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CN202811078U - Ultra-supercritical air energy storage/release system - Google Patents

Ultra-supercritical air energy storage/release system Download PDF

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CN202811078U
CN202811078U CN2012203708776U CN201220370877U CN202811078U CN 202811078 U CN202811078 U CN 202811078U CN 2012203708776 U CN2012203708776 U CN 2012203708776U CN 201220370877 U CN201220370877 U CN 201220370877U CN 202811078 U CN202811078 U CN 202811078U
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storage
air
heat exchanger
energy
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陈海生
许剑
刘金超
盛勇
谭春青
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Institute of Engineering Thermophysics of CAS
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/16Mechanical energy storage, e.g. flywheels or pressurised fluids
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E70/00Other energy conversion or management systems reducing GHG emissions
    • Y02E70/30Systems combining energy storage with energy generation of non-fossil origin

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Abstract

本实用新型公开了一种超超临界空气储能/释能系统,是新型大规模储能系统,它涉及能量储存技术,即采用电站低谷(低价)电将空气压缩至超超临界状态(同时存储压缩热),利用膨胀机使空气降温同时回收膨胀功提高效率,并利用已存储的冷能将超超临界空气冷却、液化并存储(储能);在用电高峰,液态空气经过加压、吸热至超超临界状态(同时回收冷能),并在进一步吸收压缩热后通过涡轮驱动发电机发电(释能)。本实用新型的系统具有能量密度高、效率高、不受储能周期和地理条件限制、适用于各种电站(包括风能等可再生能源电站)、对环境友好、可回收中低温(热值)废热等优点。

Figure 201220370877

The utility model discloses an ultra-supercritical air energy storage/release system, which is a new type of large-scale energy storage system, which relates to energy storage technology, that is, the air is compressed to an ultra-supercritical state ( Simultaneously store the heat of compression), use the expander to cool the air while recovering the expansion work to improve efficiency, and use the stored cold energy to cool, liquefy and store the ultra-supercritical air (energy storage); at the peak of power consumption, the liquid air is heated Compression, heat absorption to an ultra-supercritical state (while recovering cold energy), and after further absorption of compression heat, a turbine drives a generator to generate electricity (energy release). The system of the utility model has high energy density, high efficiency, is not limited by the energy storage period and geographical conditions, is suitable for various power stations (including wind energy and other renewable energy power stations), is environmentally friendly, and can recycle medium and low temperature (calorific value) Advantages such as waste heat.

Figure 201220370877

Description

超超临界空气储能/释能系统Ultra-supercritical air energy storage/energy release system

技术领域 technical field

本实用新型涉及能量储存技术领域,特别是一种基于超超临界过程的大规模空气储能/释能系统。  The utility model relates to the technical field of energy storage, in particular to a large-scale air energy storage/energy release system based on an ultra-supercritical process. the

背景技术 Background technique

电力储能技术是目前调整电网峰谷、改善电力系统经济性和稳定性的重要手段,是制约不稳定、间歇式的可再生能源大规模利用的最重要瓶颈之一,也是分布式能源和智能电网的关键技术。目前已有电力储能技术包括抽水蓄能电站、压缩空气、蓄电池、超导磁能、飞轮和电容等。但由于容量、储能周期、能量密度、充放电效率、寿命、运行费用、环保等原因,目前已在大型商业系统中运行的只有抽水电站和压缩空气两种。  Power energy storage technology is currently an important means to adjust the peak and valley of the power grid and improve the economy and stability of the power system. It is one of the most important bottlenecks restricting the large-scale utilization of unstable and intermittent renewable energy. The key technology of power grid. At present, the existing electric energy storage technologies include pumped storage power stations, compressed air, storage batteries, superconducting magnetic energy, flywheels and capacitors. However, due to capacity, energy storage period, energy density, charge and discharge efficiency, lifespan, operating costs, environmental protection and other reasons, only pumped hydropower stations and compressed air have been used in large-scale commercial systems. the

传统压缩空气储能系统是基于燃气轮机技术开发的一种储能系统。在用电低谷,将空气压缩并存于储气室中,使电能转化为空气的内能存储起来;在用电高峰,高压空气从储气室释放,进入燃气轮机燃烧室同燃料一起燃烧,然后驱动透平发电。压缩空气储能系统具有储能容量较大、储能周期长、效率高(50%~70%)和单位投资相对较小等优点,但是,传统压缩空气储能系统不是一项独立的技术,它必须同燃气轮机电站配套使用,不能适合其他类型,如燃煤电站、核电站、风能和太阳能等电站,特别不适合我国以燃煤发电为主,不提倡燃气燃油发电的能源战略。而且,压缩空气储能系统仍然依赖燃烧化石燃料提供热源,一方面面临化石燃料 逐渐枯竭和价格上涨的威胁,另一方面其燃烧仍然产生氮化物、硫化物和二氧化碳等污染物,不符合绿色(零排放)、可再生的能源发展要求。更为致命的是,由于储能密度低,压缩空气储能系统也需要特定的地理条件建造大型储气室,如岩石洞穴、盐洞、废弃矿井等,从而大大限制了压缩空气储能系统的应用范围。  The traditional compressed air energy storage system is an energy storage system developed based on gas turbine technology. During the low electricity consumption, the air is compressed and stored in the gas storage chamber, so that the electric energy is converted into the internal energy of the air and stored; at the peak power consumption, the high-pressure air is released from the gas storage chamber, enters the combustion chamber of the gas turbine and burns together with the fuel, and then drives Turbine power generation. The compressed air energy storage system has the advantages of large energy storage capacity, long energy storage period, high efficiency (50% to 70%) and relatively small unit investment. However, the traditional compressed air energy storage system is not an independent technology. It must be used in conjunction with gas turbine power plants, and cannot be suitable for other types, such as coal-fired power plants, nuclear power plants, wind and solar power plants, and is especially not suitable for my country's energy strategy that focuses on coal-fired power generation and does not advocate gas-fired power generation. Moreover, the compressed air energy storage system still relies on the combustion of fossil fuels to provide heat sources. On the one hand, it faces the threat of the gradual depletion of fossil fuels and rising prices; Zero emissions), renewable energy development requirements. What's more fatal is that due to the low energy storage density, the compressed air energy storage system also requires specific geographical conditions to build large gas storage chambers, such as rock caves, salt caverns, abandoned mines, etc., which greatly limits the use of compressed air energy storage systems. application range. the

