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CN201234412Y - Plastic rubber case and mobile phone adopting the plastic rubber case - Google Patents

Plastic rubber case and mobile phone adopting the plastic rubber case Download PDF

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Publication number
CN201234412Y
CN201234412Y CNU200820095680XU CN200820095680U CN201234412Y CN 201234412 Y CN201234412 Y CN 201234412Y CN U200820095680X U CNU200820095680X U CN U200820095680XU CN 200820095680 U CN200820095680 U CN 200820095680U CN 201234412 Y CN201234412 Y CN 201234412Y
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film layer
adhesive layer
plastic casing
thickness
transparent film
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卜来来
付军
方焱
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BYD Co Ltd
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BYD Co Ltd
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Abstract

本实用新型提供了一种塑胶壳体及采用该塑胶壳体的手机,该塑胶壳体包括基材和位于所述基材表面之上的透明膜层,其特征在于,该塑胶壳体还包括金属膜层,该金属膜层位于基材表面与透明膜层之间。采用此结构的产品,在产品基材表面设有金属膜层,金属膜层外设有透明膜层保护,使该产品在具有金属质感和高光亮的金属光泽的同时,更加耐磨擦,质量更可靠,提升了产品的品质和档次。

Figure 200820095680

The utility model provides a plastic shell and a mobile phone using the plastic shell. The plastic shell includes a base material and a transparent film layer on the surface of the base material. It is characterized in that the plastic shell also includes The metal film layer is located between the substrate surface and the transparent film layer. The product with this structure has a metal film layer on the surface of the product base material, and a transparent film layer is protected outside the metal film layer, so that the product has a metallic texture and a high-bright metallic luster, and is more abrasion-resistant and of high quality. It is more reliable and improves the quality and grade of the product.

Figure 200820095680

Description

一种塑胶壳体及采用该塑胶壳体的手机 A plastic casing and a mobile phone using the plastic casing

技术领域 technical field

本实用新型涉及一种塑胶壳体及采用该塑胶壳体的手机。The utility model relates to a plastic shell and a mobile phone using the plastic shell.

背景技术 Background technique

目前的电子产品的壳体如手机、电脑、mp3等通常是采用塑胶产品来制成的。为了使外壳获得高质量的图案或者色彩的外观效果,行业内常采用模内镶件注塑(IML)工艺对电子产品壳体进行加工,该工艺是通过把印刷有油墨的的薄片放入模具内进行注塑,在注塑过程中,薄片与熔化的塑料粒子结合在一起成为成品。其工艺制得的产品的特点是:产品基材表面覆盖有一层硬化的透明薄膜,透明薄膜内表面印刷有油墨图案层,这样由于油墨有薄膜保护,可使防止油墨被刮花,使产品耐磨擦,并可长期保持颜色的鲜明不易褪色。The casings of current electronic products such as mobile phones, computers, mp3s, etc. are usually made of plastic products. In order to obtain a high-quality pattern or color appearance for the shell, the industry often uses the in-mold insert molding (IML) process to process the electronic product shell. This process is to put the printed sheet into the mold Injection molding is performed, in which the flakes are combined with molten plastic particles to form the finished product. The characteristics of the products produced by this process are: the surface of the product substrate is covered with a layer of hardened transparent film, and the inner surface of the transparent film is printed with an ink pattern layer, so that the ink is protected by a film, which can prevent the ink from being scratched and make the product durable. Friction, and can keep the color bright and not easy to fade for a long time.

虽然IML产品质量过硬,形式美观。但是其图案仅限于油墨本身的色泽,并且经过透明基材的损耗,透射出来的油墨颜色也不能如原色那样鲜亮。在体现金属光泽方面,既使使用金属油墨,也不能体现鲜亮的金属质感。Although the quality of IML products is excellent, the form is beautiful. However, its pattern is limited to the color of the ink itself, and after the loss of the transparent substrate, the color of the transmitted ink cannot be as bright as the original color. In terms of expressing metallic luster, even if metallic ink is used, it cannot reflect a bright metallic texture.

实用新型内容Utility model content

本实用新型的目的在于克服现有技术中的塑胶壳体光泽度较差的缺陷,提供一种装饰效果较完善的的塑胶壳体。The purpose of the utility model is to overcome the defect of poor glossiness of the plastic shell in the prior art, and provide a plastic shell with perfect decorative effect.

