CN1933809B - oily cleaning material - Google Patents

Abstract

A solid or semi-solid cleansing material which has excellent aesthetic appearance and is satisfactory in detergency, suitability for use, and use feeling. It further has a massage effect when applied with rubbing to thereby enhance blood circulation and make the skin condition satisfactory. The oily cleansing material is characterized by comprising (A) a specific polyamide-modified silicone, (B) a surfactant having an amide group and/or a surfactant having no amide group and having an organic value of 2,000 or lower and an inorganic value of 1,500 or lower, and (C) an ester oil, and by being semi-solid or solid.

Description

oily cleaning material

technical field

The present invention relates to a semi-solid to solid oil-based cleaning material, in particular to an oil-based cleaning material with good detergency, usability and feeling of use, good transparency, good high-temperature stability, and good massage effect. cleaning material. the

Background technique

In recent years, with the popularity of hard cosmetics such as oily mascara and lipsticks that are not easy to fade, cleaning materials are required to have higher cleaning power, which can remove water-resistant or durable beauty cosmetics, etc. The demand for oil-based cleaning materials has increased dramatically. the

However, since the mainstream of general oil-based cleansing materials is liquid oil as the main component, there are problems such as usability such as difficulty in handling with fingers, and problems such as sticky skin after wiping off or washing. In order to solve these problems, studies have been made on oil-based cleansing materials that use bentonite, oil-based gelling agents, or solid oils to gel the oil-based components to make the system viscous (eg, Patent Document 1). the

In addition, as oil-based solid cosmetics with a transparent appearance and aesthetic appeal, materials containing polyamide resins (for example, Patent Documents 2 and 3), materials containing 12-hydroxystearic acid (for example, Patent Documents 4 and 5), A material to which dextrin stearate is added (for example, Patent Document 6) and the like. the

Patent Document 1: Japanese Patent Application Laid-Open No. 2001-213726

Patent Document 2: Japanese Patent Application Publication No. 45-41318

Patent Document 3: Japanese Patent Publication No. 52-7067

Patent Document 4: Japanese Patent Application Laid-Open No. 63-119405

Patent Document 5: Japanese Patent Laid-Open Publication No. 2-264707

Patent Document 6: Japanese Patent Laid-Open Publication No. 9-235210

Contents of the invention

However, although the cosmetics that use bentonite, oil-based gelling agent, or solid oil to gel the oil-based components to make the system viscous have better usability, they are cloudy due to the gel itself. The aesthetics of the appearance is poor, and there are some aspects such as stickiness after use due to solid oil and the like, which do not satisfy the feeling of use. the

In addition, it is expected to improve the following effects: the rubbing action of spreading the cleansing material on the skin and blending with the beauty material, like massage, has the effect of promoting skin blood circulation and making the skin soft and shiny. The cosmetics used at this time It is sticky and moderately resistant on the skin. However, the cleansing materials that use bentonite, oily gelling agent, or solid oil to gel the oil-based components to make the system viscous will significantly reduce the viscosity of the system due to the rubbing behavior during use, and cannot obtain a sufficient massage effect. . the

In addition, in oil-based solid cosmetics with a transparent appearance, polyamide resin-added materials tend to bleed out oil due to changes in time or temperature, and have a disadvantage of poor storage stability. In addition, the material with 12-hydroxystearic acid has good transparency in appearance, but the temperature stability is slightly poor, and the material with dextrin fatty acid ester cannot meet the requirements of both transparency and solidity of the system. Furthermore, these transparency-related techniques are expected to be transparent lipsticks, and when used as cleansing materials, it is difficult to spread, sticky, etc., and a good feeling of use cannot be obtained. the

That is, there is no oil-based cleansing material that has a transparent to translucent appearance, a good feeling of use, does not reduce viscosity due to rubbing behavior during use, and has a good massage effect. the

