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CN201431647Y - A chlorine dioxide gas slow release device for removing indoor formaldehyde - Google Patents

A chlorine dioxide gas slow release device for removing indoor formaldehyde Download PDF

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CN201431647Y
CN201431647Y CN2009201037031U CN200920103703U CN201431647Y CN 201431647 Y CN201431647 Y CN 201431647Y CN 2009201037031 U CN2009201037031 U CN 2009201037031U CN 200920103703 U CN200920103703 U CN 200920103703U CN 201431647 Y CN201431647 Y CN 201431647Y
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chlorine dioxide
indoor formaldehyde
box body
dioxide gas
formaldehyde
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王奎涛
吴海霞
刘晓青
丁跃
赵善祥
王瑞恒
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Hebei University of Science and Technology
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Abstract

一种用于清除室内甲醛的二氧化氯气体缓释器,用于清除室内甲醛。其技术方案是:它包括盒体、盒盖,盒体内盛装二氧化氯母体凝胶,二氧化氯母体凝胶上面覆盖隔离膜,隔离膜上置放活化剂袋。本实用新型与现有消除室内甲醛污染技术相比具有以下显著优点:a.制备工艺简单,价格低廉,使用安全有效,不产生二次污染;b.产品稳定,保质期长,有效期超过两年;c.二氧化氯气体释放时间长,释放出来的二氧化氯气体可快速的氧化空气中的甲醛;d.对空气有杀菌、除臭等功效。

Figure 200920103703

The utility model relates to a chlorine dioxide gas slow release device for removing indoor formaldehyde, which is used for removing indoor formaldehyde. The technical scheme is as follows: it comprises a box body and a box cover, the box body contains chlorine dioxide matrix gel, the chlorine dioxide matrix gel is covered with an isolation film, and an activator bag is placed on the isolation film. Compared with the existing indoor formaldehyde pollution elimination technology, the utility model has the following significant advantages: a. The preparation process is simple, the price is low, the use is safe and effective, and no secondary pollution occurs; b. The product is stable and has a long shelf life, and the validity period exceeds two years; c. The release time of chlorine dioxide gas is long, and the released chlorine dioxide gas can quickly oxidize formaldehyde in the air; d. It has the effects of sterilization and deodorization on the air.

Figure 200920103703

Description

一种用于清除室内甲醛的二氧化氯气体缓释器 A chlorine dioxide gas slow release device for removing indoor formaldehyde

技术领域 technical field

本实用新型涉及一种对室内空气进行净化消毒的器具,特别是一种用于清除室内甲醛、能缓慢持续释放二氧化氯气体的缓释器,属气体净化器具技术领域。The utility model relates to an appliance for purifying and disinfecting indoor air, in particular to a slow release device for removing indoor formaldehyde and capable of releasing chlorine dioxide gas slowly and continuously, belonging to the technical field of gas purification appliances.

背景技术 Background technique

随着科学技术的发展,人民生活水平日益提高,办公及家庭场所装修愈来愈普遍,但装修不当也能给人们的健康带来隐患。近年来,因室内装修引发的空气污染危害居民身体健康的事件时有发生,尤其是“甲醛”,已被确认为一种强致癌物,主要对人体的呼吸道产生影响,是一个变态反应源,它引起咳嗽、胸闷、哮喘、各种过敏症、眼疾及鼻咽癌等。目前,市场上甲醛祛除剂有十几种,大部分为液体制剂,使用时喷洒到空间里,这样会浪费很多有效成分,而且是间歇操作,没有持续的效果,有些还会产生二次污染。另外一些属于吸附型甲醛祛除剂,它要求必须有空气的强制循环才能达到较好的祛除效果。With the development of science and technology, people's living standards are improving day by day, office and family decoration is becoming more and more common, but improper decoration can also bring hidden dangers to people's health. In recent years, incidents of air pollution caused by interior decoration endangering the health of residents have occurred frequently, especially "formaldehyde", which has been recognized as a strong carcinogen, mainly affects the human respiratory tract, and is a source of allergies. It causes cough, chest tightness, asthma, various allergies, eye diseases and nasopharyngeal cancer. At present, there are more than a dozen formaldehyde removers on the market, most of which are liquid preparations, which are sprayed into the space during use, which will waste a lot of active ingredients, and are intermittently operated without continuous effect, and some will cause secondary pollution. Others are adsorption-type formaldehyde removers, which require forced circulation of air to achieve a better removal effect.

