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CN1946571A - Apparatus and process for manufacturing a film for applying varnish and colour onto an object - Google Patents

Apparatus and process for manufacturing a film for applying varnish and colour onto an object Download PDF

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Publication number
CN1946571A
CN1946571A CNA2005800127730A CN200580012773A CN1946571A CN 1946571 A CN1946571 A CN 1946571A CN A2005800127730 A CNA2005800127730 A CN A2005800127730A CN 200580012773 A CN200580012773 A CN 200580012773A CN 1946571 A CN1946571 A CN 1946571A
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Prior art keywords
film
varnish
layer
coating roll
equipment
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M·赞赫
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DEMAXZ LLC
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/16Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
    • B44C1/165Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
    • B44C1/17Dry transfer
    • B44C1/1708Decalcomanias provided with a layer being specially adapted to facilitate their release from a temporary carrier
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00Processes for applying liquids or other fluent materials
    • B05D1/28Processes for applying liquids or other fluent materials performed by transfer from the surfaces of elements carrying the liquid or other fluent material, e.g. brushes, pads, rollers
    • B05D1/286Processes for applying liquids or other fluent materials performed by transfer from the surfaces of elements carrying the liquid or other fluent material, e.g. brushes, pads, rollers using a temporary backing to which the coating has been applied
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/06Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation
    • B05D3/061Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation using U.V.
    • B05D3/065After-treatment
    • B05D3/067Curing or cross-linking the coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/02Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to macromolecular substances, e.g. rubber
    • B05D7/04Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to macromolecular substances, e.g. rubber to surfaces of films or sheets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50Multilayers
    • B05D7/52Two layers
    • B05D7/53Base coat plus clear coat type
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/02Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
    • B05D3/0254After-treatment

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  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Decoration By Transfer Pictures (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

A process and apparatus for manufacturing a film that can be used to apply varnish and colour onto an object to be decorated. The process includes the steps of; (1) applying a layer of colour onto a first film, which has release properties; (2) applying a layer of varnish onto the colour layer of the first film; (3) partially curing the varnish layer; (4) transferring by release the layers of varnish and colour from the first film onto a second film having release properties, wherein the second film is more flexible than the first; and (5) further curing the transferred layer of varnish on the second film.

Description

用于制造施用清漆和 颜料到物体上的膜的设备和方法Apparatus and method for producing films for applying varnishes and pigments to objects

本申请要求在2004年2月23日提交的序列号为60/546,736的美国专利申请的优先权,在此通过引用将其全文纳入本文中。This application claims priority to US Patent Application Serial No. 60/546,736, filed February 23, 2004, which is hereby incorporated by reference in its entirety.

技术领域technical field

本发明涉及一种用于制造能够将颜色和清漆施用到拟装饰物体上的膜的方法和设备。The invention relates to a method and a device for the manufacture of films enabling the application of colors and varnishes to objects to be decorated.

背景技术Background technique

具有通常所说脱膜性能的膜在现有技术中已经众所周知,例如,参见EP1 053 793 A1和EP 0 573 676 B1。现有技术中已知由树脂制成的纸张和膜,其表面被制备为使得膜具有脱膜性能。如果颜料层或清漆层被施用到这样一种具有脱膜性能的膜上,则可以将从该膜上剥离下来的清漆层或颜料层转移到拟装饰的物体上。通常,这些脱膜性能通过在膜和颜料层以及清漆层之间施用硅基脱膜剂(silicon basedrelease agent)来获得或者增强。但是,通常不希望有硅残留物残存在施用到拟装饰物上的颜料/清漆层上。Membranes with so-called release properties are known in the prior art, see, for example, EP 1 053 793 A1 and EP 0 573 676 B1. Papers and films made of resins are known in the art, the surface of which is prepared so that the film has release properties. If the paint or varnish layer is applied to such a film having release properties, the varnish or paint layer peeled off from the film can be transferred to the object to be decorated. Typically, these release properties are obtained or enhanced by applying silicon based release agents between the film and the pigment and varnish layers. However, it is generally undesirable for silicon residues to remain on the paint/varnish layer applied to the intended decoration.

