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CN1915891A - Lightweight heatproof porous wall material and building blocks - Google Patents

Lightweight heatproof porous wall material and building blocks Download PDF

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Publication number
CN1915891A
CN1915891A CNA2005100214660A CN200510021466A CN1915891A CN 1915891 A CN1915891 A CN 1915891A CN A2005100214660 A CNA2005100214660 A CN A2005100214660A CN 200510021466 A CN200510021466 A CN 200510021466A CN 1915891 A CN1915891 A CN 1915891A
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parts
interlayer
wall material
porous wall
hydrogen peroxide
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CNA2005100214660A
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CN100398483C (en
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周正华
黄元龙
顾明
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周正华
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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Abstract

This invention relates to a lightweight heat-insulating porous wall material and its blocks. The lightweight heat-insulating porous wall material is composed of: Portland cement 20-50 parts, lightweight sintered magnesium oxide 10-20 parts, hydrogen peroxide foamer 5-10 parts, rosin soda soap 5-10 parts, calcium stearate stabilizer 2-6 parts, naphthalene 1-5 parts, straw or wood powder or fly ashes filler 10-20 parts, and water. The block comprises a concrete inner-interlayer, a concrete outer-interlayer, more than two insulating connecting bars disposed between the concrete inner-interlayer and the concrete outer-interlayer, and the lightweight heat-insulating porous wall material filled between the concrete inner-interlayer and the concrete out-interlayer. The lightweight heat-insulating porous wall material has such advantages as small volume and low heat conductivity. The block has such advantages as high compressive strength, stable morphology, good fire and water resistance, easy cutting and good heat insulation.

