CN1996063A - Film narrow band-pass reflective filter - Google Patents
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Abstract
本发明公开了一种新型的薄膜窄带反射滤光片。它由高低折射率薄膜与一层极薄的金属薄膜构成。其基本结构为:从基板侧开始是高周期数的高、低折射率交替膜堆-间隔层薄膜-若干周期的高低折射率交替膜堆-极薄的金属膜到入射媒介,入射光从入射媒介入射到薄的金属膜。利用极薄的金属薄膜,实现了窄的半高宽、高的峰值反射率与深的反射截止度。本发明结构直观,设计方便,可以根据实际需要来自由调整峰值反射率与半高宽的大小,且入射光损耗小,制作工艺方便,制作成本低,易于集成,适合应用于光波分复用、显示等光学系统中。
The invention discloses a novel thin-film narrow-band reflective filter. It consists of high and low refractive index films and an extremely thin metal film. Its basic structure is: starting from the substrate side, there are alternating high and low refractive index film stacks with a high number of periods - spacer film - several periods of alternating high and low refractive index film stacks - an extremely thin metal film to the incident medium, and the incident light from the incident light The medium is incident on a thin metal film. Utilizing an extremely thin metal film, a narrow FWHM, high peak reflectivity and deep reflection cutoff are achieved. The invention has an intuitive structure, convenient design, and can freely adjust the peak reflectivity and half-width according to actual needs, and the incident light loss is small, the manufacturing process is convenient, the manufacturing cost is low, and it is easy to integrate. It is suitable for optical wavelength division multiplexing, display and other optical systems.
Description
技术领域technical field
本发明涉及一种新型的薄膜窄带反射滤光片。The invention relates to a novel thin-film narrow-band reflective filter.
背景技术Background technique
20世纪90年代初,对光网络通信系统的研究已经成为各国和跨国研究计划的重点,亚洲与欧美国家都纷纷制定了各种研究计划,同时,各种学术团体和标准化组织也积极开展了光通信尤其是光波分复用系统方面的研究。而在光波分复用系统中,处处都离不开对单一波长光的操作处理,因此光波解复用器就成为这个系统中最关键的器件之一。于是以法布里-珀罗滤光片为代表的介质膜滤光型波分复用器,便因其高的峰值透过率及特宽的截止区在光学、天文物理学等各个领域得到了广泛的应用。但是由于这些滤光片大都属于透射式,在系统中的排列较占空间,不易于集成;此外,为了获得高的峰值透过率和窄的半高宽,这些滤光片不得不成倍增加反射膜堆的周期数,且大幅提高对膜系对称性的要求,造成了镀制的困难。In the early 1990s, research on optical network communication systems has become the focus of national and transnational research programs. Asian, European and American countries have formulated various research programs. At the same time, various academic groups and standardization organizations have also actively carried out optical Communication, especially research on optical wavelength division multiplexing systems. In the optical wavelength division multiplexing system, the operation and processing of single wavelength light is indispensable everywhere, so the optical wave demultiplexer becomes one of the most critical devices in this system. Therefore, the dielectric film filter type wavelength division multiplexer represented by the Fabry-Perot filter has been widely used in various fields such as optics and astrophysics because of its high peak transmittance and ultra-wide cut-off area. a wide range of applications. However, since most of these filters are transmissive, the arrangement in the system takes up more space and is not easy to integrate; in addition, in order to obtain high peak transmittance and narrow half-width, these filters have to be multiplied The number of cycles of the reflective film stack and the greatly increased requirements for the symmetry of the film system have caused difficulties in plating.
发明内容Contents of the invention
本发明的目的是提供一种新型的薄膜窄带反射滤光片,它可以实现对反射光波的解复用效果。The purpose of the present invention is to provide a novel thin-film narrow-band reflective filter, which can realize the demultiplexing effect on reflected light waves.
该薄膜滤光片,采用极薄的金属薄膜-高低折射率交叠膜层构成的较低反射率的反射膜堆-间隔层薄膜-高反射率的(周期更多)高低折射率交叠构成的反射膜堆,组成薄膜器件。由反射率较低的反射膜堆、间隔层(可看作谐振腔)薄膜与高反膜堆组成所谓的Gires-Tournois(GT)谐振腔,因此该器件可以认为是在基板上镀制了GT腔,然后在入射媒介与GT腔之间增加了一层厚度极薄的金属层。The thin-film filter is composed of an extremely thin metal film-high and low refractive index overlapping film layers, a low reflectivity reflective film stack-spacer film-high reflectivity (more cycles) high and low refractive index overlapping composition The reflective film stack constitutes a thin film device. The so-called Gires-Tournois (GT) resonant cavity is composed of a reflective film stack with low reflectivity, a spacer layer (which can be regarded as a resonant cavity) film and a high reflective film stack, so the device can be considered as a GT plated on the substrate. cavity, and then an extremely thin metal layer is added between the incident medium and the GT cavity.