本实用新型提供了一种塑胶壳体,该塑胶壳体包括基材和位于所述基材表面之上的透明膜层,该塑胶壳体还包括金属膜层,该金属膜层位于基材表面与透明膜层之间。The utility model provides a plastic shell, the plastic shell includes a base material and a transparent film layer on the surface of the base material, the plastic shell also includes a metal film layer, and the metal film layer is located on the surface of the base material between the transparent film layer.

进一步的,该塑胶壳体还包括设置在所述透明膜层和金属膜层之间的油墨层。Further, the plastic casing also includes an ink layer disposed between the transparent film layer and the metal film layer.

更进一步的,该塑胶壳体还包括设置在金属膜层和基材表面之间的粘合层。Furthermore, the plastic casing also includes an adhesive layer disposed between the metal film layer and the surface of the substrate.

本实用新型还提供了一种手机外壳,该手机外壳由上述塑胶壳体制得。The utility model also provides a mobile phone casing, which is made of the above-mentioned plastic casing.

根据本实用新型提供的塑胶壳体,在基材表面设有金属膜层,金属膜层外设有透明膜层,使该壳体在具有很强的金属质感和高光亮的金属光泽的同时,更加耐磨擦,质量更可靠。使得采用该塑胶壳体的产品提升了产品的品质和档次。According to the plastic shell provided by the utility model, a metal film layer is provided on the surface of the base material, and a transparent film layer is provided outside the metal film layer, so that the shell has a strong metallic texture and a high-bright metallic luster, More wear-resistant, more reliable quality. The quality and grade of the product adopting the plastic shell are improved.

附图说明 Description of drawings

图1为本实用新型实施例塑胶壳体的示意图。FIG. 1 is a schematic diagram of a plastic housing of an embodiment of the present invention.

具体实施方式 Detailed ways

本实用新型提供的塑胶壳体包括基材和位于所述壳体基材表面之上的透明膜层,其中,该壳体还包括金属膜层,该金属膜层位于基材表面与透明膜层之间。The plastic shell provided by the utility model includes a base material and a transparent film layer on the surface of the base material of the shell, wherein the shell also includes a metal film layer, and the metal film layer is located on the surface of the base material and the transparent film layer. between.

如图1所示,根据本实施例提供的塑胶壳体包括壳体基材1,位于基材1表面之上的透明膜层6,和位于基材1表面与透明膜层6之间的金属膜层4。As shown in Figure 1, the plastic housing provided according to this embodiment includes a housing base material 1, a transparent film layer 6 located on the surface of the base material 1, and a metal layer located between the surface of the base material 1 and the transparent film layer 6. Film layer 4.

在金属膜层4和透明膜层6之间设置油墨层5,用以体现产品的图案颜色。为了增加金属膜层4和基材1之间的结合力同时保护金属膜层4,在金属膜层4和基材1之间设置有粘合层。本实施例粘合层优选为两层,包括基材1表面之上的第一粘合层2和位于第一粘合层2之上的第二粘合层3,所述第一粘合层为粘合剂层,第二粘合层为光油层。An ink layer 5 is arranged between the metal film layer 4 and the transparent film layer 6 to reflect the pattern color of the product. In order to increase the bonding force between the metal film layer 4 and the base material 1 while protecting the metal film layer 4 , an adhesive layer is provided between the metal film layer 4 and the base material 1 . The adhesive layer in this embodiment is preferably two layers, including a first adhesive layer 2 on the surface of the substrate 1 and a second adhesive layer 3 on the first adhesive layer 2, the first adhesive layer is an adhesive layer, and the second adhesive layer is a varnish layer.

所述壳体基材可以为各种塑胶基材,例如通常的电子产品所采用的塑胶材料,如聚酯、聚碳酸酯PC、丙烯腈-丁二烯-苯乙烯ABS、聚甲基丙烯酸甲酯PMMA、或它们之中至少两种的复合材料The housing substrate can be various plastic substrates, such as plastic materials commonly used in electronic products, such as polyester, polycarbonate PC, acrylonitrile-butadiene-styrene ABS, polymethacrylate Ester PMMA, or a composite of at least two of them

所述透明膜层6材料有许多种,如聚碳酸酯PC,聚对苯二甲酸乙二醇酯PET,聚甲基丙烯酸甲酯PMMA等。本例选用PC材质的片材,PC片材的成型及加工都较优良,表面光泽度、耐磨性能也较好。本例使用的PC片材为GE公司的DMX光面片材。There are many kinds of materials for the transparent film layer 6, such as polycarbonate PC, polyethylene terephthalate PET, polymethyl methacrylate PMMA and the like. In this example, the PC sheet is selected. The molding and processing of the PC sheet are relatively good, and the surface gloss and wear resistance are also good. The PC sheet used in this example is the DMX glossy sheet of GE Company.