依照EP 0 573 676 B1的现有技术公开了一种装饰物体的方法,该方法中,清漆层被施用到具有脱膜性能的膜上。不完全地固化该清漆层。向不完全被固化的清漆层施用颜料层并在该颜料层上施用第二清漆层。并且不完全地固化第二清漆层。其后,将清漆层和颜料层分别转移到拟装饰的物体上(“基底”)。在通过脱膜转移之后,完全固化第一和第二清漆层。“固化”也被称之为“交联”。The prior art according to EP 0 573 676 B1 discloses a method for decorating objects in which a varnish layer is applied to a film with release properties. The varnish layer is incompletely cured. A pigment layer is applied to the incompletely cured clearcoat layer and a second clearcoat layer is applied on top of this pigment layer. And the second varnish layer is not fully cured. Thereafter, the varnish layer and the pigment layer are transferred separately onto the object to be decorated ("substrate"). After transfer by stripping, the first and second varnish layers are fully cured. "Curing" is also referred to as "crosslinking".

EP 1 053 793 Al教导了通过离型膜的方法将清漆和颜料施用到物体上,其中一种胶水被施用到离型膜的清漆层和颜料层的上面。当将膜转移到拟装饰的物体上时,该胶水与该物体直接接触。EP 1 053 793 Al teaches the application of varnish and pigment to objects by means of a release film, wherein a glue is applied on top of the varnish and pigment layers of the release film. When the film is transferred to the object to be decorated, the glue is in direct contact with the object.

制造该可被用来向拟装饰物体上施用颜料和清漆的膜的方法也是现有技术已知的,其中在具有脱膜性能的第一膜上印制颜料层,并在此后通过脱膜的方式将该颜料层转移到具有脱膜性能的另一膜上。该另一膜比该第一膜更柔软。Also known in the prior art is the method of producing films that can be used to apply paints and varnishes to objects to be decorated, in which a layer of pigments is printed on a first film with release properties, and thereafter is removed by means of a release process. The method is to transfer the pigment layer to another film with release properties. The other membrane is more flexible than the first membrane.

使用通常所说的涂料辊和通常所说的压紧辊(有时也称之为反作用辊)来将清漆施用到一柔性膜上在现有技术中也已公知。该柔性膜可以优选地具有所谓的脱膜性能,从而使得该清漆层可以被从该膜上转移到物体上,例如在清漆固化(交联)之后或不完全固化之后,可以通过将该清漆层剥离下来实现该转移。由例如象聚丙烯、聚乙稀、聚乙烯醇、聚氯乙烯、聚甲基丙烯酸甲酯或聚对苯二甲酸乙二醇酯这样材料制成的膜一般具有良好的脱膜性能。膜的脱膜性能也可以用象处理膜表面张力(例如通过常规的电晕处理)这样的物理方法或象施用多种常规脱膜剂的这样的化学方法来提高。It is also known in the art to apply varnishes to a flexible film using so-called applicator rolls and so-called pinch rolls (sometimes also called counter rolls). The flexible film may preferably have so-called release properties, so that the varnish layer can be transferred from the film to the object, for example after curing (crosslinking) of the varnish or after incomplete curing, by Peel off to achieve this transfer. Films made of materials such as polypropylene, polyethylene, polyvinyl alcohol, polyvinyl chloride, polymethyl methacrylate or polyethylene terephthalate generally have good release properties. The release properties of the film can also be enhanced by physical methods such as manipulating the surface tension of the film (for example by conventional corona treatment) or by chemical methods such as the application of various conventional release agents.

发明目的purpose of invention

本发明的目的在于提供一种用于制造能够被用于将颜料和清漆施用到拟装饰的物体上的方法和设备,其中该颜料和清漆在被装饰的物体上具有很好的粘附性。The object of the present invention is to provide a method and a device for the manufacture of paints and varnishes that can be used to apply paints and varnishes to objects to be decorated, wherein the paints and varnishes have good adhesion on the objects to be decorated.

