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CN201307601Y - Filled type inverted trapezoidal microstructure high-brightness light-emitting diode - Google Patents

Filled type inverted trapezoidal microstructure high-brightness light-emitting diode Download PDF

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Publication number
CN201307601Y
CN201307601Y CNU2008200279630U CN200820027963U CN201307601Y CN 201307601 Y CN201307601 Y CN 201307601Y CN U2008200279630 U CNU2008200279630 U CN U2008200279630U CN 200820027963 U CN200820027963 U CN 200820027963U CN 201307601 Y CN201307601 Y CN 201307601Y
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epitaxial wafer
metal
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permanent substrate
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洪灵愿
潘群峰
林雪娇
陈文欣
吴志强
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Xiamen Sanan Optoelectronics Technology Co Ltd
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Xiamen Sanan Optoelectronics Technology Co Ltd
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Abstract

The utility model discloses a filling type inverted trapezoid microstructure high-brightness light-emitting diode, which comprises a permanent substrate and an epitaxial wafer, wherein a dielectric layer is deposited on the conical wall of an inverted cone frustum hole etched on the epitaxial wafer which is arranged right above and on the surface of the epitaxial wafer, a metal layer is deposited on the surfaces of the dielectric layer and the epitaxial wafer, a barrier layer is deposited on the metal layer, and a metal filling layer is deposited in the space of the inner wall of the barrier layer by metal sputtering; the epitaxial wafer is inverted and connected with the permanent substrate in a vacuum bonding way; and depositing a metal electrode on the permanent substrate, and depositing an ohmic contact electrode on the top of the epitaxial wafer. The utility model discloses metal sputtering is filled up in the space of barrier layer inner wall has the metal filling layer, realizes the seamless plane bonding of epitaxial wafer and permanent substrate, has solved the poor problem of epitaxial wafer and permanent substrate bonding force to and there is the crack problem easily to lead to epitaxial wafer and permanent substrate bonding process in the inverted cone frustum hole that etches out in the epitaxial wafer.

Description

一种填充式倒梯形微结构高亮度发光二极管 A Filled Inverted Trapezoidal Microstructure High Brightness Light Emitting Diode

技术领域 technical field

本实用新型涉及LED发光二极管,特别是一种填充式倒梯形微结构高亮度发光二极管。The utility model relates to an LED light-emitting diode, in particular to a filling-type inverted trapezoidal microstructure high-brightness light-emitting diode.

背景技术 Background technique

发光二极管(Light Emitting Diode,LED)属于冷光源,其体积小、寿命长、驱动电压低、反应速率快、耐震性特佳,因此得到广泛应用,但传统的二极管发光效率比较低。如以磷化铝镓铟(AlGaInP)发光二极管为例,磷化铝镓铟为一四元素化合物半导体材料,其生长在晶格匹配的砷化镓(GaAs)衬底上,用于制造高亮度红、橙、黄、及黄绿光发光二极管,拥有较高发光效率,然而,由于砷化镓衬底为一吸光性衬底,会吸收磷化铝镓铟发出的可见光,且其热传导性较差,因此限制了其在大电流工作时的发光效率。Light Emitting Diode (LED) is a cold light source, which is widely used because of its small size, long life, low driving voltage, fast response rate, and excellent shock resistance. However, traditional diodes have relatively low luminous efficiency. For example, take aluminum gallium indium phosphide (AlGaInP) light-emitting diodes as an example, aluminum gallium indium phosphide is a four-element compound semiconductor material, which is grown on a lattice-matched gallium arsenide (GaAs) substrate for manufacturing high brightness Red, orange, yellow, and yellow-green light-emitting diodes have high luminous efficiency. However, because the gallium arsenide substrate is a light-absorbing substrate, it will absorb the visible light emitted by aluminum gallium indium phosphide, and its thermal conductivity is poor. Therefore, its luminous efficiency in high current operation is limited.

