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CN1983543A - Print mask and method of manufacturing electronic components using the same - Google Patents

Print mask and method of manufacturing electronic components using the same Download PDF

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Publication number
CN1983543A
CN1983543A CNA2006101724580A CN200610172458A CN1983543A CN 1983543 A CN1983543 A CN 1983543A CN A2006101724580 A CNA2006101724580 A CN A2006101724580A CN 200610172458 A CN200610172458 A CN 200610172458A CN 1983543 A CN1983543 A CN 1983543A
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openings
printing
mask
barrier metal
opening
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CN100437960C (en
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下赤善男
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Kyocera Corp
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Kyocera Corp
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Abstract

一种印刷掩模及使用该掩模的电子零件的制造方法,该印刷掩模由多个开口部排列成一列或多列而成,用于透过开口部将印刷糊剂印刷、涂布在晶片上,从而在晶片上的阻挡金属层上形成凸起,其特征在于,开口部的排列密度根据排列区域而有所不同,设定为开口部的排列密度越大的排列区域,开口部的开口面积越小。A printing mask and a method for manufacturing an electronic component using the mask. The printing mask is formed by arranging a plurality of openings in one or more rows, and is used for printing and coating a printing paste on the surface through the openings. On the wafer, thereby forming protrusions on the barrier metal layer on the wafer, it is characterized in that the arrangement density of the openings is different according to the arrangement area, and the arrangement area with the larger arrangement density of the openings is set. The smaller the opening area.

Description

印刷掩模及使用该掩模的电子零件的制造方法Printing mask and method of manufacturing electronic parts using the same

本申请是基于申请号为200410033029.6、发明名称为“印刷掩模及使用该掩模的电子零件的制造方法”、申请日为2004年2月25日的专利申请的分案申请。This application is a divisional application based on the patent application No. 200410033029.6, the title of the invention is "Printing Mask and Method for Manufacturing Electronic Parts Using the Mask", and the filing date is February 25, 2004.

技术领域technical field

本发明涉及用于在晶片上印刷糊剂,从而在晶片上的阻挡金属层上形成凸起,即突起电极的印刷掩模(也称为丝网印刷用掩模)。本发明涉及用印刷掩模制造电子零件的方法,特别涉及通过倒装焊接法置于电路基板上的倒装片型集成电路的制造方法。The present invention relates to a printing mask (also referred to as a mask for screen printing) for printing a paste on a wafer to form bumps, ie bump electrodes, on a barrier metal layer on the wafer. The present invention relates to a method of manufacturing electronic parts using a printed mask, and more particularly to a method of manufacturing a flip-chip type integrated circuit placed on a circuit substrate by flip-chip bonding.

背景技术Background technique

〖特许文献1〗特开昭52-68366号公报Patent Document 1〗JP-A-52-68366

作为现有的集成电路的一种安装方法,倒装焊接法已众所周知。所谓该安装方法就是将集成电路置于带有电路配线的电路基板的上面,并使其电路形成面位于电路基板表面的对面,在此状态下完成集成电路与电路基板的电极之间的接合。Flip-chip bonding is known as a conventional mounting method for integrated circuits. The so-called mounting method is to place the integrated circuit on the circuit substrate with circuit wiring, and make the circuit formation surface opposite to the surface of the circuit substrate, and complete the bonding between the integrated circuit and the electrodes of the circuit substrate in this state. .

倒装焊接法中采用的集成电路称为倒装片型集成电路(倒装片型IC),一般通过焊锡及导电性粘结剂使其端子与电路基板上的电路配线连接。The integrated circuit used in the flip-chip bonding method is called a flip-chip integrated circuit (flip-chip IC), and its terminals are generally connected to circuit wiring on a circuit board by solder and a conductive adhesive.

众所周知,现有的倒装片型集成电路具有下述构造:形成覆盖在半导体晶片的一个主面上的由镍等制成的多个阻挡金属层,作为焊盘电极,在上述阻挡金属层之上选择性地形成焊锡凸起的电极。将其安装在电路基板上时,与电路基板上的对应的电路配线相对地将倒装片型集成电路的焊锡凸起定位在焊盘电极处,并将倒装片型集成电路搭载在电路基板上,此后,通过用高温加热,使焊锡凸起熔融,涂上焊锡,将倒装片型集成电路的阻挡金属层置于电路基板上的电路配线处。As is well known, conventional flip-chip integrated circuits have a structure in which a plurality of barrier metal layers made of nickel or the like are formed covering one main surface of a semiconductor wafer as pad electrodes, and between the barrier metal layers Electrodes on which solder bumps are selectively formed. When mounting it on a circuit board, position the solder bumps of the flip chip IC on the pad electrodes facing the corresponding circuit wiring on the circuit board, and mount the flip chip IC on the circuit board. On the substrate, thereafter, by heating at a high temperature, the solder bumps are melted, solder is coated, and the barrier metal layer of the flip-chip integrated circuit is placed on the circuit wiring on the circuit substrate.

这样的倒装片型集成电路通常由下述工艺制作而成(参照图4~图6)。即:Such a flip-chip integrated circuit is generally produced by the following process (see FIGS. 4 to 6 ). Right now:

(1)调制半导体晶片11,多个阻挡金属层13直线状地排列在半导体晶片的集成电路形成面之上,电路配线12覆盖住相邻阻挡金属层13之间的区域,用钝化层14覆盖该电路配线12。电路配线12具有向设在半导体晶片11上的半导体元件供给电源和电信号的供电配线的功能,通常,用铝等金属材料在与阻挡金属层13的排列方向相垂直的方向上形成布线图案。(1) Modulating the semiconductor wafer 11, a plurality of barrier metal layers 13 are linearly arranged on the integrated circuit formation surface of the semiconductor wafer, the circuit wiring 12 covers the area between the adjacent barrier metal layers 13, and the passivation layer 14 covers the circuit wiring 12 . The circuit wiring 12 has the function of supplying power and electrical signals to the semiconductor elements provided on the semiconductor wafer 11. Generally, the wiring is formed in a direction perpendicular to the arrangement direction of the barrier metal layer 13 with a metal material such as aluminum. pattern.

(2)调制印刷掩模16,印刷掩模形成具有多个与阻挡金属层13一一对应,且比该阻挡金属层的外径大的长圆形开口部17的印刷掩模16。(2) The printing mask 16 is prepared, and the printing mask 16 is formed to have a plurality of oblong openings 17 corresponding to the barrier metal layers 13 one by one and larger than the outer diameter of the barrier metal layers.

(3)此后,使印刷掩模16的开口部17位于阻挡金属层13上地将印刷掩模16设置在半导体晶片11之上。(3) Thereafter, the printing mask 16 is placed on the semiconductor wafer 11 so that the openings 17 of the printing mask 16 are located on the barrier metal layer 13 .

(4)接着,将焊锡糊剂15供给到印刷掩模16上,橡皮刮刀对印刷掩模16加压,同时使焊锡糊剂向所定方向移动,焊锡糊剂15通过开口部17,在阻挡金属层13上进行印刷。(4) Next, the solder paste 15 is supplied onto the print mask 16, the squeegee presses the print mask 16, and at the same time moves the solder paste in a predetermined direction. Print on layer 13.

(5)最后,通过加热半导体晶片,使涂布的焊锡糊剂15熔融,从而在阻挡金属层13上形成球状的焊锡凸起。将这样的半导体晶片11切割成所定形状,从而制成多个倒装片型集成电路。(5) Finally, the semiconductor wafer is heated to melt the applied solder paste 15 to form spherical solder bumps on the barrier metal layer 13 . Such a semiconductor wafer 11 is cut into a predetermined shape to produce a plurality of flip-chip integrated circuits.

