CN201010552Y - Device for processing beverage water and wine by way of electrolyzation or electrodialysis - Google Patents
Device for processing beverage water and wine by way of electrolyzation or electrodialysis Download PDFInfo
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- CN201010552Y CN201010552Y CN 200720005880 CN200720005880U CN201010552Y CN 201010552 Y CN201010552 Y CN 201010552Y CN 200720005880 CN200720005880 CN 200720005880 CN 200720005880 U CN200720005880 U CN 200720005880U CN 201010552 Y CN201010552 Y CN 201010552Y
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- electrodialysis
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- barrier film
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 75
- 235000013361 beverage Nutrition 0.000 title claims abstract description 17
- 235000014101 wine Nutrition 0.000 title description 24
- 238000012545 processing Methods 0.000 title description 13
- 238000005868 electrolysis reaction Methods 0.000 claims abstract description 82
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- 150000001450 anions Chemical class 0.000 claims description 3
- 235000016213 coffee Nutrition 0.000 abstract description 29
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- 229910052500 inorganic mineral Inorganic materials 0.000 abstract description 15
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- 238000006479 redox reaction Methods 0.000 abstract description 3
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- 238000004519 manufacturing process Methods 0.000 abstract 1
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- 238000012360 testing method Methods 0.000 description 16
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- 241000234435 Lilium Species 0.000 description 9
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 9
- 125000002091 cationic group Chemical group 0.000 description 9
- 239000010936 titanium Substances 0.000 description 9
- 229910052719 titanium Inorganic materials 0.000 description 9
- 241000219095 Vitis Species 0.000 description 8
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- 235000014787 Vitis vinifera Nutrition 0.000 description 8
- 230000008859 change Effects 0.000 description 8
- CWVRJTMFETXNAD-FWCWNIRPSA-N 3-O-Caffeoylquinic acid Natural products O[C@H]1[C@@H](O)C[C@@](O)(C(O)=O)C[C@H]1OC(=O)\C=C\C1=CC=C(O)C(O)=C1 CWVRJTMFETXNAD-FWCWNIRPSA-N 0.000 description 7
- PZIRUHCJZBGLDY-UHFFFAOYSA-N Caffeoylquinic acid Natural products CC(CCC(=O)C(C)C1C(=O)CC2C3CC(O)C4CC(O)CCC4(C)C3CCC12C)C(=O)O PZIRUHCJZBGLDY-UHFFFAOYSA-N 0.000 description 7
- CWVRJTMFETXNAD-KLZCAUPSSA-N Neochlorogenin-saeure Natural products O[C@H]1C[C@@](O)(C[C@@H](OC(=O)C=Cc2ccc(O)c(O)c2)[C@@H]1O)C(=O)O CWVRJTMFETXNAD-KLZCAUPSSA-N 0.000 description 7
- 235000001368 chlorogenic acid Nutrition 0.000 description 7
- CWVRJTMFETXNAD-JUHZACGLSA-N chlorogenic acid Chemical compound O[C@@H]1[C@H](O)C[C@@](O)(C(O)=O)C[C@H]1OC(=O)\C=C\C1=CC=C(O)C(O)=C1 CWVRJTMFETXNAD-JUHZACGLSA-N 0.000 description 7
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- FFQSDFBBSXGVKF-KHSQJDLVSA-N chlorogenic acid Natural products O[C@@H]1C[C@](O)(C[C@@H](CC(=O)C=Cc2ccc(O)c(O)c2)[C@@H]1O)C(=O)O FFQSDFBBSXGVKF-KHSQJDLVSA-N 0.000 description 7
- BMRSEYFENKXDIS-KLZCAUPSSA-N cis-3-O-p-coumaroylquinic acid Natural products O[C@H]1C[C@@](O)(C[C@@H](OC(=O)C=Cc2ccc(O)cc2)[C@@H]1O)C(=O)O BMRSEYFENKXDIS-KLZCAUPSSA-N 0.000 description 7
- 235000020095 red wine Nutrition 0.000 description 6
- PPASLZSBLFJQEF-RXSVEWSESA-M sodium-L-ascorbate Chemical class [Na+].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RXSVEWSESA-M 0.000 description 6
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- BOKGTLAJQHTOKE-UHFFFAOYSA-N 1,5-dihydroxynaphthalene Chemical compound C1=CC=C2C(O)=CC=CC2=C1O BOKGTLAJQHTOKE-UHFFFAOYSA-N 0.000 description 1
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Abstract
The utility model discloses a device using electrolysis method or electro dialysis method to process the drinking water and alcoholic drinks. The device using the electrolysis method or electro dialysis method to process the drinking water and alcoholic drinks comprises: an electrolysis groove or an electro dialysis groove. The electrolysis groove or the electro dialysis groove is provided with a diaphragm used for completing the reactions of reduction and oxidation. Under the conditions on not using the chemicals, the device in the utility model is used to enhance and improve the quality of the drinking water (cold drink, mineral water, fruit juice, coffee, milk, black tea, green tee, or other mixed liquid etc.) and the alcoholic drinks through the electric oxidation-reduction reaction generated in the solution. Through the useful effect of electric chemical reaction to improve the water neutrality, the problem can be solved that because the composition except the water can't be well melted into the water so that the taste is declined, thereby manufacturing the beverages and alcoholic drinks with excellent quality.