因此,为了提高发光二极管的发光效率,必须把向下传播的光子和上表面反射回半导体材料内部的光子也能大部分提取出来,减少GaAs衬底的吸收,人们在GaAs衬底和有源区之间生长了布拉格反射镜(Distributed BraggReflectors,DBRs),以便把背面的光反射到芯片表面。图1是一现有带有高反射率DBRs的AlGaInP多量子阱(MQW)发光二极管200剖面结构示意图。此AlGaInP多量子阱(MQW)发光二极管结构包括n-GaAs衬底201,n-GaAs缓冲层202,DBRs结构层203,n-AlInP下限制层(n-cladding layer)204,非掺杂的(Al0.15Ga0.85)0.5In0.5P多量子阱(MQW)有源区205,p-AlInP上限制层(p-cladding layer)206,p型电流扩展层207,p型欧姆接触层208,底部平面金属接触210和上表面电极209。也就是在图1结构的基础上在GaAs衬底和有源区之间生长了DBRs结构,在p型欧姆接触层下生长了电流扩展层(窗口层)可有效扩展电流。但因为实际的DBRs反射镜的反射率角带宽有限,只对接近法向入射的光反射率大,对此范围之外的光反射率急剧下降,因此不能有效反射向衬底GaAs传播的光,仍有相当部分的光被GaAs衬底吸收。Therefore, in order to improve the luminous efficiency of light-emitting diodes, it is necessary to extract most of the photons propagating downward and the photons reflected back to the interior of the semiconductor material to reduce the absorption of the GaAs substrate. Bragg reflectors (Distributed BraggReflectors, DBRs) are grown between them to reflect the light from the back to the surface of the chip. FIG. 1 is a schematic cross-sectional structure diagram of an existing AlGaInP multi-quantum well (MQW) light-emitting diode 200 with high reflectivity DBRs. This AlGaInP multi-quantum well (MQW) light-emitting diode structure includes n-GaAs substrate 201, n-GaAs buffer layer 202, DBRs structure layer 203, n-AlInP lower confinement layer (n-cladding layer) 204, non-doped ( Al 0.15 Ga 0.85 ) 0.5 In 0.5 P multiple quantum well (MQW) active region 205, p-AlInP upper confinement layer (p-cladding layer) 206, p-type current spreading layer 207, p-type ohmic contact layer 208, bottom plane Metal contacts 210 and upper surface electrodes 209 . That is, on the basis of the structure in Figure 1, a DBRs structure is grown between the GaAs substrate and the active region, and a current expansion layer (window layer) is grown under the p-type ohmic contact layer to effectively expand the current. However, because the reflectivity angular bandwidth of the actual DBRs mirror is limited, the reflectivity is only large for the light incident near the normal direction, and the light reflectivity outside this range drops sharply, so it cannot effectively reflect the light propagating to the GaAs substrate. A considerable portion of the light is still absorbed by the GaAs substrate.

实用新型内容 Utility model content

为解决上述发光二极管的发光效率问题,本实用新型旨在提出一种填充式倒梯形微结构高亮度发光二极管。In order to solve the problem of luminous efficiency of the above-mentioned light-emitting diodes, the utility model aims to propose a high-brightness light-emitting diode with a filled inverted trapezoidal microstructure.

本实用新型为解决上述问题所采用的技术方案是:一种填充式倒梯形微结构高亮度发光二极管,含永久性衬底和外延片,其特征在于:在正置的外延片上蚀刻出的倒圆锥台孔的锥壁上及外延片表面上淀积有介质层,介质层和外延片表面上淀积金属层,金属层淀积有阻挡层,在阻挡层内壁的空间中金属溅射填积有金属填充层;外延片倒置与永久性衬底真空键合连接;在永久性衬底部淀积金属电极,在外延片顶部淀积欧姆接触电极。The technical scheme adopted by the utility model to solve the above problems is: a filled-type inverted trapezoidal microstructure high-brightness light-emitting diode, including a permanent substrate and an epitaxial wafer, which is characterized in that: the inverted epitaxial wafer etched on the upright A dielectric layer is deposited on the conical wall of the conical frustum hole and the surface of the epitaxial wafer, a metal layer is deposited on the dielectric layer and the surface of the epitaxial wafer, a barrier layer is deposited on the metal layer, and metal sputtering is deposited in the space of the inner wall of the barrier layer. There is a metal filling layer; the epitaxial wafer is inverted and connected to the permanent substrate by vacuum bonding; metal electrodes are deposited on the permanent substrate, and ohmic contact electrodes are deposited on the top of the epitaxial wafer.

