CN201084354Y - High-brightness luminous, light-reflecting signboard - Google Patents
High-brightness luminous, light-reflecting signboard Download PDFInfo
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- CN201084354Y CN201084354Y CNU2007201270107U CN200720127010U CN201084354Y CN 201084354 Y CN201084354 Y CN 201084354Y CN U2007201270107 U CNU2007201270107 U CN U2007201270107U CN 200720127010 U CN200720127010 U CN 200720127010U CN 201084354 Y CN201084354 Y CN 201084354Y
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- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229910052742 iron Inorganic materials 0.000 claims abstract description 9
- 239000003973 paint Substances 0.000 claims abstract description 7
- 239000000463 material Substances 0.000 claims description 14
- 239000000758 substrate Substances 0.000 claims description 13
- 229910003668 SrAl Inorganic materials 0.000 claims description 6
- 241000779819 Syncarpia glomulifera Species 0.000 claims description 3
- 239000001739 pinus spp. Substances 0.000 claims description 3
- 229940036248 turpentine Drugs 0.000 claims description 3
- 239000002966 varnish Substances 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 10
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract description 2
- 238000012423 maintenance Methods 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 57
- 238000000034 method Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 3
- 238000004020 luminiscence type Methods 0.000 description 3
- 229910052761 rare earth metal Inorganic materials 0.000 description 3
- 230000000007 visual effect Effects 0.000 description 3
- 238000007590 electrostatic spraying Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000011241 protective layer Substances 0.000 description 2
- 150000002910 rare earth metals Chemical class 0.000 description 2
- 239000005084 Strontium aluminate Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000031700 light absorption Effects 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 239000005101 luminescent paint Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000002285 radioactive effect Effects 0.000 description 1
- 239000000941 radioactive substance Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- FNWBQFMGIFLWII-UHFFFAOYSA-N strontium aluminate Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Al+3].[Sr+2].[Sr+2] FNWBQFMGIFLWII-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
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Abstract
Description
技术领域 technical field
本实用新型涉及发光、反光标志牌的制作,是对现有指示或警示标志牌的改进,可用于制作楼牌、安全指示牌、防火标志牌、警示标志牌等。The utility model relates to the production of luminous and reflective signboards, which is an improvement on existing instruction or warning signboards, and can be used for making building signs, safety signboards, fireproof signboards, warning signboards and the like.
背景技术 Background technique
发光材料可以在太阳光或灯光等可见光照射下吸收并储存光能,光照停止后,在黑暗处将吸收的能量再以可见光的形式缓慢释放出来。过去使用ZnS型发光材料,虽然可以通过吸收光线并在无光情况下发光,但其发光强度低,所需吸收光源要求高(一般需紫外光作激发光源),发光时间也很短,只有十几分钟,若加入少量放射性物质后,虽可延长发光时间,提高亮度,但具有一定的放射性,对人体有一定伤害,同时其化学性质也不稳定,给实际的生产应用带来诸多不便因素。Luminescent materials can absorb and store light energy under the irradiation of visible light such as sunlight or light, and slowly release the absorbed energy in the form of visible light in the dark after the light stops. In the past, ZnS-type luminescent materials were used, although they can absorb light and emit light in the absence of light, but their luminous intensity is low, and the required absorption light source is high (generally ultraviolet light is required as the excitation light source), and the luminous time is also very short, only ten After a few minutes, if a small amount of radioactive substances are added, although the luminous time can be prolonged and the brightness can be increased, it has certain radioactivity and is harmful to the human body. At the same time, its chemical properties are also unstable, which brings many inconveniences to actual production and application.