Description
Technical field
The utility model relates to a kind of method and device that improves sweet water and drinks quality by electrolysis or electrodialysis.
Background technology
Use many methods in order to improve sweet water (refreshment drink, mineral water, fruit juice, coffee, milk, black tea, green tea or its mixing liquid etc.) and drinks quality in the past, recorded and narrated the method for several typical.
Use chemical additive to adjust PH, the method for carrying out anti-oxidation processing; By heating albumen is changed, thereby change the method for the quality of product; Solution is trapped in the hold-up vessel for a long time, makes its sophisticated method.
, even if use diverse ways to handle, but some problems are arranged all.For example: when using chemical, can produce the problem of drinks themselves security; Oxidizing reaction is fiercer than normal temperature during heating, may reduce quality; Handle if carry out maturation, except that needs the time, problems such as oxidation take place in maturation simultaneously, also may cause quality to descend.
As the countermeasure of improving, in product, do not add chemical, do not heat and handle, the idea that adds the device that oxidizing reaction does not take place in ripening process implements all and is difficult to.
Summary of the invention
The purpose of this utility model provides a kind of device that uses electrolysis or electrodialysis mode to handle sweet water and drinks, do not using under the chemical condition at first to solve, by electricity the problem that redox reaction improves sweet water and drinks quality taking place in solution, secondly solves water and the property problem of utilizing electrochemical reaction effectively to improve the composition beyond the water in the beverage.
The device that use electrolysis described in the utility model or electrodialysis mode are handled sweet water and drinks comprises: electrolysis or electrodialysis groove, be positioned at the electrode of electrolysis or electrodialysis groove both sides and be positioned at electrolysis or electrodialysis the groove in addition corresponding beverage that is provided with in both sides or the entrance and exit of drinks.
Use electrolysis or electrodialysis mode to handle sweet water and drinks device as mentioned above, in electrolysis or electrodialysis groove, groove side directions along the electrode place, one deck is set does not have ion selective separator, be positioned at the groove of barrier film both sides, form two electrolysis or electrodialysis treatment channel, and be provided with separately beverage or the entrance and exit of drinks.
Use electrolysis or electrodialysis mode to handle sweet water and drinks device as mentioned above, in electrolysis or electrodialysis groove, groove side directions along the electrode place, one deck cation exchange membrane is set, be positioned at the groove of barrier film both sides, form two electrolysis or electrodialysis treatment channel, and be provided with separately beverage or the entrance and exit of drinks.
Use electrolysis or electrodialysis mode to handle sweet water and drinks device as mentioned above, in electrolysis or electrodialysis groove, groove side directions along the electrode place, one deck anionresin barrier film is set, be positioned at the groove of barrier film both sides, form two electrolysis or electrodialysis treatment channel, and be provided with separately beverage or the entrance and exit of drinks.
Use electrolysis or electrodialysis mode to handle sweet water and drinks device as mentioned above, the two ends of undivided cell wherein or electrodialysis groove, the electrolyzer that is provided with no ion selective separator or electrodialysis groove all are inlets of sweet water of the same race or drinks.
