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CN1912030B - High temperature applied acrylic resin paint and method of manufacture - Google Patents

High temperature applied acrylic resin paint and method of manufacture Download PDF

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Publication number
CN1912030B
CN1912030B CN 200510090153 CN200510090153A CN1912030B CN 1912030 B CN1912030 B CN 1912030B CN 200510090153 CN200510090153 CN 200510090153 CN 200510090153 A CN200510090153 A CN 200510090153A CN 1912030 B CN1912030 B CN 1912030B
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CN1912030A (en
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张丽萍
张彦军
贺江
李小朋
梁镐
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China National Petroleum Corp
CNPC Engineering Technology Research Institute Co Ltd
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China National Petroleum Corp
CNPC Engineering Technology Research Institute Co Ltd
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Abstract

The invention relates to a high temperature-coated crylic resin coating and the manufacturing method thereof, using acrylic resin, anhydrous dimethylbenzene, butyl acetate and isophorone mixed solvent, n-butyl alcohol etherified amino resin, zinc iso-octoate solution, superfine talcum powder, titanium dioxide, calcined kaoline, organic modified bentone solution, gamma-ethyl propylene acyloxy propyl trimethyl silane solution, vinyl resin copolymer solution to compose solution A, and using hexamethylene diisocyanate polyisocyanate, dimethylbenzene and methoxy propyl acetate mixed solution to compose solution B, and as using, mixing the two solutions. And it has low cost, convenient to construct, able to normally construct when the surface temperature of workpiece is up to 70 deg.C and forms a coating with excellent appearance, and can be used to make external anticorrosive coatings for petrochemical storage tanks and roofs in high temperature environment.