拟装饰的物体可以是例如由木材或类似木材的材料制成,或者该物体也可以由塑料等制成。由金属制成的物体也可以通过依据本发明的膜覆盖上颜料和清漆。此外,由玻璃或陶瓷材料制成的物体也可以通过依据本发明的膜以颜料和清漆装饰。The object to be decorated may be, for example, made of wood or a wood-like material, or the object may also be made of plastic or the like. Objects made of metal can also be covered with paints and varnishes by means of the films according to the invention. Furthermore, objects made of glass or ceramic materials can also be decorated with paints and varnishes by means of the film according to the invention.

为此,本发明教导了一种用于制造一种膜的方法和设备,该膜能够用于将清漆和颜料施用到物体上,该方法包括如下步骤:(1)将颜料层施用到第一膜上,该第一膜包含脱模特性;(2)将清漆层施用到在第一膜上的颜料层上;(3)不完全地固化该清漆层;(4)通过脱膜技术将清漆层和颜料层从第一膜上转移到具有脱膜性能的第二膜上,其中该第二膜比第一膜更柔软;并且(5)进一步固化在第二膜上的已被转移的清漆层。To this end, the present invention teaches a method and apparatus for producing a film that can be used to apply varnishes and pigments to objects, the method comprising the steps of: (1) applying a layer of pigment to a first (2) applying a varnish layer to the pigment layer on the first film; (3) incompletely curing the varnish layer; (4) applying the varnish by a release technique layer and pigment layer are transferred from the first film to a second film with release properties, wherein the second film is more flexible than the first film; and (5) further curing the transferred varnish on the second film layer.

作为一种替换方式,本发明教导了一种用于制造一种膜的方法,该膜能够用于将颜料和清漆施用到物体上,该方法包括如下步骤:(1)将清漆层施用到第一膜上,该第一膜包含脱膜性能;(2)将颜料层施用到第一膜上的清漆层上;(3)不完全地固化该清漆层;(4)通过脱膜技术将颜料层和清漆层从第一膜上转移到具有脱膜性能的第二膜上,其中该第二膜比第一膜更柔软;并且(5)进一步固化在第二膜上的已被转移的清漆层。As an alternative, the present invention teaches a method for producing a film that can be used to apply paint and varnish to an object, the method comprising the steps of: (1) applying a layer of varnish to a first (2) applying a pigment layer to the varnish layer on the first film; (3) incompletely curing the varnish layer; (4) applying the pigment layer by a release technique layer and varnish layer are transferred from the first film to a second film having release properties, wherein the second film is more flexible than the first film; and (5) further curing the transferred varnish on the second film layer.

同样,用于制造该膜的设备可以包括:(1)用于将清漆层施用到第一膜上的清漆施用站,该第一膜具有脱膜性能;(2)用于不完全地固化该清漆层的第一固化站;(3)用于供给第二膜的供料圆筒,该第二膜比第一膜更柔软;(4)用于通过脱膜技术将至少清漆层从第一膜上转移到第二膜上的转移站;和(5)用于进一步固化清漆层的第二固化站。Likewise, the equipment used to manufacture the film may include: (1) a varnish application station for applying a layer of varnish to a first film having release properties; (2) a station for incompletely curing the A first curing station for the varnish layer; (3) a feed cylinder for feeding a second film, which is more flexible than the first film; (4) for removing at least the varnish layer from the first a transfer station on the film to a second film; and (5) a second curing station for further curing of the varnish layer.

根据本发明的优选实施方案,第一膜包括颜料层。该颜料层可以在该清漆层的上面或在该漆层的下面,即与第一膜直接接触。根据另一优选实施方案,一加热站,优选为一使用红外辐射线(红外)的加热站,被布置在清漆施用站和第一固化站之间。在这一点上,术语“在......之间”是就第一膜通过该设备的运动方向而言的,例如,从用于第一膜的供料圆筒到转移站的方向。根据本发明的另一优选实施方案,该第一膜由聚丙烯制成,而第二膜由聚烯烃、聚乙烯或聚氯乙烯(PVC)制成。According to a preferred embodiment of the invention, the first film comprises a pigment layer. The pigment layer may be on top of the varnish layer or below the lacquer layer, ie in direct contact with the first film. According to another preferred embodiment, a heating station, preferably a heating station using infrared radiation (infrared), is arranged between the varnish application station and the first curing station. In this regard, the term "between" refers to the direction of movement of the first film through the apparatus, for example, the direction from the feed cylinder for the first film to the transfer station . According to another preferred embodiment of the invention, the first film is made of polypropylene and the second film is made of polyolefin, polyethylene or polyvinyl chloride (PVC).