Use electrolysis or electrodialysis mode to handle sweet water and drinks device as mentioned above, in electrolyzer or electrodialysis groove, along the described groove side directions of electrode, cation exchange membrane, anionresin barrier film are set, electrolysis that forms between anionresin barrier film and negative electrode, cation exchange membrane and anionresin barrier film and cation exchange membrane and anode or electrodialysis treatment channel are independent separately, have the inlet of corresponding separately sweet water or drinks.
Use electrolysis or electrodialysis mode to handle sweet water and drinks device as mentioned above, in electrolyzer or electrodialysis groove, groove side directions along the electrode place, two-layer no ion selective separator is set, or one deck does not have ion selective separator and one deck positively charged ion or anion membrane, between above-mentioned two-layer barrier film and electrode and two-layer barrier film, form separately independently electrolysis or electrodialysis treatment channel, have the corresponding sweet water or the inlet of drinks separately.
Use electrolysis or electrodialysis mode to handle sweet water and drinks device as mentioned above, between the inlet of described electrolyzer and the outlet, form a circulation passage by recycle pump, surge tank and pipeline, described circulation passage is connected between the inlet and outlet of same electrolysis or electrodialysis treatment channel, or be connected between the inlet and outlet of different electrolysis or electrodialysis treatment channel, form single passage circulation or hyperchannel loop structure.
Method described in the utility model and device are under the condition of not using chemical, by electricity redox reaction taking place in solution, improves and improve the quality of sweet water (refreshment drink, mineral water, fruit juice, coffee, milk, black tea, green tea or its mixing liquid etc.) and drinks.Useful effect by the electrochemical reaction recorded and narrated above improves water and property, solves because of the composition beyond the water can not incorporate in the water well, and the problem that the taste that causes descends, and then produce colory beverage and drinks.This treatment process is compared with the method that additives such as adding chemical carries out the modification processing, and it just makes the solution energising, so necessity is not added chemical again.Aspect raising water and property, when the maturation of drinks is handled, can improve alcoholic acid water and property by the electrolysis treatment of moment, thereby make it reach the effect same in addition with the wine of standing storage.The characteristics of this treatment process are not use chemical, and its reduction reaction, oxidizing reaction are only undertaken by electricity, so control performance is good.Reactions such as the application that is accompanied by membrane technique can also be reduced selectively, oxidation.In addition, owing to improved its water and property, make product directly carry out electrolysis treatment or directly carry out electrodialysis and handle,, and can carry out maturation processing compared with its efficient height of original method.
Description of drawings
Shown in Figure 1 is the species structure graph of a relation of the utility model electrolyzer or electrodialysis groove.
Shown in Figure 2 is the structure of aseptate electrolyzer of the utility model or electrodialysis groove.
Shown in Figure 3 is the structure that the utlity model has membranous electrolyzer or electrodialysis groove.
Shown in Figure 4 is the structure that diaphragm sell or electrodialysis groove are arranged that the utlity model has single groove circulation loop.
Shown in Figure 5 is the structure that diaphragm sell or electrodialysis groove are arranged that the utlity model has two groove circulation loops.
Shown in Figure 6 is the structure that the utlity model has two diaphragm sells or electrodialysis groove.
Shown in Figure 7 is the utility model after electrolysis treatment not as the variation synoptic diagram of PH, the ORP of sodium ascorbate salts solution.
Shown in Figure 8 is the chromatography analysis chart of the coffee of the utility model after electrolytic reduction is handled.
The chromatography analysis chart of the coffee that shown in Figure 9 is handles without electrolytic reduction.
Figure 10 is the different change curves of pH value when respectively 10 liters of japanese wine solution pass through electrolyzer 3 times.
Figure 11 is the different change curves of ORP value when respectively 10 liters of japanese wine solution pass through electrolyzer 3 times.
Figure 12 is the different change curves of pH value when respectively 10 liters of grape wine solution pass through electrolyzer 3 times.
Figure 13 is the different change curves of ORP value when respectively 10 liters of grape wine solution pass through electrolyzer 3 times.
