CN201728054U - Device for alkali-based desulfurization of exhausted smoke on ship - Google Patents
Device for alkali-based desulfurization of exhausted smoke on ship Download PDFInfo
- Publication number
- CN201728054U CN201728054U CN2010202487438U CN201020248743U CN201728054U CN 201728054 U CN201728054 U CN 201728054U CN 2010202487438 U CN2010202487438 U CN 2010202487438U CN 201020248743 U CN201020248743 U CN 201020248743U CN 201728054 U CN201728054 U CN 201728054U
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- Prior art keywords
- alkali
- separator
- boats
- pipes
- ships
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 239000003513 alkali Substances 0.000 title claims abstract description 36
- 239000000779 smoke Substances 0.000 title claims abstract description 8
- 238000006477 desulfuration reaction Methods 0.000 title abstract description 12
- 230000023556 desulfurization Effects 0.000 title abstract description 7
- 239000013505 freshwater Substances 0.000 claims abstract description 10
- 238000005507 spraying Methods 0.000 claims abstract description 6
- 239000010802 sludge Substances 0.000 claims abstract description 5
- 238000005201 scrubbing Methods 0.000 claims description 19
- 239000007921 spray Substances 0.000 claims description 7
- 238000005406 washing Methods 0.000 abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 13
- 238000007599 discharging Methods 0.000 abstract description 6
- 239000003344 environmental pollutant Substances 0.000 abstract description 5
- 231100000719 pollutant Toxicity 0.000 abstract description 5
- 206010022000 influenza Diseases 0.000 abstract 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 33
- 239000000243 solution Substances 0.000 description 13
- 238000004140 cleaning Methods 0.000 description 11
- 239000003546 flue gas Substances 0.000 description 11
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 10
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 10
- 239000003921 oil Substances 0.000 description 8
- 239000013535 sea water Substances 0.000 description 8
- 239000007788 liquid Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 238000001816 cooling Methods 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 239000000295 fuel oil Substances 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000003517 fume Substances 0.000 description 2
- 239000012510 hollow fiber Substances 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 238000012544 monitoring process Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 235000019628 coolness Nutrition 0.000 description 1
- 239000008358 core component Substances 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000003009 desulfurizing effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 239000010705 motor oil Substances 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical compound S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
- 229910052815 sulfur oxide Inorganic materials 0.000 description 1
- 230000000153 supplemental effect Effects 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
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- Treating Waste Gases (AREA)
Abstract
The utility model relates to the technical field of the protection of atmospheric environment, in particular to a device for the alkali-based desulfurization of exhausted smoke on a ship. The device comprises an engine/oil-fired boiler on the ship, wherein the device is structurally characterized in that the exhaust of the engine/oil-fired boiler is connected to a washing tower via flues; a spraying layer connected with alkali liquor supplying pipes is arranged in the washing tower; a fresh water supplying unit is connected to the lower part of the washing tower via pipes; the outlet at the bottom of the washing tower is connected to the alkali liquor supplying pipes via a buffer tank, a pump and a heat exchanger sequentially; the outlet of the heat exchanger is connected with the inlet of a separator; two outlets of the separator are respectively connected with discharging pipes and sludge tanks; and an alkali liquor supplying unit is connected with the alkali liquor supplying pipes. Compared with the prior art, the utility model achieves the high efficiency of desulfurization under the condition that the water consumption is lower and has the characteristics of small occupied space and low cost. Therefore, the device of the utility model is applicable to the desulfurization of oil-fired boilers or ships sailing or traveling in various sea areas and pollutant control areas.
Description
Technical field
The utility model relates to the atmospheric environment protection technical field, particularly boats and ships is discharged fume and carries out the device of alkali desulphurization.
Background technology
The sulfur dioxide of boats and ships reduces discharging the execution along with 73/78 supplemental provisions V I of International Maritime Organization, is paid close attention to by more and more countries.The shipping business in the whole world, have the engine of a large amount of use poor oils or the boats and ships of oil burning boiler, if, will cause the significantly raising of shipping business financial cost according to the standard of low sulfur content fuel oil, then under the prerequisite that guarantees sulfur dioxide (SO2) emissions, it is less to make that cost improves for the employing flue gases purification.
In the prior art, the main technology that removes the boats and ships flue gas pollutant has:
1. Chinese patent application number is 200710012371.1, name is called " a kind of apparatus and method of ship tail gas being carried out the seawer washing processing ", it is in the hollow fiber membrane contactors as washer, the ship tail gas later to dedusting uses Seawater Treatment, by SO2 concentration monitor, water quality monitor and PLC forming control system.There is following problems in this technology: washer is realized washing function with hollow fiber membrane contactors, and pressure drop and resistance are very big, set up booster fan, has improved the investment and the operating cost of system.