稀土工业和稀土的应用是在20世纪60年代伴随着世界新技术潮流而迅猛崛起的一项新兴产业。稀土和应用稀土的产品已经广泛的深入到我们生活的各个领域。在铝酸锶体系中掺杂稀土元素的SrAl2O4:Eu2+,Dy3+是上世纪90年代发展起来的新型蓄光型发光材料,该材料的突出特点是发光强度和持续时间是传统ZnS发光材料的数十倍,而且材料本身无毒无害,不含任何放射性元素,稳定性和耐久性优良,吸光和发光过程可重复,低度照明、指示作用良好,给人们的生活生产带来了便利,又能节能节源不污染环境,符合绿色社会发展的要求。本实验室在文献报道的基础上对各组分的配比进行了优化,研制出初始亮度高,余辉时间长的SrAl2O4:Eu2+,Dy3+发光材料,并将该材料用于下游产品的研发。The rare earth industry and the application of rare earths are a new industry that rose rapidly in the 1960s along with the trend of new technologies in the world. Rare earths and their products have been widely used in every field of our lives. SrAl 2 O 4 :Eu 2+ doped with rare earth elements in the strontium aluminate system, Dy 3+ is a new light-storage luminescent material developed in the 1990s. The outstanding feature of this material is that the luminous intensity and duration are traditional Dozens of times that of ZnS luminescent materials, and the material itself is non-toxic and harmless, does not contain any radioactive elements, has excellent stability and durability, the process of light absorption and luminescence can be repeated, low-level lighting, and good indication function, which brings great benefits to people's life and production. It brings convenience, saves energy and sources, does not pollute the environment, and meets the requirements of the development of a green society. On the basis of literature reports, the laboratory optimized the ratio of each component, developed a SrAl 2 O 4 :Eu 2+ , Dy 3+ luminescent material with high initial brightness and long afterglow time, and used the material in the development of downstream products.
关于发光标志牌的制作方法已有许多的专利及文献报道,如:公开号CN 1108413A说明书中公开的发光标志牌,底牌表面采用静电喷涂工艺制成防护层,字码图案部位用丝网漏印干粉后再经170-190℃高温烧制成遮色层和发光层,该工艺需要有专门的静电喷涂设备,在高温烧制过程中会产生有害气体污染环境,发光层中的部分Eu2+也被氧化成Eu3+,减少了发光离子的数目,势必会影响整个发光层的发光效果。ZL专利号99229371.5说明书中介绍的长余辉发光标牌由基板、防护层、有色漆层、发光层、保护膜组成,在该组成结构中,有色漆层对发光层发出的光有一定吸收性,降低了发光层的发光强度。ZL专利号03215004.0介绍的长余辉发光牌,包括基板以及制备于基板上多层膜,该多层膜依次为底色层、反光层、发光层和户外型树脂透明保护层,所述的反光层与发光层为对应叠印的字符或图案标志,其余地方无反光层,这种长余辉发光牌在夜间有较好的发光效果。但这种结构布局在夜间遇到光线照射时,不能很好的突现出所要表达的文字或图案标志。ZL专利号98243539.8公开了一种反光标志牌,在发光油漆层上连有反光体,虽然实现了标志牌即可发光又可反光的目的,但这种结构设计会影响发光层的发光效率。ZL专利号02257587.1设计的发光反光标识板由基板、反光层和发光层组成,这种结构设计在夜间有较好的视觉效果。其使用的反光层为反光膜,这就要求所使用的油墨与反光膜有较好的匹配性,从而限制了原材料的选择性。与此同时,发光层的颜色是确定的,这对反光膜的选择提出了新的要求,以便白天衬托出反光层的颜色。There are many patents and literature reports about the production method of the luminous signboard, such as: the luminous signboard disclosed in the specification of the publication number CN 1108413A, the surface of the bottom plate is made of a protective layer by electrostatic spraying process, and the word code pattern part is printed with a silk screen After the dry powder is fired at a high temperature of 170-190°C to form a color-shielding layer and a luminescent layer, this process requires special electrostatic spraying equipment, and harmful gases will be produced during the high-temperature firing process to pollute the environment. Part of the Eu 2+ in the luminescent layer It is also oxidized to Eu 3+ , reducing the number of luminescent ions, which will inevitably affect the luminescence effect of the entire luminescent layer. The long afterglow luminescent signboard introduced in the ZL Patent No. 99229371.5 specification is composed of a substrate, a protective layer, a colored paint layer, a luminescent layer, and a protective film. The luminous intensity of the luminescent layer. The long afterglow luminescent sign introduced by ZL Patent No. 03215004.0 includes a substrate and a multilayer film prepared on the substrate. The corresponding superimposed characters or logos on the luminous layer, and no reflective layer in other places, this kind of long afterglow luminous card has a better luminous effect at night. However, when this structural layout is exposed to light at night, it cannot well highlight the text or pattern signs to be expressed. ZL Patent No. 98243539.8 discloses a reflective signboard, which is connected with a reflector on the luminescent paint layer. Although the purpose of the signboard can be luminous and reflective, this structural design will affect the luminous efficiency of the luminescent layer. The luminescent reflective sign board designed by ZL patent No. 02257587.1 is composed of a substrate, a reflective layer and a luminescent layer. This structural design has a better visual effect at night. The reflective layer used is a reflective film, which requires a good match between the ink used and the reflective film, thus limiting the selectivity of raw materials. At the same time, the color of the luminous layer is determined, which puts forward new requirements for the choice of reflective film, so that the color of the reflective layer can be set off during the day.
