten glass overflowing from the forming body flow down along the both sides of the forming body, and then merge near the lower end of the forming body to manufacture glass plates. It is equipped with a plurality of cooling adjustment plates, and temperature control unit. A plurality of cooling adjustment plates are arranged in parallel along the flow direction of the molten glass below the confluence point of the molten glass, and adjust the cooling rate of the glass plate. The temperature control unit is provided corresponding to each cooling adjustment plate, and controls the temperature of each cooling adjustment plate. the
于熔融玻璃的流动方向上并列的冷却调整板藉由与各冷却调整板对应的温度控 制单元而分别受到温度控制。冷却调整板以藉由温度控制单元而保持宽度方向的温度均匀性的方式受到控制,从而对玻璃板的冷却速度进行调整。 The cooling adjustment plates arranged side by side in the flow direction of the molten glass are respectively temperature-controlled by the temperature control unit corresponding to each cooling adjustment plate. The cooling adjustment plate is controlled by the temperature control unit so as to maintain temperature uniformity in the width direction, thereby adjusting the cooling rate of the glass plate. the
藉此,能够有效地进行玻璃板的温度控制。 Thereby, temperature control of a glass plate can be performed efficiently. the
又,较佳为,多个冷却调整板配置于上下环境分隔构件的下方。上下环境分隔构件配置于熔融玻璃的合流点的附近并分隔合流点的上侧环境及下侧环境。 Also, preferably, a plurality of cooling adjustment plates are arranged below the upper and lower environment partition members. The upper and lower environment partition members are arranged near the confluence point of molten glass, and separate the upper side environment and the lower side environment of the confluence point. the
于藉由上下环境分隔构件而阻断成形体的热的空间内,冷却调整板对熔融玻璃的冷却速度进行控制,故温度控制单元对冷却的影响难以波及至成形体。又,不使沿成形体上流动的熔融玻璃的最佳玻璃黏度发生变化即能够高效地进行黏弹性区域内的玻璃板的温度控制。 In the space where the heat of the molded body is blocked by the upper and lower environmental partition members, the cooling adjustment plate controls the cooling rate of the molten glass, so the influence of the temperature control unit on cooling is difficult to affect the molded body. In addition, temperature control of the glass sheet in the viscoelastic region can be efficiently performed without changing the optimum glass viscosity of the molten glass flowing along the molded body. the
进而,较佳为,各冷却调整板在与熔融玻璃的流动方向交叉的水平方向上延伸,温度控制单元包含管。管中流通对各冷却调整板的整体进行冷却或加热的流体。 Furthermore, it is preferable that each cooling adjustment plate extends in the horizontal direction intersecting with the flow direction of molten glass, and it is preferable that a temperature control means contains a pipe. A fluid that cools or heats the entirety of each cooling adjustment plate flows through the tubes. the
能够藉由于管内流动的流体,自玻璃板对向面的背面侧对与玻璃板对向的各冷却调整板的整体进行冷却或加热。 The entirety of the cooling adjustment plates facing the glass plate can be cooled or heated from the back side of the glass plate facing surface by the fluid flowing in the tube. the
进而,较佳为,管包含主管及副管。主管沿冷却调整板的长度方向而配置。副管分别连结于主管的两侧部。副管向主管传送作为热交换介质的气体。又,较佳为,主管具有多个吹出口。多个吹出口将自副管传送的气体向主管外吹出而吹送至冷却调整板。 Furthermore, preferably, the pipe includes a supervisor and a sub pipe. The main pipe is arranged along the length direction of the cooling adjustment plate. The auxiliary pipes are respectively connected to both sides of the main pipe. The secondary pipe conveys gas as a heat exchange medium to the main pipe. Also, preferably, the main pipe has a plurality of outlets. The plurality of outlets blow the gas sent from the sub-pipe to the outside of the main pipe and blow it to the cooling adjustment plate. the