而且,形成长圆形的开口部17在印刷掩模16中直线状排列,沿上述开口部17长度方向的边缘部与开口部17的排列方向垂直地设置。这是将印刷掩模16设在半导体晶片11上时,开口部17的上述边缘部相对相邻的阻挡金属层13之间的电路配线大致平行地设置所构成的形状(参照图4)。Further, the openings 17 formed in an oblong shape are arranged linearly in the printing mask 16 , and the edge portions along the longitudinal direction of the openings 17 are provided perpendicular to the arrangement direction of the openings 17 . When the printing mask 16 is placed on the semiconductor wafer 11, the edge portions of the openings 17 are arranged substantially parallel to the circuit wiring between the adjacent barrier metal layers 13 (see FIG. 4 ).

进而,公知的其它印刷用掩模,如图10所示,多个开口部17直线状地排列在由不锈钢等形成的掩模主体上,形成多个开口部列17a、17b、17c,用丝网印刷用掩模形成倒装片IC的焊锡凸起。本例中,分别构成3个开口部列17a、17b、17c的开口部17与半导体晶片上的阻挡金属层相对应地每个开口部列以所定密度排列,其开口面积与所有的开口部列17a、17b、17c大致相等。Furthermore, in other known printing masks, as shown in FIG. Masks are used for screen printing to form solder bumps for flip-chip ICs. In this example, the openings 17 constituting the three opening rows 17a, 17b, and 17c correspond to the barrier metal layers on the semiconductor wafer. Each opening row is arranged at a predetermined density, and its opening area is the same as that of all the opening rows. 17a, 17b, 17c are approximately equal.

由此,上述半导体晶片11上,由于设在相邻的阻挡金属层13之间的电路配线12具有所定厚度(例如,0.5μm~1.5μm),因此,在覆盖电路配线12的钝化层14的表面上形成突出部14a及阶部,该突出部14a突出形成与电路配线12的厚度外形适应的形状。当在具有该突出部14a的半导体晶片11上设置前述印刷掩模16时,在处于钝化层14的突出部14a的基部的角部,常常有沿开口部17的长度方向的边缘部。在此状态下,如果按压印刷掩模16,对半导体晶片11加压,开口部17的边缘部进入上述角部中,会损伤钝化层14的表面(参照图5、图6)。由此,钝化层14的密封性恶化,有可能大气中的水分等会腐蚀电路配线12。当沿开口部17长度方向的边缘部形成直线状时,这个问题十分显著。Thus, on the above-mentioned semiconductor wafer 11, since the circuit wiring 12 provided between the adjacent barrier metal layers 13 has a predetermined thickness (for example, 0.5 μm to 1.5 μm), the passivation covering the circuit wiring 12 On the surface of the layer 14, a protruding portion 14a and a step portion are formed, and the protruding portion 14a is protruded into a shape conforming to the thickness profile of the circuit wiring 12. As shown in FIG. When the aforementioned printing mask 16 is provided on the semiconductor wafer 11 having the protruding portion 14 a , at the corner portion at the base of the protruding portion 14 a of the passivation layer 14 , there is always an edge portion along the length direction of the opening 17 . In this state, if the printing mask 16 is pressed to apply pressure to the semiconductor wafer 11, the edge of the opening 17 enters the corner and damages the surface of the passivation layer 14 (see FIGS. 5 and 6 ). As a result, the sealing performance of the passivation layer 14 deteriorates, and there is a possibility that moisture in the atmosphere may corrode the circuit wiring 12 . This problem is conspicuous when the edge portion along the longitudinal direction of the opening portion 17 is formed in a linear shape.

而且,采用如图10所示构成的印刷用掩模,当用橡皮刮刀使置于掩模上的焊锡糊剂移动一定距离时,与比开口部列17a的排列密度小的开口部列17b及17c附近的焊锡糊剂相比,开口部17的排列密度大的开口部列17a附近的掩模上的焊锡糊剂流到阻挡金属层上的次数更多。上述糊剂的流出导致掩模上的焊锡糊剂剧烈旋转、流动,其结果产生开口部列17a附近的焊锡糊剂的粘性比其它开口部列附近的焊锡糊剂的粘性小的倾向。10, when the solder paste placed on the mask is moved by a certain distance with a squeegee, the opening row 17b and the opening row 17b having a smaller arrangement density than the opening row 17a The number of times the solder paste on the mask near the opening row 17 a where the arrangement density of the openings 17 is high flows onto the barrier metal layer is higher than the solder paste near 17 c. The outflow of the paste causes the solder paste on the mask to swirl and flow vigorously, and as a result, the viscosity of the solder paste near the opening row 17a tends to be lower than that of the solder paste near the other opening row.

因此,涂布在阻挡金属层上的焊锡糊剂的量是开口部列17a比开口部列17b、17c多,存在焊锡凸起的大小不一的缺点。如果焊锡凸起的大小不一,将倒装片IC安装在其它电路基板上时,会产生倒装片IC倾斜,倒装片IC相对于电路基板的安装强度低下的问题。Therefore, the amount of solder paste coated on the barrier metal layer is more in the opening row 17a than in the opening row 17b, 17c, and there is a disadvantage that the size of the solder bumps varies. If the size of the solder bumps is different, when the flip chip IC is mounted on another circuit board, the flip chip IC will be tilted and the mounting strength of the flip chip IC to the circuit board will be lowered.

发明内容Contents of the invention

本发明的目的在于提供一种印刷掩模,该掩模可有效地防止糊剂在印刷时损伤钝化层的表面。并提供一种倒装片型集成电路的制造方法,该方法采用印刷掩模不会划伤钝化层的表面。The object of the present invention is to provide a printing mask, which can effectively prevent the paste from damaging the surface of the passivation layer during printing. It also provides a method for manufacturing flip-chip integrated circuits, which does not scratch the surface of the passivation layer by using a printing mask.

本发明的另一个目的在于提供一种可形成大致均匀大小的凸起的高品质印刷掩模,及采用该掩模的电子零件的制造方法。Another object of the present invention is to provide a high-quality printing mask capable of forming bumps of approximately uniform size, and a method of manufacturing electronic components using the mask.

本发明的形态中,印刷掩模由形成长孔状的多个开口部排列而成,用于透过该开口部将糊剂涂布在被印刷物上,沿开口部的长度方向的边缘部相对于与开口部的排列方向相垂直的方向是倾斜的。In the aspect of the present invention, the printing mask is formed by arranging a plurality of openings forming a long hole shape, and is used to apply the paste on the object to be printed through the openings, and the edges along the longitudinal direction of the openings are opposite to each other. It is inclined in a direction perpendicular to the direction in which the openings are arranged.

关于开口部的倾斜角度,最好,沿开口部的长度方向的边缘部相对于与开口部的排列方向相垂直的方向倾斜5°~45°。Regarding the inclination angle of the openings, it is preferable that the edge portions along the longitudinal direction of the openings are inclined by 5° to 45° relative to the direction perpendicular to the arrangement direction of the openings.

而且,本发明的印刷掩模的沿开口部的长度方向的边缘部最好成直线状。特别是,可使用多个开口部排列成直线状的印刷掩模。这样的印刷掩模在集成电路制造领域,在倒装片型集成电路的制造方法中可广泛利用。Moreover, it is preferable that the edge part along the longitudinal direction of an opening part of the printing mask of this invention is linear. In particular, a printing mask in which a plurality of openings are arranged in a straight line can be used. Such a printing mask is widely used in the field of integrated circuit manufacturing and in the manufacturing method of flip-chip integrated circuits.