Description

A kind of lightweight heatproof porous wall material and building block thereof
One, technical field
The present invention relates to building wall material, particularly lightweight heatproof porous wall material and adopt the building block of this material to make the field.
Two, background technology
The existing building insulation blocks is at building block inner chamber filling styrofoam or granular polystyrene etc., adopts concrete prefabricated forming.Have heat bridge, cold bridge to produce in building block, heat insulation effect is poor, therefore, must also will carry out one time the paste heat-preserving material in the building block outside, just can reach heat insulation effect.Though it has the adiabatic advantage, its shortcoming is that construction is numerous and diverse, the cost height.And under the hot conditions when presence of fire, the porous plastics decomposes discharges toxic and harmful, as: discharge chlorine after the polyvinyl chloride foam decomposes, discharge benzene class toxic gas after the polystyrene foam decomposes, polluted air jeopardizes human health.
Chinese patent literature discloses " a kind of light-weight building block made from slag-pearlite and production method thereof ", and (application number: 92108693.8), it is formed according to certain production technique manufacturing by perlite slag, slag, cement and water.It than the weight of general cement, cinder porous building-brick lightly has cheap advantage.But its unit weight (being volume density) is higher, and heat insulating effect is relatively poor.Chinese patent literature has also disclosed a kind of " thermally insulating building blocks of pearlite " (application number: 99101667.x), it is rosin, phenol, caustic soda, sulfuric acid and water to be mixed stir evenly, mix with perlite, cement and water with it stir evenly the mould molding of packing into, maintenance forms.The building block that this material is made is after being built into body of wall, and cement sand plaster also need be used again in its inside and outside surface, thereby construction is more numerous and diverse; Secondly, still there be problem and the defective that unit weight is big, heat insulating effect is not good enough in it.
Three, summary of the invention
The object of the present invention is to provide the lightweight heatproof porous wall material that a kind of unit weight is little, porosity is high, thermal conductivity is low.
Another purpose of the present invention provides a kind of concrete foamed heat insulating building block of adopting above-mentioned materials, and it has better heat insulating effect and bulk strength.
The object of the present invention is achieved like this: a kind of lightweight heatproof porous wall material, it is characterized in that, and form by component with following weight part:
Silicate cement 20-50 part; Light calcined magnesia 10-20 part; Hydrogen peroxide 5-10 part and rosin soda soap 5-10 part as whipping agent; Calcium stearate 2-6 part and naphthalene 1-5 part as stablizer; Be selected from stopping composition 10-20 part of plant stalk powder or wood powder or flyash; Add an amount of water.
Another purpose of the present invention is achieved in that a kind of concrete foamed heat insulating building block of adopting above-mentioned materials, it is characterized in that, comprise that perfusion is filled with the lightweight heatproof porous wall material layer between the inside and outside interlayer by the insulation connecting strip that is provided with between coagulation intraformational bed and outside sandwich and the inside and outside interlayer that is parallel to each other more than two.
Described adiabatic connecting strip is a plastics tubing, and the material of casing pack and lightweight heatproof porous wall material layer is identical.
Described adiabatic connecting strip is a batten.
Described adiabatic connecting strip is a thick bamboo tube.
Described intraformational bed thickness is 20mm, and outside sandwich thickness is 30mm; Be embedded with woven wire or fibrous reticulum in the inside and outside interlayer; Described insulation connecting strip is three, and is distributed on the midline position of building block length direction.
During making, with silicate cement (or aluminosulfate cement, or other cement material), light calcined magnesia, stopping composition (as plant stalk powder or wood powders such as rice wheats) add suitable quantity of water and mix stirring after 3-5 minute, adding stablizer such as calcium stearate and naphthalene again mixes, adding whipping agent at last is that hydrogen peroxide and rosin soda soap stir the time through about 1 minute, and it is stand-by promptly to become the foaming grog; Meanwhile, with cement (silicate cement, aluminosulfate cement or other cement material) reverse mould perfusion (or extruding) the inside and outside interlayer of moulding, then, the foaming grog is cast in the filling of building block external mold interlayer inner chamber, moulding once more.Form through heat drying or natural curing.
Compared with prior art, characteristics of the present invention are: 1, the unit weight of lagging material is little (is 230-250Kg/m 3), thermal conductivity low (under 25 ℃≤0.065w/m.k), hydrophobic rate (〉=95%), dry shrinkage little (≤0.5mm/m); 2, protective layer, thermal insulation layer are stopped thermal insulation dehiscence in one, the good integrity of building block, the crushing strength height (〉=1.5Mpa), the good effect of heat insulation of building block.Be specially adapted to the insulation of non-load bearing walls such as exterior wall, interior wall.3, have uninflammability, at high temperature can not produce obnoxious flavour, contaminate environment.
Four, description of drawings
Fig. 1 is the stereographic map (not shown heat-insulation foam material layer) of this novel embodiment;
Fig. 2 is the transverse cross-sectional view of the adiabatic connecting strip axis in the edge of Fig. 1;
Fig. 3 stereographic map that to be intraformational bed shown in Figure 1 and adiabatic connecting strip dissectd after half.
Five, embodiment
Fig. 1 illustrates, intraformational bed 2 and outside sandwich 1 adopt concrete or other materials for wall to make, inside and outside interlayer is parallel to each other, be provided with between the inside and outside interlayer more than two, as three eradication hot tie-in bars 4,5,6, this connecting strip can adopt plastics tubing, batten or thick bamboo tube to make, and be distributed on the midline position of building block length direction and (should comprise other possible position, as uniform on the diagonal), adiabatic connecting strip two ends all are embedded among the inside and outside interlayer, referring to Fig. 2.Perfusion is filled with light thermal-insulation foamed material layer 3 between the inside and outside interlayer, and it adopts plastics tubing is adiabatic connecting strip, and the material of its casing pack is identical with light thermal-insulation foamed material layer 3.Usually, intraformational bed 2 thickness are 20mm, and outside sandwich thickness is 30mm (inside and outside interlayer is meant for the inboard and the outside of body of wall), certainly, should comprise that other may thickness.Be embedded with woven wire or fibrous reticulum in the inside and outside interlayer, make framework material.
The physical dimension of building block decides according to relevant code of building design.The thickness of building block is except outside the inside and outside cement interlayer (being generally 20+30mm is 50mm), and all the other are insulation layer thickness, and insulation layer thickness requires can be 130mm, 190mm, 310mm or the like according to insulation.
(in the weight part, down together) composed as follows of the material of above-mentioned light thermal-insulation foaming layer 3:
Silicate cement 20-50 part; Light calcined magnesia 10-20 part; Hydrogen peroxide 5-10 part and rosin soda soap 5-10 part as whipping agent; Calcium stearate 2-6 part and naphthalene 1-5 part as stablizer; Be selected from stopping composition 10-20 part of plant stalk powder or wood powder or flyash; Add an amount of water.
In the said components, light calcined magnesia claims caustic magnesia again, and it is being burnt till below 950 ℃ by magnesiumcarbonate, magnesite or magnesium hydroxide.It has activity, can be with the water effect because of knot; Hydrogen peroxide is a hydrogen peroxide, and (30% commercially available hydrogen peroxide) has strong oxygenizement; Rosin soda soap (rosined soap is the general name of the metal-salt of sylvic acid) plays saponification by rosin and soda ash solution and forms; Calcium stearate claims calcium stearate again, can absorb moisture in air, mainly plays water-reduction (available barium stearate or Ying Zhi Suan Cadmium substitute).Naphthalene (C 10H 8) be the simplest fused ring compound, the tabular crystal of light, volatile, also easily distillation, under suitable situation, the Hydrogen Energy in the molecule also can be played addition reaction with chlorine and hydrogen by replacements such as chlorine, bromine, nitro, sulfo groups.
Embodiment 1
In the materials for wall of the present invention, each ingredients weight parts is as follows:
20 parts of silicate cements; 10 parts of light calcined magnesias; As 5 parts of 5 parts in the hydrogen peroxide of whipping agent and rosin soda soaps; As 1 part of 2 parts of the calcium stearates of stablizer and naphthalene; 10 parts of plant stalk powders.25 parts in water.
Embodiment 2
In the materials for wall of the present invention, each ingredients weight parts is as follows:
25 parts of silicate cements; 12 parts of light calcined magnesias; As 6 parts of 7 parts in the hydrogen peroxide of whipping agent and rosin soda soaps; As 2 parts of 4 parts of the calcium stearates of stablizer and naphthalenes; 12 parts of wood powders; 30 parts in water.
Embodiment 3
In the materials for wall of the present invention, each ingredients weight parts is as follows:
35 parts of silicate cements; 16 parts of light calcined magnesias; As 8 parts of 8 parts in the hydrogen peroxide of whipping agent and rosin soda soaps; As 3 parts of 5 parts of the calcium stearates of stablizer and naphthalenes; 16 parts of plant stalk powders; 33 parts in water.
Embodiment 4
In the materials for wall of the present invention, each ingredients weight parts is as follows:
50 parts of silicate cements; 20 parts of light calcined magnesias; As 10 parts of 10 parts in the hydrogen peroxide of whipping agent and rosin soda soaps; As 5 parts of 6 parts of the calcium stearates of stablizer and naphthalenes; 20 parts in flyash; 35 parts in water.
After testing, the unit weight of lagging material of the present invention is 230-250Kg/m 325 ℃ of following thermal conductivity≤0.065w/m.k, 800 ℃ (rock wool fat plate is 300 ℃ to maximum operation (service) temperature, polystyrene board and polyurethane sheet are 100 ℃), hydrophobic rate 〉=98% (rock wool fat plate and pearlite slab all not hydrophobic), non-inflammability (and vinylbenzene plate, polyurethane sheet and rock wool fat plate all have combustibility); Dry shrinkage≤0.5mm/m.Building block crushing strength of the present invention is 1.5Mpa, crushing resistance 〉=0.8Mpa.
The advantage that building block of the present invention has ultimate compression strength height, dimensional stability, waterproof, prevents fires, is easy to cut.