Description

High temperature coated acrylic resin paint and manufacture method
Technical field
The present invention relates to a kind of high temperature coated acrylic resin paint and manufacture method, be used for the outer anticorrosive coating of petrochemical complex storage tank outside surface and buildings roof surface under the hot environment.
Background technology
Existing synthetic resin coating, the outside surface anticorrosion coating that is used for the petrochemical complex storage tank, the envrionment temperature adaptive faculty is poor to external world for its coating, when envrionment temperature is high, especially the coat objects surface temperature reaches 70 ℃, the coating that its coating forms contains a large amount of bubbles, and coating is apparent relatively poor, influences ornamental and preservative effect.
Summary of the invention
The technical problem to be solved in the present invention: but avoid above-mentioned weak point of the prior art and provide that a kind of manufacture method is simple, cost is low, easy construction, its coating has good protection against corrosion and decorate properties, particularly coating can reach high temperature coated acrylic resin paint and the manufacture method that 70 ℃ of normal constructions obtain the good-looking coating on the coat objects surface.
The technical solution used in the present invention
A kind of high temperature coated acrylic resin paint of the present invention, it is characterized in that being made up of A liquid and B liquid, wherein A liquid is by 1 parts by weight of acrylic acid resin, 0.1~0.4 weight part such as presses at the mixed solvent of weight blended anhydrous dimethyl benzene and N-BUTYL ACETATE and isophorone, 0.01 the propyl carbinol etherified amino resins of~0.05 weight part, 0.01 the isocaprylic acid zinc solution of~0.05 weight part, 0.01~0.06 weight part particle diameter is 1~100nm superfine talcum powder, 0.1~0.4 weight part titanium dioxide, 0.2~0.5 weight part calcined kaolin, 0.01~0.05 weight part organic bentonite solution, 0.001 the γ of~0.005 weight part-ethyl propylene acyloxy propyl trimethoxy silicane solution, 0.0 the Vinylite copolymer solution of 1~0.06 weight part is formed; B liquid is made up of the methoxyacetic acid propyl ester mixing solutions of hexamethylene diisocyanate polymeric polyisocyanate, 0.5~1 weight part dimethylbenzene and 0.5~1 weight part 1 weight part, is made up of 1 weight part A liquid and 0.06~0.1 weight part B liquid during use.
More excellent high temperature coated acrylic resin paint, it is characterized in that being made up of A liquid and B liquid, wherein A liquid is by 1 parts by weight of acrylic acid resin, 0.4 weight part such as presses at the mixed solvent of weight blended anhydrous dimethyl benzene and N-BUTYL ACETATE and isophorone, 0.05 the propyl carbinol etherified amino resins of weight part, 0.05 the isocaprylic acid zinc solution of weight part, 0.06 the weight part particle diameter is 1~100nm superfine talcum powder, 0.12 the titanium dioxide of weight part, 0.35 weight part calcined kaolin, 0.014 weight part organic bentonite solution, 0.005 weight part γ-ethyl propylene acyloxy propyl trimethoxy silicane solution, 0.06 the Vinylite copolymer solution of weight part is formed; B liquid is made up of the methoxyacetic acid propyl ester mixing solutions of 1 weight part hexamethylene diisocyanate polymeric polyisocyanate, 1 weight part dimethylbenzene and 1 weight part, is made up of 1 weight part A liquid and 0.083 weight part B liquid during use.
The manufacture method of high temperature coated acrylic resin paint, it is characterized in that in 1 parts by weight of acrylic acid resin, adding 0.1~0.4 weight part by etc. the mixed solvent of weight blended anhydrous dimethyl benzene and N-BUTYL ACETATE and isophorone, the propyl carbinol etherified amino resins that adds 0.01~0.05 weight part, the isocaprylic acid zinc solution that adds 0.01~0.05 weight part again, adding 0.01~0.06 weight part particle diameter is 1~100nm superfine talcum powder, be heated and be controlled at 25 ℃, high-speed stirring 1h, under agitation add 0.1~0.4 weight part titanium dioxide, 0.2~0.5 weight part calcined kaolin, 0.01~0.05 weight part organic bentonite solution, grind 1.5h with sand mill then, γ-ethyl propylene acyloxy propyl trimethoxy silicane the solution that adds 0.001~0.005 weight part afterwards, 0.01 the Vinylite copolymer solution of~0.06 weight part, mix, make A liquid; Make B liquid by 1 weight part hexamethylene diisocyanate polymeric polyisocyanate, 0.5~1 weight part dimethylbenzene and 0.5~1 weight part methoxyacetic acid propyl ester mixing solutions, mix by 1 weight part A liquid and 0.06~0.1 weight part B liquid during use.