本实用新型在层状结构的基板衬底上粘上一层粘贴层,在粘贴层上淀积连接一金属焊料层构成层叠结构的永久性衬底;外延片依次由第一导电型欧姆接触层、第一导电型电流扩展层、第一导电型下限制层、非掺杂的有源区、第二导电型上限制层、第二导电型电流扩展层和第二导电型欧姆接触层层叠连接构成;金属填充层截面为倒梯形。In the utility model, a layer of sticking layer is pasted on the substrate substrate of the layered structure, and a metal solder layer is deposited and connected on the sticking layer to form a permanent substrate of a laminated structure; , the first conductivity type current spreading layer, the first conductivity type lower confinement layer, the non-doped active region, the second conductivity type upper confinement layer, the second conductivity type current spreading layer and the second conductivity type ohmic contact layer are stacked and connected Composition; the cross-section of the metal filling layer is an inverted trapezoid.

本实用新型的有益效果是:本实用新型在阻挡层内壁的空间中金属溅射填积有金属填充层,实现外延片与永久性衬底的无缝隙平面键合,解决了外延片与永久性衬底结合力差的问题,以及外延中蚀刻出的倒圆锥台孔存在空隙容易导致外延片与永久性衬底键合过程易产生裂缝的问题。The beneficial effects of the utility model are: the utility model is filled with a metal filling layer by metal sputtering in the space of the inner wall of the barrier layer, realizing the seamless plane bonding of the epitaxial wafer and the permanent substrate, and solving the problem of the connection between the epitaxial wafer and the permanent substrate. The problem of poor bonding force of the substrate and the existence of gaps in the inverted frustum hole etched during epitaxy can easily cause cracks in the bonding process between the epitaxial wafer and the permanent substrate.

附图说明 Description of drawings

图1为现有带有高反射率DBRs的AlGaInP多量子阱(MQW)发光二极管剖面结构示意图;Fig. 1 is the schematic cross-sectional structure schematic diagram of the existing AlGaInP multi-quantum well (MQW) light-emitting diode with high reflectivity DBRs;

图2为本实用新型的层状结构剖视图;Fig. 2 is the sectional view of layered structure of the present utility model;

图2中:304.第一导电型欧姆接触层; 305.第一导电型电流扩展层;In Fig. 2: 304. The ohmic contact layer of the first conductivity type; 305. The current spreading layer of the first conductivity type;

       306.第一导电型下限制层;   307.非掺杂的有源区;                306. The first conductivity type lower confinement layer;     307. The non-doped active region;

       308.第二导电型上限制层;  309.第二导电型电流扩展层;            308. The upper confinement layer of the second conductivity type; 309. The current spreading layer of the second conductivity type;

       310.第二导电型欧姆接触层;401.基板衬底;                                                                              .

       402.粘贴层;              403.金属焊料层;402. Paste layer; 403. Metal solder layer;

       501.介质层;              502.金属层;501. Dielectric layer; 502. Metal layer;

       503.阻挡层;              504.金属填充层;503. Barrier layer; 504. Metal filling layer;

       505.金属电极;            506.欧姆接触电极。505. Metal electrodes; 506. Ohmic contact electrodes.

具体实施方式 Detailed ways

下面结合附图和实施例对本实用新型进一步说明。Below in conjunction with accompanying drawing and embodiment the utility model is further described.