Claims (10)

1, a kind of lightweight heatproof porous wall material is characterized in that, is made up of the component with following weight part:
Silicate cement 20-50 part; Light calcined magnesia 10-20 part; Hydrogen peroxide 5-10 part and rosin soda soap 5-10 part as whipping agent; Calcium stearate 2-6 part and naphthalene 1-5 part as stablizer; Be selected from stopping composition 10-20 part of plant stalk powder or wood powder or flyash; Add an amount of water.
2, materials for wall according to claim 1 is characterized in that, described each ingredients weight parts is as follows:
20 parts of silicate cements; 10 parts of light calcined magnesias; As 5 parts of 5 parts in the hydrogen peroxide of whipping agent and rosin soda soaps; As 1 part of 2 parts of the calcium stearates of stablizer and naphthalene; 10 parts of plant stalk powders.
3, materials for wall according to claim 1 is characterized in that, described each ingredients weight parts is as follows:
25 parts of silicate cements; 12 parts of light calcined magnesias; As 6 parts of 7 parts in the hydrogen peroxide of whipping agent and rosin soda soaps; As 2 parts of 4 parts of the calcium stearates of stablizer and naphthalenes; 12 parts of wood powders.
4, materials for wall according to claim 1 is characterized in that, described each ingredients weight parts is as follows:
35 parts of silicate cements; 16 parts of light calcined magnesias; As 8 parts of 8 parts in the hydrogen peroxide of whipping agent and rosin soda soaps; As 3 parts of 5 parts of the calcium stearates of stablizer and naphthalenes; 16 parts of plant stalk powders.
5, materials for wall according to claim 1 is characterized in that, described each ingredients weight parts is as follows:
50 parts of silicate cements; 20 parts of light calcined magnesias; As 10 parts of 10 parts in the hydrogen peroxide of whipping agent and rosin soda soaps; As 5 parts of 6 parts of the calcium stearates of stablizer and naphthalenes; Flyash 20.
6, a kind of concrete foamed heat insulating building block of adopting material as claimed in claim 1, it is characterized in that, comprise that perfusion is filled with lightweight heatproof porous wall material layer (3) between the inside and outside interlayer by the insulation connecting strip that is provided with between concrete intraformational bed (2) and outside sandwich (1) and the inside and outside interlayer that is parallel to each other more than two.
7, insulation blocks according to claim 6 is characterized in that, described adiabatic connecting strip is a plastics tubing, and the material of casing pack and lightweight heatproof porous wall material layer (3) is identical.
8, insulation blocks according to claim 6 is characterized in that, described adiabatic connecting strip is a batten.
9, insulation blocks according to claim 6 is characterized in that, described adiabatic connecting strip is a thick bamboo tube.
According to the described insulation blocks of the arbitrary claim of claim 6-9, it is characterized in that 10, described intraformational bed (2) thickness is 20mm, outside sandwich (1) thickness is 30mm; Be embedded with woven wire or fibrous reticulum in the inside and outside interlayer; Described insulation connecting strip is three, and is distributed on the midline position of building block length direction.
CNB2005100214660A 2005-08-15 2005-08-15 Lightweight heatproof porous wall material and building blocks Expired - Fee Related CN100398483C (en)