在透明膜层6成型前,需要先在PC片材上依次成型印刷油墨层5、金属膜层4、第二粘合层3、第一粘合层2。Before the transparent film layer 6 is formed, the printing ink layer 5, the metal film layer 4, the second adhesive layer 3, and the first adhesive layer 2 need to be sequentially formed on the PC sheet.

所述印刷油墨层5,选用耐高温、附着力好、柔软性好且软化点高的油墨。本实施例使用的是德国宝龙公司的N2K系列油墨:油墨为N2K系列半透黄绿色油墨,稀释剂选用N2K097-003,加入量为15%;硬化剂选用N2K005,加入量为3%;所用印刷方法是网版印刷:选用150~300目/cm有色聚酯丝网,耐溶剂型感光涂层,印刷机为传统印刷机,印刷方法为业内技术人员熟知,此处不再过多描述。将印刷了油墨的PC片材放入烤箱里用80℃烘烤30分钟,使油墨中的溶剂挥发完全,彻底干燥。The printing ink layer 5 is selected from inks with high temperature resistance, good adhesion, good flexibility and high softening point. What this embodiment uses is the N2K series ink of Germany Powerlong Company: the ink is the N2K series translucent yellow-green ink, the thinner is selected from N2K097-003, and the addition is 15%; the hardener is selected from N2K005, and the addition is 3%; The printing method is screen printing: 150-300 mesh/cm colored polyester screen is selected, solvent-resistant photosensitive coating is used, and the printing machine is a traditional printing machine. The printing method is well known to those skilled in the industry, and will not be described here. Put the PC sheet printed with ink into the oven and bake at 80°C for 30 minutes to completely evaporate the solvent in the ink and dry it thoroughly.

所述金属层4可以为各种可以镀覆在所述壳体基材上的金属层,例如镍、铬、锡、铟、铟锡合金、铝或不锈钢,使本实用新型的壳体具有金属的质感。本实用新型实施例述金属层4优选为锡,该金属层的形成方法可以采用各种方法,在本实用新型中优选采用物理气相沉积(PVD)的方法,物理气相沉积(PVD)的方法包括溅射镀膜、离子镀膜、蒸发镀膜,优选采用蒸发镀膜的方法。蒸发镀膜的方法采用常规的方法进行,例如使用腾胜炉式蒸发设备,真空度为1-8×10-2Pa,预热功率为10%-30%(占总功率的百分比),预热时间10-20s;预熔功率25%-35%(占总功率的百分比),预熔时间15-25s;镀膜功率30%-60%(占总功率的百分比),镀膜时间为15-25s。溅射镀膜也是常规方法,例如使用友威水平镀膜机,清洗真空度1-5×10-2Pa,清洗功率600W,清洗时间20s,镀膜真空度2-5×10-3Pa,镀膜功率3KW,镀膜时间2S,镀膜次数一次。溅射镀膜的膜层比蒸发的要致密,也要薄一些,附着力比蒸发的好The metal layer 4 can be various metal layers that can be plated on the base material of the housing, such as nickel, chromium, tin, indium, indium tin alloy, aluminum or stainless steel, so that the housing of the present utility model has a metal layer. texture. The metal layer 4 described in the embodiment of the utility model is preferably tin, and various methods can be used for the formation method of the metal layer. In the utility model, the method of physical vapor deposition (PVD) is preferably used, and the method of physical vapor deposition (PVD) includes Sputtering coating, ion coating, evaporation coating, preferably adopt the method of evaporation coating. The method of evaporating and coating is carried out by conventional methods, such as using Tengsheng furnace evaporation equipment, the vacuum degree is 1-8×10-2Pa, the preheating power is 10%-30% (the percentage of the total power), the preheating time 10-20s; pre-melting power 25%-35% (percentage of total power), pre-melting time 15-25s; coating power 30%-60% (percentage of total power), coating time 15-25s. Sputtering coating is also a conventional method, for example, using a Youwei horizontal coating machine, the cleaning vacuum is 1-5×10 -2 Pa, the cleaning power is 600W, the cleaning time is 20s, the coating vacuum is 2-5×10 -3 Pa, and the coating power is 3KW , coating time 2S, coating times once. The film layer of sputtering coating is denser and thinner than that of evaporation, and its adhesion is better than that of evaporation

所述第二粘合层3采用德国宝龙公司的N2K093透明光油,可通过印刷工艺成型,印刷之前将附着有金属膜层4的PC片材的清洁,否则金属膜层4表面的脏污会引起印刷的色差和气泡等不良。印刷设备与印刷方法与上述印刷油墨层2相同。The second adhesive layer 3 adopts N2K093 transparent varnish from Baolong Company of Germany, which can be formed by printing process. Before printing, the PC sheet attached with the metal film layer 4 will be cleaned, otherwise the surface of the metal film layer 4 will be dirty. It will cause defects such as color difference and air bubbles in printing. The printing equipment and printing method are the same as the printing ink layer 2 above.