在第一固化站内的不完全固化优选地通过紫外线辐射源发出的紫外辐射线来实施。在第二固化站内的清漆的完全固化也优选地通过紫外辐射线辐射源发出的紫外辐射线来实施。The incomplete curing in the first curing station is preferably carried out by means of UV radiation emitted by a UV radiation source. Complete curing of the varnish in the second curing station is also preferably carried out by means of UV radiation emitted by a UV radiation source.

根据本发明的优选实施方案,第一膜由聚丙烯制成。与现有技术中已知的具有脱膜性能的其它膜相比,聚丙烯是相对较硬的。从另一方面来说,聚丙烯能够以非常好的质量被印刷上彩色装饰。特别的是,如果拟被装饰的是三维物体,则相对较硬(不柔软)的聚丙烯膜就会产生问题。因此,根据本发明,颜料层和被施用在颜料层上或颜料层下的清漆层被通过脱膜技术转移到具有脱膜性能的另一膜上,其中另一膜比聚丙烯膜更柔软,因此该颜料层和该清漆层能够被从更柔软的膜上高质量地转移到三维物体上,包括在该物体上的边缘和凹处。用于更柔软的第二膜的优选的材料为聚烯烃、聚乙烯、聚氯乙烯(PVC)、或者聚乙烯醇(PVA)。在一个优选实施方案中,该颜料层和清漆层没有使用脱膜剂(即没有脱膜剂)而被施用到该第一膜和第二膜上。According to a preferred embodiment of the invention, the first membrane is made of polypropylene. Polypropylene is relatively stiff compared to other films with release properties known in the art. Polypropylene, on the other hand, can be printed with color decorations in very good quality. In particular, the relatively stiff (not flexible) polypropylene film presents problems if the object to be decorated is a three-dimensional object. Thus, according to the invention, the pigment layer and the varnish layer applied on or under the pigment layer are transferred by release technology to another film having release properties, wherein the other film is softer than the polypropylene film, The pigment layer and the varnish layer can thus be transferred from a more flexible film to a three-dimensional object with high quality, including edges and recesses on the object. Preferred materials for the second, more flexible film are polyolefins, polyethylene, polyvinyl chloride (PVC), or polyvinyl alcohol (PVA). In a preferred embodiment, the pigment and varnish layers are applied to the first and second films without the use of a release agent (ie without a release agent).

最优选地,依据本发明的方法的步骤由同一个设备在两个步骤之间无时间延迟地执行。特别地,通过脱膜技术从第一膜上转移清漆层和颜料层到第二膜层的步骤是在清漆层不完全固化之后以最小的时间延迟直接执行的。不完全固化优选地通过UV(紫外线)辐射完成的。同样方法也施用到转移后的清漆层的进一步固化中。该进一步的固化优选的为清漆的完全固化,也就是说是清漆的完全交联。Most preferably, the steps of the method according to the invention are performed by the same device without a time delay between the two steps. In particular, the step of transferring the varnish layer and the pigment layer from the first film to the second film layer by stripping techniques is carried out directly after the incomplete curing of the varnish layer with minimal time delay. Incomplete curing is preferably accomplished by UV (ultraviolet) radiation. The same method is applied to the further curing of the transferred varnish layer. This further curing is preferably a complete curing of the varnish, that is to say a complete crosslinking of the varnish.