藉由相对于冷却调整板而自多个吹出口吹送气体,能够有效地进行冷却调整板的温度控制。 The temperature control of the cooling adjustment plate can be efficiently performed by blowing gas from a plurality of outlets with respect to the cooling adjustment plate. the
进而,较佳为,多个吹出口根据距主管的侧部的距离而分别具有既定的大小,以使自各吹出口吹出的气体量变得均匀。 Furthermore, it is preferable that the plurality of outlets each have a predetermined size in accordance with the distance from the side portion of the main pipe so that the amount of gas blown out from each outlet becomes uniform. the
藉由对朝向冷却调整板吹出气体的吹出口的大小及位置进行调节,即便以某种程度变更向管供给的气体的压力,亦能够使于第1方向上延伸的冷却调整板整体的宽度方向上的冷却量大致保持为固定。藉由冷却调整板整体的宽度方向上的冷却量大致保持为固定,能够制造保有较高的平面度的较佳的玻璃板。 By adjusting the size and position of the outlet for blowing gas toward the cooling adjustment plate, even if the pressure of the gas supplied to the tube is changed to some extent, the width direction of the entire cooling adjustment plate extending in the first direction can be adjusted The amount of cooling on the board remains roughly constant. By keeping the amount of cooling in the width direction of the entire cooling adjustment plate substantially constant, it is possible to manufacture a preferable glass plate with high flatness. the
又,较佳为,冷却调整板为槽钢,槽钢的主部与玻璃板对向。藉此,能够提高冷却调整板的强度。 Also, preferably, the cooling adjustment plate is a channel steel, and the main part of the channel steel faces the glass plate. Thereby, the intensity|strength of a cooling adjustment plate can be improved. the
进而,较佳为,玻璃板的制造装置还具备第1包围构件、第2包围构件、及隔热构件。第1包围构件包围第1管而形成第1空间。所谓第1管是指流通对第1冷却调 整板进行冷却或加热的流体的管,所谓第1空间是指用以调整第1冷却调整板的冷却速度的空间。第2包围构件包围第2管而形成第2空间。所谓第2管是指流通对邻接于第1冷却调整板的第2冷却调整板进行冷却或加热的流体的管。所谓第2空间是指用以调整第2冷却调整板的冷却速度的空间。隔热构件配置于第1空间与第2空间之间,阻断第1空间与第2空间之间的热的移动。 Furthermore, it is preferable that the manufacturing apparatus of a glass plate further includes a 1st surrounding member, a 2nd surrounding member, and a heat insulating member. The first surrounding member surrounds the first pipe to form a first space. The so-called first pipe refers to a pipe through which a fluid that cools or heats the first cooling adjustment plate flows, and the so-called first space refers to a space for adjusting the cooling rate of the first cooling adjustment plate. The second surrounding member surrounds the second pipe to form a second space. The second pipe refers to a pipe through which a fluid that cools or heats the second cooling adjustment plate adjacent to the first cooling adjustment plate flows. The second space refers to a space for adjusting the cooling rate of the second cooling adjustment plate. The heat insulating member is arranged between the first space and the second space, and blocks the transfer of heat between the first space and the second space. the
由于藉由隔热构件阻断第1空间与第2空间的热的移动,故于第1冷却调整板的温度控制时,能够减少对第2冷却调整板的温度的影响。 Since the heat transfer between the first space and the second space is blocked by the heat insulating member, it is possible to reduce the influence on the temperature of the second cooling adjustment plate when controlling the temperature of the first cooling adjustment plate. the
又,较佳为,玻璃板的制造装置还具备气体控制单元。气体控制单元对吹送至冷却调整板的气体的流动进行控制。藉此,能够减少自一吹出口向冷却调整板吹送的气体对自另一吹出口吹出的气体造成的影响。 Moreover, it is preferable that the manufacturing apparatus of a glass plate is further equipped with the gas control means. The gas control unit controls the flow of gas blown to the cooling adjustment plate. Thereby, the influence of the gas blown from one outlet to the cooling adjustment plate on the gas blown from the other outlet can be reduced. the
[实用新型的效果] [Effect of utility model]