二氧化氯是一种国际公认的高效、无毒、快速、广谱的杀菌消毒剂,它对细菌、真菌、病毒、芽孢有100%的灭菌效果,还可通过它的强力氧化作用对室内空气中的甲醛、甲苯等有害物质有着非常理想的降解作用。二氧化氯具有很好的除臭效果,它产生的原子态氧能将氨水脱水而成为氮气,将硫化氢、二氧化硫及硫醇等臭味气体氧化成硫酸或磺酸而除去,从而成为一种性能优越的新一代空气污染净化剂。但二氧化氯不稳定,较难储存,需要现场制备,需要一种制备手段。中国专利200610134083.9号公开了一种甲醛祛除剂的制备方法,它将制备好的二氧化氯用于祛除甲醛,但该专利提供的制备和应用方法都很复杂,而且现场应用剂型为液态,不易移动,且有效使用期很短。Chlorine dioxide is an internationally recognized high-efficiency, non-toxic, fast, and broad-spectrum disinfectant. It has a 100% sterilization effect on bacteria, fungi, viruses, and spores. It can also be used for indoor disinfection through its strong oxidation. Harmful substances such as formaldehyde and toluene in the air have a very ideal degradation effect. Chlorine dioxide has a good deodorizing effect. The atomic oxygen it produces can dehydrate ammonia water into nitrogen, and oxidize hydrogen sulfide, sulfur dioxide, and mercaptans into sulfuric acid or sulfonic acid for removal, thus becoming a A new generation of air pollution purifier with superior performance. However, chlorine dioxide is unstable and difficult to store. It needs to be prepared on site, and a preparation method is needed. Chinese patent No. 200610134083.9 discloses a preparation method of a formaldehyde remover, which uses the prepared chlorine dioxide to remove formaldehyde, but the preparation and application methods provided by this patent are very complicated, and the dosage form for field application is liquid and difficult to move , and the effective use period is very short.

发明内容 Contents of the invention

本实用新型用于克服现有技术之缺陷而提供一种使用安全、方便、不产生二次污染的用于清除室内甲醛的二氧化氯气体缓释器。The utility model is used to overcome the defects of the prior art and provide a chlorine dioxide gas slow release device for removing indoor formaldehyde which is safe, convenient and does not produce secondary pollution.

本实用新型所述问题是由以下技术方案解决的:Problem described in the utility model is solved by following technical scheme:

一种用于清除室内甲醛的二氧化氯气体缓释器,它包括盒体、盒盖,盒体内盛装二氧化氯母体凝胶,二氧化氯母体凝胶上面覆盖隔离膜,隔离膜上置放活化剂袋。A chlorine dioxide gas slow-release device for removing indoor formaldehyde, which includes a box body and a box cover. The box body is filled with chlorine dioxide matrix gel, and the chlorine dioxide matrix gel is covered with an isolation film. Activator bag.

上述雾化双氧水除室内甲醛装置,所述盒盖下部与盒体旋合,盒盖上部设有与盒体直径匹配的盒体置放槽。The above atomized hydrogen peroxide indoor formaldehyde removal device, the lower part of the box cover is screwed with the box body, and the upper part of the box cover is provided with a box body placement groove matching the diameter of the box body.

上述雾化双氧水除室内甲醛装置,所述隔离膜为塑料膜或铝箔膜,所述活化剂袋体为无纺布,袋体内装有缓释活化剂。In the above indoor formaldehyde removal device for atomized hydrogen peroxide, the isolation film is a plastic film or an aluminum foil film, the activator bag is a non-woven fabric, and a slow-release activator is housed in the bag.

