CN201214294Y - Composite plate containing phase change energy storage material - Google Patents
Composite plate containing phase change energy storage material Download PDFInfo
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- CN201214294Y CN201214294Y CNU2008200351239U CN200820035123U CN201214294Y CN 201214294 Y CN201214294 Y CN 201214294Y CN U2008200351239 U CNU2008200351239 U CN U2008200351239U CN 200820035123 U CN200820035123 U CN 200820035123U CN 201214294 Y CN201214294 Y CN 201214294Y
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- 239000002131 composite material Substances 0.000 title claims abstract description 49
- 238000004146 energy storage Methods 0.000 title claims abstract description 49
- 230000008859 change Effects 0.000 title claims description 40
- 239000011232 storage material Substances 0.000 title claims description 39
- 239000006260 foam Substances 0.000 claims abstract description 33
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 32
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 32
- 230000002093 peripheral effect Effects 0.000 claims abstract description 4
- 238000007789 sealing Methods 0.000 claims description 23
- 239000000758 substrate Substances 0.000 claims description 11
- 238000009413 insulation Methods 0.000 claims description 8
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 239000010949 copper Substances 0.000 claims description 3
- 229910001220 stainless steel Inorganic materials 0.000 claims description 3
- 239000010935 stainless steel Substances 0.000 claims description 3
- 239000012782 phase change material Substances 0.000 abstract description 25
- 239000007787 solid Substances 0.000 abstract description 6
- 239000012071 phase Substances 0.000 description 30
- 230000000694 effects Effects 0.000 description 12
- 238000005192 partition Methods 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 6
- 229920002635 polyurethane Polymers 0.000 description 5
- 239000004814 polyurethane Substances 0.000 description 5
- 239000004698 Polyethylene Substances 0.000 description 4
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- 239000007791 liquid phase Substances 0.000 description 3
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- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000005338 heat storage Methods 0.000 description 2
- 239000012774 insulation material Substances 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
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- 150000002739 metals Chemical class 0.000 description 1
- 239000003094 microcapsule Substances 0.000 description 1
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- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000010451 perlite Substances 0.000 description 1
- 235000019362 perlite Nutrition 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D20/00—Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00
- F28D20/02—Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00 using latent heat
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/14—Thermal energy storage
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- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Building Environments (AREA)
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Abstract
Description
技术领域 technical field
本实用新型涉及一种建筑、仪器设备上用的节能复合板(隔板或隔墙板),尤其设计一种相变蓄能材料复合板。The utility model relates to an energy-saving composite board (partition board or partition wall board) used in buildings and instruments, in particular to a phase-change energy-storage material composite board.
背景技术 Background technique
由于金属、石油、电力等基本原料价格飞涨、消耗量直线上升,人类社会不得不考虑在各个领域节能的问题,包括在建筑领域采用轻质、节能的建筑隔板或轻质复合节能板的问题;在建筑领域,现在已经采用的节能建筑隔板或轻质复合节能板,如用在方舱或活动房中的隔板,通常是在两层骨架(支撑板)之间,填充聚氨酯或聚乙烯泡沫板而形成,其中的骨架主要是钢板、铁板、铝板、玻璃钢板凳,起到承重的作用,其中间填充的聚氨酯、聚乙烯泡沫板或膨胀珍珠岩等轻质矿物保温材料主要起到保温、减轻重量的作用;聚氨酯或聚乙烯泡沫板的导热系数很低(在0.05以下),运用在方舱或活动房上,具有良好的热阻。但聚氨酯或聚乙烯泡沫板质量轻(密度<30KG/立方米),蓄热系数很小。因此,采用聚氨酯或聚乙烯泡沫板作为夹芯层的隔板或轻质复合节能板,其热惰性很差,受外界温度波动影响明显,保温节能效果不理想。Due to the soaring prices of basic raw materials such as metals, oil, and electricity, and the sharp increase in consumption, human society has to consider the issue of energy conservation in various fields, including the use of lightweight, energy-saving building partitions or lightweight composite energy-saving panels in the construction field. In the field of construction, the energy-saving building partitions or lightweight composite energy-saving panels that have been adopted now, such as partitions used in shelters or mobile houses, are usually filled with polyurethane or polyester between two layers of skeletons (supporting boards). Formed from ethylene foam boards, the skeleton of which is mainly steel plates, iron plates, aluminum plates, and glass-steel stools, which play a load-bearing role, and the lightweight mineral insulation materials such as polyurethane, polyethylene foam boards, or expanded perlite filled in the middle mainly play a role. The effect of heat preservation and weight reduction; the thermal conductivity of polyurethane or polyethylene foam board is very low (below 0.05), and it has good thermal resistance when used in shelters or mobile houses. However, polyurethane or polyethylene foam boards are light in weight (density <30KG/m3), and have a small heat storage coefficient. Therefore, polyurethane or polyethylene foam boards are used as partitions or lightweight composite energy-saving panels for the sandwich layer, which have poor thermal inertia, are significantly affected by external temperature fluctuations, and have unsatisfactory thermal insulation and energy-saving effects.