以本实用新型的玻璃板制造装置,能够有效地进行玻璃板的温度控制。 With the glass plate manufacturing device of the present invention, the temperature control of the glass plate can be effectively performed. the
附图说明 Description of drawings
图1为玻璃板制造装置的概略构成图; Fig. 1 is a schematic configuration diagram of a glass plate manufacturing device;
图2为成形装置的概略构成图(剖面图); Figure 2 is a schematic composition diagram (sectional view) of the forming device;
图3为成形装置的概略构成图(侧视图); Figure 3 is a schematic composition diagram (side view) of the forming device;
图4为表示冷却调整板的图; Figure 4 is a diagram representing a cooling adjustment plate;
图5为表示藉由冷却调整板与包围构件形成的空间的图; Figure 5 is a diagram showing the space formed by the cooling adjustment plate and the surrounding member;
图6为表示自主管吹出的气体、及吹出后的气体的流动的图; Figure 6 is a diagram representing the flow of gas blown out from the main pipe and the flow of the blown gas;
图7为表示管的构成的图; Figure 7 is a diagram representing the composition of the tube;
图8为表示控制装置及连接于控制装置的各机构的图。 Fig. 8 is a diagram showing a control device and various mechanisms connected to the control device. the
具体实施方式 Detailed ways
(1)整体构成 (1) Overall composition
于图1中,表示本实用新型的第1实施例的玻璃板制造装置100的概略构成图。玻璃板制造装置100是采用熔融法制造玻璃板91的装置。藉由玻璃板制造装置100制造的玻璃板91使用于液晶显示器或电浆显示器等平板显示器的玻璃基板。又,于本实施例中,玻璃板制造装置100制造使用于G5尺寸的玻璃基板的玻璃板91。玻璃 板制造装置100连续地制造带状的玻璃板91。
In FIG. 1, the schematic structural diagram of the glass
玻璃板制造装置100主要包含熔解槽200、清澄槽300、及成形装置101。于熔解槽200中,玻璃的原料被熔解而生成熔融玻璃。其后,熔融玻璃传送至清澄槽300内。于清澄槽300内,进行熔融玻璃中的气泡的去除。其后,熔融玻璃传送至成形装置101。
The glass
于图2及图3中,表示成形装置101的概略构成。图2是成形装置101的剖面图。图3是成形装置101的侧视图。如图2、图3及图6所示,成形装置101主要由成形体10、上下环境分隔构件20、20、多个冷却辊30、冷却调整单元40a~40f、包围构件70a、70b、70c、多个隔热构件71、多个下拉辊60、及控制装置80构成。以下,详细地对成形装置101中所包含的各构成进行说明。
In FIG. 2 and FIG. 3, the schematic structure of the
(2)详细构成 (2) Detailed composition
(2-1)成形体 (2-1) Formed body
成形体10藉由使熔融玻璃90溢流而将熔融玻璃90成形为板状的玻璃(玻璃板91)。成形体10具有流入口12(参照图3)。经由熔解槽200及清澄槽300的熔融玻璃90自流入口12流入。如图2所示,成形体10具有剖面形状为大致5边形的形状。大致5边形的前端相当于成形体10的下端部。于成形体中,形成有槽11。槽11于成形体10的长度方向上延伸。具体而言,槽11自设置有流入口12的第1端部延伸至与第1端部对向的第2端部。槽11以如下方式形成:流入口12附近最深,且随着接近第2端部逐渐变浅。自成形体10溢流的熔融玻璃90沿成形体10的两侧面而流下,并于成形体10的下端部合流。
The molded
(2-2)上下环境分隔构件 (2-2) Upper and lower environment separation components
上下环境分隔构件20、20配置于熔融玻璃90的合流点附近。
The upper and lower
又,如图2所示,上下环境分隔构件20、20配置于玻璃板91的厚度方向两侧。上下环境分隔构件20、20是隔热材料。即,上下环境分隔构件20、20藉由分隔熔融玻璃90的合流点的上侧环境及下侧环境,而阻断热自上下环境分隔构件20、20的上侧向下侧移动。
Moreover, as shown in FIG. 2 , the upper and lower
(2-3)冷却辊 (2-3) cooling roll
多个冷却辊30与于成形体10的下端部合流而呈板状的熔融玻璃90(玻璃板91)接触,且为了对玻璃进行冷却而设置。
The plurality of cooling rolls 30 are provided to cool the glass in contact with the molten glass 90 (glass plate 91 ) that joins the lower end of the molded
(2-4)冷却调整单元 (2-4) Cooling adjustment unit
冷却调整单元40a~40f是对玻璃板91的冷却速度进行调整的单元。于本实施例中,设置有6个冷却调整单元40a~40f。如图2及图3所示,冷却调整单元40a~40f配置于上下环境分隔构件20、20的下方。又,冷却调整单元40a~40f沿玻璃板91的流下方向而并列配置。多个冷却调整单元40a~40f是无间隙地并列。各冷却调整单元40a~40f呈能够独立地受到控制的构成。于本实施例中,冷却调整单元40a~40f分别以沿玻璃板91的流下方向而能够阶段性地对玻璃板91进行冷却的方式受到控制。
The
于冷却调整单元40a中,包含冷却调整板41a、及对冷却调整板41a的温度进行控制的温度控制单元50a(参照图6)。相同地,于冷却调整单元40b中,包含冷却调整板41b、及对冷却调整板41b的温度进行控制的温度控制单元,于冷却调整单元40c中,包含冷却调整板41c、及对冷却调整板41c的温度进行控制的温度控制单元。对于其他冷却调整单元40d-40f亦相同。对于对冷却调整板41b、41c的温度进行控制的温度控制单元,仅图示有温度控制单元所包含的管51b、51c(参照图5)。再者,所有冷却调整单元40a~40f的构成均相同。因此,以下举冷却调整单元40a为例,对冷却调整单元40a所包含的冷却调整板41a、及温度控制单元50a进行说明。冷却调整单元40a于6个冷却调整单元40a~40f中,相对于玻璃板91的流下方向而配置于最上游。
The
(2-4-1)冷却调整板 (2-4-1) Cooling adjustment plate
冷却调整板41a是配置于玻璃板91的表面附近,且对玻璃板91的冷却速度进行调整的构件。冷却调整板41a在与熔融玻璃90(玻璃板91)的流动方向交叉的方向(即水平方向)上延伸。冷却调整板41a的长度方向的长度略短于玻璃板91的宽度方向的长度。于本实施例中,冷却调整板41a的长度方向的长度为1,500mm。
The cooling