本实用新型将二氧化氯母体凝胶和缓释活化袋置于盒体中,两者中间由隔离膜隔开,使用时,揭开隔离膜将缓释活化袋插入二氧化氯母体凝胶中,缓释活化剂会缓慢溶解于凝胶中,并与胶体中的亚氯酸钠反应生成二氧化氯气体,二氧化氯气体从凝胶中释放出,挥发到空气中,对甲醛进行有效祛除。它与现有技术相比具有以下显著优点:(1)制备工艺简单,价格低廉,使用安全有效,不产生二次污染;(2)产品稳定,保质期长,有效期超过两年;(3)二氧化氯气体释放时间长,释放出来的二氧化氯气体可快速的氧化空气中的甲醛;(4)对空气还有杀菌、除臭等功效。In the utility model, the chlorine dioxide matrix gel and the slow-release activation bag are placed in the box body, and the middle of the two is separated by an isolation film. When in use, the isolation film is uncovered and the slow-release activation bag is inserted into the chlorine dioxide matrix gel. , the slow-release activator will slowly dissolve in the gel and react with sodium chlorite in the colloid to generate chlorine dioxide gas, which is released from the gel and volatilizes into the air to effectively remove formaldehyde . Compared with the existing technology, it has the following significant advantages: (1) the preparation process is simple, the price is low, the use is safe and effective, and no secondary pollution occurs; (2) the product is stable, the shelf life is long, and the validity period exceeds two years; (3) the two The release time of chlorine oxide gas is long, and the released chlorine dioxide gas can quickly oxidize formaldehyde in the air; (4) it also has the effects of sterilization and deodorization on the air.

附图说明 Description of drawings

图1是本实用新型结构示意图。Fig. 1 is the structural representation of the utility model.

图中标号表示如下:1-盒体;2-盒盖;2-1-盒体置放槽;3-活化剂袋;4-隔离膜;5-二氧化氯母体凝胶。The symbols in the figure are as follows: 1-box body; 2-box cover; 2-1-box body placement groove; 3-activator bag; 4-isolation film; 5-chlorine dioxide matrix gel.

具体实施方式 Detailed ways

参看图1,本实用新型构成中包括盒体1、盒盖2,盒体1和盒盖2螺纹旋合,盒体内盛装由亚氯酸钠、琼脂和水制成的二氧化氯母体凝胶5,在二氧化氯母体凝胶上部覆盖塑料或铝箔隔离膜4,隔离膜上置放盛有缓释活化剂的活化剂袋3,活化剂袋的袋体采用无纺布制成。盒盖上部设有与盒体直径匹配的盒体置放槽2-1。Referring to Fig. 1, the utility model comprises box body 1, box cover 2 in the composition, and box body 1 and box cover 2 threads are screwed together, and the chlorine dioxide precursor gel that is made of sodium chlorite, agar and water is contained in the box body 5. Cover the upper part of the chlorine dioxide matrix gel with a plastic or aluminum foil isolation film 4, place an activator bag 3 filled with a slow-release activator on the isolation film, and the bag body of the activator bag is made of non-woven fabric. The top of the box cover is provided with a box body placement groove 2-1 matched with the box body diameter.

本实用新型所述的二氧化氯母体凝胶,以琼脂为凝胶剂,将二氧化氯母体亚氯酸钠溶液稳定于凝胶中。所述缓释活化剂为粉状,它选自硼酸、柠檬酸、酒石酸、草酸、磷酸二氢盐、硫酸氢钠、氨基磺酸中的一种或其混合物,包装于无纺布袋体中。本实用新型使用时,打开盒盖,将盒体安放到盒体置放槽中,撕开隔离膜,将活化剂袋插入凝胶中,缓释活化剂就会缓慢的溶解于凝胶中,并在凝胶中与亚氯酸钠缓慢的反应生成二氧化氯气体,其反应式为:The chlorine dioxide matrix gel described in the utility model uses agar as a gelling agent to stabilize the chlorine dioxide matrix sodium chlorite solution in the gel. The sustained-release activator is powder, which is selected from boric acid, citric acid, tartaric acid, oxalic acid, dihydrogen phosphate, sodium bisulfate, sulfamic acid or a mixture thereof, and is packed in a non-woven bag . When the utility model is used, open the box cover, place the box body in the box body placement groove, tear off the isolation film, insert the activator bag into the gel, and the slow-release activator will slowly dissolve in the gel, And react slowly with sodium chlorite in the gel to generate chlorine dioxide gas, the reaction formula is:

5ClO2 -+4H+→4ClO2+Cl-+2H2O5ClO 2 - +4H + → 4ClO 2 +Cl - +2H 2 O

二氧化氯气体在凝胶中溶解度较低,部分二氧化氯气体就会从凝胶中释放出,挥发到空气中,释放出来的二氧化氯气体可快速的氧化空气中的甲醛,其反应式为:The solubility of chlorine dioxide gas in the gel is low, and part of the chlorine dioxide gas will be released from the gel and volatilized into the air. The released chlorine dioxide gas can quickly oxidize the formaldehyde in the air, and its reaction formula for:

4ClO2+5HCHO==5CO2+4HCl+3H2O4ClO 2 +5HCHO==5CO 2 +4HCl+3H 2 O

反应产物为二氧化碳、水和氯化氢,氯化氢又可以与灰尘中的碳酸盐继续作用生成氯化物,不会产生二次污染。The reaction products are carbon dioxide, water and hydrogen chloride, and the hydrogen chloride can continue to react with the carbonate in the dust to generate chloride without secondary pollution.

本实用新型产品制备工艺简单,价格低廉,使用安全有效,不产生二次污染。除了具有清除甲醛的作用,还可对空气起到消毒、净化、清新的多重功效。The product of the utility model has simple preparation process, low price, safe and effective use, and no secondary pollution. In addition to the function of removing formaldehyde, it can also have multiple functions of disinfection, purification and freshening of the air.

Claims (3)

1.一种用于清除室内甲醛的二氧化氯气体缓释器,其特征在于:构成包括盒体(1)、盒盖(2),盒体内盛装二氧化氯母体凝胶(5),二氧化氯母体凝胶上面覆盖隔离膜(4),隔离膜上置放活化剂袋(3)。1. A chlorine dioxide slow-releasing device for removing indoor formaldehyde, characterized in that: the composition includes a box body (1), a lid (2), and the box body is filled with chlorine dioxide precursor gel (5), two The chlorine oxide matrix gel is covered with an isolation membrane (4), and an activator bag (3) is placed on the isolation membrane. 2.根据权利要求1所述的雾化双氧水除室内甲醛装置,其特征在于:所述盒盖下部与盒体旋合,盒盖上部设有与盒体直径匹配的盒体置放槽(2-1)。2. The atomized hydrogen peroxide indoor formaldehyde removal device according to claim 1, characterized in that: the lower part of the lid is screwed with the box body, and the upper part of the lid is provided with a box placement groove (2 -1). 3.根据权利要求1或2所述的雾化双氧水除室内甲醛装置,其特征在于:所述隔离膜(4)为塑料膜或铝箔膜,所述活化剂袋体(3)为无纺布,袋体内装有缓释活化剂。3. The atomized hydrogen peroxide indoor formaldehyde removal device according to claim 1 or 2, characterized in that: the isolation film (4) is a plastic film or an aluminum foil film, and the activator bag (3) is a non-woven fabric , the bag is filled with a slow-release activator.
CN2009201037031U 2009-07-15 2009-07-15 A chlorine dioxide gas slow release device for removing indoor formaldehyde Expired - Fee Related CN201431647Y (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103418014A (en) * 2012-05-16 2013-12-04 曹恒 Chlorine dioxide slow-release preparation agent suitable for indoor air purification
CN105379632A (en) * 2014-09-03 2016-03-09 中粮营养健康研究院有限公司 Auxiliary tool for breeding and breeding device
CN113767899A (en) * 2021-09-28 2021-12-10 中北大学 A kind of controllable slow-release reaction type chlorine dioxide generating device and generating method

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103418014A (en) * 2012-05-16 2013-12-04 曹恒 Chlorine dioxide slow-release preparation agent suitable for indoor air purification
CN105379632A (en) * 2014-09-03 2016-03-09 中粮营养健康研究院有限公司 Auxiliary tool for breeding and breeding device
CN113767899A (en) * 2021-09-28 2021-12-10 中北大学 A kind of controllable slow-release reaction type chlorine dioxide generating device and generating method

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Granted publication date: 20100331

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