所述第一粘合层2采用水性粘合剂,印刷设备与印刷方法与上述印刷第二粘合剂3相同。当因粘合计较黏而导致印刷时有气泡产生时,可以加入一些消泡剂解决此问题,一般加入比例不超过0.5%,为了配合整个工艺,本实施例印刷了三遍粘合剂,每印刷一遍都要烘干后再进行下一遍印刷,且每一遍印刷都要保证质量,防止色差、杂质、气泡等不良出现。The first adhesive layer 2 uses a water-based adhesive, and the printing equipment and printing method are the same as the printing of the second adhesive 3 above. When there are air bubbles during printing due to the stickiness of the adhesive, some defoaming agent can be added to solve this problem. Generally, the proportion of addition should not exceed 0.5%. In order to cooperate with the whole process, this embodiment printed the adhesive three times, each The printing must be dried before the next printing, and the quality of each printing must be guaranteed to prevent color difference, impurities, bubbles and other defects.

将进行完上述工序的PC片材裁切成需要的尺寸,然后对PC料进行模压成型,将平整的PC片材成型为与基材1外表面配合的形状。模压成型对模具的设计与制造有严格的要求。必须注意成型模与注塑模的模腔相互配合,二者的形状、尺寸误差应有很高的加工精度。要避免出现锐角的转折,凡是转角处均应采用圆弧过渡方式。本实施例为高压成型,即用150℃以上的温度对进行了预热的PC片材在金属模具上以空气加压成型。成型过程需要注意调好成型温度,配置压力大小及保压时间,本例使用设备是LFORM100-A型高压成型机,成型温度380℃,烘烤时间7s,高压加压41Kg,保压6s,然后低压加压7Kg,保压5s。最后排气12s。The PC sheet after the above process is cut into the required size, and then the PC material is molded, and the flat PC sheet is formed into a shape that matches the outer surface of the substrate 1 . Compression molding has strict requirements on the design and manufacture of molds. Attention must be paid to the mutual cooperation between the forming mold and the cavity of the injection mold, and the shape and size errors of the two should have high processing accuracy. To avoid sharp corners, all corners should adopt a circular arc transition method. This embodiment is high-pressure molding, that is, the preheated PC sheet is molded with air on a metal mold at a temperature above 150°C. During the molding process, attention should be paid to adjusting the molding temperature, configuring the pressure and holding time. The equipment used in this example is LFORM100-A high-pressure molding machine. Pressurize 7Kg under low pressure and keep the pressure for 5s. Finally exhaust 12s.

将PC片材上不需要与基材1配合的部分冲切掉后,定型为透明膜层6。在基材1注射成型开始之前,预先定形的透明膜层6从背部镶入到注塑模具中。该注塑模具包括凹模与成型模(凸模),凹膜型腔的深度应比成型模的高度大一个透明膜层6的厚度,透明膜层6放入凹模后,将基材1的注塑料注射在透明膜层6的内表面,使注塑料与透明膜层6接合成一体固化成型。本实施例使用注塑料为PC7300,注塑温度260-275℃。所述注塑成型的方法已为本领域技术人员所公知,例如可以通过使用海天100吨级注塑成型机进行注塑成型。After the part of the PC sheet that does not need to cooperate with the base material 1 is punched off, it is shaped into a transparent film layer 6 . Before starting the injection molding of the substrate 1, the pre-shaped transparent film layer 6 is inserted into the injection mold from the back. This injection mold comprises die and molding die (convex die), the depth of concave film cavity should be bigger than the thickness of a transparent film layer 6 than the height of molding die, after transparent film layer 6 is put into die, the base material 1 The injection compound is injected on the inner surface of the transparent film layer 6, so that the injection compound and the transparent film layer 6 are bonded together to be solidified and molded. In this embodiment, the injection molding material used is PC7300, and the injection molding temperature is 260-275° C. The injection molding method is well known to those skilled in the art, for example, injection molding can be performed by using a Haitian 100-ton injection molding machine.