最适于本发明的染料或者墨水应挑选抗紫外线的色散颜料(dispersion colour dyes)。优选地,颜料层由每平方米施用大约10克(湿)或者3克(干)染料来形成。可升华的色散染料也能被用于颜料层。可升华的色散染料是指能够直接从固体状态转变到气体状态并且易于渗入基底而不是全然残留在基底表面的染料。拟使用的清漆是现有技术中已知的,例如基于烷基氨基甲酸酯树脂的清漆。The most suitable dyestuff or ink of the present invention should choose anti-ultraviolet dispersion pigment (dispersion color dyes). Preferably, the pigment layer is formed by applying about 10 grams (wet) or 3 grams (dry) of dye per square meter. Sublimable disperse dyes can also be used for the pigment layer. Sublimable disperse dyes refer to dyes that can directly transition from a solid state to a gas state and tend to penetrate into the substrate instead of remaining completely on the surface of the substrate. The varnishes to be used are known from the prior art, for example varnishes based on alkylurethane resins.

根据本发明的方法和设备所获得的产品是一种能够被用于将颜料和清漆施用到所装饰的物体上的膜。该产品是能够被制造和销售的膜。正如在EP 0 282 859B1所公开地,例如,消费者可以在一使用膜的设备中将该膜压靠在拟装饰的三维物体上对该膜加以使用。根据本发明所制造的膜也能够在注射机中使用。The product obtained according to the method and device of the invention is a film that can be used to apply paints and varnishes to decorated objects. The product is a film that can be manufactured and sold. As disclosed in EP 0 282 859 B1, for example, the consumer can use the film by pressing the film against the three-dimensional object to be decorated in a device using the film. Films produced according to the invention can also be used in injection machines.

本发明的另一实施方案涉及施用一清漆层到这种膜上,该膜优选地具有脱膜性能。该膜可以在施用清漆层之前或之后被印刷上颜料层。Another embodiment of the invention involves the application of a varnish layer to such a film, which preferably has release properties. The film can be printed with a pigment layer before or after the application of the varnish layer.

在现有技术中,施用相对厚的清漆层到膜上,即使可能,也是非常困难的。本文涉及的膜通常具有大于100厘米的宽度,例如在160到180厘米范围内的宽度。根据现有技术的机器只能够施用厚度通常小于60μm的清漆层。Applying relatively thick layers of varnish to films is very difficult, if not impossible, in the prior art. The films referred to herein generally have a width greater than 100 centimeters, for example a width in the range of 160 to 180 centimeters. Machines according to the prior art are only capable of applying varnish layers with a thickness of generally less than 60 μm.

本发明旨在提供一种能够适于施用多种不同厚度的清漆层的设备,特别是相对厚的清漆层。The present invention aims to provide a device which can be adapted to apply layers of varnish of various thicknesses, in particular relatively thick varnish layers.

本发明提供一种用于将清漆施用到膜上的设备和方法。该设备包括涂料辊和邻近该涂料辊布置的压紧辊,该涂料辊用于从该涂料辊上将清漆转移到膜上。除了用于转动涂料辊以使得邻近膜的涂料辊的圆周以不同于第一速度的第二速度转动的装置之外,还设有用于以第一速度送进该膜通过在涂料辊和压紧辊之间的缝隙的装置。The present invention provides an apparatus and method for applying varnish to a film. The apparatus includes an applicator roll for transferring varnish from the applicator roll to the film and a pinch roll disposed adjacent to the applicator roll. In addition to the means for rotating the applicator roll so that the circumference of the applicator roll adjacent to the film rotates at a second speed different from the first speed, there is also provided for feeding the film at the first speed through the applicator roll and the compactor The device for the gap between the rollers.

根据本发明的一个优选实施方案,用于送进该膜的装置将该膜在第一方向上送进通过在涂料辊和压紧辊之间的缝隙,并且用于转动涂料辊的装置转动涂料辊以使得邻近该膜的涂料辊的圆周在与第一方向相反的第二方向上运动。According to a preferred embodiment of the present invention, the means for feeding the film feeds the film in a first direction through the nip between the coating roller and the pinch roller, and the means for rotating the coating roller rotates the coating The roller moves such that the circumference of the coating roller adjacent the film is in a second direction opposite the first direction.