Under such circumstances, the inventors of the present invention have conducted many studies on the composition of oil-based cleaning materials in order to solve the above-mentioned technical problems. As a result, it was found that by adding a specific polyamide-modified siloxane, a surfactant with specific properties, and an ester oil in combination, a semi-solid with good detergency, a transparent to translucent appearance, and excellent aesthetics can be obtained It is an oil-based cleansing material that is stable at high temperatures and has good usability that is easy to handle without dripping from the hands, and massage effects such as promoting blood circulation, softening, and exfoliating. , and complete the present invention. the

In addition, the rubbing action of the oil-based cleansing material not only has massage effects such as promoting blood circulation, but also improves the penetration of the cleansing material into the skin texture, dissolves the cleansed components, and floats the cleansed components onto the skin. Cleaning effect. the

That is, the present invention provides a kind of oily cleansing material, it is characterized in that containing following composition (A)～(C):

(A) A polyamide-modified siloxane having a repeating unit represented by the following general formula (1):

[chemical formula 2]

(In the formula, X represents a divalent hydrocarbon group with 1 to 30 carbon atoms, Y represents a divalent hydrocarbon group with 1 to 40 carbon atoms, m represents an integer of 1≤m≤700, n represents a group of 1≤n≤500 integer);

(B) Surfactants with an organic value below 2000 and an inorganic value below 1500;

(C) ester oil,

The oily cleansing material is semi-solid to solid. the

The present invention further provides the above-mentioned oily cleaning material whose appearance is transparent to translucent. the

The effect of the invention

The oil-based cleansing material of the present invention has good detergency, is semi-solid to solid, and has good usability and massage effect that cosmetics do not drip from hands when used, and has good aesthetic appearance and high temperature stability. Better new cleaning material. the

Therefore, with the cleansing material of the present invention, it is possible to simultaneously obtain a cleansing effect and a massage effect that can remove water-resistant or long-lasting beauty cosmetics and the like. the

The best form for implementing the invention

In the cleaning material of the present invention, the above-mentioned components (A) to (C) are essential components, wherein the component (A) is a gelling agent for the oily component, and is maintained by maintaining the oily component of the oily cleaning material in a semi-solid state to a solid state, It is an ingredient that provides good usability such as not dripping from hands when used, and massage effects such as promoting blood circulation and softening and exfoliating. The polyamide-modified siloxane of the component (A) is represented by the following general formula (1). the

[chemical formula 3]

(In the formula, X represents a divalent hydrocarbon group with 1 to 30 carbon atoms, Y represents a divalent hydrocarbon group with 1 to 40 carbon atoms, m represents an integer of 1≤m≤700, n represents a group of 1≤n≤500 integer). the

In the above formula (1), X is a linear or branched divalent hydrocarbon group having 1 to 30 carbon atoms, preferably a linear or branched divalent hydrocarbon group having 3 to 10 carbon atoms. Also, Y is a linear or branched divalent hydrocarbon group having 1 to 40 carbon atoms, preferably a linear or branched divalent hydrocarbon group having 2 to 6 carbon atoms. the

In addition, in said formula (1), m is an integer of 1-700, Preferably it is an integer of 15-500, Especially preferably, it is an integer of 15-45. n is an integer of 1-500, preferably an integer of 1-100, particularly preferably an integer of 4-25. the

Specific examples of the component (A) polyamide-modified siloxane represented by the formula (1) are described in Japanese Patent Application Laid-Open No. 2001-512164, and Dow Corning 2-8178 Gellant is listed as its commercially available product. (manufactured by Dow Corning Corporation), etc. the

The content of the above-mentioned component (A) is not particularly limited, but is preferably 0.5-50% by mass (hereinafter, expressed only by "%") in the total composition. If it is within this range, an oil-based cleansing material having a moderate gel strength, a massage effect, and no problems with high-temperature stability and cleansing power can be obtained. Furthermore, it is most preferably 0.5 to 15% in terms of usability such as ease of handling by hand and ease of blending with the skin (applied site). the

In addition, the component (B) surfactant used in the present invention is a surfactant with an organic value of 2000 or less and an inorganic value of 1500 or less, and it is used together with the component (A) to play a role in interacting with the components to be cleaned. Components added for the purpose of dissolving and floating the components to be washed. the

