Background technology
Method of wastewater treatment now comprises methods such as utilizing physics, chemistry and biology to be handled waste water, so that purification of waste water reduces and pollutes, reaches waste water reclamation and uses, and takes full advantage of water resources.Wherein chemical process for example can be enumerated: chemical coagulation process, membrane-filter procedure, electrochemical coagulation method and ion exchange method etc.
The chemical coagulation process of general frequent use, it is to add inorganic salts coagulating agent (coagulant) mode with the fine particle coacervating large particle, again with the sedimentation in settling tank of gravity mode.The water that flow out in the autoprecipitation pond can be by the pre-treatment of sand filter process again by after the chlorine disinfectant, water in the formation.So-called " middle water " can be called reuse water or recycle-water again, it refers to that sewage reclaims the water that re-uses after treatment, owing in the urban architecture water supply is called " going up water ", sewage is called " following water ", therefore middle water has gets its meaning between the two, and middle water can be used as the miscellaneous water of poor benefits such as cooling water, water tower make up water, cleaning water or greening water.
Along with water scarcity, demand for middle water has developed into further use reverse osmosis (Reverse Osmosis membrane, RO) handle, with produce highly purified reuse water with from (Reverse Osmosis membrane, RO) handle, enter the pure water processing procedure to mix with tap water to produce highly purified reuse water.
But the reverse osmosis processing procedure is strict for feed water, comprise pH-value, the concentrated fouling of salt, sludge density index (SDI) (Sludge Density Index, SDI) etc., its pretreatment unit complexity, and can increase cost, doing further reverse osmosis for water in desiring to reclaim and handle and use, is not good execution scheme actually.
The utility model content
In view of this, in order to overcome above-mentioned shortcoming, the utility model people invents this wastewater treatment equipment through repeatedly attempting, it need not via traditional chemical coagulation required settling tank or air flotation pool, and can tolerate flooding velocity and water quality and impact, and the middle quality that produces can directly be carried out reverse osmosis and be need not the pretreated wastewater treatment equipment of any reverse osmosis.
Wastewater treatment equipment of the present utility model comprises a feeder and a treatment trough.Described feeder comprises an opening for feed, a dosing opening for feed and a line mixer at least; Described opening for feed is to enter for waste water, described dosing opening for feed is to drop into for the water purification medicament, described line mixer is connected with described opening for feed and described dosing opening for feed, and after will mixing by the waste water of described throat-fed and by the water purification medicament of described dosing throat-fed, be fed in the described treatment trough; Described treatment trough comprises at least one cell body, a gas blower and a water outlet; The described line mixer of wherein said feeder will be fed in described at least one cell body of described treatment trough; Each cell body is provided with a film filter, and described cell body carries out aeration by described gas blower, and described cell body is provided with a water outlet to reclaim the water after filtering.
Preferably, the described cell body of described treatment trough further is provided with a waste outlet.
Preferably, the described cell body of described treatment trough is provided with one acid solution/alkali lye opening for feed and pH-value mensuration meter.
Preferably, the charging acid solution of described acid solution/alkali lye opening for feed is selected sulfuric acid or hydrochloric acid for use, and charging alkali lye is selected sodium hydroxide for use.
Preferably, described treatment trough comprises three cell bodies, be respectively first groove, second groove and three-flute, in described first groove, described second groove and described three-flute, be provided with described film filter separately, it is tabular film or the tubular fibre cortina of negative pressure leaching, and its membrane pore size is 0.01 to 10 micron.
Preferably, the glue plumage concentration of the waste water that is flowed out by described waste outlet is about 10,000 to 25,000mg/L.
Preferably, the membrane material of described film filter is selected among polyvinylchloride, polyacrylonitrile (PAN), polypropylene PP, polysulfones PS, polyethersulfone PES and the polyvinylidene difluoride (PVDF) PVDF at least a.
Preferably, be provided with one between the described cell body of described treatment trough and the described water outlet and produce water ga(u)ge, and the film of described treatment trough to produce water flux be 10 to 100L/m
2/ hr.
Wastewater treatment equipment of the present utility model has the following advantages and effect: water during 1, wastewater treatment equipment of the present utility model can produce with high-recovery (more than 97.5%), in this quality be high purity and the middle water that produces can be directly by the reverse osmosis processing procedure (SDI that is for further processing
15<4); 2, wastewater treatment equipment of the present utility model need not settling tank or the air flotation pool of traditional chemical Coagulation Method, and institute's separated solids and waste liquid can directly enter sludge dewatering equipment and handle, need not to arrange in addition sludge thickener, the tolerance of the employed ultra-filtration membrane of its treatment trough is also high, can keep the stable middle water of the quality of production.