2. mention the research report of colleges and universities' associating foundations such as masschusetts, u.s.a science and engineering, Tokyo Univ Japan " seawer washing-minimizing is from the SOx of marine exhaust discharging " that " seawer washing is a kind of up-and-coming technology to reducing from the oxysulfide of boats and ships discharging.The calculating basis of this article is the 12MW engine, and fuel oil sulfur content 3% obtains different desulfuration efficiencies after using sea water desulfuration, during different water temperature, and 6 water yields that dissimilar waters is required." this research still is in the technological principle exploratory stage, is faced with the low and big problem of the dilution water yield of absorption efficiency.；
3.MES the Ecosilencer seawer washing device of company's utility model, its core component washer adopts U.S. Patent number US7056367, title " is utilized the method and apparatus of hybrid blade washing gas ", it is the bubble cleaning mode that this washer adopts " exhaust feeds in the cleaning solution of pond ", cooling and washing absorption to high-temperature flue gas are born by same pond water body simultaneously, mass-transfer efficiency is low, the raising of absorption efficiency must strengthen the washing water yield and intensified pressure loss, to cause energy consumption and operating cost to increase, and exist cooling down high-temperature flue gas and low temperature absorption sulfur dioxide conflicting.
4. Chinese patent 200810048002, and title " desulfurizing exhaust gas of seagoing vessel method and device " is used the material filling type washer that the flue gas of seagoing vessel engine is carried out desulfurization and handled, and it is big to have a washer diameter, and equipment occupation space is big, problems such as cost height.
5. marine diesel giant
The alkali liquid washing technology of company, volume is big, and equipment is many, and is newly-built all very high with improvement cost.
In the above-mentioned prior art, the use that has the method for seawer washing, boats and ships are endless to be provided though seawater can be, and in order to raise the efficiency, needs high flowing seawater that enough basicity is provided, the seawater consumption is very big.
Above prior art also faces following common problem:
(1) in the present circumstance, its cost of environmental requirement that satisfy the discharging of fume emission and seawater is difficult to accept; If drainage condition further improves, its cost will continue to increase.
(2) device takes up room greatly, to the transformation difficulty of spot ship.
(3) can not satisfy boats and ships in variant sea area, every environmental condition of different pollutants control zone.
Summary of the invention
In order to solve the problem that above-mentioned prior art exists, the purpose of this utility model provides a kind of device to boats and ships smoke evacuation carrying out alkali desulphurization.It can satisfy very high desulfuration efficiency under the smaller situation of water consumption, have the advantages that space hold is little, cost is low, is applicable to boats and ships or oil burning boiler desulfurization that the navigation of different sea areas and pollutant control interval is moved.
In order to reach the foregoing invention purpose, the technical solution of the utility model realizes as follows:
A kind of device to boats and ships smoke evacuation carrying out alkali desulphurization, it comprises the engine/oil burning boiler on the boats and ships.Its design feature is, the exhaust of described engine/oil burning boiler is connected to scrubbing tower through flue, is provided with the spraying layer that is connected with the alkali lye service in the washing Tata, and fresh water supply unit is connected to the bottom of scrubbing tower by pipeline.The wash tower bottoms outlet is connected to the alkali lye service through baffle-box, pump and heat exchanger successively, and the outlet of heat exchanger also links to each other with the inlet of separator, and two outlets of separator connect discharge tube and sludge tank respectively.Alkali lye supply unit is connected with the alkali lye service.
In the device of above-mentioned alkali desulphurization, described spray thrower adopts one-level or multi-stage spray layer.
In the device of above-mentioned alkali desulphurization, described separator adopts one-level or multistage cyclone separator.
With prior art relatively, advantage of the present utility model is:
1) used heat exchanger, the cleaning solution temperature is reduced, this will reduce the scrubbing tower exit gas temperature, and it is minimum that water evaporates is dropped to.
2) scrubbing tower uses the spray mode, and its reaction speed is fast, and the gas-liquid contact-making surface is big, helps SO
2Absorption and reaction, velocity of flue gas height simultaneously, resistance is little, the sectional area of scrubbing tower is little, whole scrubbing tower takes up room little.
3) utilize one or more levels cyclone separator, the solids such as soot dust granule that cleaning solution washs out are separated, make cleaning solution reach discharge standard.
4) cleaning solution is an alkali lye, and alkali liquid washing can provide the desulfuration efficiency of superelevation, compares the expense cost of Low Sulfur Fuel Oil and saves greatly.Because the desulfuration efficiency height, the alkali lye consumption is few, compares the seawer washing water consumption and significantly reduces, and needs additional fresh water seldom.
The utility model is described in further detail below in conjunction with the drawings and specific embodiments.