为了克服上述隔板或轻质节能复合板热惰性差、保温节能效果不理想的缺点,中国实用新型专利CN200968018Y提供了一种含有相变材料的轻质节能复合板,该含有相变材料的轻质节能复合板包括外支撑板和内支撑板,在外支撑板和内支撑板构成的空腔中,设置相变材料填充层;相变材料填充层在轻质保温材料填充层的一侧或两侧面上,或者在轻质保温材料填充层的中间。相变材料(Phase Change Material,PCM)是利用在其物相变化过程(熔化或凝固)中,吸收或释放的热量来进行潜热储能的物质,上述复合板即是利用了相变材料具有很高的蓄热系数的特点,以及在相变过程中,相变材料储存或释放能量而相变材料自身的温度在相变完成前几乎维持不变得特点,达到保温、节能的目的,将其填充在由内、外支撑板所构成的空腔内,从而能够使该含有相变材料的轻质复合节能板内的空间温度保持在一个较小的波动范围之内,“冬暖夏凉”,较之于以往使用的节能建筑隔板或轻质复合节能板,其控温节能效果更明显,且其质量轻、价格低,因此得到了广泛的应用。但相变材料在液相时会发生泄漏,为防止相变材料的泄漏,在该复合板内填充的相变材料只能为经过特殊技术制成的内部可发生固液相变的颗粒、粉末、块状复合相变材料,该复合相变材料在宏观上始终是固态形状,而在细观或微观尺度上发生固-液相变。所述的特殊技术为微胶囊技术、溶胶—凝胶技术、活性炭吸附、聚合物定性封装等。In order to overcome the above-mentioned shortcomings of poor thermal inertia and unsatisfactory thermal insulation and energy-saving effect of the separator or lightweight energy-saving composite panel, the Chinese utility model patent CN200968018Y provides a lightweight energy-saving composite panel containing phase change materials. The quality and energy-saving composite board includes an outer support plate and an inner support plate. In the cavity formed by the outer support plate and the inner support plate, a filling layer of phase change material is set; on the sides, or in the middle of the fill layer of lightweight insulation material. Phase Change Material (Phase Change Material, PCM) is a substance that uses the heat absorbed or released during its phase change process (melting or solidification) to store latent heat energy. The characteristics of high heat storage coefficient, as well as the characteristics that during the phase change process, the phase change material stores or releases energy and the temperature of the phase change material itself remains almost unchanged before the phase change is completed, so as to achieve the purpose of heat preservation and energy saving. It is filled in the cavity formed by the inner and outer support plates, so that the space temperature in the lightweight composite energy-saving panel containing phase change materials can be kept within a small fluctuation range, "warm in winter and cool in summer". Compared with the energy-saving building partitions or lightweight composite energy-saving panels used in the past, its temperature control and energy-saving effect is more obvious, and its weight is light and the price is low, so it has been widely used. However, the phase change material will leak when it is in the liquid phase. In order to prevent the leakage of the phase change material, the phase change material filled in the composite plate can only be particles and powders that can undergo solid-liquid phase change inside through special technology. 1. A bulk composite phase change material, the composite phase change material is always in a solid state macroscopically, but undergoes a solid-liquid phase transition on a mesoscopic or microscopic scale. The special technology mentioned is microcapsule technology, sol-gel technology, active carbon adsorption, polymer qualitative encapsulation and so on.