根据本实用新型实施例提供的塑胶壳体,所形成的第一粘合层2的厚度为20~70微米、优选为50微米,所形成的第二粘合层的厚度为15~25微米、优选为20微米,所形成的金属膜层的厚度为20~40纳米、优选为30纳米,所形成的油墨层的厚度为15~25微米、优选为20微米,所形成的透明膜层的厚度为0.1~0.2毫米、优选为0.175毫米。According to the plastic housing provided by the embodiment of the present invention, the formed first adhesive layer 2 has a thickness of 20-70 microns, preferably 50 microns, and the formed second adhesive layer has a thickness of 15-25 microns, Preferably 20 microns, the thickness of the formed metal film layer is 20-40 nanometers, preferably 30 nanometers, the thickness of the formed ink layer is 15-25 microns, preferably 20 microns, the thickness of the formed transparent film layer 0.1 to 0.2 mm, preferably 0.175 mm.

根据本实用新型提供的塑胶壳体,可以在壳体基材上实现高质量的金属高光亮度、色彩绚丽的效果和具有精美、精致纹理的图案,使得壳体的装饰效果更提高一步,且耐磨损,质量更高。According to the plastic shell provided by the utility model, high-quality metal high-brightness, colorful effects and patterns with exquisite and delicate textures can be realized on the base material of the shell, so that the decorative effect of the shell is further improved, and it is durable Worn, higher quality.

根据本实用新型提供的塑胶壳体,壳体的各种性能例如附着力、抗划痕性能、耐振动磨损性能仍可以保持很好的效果,如附着力百格试验测试可以达到0级(共有0、1、2、3、4和5级,0级最好),抗划痕可以达到2N,振动磨损可以达到2H(H为小时,一般要求1.5小时以上)。According to the plastic shell provided by the utility model, the various properties of the shell such as adhesion, scratch resistance, vibration and wear resistance can still maintain good effects, such as the adhesion test can reach level 0 (shared 0, 1, 2, 3, 4 and 5 grades, 0 grade is the best), scratch resistance can reach 2N, vibration wear can reach 2H (H is hour, generally requires more than 1.5 hours).

Claims (8)

1, a kind of plastic casing, this plastic casing comprise base material and the transparent film layer that is positioned on the described substrate surface, it is characterized in that this plastic casing also comprises metallic diaphragm, and this metallic diaphragm is between substrate surface and transparent film layer.
2, plastic casing according to claim 1 is characterized in that, this plastic casing also comprises the ink lay that can be arranged between described transparent film layer and the metallic diaphragm.
3, plastic casing according to claim 1 and 2 is characterized in that, this plastic casing also comprises the adhesive layer that is arranged between metallic diaphragm and the substrate surface.
4, plastic casing according to claim 3 is characterized in that, described adhesive layer comprises first adhesive layer and second adhesive layer that is positioned on first adhesive layer on the substrate surface.
5, plastic casing according to claim 4 is characterized in that, described first adhesive layer is an adhesive phase, and second adhesive layer is the gloss oil layer.
6, plastic casing according to claim 4, wherein, the thickness of described first adhesive layer is 15~100 microns, the thickness of described second adhesive layer is 15~40 microns, the thickness of described metallic diaphragm is 20~50 nanometers, described thickness transparent or that be printed on the ink lay of pattern color is 20~40 microns, and the thickness of described transparent film layer is 0.1~0.3 millimeter.
7, plastic casing according to claim 6, wherein, the thickness of described first adhesive layer is 20~70 microns, the thickness of described second adhesive layer is 15~25 microns, the thickness of described metallic diaphragm is 30~40 nanometers, described thickness transparent or that be printed on the ink lay of pattern color is 25~35 microns, and the thickness of described transparent film layer is 0.1~0.2 millimeter.
8, a kind of mobile phone is characterized in that, described phone housing requires 1 to 8 each described plastic casing to make by aforesaid right.
CNU200820095680XU 2008-07-15 2008-07-15 Plastic rubber case and mobile phone adopting the plastic rubber case Expired - Lifetime CN201234412Y (en)