冷却调整板41a是实施了弯折加工的金属构件。较佳为,金属构件是于大气中具有600℃以上的耐热性的构件。又,较佳为,金属构件具有至少30W/m?K以上的热传导率。如上所述,藉由使用热传导率较高的金属构件,冷却调整板41a的表面与背面的温度差变小,表面的热膨胀与背面的热膨胀的差受到抑制,从而冷却调整板41a的翘曲受到抑制。又,由于热传导率较高,因此于产生冷却调整板41a的各部分的温度差的情形时,该温度差亦迅速地得以缓和。进而,由于使用热传导率较高的金属构 件作为冷却调整板41a,故玻璃板91的冷却效率亦变高。对于金属构件的放射率特性,为了确保较高的热交换率,较佳为于使用温度区域内为0.85以上。于本实施例中,使用纯镍(热传导率:90.7W/m?K)作为金属构件。
The cooling
如图4所示,冷却调整板41a由弯折部42a、及主要部分43a构成。弯折部42a位于在水平方向上延伸的金属构件的上下方,且是金属构件的弯折部分。于水平方向上延伸的金属构件中的除弯折部42a外的部分为主要部分43a。主要部分43a具有与玻璃板91对向的平坦的面(对向面)。具体而言,冷却调整板41a为槽钢(槽形钢)。
As shown in FIG. 4, the cooling
此处,为了获得所需的冷却速度而能够适当变更主要部分43a的尺寸h。例如,根据玻璃的每单位宽度的流量而变更。又,较佳为,主要部分43a具有既定值以上的厚度t。具体而言,厚度t较佳为约4mm以上。自热容量的观点而言,厚度t更佳为6mm以上、进而较佳为8mm以上。于使用该程度的厚度t的槽钢的情形时,冷却调整板41a的热容量充分变大,从而温度差变小而玻璃板91的温度分布的均匀性更提高。又,弯折部42a的尺寸w为约20mm~约50mm。再者,冷却调整板41a与邻接的冷却调整板41b螺固(参照图5)。具体而言,冷却调整板41a的弯折部42a与冷却调整板41b的弯折部42b螺固而连结。因此,弯折部42a只要基本上具有能够螺固的程度的尺寸即可。然而,弯折部42a亦有助于增大冷却调整板41a的断面二次矩,故弯折部42a过短的情形不佳。
Here, the dimension h of the
(2-4-2)温度控制单元 (2-4-2) Temperature control unit
温度控制单元50a对冷却调整板41a的温度进行调整。具体而言,温度控制单元50a以沿玻璃板91的流下方向而阶段性地冷却玻璃板91的方式,对对应的冷却调整板41a的温度进行调整。
The
温度控制单元50a主要由管51a、热敏电阻56(参照图7)、及气体控制单元57a构成。
The
a)管 a) Tube
管51a流通用以对冷却调整板41a的整体进行冷却或加热的流体。此处,所谓于管内流通的流体是指气体(例如空气、或氮等惰性气体)。于管51a中,包含主管52a、及副管531a、532a。
The
如图6所示,主管52a沿冷却调整板41a的长度方向而配置。于主管52a上,均匀地形成有多个吹出口521。具体而言,多个吹出口521形成于相对于主管52a的中 心线C对称的位置上。又,如图5所示,吹出口521设置在与冷却调整板41a的主要部分43a对向的位置上。即,自吹出口521吹出的气体吹送至冷却调整板41a的主要部分43a。更具体而言,自吹出口521吹出的气体吹送至对向面的背面侧。吹出口521根据距主管52a的侧部的距离而分别具有既定的大小。即,吹出口521的大小亦相对于主管52a的中心线C对称。此处,于主管52a的侧部,包含第1侧部及第2侧部。第1侧部及第2侧部以主管52a的长度方向的中心线C为基准,配置于对称的位置上。又,所谓既定的大小是指自各吹出口521吹出的气体的量变均匀的大小。具体而言,吹出口521的大小是形成吹出口521的位置越远离侧部则越大(参照图7)。
As shown in FIG. 6, the
副管531a、532a是向主管52a传送作为热交换介质的气体的管。副管531a、532a分别连接于主管52a的两侧部(第1侧部及第2侧部)。具体而言,于主管52a的第1侧部,连接有第1副管531a,于主管52a的第2侧部,连接有第2副管532a。如图6所示,第1副管531a及第2副管532a与气体供给单元54连接。自气体供给单元54传送至第1副管531a及第2副管532a的气体的量是藉由气体供给阀55而调整。
The sub-pipes 531a and 532a are pipes that send gas as a heat exchange medium to the
b)热敏电阻 b) Thermistor
热敏电阻56测定冷却调整板41a的温度。热敏电阻56于冷却调整板41a的长度方向上安装有多个。藉由热敏电阻56而测定的冷却调整板41a的温度传送至下文将述的控制装置80。
The thermistor 56 measures the temperature of the cooling
c)气体控制单元 c) Gas control unit
气体控制单元57a是对吹送至冷却调整板41a的气体的流动进行控制的单元。具体而言,气体控制单元57a以如下方式进行控制:吹送至冷却调整板41a的气体不会于冷却调整板41a的长度方向上流动。更具体而言,如图6所示,气体控制单元57a以如下方式对气体的流动进行控制:自主管52a的吹出口521吹出的气体于吹送至冷却调整板41a之后且沿冷却调整板41a的长度方向流动之前,向与吹出方向d1正相反的方向d2流动。气体控制单元57a以如下方式构成:藉由以将自吹出口521吹出的气体往方向d2流动的方式进行控制,自一吹出口521吹出的气体不会对自另一吹出口521吹出的气体的流动方向d1造成影响。于方向d2上流动的气体向炉外释放。
The
(2-5)包围构件 (2-5) Surrounding components
包围构件70a、70b、70c是形成用以对冷却调整板41a、41b、41c的温度进行控制的空间72a、72b、72c的构件。包围构件70a、70b、70c连接于冷却调整板41a、 41b、41c的弯折部42a、42b、42c。冷却调整板41a、41b、41c、与连接于冷却调整板41a、41b、41c的包围构件70a、70b、70c形成包围管51a、51b、51c的空间72a、72b、72c。
The surrounding
具体而言,如图5所示,于第1冷却调整板41a连接有第1包围构件70a、70a。藉由第1冷却调整板41a与第1包围构件70a、70a,形成包围第1管51a的第1空间72a。藉由第1空间72a而调整第1冷却调整板41a的温度。
Specifically, as shown in FIG. 5 , first surrounding
又,于第2冷却调整板41b连接有第2包围构件70b、70b。藉由第2冷却调整板41b与第2包围构件70b、70b,形成包围第2管51b的第2空间72b。藉由第2空间72b而调整第2冷却调整板41b的温度。
Moreover, the
进而,于第3冷却调整板41c连接有第3包围构件70c,藉由第3冷却调整板41c与第3包围构件70c,形成包围第3管51c的第3空间72c。藉由第3空间72c而调整第3冷却调整板41c的温度。
Furthermore, a third surrounding
再者,包围构件70a、70b、70c的作用亦能够由下述多个隔热构件71来实现,故包围构件70a、70b、70c亦能够为隔热板,且亦能够使下述多个隔热构件71兼用为包围构件的作用。
Furthermore, the functions of the surrounding
(2-6)隔热构件 (2-6) Thermal insulation components
多个隔热构件71是阻断邻接的空间72a、72b、72c的热的移动的构件。具体而言,多个隔热构件71配置于形成邻接的空间72a、72b、72c的包围构件70a、70b、70c之间。更具体而言,如图5所示,隔热构件71配置于形成第1空间72a的第1包围构件70a、与形成邻接于第1空间72a的第2空间72b的第2包围构件70b之间,阻断第1空间72a与第2空间72b之间的热的移动。又,隔热构件71配置于形成第2空间72b的第2包围构件70b、与形成邻接于第2空间72b的第3空间72c的第3包围构件70c之间,阻断第2空间72b与第3空间72c之间的热的移动。
The some