Embodiment
For making your auditor can further understand structure of the present utility model, feature and other purposes, now be described in detail as follows with accompanying drawing in conjunction with appended preferred embodiment is attached, the illustrated embodiment of this accompanying drawing only is used for explanation the technical solution of the utility model and non-limiting the utility model.
The utility model uses the water purification medicament to catch pollutants in waste water, and pollutent is transformed the water-fast throw out of formation, and utilize one or more snippets membrane filter unit, and carry out the membrane filtration of multistage, the middle quality that makes it to produce meets the water inlet requirement of reverse osmosis.The high density flocs unit that final treatment trough is discharged, that is so-called waste liquid or mud can directly enter sludge dewatering treatment, need not to arrange sludge thickener.
During membrane filtration, be accumulated in the lip-deep glue plumage of ultra-filtration membrane (Ultra Filtration Membrane) and can densification become to have the mud cake that increases the filter pressure impedance, the upward water flow that the aeration that produces by the gas blower at the bottom of the treatment trough causes can suppress formed hmc on the ultra-filtration membrane surface.Be provided with variable valve between gas blower and each treatment trough, can adjust or strengthen aeration intensity, remove the too much mud cake of accumulation on the face to wash away.
Wherein, owing to use a plurality for the treatment of troughs to filter, the flco substrate concentration improves by groove in the groove.Ultra-filtration membrane in the treatment trough of most end, because bear the throw out concentration of maximum concentration, it is the fastest that face is piled up the speed of mud cake, therefore needs the special aeration of strengthening to scrub face, and reduce the membrane filtration flux.
Hereinafter with reference to correlative type, the wastewater treatment equipment according to the utility model preferred embodiment is described, in order to make it easy to understand, the same components among the following embodiment illustrates with identical symbology.
See also Fig. 1, wastewater treatment equipment of the present utility model comprises a feeder 1 and a treatment trough 2, and this feeder 1 interconnects with this treatment trough 2, and can make wastewater feed to this treatment trough 2.
This feeder 1 comprises an opening for feed 101, a dosing opening for feed 102 and a line mixer 103.
This opening for feed 101 enters in the treatment trough 2 of this wastewater treatment equipment for waste water, and the waste water of indication means usually at chemical grinding and adds man-hour (Chemical Mechanical Polishing, the waste water that CMP) produces in the utility model.
This dosing opening for feed 102 is to enter in the treatment trough 2 of this wastewater treatment equipment for aforementioned water purification medicament, purifies medicament and is selected from aluminium salt such as Tai-Ace S 150 (aluminum sulfate), polymerize aluminum chloride (PAC), sodium aluminate; Molysite such as iron(ic) chloride, ferrous sulfate, bodied ferric sulfate and can use throw out (glue plumage) in water separately.
This line mixer (Static mixer) 103 interconnects with this opening for feed 101 and this dosing opening for feed 102, can will carry out online fast mixing by the waste water of aforementioned opening for feed 101 chargings and by the water purification medicament of aforementioned dosing opening for feed 102 chargings, produce water-fast throw out, and this throw out is fed in the treatment trough 2.
This treatment trough 2 comprises one first groove 21, one second groove 22, a three-flute 23, a gas blower 3 and a water outlet 4, and wherein the throw out that produces of the line mixer 103 of this feeder 1 is in first groove 21 of this treatment trough 2 of charging.
This first groove 21, second groove 22 and three-flute 23 are respectively arranged with film filter 211,221,231, and first groove 21 and second groove 22 are interconnected and second groove 22 and three-flute 23 are interconnected, and this first groove 21, second groove 22 and three-flute 23 are to be interconnected with the series connection form.Film filter 211,221, the 231st, the tabular film of negative pressure leaching or tubular fibre cortina.Membrane pore size is 0.01 to 10 micron, is preferably 0.03 to 0.1 micron.Membrane material can be polyvinyl chloride (PVC), polyacrylonitrile (PAN), polypropylene (PP), polysulfones (PS), polyethersulfone (PES) or polyvinylidene difluoride (PVDF) (PVDF).The bottom land of this first groove 21, second groove 22 and three-flute 23 leads to mutually with this gas blower 3 respectively, and be provided with variable valve 31,32,33, therefore can be with air aeration bottom the diaphragm of each groove, make and produce bubble and the current that upwards flow between the diaphragm, wash away the film surface, suppress face and produce the accumulation of glue plumage.Film filter 211,221,231 leaches the water of purification via negative pressure-pumping.The top of this first groove 21, second groove 22 and three-flute 23 links mutually with this water outlet 4 respectively, and is provided with product water ga(u) ge 41,42,43, and the film of each treatment trough produces water flux and is about 10 to 100L/m
2/ hr is preferably 20 to 50L/m
2/ hr.