Embodiment
Attached number description: 1 positive pole, 2 negative poles, 3 neutral films, 4 anonite membranes, 5 cathodic coatings, 6 barrier films (neutral film, anonite membrane, cathodic coating), 7 need interpolation mouth, 8 cathodic coatings or neutral film, 9 anonite membranes or the neutral film of material.
The utility model adds voltage method and is meant immerses electrode in solution in solution, pressurize on electrode.This device (part of pressurizing device in solution) is referred to as electrolyzer or electrodialysis groove in the utility model.The kind of electrolyzer or electrodialysis groove by shown in Figure 1, is used electrolyzer or electrodialysis groove according to the different or selection of its object solution, processing intent from system.
Next will be illustrated example of the present utility model in conjunction with diagram.Fig. 2 is for allowing sweet water (refreshment drink, mineral water, carbonated drink, coffee, milk, black tea or its mixing liquid etc.) flow into devices such as electrolyzer in the undivided cell or electrodialysis groove.It is the difference according to solution, carries out electrolysis or electrodialysis processing with this method, thereby carries out the reduction processing of object solution and the device of oxide treatment.
Fig. 3-1 is depicted as to diaphragm sell being arranged or the device that adds sweet water (refreshment drink, mineral water, carbonated drink, coffee, milk, black tea, green tea or its mixing liquid etc.) and drinks etc. in the barrier film electrodialysis groove being arranged.This device is neutral diaphragm sell, upward is among the figure to be reducing bath down by oxidation trough, can carry out electrochemical oxidation and reduction processing to beverage and drinks simultaneously, makes the positively charged ion of solution, the device that negatively charged ion moves simultaneously.
Fig. 3-2 is depicted as to diaphragm sell (anonite membrane) being arranged or the device that adds sweet water (refreshment drink, mineral water, carbonated drink, coffee, milk, black tea, green tea or its mixing liquid etc.) and drinks etc. in the barrier film electrodialysis groove being arranged.This device can carry out electrochemical oxidation simultaneously to beverage and drinks, reduction is handled.Only there is positively charged ion to move to cathode can in the solution of inflow anode slot from anode slot.The positively charged ion, the negatively charged ion that flow in the solution of cathode can are not moved, so it is the electrochemical reduction treatment unit that the formation that flows into solution is changed.
Fig. 3-3 is depicted as to diaphragm sell (cathodic coating) being arranged or the device that adds sweet water (refreshment drink, mineral water, carbonated drink, coffee, milk, black tea, green tea or its mixing liquid etc.) and drinks etc. in the barrier film electrodialysis groove (cathodic coating) being arranged.This device can carry out electrochemical oxidation simultaneously to beverage and drinks, reduction is handled.Only there is negatively charged ion to move in the solution of inflow cathode can from cathode can anode groove.The positively charged ion, the negatively charged ion that flow in the solution of anode slot are not moved, so it is the electrochemical oxidation treatment unit that the formation that flows into solution is changed.
Fig. 3-4 is depicted as to diaphragm sell (paying no attention to the barrier film kind) being arranged or having in the oxidation trough and reducing bath of barrier film electrodialysis groove (paying no attention to the barrier film kind), adds the device of same sweet water (refreshment drink, mineral water, carbonated drink, coffee, milk, black tea, green tea or its mixing liquid etc.) or same drinks.Just can carry out oxidation and reductive device simultaneously to same solution.
Fig. 3-5 be depicted as to diaphragm sell (paying no attention to the barrier film kind) is arranged or the oxidation of barrier film electrodialysis groove is arranged and reducing bath in add the device of different types of sweet water (refreshment drink, mineral water, carbonated drink, coffee, milk, black tea, green tea or its mixing liquid etc.) or different sorts wine, comprise the mixture of sweet water and wine.
Fig. 3-6 is depicted as the device that adds desired material before the electrolysis treatment in sweet water (refreshment drink, mineral water, carbonated drink, coffee, milk, black tea, green tea or its mixing liquid etc.) in flowing into electrolyzer or electrodialysis groove and the drinks, is in order to increase the device of mineral quality.Substance is because electrolysis treatment can improve the activity of its material.