为解决传统压缩空气储能系统面临的主要问题,特别是对燃气轮机的依赖问题,最近几年国内外学者分别开展了地面压缩空气储能系统(SVCAES)、带回热的压缩空气储能系统(AACAES)、空气蒸汽联合循环压缩空气储能系统(CASH)等,使压缩空气储能系统基本可以脱离化石燃料燃烧热源。但由于不采用化石燃料热源,压缩空气储能系统的能量密度更低,更加凸显了对大型储气室依赖,同时效率也不够高,必须找到合理的解决办法,才能使空气储能系统得到更广泛而又有效地利用。  In order to solve the main problems faced by traditional compressed air energy storage systems, especially the dependence on gas turbines, scholars at home and abroad have developed ground compressed air energy storage systems (SVCAES), compressed air energy storage systems with heat recovery ( AACAES), air-steam combined cycle compressed air energy storage system (CASH), etc., so that the compressed air energy storage system can basically be separated from the fossil fuel combustion heat source. However, since no fossil fuel heat source is used, the energy density of the compressed air energy storage system is lower, which further highlights the dependence on large gas storage chambers, and the efficiency is not high enough. A reasonable solution must be found to make the air energy storage system more efficient. widely and effectively. the

近年来,国内外学者发展了超临界空气储能系统,它利用空气的超临界条件下的性质,解决传统压缩空气储能存在的主要技术瓶颈。  In recent years, scholars at home and abroad have developed supercritical air energy storage systems, which use the properties of air under supercritical conditions to solve the main technical bottlenecks in traditional compressed air energy storage. the

本实用新型提出一种超超临界空气储能系统,进一步提升超临界空气储能系统的性能。  The utility model proposes an ultra-supercritical air energy storage system, which further improves the performance of the supercritical air energy storage system. the

发明内容 Contents of the invention

本实用新型的目的是公开一种超超临界空气储能/释能系统,它是新型空气储能系统,利用超超临界状态下空气的性质和系统流程创新,提升超临界空气储能系统性能,适合于各种类型电站和电网储能的配套使用。  The purpose of this utility model is to disclose an ultra-supercritical air energy storage/energy release system, which is a new type of air energy storage system, which utilizes the properties of air in the ultra-supercritical state and the innovation of the system process to improve the performance of the supercritical air energy storage system , suitable for supporting use of various types of power stations and grid energy storage. the

为达到上述目的,本实用新型的技术解决方案是:  In order to achieve the above object, the technical solution of the utility model is:

一种超超临界空气储能/释能系统,包括压缩机组、蓄热/换热器、蓄 冷/换热器、低温储罐、阀门、低温泵、涡轮机组、发电机、驱动单元,其特征在于:所述系统还包括膨胀机组,所述压缩机组将空气压缩至超超临界状态后,通过所述膨胀机组或膨胀机组和节流阀的组合将超超临界空气降温降压至液态,液态空气储存至所述低温储罐中。  An ultra-supercritical air energy storage/energy release system, including a compressor unit, a heat storage/heat exchanger, a cold storage/heat exchanger, a cryogenic storage tank, a valve, a cryogenic pump, a turbine unit, a generator, and a drive unit. It is characterized in that: the system also includes an expansion unit, after the compressor unit compresses the air to an ultra-supercritical state, the temperature and pressure of the ultra-supercritical air is reduced to a liquid state through the expansion unit or the combination of the expansion unit and a throttle valve, Liquid air is stored into the cryogenic storage tank. the

它与超临界压缩空气储能系统的显著区别在于参数更高,压力达到50~420bar,同时用膨胀机或膨胀机和节流阀的组合代替节流阀,使系统的能量密度和效率得到大幅提升。  The significant difference between it and the supercritical compressed air energy storage system is that the parameters are higher, and the pressure reaches 50-420bar. At the same time, the throttle valve is replaced by an expander or a combination of an expander and a throttle valve, which greatly improves the energy density and efficiency of the system. promote. the

本实用新型的压缩机组包括至少一台低压压缩机、至少一台高压压缩机,相互串联或集成为整体多级压缩机,每一台低压压缩机入口接空气源,压缩系统串联至少一台膨胀机以降低气体温度,提高系统效率,膨胀机的出口接入节流阀稍微降温即可实现液化,膨胀机可以是活塞式、离心式、轴流式和组合式,膨胀机的类型和台数视系统参数而定;膨胀机和压缩机可以设计成同轴组合,也可以通过变速箱连接提供压缩动力,从而提高系统效率和经济性。系统布置如下:  The compressor unit of the utility model includes at least one low-pressure compressor and at least one high-pressure compressor, which are connected in series or integrated into a whole multi-stage compressor. The inlet of each low-pressure compressor is connected to an air source, and the compression system is connected in series with at least one expansion compressor The expansion machine can reduce the gas temperature and improve the system efficiency. The outlet of the expander is connected to the throttle valve to cool down slightly to realize liquefaction. The expander can be piston type, centrifugal type, axial flow type and combined type. The type and number of expanders depend on Depending on the system parameters; the expander and compressor can be designed as a coaxial combination, or can be connected through a gearbox to provide compression power, thereby improving system efficiency and economy. The system layout is as follows:

低压压缩机经管线、高压压缩机经管线分别与蓄热/换热器相连;存储压缩热后的高压空气经过管线进入蓄冷换热器降温后进入膨胀机进一步降温降压液化后经过管线进入低温储罐,在管线中设有阀门、至少一台低温泵,阀门位于低温泵上游;蓄冷/换热器底端设有排渣管线与排气管线;蓄热/换热器经管线分别与高压涡轮、低压涡轮相通连。  The low-pressure compressor and the high-pressure compressor are respectively connected to the heat storage/heat exchanger through the pipeline; the high-pressure air after storing the compression heat enters the cold storage heat exchanger through the pipeline to cool down, and then enters the expander for further cooling and decompression liquefaction, and then enters the low temperature through the pipeline The storage tank is equipped with a valve and at least one cryopump in the pipeline, and the valve is located upstream of the cryopump; the bottom of the cold storage/heat exchanger is provided with a slag discharge pipeline and an exhaust pipeline; the heat storage/heat exchanger is respectively connected to the high-pressure The turbine and the low-pressure turbine are connected. the

其工作流程为:储能时,利用驱动单元驱动组合式压缩机组,将一定量的空气压缩至超超临界状态,每级的压缩热被回收并存储在蓄热/换热器中;然后一定参数的超超临界空气进入蓄冷/换热器中冷却,再经过膨 胀机组膨胀降温降压转变为液态空气进入低温储罐存储,部分未液化的空气通过管线进入蓄冷换热器后排出;释能时,低温泵对液态空气加压到超超临界压力,高压液态空气在蓄冷/换热器中升温至超超临界状态并回收冷能,在蓄热/换热器中吸收压缩热使超超临界空气进一步升温,然后进入高压涡轮机与低压涡轮机组成的涡轮机组膨胀做功,带动发电机发电。  Its working process is: when storing energy, use the driving unit to drive the combined compressor unit to compress a certain amount of air to an ultra-supercritical state, and the compression heat of each stage is recovered and stored in the heat storage/heat exchanger; Parameter ultra-supercritical air enters the cold storage/heat exchanger for cooling, and then expands and cools down through the expansion unit to transform into liquid air and enters the low-temperature storage tank for storage. Part of the unliquefied air enters the cold storage heat exchanger through the pipeline and is discharged; When energy is available, the cryopump pressurizes the liquid air to an ultra-supercritical pressure, and the high-pressure liquid air is heated to an ultra-supercritical state in the cold storage/heat exchanger to recover cold energy, and the heat of compression is absorbed in the heat storage/heat exchanger to make the supercritical The supercritical air heats up further, and then enters the turbine unit composed of the high-pressure turbine and the low-pressure turbine to expand and do work, driving the generator to generate electricity. the

所述的超超临界空气储能系统,其所述驱动单元,是以电网或常规电站低谷电、核电、风电、太阳能发电、生物质发电、水电或潮汐发电其中的一种或多种为电源带动的电机。  In the ultra-supercritical air energy storage system, the drive unit is powered by one or more of grid or conventional power station low-peak power, nuclear power, wind power, solar power, biomass power, hydropower or tidal power driven motor. the

所述的超超临界空气储能系统,其储能过程在电力低谷、可再生能源限电或电能质量不符合上网要求时启用;释能过程在用电高峰、电力事故、可再生能源发电大幅波动时启用。  The ultra-supercritical air energy storage system described above, its energy storage process is activated when the power is low, renewable energy is limited, or the power quality does not meet the requirements for grid connection; Enabled when fluctuating. the

优选地,所述系统包括储能子系统和释能子系统:所述储能子系统中,所述驱动单元、压缩机组、蓄热/换热器、蓄冷/换热器、膨胀机组、低温储罐经一管线组依次顺序联通;所述释能子系统中,所述低温储罐、阀门、低温泵、蓄冷/换热器、蓄热/换热器、涡轮机组、发电机经另一管线组依次顺序联通。  Preferably, the system includes an energy storage subsystem and an energy release subsystem: in the energy storage subsystem, the drive unit, compressor unit, heat storage/heat exchanger, cold storage/heat exchanger, expansion unit, low temperature The storage tanks are sequentially connected through a pipeline group; in the energy release subsystem, the low-temperature storage tanks, valves, cryopumps, cold storage/heat exchangers, heat storage/heat exchangers, turbine units, and generators are connected through another The pipeline groups are connected sequentially. the

优选地,所述压缩机组包括至少一台低压压缩机、至少一台高压压缩机,相互串联或集成为整体多级压缩机组,其中第一级压缩机的进气口接空气源,且各级压缩机中,上一级压缩机的出气口经管线穿过所述蓄热/换热器后与下一级压缩机的进气口相连,最后一级高压压缩机的出气口经管线穿过所述蓄热/换热器和蓄冷/换热器后与所述膨胀机组的进气口联通。  Preferably, the compressor unit includes at least one low-pressure compressor and at least one high-pressure compressor, which are connected in series or integrated into an overall multi-stage compressor unit, wherein the air inlet of the first-stage compressor is connected to the air source, and each stage In the compressor, the air outlet of the upper-stage compressor passes through the heat storage/heat exchanger through the pipeline and is connected to the air inlet of the next-stage compressor, and the air outlet of the last-stage high-pressure compressor passes through the pipeline The heat storage/heat exchanger and the cold storage/heat exchanger are communicated with the air inlet of the expansion unit. the

优选地,所述涡轮机组包括至少一台低压涡轮机、至少一台高压涡轮机,相互串联或集成为整体多级涡轮机组,所述低温储罐中的液态空气经管线依次通过阀门、低温泵、蓄冷/换热器、蓄热/换热器转变为超超临界状态的空气后通入第一级中,各级涡轮机中,上一级涡轮机的出气口经管线穿过所述蓄热/换热器后依次与下一级涡轮机的进气口相连通,最后一级低压涡轮机的出气口通大气。  Preferably, the turbine unit includes at least one low-pressure turbine and at least one high-pressure turbine, which are connected in series or integrated into an overall multi-stage turbine unit, and the liquid air in the cryogenic storage tank passes through the valve, the cryopump, the cold storage tank in turn through the pipeline. /Heat exchanger, heat storage/Heat exchanger is converted into ultra-supercritical air and then passed into the first stage, turbines at all levels, the gas outlet of the upper stage turbine passes through the heat storage/heat exchange through the pipeline After the device, it is connected with the air inlet of the next-stage turbine in turn, and the air outlet of the last-stage low-pressure turbine is opened to the atmosphere. the