Description of drawings
Fig. 1 is the structural representation of the utility model device;
Fig. 2 is the method flow diagram of the utility model work.
The specific embodiment
Referring to Fig. 1, the exhaust of the engine/oil burning boiler 1 in the utility model on the boats and ships is connected to scrubbing tower 3 through flue 2.Be provided with the spraying layer 4 that is connected with the alkali lye service in scrubbing tower 3 towers, spraying layer 4 adopts one-level or multi-stage spray layer.Fresh water supply unit 13 is connected to the bottom of scrubbing tower 3 by pipeline.Scrubbing tower 3 outlet at bottoms are connected to the alkali lye service through baffle-box 6, pump 7 and heat exchanger 8 successively, the outlet of heat exchanger 8 also links to each other with the inlet of the separator 9 that adopts one-level or multistage cyclone separator, and two outlets of separator 9 connect discharge tube 11 and sludge tank 10 respectively.The outlet of alkali lye supply unit 12 is connected to the alkali lye service.
Referring to Fig. 2, the method step of the utility model device desulfurization is:
1) washing and cooling: with the SO that contains of engine of boat and ship/oil burning boiler 1 generation
2High-temperature flue gas wash and cool off, then with the flue gas after being purified demist after chimney 5 dischargings.The discharged flue gas temperature is controlled at below the pairing water dew point temperature of engine/oil burning boiler 1 outlet raw flue gas, to reduce the consumption of fresh water.
2) cleaning solution is handled: the cleaning solution overflow of scrubbing tower 3 bottoms enters baffle-box 6, sends into heat exchanger 8 coolings with water pump 7 then, and the cooling medium in the heat exchanger 8 can be fresh water or seawater.Fresh water after the heat exchange can recycle after heat pump utilizes heat, and the seawater after the heat exchange directly discharges.A cooled cleaning solution part is sent into separator 9, and isolated solid pollutant and greasy dirt are sent into the sludge tank 10 on the ship, and the liquid after the processing enters the sea through discharge tube 11; Another part cleaning solution is sent into spraying layer spray washing flue gas in the scrubbing tower 3 through the alkali lye service, and is recycling.
3) alkali is mended in moisturizing: when the liquid level in the instrument monitoring scrubbing tower 3 is reduced to a certain degree, start water pump, add fresh water by fresh water supply unit 13 in tower, reach setting value until liquid level.When cleaning solution pH is lower than setting value in the instrument monitoring scrubbing tower 3, start lye pump, in scrubbing tower 3, add alkali lye, reach setting value until the pH value by alkali lye supply unit 12.Alkali lye is sodium hydroxide solution, sodium carbonate liquor or sodium bicarbonate solution.
Claims (3)
1. device that boats and ships smoke evacuations is carried out alkali desulphurization, it comprises the engine/oil burning boiler (1) on the boats and ships, it is characterized in that, the exhaust of described engine/oil burning boiler (1) is connected to scrubbing tower (3) through flue (2), be provided with the spraying layer (4) that is connected with the alkali lye service in scrubbing tower (3) tower, fresh water supply unit (13) is connected to the bottom of scrubbing tower (3) by pipeline, scrubbing tower (3) outlet at bottom is successively through baffle-box (6), pump (7) and heat exchanger (8) are connected to the alkali lye service, the outlet of heat exchanger (8) also links to each other with the inlet of separator (9), two outlets of separator (9) connect discharge tube (11) and sludge tank (10) respectively, and alkali lye supply unit (12) is connected with the alkali lye service.
2. the device to boats and ships smoke evacuation carrying out alkali desulphurization according to claim 1 is characterized in that described spray thrower (4) adopts one-level or multi-stage spray layer.