Fig. 3-7 is depicted as Fig. 6-6 and is depicted as the device that adds desired material after the electrolysis treatment in sweet water (refreshment drink, mineral water, carbonated drink, coffee, milk, black tea, green tea or its mixing liquid etc.) in flowing into electrolyzer or electrodialysis groove and the drinks, is in order to increase the device of mineral quality.Substance itself is not carried out the processing of electrolysis treatment or electrodialysis, so be difficult to cause problems such as rotten.
Shown in Figure 4 is to allow effusive sweet water from electrolyzer or electrodialysis groove (refreshment drink, mineral water, carbonated drink, coffee, milk, black tea, green tea or its mixing liquid etc.) and drinks once more by the device in the same direction inflow groove, be to allow circulate once more flow into device the same groove from reducing bath or the effusive solution of oxidation trough, be if want that object solution is carried out forceful electric power to be separated and handle or electrodialysis when handling, according to said method carry out repeatedly electrolysis or the device handled of electrodialysis repeatedly.
Shown in Figure 5 is to allow press reverse direction once more from oxidation trough or the effusive sweet water of electrodialysis groove (refreshment drink, mineral water, carbonated drink, coffee, milk, black tea, green tea or its mixing liquid etc.) and drinks and flow into device the groove, is to allow from reducing bath or oxidation trough effusive solution flow into circulation device in the groove of other direction once more.Carrying out using this method when oxide treatment and reduction are handled.
Figure 6 shows that compound use negative electrode, anonite membrane processing sweet water or the device of drinks.Sweet water B among the figure is the sweet water that ionic concn is reduced owing to electrolyzer or electrodialysis groove.Sweet water A increases negatively charged ion, and sweet water C increases positively charged ion.So owing to used such electrolyzer or the electrodialysis groove just has corresponding reaction.Sweet water B is that positively charged ion, negatively charged ion move to the groove on both sides, and ionic concn reduces.Sweet water A is because the negatively charged ion among the sweet water B moves, thereby anion concentration is increased.Sweet water C is because the positively charged ion among the sweet water B moves, thereby cation concn is increased.
PH when Figure 7 shows that in the electrolyzer of Fig. 3-2 electrolysis sodium ascorbate salt and the changing conditions of ORP.
Figure 8 shows that the result who the solution before and after the electrolysis treatment is analyzed according to the liquid chromatography.
Because of the electrolysis of Fig. 7 makes pH value deflection alkalescence, also shown the reductibility of 0RP.
Can understand through Fig. 8 electrolysis sodium ascorbate salts solution not rotten.
From experimental result, do not use any additives, the redox of solution takes place owing to electro-reduction reaction.
In the synoptic diagram 2-Fig. 6 that provides, selected Fig. 3-5 does experiment.
Put down in writing among Fig. 3-5 and can add different liquid, but be only limited to the water of specifying beverage (wine, beverages such as coffee) and can reach the tap water sanitation degree.
Under this condition, carried out the test of grape wine and japanese wine.
The test of zero japanese wine
＜test conditions 〉
The electrolyzer formation → shown in Fig. 3-5
2 * 2 of electrode area → 200cm (lily gilding 1 μ, titanium metal mother metal)
Barrier film → cationic exchange membrane
Wine flow → 0.5 liter/minute
Tap water flow → 0.5 liter/minute
Faradaic current → 4A (deciding electric current)
It is to instigate japanese wine to flow to negative electrode one side that reduction is handled, and makes tap water flow to anode one side.
Oxide treatment is to instigate tap water to flow to negative electrode one side, makes japanese wine flow to anode one side.
Reduce and handle back PH and be alkalescence, carry out oxide treatment after PH for acid.
Figure 10 is that the difference of pH value changed when respectively 10 liters of solution passed through electrolyzer 3 times.
The line segment of top is represented to reduce the difference of the pH value handled and is changed among the figure, and following line segment represents that the difference of the pH value of oxide treatment changes.
＜test conditions 〉
The electrolyzer formation → shown in Fig. 3-5
2 * 2 of electrode area → 200cm (lily gilding 1 μ, titanium metal mother metal)
Barrier film → cationic exchange membrane
Wine flow → 0.5 liter/minute
Tap water flow → 0.5 liter/minute
Faradaic current → 4A (deciding electric current)
It is to instigate japanese wine to flow to negative electrode one side that reduction is handled, and makes tap water flow to anode one side.