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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102153363A (en) * 2010-12-28 2011-08-17 南京工业大学 Ultra-low density foam concrete and preparation method thereof
CN102303979A (en) * 2011-06-30 2012-01-04 谢文靖 Light fireproof insulation board and production method thereof
CN102372495A (en) * 2011-08-16 2012-03-14 天津市得全轻质板制造有限公司 Cement foaming insulation board, preparation method and application thereof
GB2486761A (en) * 2011-10-18 2012-06-27 Lee Read Soap based thermal insulation
CN102557721A (en) * 2012-02-22 2012-07-11 武汉理工大学 Non-combustible energy-saving heat-preserving board and preparation method thereof
CN103113053A (en) * 2013-01-25 2013-05-22 深圳市展图新材料科技有限公司 Light-weight high-strength inorganic foam heat-insulation wall material
CN103159442A (en) * 2013-03-08 2013-06-19 张凤阳 Double insulation and multiple protection light weight wallboard and preparation method
CN105907118A (en) * 2016-04-29 2016-08-31 苏州蔻美新材料有限公司 Straw based porous material preparation method
CN107419813A (en) * 2016-02-24 2017-12-01 张日龙 A kind of building panel
CN107514091A (en) * 2017-08-25 2017-12-26 太仓卡斯特姆新材料有限公司 A kind of exterior wall fire-retardant heat insulation composite
CN108409241A (en) * 2018-03-26 2018-08-17 宋正国 A kind of stand alone type abscess lightweight filler and foaming method
CN110107015A (en) * 2018-02-01 2019-08-09 陆相成 A kind of no heat bridge is mostly used wall block

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1174824A (en) * 1996-08-26 1998-03-04 王展 Flame-retarded light wall plate
CN2320698Y (en) * 1997-07-22 1999-05-26 华荣南 Monolithic wire-net frame light foamed wallboard
CN1178202A (en) * 1997-11-03 1998-04-08 内江市车务段装卸服务公司 Lightweight hollow wall panel and manufacture thereof
CN1251358A (en) * 1999-10-15 2000-04-26 唐绍林 Light-wt. composite wall slurry and method for forming composite wall thereof

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102153363B (en) * 2010-12-28 2013-07-17 南京工业大学 Ultra-low density foam concrete and preparation method thereof
CN102153363A (en) * 2010-12-28 2011-08-17 南京工业大学 Ultra-low density foam concrete and preparation method thereof
CN102303979A (en) * 2011-06-30 2012-01-04 谢文靖 Light fireproof insulation board and production method thereof
CN102372495A (en) * 2011-08-16 2012-03-14 天津市得全轻质板制造有限公司 Cement foaming insulation board, preparation method and application thereof
GB2486761A (en) * 2011-10-18 2012-06-27 Lee Read Soap based thermal insulation
GB2486761B (en) * 2011-10-18 2012-11-14 Lee Read Soap based thermal insulation
CN102557721A (en) * 2012-02-22 2012-07-11 武汉理工大学 Non-combustible energy-saving heat-preserving board and preparation method thereof
CN103113053A (en) * 2013-01-25 2013-05-22 深圳市展图新材料科技有限公司 Light-weight high-strength inorganic foam heat-insulation wall material
CN103159442A (en) * 2013-03-08 2013-06-19 张凤阳 Double insulation and multiple protection light weight wallboard and preparation method
CN107419813A (en) * 2016-02-24 2017-12-01 张日龙 A kind of building panel
CN105907118A (en) * 2016-04-29 2016-08-31 苏州蔻美新材料有限公司 Straw based porous material preparation method
CN107514091A (en) * 2017-08-25 2017-12-26 太仓卡斯特姆新材料有限公司 A kind of exterior wall fire-retardant heat insulation composite
CN110107015A (en) * 2018-02-01 2019-08-09 陆相成 A kind of no heat bridge is mostly used wall block
CN108409241A (en) * 2018-03-26 2018-08-17 宋正国 A kind of stand alone type abscess lightweight filler and foaming method

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