上述专利产品尽管已经使用多年,但仍存在一些缺点:1、由于上述含有相变材料的轻质节能复合板内填充的相变材料只能为经过特殊工艺技术制成的复合相变材料,其限制性大,且费用较高;2、由于该轻质节能复合板其主要特点是轻质和节能,为达到其要求,其内、外支撑板的板体都要求质量要轻,而将复合相变材料直接填充到由内、外支撑板所构成的空腔内,其支撑强度不高。Although the above-mentioned patented products have been used for many years, there are still some shortcomings: 1. Since the phase-change materials filled in the above-mentioned light-weight and energy-saving composite panels containing phase-change materials can only be composite phase-change materials made by special technology, its It is highly restrictive and expensive; 2. Since the main features of the lightweight energy-saving composite board are light weight and energy saving, in order to meet its requirements, the board body of the inner and outer support boards requires light weight, and the composite board The phase change material is directly filled into the cavity formed by the inner and outer support plates, and its support strength is not high.
因此,本实用新型从改进现有技术角度出发,提供一种含相变蓄能材料的复合板,以克服现有技术中的不足。Therefore, from the perspective of improving the prior art, the utility model provides a composite plate containing phase-change energy storage materials to overcome the deficiencies in the prior art.
发明内容 Contents of the invention
本实用新型提供一种含相变蓄能材料的复合板,其目的是解决现有轻质节能复合板其填充的相变材料只能是固态的复合相变材料及现有轻质节能复合板支撑强度不高的问题。The utility model provides a composite board containing phase change energy storage materials, the purpose of which is to solve the problem that the phase change material filled in the existing lightweight energy-saving composite board can only be a solid composite phase change material and the existing light energy-saving composite board The problem of low support strength.
为达到上述目的,本实用新型采用的技术方案是:一种含相变蓄能材料的复合板,包括基板,该基板由蜂窝板构成,蜂窝板两板面上分别设有密封层,该密封层将蜂窝板中的微孔腔密封成密封腔,所述密封腔内填充相变蓄能材料。In order to achieve the above purpose, the technical solution adopted by the utility model is: a composite plate containing phase change energy storage material, including a base plate, the base plate is composed of a honeycomb plate, and the two plates of the honeycomb plate are respectively provided with sealing layers. The layer seals the microporous cavity in the honeycomb panel into a sealed cavity, and the sealed cavity is filled with phase change energy storage material.
上述技术方案中的有关内容解释如下:The relevant content in the above-mentioned technical scheme is explained as follows:
1、上述方案中,所述密封层的外侧还设有一保温层。1. In the above solution, an insulation layer is provided outside the sealing layer.
2、上述方案中,所述蜂窝板为铝质蜂窝板不锈钢质蜂窝板、铜质蜂窝板等金属蜂窝板或纸质蜂窝板,由于蜂窝板内有大量的微孔腔(规则的蜂窝孔),可以提高相变蓄能材料的装载量,以达到更好的蓄能效果。2. In the above scheme, the honeycomb panels are metal honeycomb panels such as aluminum honeycomb panels, stainless steel honeycomb panels, copper honeycomb panels, or paper honeycomb panels. Since there are a large number of micropores (regular honeycomb holes) in the honeycomb panels , can increase the loading capacity of the phase change energy storage material to achieve a better energy storage effect.
3、上述方案中,可根据外界环境需要控制温度变化的范围来选择相应的相变蓄能材料。3. In the above solution, the corresponding phase change energy storage material can be selected according to the range of temperature change required by the external environment.
4、上述方案中,所述密封层可以为一板状,也可以为与蜂窝板尺寸配合的盒体。4. In the above solution, the sealing layer may be in the shape of a plate, or a box that matches the size of the honeycomb plate.
为达到上述目的,本实用新型采用的技术方案是:一种含相变蓄能材料的复合板,包括基板,该基板由铝泡沫板构成,铝泡沫板的周边微孔腔端面上分别设有密封层,该密封层将铝泡沫板中的微孔腔密封成密封腔,所述密封腔内填充相变蓄能材料。In order to achieve the above purpose, the technical solution adopted by the utility model is: a composite plate containing phase change energy storage material, including a base plate, the base plate is composed of an aluminum foam plate, and the peripheral microporous cavity end surfaces of the aluminum foam plate are respectively provided with The sealing layer seals the microporous cavities in the aluminum foam board into a sealed cavity, and the sealed cavity is filled with phase-change energy storage materials.