Here, the organic value and the inorganic value are values obtained from an organic concept map (Fujita Mu, Prediction of Organic Compounds and Organic Concept Map, Field of Chemistry Vol.11, No.10(1957) 719-715). Specifically, in this organic concept diagram, for the physical and chemical properties of compounds, the degree of physical properties mainly determined by Van Der Waals force is defined as "organicity", and the degree of physical properties mainly determined by electrostatic affinity is " Inorganicity", and then the value of performance. the

If the organic value and inorganic value of component (B) are within this range, good compatibility with component (A) and component (C) can be obtained, the system will not become cloudy, there will be moderate gelling power, no Good cleaning material for problems like liquid waste. the

Specific examples of the surfactant component (B) having an organic value of 2000 or less and an inorganic value of 1500 or less include coconut oil fatty acid diethanolamide, lauric acid diethanolamide, myristic acid diethanolamide, myristic acid Acid monoisopropanolamide, coconut oil fatty acid monoethanolamide, lauric acid monoisopropanolamide, polyoxypropylene coconut oil fatty acid monoisopropanolamide and other active agents containing amino groups; polyethylene glycol monoisostearate , polyoxyethylene glyceryl isostearate and other ester surfactants; polyoxyethylene stearyl ether, polyoxyethylene isostearyl ether, polyoxyethylene cetyl ether, polyoxyethylene isocetyl ether , polyoxyethylene oleyl ether, polyoxyethylene lauryl ether and other polyoxyethylene chain and fatty acid ether surfactants. the

Examples of commercially available products of this component (B) include: Amizole CDE (coconut oil fatty acid diethanolamide (manufactured by Kawaken Fine Chemicals); organic value 327, inorganic value 400), Amizole LDE (lauric acid Diethanolamide (manufactured by Chuanyan Fine Chemical Company); organic value 320, inorganic value 400), Amizole CME (coconut oil fatty acid monoethanolamide (manufactured by Chuanyan Fine Chemical Company); organic value 300, inorganic value 300 ), PEIS-8EX (polyethylene glycol monoisostearate (manufactured by Japan Emerujiyon Corporation); organic value 670, inorganic value 685), PEIS-10EX (polyethylene glycol monoisostearate (Japan Emerald Gyon Corporation), organic value 750, inorganic value 835), GWIS-108 (polyoxyethylene glyceryl isostearate (manufactured by Emerald Gyon Co., Ltd. in Japan); organic value 730, inorganic value 695), GWIS-110 (manufactured by Polyoxyethylene Glyceryl Isostearate (manufactured by Emerald Gyon Corporation of Japan); organic value 810, inorganic value 845), GWIS-115 (polyoxyethylene glyceryl isostearate (manufactured by Emerald Glycerin Company of Japan); organic value 1010, inorganic value 1220), etc. the

Adding this component (B) is preferable because it satisfies the performance of an oil-based cleanser, maintains the composition's transparent appearance, and obtains excellent aesthetics. Especially as component (B) if coconut oil fatty acid diethanolamide, coconut oil fatty acid monoethanolamide, polyoxyethylene (E.O.8-10) diol monoisostearate, polyoxyethylene (E.O.8-10) Glyceryl isostearate and the like are preferable because they have good compatibility with the component (A) and can obtain moderate gel strength. the

The content of component (B) is not particularly limited, preferably 0.5-50% of the total composition, particularly preferably 3-20%. If it is within this range, an oil-based cleansing material with good detergency, a refreshing feeling during rinsing, and a condition of the skin after use can be obtained. Moreover, 1 type or 2 or more types of this component (B) can be used. the

In addition, as the component (C) ester oil used in this invention, any of the materials used for cosmetics normally can be used. Examples of the component (C) include: 2-ethylhexyl palmitate, cetyl 2-ethylhexanoate, isopropyl palmitate, isopropyl myristate, isotridecyl isononae Ito, Isononyl Isononate, Neopentyl Glycol Dicaprylate, Glyceryl Tris 2-Ethylhexanoate, Propylene Glycol Dicaprate, Propylene Glycol Dicaprylate, Glyceryl Tri(caprylic/capric Acid), etc. Furthermore, among the above-mentioned ester oils, those with branched alkyl chains in the structure such as tri-2-ethylhexanoic acid glyceride are most preferred, because they have good compatibility with component (A), making the oily cleaning materials stable and transparent in appearance sex is good. the