在又一个实施方案中,膜以与一平面成不为零的角度(α)进入间隙,该平面与涂料辊和压紧辊相切。根据本发明的另一优选实施方案,涂料辊包括橡胶表面。根据本发明的还一个实施方案,设置有一用于在一平面平行的方向上移动至少一个压紧辊或涂料辊的装置,该平面与涂料辊和压紧辊都相切。In yet another embodiment, the film enters the nip at a non-zero angle (α) to a plane that is tangent to the applicator roll and pinch roll. According to another preferred embodiment of the invention, the coating roller comprises a rubber surface. According to yet another embodiment of the invention, there is provided a device for moving at least one pressure roller or coating roller in a direction parallel to a plane which is tangential to both the coating roller and the pressure roller.

附图说明Description of drawings

图1至4示出了用于制造能将颜料和清漆施用到物体上的膜的方法的第一实施方案。1 to 4 show a first embodiment of a method for producing a film enabling the application of pigments and varnishes to objects.

图5至7示出了这种方法的另一实施方案。Figures 5 to 7 show another embodiment of this method.

图8示出了根据本发明的用于制造能将清漆和颜料施用到物体上的膜的设备。FIG. 8 shows an apparatus according to the invention for producing a film enabling the application of varnishes and pigments to objects.

图9示意性地示出了用于将清漆施用到膜上的本发明的一个实施方案。Figure 9 schematically shows an embodiment of the invention for applying varnish to a film.

具体实施方式Detailed ways

根据图1,聚丙烯制成的第一膜10被印刷有一层,该层包括颜料装饰物并形成颜料层14,在一个实施方案中,该第一膜可以是15-40μm厚。如此处所使用的,术语“颜料层”包括一印有图案的墨水层,例如象木材纹理图案或者任何其它想要的图案。该印刷方法本身是现有技术中已知的,其一个实施例被称作“影印版(Gravure)”方法。在一个实施方案中,第一膜10会具有在大约30至40达因(dynes)的表面张力(或表面能),该表面张力优选为大约35至40达因,并且最优选在大约39至40达因之间。这种表面张力可以通过选用天然具有这种表面张力的材料或者通过改变该表面张力,例如通过电晕处理方法,来获得。依靠上述表面张力,颜料层可以被施用而无需使用脱膜剂。According to FIG. 1 , a first film 10 of polypropylene is printed with a layer comprising pigment decorations and forming a pigment layer 14 , which in one embodiment may be 15-40 μm thick. As used herein, the term "pigment layer" includes an ink layer imprinted with a pattern, for example like a wood grain pattern or any other desired pattern. This printing method is known per se in the prior art, one embodiment of which is known as the "Gravure" method. In one embodiment, the first film 10 will have a surface tension (or surface energy) of about 30 to 40 dynes, preferably about 35 to 40 dynes, and most preferably about 39 to 40 dynes. Between 40 dynes. This surface tension can be achieved by selecting a material that naturally has this surface tension or by altering the surface tension, for example by corona treatment. By virtue of the above-mentioned surface tension, the pigment layer can be applied without using a release agent.

此后,清漆层12被施用到颜料层14上面。通常,这一清漆层的厚度在1到130μm的范围内。这两个步骤产生在图1显示的产品。Thereafter, the varnish layer 12 is applied on top of the paint layer 14 . Typically, the thickness of this varnish layer is in the range of 1 to 130 μm. These two steps yield the product shown in Figure 1.

此后,在图2中用箭头标示的紫外线辐射18被施用到载有颜料层(14)和清漆层(12)的膜10上。紫外线辐射的强度可被控制为使得清漆不是被完全固化(交联),而是仅仅被不完全固化,也就是说清漆还是相对柔软。清漆的剩余柔软度可以通过紫外线辐射量来调整,并且取决于最终成品膜必须满足的特殊需求,在另一方面,该特殊要求取决于最终所要装饰的物体的尺寸和形状。例如,依据清漆层的厚度可以通过大约50到80瓦特/平方厘米的辐射来获得不完全固化。Thereafter, ultraviolet radiation 18 , indicated by arrows in FIG. 2 , is applied to the film 10 carrying the pigment layer ( 14 ) and the varnish layer ( 12 ). The intensity of the UV radiation can be controlled such that the varnish is not fully cured (crosslinked), but only incompletely cured, ie the varnish is still relatively soft. The remaining softness of the varnish can be adjusted by means of the amount of UV radiation and depends on the particular requirements that the final finished film must fulfill, which on the other hand depends on the size and shape of the final object to be decorated. For example, incomplete curing can be achieved by irradiation of about 50 to 80 watts per square centimeter, depending on the thickness of the varnish layer.