优选地,所述驱动单元与压缩机组的传动轴固接;所述膨胀机组可通过变速箱直接驱动所述压缩机组或通过另一发电机并网;所述发电机与涡轮机组的传动轴固接。  Preferably, the drive unit is fixedly connected to the transmission shaft of the compressor unit; the expansion unit can directly drive the compressor unit through a gearbox or be connected to the grid through another generator; the generator is fixed to the transmission shaft of the turbo unit catch. the

优选地,所述蓄热/换热器为绝热保温容器,蓄热介质储存在容器中,超超临界空气在其中与蓄热介质直接接触换热或非直接接触换热,蓄热方式为显热、潜热蓄热中的一种或组合;所述蓄热/换热器还设有与外界热源相联通的管线;所述蓄冷/换热器为绝热保温容器,蓄冷介质存储在容器中,超超临界空气或液态空气在其中与蓄冷介质直接接触换热或非直接接触换热,其蓄冷形式是显热蓄冷或固液相变蓄冷中的一种或组合;蓄冷/换热器底端设有排渣管线。  Preferably, the heat storage/heat exchanger is an insulated container, in which the heat storage medium is stored, and the ultra-supercritical air exchanges heat with the heat storage medium in direct contact or non-direct contact. One or a combination of heat and latent heat storage; the heat storage/heat exchanger is also provided with a pipeline connected to an external heat source; the cold storage/heat exchanger is an insulated container, and the cold storage medium is stored in the container. The ultra-supercritical air or liquid air is in direct contact or non-direct contact heat exchange with the cold storage medium, and the cold storage form is one or a combination of sensible heat storage or solid-liquid phase change cold storage; the bottom of the cold storage/heat exchanger There is a slag discharge pipeline. the

所述的超超临界空气储能系统,其压缩流程包括至少一台膨胀机,用于使压缩空气降温降压便于液化并回收膨胀功,提高系统效率。  The compression process of the ultra-supercritical air energy storage system includes at least one expander, which is used to reduce the temperature and pressure of the compressed air for liquefaction and recovery of expansion work to improve system efficiency. the

所述的超超临界空气储能系统,其所述蓄热/换热器还设有管线,该管线与外界热源相通连,外界热源可以是太阳能集热器、工业余热和各类废热。所述余热、废热,为电厂、水泥行业、钢铁冶金行业、化工行业的余热、废热;余热、废热可储存在蓄热/换热器中,也可以存储在专用的 蓄热/换热器中。  In the ultra-supercritical air energy storage system, the heat storage/heat exchanger is also provided with a pipeline, which is connected to an external heat source. The external heat source can be a solar collector, industrial waste heat and various types of waste heat. The waste heat and waste heat mentioned above are the waste heat and waste heat of power plants, cement industry, iron and steel metallurgy industry and chemical industry; waste heat and waste heat can be stored in heat storage/heat exchanger, or can be stored in special heat storage/heat exchanger . the

所述的超超临界空气储能系统,其空气压缩、冷却过程中还包括空气净化与纯化,除去空气中的固体物及杂质气体;空气净化与纯化设备集成在压缩机组及蓄冷/换热器中,不单独表示。  The ultra-supercritical air energy storage system, the air compression and cooling process also includes air purification and purification to remove solids and impurity gases in the air; the air purification and purification equipment is integrated in the compressor unit and the cold storage/heat exchanger , not represented separately. the

所述的超超临界空气储能系统,其所述压缩机组;当为多台压缩机时,多台压缩机为共轴串联形式、或分轴并联形式;并联形式中,各分轴与主驱动轴动连接;各级压缩机的排气均经过蓄热/换热器冷却降温。  The ultra-supercritical air energy storage system, the compressor unit; when there are multiple compressors, the multiple compressors are in the form of coaxial series connection or sub-shaft parallel connection; The drive shaft is dynamically connected; the exhaust gas of the compressors at all levels is cooled by the heat storage/heat exchanger. the

所述的超超临界空气储能系统,其所述涡轮机组,总膨胀比在50~420之间,末级涡轮机排气接近常压;当为多台涡轮机时,多台涡轮机为共轴串联形式、或分轴并联形式;并联形式中,各分轴与主驱动轴动连接;各级涡轮机的进气均先经过蓄热/换热器加热升温。  In the ultra-supercritical air energy storage system, the total expansion ratio of the turbine unit is between 50 and 420, and the exhaust gas of the final stage turbine is close to normal pressure; when there are multiple turbines, the multiple turbines are coaxial and connected in series In the parallel connection mode, each sub-shaft is dynamically connected with the main drive shaft; the intake air of the turbines at all levels is first heated by the heat storage/heat exchanger. the

所述的超超临界空气储能系统,其所述压缩机可以是活塞式、离心式、轴流式、螺杆式或组合式;其所述膨胀机和涡轮机,可以是活塞式、轴流式、向心式、螺杆式或混合式。  In the ultra-supercritical air energy storage system, the compressor can be piston type, centrifugal type, axial flow type, screw type or combined type; the expander and turbine can be piston type, axial flow type , centripetal, screw or mixed. the

所述的超超临界空气储能系统,其所述在多台压缩机、多台膨胀机/涡轮机时,多台压缩机、多台膨胀机/涡轮机分布在一根驱动轴或多根驱动轴上,通过变速箱连接。  In the ultra-supercritical air energy storage system, when there are multiple compressors and multiple expanders/turbines, the multiple compressors and multiple expanders/turbines are distributed on one drive shaft or multiple drive shafts on, connected through the gearbox. the