The content of the above component (C) is not particularly limited, preferably 10-99% of the total composition, more preferably 10-80%. Moreover, 1 type or 2 or more types of this component (C) can be used. the

The oil-based cleansing material of the present invention contains the above-mentioned components (A) to (C) as essential components, and its shape is semi-solid to solid. In this specification, semi-solid state to solid state refers to the gel hardness measured by a rheometer (manufactured by Fudo Kogyo Co., Ltd., rheometer NRM-2002D.D) (sample storage temperature 25°C, pressure sensitive axis ( In a needle penetration test with a needle diameter of 10 mmφ and a table moving speed of 60 mm/min, the load applied to the pressure-sensitive shaft when the pressure-sensitive shaft is inserted to a depth of 5 mm) is 15 gf or more, preferably 50 gf or more. the

Also, the oil-based cleansing material of the present invention is more preferably transparent to translucent. In this specification, "transparent to translucent" refers to the state (translucent) to the state (translucent) in which the characters on the paper placed at the bottom of the glass (about 11) can be recognized when the product of the present invention is filled in a glass beaker to a depth of 15 mm. more transparent. the

In order to make the oil-based cleansing material of the present invention appear transparent to translucent as described above, it is preferable to use a surfactant having an amido group as the component (B) of the present invention. The surfactant has better compatibility with component (A), so while improving the stability of the oily cleaning material, it also contributes to the transparent to translucent appearance of the oily cleaning material. the

In the oil-based cleansing material of the present invention, in addition to the above-mentioned components, volatile siloxanes such as decamethylcyclopentasiloxane may be further added. By adding these volatile siloxanes, cosmetics such as lipstick and mascara can be blended particularly well with cleaning materials, and as a result, cleaning materials with improved cleaning power and excellent stain removal can be obtained. The content of these volatile siloxanes is preferably about 3 to 25% of the total composition. the

In the oil-based cleansing material of the present invention, in addition to the above-mentioned components, common components in cosmetics such as oil agents, surfactants, water-soluble polymers, and clay minerals can be added according to the purpose within the range that does not impair the effects of the present invention. , powder, water-soluble moisturizing ingredients, beauty ingredients, antioxidants, preservatives, chelating agents, pH regulators, colorants, medicinal ingredients, fragrances and other ingredients.

However, it is not desirable to add a large amount of aqueous components to the oil-based cleansing material of the present invention, and it is preferable not to substantially contain aqueous components. the

Example

Hereinafter, the present invention will be specifically described with reference to examples, but the present invention is not limited to these examples at all. the

Example 1

Oil-based cleaning materials:

Cleaning materials of Invention Products 1 to 19 and Comparative Products 1 to 9 were prepared with the compositions shown in Table 1 and Table 2 and the following production methods, and performance evaluation was performed on the following evaluation items with the following evaluation methods and judgment criteria. These results are shown in Table 3. the

(composition)

Table 1

^* 1 Dow Corning 2-8178 gellant manufactured by Dow Corning Silicone

^* 2 GWIS-320 manufactured by Japan Emerujiyon Co., Ltd. (organic value 1940 inorganic value 1515)

^* 3 PEIS-8EX manufactured by Emerald Japan Co., Ltd. (organic value 670 inorganic value 685)

^* 4 GWIS-110 manufactured by Japan Emerujiyon Co., Ltd. (organic value 810 inorganic value 845)

^* 5 GWIS-330 manufactured by Japan Emerujiyon Co., Ltd. (organic value 2310 inorganic value 2265)

[Table 2]

^* 1 Dow Corning 2-8178 gellant manufactured by Dow Corning Silicone

^* 2 GWIS-320 manufactured by Japan Emerujiyon Co., Ltd. (organic value 1940 inorganic value 1515)

^* 3 PEIS-8EX manufactured by Emerald Japan Co., Ltd. (organic value 670 inorganic value 685)