The manufacture method of more excellent high temperature coated acrylic resin paint, it is characterized in that in 1 parts by weight of acrylic acid resin adding 0.4 weight part by etc. the mixed solvent of weight blended anhydrous dimethyl benzene and N-BUTYL ACETATE and isophorone, the propyl carbinol etherified amino resins that adds 0.05 weight part, the isocaprylic acid zinc solution that adds 0.05 weight part again, adding 0.06 weight part particle diameter is 1~100nm superfine talcum powder, be heated and be controlled at 25 ℃, high-speed stirring 1h, under agitation add 0.12 weight part titanium dioxide, 0.35 weight part calcined kaolin, 0.014 weight part organic bentonite solution, grind 1.5h with sand mill then, γ-ethyl propylene acyloxy propyl trimethoxy silicane the solution that adds 0.005 weight part afterwards, 0.06 the Vinylite copolymer solution of weight part, mix, make A liquid; Make B liquid by 1 weight part hexamethylene diisocyanate polymeric polyisocyanate, 1 weight part dimethylbenzene and 1 weight part methoxyacetic acid propyl ester mixing solutions, mix by 1 weight part A liquid and 0.083 weight part B liquid during use.
High temperature coated acrylic resin paint of the present invention, wherein A liquid is made up of acrylic resin, propyl carbinol etherified amino resins, anhydrous dimethyl benzene and N-BUTYL ACETATE and isophorone mixed solvent, isocaprylic acid zinc, superfine talcum powder, titanium dioxide, superfine calcined kaolin, organic bentonite solution, γ-ethyl propylene acyloxy propyl trimethoxy silicane solution, Vinylite copolymer solution, B liquid is made up of hexamethylene diisocyanate polymeric polyisocyanate, dimethylbenzene and methoxyacetic acid propyl ester mixing solutions, and A liquid and B liquid are formed coating during use.The particle diameter that uses is 1~100nm superfine talcum powder, calcined kaolin etc., helps the dispersion film forming of color stuffing, helps to form bubble-freely well to film.Dimethylbenzene that uses and N-BUTYL ACETATE and isophorone mixed solvent help solvent to form the gradient type volatilization, can be in the high temperature surface applied, and superfine talcum powder etc. is disperseed with the resin thorough mixing, wherein the three is by equal weight part batching.The Vinylite copolymer solution that uses helps to eliminate the bubble in the coating, makes coating level and smooth.The organic bentonite solution that uses helps to improve the thixotropy and the application property of coating, improves the stability in storage of coating.Thereby the γ-ethyl propylene acyloxy propyl trimethoxy silicane solution that uses helps to improve the ornamental and anticorrosion ability that the glossiness of coating improves coating.
The present invention's beneficial effect compared with prior art
1, high temperature coated acrylic resin paint of the present invention, the coating cost is low, the construction application scope is wide, easy construction, its coating can reach 70 ℃ in the coat objects surface temperature and carry out the coating that coating construction obtains good-looking.Its coating has good weathering resistance, abrasion resistance, contamination resistance.The erosion shield that can be used for erosion shield, buildings roof and the exterior wall surface of petrochemical complex steel tank outside surface.
2, the manufacture method of high temperature coated acrylic resin paint of the present invention, technology is simple, need not specific installation, the ratio of performance to price is good, and cost is low.
Embodiment 1
The manufacture method of high temperature coated acrylic resin paint of the present invention.In 1 parts by weight of acrylic acid resin, add 0.4 weight part and the mixed solvent of weight blended anhydrous dimethyl benzene and N-BUTYL ACETATE and isophorone such as press, the propyl carbinol etherified amino resins that adds 0.05 weight part, the isocaprylic acid zinc solution that adds 0.05 weight part again, adding 0.06 weight part particle diameter is 1~100nm superfine talcum powder, be heated and be controlled at 25 ℃, high-speed stirring 1h, under agitation add 0.12 weight part titanium dioxide, 0.35 weight part calcined kaolin, 0.014 weight part organic bentonite solution, grind 1.5h with sand mill then, γ-ethyl propylene acyloxy propyl trimethoxy silicane the solution that adds 0.005 weight part afterwards, 0.06 the Vinylite copolymer solution of weight part, mix, make A liquid; Make B liquid by 1 weight part hexamethylene diisocyanate polymeric polyisocyanate, 1 weight part dimethylbenzene and 1 weight part methoxyacetic acid propyl ester mixing solutions, mix by 1 weight part A liquid and 0.083 weight part B liquid during use.
High temperature coated acrylic resin paint is at 70 ℃ of coating constructions of high temperature, its formed coating test in coating sclerosis back shows, the coat objects surface temperature reach 70 ℃ can obtain good-looking, the complete coating of filming, this coating has good weathering resistance, abrasion resistance, contamination resistance.
Raw materials used is commercially available product.