倒装片型集成电路的制造方法包含下述工艺:调整半导体晶片,使起到凸起电极作用的多个阻挡金属层排列在晶片的上面,将电路配线覆盖在相邻的阻挡金属层之间,并用钝化层覆盖该电路配线,从而形成该半导体晶片。调制带有多个与上述阻挡金属层相对应的长孔状的开口部的印刷掩模。接着,将印刷掩模的开口部设置在阻挡金属层上,使得沿其长度方向的边缘部相对于覆盖在相邻的阻挡金属层之间的电路配线是倾斜的。印刷掩模与晶片接触也可以,处于不接触状态也可以。接着,将供给到印刷掩模上的糊剂通过开口部,印刷在阻挡金属层上,然后对阻挡金属层上涂布的糊剂进行加热处理,形成凸起。A method of manufacturing a flip-chip integrated circuit includes the following processes: adjusting a semiconductor wafer so that a plurality of barrier metal layers functioning as bump electrodes are arranged on the wafer, and covering circuit wiring between adjacent barrier metal layers space, and cover the circuit wiring with a passivation layer, thereby forming the semiconductor wafer. A printing mask having a plurality of long-hole-shaped openings corresponding to the barrier metal layer was prepared. Next, the opening portion of the printing mask is provided on the barrier metal layer such that the edge portion in the length direction thereof is inclined with respect to the circuit wiring covering between adjacent barrier metal layers. The printing mask may be in contact with the wafer or may be in a non-contact state. Next, the paste supplied to the printing mask is passed through the openings to be printed on the barrier metal layer, and the paste coated on the barrier metal layer is then heat-treated to form protrusions.

采用本发明,形成长孔状的多个开口部排列而成的印刷掩膜中,由于沿开口部的长度方向的边缘部倾斜于与开口部的排列方向相垂直的方向,因此,将印刷掩膜设置在带有与开口部相对应的阻挡金属层的半导体晶片上时,沿开口部的长度方向的边缘部相对于相邻的阻挡金属层之间的电路配线是倾斜的。According to the present invention, in the printing mask formed by arranging a plurality of long-hole-shaped openings, since the edges along the longitudinal direction of the openings are inclined in the direction perpendicular to the direction in which the openings are arranged, the printing mask When the film is provided on a semiconductor wafer with a barrier metal layer corresponding to the opening, the edge portion along the longitudinal direction of the opening is inclined with respect to the circuit wiring between the adjacent barrier metal layers.

因而,进行糊剂的印刷时,即使相对于半导体晶片压紧印刷掩膜,印刷掩膜的开口部的边缘部伸入适应电路配线的形状而形成的钝化层的突出部的基部处的角部中,从而可有效地防止对钝化层的表面造成大的损伤。因而,可良好地维持钝化层的密封性,可解决电路配线的腐蚀等问题。Therefore, when printing the paste, even if the printing mask is pressed against the semiconductor wafer, the edges of the openings of the printing mask protrude into the bases of the protrusions of the passivation layer formed in accordance with the shape of the circuit wiring. In the corners, it is possible to effectively prevent large damage to the surface of the passivation layer. Therefore, the sealing property of a passivation layer can be maintained favorably, and problems, such as corrosion of a circuit wiring, can be solved.

当沿开口部的长度方向的边缘部成直线状时,本发明特别有效。The present invention is particularly effective when the edge portion along the longitudinal direction of the opening is linear.

本发明的其它形态中的印刷掩模由多个开口部排列成一列或多列而成,用于透过开口部将印刷糊剂印刷、涂布在晶片上,从而在晶片上的阻挡金属层上形成凸起,开口部的排列密度根据排列区域而有所不同,设定为开口部的排列密度越大的排列区域,开口部的开口面积越小。The printing mask in other forms of the present invention is formed by arranging a plurality of openings in one or more rows, and is used to print and coat the printing paste on the wafer through the openings, so that the barrier metal layer on the wafer Protrusions are formed on the top, and the arrangement density of the openings differs depending on the arrangement area, and the arrangement area with the higher the arrangement density of the openings is set to have a smaller opening area of the openings.

最好,开口部排列成多列,且对每列设定开口部的排列密度。而且,开口部排列的多列最好相互大致平行。Preferably, the openings are arranged in a plurality of rows, and the arrangement density of the openings is set for each row. Furthermore, it is preferable that the plurality of rows in which the openings are arranged are substantially parallel to each other.

本发明其它形态的电子零件的制造方法包含下述工艺:将印刷糊剂放置在上述丝网印刷用掩模上,使该印刷糊剂沿开口部排列的方向移动,通过开口部将印刷糊剂印刷、涂布在位于前述开口部之下的阻挡金属层上,从而在阻挡金属层上形成凸起。The manufacturing method of the electronic part of another aspect of this invention comprises the following process: The printing paste is placed on the said mask for screen printing, this printing paste is moved along the direction in which openings are arranged, and the printing paste is sprayed through the openings. printing and coating on the barrier metal layer located under the aforementioned openings, thereby forming protrusions on the barrier metal layer.

采用本发明,由于设定了该开口部的排列密度越大的排列区域,设在丝网印刷用掩模上的开口部的开口面积越小,因此,放置在印刷用掩模上的印刷糊剂中,即使开口部的排列密度大的区域附近的印刷糊剂的粘性较小,涂布在阻挡金属层上的印刷糊剂的量也可以大致均匀地形成在所有的开口部处,使形成在电子零件装置的阻挡金属层上的凸起的大小一致,从而提供具有高装配性能的电子零件,特别是倒装片型集成电路。Adopt the present invention, owing to setting the arrangement area that the arrangement density of this opening part is bigger, the opening area of the opening part that is arranged on the mask for screen printing is smaller, therefore, the printing paste that is placed on the mask for printing In the agent, even if the viscosity of the printing paste near the area where the arrangement density of the openings is high is low, the amount of the printing paste coated on the barrier metal layer can be formed approximately uniformly at all the openings, so that the formed The size of the bumps on the barrier metal layer of the electronic part device is uniform, thereby providing electronic parts with high assembly performance, especially flip-chip type integrated circuits.

附图说明Description of drawings

图1示出了本发明一个实施形态的印刷掩模的平面图。FIG. 1 shows a plan view of a printing mask according to one embodiment of the present invention.

图2示出了按照本发明一个实施形态的倒装片型集成电路的制造方法制作的倒装片型集成电路的截面图。FIG. 2 shows a cross-sectional view of a flip-chip integrated circuit manufactured according to a method for manufacturing a flip-chip integrated circuit according to an embodiment of the present invention.

图3是表示制造图2的倒装片型集成电路时,将印刷掩模设置在半导体晶片上时二者的位置关系的平面图。FIG. 3 is a plan view showing the positional relationship between the print mask and the semiconductor wafer when the flip-chip integrated circuit of FIG. 2 is manufactured.

图4是表示制造现有的倒装片型集成电路时,将印刷掩模设置在半导体晶片上时二者的位置关系的平面图。4 is a plan view showing the positional relationship between a print mask and a semiconductor wafer when a conventional flip-chip integrated circuit is manufactured.

图5是表示形成现有的倒装片型集成电路的焊锡糊剂的印刷工艺的图。FIG. 5 is a diagram showing a printing process of solder paste for forming a conventional flip-chip integrated circuit.

图6是表示形成现有的倒装片型集成电路的焊锡糊剂的印刷工艺的图。FIG. 6 is a diagram showing a printing process of solder paste for forming a conventional flip-chip integrated circuit.

图7是表示第2实施形态的印刷掩模的图。Fig. 7 is a diagram showing a printing mask according to a second embodiment.

图8A~C是表示使用图7的印刷掩模形成电子零件的焊锡凸起的方法的图。8A to C are diagrams showing a method of forming solder bumps of electronic components using the printing mask of FIG. 7 .

图9是表示改变一个开口部的排列密度的印刷掩模的图。FIG. 9 is a diagram showing a printing mask in which the arrangement density of one opening is changed.

图10是表示以前的印刷掩模的图。FIG. 10 is a diagram showing a conventional printing mask.

具体实施方式Detailed ways

印刷掩模的说明Description of printing mask

如图1所示,本发明的第一实施形态的印刷掩模6在平板状的掩模主体8上排列有多个开口部7。掩模主体8由金属材料、树脂材料、或组合这些材料的薄层形成,通常外形呈矩形。As shown in FIG. 1 , in the print mask 6 according to the first embodiment of the present invention, a plurality of openings 7 are arranged in a flat mask main body 8 . The mask main body 8 is formed of a metal material, a resin material, or a thin layer combining these materials, and generally has a rectangular shape.