本发明采用传统的薄膜沉积工艺进行制备,方法简单、制作成本低、易集成。而整个GT腔完全由高、低折射率介质材料蒸镀而成,有插入损耗小、完全无源、无须温度控制等特点。本发明是反射式器件,在不同波长光束入射时,可以实现对反射光波滤波、分色、解复用的效果,在光学系统中易于排列。此外,本发明结构直观、设计方便,可以根据实际需要自由调整峰值反射率与半高宽的大小,获得尽可能高的峰值反射率、极窄的半高宽以及很深的宽带截止度。在密集波分复用、光电显示以及光学信息处理等系统中的应用前景将会非常广泛。The invention adopts the traditional thin film deposition process for preparation, the method is simple, the production cost is low, and the integration is easy. The whole GT cavity is completely made of high and low refractive index dielectric materials, which has the characteristics of low insertion loss, completely passive, and no need for temperature control. The invention is a reflective device, which can realize the effects of filtering, color separation and demultiplexing of reflected light waves when light beams of different wavelengths are incident, and is easy to arrange in an optical system. In addition, the present invention has an intuitive structure and convenient design, and can freely adjust the peak reflectivity and FWHM according to actual needs, so as to obtain the highest possible peak reflectivity, extremely narrow FWHM and deep broadband cutoff. The application prospects in systems such as dense wavelength division multiplexing, optoelectronic display and optical information processing will be very broad.
附图说明Description of drawings
下面结合附图和实施例对本发明进一步说明。The present invention will be further described below in conjunction with the accompanying drawings and embodiments.
图1是薄膜窄带反射滤光片结构示意图;Fig. 1 is a structural schematic diagram of a thin-film narrow-band reflective filter;
图2是理论设计薄膜窄带反射滤光片的反射率光谱曲线示意图;Fig. 2 is a schematic diagram of the reflectance spectrum curve of a theoretically designed thin-film narrow-band reflective filter;
图3是实际镀制薄膜窄带反射滤光片的反射率光谱曲线示意图;Fig. 3 is the reflectance spectrum curve schematic diagram of actual plated thin-film narrow-band reflective filter;
图4是薄膜窄带反射滤光片的波长解复用应用示意图;Fig. 4 is a schematic diagram of wavelength demultiplexing application of thin-film narrow-band reflective filter;
图5是薄膜窄带反射滤光片在彩色显示领域中的应用示意图;Fig. 5 is a schematic diagram of the application of thin-film narrow-band reflective filters in the field of color display;
图中:1、入射媒介,2、金属膜,3、若干周期的高、低折射率交替膜堆,4、间隔层薄膜,5、高周期的高、低折射率交替膜堆,6、基板,7、四个中心波长不同的薄膜窄带反射滤光片,8、中心波长分别对应红、绿、蓝三原色的薄膜窄带反射滤光片。In the figure: 1. Incident medium, 2. Metal film, 3. Several periods of alternating high and low refractive index film stacks, 4. Spacer film, 5. High period high and low refractive index alternating film stacks, 6. Substrate , 7, four thin-film narrow-band reflective filters with different central wavelengths, 8, thin-film narrow-band reflective filters with central wavelengths corresponding to red, green and blue primary colors respectively.
具体实施方式Detailed ways
薄膜窄带反射滤光片在基板6侧首先镀制了高周期数的高、低折射率交替膜堆5,接着镀制了间隔层薄膜4-若干周期的高低折射率交替膜堆3-极薄的金属膜2到入射媒介1,入射光从入射媒介入射到薄的金属膜。The thin-film narrow-band reflective filter is first coated with alternating high and low refractive index film stacks 5 with a high number of cycles on the side of the substrate 6, and then coated with a spacer layer film 4-several periods of high and low refractive index alternating film stacks 3-extremely thin The metal film 2 enters the incident medium 1, and the incident light enters the thin metal film from the incident medium.