Oxide treatment is to instigate tap water to flow to negative electrode one side, makes japanese wine flow to anode one side.
By being carried out redox respectively, japanese wine handles the variation of measuring ORP.
Reducing and handling back ORP is reductibility, carries out that ORP is an oxidisability after the oxide treatment.
Figure 11 is that the difference of ORP value when respectively 10 liters of solution pass through electrolyzer 3 times changes.
The line segment of top is represented to reduce the difference of the ORP value handled and is changed among the figure, and following line segment is represented the difference variation of the ORP value of oxide treatment.
Zero test vinous
＜test conditions 〉
The electrolyzer formation → shown in Fig. 3-5
2 * 2 of electrode area → 200cm (lily gilding 1 μ, titanium metal mother metal)
Barrier film → cationic exchange membrane
Grape wine flow → 0.5 liter/minute
Tap water flow → 0.5 liter/minute
Faradaic current → 4A (deciding electric current)
It is to instigate grape to flow to negative electrode one side that reduction is handled, and makes tap water flow to anode one side.
Oxide treatment is to instigate tap water to flow to negative electrode one side, makes grape wine flow to anode one side.
White wine and red wine are carried out oxidation respectively and the variation of measuring pH value is handled in reduction.
Reduce and handle back PH and be alkalescence, carry out oxide treatment after PH for acid.
Figure 12 is that the difference of pH value changed when respectively 10 liters of solution passed through electrolyzer 3 times.
Being positioned at top broken line epimere among the figure is the different changing conditions of representing the pH value of red wine reduction processing, and hypomere is different changing conditions of representing the pH value of red wine oxide treatment.
Being positioned at following broken line epimere among the figure is the different changing conditions of representing the pH value of white wine reduction processing, and hypomere is different changing conditions of representing the pH value of white wine oxide treatment.
＜test conditions 〉
The electrolyzer formation → shown in Fig. 3-5
2 * 2 of electrode area → 200cm (lily gilding 1 μ, titanium metal mother metal)
Barrier film → cationic exchange membrane
Wine flow → 0.5 liter/minute
Tap water flow → 0.5 liter/minute
Faradaic current → 5A (deciding electric current)
It is to instigate grape wine to flow to negative electrode one side that reduction is handled, and makes tap water flow to anode one side.
Oxide treatment is to instigate tap water to flow to negative electrode one side, makes grape wine flow to anode one side.
By being carried out redox separately, white wine and red wine handle the variation of measuring ORP.
Reducing and handling back ORP is reductibility, carries out that ORP is an oxidisability after the oxide treatment.
Figure 13 is that the difference of ORP value when respectively 10 liters of solution pass through electrolyzer 3 times changes.
ORP: redox potential
Uppermost one section line is the different changing conditions of ORP value of representing the oxide treatment of red wine among the figure, is positioned at one section line that uppermost one section line below is closed on, and represents the different changing conditions of ORP value of the oxide treatment of white wine.A top line segment that is positioned at above-mentioned line segment below represent the different changing conditions of the ORP value that the reduction of red wine handles, and is positioned at the different changing conditions of ORP value that a following line segment below the above-mentioned line segment is represented the reduction processing of white wine,
The detailed test conditions of＜following data 〉
The electrolyzer formation → shown in Fig. 3-5
Electrode → 200cm2 (lily gilding 1 μ, titanium metal mother metal)
Barrier film → cationic exchange membrane
The electrolysis treatment of electrolysis process → reduction electrolysis (make sodium ascorbate salt flow into cathode can, make tap water flow into anode slot) Fig. 3-6 adopts identical electrolytic condition with Fig. 3-5
Use 0.1% sodium ascorbate salts solution to experimentize.ORP after the electrolysis is-790mv that electrolysis is not-40mv, and is widely different.This expression becomes big by the reductibility of electrolysis sodium ascorbate salts solution.
Remove the electrolytic condition of oxidation base energy simultaneous test
The electrolyzer formation → shown in Fig. 3-5
2 * 2 of electrode area → 200cm (lily gilding 1 μ, titanium metal mother metal)
Barrier film → cationic exchange membrane
Coffee flow → 0.5 liter/minute
Tap water flow → 0.5 liter/minute
Faradaic current → 3A (deciding electric current)
Ratio after electrolysis process → reduction electrolysis (make coffee flow to cathode can, make tap water the flow to anode slot) electrolysis does not carry out electrolytic coffee, has improved 27.3%.