^* 4 GWIS-110 manufactured by Japan Emerujiyon Co., Ltd. (organic value 810 inorganic value 845)

^* 5 GWIS-330 manufactured by Japan Emerujiyon Co., Ltd. (organic value 2310 inorganic value 2265)

(Manufacturing method)

A. Heat and dissolve components (1) to (22) at 120°C, and mix well. the

B. Fill A in the container, let stand and cool to obtain a semi-solid to solid cleaning material. the

(performance test)

<evaluation item> 

(1) Ease of use (whether it drips from the hand)

(2) Massage effect

(3) Cleansing effect (the cleaning effect of commercially available lipsticks applied to the lips)

(4) No sticky feeling (the state of the skin after cleansing) 

(5) The skin does not feel dry (the state of the skin after cleansing) 

(6) Transparency of appearance

(7) High temperature stability (50°C, 1 month)

(8) Gel hardness

<Evaluation Method 1: Sensory Evaluation Test> 

For evaluation items (1) to (5), a sensory evaluation test was performed on each sample with respect to 10 panelists. In the sensory evaluation test, evaluation was performed on 7 levels based on the following (a) absolute evaluation index, and each sample was judged based on the following (b) judgment standard based on the average value of scores given by a 10-person panel. the

(a) Absolute evaluation criteria

(Rating): (Evaluation)

6: very good

5: good

4: slightly better

3: General

2: slightly worse

1: Poor

0: very bad

(b) Judgment criteria

(judgment): (average score)

5.0 or above (very good)

○: Above 3.5, less than 5.0 (good)

△: Above 1.0, less than 3.5 (slightly worse)

×: less than 1.0 (poor)

<Evaluation method 2: Transparency of appearance>

Fill the glass beaker with the product of the present invention or the comparative product to a depth of 5 mm to 20 mm, and judge whether the characters (approximately 11 fonts) on the paper placed at the bottom of the cup can be recognized based on the following (c) criterion. the

(c) Judgment criteria

(judgment): (evaluation)

充填20mm以上深度亦可认出文字(透明性非常好) 

Text can be recognized even when the filling depth is more than 20mm (transparency is very good)

○: 15mm depth can recognize text (good transparency)

△: Text can be recognized at a depth of 10mm (slightly less transparent)

×: The text cannot be recognized at a depth of 5mm (poor transparency)

<Evaluation Method 3: High Temperature Stability>

The product of the present invention or the comparative product was filled in the container, stored in a thermostat at 50° C., and the state after one month was observed with the naked eye, and judged based on the following (d) judgment standard. the

(d) Judgment criteria

(judgment): (evaluation)

完全没有油渗出(高温稳定性非常好) 

No oil seepage at all (very good high temperature stability)

○: There is a small amount of oil oozing out, which disappears after being placed at room temperature (good high temperature stability)

△: There is a small amount of oil oozing out, which does not disappear after being placed at room temperature (slightly poor high temperature stability) 

×: A large amount of oil seeps out, poor usability (poor high temperature stability) 

<Evaluation Method 4: Gel Hardness>

Using a rheometer (NRM-2002D.D) manufactured by Fudo Kogyo Co., Ltd., needle penetration at a sample storage temperature of 25°C, a pressure-sensitive shaft (adapter) with a needle diameter of 10mmφ, and a stage moving speed of 60mm/min In the degree test, the load applied to the pressure-sensitive shaft when the pressure-sensitive shaft is inserted to a depth of 5mm is evaluated. the

(composition)

[table 3]

The results in Table 3 show that the cleaning materials of products 1 to 19 of the present invention are in all items of ease of use, massage effect, cleaning effect, no sticky feeling, no dry feeling on the skin, transparent appearance, and high temperature stability. All good oil-based cleaning materials. the

On the other hand, as shown in Table 3, comparative products 1 to 3 in which the system was cured by substituting dextrin palmitate and 12-hydroxystearic acid for component (A) had problems in terms of high temperature stability and stickiness. In addition, Comparative Product 4, in which polyoxyethylene sorbitan tetraoleate was added instead of component (B), had poor appearance and transparency, and had problems in high-temperature stability and usability. the