在清漆层12不完全固化之后,清漆层和颜料层被立即,优选地只以膜从一个站移动到下一个站的时间延迟,通过脱膜技术转移到另一个也具有脱膜性能的第二膜16上。在一个实施方案中,第二膜16具有类似于上面描述的表面张力,并不使用脱膜剂。转移的结果显示在图3中,即清漆层12与膜16直接接触,而颜料层在清漆层的上面。After the incomplete curing of the varnish layer 12, the varnish layer and the pigment layer are immediately, preferably only delayed by the time that the film moves from one station to the next, transferred by a stripping technique to another second also having stripping properties. on the membrane 16. In one embodiment, the second membrane 16 has a surface tension similar to that described above, and no release agent is used. The result of the transfer is shown in Figure 3, ie the varnish layer 12 is in direct contact with the film 16, and the pigment layer is on top of the varnish layer.

在转移之后,如图4所示出的,用紫外线辐射20的方法完全固化清漆层。完全固化(交联)可以通过例如每平方厘米施用120瓦来获得。通过施用1至2巴的压力和大约90℃至180℃并优选为大约90℃至140℃的高温,可以使从第一膜到第二膜的转移变得容易。After transfer, the varnish layer is completely cured by means of ultraviolet radiation 20 as shown in FIG. 4 . Full cure (crosslinking) can be obtained by applying, for example, 120 watts per square centimeter. The transfer from the first membrane to the second membrane can be facilitated by applying a pressure of 1 to 2 bar and an elevated temperature of about 90°C to 180°C, preferably about 90°C to 140°C.

此后,包括颜料层14和完全固化的清漆层12的膜16可以用来装饰物体。装饰可以根据现有技术来实施,也就是说,清漆层和颜料层通过脱膜技术被转移到物体上,例如根据通过引用并入本文中的欧洲专利EP 0 573 676 B1(其中物体被称之为“基底”)来实施。然而,根据本发明,完全固化(也就是完全交联)并不是在装饰的物体(也就是载有颜料层和清漆层的物体)上实施的,相反的,根据本发明,完全固化是在具有脱膜性能的膜16上实施的。此后,装饰物从该膜上转移到物体上。Thereafter, the film 16 comprising the pigment layer 14 and the fully cured varnish layer 12 can be used to decorate the object. Decoration can be carried out according to the prior art, that is to say that layers of varnish and pigment are transferred onto the object by release techniques, for example according to European patent EP 0 573 676 B1 (where the object is called as the "base"). According to the invention, however, complete curing (i.e. complete cross-linking) is not carried out on decorated objects (i.e. objects bearing layers of paint and varnish), on the contrary, according to the invention complete curing is performed on objects having Membrane 16 for release properties. Thereafter, the decoration is transferred from the film to the object.

本领域技术人员能理解的是,颜料层14可以由几个子层,例如顶涂层、底层和粘结剂层构成。当颜料层14被施用到物体上时,将颜料层14和清漆层12结合到物体上的是粘结剂子层。作为非限定性的实施例,该粘结剂可以包括聚乙酸乙烯酯、聚丙烯酸酯、聚(甲基丙烯酸甲酯)(PMMA)、聚烯烃或者三聚氰胺-甲醛(MF)树脂。在一个优选实施方案中,该粘结剂是可热固化和可紫外线固化的。优选地,该粘结剂可以通过紫外线源固化,例如汞或者镓紫外线灯。该粘结剂可以通过在其组分中包括以重量计约5%到10%的至少下列一种化合物来变得可热固化:酯、酮、苯甲基hydroxene、二醇或水。同样作为一个非限定性实施例,底层可以是上面所描述的粘结剂化合物,但还包括约10%到50%的二氧化铁颜料(百分比取决于所需要颜料的亮度)或者如果需要白色背景时的二氧化钛颜料的添加物。Those skilled in the art will understand that the pigment layer 14 may be composed of several sub-layers, such as a top coat layer, a primer layer and an adhesive layer. When the paint layer 14 is applied to an object, it is the binder sub-layer that bonds the paint layer 14 and varnish layer 12 to the object. As non-limiting examples, the binder may include polyvinyl acetate, polyacrylate, poly(methyl methacrylate) (PMMA), polyolefin, or melamine-formaldehyde (MF) resin. In a preferred embodiment, the adhesive is heat curable and UV curable. Preferably, the adhesive is curable by a UV source, such as mercury or gallium UV lamps. The binder can be made thermally curable by including in its composition about 5% to 10% by weight of at least one of the following compounds: ester, ketone, benzyl hydroxene, glycol or water. Also as a non-limiting example, the base layer can be the binder compound described above, but also include about 10% to 50% iron dioxide pigment (percentage depends on the brightness of the pigment desired) or if a white background is desired When the titanium dioxide pigment additives.