上述技术方案中的有关内容解释如下:The relevant content in the above-mentioned technical scheme is explained as follows:
1、上述方案中,所述铝泡沫板表面外侧上还设有一保温层。1. In the above solution, an insulation layer is provided on the outer surface of the aluminum foam board.
2、上述方案中,所述铝泡沫又称泡沫铝,是一种轻质的抗冲击的多孔材料,由其构成的铝泡沫板,其上大量的微孔腔(不规则的孔)可以提高相变蓄能材料的装载量,以达到更好的蓄能效果;铝泡沫板的上下两表面有分别有一板面,其四周侧壁为裸露在外的微孔腔端面。2. In the above scheme, the aluminum foam is also called aluminum foam, which is a lightweight impact-resistant porous material. The aluminum foam board made of it has a large number of micropores (irregular holes) on it that can improve The loading capacity of the phase change energy storage material is used to achieve better energy storage effect; the upper and lower surfaces of the aluminum foam board have a plate respectively, and the side walls around it are exposed microporous cavity end faces.
3、上述方案中,可根据外界环境需要控制温度变化的范围来选择相应的相变蓄能材料。3. In the above solution, the corresponding phase change energy storage material can be selected according to the range of temperature change required by the external environment.
由于上述技术方案运用,本实用新型与现有技术相比具有下列优点:Due to the application of the above-mentioned technical solutions, the utility model has the following advantages compared with the prior art:
1、由于本实用新型采用蜂窝板或铝泡沫板做基板,在蜂窝板或铝泡沫板内微孔腔内填充相变蓄能材料,然后再将其微孔腔端面用密封层密封,防止相变蓄能材料的泄漏,本实用新型适用于各种形态的相变蓄能材料,其相变蓄能材料选择范围广,且装载量大,蓄能效果佳,克服了以往轻质节能复合板只能用固态的复合相变材料,选择范围窄及费用较高的缺点。1. Since the utility model uses honeycomb board or aluminum foam board as the substrate, phase change energy storage materials are filled in the micropores of the honeycomb board or aluminum foam board, and then the end faces of the micropores are sealed with a sealing layer to prevent phase change. Leakage of variable energy storage materials, the utility model is suitable for various forms of phase change energy storage materials, its phase change energy storage materials have a wide range of choices, and the loading capacity is large, and the energy storage effect is good, which overcomes the previous lightweight energy-saving composite board Only solid composite phase change materials can be used, which has the disadvantages of narrow selection range and high cost.
2、由于本实用新型采用高强度的蜂窝板或铝泡沫板做基板,较之以往的轻质节能复合板提高了其支撑强度。2. Since the utility model adopts high-strength honeycomb board or aluminum foam board as the base plate, its supporting strength is improved compared with the previous light weight and energy-saving composite board.
附图说明 Description of drawings
附图1为本实用新型实施例一结构示意图;Accompanying
附图2为本实用新型实施例二结构示意图。Accompanying
以上附图中:1、蜂窝板;2、相变蓄能材料;3、密封层;4、保温层;5、铝泡沫板。In the above drawings: 1. Honeycomb panel; 2. Phase change energy storage material; 3. Sealing layer; 4. Thermal insulation layer; 5. Aluminum foam board.