Claims (4)

1.一种高温涂敷的丙烯酸树脂涂料,其特征是由A液和B液组成,其中A液是由1重量份丙烯酸树脂、0.1~0.4重量份按等重量混合的无水二甲苯和醋酸丁酯及异佛尔酮的混合溶剂、0.01~0.05重量份的正丁醇醚化氨基树脂、0.01~0.05重量份的异辛酸锌溶液、0.01~0.06重量份颗粒直径为1~100nm超细滑石粉、0.1~0.4重量份钛白粉、0.2~0.5重量份煅烧高岭土、0.01~0.05重量份有机改性膨润土溶液、0.001~0.005重量份的γ-乙基丙烯酰氧基丙基三甲氧基硅烷溶液、0.01~0.06重量份的乙烯基树脂共聚物溶液组成;B液由1重量份六亚甲基二异氰酸酯聚异氰酸酯、0.5~1重量份二甲苯和0.5~1重量份的甲氧基乙酸丙酯混合溶液组成,使用时由1重量份A液与0.06~0.1重量份B液组成。1. The acrylic resin coating of a kind of high temperature coating is characterized in that it is made up of A liquid and B liquid, and wherein A liquid is anhydrous xylene and acetic acid mixed by equal weight by 1 weight part acrylic resin, 0.1~0.4 weight part Mixed solvent of butyl ester and isophorone, 0.01-0.05 parts by weight of n-butanol etherified amino resin, 0.01-0.05 parts by weight of zinc isooctanoate solution, 0.01-0.06 parts by weight of ultrafine talc with a particle diameter of 1-100 nm powder, 0.1-0.4 parts by weight of titanium dioxide, 0.2-0.5 parts by weight of calcined kaolin, 0.01-0.05 parts by weight of organically modified bentonite solution, and 0.001-0.005 parts by weight of γ-ethylacryloyloxypropyltrimethoxysilane solution , 0.01 to 0.06 parts by weight of vinyl resin copolymer solution; liquid B consists of 1 part by weight of hexamethylene diisocyanate polyisocyanate, 0.5 to 1 part by weight of xylene and 0.5 to 1 part by weight of methoxypropyl acetate The mixed solution is composed of 1 weight part of liquid A and 0.06-0.1 weight part of liquid B when in use. 2.根据权利要求1所述的高温涂敷的丙烯酸树脂涂料,其中A液是由1重量份丙烯酸树脂、0.4重量份按等重量混合的无水二甲苯和醋酸丁酯及异佛尔酮的混合溶剂、0.05重量份的正丁醇醚化氨基树脂、0.05重量份的异辛酸锌溶液、0.06重量份颗粒直径为1~100nm超细滑石粉、0.12重量份的钛白粉、0.35重量份煅烧高岭土、0.014重量份有机改性膨润土溶液、0.005重量份γ-乙基丙烯酰氧基丙基三甲氧基硅烷溶液、0.06重量份的乙烯基树脂共聚物溶液组成;B液是由1重量份六亚甲基二异氰酸酯聚异氰酸酯、1重量份二甲苯和1重量份的甲氧基乙酸丙酯混合溶液组成,使用时由1重量份A液与0.083重量份B液组成。2. the acrylic resin coating of high-temperature coating according to claim 1, wherein A liquid is by 1 weight part acrylic resin, 0.4 weight part mixed by equal weight anhydrous xylene and butyl acetate and isophorone Mixed solvent, 0.05 parts by weight of n-butanol etherified amino resin, 0.05 parts by weight of zinc isooctanoate solution, 0.06 parts by weight of ultrafine talcum powder with a particle diameter of 1-100 nm, 0.12 parts by weight of titanium dioxide, and 0.35 parts by weight of calcined kaolin , 0.014 parts by weight of organically modified bentonite solution, 0.005 parts by weight of γ-ethylacryloxypropyltrimethoxysilane solution, and 0.06 parts by weight of vinyl resin copolymer solution; B liquid is composed of 1 part by weight of hexaethylene The mixed solution of methyl diisocyanate polyisocyanate, 1 weight part of xylene and 1 weight part of methoxypropyl acetate is composed of 1 weight part of A liquid and 0.083 weight part of B liquid. 3.一种如权利要求1所述的高温涂敷的丙烯酸树脂涂料的制造方法,其特征是在1重量份丙烯酸树脂中加入0.1~0.4重量份按等重量混合的无水二甲苯和醋酸丁酯及异佛尔酮的混合溶剂,加入0.01~0.05重量份的正丁醇醚化氨基树脂,再加入0.01~0.05重量份的异辛酸锌溶液,加入0.01~0.06重量份颗粒直径为1~100nm超细滑石粉,将其加热控制在25℃,高速搅拌1h,在搅拌下加入0.1~0.4重量份钛白粉、0.2~0.5重量份煅烧高岭土、0.01~0.05重量份有机改性膨润土溶液,然后用砂磨机研磨1.5h,之后加入0.001~0.005重量份的γ-乙基丙烯酰氧基丙基三甲氧基硅烷溶液、0.01~0.06重量份的乙烯基树脂共聚物溶液,混合均匀,制成A液;由1重量份六亚甲基二异氰酸酯聚异氰酸酯、0.5~1重量份二甲苯和0.5~1重量份甲氧基乙酸丙酯混合溶液制成B液,使用时由1重量份A液与0.06~0.1重量份B液混合而成。