In addition, this first groove 21 is provided with acid solution/alkali lye opening for feed 24 and pH-value is measured meter 25, its purpose is the dose that adds by control acid solution/alkali lye, and the pH value of regulating and control in first groove 21 is best scope of carrying out chemical coagulation process, has reached the filter quality of the best.Best pH scope will be according to the characteristic of handled waste water, and it needs to decide via test of many times.Adjust the acid solution of pH value and can use sulfuric acid or hydrochloric acid etc., alkali lye can be selected sodium hydroxide for use.
Moreover three-flute 23 is provided with waste outlet 26, behind the wastewater feed, in first groove 21, disturbs the mixed and glue plumage slaking of slow motion by the current that aeration produces, and is then gone out clean water by film filter 211 suction filtrations of first groove 21, and the glue plumage in first groove 21 is concentrated.The film filter 221 that glue plumage mixed solution in first groove 21 flows into second groove, 22, the second grooves 22 also suction filtration goes out clean water, and the glue plumage in second groove 22 is concentrated again.Second groove 22 flows into the glue plumage mixed solution of three-flute 23 via film filter 231 suction filtrations of three-flute 23, after glue plumage concentration is concentrated again, with glue plumage concentration about 10,000 to 25,000mg/L, directly extracted out with the mud water pump by waste outlet 26, enter sludge dewatering equipment and handle, need not to arrange in addition sludge thickener.
Mandatory declaration be that glue plumage concentration is controlled by the water rate of recovery, the wastewater flow rate of the water yield/charging that the water rate of recovery=membrane filtration produces.Little when the pollution of the waste water of charging, the water purification additive amount of medicament just tails off, and initial glue plumage concentration is few, and therefore, the water rate of recovery can raise.Otherwise, the pollution height of influent stream water, it is big that the water purification additive amount of medicament just becomes, and initial glue plumage concentration height just must reduce the water rate of recovery, makes the glue plumage concentration of three-flute 23 can be too not high, causes the operational difficulty of film filter.
Embodiment
The utility model uses tabular ultra-filtration membrane, is immersed in the treatment trough of three series connection.Process sodium aluminate and polymerize aluminum chloride (PAC) coagulating agent that the wastewater form mechanic grinding that is produced adds appropriate amount with Silicon Wafer, carry out online fast mixing by line mixer, with the solvability silicon-dioxide in the water with how the meter level abrasive grains is transformed into water-fast aluminium glue plumage.Mix soon through line mixer, see also following embodiment:
Embodiment 1
The water yield that the wastewater form mechanic grinding of Silicon Wafer zone of oxidation reclaims is 15CMH, pH=9, solvability silica 1 30mg/L.Use is with sodium aluminate (120mg/L), and poly aluminium chloride 130mg/L is adjusted into pH=6.5 to 7 as the water purification medicament with sodium hydroxide, the about 1100mg/L of initial glue plumage concentration.Use three treatment trough series connection, place 1 group of tabular ultra-filtration membrane group in each groove, membrane filtration produces water flux 32L/m
2/ hr.Produce the water rate of recovery and can reach 95%, the silicon-dioxide residual quantity of the middle water of producing is 27mg/L, SDI
15=2.
| |
First groove |
Second groove |
Three-flute |
| The membrane filtration water production rate |
4.8CMH |
4.8CMH |
4.67CMH |
| Glue plumage concentration in the groove |
About 1,600mg/L |
About 3,050mg/L |
About 22,600mg/L |
| Concentrate the discarded amount of glue plumage |
0 |
0 |
0.73CMH |
Embodiment 2
The water yield of the nickel rinse water that tellite soft board processing procedure is discharged is 2CMH, pH=6, the total nickel 11mg/L of solvability.Use is with Tai-Ace S 150 (Al 50mg/L), and poly aluminium chloride 100mg/L adjusts pH=9 to 9.5, the about 200mg/L of initial glue plumage concentration as the water purification medicament with sodium hydroxide.Use the series connection of three treatment troughs, place 1 group of tabular ultra-filtration membrane group in each groove, it is 32L/m that membrane filtration produces water flux
2/ hr, it produces the water rate of recovery can reach 98.2%, and the nickel concentration of the middle water that produces is 0.13mg/L, SDI
15=2.
| |
First groove |
Second groove |
Three-flute |
| The membrane filtration water production rate |
0.66CMH |
0.66CMH |
0.64CMH |
| Glue plumage concentration in the groove |
About 300mg/L |
About 600mg/L |
About 11,000mg/L |
| Concentrate the discarded amount of glue plumage |
0 |
0 |
0.04CMH |
What need statement is that above-mentioned utility model content and embodiment are intended to prove the practical application of technical scheme that the utility model provides, and should not be construed as the restriction to the utility model protection domain.Those skilled in the art are in spirit of the present utility model and principle, when doing various modifications, being equal to and replacing or improve.Protection domain of the present utility model is as the criterion with appended claims.