作为构成掩模主体8的金属材料包含铝合金、不锈钢、Ni合金、Cr合金等。掩模用的树脂材料包含聚酰亚胺、聚酯、环氧树脂、聚碳酸酯、聚乙烯、聚对苯二甲酸乙二醇酯(PET)、聚丙稀等。Metal materials constituting the mask main body 8 include aluminum alloys, stainless steel, Ni alloys, Cr alloys, and the like. The resin material for the mask includes polyimide, polyester, epoxy, polycarbonate, polyethylene, polyethylene terephthalate (PET), polypropylene, and the like.

掩模主体8在由上述材料制成的薄板上形成。薄板的厚度最好在20μm~80μm。The mask main body 8 is formed on a thin plate made of the above-mentioned material. The thickness of the thin plate is preferably 20 μm to 80 μm.

掩模主体的其它例子也可以是复合材料的掩模,可以是例如,由带有多个网目的线网、和涂布在网格上的绝缘性乳剂的硬化物制成,由上述材料制成印刷用掩模。Other examples of mask bodies can also be masks of composite materials, which can be, for example, made of a wire mesh with a plurality of meshes, and a hardened object of an insulating emulsion coated on the mesh, made of the above-mentioned materials. into a printing mask.

在掩模主体的金属薄板或网上,多个开口部7设成所定的图样。在掩模主体8上开设的多个开口部7相对于掩模主体8,以例如100~300dpi(点每英寸)的密度直线状排列,其排列被设定为1列或2列以上。A plurality of openings 7 are provided in a predetermined pattern on the thin metal plate or mesh of the mask main body. A plurality of openings 7 opened in the mask main body 8 are linearly arranged at a density of, for example, 100 to 300 dpi (dots per inch) with respect to the mask main body 8 , and the arrangement is set to one row or two or more rows.

上述开口部7分别具有包含长圆形、长方形、平行四边形等的长孔形状,沿长度方向的边缘部71形成直线状。The openings 7 each have a long hole shape including an oblong shape, a rectangle, a parallelogram, and the like, and the edge portion 71 along the longitudinal direction is formed in a straight line.

开口部7是贯穿掩模主体8的厚度方向的通孔,这是为了印刷时,使放置在掩模主体8上的焊锡糊剂和银环氧化化合物等导电糊剂通过其孔内。The opening 7 is a through hole penetrating the thickness direction of the mask main body 8 for allowing conductive paste such as solder paste and silver epoxide placed on the mask main body 8 to pass through the hole during printing.

采用前述网的掩模主体8利用没有涂布乳剂的区域作为开口部7。The mask main body 8 employing the aforementioned mesh utilizes regions not coated with emulsion as openings 7 .

为了相对于被印刷物良好地涂布糊剂,上述开口部7内周的表面粗糙度最好将其算术平均粗糙度Ra设定在1.0μm以下,如果开口部7内周的表面粗糙度Ra大于1.0μm,当开口部7的面积在10000μm2以下而特别小时,糊剂难以被良好地转印到被印刷物上。开口部7内周的表面粗糙度的下限值最好在算术平均粗糙度Ra为0.05μm,如果开口部7的表面粗糙度小于0.05μm,则会导致印刷掩模6的生产性低下。In order to apply the paste well to the printed matter, the surface roughness of the inner periphery of the opening 7 is preferably set to an arithmetic mean roughness Ra of 1.0 μm or less. If the surface roughness Ra of the inner periphery of the opening 7 is greater than When the area of the opening 7 is 1.0 μm or less than 10000 μm 2 , it is difficult to transfer the paste well to the printed matter. The lower limit of the surface roughness of the inner periphery of the opening 7 is preferably 0.05 μm in arithmetic mean roughness Ra. If the surface roughness of the opening 7 is less than 0.05 μm, the productivity of the printing mask 6 will decrease.

作为开口部7的大小,一个例子是长80μm~150μm,宽60μm~100μm,但是通常,最好比被印刷物中涂布糊剂的区域(例如阻挡金属层)宽。The size of the opening 7 is, for example, 80 μm to 150 μm in length and 60 μm to 100 μm in width, but generally, it is preferably wider than the area to be printed with the paste (for example, the barrier metal layer).

印刷掩模6例如由Ni合金制成时,现有公知的添加法,即,首先将感光性树脂涂布成薄板状,同时采用现有公知的光刻技术,对该涂布的感光性树脂进行形成布线图案的处理,除去与开口部7相对应的区域以外的树脂,此后采用现有公知的电镀或无电解电镀法,在除去感光性树脂的区域上镀镍,最后通过除去感光性树脂形成印刷掩模6。When the printing mask 6 is made of Ni alloy, for example, there is a known additive method, that is, at first the photosensitive resin is coated into a thin plate shape, and at the same time, the photosensitive resin coated is coated with a photolithographic technique. Carry out the processing of forming the wiring pattern, remove the resin other than the area corresponding to the opening 7, and then adopt the known electroplating or electroless plating method to plate nickel on the area where the photosensitive resin is removed, and finally remove the photosensitive resin A printing mask 6 is formed.

而且,印刷掩模6也可以由聚酰亚胺树脂制成,此时,例如用丝网印刷法将聚酰亚胺树脂的前体涂布成层状后,对其进行烧制,此后采用现有公知的激光加工法形成与开口部7相对应的孔。Moreover, the printing mask 6 can also be made of polyimide resin. At this time, for example, after the precursor of the polyimide resin is coated into a layer by the screen printing method, it is fired, and thereafter Holes corresponding to openings 7 are formed by a conventionally known laser processing method.

不用说,也可以利用其它制造方法形成印刷掩模6,但是如果用添加法形成印刷掩模6,由于形成开口部7的面积在10000μm2以下的细微图样时,制造印刷掩模6也是很容易的,因此用添加法形成印刷掩模6,最好掩模主体由Ni合金或Cr合金等形成。Needless to say, other manufacturing methods can also be used to form the printing mask 6, but if the printing mask 6 is formed by an additive method, it is also easy to manufacture the printing mask 6 due to the formation of a fine pattern with an area of the opening 7 below 10000 μm Therefore, the printing mask 6 is formed by an additive method, and it is preferable that the main body of the mask is formed of Ni alloy or Cr alloy or the like.

倒装片型集成电路flip chip integrated circuit

下面说明用上述印刷掩模6形成凸起的倒装片型集成电路。图2所示的倒装片型集成电路大致在半导体晶片1上设有电路配线2、阻挡金属层3、钝化层4、凸起5等。Next, a flip-chip type integrated circuit in which bumps are formed using the above-mentioned printing mask 6 will be described. In the flip-chip integrated circuit shown in FIG. 2 , circuit wiring 2 , barrier metal layer 3 , passivation layer 4 , bumps 5 , and the like are generally provided on semiconductor wafer 1 .

半导体晶片1由单结晶硅等的半导体材料制成,其上面覆盖有半导体元件(图中未示出)、电路配线2、阻挡金属层3、钝化层4等,半导体晶片1起到支撑它们的支撑基材的功能。The semiconductor wafer 1 is made of semiconductor materials such as single crystal silicon, and is covered with semiconductor elements (not shown in the figure), circuit wiring 2, barrier metal layer 3, passivation layer 4, etc., and the semiconductor wafer 1 plays a supporting role. Their supporting substrate function.

上述半导体晶片1将通过例如现有公知的佐科拉尔斯基法(拉晶法)等形成的单结晶硅的结晶块切割成所定厚度,得到薄片,同时对其表面进行研磨,此后通过现有公知的热氧化法在薄片的整个表面上形成绝缘膜,从而制成上述半导体晶片1。The above-mentioned semiconductor wafer 1 cuts an ingot of single-crystal silicon formed by, for example, the conventionally known Zokorarski method (crystal pulling method) to a predetermined thickness to obtain thin slices, and at the same time polishes the surface thereof. There is a known thermal oxidation method to form an insulating film on the entire surface of the wafer, thereby producing the above-mentioned semiconductor wafer 1 .