所述的超超临界空气储能系统,其工作空气的流量不受压缩空气流量的限制。  In the ultra-supercritical air energy storage system, the flow of working air is not limited by the flow of compressed air. the

所述的超超临界空气储能系统,其所述蓄热/换热器的蓄热形式是显热、潜热或化学反应热中的一种或几种;采用的蓄热介质是水、石蜡、生物质油、无机类结晶水合盐、熔融盐、金属及其合金、有机类脂肪酸、石 头、岩石或混凝土,蓄热介质储存在绝热容器中;  In the ultra-supercritical air energy storage system, the heat storage form of the heat storage/heat exchanger is one or more of sensible heat, latent heat or chemical reaction heat; the heat storage medium used is water, paraffin wax , biomass oil, inorganic crystalline hydrated salt, molten salt, metals and their alloys, organic fatty acids, stones, rocks or concrete, and the heat storage medium is stored in an insulated container;

其中,蓄热/换热器,储能时,回收并储存压缩机产生的压缩热,释能时,加热进各级膨胀机前的压缩空气;释能时还可经管线输进余热、废热为蓄热/换热器补充热量。  Among them, the heat storage/heat exchanger, when storing energy, recovers and stores the compression heat generated by the compressor, and when releasing energy, heats the compressed air before the expanders at all levels; when releasing energy, waste heat and waste heat can also be input through pipelines Supplement heat for heat storage/exchanger. the

所述的超超临界空气储能系统,其所述蓄冷/换热器,将超超临界空气冷却至81K-150K(K为开氏温度单位),是显热蓄冷或固液相变蓄冷中的一种或组合;采用的显热蓄冷介质,是密封冰球、沙石子、混凝土、铝带盘或其它金属物质中的一种或几种;固液相变蓄冷介质,是固液相变温度在81K~273K之间的氨及其水溶液、盐类水溶液、烷烃类、烯烃类物质及其化合物,醇类及其水溶液中的一种或几种,蓄冷介质存储在绝热容器中;超超临界空气或液态空气在蓄冷/换热器中与蓄冷介质直接接触换热或非直接接触换热;储能时,蓄冷/换热器对超超临界空气进行进一步冷却便于液化,释能时,蓄冷/换热器回收并储存高压液态空气升温过程中的冷量。  In the ultra-supercritical air energy storage system, the cold storage/heat exchanger cools the ultra-supercritical air to 81K-150K (K is the Kelvin temperature unit), which is used in sensible heat storage or solid-liquid phase change storage One or a combination; the sensible heat storage medium used is one or more of sealed ice balls, sand and gravel, concrete, aluminum tape or other metal substances; the solid-liquid phase change cold storage medium is a solid-liquid phase change One or more of ammonia and its aqueous solution, salt solution, alkanes, olefins and their compounds, alcohols and their aqueous solutions at a temperature between 81K and 273K, and the cold storage medium is stored in an insulated container; The critical air or liquid air is in direct contact or non-direct contact heat exchange with the cold storage medium in the cold storage/heat exchanger; when storing energy, the cold storage/heat exchanger further cools the ultra-supercritical air for liquefaction, and when releasing energy, The cold storage/heat exchanger recovers and stores the cold energy during the heating process of high-pressure liquid air. the

所述的超超临界空气储能系统,其所述蓄冷/换热器,在低温冷量不足时,加装有节流装置使得接近液化点的空气稍微降温降压后即可液化进入储罐。节流装置也有可能被取消。  In the ultra-supercritical air energy storage system, the cold storage/heat exchanger is equipped with a throttling device when the low-temperature cooling capacity is insufficient, so that the air close to the liquefaction point can be liquefied and enter the storage tank after being slightly lowered in temperature and pressure. . Throttles are also likely to be removed. the

所述的超超临界空气储能系统,其所述低温储罐,为杜瓦储罐或低温储槽,液态空气在常压或带一定压力状况下储存。  In the ultra-supercritical air energy storage system, the low-temperature storage tank is a Dewar storage tank or a low-temperature storage tank, and liquid air is stored under normal pressure or under a certain pressure. the

所述的超超临界空气储能系统,其所述低温泵,为往复式,离心式或混合式,将液态空气增压至5.0MPa~42MPa;当多台时,是多级串联或并联。  In the ultra-supercritical air energy storage system, the cryopumps are reciprocating, centrifugal or hybrid, and pressurize the liquid air to 5.0MPa-42MPa; when there are multiple sets, they are connected in series or parallel in multiple stages. the

所述的超超临界空气储能系统,其储能时,通过控制第一级压缩机进气量来调节储能能力。所述的超超临界空气储能系统,其所述控制第一级压缩机进气量,是通过调节压缩机负载、阀门开度、驱动转速、开停部分压缩机或调节压比来实现进气量的控制。其释能时,通过控制液态空气气化量来调节发电能力。  In the ultra-supercritical air energy storage system, when storing energy, the energy storage capacity is adjusted by controlling the intake air volume of the first-stage compressor. In the ultra-supercritical air energy storage system, the control of the air intake of the first-stage compressor is achieved by adjusting the load of the compressor, the opening of the valve, the driving speed, starting and stopping some compressors, or adjusting the pressure ratio. Gas volume control. When releasing energy, the power generation capacity is adjusted by controlling the vaporization amount of liquid air. the

本实用新型的优点在于:储能效率比超临界空气系统提高4~7个百分点、储能密度比超临界空气系统提高30%以上。同时储能周期不受限制、适用于各种类型电站、对环境友好、可回收废热,不需要大的储存装置,提高了土地和资源使用效率,具有广阔的使用前景。  The utility model has the advantages that the energy storage efficiency is 4-7 percentage points higher than that of the supercritical air system, and the energy storage density is 30% higher than that of the supercritical air system. At the same time, the energy storage cycle is unlimited, applicable to various types of power stations, environmentally friendly, waste heat can be recovered, and no large storage devices are required, which improves the efficiency of land and resource use and has broad application prospects. the