如图2所示的一种填充式倒梯形微结构高亮度发光二极管,用MOCVD外延生长技术在GaAs衬底上生长发光二极管外延片,依次包括第一导电型欧姆接触层304、第一导电型电流扩展层305、第一导电型下限制层306、非掺杂的有源区307、第二导电型上限制层308、第二导电型电流扩展层309、第二导电型欧姆接触层310的层叠连接构成。在正置的外延片上蚀刻出的倒圆锥台孔的锥壁上及外延片表面上淀积有介质层,即在发光二极管外延片第二导电型欧姆接触层310上做光罩,采用干法蚀刻第二导电型欧姆接触层310和第二导电型电流扩展层309,然后湿法蚀刻第二导电型上限制层308、非掺杂的有源区307和第一导电型下限制层306,然后外延片上淀积介质层501,采用湿法蚀刻掉第二导电型欧姆接触层310中央的介质层;介质层501和外延片表面上淀积金属层502,金属层502和介质层联合作为反光镜,金属层502上淀积有阻挡层503,用于阻挡金属焊料层与金属层502之间的互扩散;蒸镀或溅射金属填充层504完成带反光镜的外延片的制作。As shown in FIG. 2, a filled inverted trapezoidal microstructure high-brightness light-emitting diode uses MOCVD epitaxial growth technology to grow a light-emitting diode epitaxial wafer on a GaAs substrate, which sequentially includes a first conductivity type ohmic contact layer 304, a first conductivity type The current spreading layer 305, the lower confinement layer 306 of the first conductivity type, the non-doped active region 307, the upper confinement layer 308 of the second conductivity type, the current spreading layer 309 of the second conductivity type, and the ohmic contact layer 310 of the second conductivity type Cascading connection composition. A dielectric layer is deposited on the cone wall of the inverted frustum hole etched on the upright epitaxial wafer and on the surface of the epitaxial wafer, that is, a photomask is made on the second conductivity type ohmic contact layer 310 of the light-emitting diode epitaxial wafer, and a dry method is used. Etching the second conductivity type ohmic contact layer 310 and the second conductivity type current spreading layer 309, and then wet etching the second conductivity type upper confinement layer 308, the non-doped active region 307 and the first conductivity type lower confinement layer 306, Then a dielectric layer 501 is deposited on the epitaxial wafer, and the dielectric layer in the center of the second conductivity type ohmic contact layer 310 is etched away by a wet method; a metal layer 502 is deposited on the dielectric layer 501 and the surface of the epitaxial wafer, and the metal layer 502 and the dielectric layer are combined as a light reflection A barrier layer 503 is deposited on the metal layer 502 for blocking the interdiffusion between the metal solder layer and the metal layer 502; evaporation or sputtering of the metal filling layer 504 completes the fabrication of the epitaxial wafer with a mirror.

永久性衬底由基板衬底401、粘贴层402、金属焊料层403层叠连接构成,具体是在层状结构的基板衬底401上粘上一层粘贴层402,在粘贴层402上淀积连接一金属焊料层403构成层叠结构的永久性衬底。The permanent substrate is composed of a substrate substrate 401, an adhesive layer 402, and a metal solder layer 403 laminated and connected. A metal solder layer 403 forms the permanent substrate of the stacked structure.

将上述的制作好带有反光镜的外延片以倒装方式叠置于永久性衬底的金属焊料层403上,真空下键合;在永久性衬底底部的基板衬底401上淀积金属电极505,在发光二极管外延片300第一导电型欧姆接触层304上淀积图形电极506,以上述图形电极506为掩膜湿法蚀刻第一导电型欧姆接触层304,经蚀刻台面和切割形成本实用新型。The above-mentioned epitaxial wafers with reflective mirrors are stacked on the metal solder layer 403 of the permanent substrate in a flip-chip manner, and bonded under vacuum; metal is deposited on the base substrate 401 at the bottom of the permanent substrate The electrode 505 is deposited on the first conductive type ohmic contact layer 304 of the light emitting diode epitaxial wafer 300, and the patterned electrode 506 is deposited, and the first conductive type ohmic contact layer 304 is wet etched with the above patterned electrode 506 as a mask, and formed by etching the mesa and cutting The utility model.