形成在半导体晶片1上的电路配线2是由铝(Al)或铜(Cu)等金属材料覆盖成0.5μm~1.5μm的厚度,起到将来自外部的电源电力和电信号等供给图中未示出的半导体元件的供电配线的作用。电路配线2利用现有公知的阴极溅镀、光刻、腐蚀,在半导体晶片1的上面形成所定图样。The circuit wiring 2 formed on the semiconductor wafer 1 is covered with a metal material such as aluminum (Al) or copper (Cu) to a thickness of 0.5 μm to 1.5 μm, and serves to supply power and electrical signals from the outside The role of power supply wiring for semiconductor elements not shown. The circuit wiring 2 is formed in a predetermined pattern on the upper surface of the semiconductor wafer 1 by conventionally known sputtering, photolithography, and etching.

多个阻挡金属层3沿半导体晶片1的端部直线状排列地形成在电路配线2的一部分上面。电路配线2的一部分与阻挡金属层3的排列方向垂直地位于相邻的阻挡金属层之间的区域中。A plurality of barrier metal layers 3 are formed on a part of the circuit wiring 2 in a linear arrangement along the end of the semiconductor wafer 1 . A part of the circuit wiring 2 is located in a region between adjacent barrier metal layers perpendicular to the arrangement direction of the barrier metal layers 3 .

而且,倒装片型集成电路搭载在电路基板上时,阻挡金属层3可有效地防止随着设在阻挡金属层3上的凸起5的熔融,形成电路配线2的铝等发生侵蚀。阻挡金属层3形成金属材料的多层结构,其最上层使用对构成凸起5的材料浸润性好的材料。Furthermore, when the flip-chip integrated circuit is mounted on the circuit board, the barrier metal layer 3 can effectively prevent the corrosion of the aluminum or the like forming the circuit wiring 2 due to the melting of the bumps 5 provided on the barrier metal layer 3 . The barrier metal layer 3 forms a multilayer structure of metal materials, and the uppermost layer uses a material with good wettability to the material constituting the protrusion 5 .

这样的多层构造可以是例如从半导体晶片1侧开始,依次叠置锌(Zn)、镍(Ni)及金(Au)的3层结构。其它构造可以是锌(Zn)、镍(Ni)的2层构造,或者钯(Pd)、镍(Ni)、金(Au)的3层构造,钯(Pd)、镍(Ni)的2层构造。Such a multilayer structure may be, for example, a three-layer structure in which zinc (Zn), nickel (Ni), and gold (Au) are stacked in order from the semiconductor wafer 1 side. Other structures can be a 2-layer structure of zinc (Zn) and nickel (Ni), or a 3-layer structure of palladium (Pd), nickel (Ni), and gold (Au), and a 2-layer structure of palladium (Pd) and nickel (Ni) structure.

另一方面,由氮化硅(Si3N4)和氧化硅(SiO2)、聚酰亚胺等电绝缘材料制成的钝化层4覆盖住电路配线2和图中未示出的半导体元件地铺设在晶片1上的没有形成阻挡金属层3的区域中。On the other hand, the passivation layer 4 made of electrical insulating materials such as silicon nitride (Si 3 N 4 ), silicon oxide (SiO 2 ), polyimide, etc. covers the circuit wiring 2 and the not shown in the figure. The semiconductor elements are laid down on the wafer 1 in regions where the barrier metal layer 3 is not formed.

在晶片上形成钝化层4后,在没有形成钝化层4的电路配线2的一部分上面形成阻挡金属层3。锌(Zn)、镍(Ni)及金(Au)3层结构时,采用现有公知的无电解电镀法等,在电路配线2的一部分上面依次叠积锌(Zn),然后是镍(Ni),再是金(Au),形成圆柱状。After the passivation layer 4 is formed on the wafer, the barrier metal layer 3 is formed on a part of the circuit wiring 2 where the passivation layer 4 is not formed. In the case of a three-layer structure of zinc (Zn), nickel (Ni) and gold (Au), zinc (Zn) and then nickel ( Ni), then gold (Au), forming a cylindrical shape.

由于钝化层4可使半导体元件、电路配线2与空气良好地隔绝,因此可有效地防止半导体元件、电路配线2由于接触水分等而被腐蚀。Since the passivation layer 4 can well isolate the semiconductor element and the circuit wiring 2 from air, it can effectively prevent the semiconductor element and the circuit wiring 2 from being corroded due to contact with moisture or the like.

而且,钝化层4上形成有与阻挡金属层3之间的电路配线2的厚度和外形相适应地向上方突出的突出部4a,该突出部4a具有沿电路配线2的形状。Furthermore, on the passivation layer 4 , a protruding portion 4 a protruding upward in conformity with the thickness and shape of the circuit wiring 2 between the barrier metal layers 3 is formed. The protruding portion 4 a has a shape along the circuit wiring 2 .

钝化层4采用现有的阴极溅镀、光刻技术、腐蚀技术等,在半导体晶片1的上面形成0.5μm~3.0μm的厚度。The passivation layer 4 is formed on the upper surface of the semiconductor wafer 1 with a thickness of 0.5 μm to 3.0 μm by adopting existing cathode sputtering, photolithography technology, corrosion technology and the like.

然后,在前述阻挡金属层3的上面形成球状的凸起5。Then, spherical bumps 5 are formed on the barrier metal layer 3 .

凸起5,在将倒装片型集成电路安装在电路基板上时,通过加热熔融,以电·机械地连接倒装片型集成电路的阻挡金属层3与电路基板上的电路配线,例如,利用使锡(Sn)、银(Ag)、铜(Cu)以96.5∶3.0∶0.5的比例熔融、固化的焊锡或银环氧化化合物等导电材料形成。The bumps 5 are heated and melted when the flip-chip integrated circuit is mounted on the circuit board to electrically and mechanically connect the barrier metal layer 3 of the flip-chip integrated circuit with the circuit wiring on the circuit board, for example , Utilize tin (Sn), silver (Ag), copper (Cu) in the ratio of 96.5:3.0:0.5 to melt, solidify solder or silver epoxy compounds and other conductive materials.

倒装片型集成电路的制造方法的说明Explanation of manufacturing method of flip-chip integrated circuit

下面说明制造上述倒装片型集成电路的方法。Next, a method of manufacturing the above-mentioned flip-chip type integrated circuit will be described.

(1)首先,制备上面覆盖有电路配线2、阻挡金属层3、钝化层4的半导体晶片1、印刷掩膜6、糊剂。(1) First, the semiconductor wafer 1 on which the circuit wiring 2, the barrier metal layer 3, and the passivation layer 4 are covered, the printing mask 6, and the paste are prepared.

作为糊剂,可适当地采用在多个焊锡颗粒中添加、混合焊剂等,并调整为所定粘度的焊锡糊剂或银环氧化化合物等的导电糊剂。As the paste, a solder paste in which a flux or the like is added and mixed to a plurality of solder particles and adjusted to a predetermined viscosity, or a conductive paste such as a silver epoxide compound can be suitably used.

(2)接着,在半导体晶片1上设置印刷掩膜6。(2) Next, the printing mask 6 is provided on the semiconductor wafer 1 .

此时,设置印刷掩膜6,使其开口部7位于半导体晶片1上的对应的阻挡金属层3的正上方,但是如前所述,为了使沿开口部7的长度方向的边缘部倾斜于与开口部7的排列方向相垂直的方向,可使开口部7的边缘部相对于相邻的阻挡金属层3之间的电路配线2倾斜(参照图3)。从而,开口部7的边缘部相对于钝化层表面的突出部4a倾斜,突出部4a的表面支撑开口部7的边缘部的一部分。At this time, the printing mask 6 is set so that the opening 7 is located directly above the corresponding barrier metal layer 3 on the semiconductor wafer 1, but as described above, in order to make the edge of the opening 7 in the In a direction perpendicular to the arrangement direction of the openings 7 , the edges of the openings 7 can be inclined with respect to the circuit wiring 2 between adjacent barrier metal layers 3 (see FIG. 3 ). Thus, the edge portion of the opening 7 is inclined with respect to the protruding portion 4 a on the surface of the passivation layer, and the surface of the protruding portion 4 a supports a part of the edge portion of the opening 7 .