附图说明 Description of drawings

图1为本实用新型的超超临界空气储能/释能系统实施例1结构示意图;  Fig. 1 is the structural schematic diagram of Embodiment 1 of the ultra-supercritical air energy storage/energy release system of the present utility model;

图2为本实用新型的超超临界空气储能/释能系统实施例2结构示意图。  Fig. 2 is a structural schematic diagram of Embodiment 2 of the ultra-supercritical air energy storage/energy release system of the present invention. the

具体实施方式 Detailed ways

为使本实用新型的目的、技术方案及优点更加清楚明白,以下参照附图并举实施例,对本实用新型进一步详细说明。  In order to make the purpose, technical solutions and advantages of the utility model clearer, the utility model will be further described in detail below with reference to the accompanying drawings and examples. the

本实用新型的超超临界空气储能/释能系统,采用电站低谷(低价)电能将空气压缩至超超临界状态(同时存储压缩热),然后利用膨胀机使空气降温降压同时回收膨胀功提高效率,并利用已存储的冷能将压缩空气冷却、液化并存储(储能);在用电高峰,液态空气加压吸热至超超临界状态(同时液态空气中的冷能被回收存储),并进一步吸收存储的压缩热后通过涡轮 机组驱动发电机发电(释能),在此过程中一些工业废热可以被回收以提高系统效率。本实用新型提出的超超临界空气储能系统具有储能效率高的突出优点,由于采用优化流程和更高参数,系统效率可比超临界空气储能系统更高,初步估算可达70%以上,储能密度提高约30%~50%、储能周期不受限制、储存装置大幅减小、适用各种类型电站、对环境友好、可回收各种工业废热等优点。  The ultra-supercritical air energy storage/energy release system of the utility model uses the power station's trough (low price) electric energy to compress the air to an ultra-supercritical state (while storing compression heat), and then uses an expander to cool down and depressurize the air while recovering the expansion use the stored cold energy to cool, liquefy and store the compressed air (energy storage); at the peak of power consumption, the liquid air is pressurized to absorb heat to an ultra-supercritical state (while the cold energy in the liquid air is recovered Storage), and after further absorbing the stored compression heat, drive the generator to generate electricity (energy release) through the turbine unit, during which some industrial waste heat can be recovered to improve system efficiency. The ultra-supercritical air energy storage system proposed by the utility model has the outstanding advantage of high energy storage efficiency. Due to the use of optimized processes and higher parameters, the system efficiency can be higher than that of the supercritical air energy storage system, and the preliminary estimate can reach more than 70%. The energy storage density is increased by about 30% to 50%, the energy storage period is not limited, the storage device is greatly reduced, it is suitable for various types of power stations, it is environmentally friendly, and various industrial waste heat can be recycled. the

实施例:  Example:

图1为本实用新型的超超临界空气储能/释能系统实施例1。包括低压压缩机1、3,蓄热/换热器2,高压压缩机35、38,膨胀机40(至少一级)、蓄冷/换热器4,低温储罐6,阀门7,低温泵8,高压涡轮9、10,低压涡轮43、46,发电机11,驱动单元12,管线13、14、15、16、17、18、19、20、21、22、23、24、30、31、34、36、37、39、41、42、44、45等,及空气A。  Fig. 1 is the embodiment 1 of the ultra-supercritical air energy storage/energy release system of the present invention. Including low-pressure compressors 1, 3, heat storage/heat exchanger 2, high-pressure compressors 35, 38, expander 40 (at least one stage), cold storage/heat exchanger 4, cryogenic storage tank 6, valve 7, cryopump 8 , high-pressure turbines 9, 10, low-pressure turbines 43, 46, generator 11, drive unit 12, pipelines 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 30, 31, 34, 36, 37, 39, 41, 42, 44, 45, etc., and Air A. the

驱动单元12与压缩机1、3、35、38的共有传动轴固接,发电机11与涡轮机9、10、43、46的共有传动轴固接。低压压缩机1、3经管线13、14、15,高压压缩机35、38经管线34、36、37、39分别与蓄热/换热器2相连。低压压缩机1入口接空气A。经过蓄热/换热器的超超临界空气经管线16通过蓄冷换热器4冷却,再经过膨胀机40做功并降温降压后液化。蓄热/换热器2、蓄冷/换热器4、低温储罐6经管线16、30、31、18、19顺序相连。在管线31中设有阀门7、低温泵8,阀门7位于低温泵8上游。蓄热/换热器2经管线20、21、22分别与高压涡轮9、10相连,经过41、42、44、45分别与低压涡轮43、46相连。低压涡轮46的气体出口通大气。  The driving unit 12 is fixedly connected to the common transmission shafts of the compressors 1, 3, 35, 38, and the common transmission shafts of the generator 11 and the turbines 9, 10, 43, 46 are fixedly connected. Low-pressure compressors 1 and 3 are connected to heat storage/heat exchanger 2 through pipelines 13, 14 and 15, and high-pressure compressors 35 and 38 are connected to heat storage/heat exchanger 2 through pipelines 34, 36, 37 and 39, respectively. The inlet of low-pressure compressor 1 is connected with air A. The ultra-supercritical air passing through the heat storage/heat exchanger is cooled by the cold storage heat exchanger 4 through the pipeline 16, and then liquefied after being cooled by the expander 40 to perform work. The heat storage/heat exchanger 2 , the cold storage/heat exchanger 4 , and the low-temperature storage tank 6 are connected in sequence through pipelines 16 , 30 , 31 , 18 , and 19 . A valve 7 and a cryopump 8 are provided in the pipeline 31 , and the valve 7 is located upstream of the cryopump 8 . Heat storage/heat exchanger 2 is connected to high-pressure turbines 9 and 10 through pipelines 20 , 21 and 22 , and connected to low-pressure turbines 43 and 46 through pipelines 41 , 42 , 44 and 45 . The gas outlet of the low-pressure turbine 46 leads to the atmosphere. the

