CN201052990Y - Device for treating water by using oxidation-resisting composite reverse osmosis membrane - Google Patents
Device for treating water by using oxidation-resisting composite reverse osmosis membrane Download PDFInfo
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- CN201052990Y CN201052990Y CNU2007202003404U CN200720200340U CN201052990Y CN 201052990 Y CN201052990 Y CN 201052990Y CN U2007202003404 U CNU2007202003404 U CN U2007202003404U CN 200720200340 U CN200720200340 U CN 200720200340U CN 201052990 Y CN201052990 Y CN 201052990Y
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 67
- 238000001223 reverse osmosis Methods 0.000 title claims abstract description 44
- 239000012528 membrane Substances 0.000 title claims abstract description 40
- 239000002131 composite material Substances 0.000 title claims abstract description 21
- 230000003068 static effect Effects 0.000 claims abstract description 11
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000001914 filtration Methods 0.000 claims abstract description 8
- 239000003795 chemical substances by application Substances 0.000 claims abstract 2
- 238000005189 flocculation Methods 0.000 claims description 2
- 230000016615 flocculation Effects 0.000 claims description 2
- 239000003610 charcoal Substances 0.000 claims 2
- 239000002455 scale inhibitor Substances 0.000 claims 1
- 239000002351 wastewater Substances 0.000 claims 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 19
- 230000003647 oxidation Effects 0.000 abstract description 17
- 238000007254 oxidation reaction Methods 0.000 abstract description 17
- 239000005708 Sodium hypochlorite Substances 0.000 abstract description 8
- 238000003860 storage Methods 0.000 abstract description 8
- 239000008213 purified water Substances 0.000 abstract description 7
- 229910052799 carbon Inorganic materials 0.000 abstract description 6
- 238000004140 cleaning Methods 0.000 abstract description 4
- 238000012423 maintenance Methods 0.000 abstract description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 14
- 239000000460 chlorine Substances 0.000 description 14
- 229910052801 chlorine Inorganic materials 0.000 description 14
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 244000005700 microbiome Species 0.000 description 5
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000000084 colloidal system Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000005416 organic matter Substances 0.000 description 3
- 230000003204 osmotic effect Effects 0.000 description 3
- 238000001179 sorption measurement Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 241000700605 Viruses Species 0.000 description 2
- 230000003064 anti-oxidating effect Effects 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 230000002427 irreversible effect Effects 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000013535 sea water Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 239000002352 surface water Substances 0.000 description 2
- 108010077805 Bacterial Proteins Proteins 0.000 description 1
- 101710088194 Dehydrogenase Proteins 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000006004 Quartz sand Substances 0.000 description 1
- RHZUVFJBSILHOK-UHFFFAOYSA-N anthracen-1-ylmethanolate Chemical compound C1=CC=C2C=C3C(C[O-])=CC=CC3=CC2=C1 RHZUVFJBSILHOK-UHFFFAOYSA-N 0.000 description 1
- 239000003830 anthracite Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 230000030833 cell death Effects 0.000 description 1
- 210000002421 cell wall Anatomy 0.000 description 1
- XTEGARKTQYYJKE-UHFFFAOYSA-N chloric acid Chemical compound OCl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-N 0.000 description 1
- 229940005991 chloric acid Drugs 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000010612 desalination reaction Methods 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 208000018914 glucose metabolism disease Diseases 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000013327 media filtration Methods 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
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Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A20/00—Water conservation; Efficient water supply; Efficient water use
- Y02A20/124—Water desalination
- Y02A20/131—Reverse-osmosis
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- Separation Using Semi-Permeable Membranes (AREA)
- Water Treatment By Sorption (AREA)
Abstract
Description
技术领域 technical field
本实用新型涉及一种水处理的净化处理装置,特别涉及一种用耐氧化复合反渗透膜进行水处理的处理装置。The utility model relates to a purification treatment device for water treatment, in particular to a treatment device for water treatment with an oxidation-resistant composite reverse osmosis membrane.
背景技术 Background technique
反渗透膜是一种孔径小至纳米级,在一定的压力下,水分子才可以通过膜表面,从而可去除水中的无机盐、重金属离子、有机物、胶体、细菌、病毒等杂质。因此反渗透技术以其新型、高效、节能的分离技术在水及液体分离域占有重要位置,目前在海水淡化、中水回用、微污染地表水处理等多个领域得到广泛应用。The reverse osmosis membrane is a kind of pore size as small as nanometers. Under a certain pressure, water molecules can pass through the surface of the membrane, thereby removing impurities such as inorganic salts, heavy metal ions, organic matter, colloids, bacteria, and viruses in the water. Therefore, reverse osmosis technology occupies an important position in the field of water and liquid separation with its new, efficient and energy-saving separation technology. It is currently widely used in many fields such as seawater desalination, reclaimed water reuse, and micro-polluted surface water treatment.