(2-7)下拉辊 (2-7) pull down roller
多个下拉辊60相对于冷却调整单元40a~40f而配置于玻璃板91的流下方向下游,向下方下拉玻璃板91。
The plurality of pull-down rolls 60 are arranged downstream of the flow direction of the
多个下拉辊60配置于玻璃板91的厚度方向两侧(参照图2)、及玻璃板91的宽度方向两侧(参照图3)。多个下拉辊60藉由马达(未图示)而驱动。又,多个下拉辊60相对于玻璃板91向内侧旋转。藉此,二对下拉辊60向下方下拉玻璃板91。
The plurality of pull-down rolls 60 are arranged on both sides in the thickness direction of the glass plate 91 (see FIG. 2 ) and on both sides in the width direction of the glass plate 91 (see FIG. 3 ). The plurality of pull-down
(2-8)控制装置 (2-8) Control device
控制装置80由CPU、RAM、ROM、及硬碟等构成。如图8所示,控制装置80与多个冷却辊30、多个下拉辊60、气体控制单元57a、气体供给单元54、气体供给阀55、及热敏电阻56等连接。
The control device 80 is composed of a CPU, RAM, ROM, hard disk, and the like. As shown in FIG. 8, the control device 80 is connected to the plurality of cooling rolls 30, the plurality of pull-down rolls 60, the
控制装置80对冷却辊30、下拉辊60、气体控制单元57a、及气体供给单元54的驱动部进行控制。又,控制装置80对气体供给阀55的开闭或开度进行控制。又,控制装置80获取藉由热敏电阻56而测量的温度并储存。进而,控制装置80基于藉由热敏电阻56而测量的温度,对气体的供给量进行调整。
The control device 80 controls the drive units of the
(3)整体动作 (3) Overall action
自成形体10溢流的熔融玻璃90沿成形体10的两侧面流下,在成形体10的下端部合流。于成形体10的下端部合流的熔融玻璃90在其后成为板状(玻璃板91)而进一步流下。玻璃板91藉由冷却辊30夹持宽度方向两端部,从而两端部被冷却。又,除玻璃板91的宽度方向两端部外的部分藉由多个冷却调整单元40a~40f,沿流下方向阶段性地调整冷却速度。具体而言,以如下方式进行控制:藉由第1冷却调整板41a、及与该第1冷却调整板41a对应的第1温度控制单元50a,而玻璃板91的宽度方向的温度变为固定。其后,玻璃板91藉由与第1冷却调整板41a并列配置的第2冷却调整板41b、及与第2冷却调整板41b对应的第2温度控制单元50b而进一步受到冷却。此时,第2温度控制单元50b亦又以如下方式控制:使第2冷却调整板41b的长度方向的温度变为固定,并使玻璃板91的宽度方向的温度变均匀。如上所述,多个冷却调整单元40a~40f一面使玻璃板91的宽度方向的温度变均匀,一面沿玻璃板91的流下方向阶段性地冷却玻璃板91。其后,玻璃板91藉由下拉辊60而进一步向下方下拉,其后以既定的长度为单位进行切断。
The
(4)特征 (4) Features
(4-1) (4-1)
于上述实施例的玻璃板制造装置100中,在成形装置101中,多个冷却调整单元40a~40f沿玻璃板91(熔融玻璃90)的流下方向并列配置。冷却调整单元40a~40f中所包含的冷却调整板41a、41b、41c的温度藉由对应的温度控制单元50a而调整。即,于玻璃板制造装置100中,玻璃板91的上下方向(长度方向)的冷却速度的控制的自由度得到提高。
In the glass
于先前的玻璃板制造装置中,藉由在玻璃板的附近配置板状构件,防止因于炉内产生的对流而玻璃板的冷却变得不均匀的情形,但不具有能够于玻璃板的下拉方向上任意地调整板状构件的温度的机构。伴随玻璃基板的需求增加,期待控制玻璃板的冷却速度并提高玻璃板的生产量,但于先前的玻璃板制造装置中,为了确保伴随生产量增大的所需冷却量,无法实现无装置整体的玻璃板向下拉方向的大型化而充分地提高生产量。 In the conventional glass sheet manufacturing apparatus, by arranging the plate-shaped member near the glass sheet, it is possible to prevent the cooling of the glass sheet from becoming uneven due to convection generated in the furnace, but it does not have the ability to pull down the glass sheet. A mechanism for adjusting the temperature of a plate-like member in any direction. With the increase in demand for glass substrates, it is expected to control the cooling rate of glass sheets and increase the throughput of glass sheets. However, in the conventional glass sheet manufacturing equipment, in order to ensure the required cooling amount due to the increase in throughput, it is impossible to realize the whole without equipment. The increase in the size of the glass plate in the downward pull direction can fully improve the throughput. the
于上述实施例的玻璃板制造装置100中,在成形装置101中,为了调整玻璃板91的冷却速度而使用冷却调整单元40a~40f。于冷却调整单元40a~40f中,分别包含冷却调整板41a、41b、41c及温度控制单元50a,且藉由温度控制单元50a对冷却调整板41a、41b、41c的温度进行调整,故能够根据所需对玻璃板91的冷却速度进行调整。藉此,能够不使装置整体大型化而于有限的空间中有效率地对冷却速度进行控制,故能够提高玻璃板91的生产量。
In the glass
(4-2) (4-2)
又,于上述实施例的玻璃板制造装置100中,在成形装置101中使用多个冷却调整单元40a~40f。一冷却调整单元40a中所包含的冷却调整板41a于玻璃板91的宽度方向上延伸。而且,温度控制单元50a进行冷却调整板41a的整体的温度控制。因此,可以均匀地保持玻璃板91的宽度方向上的温度的状态,沿玻璃板91的流下方向阶段性地降低玻璃板91的温度。藉此,能够良好地保持玻璃板91的有效宽度内的平面度品质。
Moreover, in the glass
(4-3) (4-3)
于上述实施例的玻璃板制造装置100中,在上下环境分隔构件20、20的下方设置有多个冷却调整单元40a~40f。上下环境分隔构件20、20的下方成为藉由上下环境分隔构件20、20而阻断成形体10的热的空间。冷却调整单元40a~40f于成形体10的热被阻断的空间内,对熔融玻璃90的冷却速度进行控制。藉此,减少对在成形体上流动的熔融玻璃的温度造成的影响,从而能够高效地进行温度控制。
In the glass
(4-4) (4-4)