本发明可以实现对反射光波的解复用效果。该器件由高、低折射率交替的多层介质光学干涉薄膜与金属构成,其膜系结构可以表述为:基板-(HL)m2H 2L(HL)m1 M-入射媒介。M代表金属,一般选用铬(Cr),因为这种金属复折射率的实部(nc)与虚部(kc)较为接近,既不会将入射光在初入射时就过多的反射回去,而且可以对非中心波长的入射光实现较强的吸收,从而获得很深的宽带截止度。但是需要注意这层金属需要控制在纳米量级,否则大部分入射光会直接被金属吸收,而无法获得高的峰值反射率。H、L分别代表高、低折射率介质,光学厚度均为中心波长的1/4,折射率分别表示为nH与nL,可以根据实际需要自由选取。m1、m2代表反射膜堆的周期数,对本发明而言,m1一般较小,而m2需要很大,以实现足够高的反射率。在这种结构中,中心波长的光波在间隔层薄膜(即谐振腔)内不断来回振动而存贮了大量的能量,这些能量出射后被后方的高反膜反射回去,而返回的场强由于薄膜干涉的作用,在金属层与相邻反射膜堆的界面上必定会达到一个极值,只要控制这时的极值为极小值,即进入金属层中的场强达到极小,因为金属层的尺寸仅在纳米量级,它便无法对光波进行强烈的吸收,由能量守恒定律可知,大部分光波均被反射回入射界面,达到很高的峰值反射率。而对于非中心波长的光来说,由于在金属层与反射膜堆的界面上无法达到场强的干涉极小值,势必有大量的能量被金属层吸收,于是形成了很深的宽带截止。The invention can realize the effect of demultiplexing reflected light waves. The device is composed of alternating high and low refractive index multi-layer dielectric optical interference films and metals, and its film structure can be expressed as: substrate-(HL) m2 H 2L(HL) m1 M-incident medium. M stands for metal, and chromium (Cr) is generally used, because the real part ( nc ) and imaginary part (k c ) of the complex refractive index of this metal are relatively close, and the incident light will not be reflected too much when it is first incident. Go back, and can achieve strong absorption of incident light at non-central wavelengths, thereby obtaining a deep broadband cut-off. However, it should be noted that this layer of metal needs to be controlled at the nanometer level, otherwise most of the incident light will be directly absorbed by the metal, and high peak reflectivity cannot be obtained. H and L represent high and low refractive index media respectively, the optical thickness is 1/4 of the central wavelength, and the refractive indices are expressed as n H and n L , which can be freely selected according to actual needs. m1 and m2 represent the period numbers of the reflective film stack. For the present invention, m1 is generally small, while m2 needs to be large to achieve a sufficiently high reflectivity. In this structure, the light wave of the central wavelength continuously vibrates back and forth in the spacer film (that is, the resonant cavity) and stores a large amount of energy. After the energy is emitted, it is reflected back by the rear high-reflection film, and the returned field strength is due to The effect of thin-film interference must reach an extreme value on the interface between the metal layer and the adjacent reflective film stack. As long as the extreme value at this time is controlled to be a minimum value, that is, the field strength entering the metal layer reaches a minimum, because the metal The size of the layer is only on the order of nanometers, so it cannot strongly absorb light waves. According to the law of energy conservation, most of the light waves are reflected back to the incident interface, reaching a high peak reflectivity. For the non-central wavelength light, since the interference minimum value of the field strength cannot be reached at the interface between the metal layer and the reflective film stack, a large amount of energy is bound to be absorbed by the metal layer, thus forming a deep broadband cut-off.
借助薄膜光学特征矩阵原理及微扰理论,可以近似求出薄膜窄带反射滤光片的峰值反射率R0及半高宽FWHM,表示为:With the help of thin-film optical characteristic matrix principle and perturbation theory, the peak reflectivity R 0 and half-maximum width FWHM of thin-film narrow-band reflective filter can be approximated, expressed as:
其中
公式中n0是入射媒介折射率,d是金属膜厚度,λ0是中心波长,高折射率与低折射率膜层的光学厚度均为这个波长的1/4。发现当膜堆周期数m2远大于m1时,峰值反射率R0基本可以认为达到100%;而在高低折射率比nH/nL或周期数m1足够大时,便可以达到尽可能窄的半高宽。因此,适当选取本发明中的各种参数,即可以满足不同使用环境的需要。In the formula, n 0 is the refractive index of the incident medium, d is the thickness of the metal film, λ 0 is the central wavelength, and the optical thickness of the high refractive index and low refractive index film layers is 1/4 of this wavelength. It is found that when the period number m2 of the film stack is much greater than m1, the peak reflectivity R 0 can basically be considered to reach 100%; and when the high-low refractive index ratio n H /n L or the period number m1 is sufficiently large, the narrowest possible reflectivity can be achieved. width at half height. Therefore, by properly selecting various parameters in the present invention, the requirements of different usage environments can be met.