但普通反渗透膜在使用过程中微生物污染是困拢反渗透实际使用的主要问题之一,由于我国所使用的自来水水源来自于河道、湖泊或水库,因河道、湖泊或水库的水中溶解氧(DO)含量高,含磷、氮等富营养物质多,水的TOC、COD、BOD值较高,气温、水温较高等特点,水中微生物种类多,繁殖快,在采用反渗透膜过滤时容易导致反渗透膜被微生物污染。同时微生物在反渗透膜表面的吸附和繁殖会导致反渗透表面的污堵,这种污堵往往采用清洗等手段依然是不可回复的,并且导致反渗透产水中存有微生物。因此目前将反渗透膜技术应用于水处理中,需要对进入反渗透系统之前水源进行非常好的预处理。现有的方法是建立在消毒、絮凝、澄清和介质过滤之上的多级处理,即使采取上述手段后对反渗透膜还是存在非常高的潜在污染。为维持水处理系统的产水量和水处理后的要求,致使反渗透膜必须频繁定期进行清洗。同时目前大多数反渗透膜元件供应商对进水中的游离氯有苛刻的要求,要求游离氯含量要<0.1mg/L,否则将会破坏渗透膜膜片结构,因此一些水处理系统设计为达到这一进水要求还需用还原剂还原水中余氯,或在反渗透系统前设置活性炭过滤器吸附水中余氯。However, microbial contamination during the use of ordinary reverse osmosis membranes is one of the main problems in the actual use of reverse osmosis. Since the tap water used in my country comes from rivers, lakes or reservoirs, the dissolved oxygen in the water of rivers, lakes or reservoirs ( DO) content is high, phosphorus, nitrogen and other eutrophic substances are abundant, water has high TOC, COD, and BOD values, and high air temperature and water temperature. The reverse osmosis membrane is fouled by microorganisms. At the same time, the adsorption and reproduction of microorganisms on the surface of the reverse osmosis membrane will lead to fouling on the surface of the reverse osmosis. This kind of fouling is often irreversible by cleaning and other means, and leads to the presence of microorganisms in the reverse osmosis product water. Therefore, the current application of reverse osmosis membrane technology in water treatment requires a very good pretreatment of the water source before entering the reverse osmosis system. The existing method is a multi-stage treatment based on disinfection, flocculation, clarification and media filtration. Even after the above methods are adopted, there is still a very high potential pollution to the reverse osmosis membrane. In order to maintain the water production rate of the water treatment system and the requirements after water treatment, the reverse osmosis membrane must be cleaned frequently and regularly. At the same time, most suppliers of reverse osmosis membrane components have strict requirements on the free chlorine in the feed water, requiring the free chlorine content to be less than 0.1mg/L, otherwise the membrane structure of the osmotic membrane will be damaged, so some water treatment systems are designed as To meet this water inlet requirement, it is necessary to use a reducing agent to reduce the residual chlorine in the water, or install an activated carbon filter before the reverse osmosis system to absorb the residual chlorine in the water.
实用新型内容Utility model content
本实用新型的目的在于:提供一种用耐氧化复合反渗透膜进行水处理的处理装置。通过将抗氧化的反渗透膜,应用在水处理中,使得水处理系统的处理步骤更加简化,处理装置更加简单,提高了反渗透系统使用周期和水处理效果好,可以克服现有技术的不足。The purpose of the utility model is to provide a treatment device for water treatment using an oxidation-resistant composite reverse osmosis membrane. By applying the anti-oxidation reverse osmosis membrane in water treatment, the treatment steps of the water treatment system are simplified, the treatment device is simpler, the service life of the reverse osmosis system is improved and the water treatment effect is good, and the shortcomings of the existing technology can be overcome .