In addition, comparative products 5 to 7, in which the system was cured with paraffin wax and polyethylene wax, were inferior in high temperature stability and appearance transparency, and had a sticky feeling. In addition, among comparative products 8 and 9 in which component (B) was not added but only surfactants whose organic value or inorganic value was out of the range, the comparative product 8 (inorganic value 1515) could not obtain transparency in appearance, High temperature stability is also poor. Comparative product 9 (organic value 2310, inorganic value 2265), by increasing the amount of volatile siloxane, can obtain the transparency of the appearance, but the skin feels dry after use, and the storage stability is not good, it is not good. ideal. the

Example 2

Solid Cleaning Materials:

(Element) (%)

(1) Polyamide modified siloxane ^*1 5.0

(2) Triglyceride 2-ethylhexanoate 73.6

(3) Decamethylcyclopentasiloxane 15.0

(4) Squalane 3.0

(5) Coconut oil fatty acid diethanolamide 3.0

(6) Spice 0.3

(7) Rosemary oil 0.1

^* 1 Dow Corning 2-8178 gellant (manufactured by Dow Corning Silicone)

(Preparation)

The above (1) to (7) were uniformly heated and mixed at 100° C., and filled into a container to obtain a solid cleansing material. the

The solid-shaped cleaning material of Example 2 is a solid-shaped cleaning material that has excellent high-temperature stability and appearance transparency, is easy to use by hand, has good usability, has a good massage effect, has a high cleaning effect, does not feel sticky, and has a good sense of use . the

Example 3

Solid Cleaning Materials:

(Element) (%)

(1) Polyamide modified siloxane ^*1 5.0

(2) Triglyceride 2-ethylhexanoate 69.9

(3) Decamethylcyclopentasiloxane 15.0

(4) Squalane 3.0

(5) Coconut oil fatty acid diethanolamide 7.0

(6) Rosemary oil 0.1

^* 1 Dow Corning 2-8178 gellant (manufactured by Dow Corning Silicone)

(Preparation)

The above (1) to (6) were uniformly heated and mixed at 100° C., and filled into a container to obtain a solid cleansing material for rinsing. the

The solid-shaped cleaning material of Example 3 is a solid-shaped cleaning material that has excellent high-temperature stability and appearance transparency, is easy to use by hand, has good usability, has a good massage effect, has a high cleaning effect, does not feel sticky, and has a good sense of use . the

Example 4

Solid Cleaning Materials:

(Element) (%)

(1) Polyamide modified siloxane ^*1 5.0

(2) Triglyceride 2-ethylhexanoate 69.9

(3) Decamethylcyclopentasiloxane 15.0

(4) Squalane 3.0

(5) Coconut oil fatty acid diethanolamide 5.0

(6) Polyethylene glycol monoisostearate ^*3 2.0

(7)Orange oil 0.1

^* 1 Dow Corning 2-8178 gellant (manufactured by Dow Corning Silicone)

^* 3 PEIS-8EX (manufactured by Japan Emerujiyon Co., Ltd.; organic value 670 inorganic value 685)

(Preparation)

The above (1) to (7) were uniformly heated and mixed at 100° C., and filled into a container to obtain a solid cleaning material for rinsing. the

The solid-shaped cleaning material of Example 4 is a solid-shaped cleaning material that has excellent high-temperature stability and appearance transparency, is easy to use by hand, has good usability, has a good massage effect, has a high cleaning effect, does not feel sticky, and has a good sense of use . the

Industrial availability

The oil-based cleaning material of the present invention has strong cleaning power, is semi-solid to solid, and has good usability such that cosmetics will not drip from hands when used, and massage effect, and has good aesthetic appearance and high temperature stability. A new type of cleaning material with better performance. the

Therefore, it is useful as a novel oil-based cleanser capable of simultaneously obtaining a cleansing effect and a massage effect capable of removing water-resistant and long-lasting beauty cosmetics and the like. the

Claims (35)

1. oily cleansing material is characterized in that: contain following composition (A)～(C):

(A) have polyamide modified siloxanes with the repetitive of following general expression (1) expression,

In the formula, X represents to have the bivalent hydrocarbon radical of 1～30 carbon atom, and Y represents to have the bivalent hydrocarbon radical of 1～40 carbon atom, and m represents the integer of 1≤m≤700, and n represents the integer of 1≤n≤500;

(B) organic value is below 2000 and inorganic value is a surfactant below 1500; With

(C) ester oil,

This oily cleansing material be semi-solid to solid, shaped, and property of water-bearing composition not.