具体实施方式 Detailed ways
下面结合附图及实施例对本实用新型作进一步描述:Below in conjunction with accompanying drawing and embodiment the utility model is further described:
实施例一:Embodiment one:
如图1所示,一种含相变蓄能材料的复合板,包括基板,该基板由蜂窝板1构成,蜂窝板1两板面上分别设有密封层3,其中一端的密封层3作为该复合板的内面板,另一端的密封层3作为该复合板的外面板;该密封层3将蜂窝板中的微孔腔密封成密封腔,所述密封腔内填充相变蓄能材料2。As shown in Figure 1, a composite panel containing a phase change energy storage material includes a substrate, the substrate is composed of a
其中,密封层3为一与蜂窝板1尺寸配合的板体,也可以为一与蜂窝板1尺寸配合的盒体,将蜂窝板1装配在该密封盒体内,以达到蜂窝板1的四周外壁外形美观,所述蜂窝板1为铝质蜂窝板不锈钢质蜂窝板、铜质蜂窝板等金属蜂窝板或纸质蜂窝板。Wherein, the
制作时,先将内面板与蜂窝板1一端的微孔腔端面粘结,使得内面板将蜂窝板1一端的微孔腔(蜂窝孔)密封住,然后将根据外界环境需要所选择的相变蓄能材料2填充到该微孔腔(蜂窝孔)中,再将外面板密封住蜂窝板1另一端的微孔腔(蜂窝孔),另外还可以在外面板上粘结一层聚苯乙烯保温层4,以达到更好的蓄能保温效果。During production, the inner panel is first bonded to the end surface of the microcavity at one end of the
由于本实用新型采用蜂窝板1做基板,在蜂窝板1微孔腔内填充相变蓄能材料2,然后再将其微孔腔端面用密封层3密封,防止相变蓄能材料2的泄漏,本实用新型适用于各种形态的相变蓄能材料2,其相变蓄能材料2的选择范围广,且装载量大,蓄能效果佳,克服了以往轻质节能复合板只能用固态的复合相变材料,选择范围窄及费用较高的缺点,且由于基板选用了强度高、重量轻、刚性大的蜂窝板1做基板,较之以往的轻质节能复合板提高了其支撑强度。且蜂窝板的侧面蜂窝孔壁自身有密封功能,所以,当该复合板制成后,可以根据使用需要任意裁剪尺寸,都能保证相变蓄能材料在其复合板材内的密封性,而不泄漏,以保证其稳定的蓄能效果。Since the utility model adopts the
实施例二:Embodiment two:
如图2所示,一种含相变蓄能材料的复合板,包括基板,该基板由铝泡沫板5构成,铝泡沫板5的周边微孔腔端面上分别设有密封层3(图中只示出了一个端面的密封层示意图,其他端面与其相同,这里不再详细描述),该密封层3将铝泡沫板5中的微孔腔密封成密封腔,所述密封腔内填充相变蓄能材料2。As shown in Figure 2, a kind of composite plate containing phase change energy storage material comprises a base plate, and this base plate is made of aluminum foam plate 5, and sealing
铝泡沫板5又称泡沫铝,是一种轻质的抗冲击的多孔材料,具有上下两个表面,其四周为裸露的微孔腔端面,铝泡沫板5上大量的微孔腔可以提高相变蓄能材料2的装载量,以达到更好的蓄能效果。Aluminum foam board 5, also known as aluminum foam, is a lightweight impact-resistant porous material with upper and lower surfaces surrounded by exposed micro-cavity end faces. A large number of micro-cavities on aluminum foam board 5 can improve the relative The loading amount of the
由于本实用新型采用铝泡沫板5做基板,在铝泡沫板5微孔腔内填充相变蓄能材料2,然后再将其微孔腔端面用密封层3密封,防止相变蓄能材料2的泄漏,本实用新型适用于各种形态的相变蓄能材料2,其相变蓄能材料2的选择范围广,且装载量大,蓄能效果佳,克服了以往轻质节能复合板只能用固态的复合相变材料,选择范围窄及费用较高的缺点,且由于基板选用了强度高、重量轻、刚性大的铝泡沫板5做基板,较之以往的轻质节能复合板提高了其支撑强度。Since the utility model adopts the aluminum foam board 5 as the substrate, the phase change
上述实施例只为说明本实用新型的技术构思及特点,其目的在于让熟悉此项技术的人士能够了解本实用新型的内容并据以实施,并不能以此限制本实用新型的保护范围。凡根据本实用新型精神实质所作的等效变化或修饰,都应涵盖在本实用新型的保护范围之内。The above-mentioned embodiments are only to illustrate the technical concept and characteristics of the present utility model, and its purpose is to enable those familiar with this technology to understand the content of the present utility model and implement it accordingly, and not to limit the protection scope of the present utility model. All equivalent changes or modifications made according to the spirit of the utility model shall fall within the protection scope of the utility model.
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| CN113400739A (en) * | 2021-07-15 | 2021-09-17 | 中国科学院苏州纳米技术与纳米仿生研究所 | Aerogel-containing phase change energy storage heat preservation plate and preparation method and application thereof |
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