于上述实施例中,向冷却调整板41a、41b、41c吹送气体的主管52a与冷却调整板41a、41b、41c相同地于水平方向上延伸。
In the said embodiment, the
又,主管52a具有与冷却调整板41a、41b、41c对向且空开既定的距离间隔而设 置的吹出口。吹出口根据距连结有副管的侧部的位置而设定大小。冷却调整板41a、41b、41c的温度藉由自吹出口吹送的气体而调整。藉此,可以使冷却调整板41a、41b、41c的宽度方向上的温度接近均匀的方式进行温度控制。
In addition, the
(4-5) (4-5)
又,于上述实施例中,主管52a具有的吹出口521根据距侧部的距离,以宽度方向上的中心线C为对称轴具有不同的大小。藉由回路配管而自两侧部供给相等的压力的冷却气体,故侧部(气体自副管向主管的供给位置)至吹出口521为止的距离越远,压力损耗越大。即,吹出口521的位置距侧部越远,自吹出口521吹出的气体的压力越下降,从而难以于所有吹出口521确保充分的流量。因此,于上述实施例中,根据距侧部的距离而变更各吹出口的大小(开口面积)。具体而言,越远离侧部,吹出口521的开口面积越大。又,吹出口521形成于相对于中心线C成为对称的位置上。其结果,以冷却调整板41a的长度方向上的温度变均匀的方式,气体自主管52a吹出。藉此,各个冷却调整板41a、41b、41c于宽度方向上大致保持为均匀的温度,从而能够制造较佳的平面度的玻璃板91。
Moreover, in the above-mentioned embodiment, the
(4-6) (4-6)
进而,于上述实施例中,冷却调整板41a、41b、41c为槽钢。即,冷却调整板41a是具有弯折部42a及主要部分43a,弯折部42a是于水平方向上延伸的金属构件的上下弯折的部分,主要部分43a是于水平方向上延伸的金属构件中的除弯折部42a外的部分,是与玻璃板91对向的平坦的面。因此,冷却调整板41a、41b藉由采用该弯折构造,而相对于平面方向的弯曲应力的断面二次矩变大,故能够抑制因主要部分43a的表面与背面的温度差产生的变形。即,能够抑制冷却调整板41a、41b的弯曲,从而防止玻璃板(玻璃带)91与冷却调整板41a、41b的距离尤其于玻璃板的下拉方向上根据部位而大幅不同的情形。
Furthermore, in the above-described embodiment, the
藉此,能够抑制玻璃带的冷却过程中的平面度的恶化。 Thereby, deterioration of the flatness in the cooling process of a glass ribbon can be suppressed. the
又,于上述实施例中,冷却调整板41a的主要部分43a具有约4mm以上的厚度t。藉此,于在与冷却调整板41a的玻璃对向侧相反的表面宽度方向上产生温度不均的情形时,藉由冷却调整板41a内部的热传导而玻璃对向面的温度差得以缓和,从而能够抑制对玻璃板91的温度控制造成的影响。又,于流入冷却调整板间的玻璃板91在宽度方向上原本已具有温度不均的情形时,若冷却调整板的面内温度均匀性较高, 则伴随与调整板的热交换,玻璃板91所具有的温度不均得以缓和。
Also, in the above-described embodiment, the
(4-7) (4-7)
又,于上述实施例中,呈如下构成:藉由使用包围构件70a、70b、70c及多个隔热构件71,一冷却调整单元40a难以对邻接的冷却调整单元40b造成影响。具体而言,于第1冷却调整单元40a的冷却调整板(第1冷却调整板)41a上所连接的包围构件70a、与第2冷却调整单元40b的冷却调整板(第2冷却调整板)41b上所连接的包围构件70b之间,配置有隔热构件71,故用以对第1冷却调整板41a的温度进行调整的第1空间72a、与用以对第2冷却调整板41b的温度进行调整的第2空间72b之间的热的移动受到阻断。
In addition, in the above-mentioned embodiment, the structure is such that one
藉此,能够减少一冷却调整单元40a对邻接的冷却调整单元40b造成的影响。
Thereby, the influence of one
(4-8) (4-8)
进而,于上述实施例中,藉由气体控制单元57a而控制向冷却调整板41a吹送后的气体的流动。气体控制单元57a向与自管向冷却调整板41a的气体的吹出方向d1正好相反的方向d2流通。藉此,能够减少自一吹出口521吹出的气体对自另一吹出口521吹出的气体的流动方向d1造成的影响。
Furthermore, in the above-mentioned embodiment, the flow of the gas blown to the cooling
(5)变形例 (5) Variations
(5-1)变形例A (5-1) Modification A
于上述实施例中,对使用熔融法制造玻璃板91的情形的例进行了说明,但使用多个冷却调整单元40a~40f的构成亦能够于使用流孔下引法制造玻璃板91的情形时采用。
In the above-mentioned embodiment, an example of the case where the
(5-2)变形例B (5-2) Modification B
于上述实施例中,采用纯镍作为热传导率较高的材料,但亦能够使用其他材料作为热传导率较高的材料。例如,亦能够为钼、烧结SiC、再结晶SiC、人造石墨、铁、钨等。然而,于采用钼的情形时,较佳为于非氧化环境下使用。又,于在氧化环境下使用钼的情形时,较佳为实施耐氧化涂敷。又,烧结SiC能够于氧化环境下采用,人造石墨、铁、及钨能够于在非氧化环境下使用的情形时采用。又,较理想的是,为了促进冷却调整板与玻璃板的因热辐射所引起的热交换,于使用放射率并不高的材料的情形时,将于其耐热性的构件表面涂布有提高放射率的材料者用作冷却调整板41a、41b、41c。
In the above embodiments, pure nickel is used as the material with high thermal conductivity, but other materials can also be used as the material with high thermal conductivity. For example, molybdenum, sintered SiC, recrystallized SiC, artificial graphite, iron, tungsten, etc. can also be used. However, when molybdenum is used, it is preferably used in a non-oxidizing environment. Also, when molybdenum is used in an oxidizing environment, it is preferable to perform an oxidation-resistant coating. Also, sintered SiC can be used in an oxidizing environment, and artificial graphite, iron, and tungsten can be used in a non-oxidizing environment. Furthermore, it is more desirable that in order to promote the heat exchange between the cooling adjustment plate and the glass plate due to heat radiation, in the case of using a material with a low emissivity, the surface of the heat-resistant member is coated with Materials that increase emissivity are used as cooling