2. the oily cleansing material of claim 1, wherein the addition of mentioned component (A) is 0.5～50 quality %.

3. the oily cleansing material of claim 1, wherein the addition of mentioned component (B) is 0.5～50 quality %.

4. the oily cleansing material of claim 2, wherein the addition of mentioned component (B) is 0.5～50 quality %.

5. the oily cleansing material of any one in the claim 1 to 4, wherein the addition of mentioned component (C) is 10～99 quality %.

6. the oily cleansing material of any one in the claim 1 to 4, its outward appearance is translucent for being clear to.

7. the oily cleansing material of claim 5, its outward appearance is translucent for being clear to.

8. the oily cleansing material of any one in the claim 1 to 4, wherein mentioned component (C) is for having the ester oil of branched alkyl chain in the structure.

9. the oily cleansing material of claim 5, wherein mentioned component (C) is for having the ester oil of branched alkyl chain in the structure.

10. the oily cleansing material of claim 6, wherein mentioned component (C) is for having the ester oil of branched alkyl chain in the structure.

11. the oily cleansing material of claim 7, wherein mentioned component (C) is for having the ester oil of branched alkyl chain in the structure.

12. the oily cleansing material of any one in the claim 1 to 4 wherein further contains volatile siloxane.

13. the oily cleansing material of claim 5 wherein further contains volatile siloxane.

14. the oily cleansing material of claim 6 wherein further contains volatile siloxane.

15. the oily cleansing material of claim 7 wherein further contains volatile siloxane.

16. the oily cleansing material of claim 8 wherein further contains volatile siloxane.

17. the oily cleansing material of claim 9 wherein further contains volatile siloxane.

18. the oily cleansing material of claim 10 wherein further contains volatile siloxane.

19. the oily cleansing material of claim 11 wherein further contains volatile siloxane.

20. the oily cleansing material of any one in the claim 1 to 4, wherein mentioned component (B) is for having the surfactant of acylamino-.

21. the oily cleansing material of claim 5, wherein mentioned component (B) is for having the surfactant of acylamino-.

22. the oily cleansing material of claim 6, wherein mentioned component (B) is for having the surfactant of acylamino-.

23. the oily cleansing material of claim 7, wherein mentioned component (B) is for having the surfactant of acylamino-.

24. the oily cleansing material of claim 8, wherein mentioned component (B) is for having the surfactant of acylamino-.

25. the oily cleansing material of claim 9, wherein mentioned component (B) is for having the surfactant of acylamino-.

26. the oily cleansing material of claim 10, wherein mentioned component (B) is for having the surfactant of acylamino-.

27. the oily cleansing material of claim 11, wherein mentioned component (B) is for having the surfactant of acylamino-.

28. the oily cleansing material of claim 12, wherein mentioned component (B) is for having the surfactant of acylamino-.

29. the oily cleansing material of claim 13, wherein mentioned component (B) is for having the surfactant of acylamino-.

30. the oily cleansing material of claim 14, wherein mentioned component (B) is for having the surfactant of acylamino-.

31. the oily cleansing material of claim 15, wherein mentioned component (B) is for having the surfactant of acylamino-.

32. the oily cleansing material of claim 16, wherein mentioned component (B) is for having the surfactant of acylamino-.

33. the oily cleansing material of claim 17, wherein mentioned component (B) is for having the surfactant of acylamino-.

34. the oily cleansing material of claim 18, wherein mentioned component (B) is for having the surfactant of acylamino-.

35. the oily cleansing material of claim 19, wherein mentioned component (B) is for having the surfactant of acylamino-.