(3)然后,向印刷掩膜6上供给糊剂,同时在橡皮刮刀等加压部件(在本实施形态中是橡皮刮刀)对印刷掩膜6施压的状态下,使加压部件移动,糊剂通过开口部7涂布在阻挡金属层3上。(3) Then, while supplying the paste onto the printing mask 6, while pressing the printing mask 6 with a pressing member such as a squeegee (a squeegee in this embodiment), the pressing member is moved, The paste is applied on the barrier metal layer 3 through the opening 7 .

此时,印刷掩膜6被橡皮刮刀等加压部件相对于半导体晶片1紧紧地压住,如前所述,由于沿开口部7的长度方向的边缘部相对于电路配线2倾斜,开口部7的边缘部71被突出部4a的表面部分地支撑,开口部7的边缘部71的大部分伸入钝化层4的突出部4a附近的角部(突出部4a的侧面与钝化层4的平坦部之间的角部)中,从而可有效防止对钝化层4的表面造成大的损伤的问题。因此,可良好地维持钝化层4的密封性,可解决电路配线2的腐蚀等问题。At this time, the printing mask 6 is tightly pressed against the semiconductor wafer 1 by a pressing member such as a squeegee. The edge portion 71 of the portion 7 is partially supported by the surface of the protruding portion 4a, and most of the edge portion 71 of the opening portion 7 protrudes into the corner near the protruding portion 4a of the passivation layer 4 (the side surface of the protruding portion 4a and the passivation layer In the corner between the flat parts of 4), the problem of large damage to the surface of the passivation layer 4 can be effectively prevented. Therefore, the sealing property of the passivation layer 4 can be maintained favorably, and problems, such as corrosion of the circuit wiring 2, can be solved.

此处,沿开口部7的长度方向的边缘部71相对电路配线2的倾斜角α最好设定在5°~45°的范围内,倾斜角α如果小于5°,由于开口部7的边缘部71受到钝化层4的突出部4a的表面支撑的区域减小,因此相对于半导体晶片1特别压紧印刷掩膜6时,会损伤钝化层4的表面。另一方面,如果倾斜角α大于45°,涂布的糊剂与相邻糊剂之间容易接触到,则难以高密度地排列开口部7。因此,开口部7的边缘部71相对于也路配线2的倾斜角α最好设定在5°~45°的范围内,从开口部7高密度排列的观点出发,倾斜角α最好设定在30°以下。Here, the inclination angle α of the edge portion 71 relative to the circuit wiring 2 along the longitudinal direction of the opening 7 is preferably set in the range of 5° to 45°. If the inclination angle α is less than 5°, due to the The area where the edge portion 71 is supported by the surface of the protruding portion 4 a of the passivation layer 4 is reduced, so that when the printing mask 6 is particularly pressed against the semiconductor wafer 1 , the surface of the passivation layer 4 is damaged. On the other hand, if the inclination angle α is greater than 45°, the applied paste is easily contacted with the adjacent paste, and it is difficult to arrange the openings 7 at a high density. Therefore, the inclination angle α of the edge portion 71 of the opening 7 with respect to the wiring 2 is preferably set in the range of 5° to 45°. Set below 30°.

而且,使开口部7的边缘部71相对于电路配线2倾斜,用最低的2个突出部4a支撑沿开口部7的长度方向的一对边缘部71中的至少一个,这样更有助于防止损伤钝化层4,最好,使开口部7的边缘部71相对于电路配线倾斜,用至少2个突出部4a支撑沿开口部7的长度方向的一对边缘部71中的每个边缘部。Moreover, it is more helpful to make the edge portion 71 of the opening portion 7 inclined relative to the circuit wiring 2, and to support at least one of the pair of edge portions 71 along the length direction of the opening portion 7 with the lowest two protruding portions 4a. In the passivation layer 4 for preventing damage, preferably, the edge portion 71 of the opening portion 7 is inclined relative to the circuit wiring, and each of the pair of edge portions 71 along the length direction of the opening portion 7 is supported by at least two protruding portions 4a. edge.

(4)此后,使涂布在阻挡金属层3上的糊剂干燥,最后使其熔融,使糊剂中的颗粒加热、熔融,颗粒之间相互结合,再使其冷却,从而在阻挡金属层3上形成大小大致均匀的球状凸起5。(4) Thereafter, the paste coated on the barrier metal layer 3 is dried, and finally melted, the particles in the paste are heated and melted, and the particles are combined with each other, and then cooled, so that the barrier metal layer Spherical projections 5 with roughly uniform sizes are formed on the 3 .

采用本发明,形成长孔状的多个开口部排列而成的印刷掩膜中,由于沿开口部的长度方向的边缘部倾斜于与开口部的排列方向相垂直的方向,因此,将印刷掩膜设置在带有与开口部相对应的阻挡金属层的半导体晶片上时,沿开口部的长度方向的边缘部相对于相邻的阻挡金属层之间的电路配线是倾斜的。因而,进行糊剂的印刷时,即使在半导体晶片上压紧印刷掩膜,印刷掩膜的开口部的边缘部伸入适应电路配线的形状而形成的钝化层的突出部的基部处的角部中,从而可有效地防止对钝化层的表面造成大的损伤。因而,可良好地维持钝化层的密封性,可解决电路配线的腐蚀等问题。According to the present invention, in the printing mask formed by arranging a plurality of long-hole-shaped openings, since the edges along the longitudinal direction of the openings are inclined in the direction perpendicular to the direction in which the openings are arranged, the printing mask When the film is provided on a semiconductor wafer with a barrier metal layer corresponding to the opening, the edge portion along the longitudinal direction of the opening is inclined with respect to the circuit wiring between the adjacent barrier metal layers. Therefore, when printing the paste, even if the printing mask is pressed against the semiconductor wafer, the edge of the opening of the printing mask protrudes into the base of the protrusion of the passivation layer formed in accordance with the shape of the circuit wiring. In the corners, it is possible to effectively prevent large damage to the surface of the passivation layer. Therefore, the sealing property of a passivation layer can be maintained favorably, and problems, such as corrosion of a circuit wiring, can be solved.

在第二实施形态中,如图7所示,印刷掩膜6可以由上述金属材料,例如铝钢、不锈钢或者Ni合金等,也可以由合成树脂形成薄板状。其厚度形成20μm~80μm,多个开口部7以所定的图样设置在金属薄板(掩膜主体)8上。In the second embodiment, as shown in FIG. 7, the printing mask 6 may be made of the above-mentioned metal material, such as aluminum steel, stainless steel, or Ni alloy, or may be formed into a thin plate shape from a synthetic resin. The thickness thereof is 20 μm to 80 μm, and a plurality of openings 7 are provided in a thin metal plate (mask main body) 8 in a predetermined pattern.

以下的实施例中,在丝网印刷时,印刷掩膜6的金属薄板8用于支撑放置在其上面的焊锡糊剂50等印刷糊剂。In the following embodiments, during screen printing, the thin metal plate 8 of the printing mask 6 is used to support printing paste such as solder paste 50 placed thereon.

贯穿金属薄板8的厚度方向地形成多个开口部7,该开口部7用于将放置在金属薄板8上的焊锡糊剂50涂布在设在各开口部7之下的阻挡金属层上。A plurality of openings 7 for applying solder paste 50 placed on the thin metal plate 8 to the barrier metal layer provided under each opening 7 are formed through the thickness direction of the thin metal plate 8 .

而且,多个开口部7各个可形成圆形、椭圆形、长圆形、多角形等各种形状,形成多列地排列在金属薄板8上,通过它们的排列构成多个开口部列7a、7b、7c。Moreover, each of the plurality of openings 7 can be formed in various shapes such as a circle, an ellipse, an oval, and a polygon, and is arranged in multiple rows on the thin metal plate 8, and a plurality of opening rows 7a, 7a, etc. are formed by their arrangement. 7b, 7c.