(5-3)变形例C (5-3) Modification C
于上述实施例中,使用槽钢(槽形钢形状)作为冷却调整板41a、41b、41c,但冷却调整板41a、41b、41c并不限定于上述形状,亦能够为其他形状。此时,较佳为设为如下的构成:将邻接的冷却调整板41a、41b间的接触设为最小限,抑制邻接的冷却调整板41a、41b间的热传导。例如,冷却调整板41a、41b、41c亦能够为圆杆(圆柱)形状、或奇数的多边柱形状等。
In the above-mentioned embodiment, channel steel (channel steel shape) was used as the
(5-4)变形例D (5-4) Modification D
于上述实施例中,在主管52a上均匀地形成有多个吹出口521,但该多个吹出口521亦可以基于距侧部的距离及吹出口521的大小的距离间隔而形成。
In the above-mentioned embodiment, the plurality of
(5-5)变形例E (5-5) Modification E
于上述实施例中,作为制造G5尺寸的玻璃基板所用的玻璃板91时的例,例示有冷却调整板41a、41b、41c的长度方向上的长度、或冷却调整单元40a~40f的数量(6个),但亦能够根据制造的玻璃板91的大小,调整长度方向的长度或冷却调整单元的数量。
In the above-mentioned embodiment, as an example when manufacturing the
(5-6)变形例F (5-6) Modification F
又,较理想的是,于上述实施例中,冷却调整板41a的主要部分43a于宽度方向上保持较高的直线度,但于高度方向上亦能够为凸凹。藉此,能够抑制沿玻璃板91产生的上升气流的流动,从而抑制因部位引起的冷却速度差的产生。
Furthermore, ideally, in the above-mentioned embodiment, the
(5-7)变形例G (5-7) Modification G
于上述实施例的玻璃板制造装置100中,亦能够为一气体供给单元54对一冷却调整单元40a供给气体的构成,又,亦能够为一气体供给单元54对多个冷却调整单元40a~40f供给气体的构成。
In the glass
符号说明 Symbol Description
10 成形体 10 Formed body
11 槽 11 slot
20 上下环境分隔构件 20 Separation components for the upper and lower environments
30 冷却辊 30 Cool Roller
40a~40f 冷却调整单元 40a~40f Cooling adjustment unit
41a、41b、41c 冷却调整板 41a, 41b, 41c cooling adjustment plate
42a、42b、42c 弯折部 42a, 42b, 42c bending part
43a、43b 主要部分 43a, 43b Main part
50a 温度控制单元 50a Temperature Control Unit
51a、51b、51c 管 51a, 51b, 51c tube
52a 主管 52a Supervisor
55 气体供给阀 55 Gas supply valve
57a 气体控制单元 57a Gas control unit
60 下拉辊 60 Pull down roller
90 熔融玻璃 90 Molten Glass
91 玻璃板 91 Glass plate
100 玻璃板制造装置 100 Glass plate manufacturing equipment
101 成形装置 101 Forming device
521 吹出口 521 Blow outlet
531a、532a 副管 531a, 532a Auxiliary pipe
专利文献 Patent Documents
专利文献1:日本特开平2-225326号公报 Patent Document 1: Japanese Patent Application Laid-Open No. 2-225326
Claims (8)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
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| JP2010-175707 | 2010-08-04 | ||
| JP2010175707 | 2010-08-04 | ||
| PCT/JP2011/067845 WO2012018072A1 (en) | 2010-08-04 | 2011-08-04 | Glass plate production device and glass plate cooling method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN203173971U true CN203173971U (en) | 2013-09-04 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN2011900005560U Expired - Lifetime CN203173971U (en) | 2010-08-04 | 2011-08-04 | Glass plate manufacturing device |
Country Status (5)
| Country | Link |
|---|---|
| JP (2) | JP5154700B2 (en) |
| KR (1) | KR101452609B1 (en) |
| CN (1) | CN203173971U (en) |
| TW (2) | TWI403471B (en) |
| WO (1) | WO2012018072A1 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103922567A (en) * | 2014-04-01 | 2014-07-16 | 成都光明光电股份有限公司 | Device for manufacturing glass plate |
| CN107771165A (en) * | 2015-04-17 | 2018-03-06 | 康宁股份有限公司 | The glass manufacturing equipment and method of heat enhancing |
| CN108196387A (en) * | 2018-01-02 | 2018-06-22 | 重庆京东方光电科技有限公司 | Underlay substrate and its manufacturing device, preparation method and display device |
| CN108367959A (en) * | 2015-11-19 | 2018-08-03 | 康宁股份有限公司 | Glass manufacturing equipment with cooling device and its application method |
| CN112146351A (en) * | 2020-09-12 | 2020-12-29 | 广西开蒙医疗科技有限公司 | Electronic scale glass plate water-cooling circulating device |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5805602B2 (en) * | 2012-09-28 | 2015-11-04 | AvanStrate株式会社 | Manufacturing method of glass substrate and cooler |