Claims (3)

1.一种填充式倒梯形微结构高亮度发光二极管,含永久性衬底和外延片,其特征在于:在正置的外延片上蚀刻出的倒圆锥台孔的锥壁上及外延片表面上淀积有介质层,介质层和外延片表面上淀积金属层,金属层淀积有阻挡层,在阻挡层内壁的空间中金属溅射填积有金属填充层;外延片倒置与永久性衬底真空键合连接;在永久性衬底部淀积金属电极,在外延片顶部淀积欧姆接触电极。1. A filling-type inverted trapezoidal microstructure high-brightness light-emitting diode, containing a permanent substrate and an epitaxial wafer, characterized in that: on the cone wall of the inverted conical frustum hole etched out on the upright epitaxial wafer and on the surface of the epitaxial wafer A dielectric layer is deposited, a metal layer is deposited on the surface of the dielectric layer and the epitaxial wafer, a barrier layer is deposited on the metal layer, and a metal filling layer is deposited in the space of the inner wall of the barrier layer by metal sputtering; the epitaxial wafer is inverted and the permanent lining Bottom vacuum bonding connection; metal electrodes are deposited on the permanent substrate, and ohmic contact electrodes are deposited on the top of the epitaxial wafer. 2.如权利要求1所述的一种填充式倒梯形微结构高亮度发光二极管,其特征是:在层状结构的基板衬底上粘上一层粘贴层,在粘贴层上淀积连接一金属焊料层构成层叠结构的永久性衬底;外延片依次由第一导电型欧姆接触层、第一导电型电流扩展层、第一导电型下限制层、非掺杂的有源区、第二导电型上限制层、第二导电型电流扩展层和第二导电型欧姆接触层层叠连接构成。2. A kind of filling type inverted trapezoidal microstructure high-brightness light-emitting diode as claimed in claim 1, is characterized in that: on the base plate substrate of layered structure sticks one deck sticking layer, deposits and connects one on the sticking layer The metal solder layer constitutes the permanent substrate of the stacked structure; the epitaxial wafer is sequentially composed of the first conductivity type ohmic contact layer, the first conductivity type current spreading layer, the first conductivity type lower confinement layer, the non-doped active region, the second The conductive type upper confinement layer, the second conductive type current spreading layer and the second conductive type ohmic contact layer are stacked and connected. 3.如权利要求1所述的一种填充式倒梯形微结构高亮度发光二极管,其特征是:所述的金属填充层截面为倒梯形。3. A high-brightness light-emitting diode with a filled inverted trapezoidal microstructure as claimed in claim 1, characterized in that: the cross-section of the metal filled layer is inverted trapezoidal.
CNU2008200279630U 2008-09-09 2008-09-09 Filled type inverted trapezoidal microstructure high-brightness light-emitting diode Expired - Lifetime CN201307601Y (en)

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CN115527854A (en) * 2022-09-22 2022-12-27 中国电子科技集团公司第十三研究所 GaAs planar doped barrier diode and preparation method thereof

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US8945958B2 (en) 2010-11-09 2015-02-03 Enraytek Optoelectronics Co., Ltd. Methods for manufacturing light emitting diode and light emitting device
CN102054914B (en) * 2010-11-09 2013-09-04 映瑞光电科技(上海)有限公司 Light emitting diode and manufacturing method thereof and light emitting device
US8809874B2 (en) 2010-11-09 2014-08-19 Enraytek Optoelectronics Co., Ltd. Light emitting diode and light emitting device
US8937322B2 (en) 2010-11-09 2015-01-20 Enraytek Optoelectronics Co., Ltd. Light emitting diode and a manufacturing method thereof, a light emitting device
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US9306122B2 (en) 2010-11-09 2016-04-05 Enraytek Optoelectronics Co., Ltd. Light emitting diode and a manufacturing method thereof, a light emitting device
CN105355740A (en) * 2015-10-19 2016-02-24 天津三安光电有限公司 Light-emitting diode and fabrication method thereof
CN105355740B (en) * 2015-10-19 2017-09-22 天津三安光电有限公司 Light emitting diode and preparation method thereof
CN105355732A (en) * 2015-12-11 2016-02-24 厦门乾照光电股份有限公司 Preparation method for inverted blue-green light-emitting diode chip
CN105355732B (en) * 2015-12-11 2017-09-15 厦门乾照光电股份有限公司 A kind of preparation method of upside-down mounting blue green LED chip
CN105762264A (en) * 2016-04-28 2016-07-13 厦门乾照光电股份有限公司 Micrometer-wire light-emitting diode having inverted-trapezoid-shaped circular truncated cone
CN115527854A (en) * 2022-09-22 2022-12-27 中国电子科技集团公司第十三研究所 GaAs planar doped barrier diode and preparation method thereof

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