The variation experiment condition of chlorogenic acid in the liquid coffee
＜test conditions 〉
The electrolyzer formation → shown in Fig. 3-5
2 * 2 of electrode area → 200cm (lily gilding 1 μ, titanium metal mother metal)
Barrier film → cationic exchange membrane
Coffee flow → 0.5 liter/minute
Tap water flow → 0.5 liter/minute
Faradaic current → 3A (deciding electric current)
Electrolysis process → reduction electrolysis (make coffee flow to cathode can, make tap water flow to anode slot)
We know that coffee one is oxidized, and the chlorogenic acid content that coffee itself comprises will reduce.This is that coffee is oxidized because chlorogenic acid itself is an antioxidant, and chlorogenic acid also can be oxidized and reduce.
Will judge the oxidisability of coffee objectively, generally all be to measure chlorogenic acid.
Under the same conditions, whether the chlorogenic acid change is observed in electrolysis by the coffee to the identical component generation, tests.
Be the chlorogenic acid amount that the coffee of 675ppm is packed in the bottle among the figure, be placed on 60 ℃ and preserve down, measure its variation.After the week as a result, electrolytic is 650ppm, and not electrolytic be 640ppm; Result after 3 weeks is electrolytic to be 630ppm, and not electrolytic is 595ppm.This shows by electrolysis, can produce the effect of controlled oxidation coffee.
Black tea flavor change experiment condition
＜test conditions 〉
The electrolyzer formation → shown in Fig. 3-5
2 * 2 of electrode area → 200cm (lily gilding 1 μ, titanium metal mother metal)
Barrier film → cationic exchange membrane
Black tea flow → 0.5 liter/minute
Tap water flow → 0.5 liter/minute
Faradaic current → 3A (deciding electric current)
Electrolysis process → reduction electrolysis (make black tea flow to cathode can, make tap water flow to anode slot)
Under the same conditions, by black tea that identical component is generated whether electrolysis observe the change of fragrance, test.
The bottle of sample is placed on 60 ℃ of preservations down, measures its variation.The electrolytic fragrance survival rate of result after 3 weeks is 88%, and not electrolytic is 71%.
In general, flavour ingredient can reduce because of oxidized, but finds out that by electrolysis the speed of oxidation has slowed down.
The formation condition of the electrolysis milk of milk function test
The electrolyzer formation → shown in Fig. 3-5
2 * 2 of electrode area → 200cm (lily gilding 1 μ, titanium metal mother metal)
Barrier film → cationic exchange membrane
The flow of milk → 2.0 liter/minute
The flow of tap water → 2.0 liter/minute
Faradaic current → 10A (deciding electric current)
Electrolysis process → reduction electrolysis (make milk stream to cathode can, make tap water flow to anode slot)
The milk function test is the test that picked at random 20 people carry out.
Feeling of freshness, milk flavor, heating flavor, sweet taste, concentration, caking, pleasant impression, 8 indexs of comprehensive evaluation of being primarily aimed at milk are carried out.
Scoring is by very good 2 minutes, better 1 minute, general 0 minute, not so good-1 minute, very bad-2 minutes these 5 grades mean value calculation.
Numerical value from table can obviously be found out, and is better than not electrolytic through electrolytic milk.
Claims (8)
1. device that uses electrolysis or electrodialysis mode to handle sweet water and drinks is characterized in that it comprises: electrolysis or electrodialysis groove, be positioned at the electrode of electrolysis or electrodialysis groove both sides and be positioned at electrolysis or electrodialysis the groove corresponding beverage that is provided with in both sides or the entrance and exit of drinks in addition.
2. a kind of according to claim 1 use electrolysis or electrodialysis mode are handled sweet water and drinks device, it is characterized in that: in electrolysis or electrodialysis groove, groove side directions along the electrode place, one deck is set does not have ion selective separator, be positioned at the groove of barrier film both sides, form two electrolysis or electrodialysis treatment channel, and be provided with separately beverage or the entrance and exit of drinks.