| JP6597953B2 (en) * | 2015-04-30 | 2019-10-30 | 日本電気硝子株式会社 | Sheet glass manufacturing apparatus and sheet glass manufacturing method |
| JP5969671B2 (en) * | 2015-09-02 | 2016-08-17 | AvanStrate株式会社 | Glass substrate manufacturing method and glass substrate manufacturing apparatus |
| JP7045320B2 (en) * | 2016-04-05 | 2022-03-31 | コーニング インコーポレイテッド | Glass ribbon manufacturing method and equipment |
| JP2025527767A (en) * | 2022-08-26 | 2025-08-22 | コーニング インコーポレイテッド | Method and apparatus for forming a glass ribbon |
| WO2024086041A1 (en) * | 2022-10-20 | 2024-04-25 | Corning Incorporated | Sheet glass thickness control apparatus |
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| JP2556567B2 (en) * | 1988-11-30 | 1996-11-20 | ホーヤ株式会社 | Glass plate manufacturing equipment |
| JPH05124827A (en) * | 1991-10-31 | 1993-05-21 | Hoya Corp | Device for producing glass plate and production of glass plate |
| JP3093000B2 (en) * | 1991-10-31 | 2000-09-25 | ホーヤ株式会社 | Glass plate manufacturing equipment |
| JP4027266B2 (en) * | 2003-05-23 | 2007-12-26 | Hoya株式会社 | Method for slowly cooling glass article, method for heating glass article, method for producing glass molded article, and heat treatment apparatus |
| US20060042314A1 (en) * | 2004-08-27 | 2006-03-02 | Abbott John S Iii | Noncontact glass sheet stabilization device used in fusion forming of a glass sheet |
| JP4821260B2 (en) * | 2005-10-20 | 2011-11-24 | 日本電気硝子株式会社 | Liquid crystal plate glass heating apparatus, liquid crystal plate glass furnace, and liquid crystal plate glass manufacturing method |
| JP5327702B2 (en) * | 2008-01-21 | 2013-10-30 | 日本電気硝子株式会社 | Manufacturing method of glass substrate |
-
2011
- 2011-08-04 JP JP2011542394A patent/JP5154700B2/en active Active
- 2011-08-04 KR KR1020127027732A patent/KR101452609B1/en active Active
- 2011-08-04 CN CN2011900005560U patent/CN203173971U/en not_active Expired - Lifetime
- 2011-08-04 TW TW100127867A patent/TWI403471B/en active
- 2011-08-04 WO PCT/JP2011/067845 patent/WO2012018072A1/en not_active Ceased
- 2011-08-04 TW TW102110645A patent/TWI414493B/en active
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2012
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103922567A (en) * | 2014-04-01 | 2014-07-16 | 成都光明光电股份有限公司 | Device for manufacturing glass plate |
| CN103922567B (en) * | 2014-04-01 | 2016-04-13 | 成都光明光电股份有限公司 | The manufacturing installation of sheet glass |
| CN107771165A (en) * | 2015-04-17 | 2018-03-06 | 康宁股份有限公司 | The glass manufacturing equipment and method of heat enhancing |
| CN107771165B (en) * | 2015-04-17 | 2020-12-01 | 康宁股份有限公司 | Thermally enhanced glass making apparatus and method |
| CN108367959A (en) * | 2015-11-19 | 2018-08-03 | 康宁股份有限公司 | Glass manufacturing equipment with cooling device and its application method |
| CN108196387A (en) * | 2018-01-02 | 2018-06-22 | 重庆京东方光电科技有限公司 | Underlay substrate and its manufacturing device, preparation method and display device |
| CN112146351A (en) * | 2020-09-12 | 2020-12-29 | 广西开蒙医疗科技有限公司 | Electronic scale glass plate water-cooling circulating device |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2013063902A (en) | 2013-04-11 |
| TWI403471B (en) | 2013-08-01 |
| JP5190558B2 (en) | 2013-04-24 |
| JP5154700B2 (en) | 2013-02-27 |
| KR20120132688A (en) | 2012-12-07 |
| TW201213247A (en) | 2012-04-01 |
| KR101452609B1 (en) | 2014-10-22 |
| TWI414493B (en) | 2013-11-11 |
| JPWO2012018072A1 (en) | 2013-10-03 |
| TW201332908A (en) | 2013-08-16 |
| WO2012018072A1 (en) | 2012-02-09 |
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