综上所述,关于既可发光又能反光的标志牌的报道甚少,在以往制作发光标志牌的工艺上还存在一些缺陷,势必会影响标牌在夜晚和白天的整体视觉效果,本实用新型的目的是对现有的工艺技术进行改进,降低生产成本,简化生产过程,提高标牌的视觉效果。To sum up, there are few reports about signboards that can both emit light and reflect light. There are still some defects in the process of making luminous signboards in the past, which will inevitably affect the overall visual effect of the signboard at night and during the day. The utility model The purpose is to improve the existing technology, reduce production costs, simplify the production process, and improve the visual effect of signs.
发明内容 Contents of the invention
本实用新型用高亮度的发光材料SrAl2O4:Eu2+,Dy3+取代传统的ZnS型发光材料作为发光层的发光基质,结合丝网印刷的优点,设计出一种既能发光又能反光的标志牌,该方法操作简单,无须专门的设备和多种助剂,降低了生产成本易于实现产业化生产。The utility model uses high-brightness luminescent material SrAl 2 O 4 :Eu 2+ , Dy 3+ to replace the traditional ZnS luminescent material as the luminescent matrix of the luminescent layer, and combines the advantages of screen printing to design a The reflective signboard has simple operation, does not need special equipment and various auxiliary agents, reduces production cost and is easy to realize industrialized production.
本实用新型技术方案采用了这样的结构:在矩形铁质基板一面上设有防锈漆层,在另一面上依次有底色层、无色反光层、白色的遮色层、发光层。The technical scheme of the utility model adopts such a structure: an antirust paint layer is provided on one side of the rectangular iron substrate, and a ground color layer, a colorless reflective layer, a white color-shielding layer, and a luminous layer are sequentially arranged on the other side.
所述底色层上均有无色反光层。There is a colorless reflective layer on the base color layer.
所述发光层由发光材料SrAl2O4:Eu2+,Dy3、清漆、松节油组成。The luminescent layer is composed of luminescent materials SrAl 2 O 4 :Eu 2+ , Dy 3 , varnish, and turpentine.
所述白色的遮色层与发光层均制作有文字或图案标志,两层的文字或图案标志对应叠印。Both the white color-shielding layer and the light-emitting layer are made with text or pattern marks, and the text or pattern marks of the two layers are overprinted correspondingly.
本实用新型与现有技术相比有如下优点:Compared with the prior art, the utility model has the following advantages:
1、本实用新型结构简单,不需要消耗电力。1. The utility model has a simple structure and does not require power consumption.
2、本实用新型的发光层使用了新型稀土长余辉蓄光材料,因此本实用新型的文字或图案层具有较强的蓄光能力,在光照射10-15分钟后,可持续发光10小时以上。2. The light-emitting layer of the present invention uses a new type of rare earth long-lasting light-storing material, so the text or pattern layer of the present invention has a strong light-storing ability, and can continue to emit light for more than 10 hours after being irradiated with light for 10-15 minutes.
3、本实用新型不仅能发光还能够反光,本实用新型在多层膜结构中设置了反光层,当夜晚有光照射标志牌时,通过反光层对光线的反射使得标志牌更加醒目。3. The utility model can not only emit light but also reflect light. The utility model is equipped with a reflective layer in the multi-layer film structure. When the signboard is illuminated by light at night, the reflective layer can reflect light to make the signboard more eye-catching.
附图说明 Description of drawings
下面结合附图对本实用新型的具体实施方式进一步详细说明。Below in conjunction with accompanying drawing, the specific embodiment of the present utility model is described in further detail.
图1为本实用新型具体实施例的结构剖视图。Fig. 1 is a structural sectional view of a specific embodiment of the present invention.
图2是图1所示具体实施例的平面示意图。Fig. 2 is a schematic plan view of the specific embodiment shown in Fig. 1 .