3, a kind of manufacture method of the acrylic resin paint of high temperature coating as claimed in claim 1 is characterized in that adding 0.1~0.4 weight part by anhydrous xylene and butyl acetate mixed by equal weight in 1 weight part of acrylic resin Mixed solvent of ester and isophorone, add 0.01-0.05 parts by weight of n-butanol etherified amino resin, then add 0.01-0.05 parts by weight of zinc isooctanoate solution, add 0.01-0.06 parts by weight of particle diameter of 1-100nm Ultrafine talc powder, heating it at 25°C, stirring at high speed for 1 hour, adding 0.1-0.4 parts by weight of titanium dioxide, 0.2-0.5 parts by weight of calcined kaolin, and 0.01-0.05 parts by weight of organically modified bentonite solution under stirring, and then using Grind with a sand mill for 1.5 hours, then add 0.001 to 0.005 parts by weight of γ-ethylacryloxypropyltrimethoxysilane solution and 0.01 to 0.06 parts by weight of vinyl resin copolymer solution, and mix well to make A liquid; liquid B is made from a mixed solution of 1 part by weight of hexamethylene diisocyanate polyisocyanate, 0.5 to 1 part by weight of xylene and 0.5 to 1 part by weight of propyl methoxyacetate. 0.06-0.1 parts by weight of liquid B are mixed. 4.根据权利要求3所述的高温涂敷的丙烯酸树脂涂料的制造方法,其特征是在1重量份丙烯酸树脂中加入0.4重量份按等重量混合的无水二甲苯和醋酸丁酯及异佛尔酮的混合溶剂,加入0.05重量份的正丁醇醚化氨基树脂,再加入0.05重量份的异辛酸锌溶液,加入0.06重量份颗粒直径为1~100nm超细滑石粉,将其加热控制在25℃,高速搅拌1h,在搅拌下加入0.12重量份钛白粉、0.35重量份煅烧高岭土、0.014重量份有机改性膨润土溶液,然后用砂磨机研磨1.5h,之后加入0.005重量份的γ-乙基丙烯酰氧基丙基三甲氧基硅烷溶液、0.06重量份的乙烯基树脂共聚物溶液,混合均匀,制成A液;由1重量份六亚甲基二异氰酸酯聚异氰酸酯、1重量份二甲苯和1重量份甲氧基乙酸丙酯混合溶液制成B液,使用时由1重量份A液与0.083重量份B液混合而成。4. the manufacture method of the acrylic resin paint of high-temperature coating according to claim 3 is characterized in that adding 0.4 weight part anhydrous xylene and butyl acetate and isophore mixed by equal weight in 1 weight part acrylic resin A mixed solvent of ketone, adding 0.05 parts by weight of n-butanol etherified amino resin, then adding 0.05 parts by weight of zinc isooctanoate solution, adding 0.06 parts by weight of particle diameter is 1 ~ 100nm ultrafine talcum powder, its heating is controlled at Stir at 25°C at high speed for 1 hour, add 0.12 parts by weight of titanium dioxide, 0.35 parts by weight of calcined kaolin, and 0.014 parts by weight of organically modified bentonite solution under stirring, then grind for 1.5 hours with a sand mill, and then add 0.005 parts by weight of γ-B Acryloyloxypropyltrimethoxysilane solution, 0.06 parts by weight of vinyl resin copolymer solution, mixed uniformly, and made into liquid A; by 1 part by weight of hexamethylene diisocyanate polyisocyanate, 1 part by weight of xylene Mixed solution with 1 weight part of methoxypropyl acetate to prepare B liquid, which is formed by mixing 1 weight part of A liquid and 0.083 weight part of B liquid during use.
CN 200510090153 2005-08-11 2005-08-11 High temperature applied acrylic resin paint and method of manufacture Expired - Lifetime CN1912030B (en)

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CN101255017B (en) * 2007-12-01 2011-07-20 芜湖力特尔涂料制造有限公司 Glass hot curing lacquer enamel and preparation method thereof
CN101440254B (en) * 2008-12-19 2012-02-29 安庆菱湖涂料有限公司 Anticorrosion paint for decorating inner and external walls of power station transformer, and preparation thereof
CN107083174A (en) * 2017-06-21 2017-08-22 鹤山市索尔达化工有限公司 A kind of XYF types high rigidity coating

Citations (2)

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US6069275A (en) * 1998-01-28 2000-05-30 Rhodia Inc. Monomers and polymers and latices therefrom
CN1391589A (en) * 1999-11-23 2003-01-15 纳幕尔杜邦公司 Clear coating composition having improved early hardness and water resistance

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6069275A (en) * 1998-01-28 2000-05-30 Rhodia Inc. Monomers and polymers and latices therefrom
CN1284949A (en) * 1998-01-28 2001-02-21 罗狄亚公司 Cycloalkylene urea-containing monomers and polymers and latexes prepared therefrom
CN1391589A (en) * 1999-11-23 2003-01-15 纳幕尔杜邦公司 Clear coating composition having improved early hardness and water resistance

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