CN201308814Y - Biological desulphurization treatment apparatus - Google Patents
Biological desulphurization treatment apparatus Download PDFInfo
- Publication number
- CN201308814Y CN201308814Y CNU2008201552057U CN200820155205U CN201308814Y CN 201308814 Y CN201308814 Y CN 201308814Y CN U2008201552057 U CNU2008201552057 U CN U2008201552057U CN 200820155205 U CN200820155205 U CN 200820155205U CN 201308814 Y CN201308814 Y CN 201308814Y
- Authority
- CN
- China
- Prior art keywords
- bioreactor
- inlet
- outlet
- precipitator
- sulfur
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000007788 liquid Substances 0.000 claims abstract description 19
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 9
- 239000011593 sulfur Substances 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 238000006477 desulfuration reaction Methods 0.000 claims abstract description 5
- 230000023556 desulfurization Effects 0.000 claims abstract description 5
- 239000007921 spray Substances 0.000 claims abstract description 5
- 238000005406 washing Methods 0.000 claims abstract 11
- 239000012716 precipitator Substances 0.000 claims abstract 6
- 239000011259 mixed solution Substances 0.000 claims description 3
- 238000005201 scrubbing Methods 0.000 description 11
- 239000000243 solution Substances 0.000 description 11
- 238000004140 cleaning Methods 0.000 description 10
- 239000005864 Sulphur Substances 0.000 description 8
- 239000007789 gas Substances 0.000 description 8
- 238000010992 reflux Methods 0.000 description 4
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 3
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 3
- 238000012544 monitoring process Methods 0.000 description 3
- DTMHTVJOHYTUHE-UHFFFAOYSA-N thiocyanogen Chemical compound N#CSSC#N DTMHTVJOHYTUHE-UHFFFAOYSA-N 0.000 description 3
- 239000002912 waste gas Substances 0.000 description 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 230000033116 oxidation-reduction process Effects 0.000 description 2
- 241000282414 Homo sapiens Species 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 241000605118 Thiobacillus Species 0.000 description 1
- 238000005273 aeration Methods 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
Images
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
Landscapes
- Treating Waste Gases (AREA)
- Gas Separation By Absorption (AREA)
Abstract
本实用新型提供了一种生物脱硫处理装置，包括洗涤塔，其特征在于，洗涤塔的洗涤液回流出口连接生物反应器的洗涤液回流入口，生物反应器的出口通过循环泵连接洗涤塔的喷淋入口以及沉淀器的混合液入口，鼓风机的一端通过管路与生物反应器内的布气系统连接，生物反应器连接补充水阀，沉淀器的清液出口连接生物反应器的清液入口，沉淀器的单质硫出口通过硫泵连接生物反应器的生物硫回流入口及排硫阀。本实用新型的优点是：处理效率高、运行费用低、操作简单且运行稳定。
The utility model provides a biological desulfurization treatment device, which includes a washing tower, and is characterized in that the washing liquid return outlet of the washing tower is connected with the washing liquid return inlet of the bioreactor, and the outlet of the bioreactor is connected with the spray nozzle of the washing tower through a circulation pump. The drenching inlet and the mixed liquid inlet of the precipitator, one end of the blower is connected to the air distribution system in the bioreactor through a pipeline, the bioreactor is connected to the supplementary water valve, and the clear liquid outlet of the precipitator is connected to the clear liquid inlet of the bioreactor. The elemental sulfur outlet of the precipitator is connected to the biosulfur return inlet of the bioreactor and the sulfur discharge valve through a sulfur pump. The utility model has the advantages of high processing efficiency, low operation cost, simple operation and stable operation.
Description
Technical field
The utility model relates to a kind of biological desulphurization treating apparatus, is used for removing the thiocyanogen of gaseous fluid (for example natural gas, biogas, process gas and waste gas), belongs to biological desulphurization treating apparatus technical field.
Background technology
Contain hydrogen sulfide in gas that various industry produce and the waste gas, for the safe operation and the corrosion that guarantee human beings'health, equipment, hydrogen sulfide must be removed.Conventional desulfurization reactor, its operating cost height, treatment effect instability and inconvenient operation.
The utility model content
The purpose of this utility model provides a kind of biological desulphurization treating apparatus, makes its treatment effeciency height, operating cost low, simple to operate and stable.
In order to achieve the above object, the technical solution of the utility model has provided a kind of biological desulphurization treating apparatus, comprise scrubbing tower, it is characterized in that, the cleaning solution bypass outlet of scrubbing tower connects the cleaning solution reflux inlet of bioreactor, the outlet of bioreactor connects the spray inlet of scrubbing tower and the entry to mixed solution of settling vessel by circulating pump, one end of air blast is connected with gas distribution system in the bioreactor by pipeline, bioreactor connects additional water valve, the purified liquor outlet of settling vessel connects the clear liquid inlet of bioreactor, and the elemental sulfur outlet of settling vessel connects the biological sulphur reflux inlet and the sulfur drain pipe of bioreactor by the sulphur pump.
The technology that the utility model adopted is under normal temperature and normal pressure, need not expensive catalysts and chemical agent and just can reach desulfurized effect efficiently, its import thiocyanogen concentration is 15000ppm, outlet thiocyanogen concentration can reach below the 100ppm, for the safe operation of clean biogas provides fit closely solution.
This shows, the utility model has the advantages that: treatment effeciency height, operating cost are low, simple to operate and stable.