图7中,设置多个开口部列7a、7b、7c,使各列7a、7b、7c相互大致平行,对每列开口部列7a、7b、7c设定开口部7的排列密度,其中一部分开口部列或者各开口部列的排列密度不同。图示的例子是各开口部列的排列密度都不同。In Fig. 7, a plurality of openings rows 7a, 7b, 7c are set, each row 7a, 7b, 7c is substantially parallel to each other, and the arrangement density of openings 7 is set for each row of openings 7a, 7b, 7c. The arrangement density of the opening row or each opening row is different. In the illustrated example, the arrangement density of each opening row is different.

此处,重要的是设定前述多个开口部7的开口面积,开口部7的排列密度越大的排列区域,即排列密度越大的开口部列,其开口面积越小。例如,开口部7的排列密度,分别将开口部列7a处设定为80~90点每厘米,开口部列7b处为50~60点每厘米,开口部列7c处为10~15点每厘米时,开口部7的开口面积分别将开口部列7a处设定为7850~7950μm2,开口部列7b处为8400~8500μm2,开口部列7c处为8800~8900μm2Here, it is important to set the opening area of the aforementioned plurality of openings 7 , and the arrangement region with higher arrangement density of the openings 7 , that is, the opening row with higher arrangement density, has a smaller opening area. For example, the arrangement density of the openings 7 is set to 80-90 dots per centimeter at the opening row 7a, 50-60 dots per centimeter at the opening row 7b, and 10-15 dots per centimeter at the opening row 7c. In centimeters, the opening area of the opening 7 is set to 7850-7950 μm 2 at the opening row 7a, 8400-8500 μm 2 at the opening row 7b, and 8800-8900 μm 2 at the opening row 7c.

因此,当用丝网印刷用掩膜,将焊锡凸起形成在设在基板上的阻挡金属层上,并用橡皮刮刀使放置在前述金属薄板8上的焊锡糊剂50移动时,即使开口部7的排列密度比开口部列7b、7c更大的开口部列7a附近的焊锡糊剂50比开口部列7b、7c附近的焊锡糊剂50在掩膜上更强烈地旋转、流动,导致粘性减小时,涂布在阻挡金属层上的焊锡糊剂50的量也可以大致均匀地形成在所有的开口部列7a、7b、7c处,从而可得到形成在电子零件的阻挡金属层上的焊锡凸起的大小一致的高品质的电子零件。Therefore, when solder bumps are formed on the barrier metal layer provided on the substrate using a mask for screen printing, and the solder paste 50 placed on the metal thin plate 8 is moved with a squeegee, even if the opening 7 The solder paste 50 near the opening row 7a whose arrangement density is higher than that of the opening row 7b and 7c rotates and flows more strongly on the mask than the solder paste 50 near the opening row 7b and 7c, resulting in a decrease in viscosity. When the amount of solder paste 50 coated on the barrier metal layer is small, the amount of solder paste 50 coated on the barrier metal layer can also be formed approximately uniformly at all the openings 7a, 7b, 7c, so that the solder bumps formed on the barrier metal layer of the electronic component can be obtained. High-quality electronic components of consistent size.

而且,如果所有的开口部7形成大致相似的形状,则具有所有的开口部列7a、7b、7c处的焊锡凸起的形状大致均匀一致的优点。Furthermore, if all the openings 7 are formed in substantially similar shapes, there is an advantage that the shapes of the solder bumps in all the opening rows 7 a , 7 b , and 7 c are substantially uniform.

另外,当金属薄板8由Ni合金构成时,前述金属薄板8及多个开口部7可采用现有公知的添加法形成。In addition, when the thin metal plate 8 is made of a Ni alloy, the thin metal plate 8 and the plurality of openings 7 can be formed by a conventionally known additive method.

下面参照图8A至图8B,详细说明用上述丝网印刷用掩膜形成电子零件的焊锡凸起的方法。以下的例子示出了倒装片IC。Next, a method of forming solder bumps of electronic components using the above screen printing mask will be described in detail with reference to FIGS. 8A to 8B. The following example shows a flip-chip IC.

(1)首先,在图8A中,准备被印刷物,即基板(半导体晶片)1、焊锡糊剂50和丝网印刷用掩膜6。(1) First, in FIG. 8A , an object to be printed, that is, a substrate (semiconductor wafer) 1 , a solder paste 50 and a mask 6 for screen printing are prepared.

前述基板1,由铝等制成的电路配线2和半导体元件等高密度地集中在由单结晶硅等制成的板体的一个主面上,多个阻挡金属层3覆盖在该电路配线2上,钝化层4覆盖在没有形成该阻挡金属层3的区域中。由此,前述多个阻挡金属层3与前述丝网印刷用掩膜6的开口部7一一对应地分成多列,每列以所定的密度排列,各列均具有依次叠积锌(Zn)、镍(Ni)、金(Au)的3层构造,另一方面,前述钝化层4由氮化硅(Si3N4)等绝缘材料如前所述地在没有形成阻挡金属层3的区域中形成。另外,前述阻挡金属层3采用现有公知的无电解电镀法,前述钝化层4采用现有公知的阴极溅射、光刻技术、腐蚀技术等,形成所定图样。The aforementioned substrate 1, circuit wiring 2 made of aluminum or the like, and semiconductor elements are concentrated on one main surface of a board body made of single crystal silicon or the like, and a plurality of barrier metal layers 3 are covered on the circuit wiring. On the line 2, the passivation layer 4 covers the area where the barrier metal layer 3 is not formed. As a result, the plurality of barrier metal layers 3 and the openings 7 of the screen printing mask 6 are divided into a plurality of rows in one-to-one correspondence, each row is arranged at a predetermined density, and each row has zinc (Zn) stacked sequentially. , nickel (Ni), and gold (Au), and on the other hand, the aforementioned passivation layer 4 is made of insulating materials such as silicon nitride (Si 3 N 4 ) as described above without forming the barrier metal layer 3 formed in the region. In addition, the barrier metal layer 3 adopts the known electroless plating method, and the passivation layer 4 adopts the known cathode sputtering, photolithography technology, corrosion technology, etc. to form a predetermined pattern.

而且,前述焊锡糊剂50可适当地在多个焊锡颗粒中添加、混合焊剂等,并调整为所定粘度。Furthermore, the aforementioned solder paste 50 may be appropriately added or mixed with a flux or the like to a plurality of solder particles, and may be adjusted to a predetermined viscosity.

(2)接着,将前述基板1放置、固定在丝网印刷机的载物台上,使在(1)的工序中准备的丝网印刷用掩膜6相对于该基板1定位(图8A)。(2) Next, the above-mentioned substrate 1 is placed and fixed on the stage of the screen printing machine, and the screen printing mask 6 prepared in the process of (1) is positioned relative to the substrate 1 ( FIG. 8A ). .

此时,设置丝网印刷用掩膜6,使前述多个开口部7位于基板1上的对应的阻挡金属层3的正上方。At this time, the mask 6 for screen printing is set so that the aforementioned plurality of openings 7 are located directly above the corresponding barrier metal layers 3 on the substrate 1 .

(3)接着,如图8B所示,将在(1)的工序中准备的焊锡糊剂50和橡皮刮刀放置在丝网印刷用掩膜6上,在橡皮刮刀的刀刃接触丝网印刷用掩膜6的状态下,使橡皮刮刀沿开口部列7a、7b、7c移动,使焊锡糊剂50透过丝网印刷用掩膜6的开口部7,印刷、涂布在阻挡金属层3上。(3) Next, as shown in FIG. 8B, the solder paste 50 and the squeegee prepared in the process of (1) are placed on the screen printing mask 6, and the edge of the squeegee contacts the screen printing mask. In the state of the film 6 , the squeegee is moved along the rows of openings 7 a , 7 b , and 7 c to pass the solder paste 50 through the openings 7 of the screen printing mask 6 to be printed and applied on the barrier metal layer 3 .