本实用新型的实施方案:Embodiment of the utility model:
一种耐氧化复合反渗透膜进行水处理的处理装置:包括需净化水的储水罐1,其特点是:储水罐1通过管道2与多介质过滤罐3相连接,在管道2上连接有水泵4和絮凝剂投放器5;多介质过滤罐3通过管道6与静态混合器9连接,在管道6上连接有次氯酸钠投放器8和阻垢剂投放器18,静态混合器9通过管道与保安过滤器7连接,保安过滤器7通过管道10与内有耐氧化复合反渗透膜的过滤装置11相连接,在管道10上连接有高压泵12,内有耐氧化复合反渗透膜的过滤装置11通过管道与活性碳过滤器14相连接,在活性碳过滤器14上还连接有输出管道15A treatment device for water treatment with an oxidation-resistant composite reverse osmosis membrane: it includes a water storage tank 1 that needs to be purified, and is characterized in that: the water storage tank 1 is connected to a multimedia filter tank 3 through a pipeline 2, and connected to the pipeline 2 Water pump 4 and flocculant dispenser 5 are arranged; Multi-media filter tank 3 is connected with static mixer 9 through pipeline 6, and sodium hypochlorite dispenser 8 and
与现有技术相比,本实用新型通过在水处理中所采用的耐氧化复合反渗透膜代替现有渗透膜,因耐氧化复合反渗透膜具有的耐氯能力26000ppm/hrs,即在氯浓度为0.5mg/L条件下可长期稳定运行6年。通过利用耐氧化复合反渗透膜极强的耐氯能力,在需净化的水中加入次氯酸钠,次氯酸钠在水中形成次氯酸,因次氯酸作用于菌体蛋白质不仅可与细胞壁发生作用,且因次氯酸分子小,不带电荷,故侵入细胞内与蛋白质发生氧化作用或破坏其磷酸脱氢酶,使糖代谢失调而致细胞死亡。并且次氯酸在透过反渗透膜时会对产水侧进行消毒,减少了反渗透膜不可逆污染和苛刻的化学清洗和消毒要求,可延长渗透膜使用寿命,使得反渗透系统受微生物污染几率大大降低,延长清洗周期。同时抗氧化渗透膜的应用,不仅省略了现有技术中为吸附余氯而投入的还原剂或活性炭过滤器工序,而且次氯酸钠的投加,可以替代现有水处理工艺中用作吸附有机物,胶体有机硅类物质的活性炭过滤器。这样即简化了水处理系统的工艺流程,节省了设备投入、设备维护费用和占地面积,又提高了反渗透系统的使用周期和水处理效果好。因此本实用新型具有很好的推广价值,具有很好的经济效益和社会效益。Compared with the prior art, the utility model replaces the existing permeable membrane by the oxidation-resistant composite reverse osmosis membrane used in water treatment, because the oxidation-resistant composite reverse osmosis membrane has a chlorine resistance capacity of 26000ppm/hrs, that is, at the concentration of chlorine It can run stably for 6 years under the condition of 0.5mg/L. By using the strong chlorine resistance of the oxidation-resistant composite reverse osmosis membrane, sodium hypochlorite is added to the water to be purified, and sodium hypochlorite forms hypochlorous acid in the water. Because hypochlorous acid acts on the bacterial protein, it can not only interact with the cell wall, but also Chloric acid molecules are small and uncharged, so it invades cells to oxidize proteins or destroy their phosphate dehydrogenase, causing glucose metabolism disorders and cell death. In addition, hypochlorous acid will disinfect the product water side when it passes through the reverse osmosis membrane, which reduces the irreversible pollution of the reverse osmosis membrane and the harsh chemical cleaning and disinfection requirements, prolongs the service life of the osmosis membrane, and makes the reverse osmosis system more likely to be contaminated by microorganisms Greatly reduce and extend the cleaning cycle. At the same time, the application of the anti-oxidation osmotic membrane not only omits the reducing agent or activated carbon filter process for the adsorption of residual chlorine in the prior art, but also the addition of sodium hypochlorite can replace the existing water treatment process for the adsorption of organic matter, colloid Activated carbon filter with silicone-based substances. This not only simplifies the technological process of the water treatment system, saves equipment investment, equipment maintenance costs and floor space, but also improves the service life of the reverse osmosis system and improves the water treatment effect. Therefore the utility model has good popularization value, has good economic benefit and social benefit.
附图说明 Description of drawings
图1是本实用新型的结构示意图。Fig. 1 is the structural representation of the utility model.