蓄热/换热器2经管线23与外界热源相通连。蓄冷/换热器4底端设有排渣管线24。  The heat storage/heat exchanger 2 communicates with an external heat source through a pipeline 23 . A slag discharge pipeline 24 is provided at the bottom of the cold storage/heat exchanger 4 . the

储能时,低谷(低价)电能驱动驱动单元12带动压缩机组,净化后的空气A进入压缩机组进行逐级压缩、通过蓄热/换热器2与蓄热介质换热存储压缩热,实现中间冷却,直至进入高压压缩机38被压缩至超超临界状态,经管线39将超超临界空气再输送到蓄热/换热器2存储压缩热,冷却至一定温度的超超临界空气进入蓄冷/换热器4被蓄冷介质进一步冷却至较低温度,进入低温膨胀机40(至少一级)膨胀做功,降温降压后液化,液态空气经管线30储存在低温储罐6中。释能时,打开阀门7,低温泵8将来自低温储罐6的液态空气增压到超超临界压力后,由管线18输送至蓄冷/换热器4与蓄冷介质换热并气化,同时回收冷量,出蓄冷/换热器4的超超临界空气再经由管线19进入蓄热/换热器2进一步升温,温度升高后的超超临界空气通过管线注入高压涡轮机组膨胀做功,涡轮出口空气继续进入蓄热/换热器2吸热升温进入下一级涡轮膨胀做功,直至经过末级涡轮做功完毕,乏气排向大气。涡轮机组带动发电机11发电。  During energy storage, low valley (low price) electric energy drives the drive unit 12 to drive the compressor unit, and the purified air A enters the compressor unit for step-by-step compression, and exchanges heat with the heat storage medium through the heat storage/heat exchanger 2 to store the compression heat, realizing Intermediate cooling until it enters the high-pressure compressor 38 and is compressed to an ultra-supercritical state. The ultra-supercritical air is sent to the heat storage/heat exchanger 2 through the pipeline 39 to store the compression heat. The ultra-supercritical air cooled to a certain temperature enters the cold storage / The heat exchanger 4 is further cooled to a lower temperature by the cold storage medium, enters the low-temperature expander 40 (at least one stage) to expand and perform work, and is liquefied after cooling down and depressurizing. The liquid air is stored in the low-temperature storage tank 6 through the pipeline 30 . When releasing the energy, open the valve 7, and the cryopump 8 pressurizes the liquid air from the cryogenic storage tank 6 to an ultra-supercritical pressure, and then transports it to the cold storage/heat exchanger 4 through the pipeline 18 to exchange heat with the cold storage medium and gasify it. The cooling capacity is recovered, and the ultra-supercritical air exiting the cold storage/heat exchanger 4 enters the heat storage/heat exchanger 2 through the pipeline 19 to further raise the temperature. The outlet air continues to enter the heat storage/heat exchanger 2 to absorb heat and heat up, enter the next stage turbine to expand and do work, until the work done by the final stage turbine is completed, and the exhausted air is discharged to the atmosphere. The turbine set drives the generator 11 to generate electricity. the

一般情况下,储能与释能过程不同时运行。储能时,压缩机组和膨胀机工作,涡轮发电机组、低温泵8关停,阀门7关闭,蓄热/换热器2回收、储存压缩热,同时冷却工作气体,蓄冷/换热器4释放冷量,将超超临界空气冷却至低温。释能时则相反,压缩机组和膨胀机关停,涡轮机组、低温泵8工作,阀门7开启,蓄冷/换热器4回收、储存冷量,同时高压液态空气升温至超超临界状态,蓄热/换热器2则释放压缩热,进一步提升超超临界空气温度。另外,太阳能、余热、废热等外界热量则可以随时 经由管线23进入蓄热/换热器2进行储存,也可以存储在一个独立的蓄热/换热器中(图中未画出);超超临界空气进入蓄冷/换热器4冷却,这一过程中分离出的杂质和污染物可通过管线24排出。  In general, the energy storage and energy release processes do not run simultaneously. When storing energy, the compressor unit and the expander work, the turbine generator unit and the cryopump 8 are shut down, the valve 7 is closed, the heat storage/heat exchanger 2 recovers and stores the compression heat, and at the same time cools the working gas, and the cold storage/heat exchanger 4 releases it Cooling capacity, which cools the ultra-supercritical air to a low temperature. The opposite is true when the energy is released, the compressor unit and the expansion unit stop, the turbine unit and the cryopump 8 work, the valve 7 opens, the cold storage/heat exchanger 4 recovers and stores cold energy, and at the same time, the high-pressure liquid air heats up to an ultra-supercritical state, heat storage /Heat exchanger 2 releases the heat of compression to further increase the temperature of the ultra-supercritical air. In addition, external heat such as solar energy, waste heat, and waste heat can enter the heat storage/heat exchanger 2 through the pipeline 23 for storage at any time, or can be stored in an independent heat storage/heat exchanger (not shown in the figure); The supercritical air enters the cold storage/heat exchanger 4 for cooling, and the impurities and pollutants separated during this process can be discharged through the pipeline 24 . the

图2为本实用新型的超超临界空气储能/释能系统实施例2。其结构同实施例1基本相同,但在低温膨胀机后增加节流阀48。经过蓄冷换热器4冷却后的超超临界空气,在膨胀机40做功并降温降压后进入经过节流阀48进一步液化。其他工作流程同实施例1类似。  Figure 2 is Embodiment 2 of the ultra-supercritical air energy storage/energy release system of the present invention. Its structure is basically the same as that of Embodiment 1, but a throttle valve 48 is added after the low-temperature expander. The ultra-supercritical air cooled by the cool-storage heat exchanger 4 enters the throttle valve 48 for further liquefaction after the expander 40 performs work and lowers the temperature and pressure. Other workflows are similar to Example 1. the