此时,由于设置丝网印刷用掩膜6的开口部7,使得排列密度越大的排列区域,即排列密度越大的开口部列,其开口面积越小,因此,即使当开口部7的排列密度大的开口部列7a附近的焊锡糊剂50比排列密度小的开口部列7b、7c附近的焊锡糊剂50更加剧烈地在丝网印刷用掩模6上旋转、流动,粘性减小时,涂布在阻挡金属层3上的焊锡糊剂50的量也可以大致均匀地形成在所有的开口部列7a、7b、7c处。At this time, since the openings 7 of the mask 6 for screen printing are provided, the arrangement area with the greater arrangement density, that is, the opening row with the greater arrangement density, has a smaller opening area. When the solder paste 50 near the opening row 7a with a large arrangement density rotates and flows on the screen printing mask 6 more violently than the solder paste 50 near the opening rows 7b and 7c with a lower arrangement density, and the viscosity decreases Therefore, the amount of the solder paste 50 coated on the barrier metal layer 3 can also be formed substantially uniformly in all the opening rows 7a, 7b, 7c.

(4)接着,如图8C所示,使涂布在阻挡金属层3上的焊锡糊剂50干燥,最后通过使其反流,使包含在焊锡糊剂50中的焊锡颗粒熔融,使焊锡颗粒之间相互结合,再使其冷却,从而在阻挡金属层3上形成大小大致均匀一致的球状焊锡凸起5。(4) Next, as shown in FIG. 8C , the solder paste 50 coated on the barrier metal layer 3 is dried, and finally by reflowing it, the solder particles contained in the solder paste 50 are melted to make the solder particles They are combined with each other, and then allowed to cool, so that spherical solder bumps 5 with approximately uniform size are formed on the barrier metal layer 3 .

本实施形态中,可以改变一个开口部列中的开口部的排列密度,此时如图9所示,可以设定为开口部7的排列密度越大的排列区域,其开口部7的开口面积越小。这样,涂布在阻挡金属层3上的焊锡糊剂50的量可大致均匀地形成在所有的开口部7处,从而形成在电子零件的阻挡金属层3上的焊锡凸起的大小可保持一致。In this embodiment, the arrangement density of the openings in one opening row can be changed. At this time, as shown in FIG. smaller. In this way, the amount of solder paste 50 coated on the barrier metal layer 3 can be formed substantially uniformly at all the openings 7, so that the size of the solder bumps formed on the barrier metal layer 3 of the electronic parts can be kept uniform. .

而且,印刷掩模如上所述,也可以用由树脂薄板,例如聚酰亚胺树脂或聚酯树脂、聚乙烯树脂等各种树脂制成的掩模代替上述在金属薄板8上设有多个开口部7的“金属掩模”。And, printing mask is as mentioned above, also can use the mask that is made of various resins such as polyimide resin or polyester resin, polyethylene resin by resin thin plate, replaces the above-mentioned a plurality of on the metal thin plate 8. The "metal mask" of the opening 7.

在其它实施形态中,除了可用于形成倒装片IC的焊锡凸起以外,还可用于形成设在电阻或电容器等其它电子零件上的焊锡凸起。In other embodiments, in addition to being used to form solder bumps for flip-chip ICs, it can also be used to form solder bumps provided on other electronic components such as resistors and capacitors.

印刷糊剂中除了上述焊锡糊剂50以外,还可采用银糊剂等其它导电糊剂,可在此处形成凸起电极。In addition to the solder paste 50 described above, other conductive pastes such as silver paste can be used as the printing paste, and bump electrodes can be formed here.

而且,上述实施形态中,开口部7的形状可形成椭圆形或长圆形,同时如果将其长度方向设定为与橡皮刮刀的移动方向垂直,则具有可非常准确地控制印刷到阻挡金属层上的焊锡糊剂的涂布量的优点。Moreover, in the above-mentioned embodiment, the shape of the opening 7 can be formed into an ellipse or an oblong shape, and if its longitudinal direction is set to be perpendicular to the moving direction of the squeegee, it has the ability to control the printing on the barrier metal layer very accurately. Advantages on the coating amount of solder paste.

如上所述,采用本发明,由于设定了该开口部的排列密度越大的排列区域,设在丝网印刷用掩模上的开口部的开口面积越小,因此,放置在丝网印刷用掩模上的印刷糊剂中,即使开口部的排列密度大的区域附近的印刷糊剂的粘性较小,涂布在阻挡金属层上的印刷糊剂的量也可以大致均匀地形成在所有的开口部处,使形成在电子零件的阻挡金属层上的凸起的大小一致,从而可获得高品质的电子零件。As mentioned above, adopt the present invention, owing to set the arrangement area that the arrangement density of this opening part is bigger, the opening area of the opening part that is located on the mask for screen printing is smaller, therefore, be placed on the mask for screen printing In the printing paste on the mask, even if the viscosity of the printing paste near the area where the arrangement density of the openings is high is low, the amount of the printing paste coated on the barrier metal layer can be formed approximately uniformly in all areas. At the opening, the size of the bumps formed on the barrier metal layer of the electronic component can be made uniform, so that a high-quality electronic component can be obtained.

本发明的范围不仅限于上述实施形态,只要不脱离本发明请求的范围和精神,可进行各种变更和改良。The scope of the present invention is not limited to the above-mentioned embodiments, and various changes and improvements can be made without departing from the scope and spirit of the claims of the present invention.

Claims (4)

1.一种印刷掩模,该印刷掩模由多个开口部排列成一列或多列而成,用于透过开口部将印刷糊剂印刷、涂布在晶片上,从而在晶片上的阻挡金属层上形成凸起,其特征在于,开口部的排列密度根据排列区域而有所不同,设定为开口部的排列密度越大的排列区域,开口部的开口面积越小。1. A printing mask, the printing mask is formed by a plurality of openings arranged in one or more rows, and is used to print and coat the printing paste on the wafer through the openings, so as to block the wafer on the wafer. Protrusions are formed on the metal layer, and the arrangement density of the openings differs depending on the arrangement region, and the arrangement region with a higher arrangement density of the openings has a smaller opening area of the openings. 2.如权利要求1所述的印刷掩模,其特征在于,开口部排列成多列,且对每列设定其开口部的排列密度。2. The printing mask according to claim 1, wherein the openings are arranged in a plurality of rows, and the arrangement density of the openings is set for each row. 3.如权利要求1或2所述的印刷掩模,其特征在于,开口部排列的多列相互大致平行。3. The printing mask according to claim 1 or 2, wherein the plurality of rows in which the openings are arranged are substantially parallel to each other. 4.一种采用权利要求1或2所述的印刷掩模制造电子零件的方法,其特征在于,该方法包含下述工序:将前述印刷掩模设置在晶片上,使得开口部位于形成在该晶片上的阻挡金属层之上;将印刷糊剂放置在前述印刷掩模上;使该印刷糊剂沿着开口部的排列移动,透过开口部将印刷糊剂印刷、涂布在前述阻挡金属层上;在前述阻挡金属层上形成凸起。4. A method for manufacturing electronic components using the printing mask according to claim 1 or 2, characterized in that the method comprises the following steps: placing the aforementioned printing mask on the wafer so that the opening is located at the On the barrier metal layer on the wafer; placing the printing paste on the aforementioned printing mask; moving the printing paste along the arrangement of the openings, printing and coating the printing paste on the aforementioned barrier metal through the openings layer; forming protrusions on the aforementioned barrier metal layer.
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US5992962A (en) * 1994-12-22 1999-11-30 Hewlett-Packard Company Print masks for inkjet printers
US6319851B1 (en) * 1999-02-03 2001-11-20 Casio Computer Co., Ltd. Method for packaging semiconductor device having bump electrodes
JP3459380B2 (en) * 1999-06-30 2003-10-20 日本特殊陶業株式会社 Manufacturing method of printed wiring board and mask

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CN110331365A (en) * 2014-06-06 2019-10-15 大日本印刷株式会社 The manufacturing method of deposition mask and its precursor and organic semiconductor device
CN110331365B (en) * 2014-06-06 2021-10-01 大日本印刷株式会社 Evaporation mask, precursor thereof, and method for producing organic semiconductor element

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