具体实施方式 Detailed ways
本实用新型的实施例;如图1所示,净化水的储水罐1可以为储水池、河流、湖泊或自流水管,需净化水可以为河水,地表水或海水,储水罐1通过管道2与多介质过滤罐3连接,所述的管道可以为水渠或水管,多介质过滤罐3中的介质可为石英砂、无烟煤或锰砂等滤料,为保证储水罐1内的水能流入多介质过滤罐3,在管道2上连接有水泵4,同时为使净化水中的水中悬浮固体粒子和金属离子生成沉淀,在管道2上还连有絮凝剂投放器5;需净化水中的水中悬浮的固体粒子和金属离子与絮凝剂反应后形成的沉淀经多介质过滤罐3过滤后通过管道6与静态混合器9相连接,在连接多介质过滤罐3和静态混合器9的管道6上连接次氯酸钠投放器8和阻垢剂投放器18,通过静态混合器9将混入需净化水的次氯酸钠混合离解,次氯酸钠在需净化水中离解为氢氧化钠和次氯酸,静态混合器9通过管道与保安过滤器7连接,通过保安过滤器7对需净化水经行二次过滤,保安过滤器7通过管道10与内有耐氧化复合反渗透膜的过滤装置11相连接,因耐氧化复合反渗透膜须克服反渗透膜的渗透压才能达到过滤效果,所以在管道10上连接高压泵12,通过内有耐氧化复合反渗透膜的装置11中的耐氧化复合反渗透膜将需净化水中的无机盐、重金属离子、有机物、胶体、细菌和病毒进行过滤。同时添加在需净化水中的次氯酸钠在静态混合器9内充分混合离解后离解出次氯酸,通过次氯酸对耐氧化复合反渗透膜表面过滤过程中附着的微生物进行控制和灭杀,加入量以游离氯的含量不超过耐氧化复合反渗透膜的耐氯能力26000ppm/hrs为上限,并可参照中华人民共和国卫生部颁布的含氯消毒液推荐用量。通过内有耐氧化复合反渗透膜的过滤器11过滤后的净化水通过管道与活性碳过滤器14相连接,通过活性炭过滤器14去除净化水中余氯,使净化水最终达到使用要求,经活性碳过滤器14过滤后可通过输出管道15供给使用用户。根据使用客户的不同,可以对去除余氯的活性炭过滤器14进行调整,使净化后水中的余氯达到客户的使用要求。也可在输出管道15上设置保安过滤器17,对活性炭过滤器14内漏出的活性炭粉末进一步过滤。Embodiment of the present utility model; As shown in Figure 1, the water storage tank 1 of purified water can be a storage tank, a river, a lake or an artesian water pipe, and the water to be purified can be river water, surface water or seawater, and the water storage tank 1 passes through the pipeline 2 is connected with the multimedia filter tank 3, the pipeline can be a water channel or a water pipe, and the medium in the multimedia filter tank 3 can be filter materials such as quartz sand, anthracite or manganese sand, in order to ensure the water energy in the water storage tank 1 It flows into the multimedia filter tank 3, and a water pump 4 is connected to the pipeline 2. At the same time, in order to make the suspended solid particles and metal ions in the purified water generate precipitation, the pipeline 2 is also connected with a flocculant dispenser 5; the water in the water needs to be purified The precipitate formed after the suspended solid particles and metal ions react with the flocculant is filtered by the multimedia filter tank 3 and then connected to the static mixer 9 through the pipeline 6. On the pipeline 6 connecting the multimedia filter tank 3 and the static mixer 9 Connect the sodium hypochlorite dispenser 8 and the
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| CNU2007202003404U CN201052990Y (en) | 2007-05-08 | 2007-05-08 | Device for treating water by using oxidation-resisting composite reverse osmosis membrane |
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| CNU2007202003404U CN201052990Y (en) | 2007-05-08 | 2007-05-08 | Device for treating water by using oxidation-resisting composite reverse osmosis membrane |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103819017A (en) * | 2014-01-23 | 2014-05-28 | 北京东方润泽生态科技股份有限公司 | Sewage treatment method and system |
| JP2025060395A (en) * | 2023-09-29 | 2025-04-10 | Wota株式会社 | Water treatment system and method |
-
2007
- 2007-05-08 CN CNU2007202003404U patent/CN201052990Y/en not_active Expired - Lifetime
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103819017A (en) * | 2014-01-23 | 2014-05-28 | 北京东方润泽生态科技股份有限公司 | Sewage treatment method and system |
| JP2025060395A (en) * | 2023-09-29 | 2025-04-10 | Wota株式会社 | Water treatment system and method |
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