图2给出了理论设计薄膜窄带反射滤光片的反射率光谱曲线示意图。中心波长为700nm,基板选用BK7(折射率为1.49),M选用Cr,中心波长处复折射率为(3.84-i4.37),厚度为3nm,H选用TiO2(折射率为2.19),L选用SiO2(折射率为1.45),m1取3,m2取7,整个滤光片的物理厚度为2.35μm。图3给出了按照理论设计而实际镀制出的薄膜窄带反射滤光片的反射率光谱曲线示意图,镀制结果为R0=91.3%,FWHM=11nm,与理论结果比较吻合,误差分别为3.1%与10%,与能够实现同样效果的窄带透射滤光片及以往成熟的介质反射滤光片相比,本发明物理厚度更薄,对结构对称性要求也不是很高;而与传统的金属诱导滤光片相比,由于本发明的反射峰并不靠诱导金属产生,所以无需在金属旁增加诱导层这些需要精确控制厚度的膜层,比较容易监控、制作。Figure 2 shows a schematic diagram of the reflectance spectrum curve of the theoretically designed thin-film narrow-band reflective filter. The central wavelength is 700nm, the substrate is BK7 (refractive index 1.49), M is Cr, the complex refractive index at the central wavelength is (3.84-i4.37), the thickness is 3nm, H is TiO 2 (refractive index 2.19), L SiO 2 (refractive index 1.45) is selected, m1 is taken as 3, m2 is taken as 7, and the physical thickness of the entire optical filter is 2.35 μm. Figure 3 shows a schematic diagram of the reflectance spectrum curve of the thin-film narrow-band reflective filter actually plated according to the theoretical design. The plated result is R 0 =91.3%, FWHM=11nm, which is consistent with the theoretical result, and the errors are respectively 3.1% and 10%, compared with the narrow-band transmission filter that can achieve the same effect and the mature dielectric reflection filter in the past, the physical thickness of the present invention is thinner, and the requirement for structural symmetry is not very high; Compared with the metal induction filter, since the reflection peak of the present invention is not generated by the induction metal, there is no need to add an induction layer next to the metal, which requires precise control of the thickness of the film layer, which is easier to monitor and manufacture.
薄膜窄带反射滤光片是反射式光学元件,只能实现对反射光波的滤光效果,尤其要注意的是,按本发明进行膜系设计时,中心波长处(LH)m1 2L(HL)m2 H-基板的导纳需要尽可能大,此时才能保证金属层与反射膜界面处的干涉场强达到极小值,实现高的峰值反射率。The thin-film narrow-band reflective filter is a reflective optical element, which can only achieve the filtering effect on reflected light waves. It should be especially noted that when the film system is designed according to the present invention, the central wavelength (LH) m1 2L(HL) m2 The admittance of the H-substrate needs to be as large as possible, so as to ensure that the interference field strength at the interface between the metal layer and the reflective film reaches a minimum value and achieve high peak reflectivity.
本发明在光通信、显示、摄影、光学信息处理等多个领域都有着很大的应用前景。The invention has great application prospects in many fields such as optical communication, display, photography, optical information processing and the like.
实施例1:薄膜窄带反射滤光片在光通信波分复用系统中的解复用应用Embodiment 1: Demultiplexing application of thin-film narrowband reflective filter in optical communication wavelength division multiplexing system
如图4所示,7-1、7-2、7-3、7-4代表四个中心波长不同的薄膜窄带反射滤光片,当λ1-λ4的波长入射时,四个滤光片将把对应其中心波长的光波分别反射回去,从而实现了四通道的解复用效果。As shown in Figure 4, 7-1, 7-2, 7-3, and 7-4 represent four thin-film narrow-band reflective filters with different center wavelengths. When the wavelength of λ 1 -λ 4 is incident, the four filters The chip will reflect the light waves corresponding to its center wavelength respectively, thus realizing the demultiplexing effect of four channels.
实施例2:薄膜窄带反射滤光片在彩色显示领域中的应用Example 2: Application of thin-film narrow-band reflective filter in the field of color display
如图5所示,8-1、8-2、8-3分别代表中心波长对应红、绿、蓝三原色的窄带反射滤光片,在宽光谱入射时,这些滤光片对三原色进行反射,既可以对三原色进行分离调制,也可以再次组合,实现需要的彩色显示。As shown in Figure 5, 8-1, 8-2, and 8-3 respectively represent narrow-band reflective filters whose central wavelengths correspond to the three primary colors of red, green, and blue. When a wide spectrum is incident, these filters reflect the three primary colors. The three primary colors can be separately modulated or combined again to achieve the required color display.
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| US10191320B2 (en) | 2013-04-16 | 2019-01-29 | Boe Technology Group Co., Ltd. | Filter sheet, manufacturing method thereof and display device |
| CN105627249A (en) * | 2015-12-31 | 2016-06-01 | 奥特路(漳州)光学科技有限公司 | Lampshade capable of filtering out blue light and conducting sterilizing and oil stain preventing and manufacturing method of lampshade |
| CN107037521A (en) * | 2017-06-22 | 2017-08-11 | 中国科学院长春光学精密机械与物理研究所 | A kind of 121.6nm arrowbands negative filter and preparation method thereof |
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