Description of drawings
The structured flowchart of a kind of biological desulphurization treating apparatus that Fig. 1 provides for the utility model.
The specific embodiment
Specify the utility model below in conjunction with embodiment.
Embodiment
As shown in Figure 1, the structured flowchart of a kind of biological desulphurization treating apparatus that provides for the utility model is by scrubbing tower 1, bioreactor 2, settling vessel 3, circulating pump 4, air blast 5, sulphur pump 6, sulfur drain pipe 7, replenish water valve 8, pH on-line determination instrument 9, redox position indicator 10, liquid level gauge 11 and gas distribution system 12 and form.
The cleaning solution bypass outlet of scrubbing tower 1 connects the cleaning solution reflux inlet of bioreactor 2, the outlet of bioreactor 2 connects the spray inlet of scrubbing tower 1 and the entry to mixed solution of settling vessel 3 by circulating pump 4, one end of air blast 5 is connected by the gas distribution system 12 in pipeline and the bioreactor 2, bioreactor 2 connects additional water valve 8, the purified liquor outlet of settling vessel 3 connects the clear liquid inlet of bioreactor 2, and the elemental sulfur outlet of settling vessel 3 connects the biological sulphur reflux inlet and the sulfur drain pipe 7 of bioreactor 2 by sulphur pump 6.Also be connected with pH on-line determination instrument 9, redox position indicator 10 and liquid level gauge 11 on the bioreactor 2.
Operation principle of the present utility model is as follows:
Biogas/waste gas at first enters scrubbing tower 1, gas in scrubbing tower 1 with the cleaning solution counter current contacting, hydrogen sulfide is washed liquid and absorbs.Gas after the desulfurization is discharged from scrubbing tower 1 top.Cleaning solution pumps into biological scrubbing tower by circulating pump 4 from the degas zone of bioreactor 2, and part water is used for reactor spray froth breaking.Cleaning solution is collected in the bottom of scrubbing tower 1 and is relied on gravity to flow back to bioreactor 2 again.Contain Thiobacillus in the liquid phase of bioreactor 2, be converted into elemental sulfur at this sulfide.The carrier of no fixation of microbe in the bioreactor 2, and biological sulphur itself has served as the role of carrier, plays the effect of further cleaning.Air blast 5 blasts air and carries out aeration by the gas distribution system 12 in the bioreactor 2.Cleaning solution in the bioreactor 2 is continuously pumped into settling vessel 3 by circulating pump 4, and The product sulfur is separated with cleaning solution in this unit, and The product sulfur is extracted out to treat further processing by sulphur pump 6.The clear liquid overflow of settling vessel 3 is to bioreactor 2.
And the effect of pH on-line determination instrument 9 is: monitoring pH of mixed value; The effect of oxidation-reduction potential instrument 10 is: monitoring mixed liquor oxidation-reduction potential value guarantees that sulfide is converted into sulphur simple substance; The effect of liquid level gauge 11 is: the liquid level of monitoring bio reactor, and control lifting rate and rate of water make-up.
Claims (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNU2008201552057U CN201308814Y (en) | 2008-11-12 | 2008-11-12 | Biological desulphurization treatment apparatus |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNU2008201552057U CN201308814Y (en) | 2008-11-12 | 2008-11-12 | Biological desulphurization treatment apparatus |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN201308814Y true CN201308814Y (en) | 2009-09-16 |
Family
ID=41106065
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNU2008201552057U Expired - Lifetime CN201308814Y (en) | 2008-11-12 | 2008-11-12 | Biological desulphurization treatment apparatus |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN201308814Y (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103127819A (en) * | 2013-03-08 | 2013-06-05 | 上海斯科瑞机电物资有限责任公司 | Methane treatment system |
| CN104140858A (en) * | 2013-05-06 | 2014-11-12 | 帕克环保技术(上海)有限公司 | A biogas treatment system used for kitchen waste treatment |
| CN109675424A (en) * | 2018-11-23 | 2019-04-26 | 宜宾海丰和锐有限公司 | The method and system of reducing substances in carbide slag slurry are removed in carbide slag sulfur removal technology |
| CN113583726A (en) * | 2020-04-30 | 2021-11-02 | 蒋建平 | Biological fine desulfurization treatment system for biogas |
-
2008
- 2008-11-12 CN CNU2008201552057U patent/CN201308814Y/en not_active Expired - Lifetime
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103127819A (en) * | 2013-03-08 | 2013-06-05 | 上海斯科瑞机电物资有限责任公司 | Methane treatment system |
| CN103127819B (en) * | 2013-03-08 | 2015-03-18 | 上海斯科瑞机电物资有限责任公司 | Methane treatment system |
| CN104140858A (en) * | 2013-05-06 | 2014-11-12 | 帕克环保技术(上海)有限公司 | A biogas treatment system used for kitchen waste treatment |
| CN104140858B (en) * | 2013-05-06 | 2019-07-16 | 帕克环保技术(上海)有限公司 | Marsh gas treating system for kitchen garbage processing |
| CN109675424A (en) * | 2018-11-23 | 2019-04-26 | 宜宾海丰和锐有限公司 | The method and system of reducing substances in carbide slag slurry are removed in carbide slag sulfur removal technology |
| CN113583726A (en) * | 2020-04-30 | 2021-11-02 | 蒋建平 | Biological fine desulfurization treatment system for biogas |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CX01 | Expiry of patent term | ||
| CX01 | Expiry of patent term |
Granted publication date: 20090916 |