3. the device to boats and ships smoke evacuation carrying out alkali desulphurization according to claim 1 and 2 is characterized in that described separator (9) adopts one-level or multistage cyclone separator.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010202487438U CN201728054U (en) | 2010-07-06 | 2010-07-06 | Device for alkali-based desulfurization of exhausted smoke on ship |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010202487438U CN201728054U (en) | 2010-07-06 | 2010-07-06 | Device for alkali-based desulfurization of exhausted smoke on ship |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN201728054U true CN201728054U (en) | 2011-02-02 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010202487438U Expired - Lifetime CN201728054U (en) | 2010-07-06 | 2010-07-06 | Device for alkali-based desulfurization of exhausted smoke on ship |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN201728054U (en) |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102309912A (en) * | 2010-07-06 | 2012-01-11 | 同方环境股份有限公司 | Device and method for performing alkali desulfurization and dust removal on ship exhaust fume |
| CN102910764A (en) * | 2012-11-16 | 2013-02-06 | 江苏科技大学 | Device and method for simultaneously treating marine waste gas and waste water |
| CN103272471A (en) * | 2013-04-27 | 2013-09-04 | 高翀 | Desulfuration system and desulfuration technology therefor |
| CN103331093A (en) * | 2013-06-26 | 2013-10-02 | 哈尔滨工程大学 | Device for washing and desulfurating waste gas of marine diesel engine |
| CN103842051A (en) * | 2011-09-30 | 2014-06-04 | 阿尔法拉瓦尔股份有限公司 | Scrubber system and method |
| CN105240826A (en) * | 2015-11-16 | 2016-01-13 | 江苏昌明环保科技有限公司 | Recovery system and method for low-temperature flue gas waste heat |
| US9387438B2 (en) | 2014-02-14 | 2016-07-12 | Tenneco Automotive Operating Company Inc. | Modular system for reduction of sulphur oxides in exhaust |
| CN106277397A (en) * | 2016-08-25 | 2017-01-04 | 张赛 | A kind of mobile device that chemical plant sewage is carried out desulfurization |
| CN109316936A (en) * | 2018-11-06 | 2019-02-12 | 张锐 | A kind of agricultural soil reparation incineration method flue gas purification device |
| CN109499298A (en) * | 2019-01-14 | 2019-03-22 | 苏州万鸿环保科技有限公司 | Marine diesel exhaust gas desulfurization I type desulfurizing tower |
| CN110975568A (en) * | 2019-11-27 | 2020-04-10 | 惠生（南通）重工有限公司 | A Ship Waste Gas Treatment System Using PCHE Vaporizer to Cool Down |
| CN112844045A (en) * | 2021-01-21 | 2021-05-28 | 交通运输部北海航海保障中心青岛航标处 | Semi-open type ship exhaust gas cleaning system |
| CN114294078A (en) * | 2022-01-04 | 2022-04-08 | 江南造船(集团)有限责任公司 | Marine diesel engine exhaust gas cleaning system |
-
2010
- 2010-07-06 CN CN2010202487438U patent/CN201728054U/en not_active Expired - Lifetime
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102309912A (en) * | 2010-07-06 | 2012-01-11 | 同方环境股份有限公司 | Device and method for performing alkali desulfurization and dust removal on ship exhaust fume |
| CN103842051B (en) * | 2011-09-30 | 2015-12-23 | 阿尔法拉瓦尔股份有限公司 | Scrubber system and method |
| CN103842051A (en) * | 2011-09-30 | 2014-06-04 | 阿尔法拉瓦尔股份有限公司 | Scrubber system and method |
| CN102910764A (en) * | 2012-11-16 | 2013-02-06 | 江苏科技大学 | Device and method for simultaneously treating marine waste gas and waste water |
| CN103272471A (en) * | 2013-04-27 | 2013-09-04 | 高翀 | Desulfuration system and desulfuration technology therefor |
| CN103331093A (en) * | 2013-06-26 | 2013-10-02 | 哈尔滨工程大学 | Device for washing and desulfurating waste gas of marine diesel engine |
| CN103331093B (en) * | 2013-06-26 | 2015-04-08 | 哈尔滨工程大学 | Device for washing and desulfurating waste gas of marine diesel engine |
| US9387438B2 (en) | 2014-02-14 | 2016-07-12 | Tenneco Automotive Operating Company Inc. | Modular system for reduction of sulphur oxides in exhaust |
| CN105240826A (en) * | 2015-11-16 | 2016-01-13 | 江苏昌明环保科技有限公司 | Recovery system and method for low-temperature flue gas waste heat |
| CN106277397A (en) * | 2016-08-25 | 2017-01-04 | 张赛 | A kind of mobile device that chemical plant sewage is carried out desulfurization |
| CN109316936A (en) * | 2018-11-06 | 2019-02-12 | 张锐 | A kind of agricultural soil reparation incineration method flue gas purification device |
| CN109499298A (en) * | 2019-01-14 | 2019-03-22 | 苏州万鸿环保科技有限公司 | Marine diesel exhaust gas desulfurization I type desulfurizing tower |
| CN110975568A (en) * | 2019-11-27 | 2020-04-10 | 惠生（南通）重工有限公司 | A Ship Waste Gas Treatment System Using PCHE Vaporizer to Cool Down |
| CN112844045A (en) * | 2021-01-21 | 2021-05-28 | 交通运输部北海航海保障中心青岛航标处 | Semi-open type ship exhaust gas cleaning system |
| CN114294078A (en) * | 2022-01-04 | 2022-04-08 | 江南造船(集团)有限责任公司 | Marine diesel engine exhaust gas cleaning system |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CX01 | Expiry of patent term |
Granted publication date: 20110202 |
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| CX01 | Expiry of patent term |