图1中各序号分别表示为:1、矩形铁质基板,2、蓝色底色层,3、无色反光层,4、白色遮色层,5、发光层,6、防锈漆层The serial numbers in Figure 1 are respectively represented as: 1. Rectangular iron substrate, 2. Blue background color layer, 3. Colorless reflective layer, 4. White color-shielding layer, 5. Light-emitting layer, 6. Anti-rust paint layer
具体实施方式 Detailed ways
参见图1,本实用新型的发光、反光标志牌,有六层结构组成:在矩形铁质基板(1)上设有蓝色底色层(2);在蓝色底色层(2)上设有无色反光层(3);在无色反光层(3)上依次为白色遮色层(4)和发光层(5),这两层为对应叠印的文字层;在矩形铁质基板(1)的背面设有防锈漆层(6)。Referring to Fig. 1, luminescence of the present utility model, reflective signboard, have six layers of structure to form: on the rectangular iron substrate (1), be provided with blue background color layer (2); On the blue background color layer (2) A colorless reflective layer (3) is provided; on the colorless reflective layer (3) are a white color-shielding layer (4) and a light-emitting layer (5) in sequence, and these two layers are corresponding overprinted text layers; on the rectangular iron substrate The back side of (1) is provided with antirust paint layer (6).
这种发光、反光标志牌的制作方法如下:对铁质基板(1)先进行脱脂、除锈处理后,在其一面刷上蓝色底漆层(2),在底漆层(2)上涂上无色反光层(3)。按照图2设计的内容制好网板,在无色反光层(3)上制作白色反光文字层(4),然后对应叠印发光文字层(5),图2中“学生公寓楼15”即为对应叠印的文字层,为达到良好的发光效果发光文字层(5)需印2~3遍使其厚度不低于0.5mm。发光层(5)由高亮度的发光材料SrAl2O4:Eu2+,Dy3+、清漆、松节油组成。最后在铁质基板(1)的背面刷上防锈漆层(6)。The manufacturing method of this luminous and reflective signboard is as follows: After degreasing and derusting the iron substrate (1), brush the blue primer layer (2) on one side of the iron substrate (1). Apply a colorless reflective layer (3). Prepare the screen according to the content of the design in Figure 2, make a white reflective text layer (4) on the colorless reflective layer (3), and then overprint the luminous text layer (5) correspondingly, the "student apartment building 15" in Figure 2 is Corresponding to the superimposed text layer, in order to achieve a good luminous effect, the luminous text layer (5) needs to be printed 2 to 3 times to make the thickness not less than 0.5 mm. The light-emitting layer (5) is composed of high-brightness light-emitting materials SrAl 2 O 4 :Eu 2+ , Dy 3+ , varnish, and turpentine. Finally, an antirust paint layer (6) is brushed on the back side of the iron substrate (1).
Claims (4)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNU2007201270107U CN201084354Y (en) | 2007-07-20 | 2007-07-20 | High-brightness luminous, light-reflecting signboard |
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| Application Number | Priority Date | Filing Date | Title |
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| CNU2007201270107U CN201084354Y (en) | 2007-07-20 | 2007-07-20 | High-brightness luminous, light-reflecting signboard |
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| CN201084354Y true CN201084354Y (en) | 2008-07-09 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102169659A (en) * | 2011-03-02 | 2011-08-31 | 方显峰 | Yellow-green and blue-green long-afterglow reflection combined traffic safety sign |
| CN102881236A (en) * | 2012-10-10 | 2013-01-16 | 陈华清 | Soft light-emitting diode (LED) indication plate sticker and manufacturing process thereof |
| CN103592707A (en) * | 2013-11-13 | 2014-02-19 | 浙江方远夜视丽反光材料有限公司 | Light-storage flame-retardant reflective stripe |
-
2007
- 2007-07-20 CN CNU2007201270107U patent/CN201084354Y/en not_active Expired - Fee Related
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102169659A (en) * | 2011-03-02 | 2011-08-31 | 方显峰 | Yellow-green and blue-green long-afterglow reflection combined traffic safety sign |
| CN102881236A (en) * | 2012-10-10 | 2013-01-16 | 陈华清 | Soft light-emitting diode (LED) indication plate sticker and manufacturing process thereof |
| CN103592707A (en) * | 2013-11-13 | 2014-02-19 | 浙江方远夜视丽反光材料有限公司 | Light-storage flame-retardant reflective stripe |
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Granted publication date: 20080709 Termination date: 20100720 |