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Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101993629A (en) * 2009-08-14 2011-03-30 比亚迪股份有限公司 Transfer printing type ultraviolet light curing ink composition, preparation method thereof and mobile phone casing using ink composition
CN103576779A (en) * 2013-10-29 2014-02-12 昆山市大久电子有限公司 Flexible computer shell
CN104411135A (en) * 2014-11-28 2015-03-11 广东欧珀移动通信有限公司 Product case, mobile terminal and method for manufacturing product case
CN104582375A (en) * 2014-12-10 2015-04-29 广东欧珀移动通信有限公司 Method, device and metal case for covering film on metal outer surface
CN105101688A (en) * 2015-07-08 2015-11-25 广东欧珀移动通信有限公司 Method for manufacturing a housing, housing and mobile terminal manufactured by the method
CN106553308A (en) * 2015-09-25 2017-04-05 广州市宝利邦德高分子材料有限公司 A kind of preparation method of plastics plating piece
CN108638729A (en) * 2018-04-13 2018-10-12 Oppo广东移动通信有限公司 Shell and preparation method thereof, mobile terminal
CN109825806A (en) * 2019-02-23 2019-05-31 厦门玉通光电有限公司 A kind of PET non-conductive film and preparation method thereof
CN110421991A (en) * 2018-05-01 2019-11-08 宝洁公司 Method for being applied to reflecting material on product and the product for having reflecting material thereon
CN111439049A (en) * 2019-01-17 2020-07-24 Oppo广东移动通信有限公司 Manufacturing method of structural member and mobile terminal
US10940685B2 (en) 2015-12-28 2021-03-09 The Procter & Gamble Company Method and apparatus for applying a material onto articles using a transfer component that deflects on both sides
US11141995B2 (en) 2015-12-28 2021-10-12 The Procter & Gamble Company Method and apparatus for applying a material onto articles with a pre-distorted transfer component
US11491803B2 (en) 2019-02-12 2022-11-08 The Procter & Gamble Company Method and apparatus for applying a material onto articles using a transfer component
US11752792B2 (en) 2020-03-09 2023-09-12 The Procter & Gamble Company Method and apparatus for applying a material onto articles using a transfer component

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101993629A (en) * 2009-08-14 2011-03-30 比亚迪股份有限公司 Transfer printing type ultraviolet light curing ink composition, preparation method thereof and mobile phone casing using ink composition
CN103576779A (en) * 2013-10-29 2014-02-12 昆山市大久电子有限公司 Flexible computer shell
CN104411135A (en) * 2014-11-28 2015-03-11 广东欧珀移动通信有限公司 Product case, mobile terminal and method for manufacturing product case
CN104582375A (en) * 2014-12-10 2015-04-29 广东欧珀移动通信有限公司 Method, device and metal case for covering film on metal outer surface
CN105101688B (en) * 2015-07-08 2019-03-15 Oppo广东移动通信有限公司 A method for manufacturing a casing, a casing and a mobile terminal manufactured using the method
CN105101688A (en) * 2015-07-08 2015-11-25 广东欧珀移动通信有限公司 Method for manufacturing a housing, housing and mobile terminal manufactured by the method
CN106553308B (en) * 2015-09-25 2021-08-06 广州市宝利邦德高分子材料有限公司 Preparation method of plastic plated part
CN106553308A (en) * 2015-09-25 2017-04-05 广州市宝利邦德高分子材料有限公司 A kind of preparation method of plastics plating piece
US10940685B2 (en) 2015-12-28 2021-03-09 The Procter & Gamble Company Method and apparatus for applying a material onto articles using a transfer component that deflects on both sides
US11141995B2 (en) 2015-12-28 2021-10-12 The Procter & Gamble Company Method and apparatus for applying a material onto articles with a pre-distorted transfer component
CN108638729A (en) * 2018-04-13 2018-10-12 Oppo广东移动通信有限公司 Shell and preparation method thereof, mobile terminal
CN108638729B (en) * 2018-04-13 2022-10-18 Oppo广东移动通信有限公司 Shell, preparation method thereof and mobile terminal
CN110421991A (en) * 2018-05-01 2019-11-08 宝洁公司 Method for being applied to reflecting material on product and the product for having reflecting material thereon
CN111439049A (en) * 2019-01-17 2020-07-24 Oppo广东移动通信有限公司 Manufacturing method of structural member and mobile terminal
US11491803B2 (en) 2019-02-12 2022-11-08 The Procter & Gamble Company Method and apparatus for applying a material onto articles using a transfer component
CN109825806A (en) * 2019-02-23 2019-05-31 厦门玉通光电有限公司 A kind of PET non-conductive film and preparation method thereof
US11752792B2 (en) 2020-03-09 2023-09-12 The Procter & Gamble Company Method and apparatus for applying a material onto articles using a transfer component

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