3. a kind of according to claim 1 use electrolysis or electrodialysis mode are handled sweet water and drinks device, it is characterized in that: in electrolysis or electrodialysis groove, groove side directions along the electrode place, one deck cation exchange membrane is set, be positioned at the groove of barrier film both sides, form two electrolysis or electrodialysis treatment channel, and be provided with separately beverage or the entrance and exit of drinks.
4. a kind of according to claim 1 use electrolysis or electrodialysis mode are handled sweet water and drinks device, it is characterized in that: in electrolysis or electrodialysis groove, groove side directions along the electrode place, one deck anionresin barrier film is set, be positioned at the groove of barrier film both sides, form two electrolysis or electrodialysis treatment channel, and be provided with separately beverage or the entrance and exit of drinks.
5. a kind of as claimed in claim 1 or 2 use electrolysis or electrodialysis mode are handled sweet water and drinks device, it is characterized in that: the two ends of undivided cell wherein or electrodialysis groove, the electrolyzer that is provided with no ion selective separator or electrodialysis groove, all establish the inlet of sweet water of the same race or drinks.
6. a kind of according to claim 1 use electrolysis or electrodialysis mode are handled sweet water and drinks device, it is characterized in that: in electrolyzer or electrodialysis groove, along the described groove side directions of electrode, cation exchange membrane, anionresin barrier film are set, electrolysis that forms between anionresin barrier film and negative electrode, cation exchange membrane and anionresin barrier film and cation exchange membrane and anode or electrodialysis treatment channel are independent separately, have the inlet of corresponding separately sweet water or drinks.
7. a kind of according to claim 1 use electrolysis or electrodialysis mode are handled sweet water and drinks device, it is characterized in that: in electrolyzer or electrodialysis groove, groove side directions along the electrode place, two-layer no ion selective separator is set, or one deck does not have ion selective separator and one deck positively charged ion or anion membrane, between above-mentioned two-layer barrier film and electrode and two-layer barrier film, form separately independently electrolysis or electrodialysis treatment channel, have the corresponding sweet water or the inlet of drinks separately.
8. handle sweet water and drinks device as a kind of use electrolysis as described in the claim 1,2,3,4,6 or 7 or electrodialysis mode, it is characterized in that: between the inlet of described electrolyzer and the outlet, form a circulation passage by recycle pump, surge tank and pipeline, described circulation passage is connected between the inlet and outlet of same electrolysis or electrodialysis treatment channel, or be connected between the inlet and outlet of different electrolysis or electrodialysis treatment channel, form single passage circulation or hyperchannel loop structure.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200720005880 CN201010552Y (en) | 2007-03-08 | 2007-03-08 | Device for processing beverage water and wine by way of electrolyzation or electrodialysis |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200720005880 CN201010552Y (en) | 2007-03-08 | 2007-03-08 | Device for processing beverage water and wine by way of electrolyzation or electrodialysis |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN201010552Y true CN201010552Y (en) | 2008-01-23 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200720005880 Expired - Lifetime CN201010552Y (en) | 2007-03-08 | 2007-03-08 | Device for processing beverage water and wine by way of electrolyzation or electrodialysis |
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| CN (1) | CN201010552Y (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101054217B (en) * | 2007-03-08 | 2011-08-17 | 希昭济 | Method and device for processing beverage and wine by electrolysis or electrodialysis manner |
| CN103338656A (en) * | 2011-02-02 | 2013-10-02 | 理研维他命股份有限公司 | Method for processing seafood extract, seafood extract, food and drink |
-
2007
- 2007-03-08 CN CN 200720005880 patent/CN201010552Y/en not_active Expired - Lifetime
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101054217B (en) * | 2007-03-08 | 2011-08-17 | 希昭济 | Method and device for processing beverage and wine by electrolysis or electrodialysis manner |
| CN103338656A (en) * | 2011-02-02 | 2013-10-02 | 理研维他命股份有限公司 | Method for processing seafood extract, seafood extract, food and drink |
| CN103338656B (en) * | 2011-02-02 | 2015-11-25 | 理研维他命股份有限公司 | The processing method of marine product extract, marine product extract and diet product |
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