以上所述仅为本实用新型的较佳实施例而已,并不用以限制本实用新型,凡在本实用新型的精神和原则之内,所做的任何修改、等同替换、改进等,均应包含在本实用新型的范围之内。  The above descriptions are only preferred embodiments of the present utility model, and are not intended to limit the present utility model. Any modifications, equivalent replacements, improvements, etc. within the spirit and principles of the present utility model shall include Within the scope of the present utility model. the

Claims (10)

1. ultra supercritical air energy storage/release can system, comprise compressor bank (1,3,35,38), accumulation of heat/heat exchanger (2), cold-storage/heat exchanger (4), low-temperature storage tank (6), valve (7), cryopump (8), turbines (9,10,43,46), generator (11), driver element (12), it is characterized in that:
Described system also comprises expansion unit (40), described compressor bank (1,3,35,38) with air compressing to the ultra supercritical state, combination by described expansion unit (40) or expansion unit (40) and throttle valve (48) is depressurized to liquid state with the ultra supercritical air cooling-down, and liquid air is stored in the described low-temperature storage tank (6).
2. ultra supercritical air according to claim 1 energy storage/release can system, it is characterized in that: described system comprises the energy storage subtense angle and releases the energy subtense angle: in the described energy storage subtense angle, described driver element (12), compressor bank (1,3,35,38), accumulation of heat/heat exchanger (2), cold-storage/heat exchanger (4), expansion unit (40), low-temperature storage tank (6) are through a pipeline group (13,14,15,34,36,37,39,16,30) successively order UNICOM; Described releasing in the energy subtense angle, described low-temperature storage tank (6), valve (7), cryopump (8), cold-storage/heat exchanger (4), accumulation of heat/heat exchanger (2), turbines (9,10,43,46), generator (11) are through another pipeline group (31,18,19,20,21,22,41,42,44,45) successively order UNICOM.
3. ultra supercritical air according to claim 1 and 2 energy storage/release can system, it is characterized in that: described compressor bank (1,3,35,38) comprise at least one low pressure compressor (1), at least one high pressure compressor (35), mutually connect or be integrated into whole multistage compression unit, wherein the suction port of first order compressor connects air-source, and in each stage compressor, the air outlet of upper level compressor links to each other with the suction port of next stage compressor after pipeline passes described accumulation of heat/heat exchanger (2), and the air outlet of afterbody high pressure compressor (38) is through pipeline (39,16) pass behind described accumulation of heat/heat exchanger (2) and the cold-storage/heat exchanger (4) and the suction port UNICOM of described expansion unit (40).
4. ultra supercritical air according to claim 1 and 2 energy storage/release can system, it is characterized in that: described turbines (9,10,43,46) comprise at least one low-pressure turbine (46), at least one high pressure turbine (10), mutually connect or be integrated into whole multistage turbine unit, liquid air in the described low-temperature storage tank (6) passes through valve (7) successively through pipeline, cryopump (8), cold-storage/heat exchanger (4), accumulation of heat/heat exchanger (2) passes in the first order after changing the air of ultra supercritical state into, in each stage turbine, the air outlet of upper level turbo machine is connected with the suction port of next stage turbo machine after pipeline passes described accumulation of heat/heat exchanger (2) successively, and the air outlet of afterbody low-pressure turbine (46) leads to atmosphere.
5. ultra supercritical air according to claim 1 energy storage/release the energy system, it is characterized in that: described driver element (12) is affixed with the transmission shaft of compressor bank (1,3,35,38); Described expansion unit (40) can directly drive described compressor bank (1,3,35,38) or pass through another generator connecting in parallel with system by gearbox; Described generator (11) is affixed with the transmission shaft of turbines (9,10,43,46).
6. ultra supercritical air according to claim 1 energy storage/release the energy system, it is characterized in that: described low-temperature storage tank (6) is Dewar storage tank or low temperature storing tank, liquid air stores under normal pressure or band certain pressure situation.
7. ultra supercritical air according to claim 1 energy storage/release can system, it is characterized in that: described accumulation of heat/heat exchanger (2) is heat-insulating container, heat storage medium is stored in the container, the ultra supercritical air therein with heat storage medium direct contact heat transfer or non-direct contact heat transfer, heat storage type is a kind of in sensible heat, the latent-heat storage or combination; Described accumulation of heat/heat exchanger (2) also is provided with the pipeline (23) that links with extraneous thermal source; Described cold-storage/heat exchanger (4) is heat-insulating container, cool storage medium is stored in the container, ultra supercritical air or liquid air therein with cool storage medium direct contact heat transfer or non-direct contact heat transfer, its cold-storage form is a kind of in sensible heat cold-storage or the solid-liquid phase change cold-storage or combination; Cold-storage/heat exchanger (4) bottom is provided with deslagging pipeline (24).
8. ultra supercritical air according to claim 1 energy storage/release the energy system, it is characterized in that: described cryopump (8) is pressurized to 5.0MPa~42MPa for reciprocating type, centrifugal or hybrid with liquid air; In the time of many, be plural serial stage or parallel connection.
9. ultra supercritical air according to claim 1 energy storage/release can system, it is characterized in that: described driver element (12) is the motor that drives with electrical network or conventional power plant trough-electricity, nuclear power, wind-powered electricity generation, solar electrical energy generation, biomass power generation, water power or tidal power generation one or more power supplys wherein.
10. ultra supercritical air according to claim 1 energy storage/release can system, it is characterized in that: described accumulation of heat/heat exchanger (2), the heat storage medium of employing are water, paraffin, bio-oil, mineral-type crystalline hydrate salt, fuse salt, metal or its alloy, organic fatty acid, stone, rock or concrete; Described cold-storage/heat exchanger (4) adopts sensible heat cool storage medium or solid-liquid phase change cool storage medium, and described sensible heat cool storage medium is sealing ice hockey, sandstone, concrete or aluminium strip dish.
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