图5示出了第一膜10,该第一膜10包括形成在第一膜10上的粘结剂层21、在粘结剂层21上的底层22、在底层22上的颜料层14以及在颜料层14上的清漆层12。如图6所示出的另一实施方案中,底层22可以被省掉。底层22是否包括在整个膜中取决于在整个膜中需要什么样的背景颜色。某些背景颜色可以通过单独改变粘结剂层21来产生,而其它背景颜色会需要另外的底层22来获得所需要的外观。如参照图3和4所论述的,不同的层被脱膜到图7中示出的第二膜16上并实施进一步固化。在以上描述讨论被施用到膜或者另一层“之上”的一个层时,这一描述包括被直接施用到膜上或其它层上的第二层以及通过一些类型的中间层被间接施用到膜或其它层上或上方的第二层。5 shows a first film 10 comprising an adhesive layer 21 formed on the first film 10, a bottom layer 22 on the adhesive layer 21, a pigment layer 14 on the bottom layer 22 and A layer of varnish 12 on a layer of paint 14 . In another embodiment as shown in FIG. 6, the bottom layer 22 may be omitted. Whether the bottom layer 22 is included in the overall film depends on what background color is desired in the overall film. Certain background colors can be produced by varying the adhesive layer 21 alone, while other background colors will require an additional base layer 22 to obtain the desired appearance. As discussed with reference to Figures 3 and 4, the various layers are stripped onto the second film 16 shown in Figure 7 and subjected to further curing. Where the above description discusses a layer that is applied "on top of" a film or another layer, this description includes second layers that are applied directly to the film or other layer as well as indirectly through some type of intermediate layer. A second layer on or above a film or other layer.

如上文结合图1至4所示出的实施方案更详细的说明地,图7中所示出的最终产品是随时可用于装饰物体的膜16。As explained in more detail above in connection with the embodiment shown in Figures 1 to 4, the final product shown in Figure 7 is a film 16 ready to be used to decorate an object.

图1至7所示出的实施方案可以被修改为使得可以施用多于一层的颜料层和可以施用多于一层的清漆层。例如,在图1和2以及图5和6中示出的步骤中,多于一层的清漆层和/或多于一层的颜料层能够分别被施用到膜10上。重要的是,根据本发明,在该至少一层清漆层被转移到图3、4和7各自所示出的更柔软的第二膜16上之前,要将该至少一层清漆层在聚丙烯膜上不完全固化。The embodiment shown in Figures 1 to 7 can be modified such that more than one paint layer can be applied and more than one varnish layer can be applied. For example, more than one varnish layer and/or more than one paint layer can be applied to the film 10 in the steps shown in FIGS. 1 and 2 and FIGS. 5 and 6 , respectively. Importantly, according to the present invention, before the at least one layer of varnish is transferred to the softer second film 16 shown in each of FIGS. Incomplete cure on film.

图8示出了一种用于实施制造能够用于将清漆和颜料施用到物体上的膜的上述两种方法的设备。根据图8,在底座30上布置有各种工作站以执行获得膜的必需步骤。FIG. 8 shows an apparatus for carrying out the two methods described above for producing films that can be used for applying varnishes and pigments to objects. According to FIG. 8 , various workstations are arranged on the base 30 to carry out the steps necessary to obtain the film.

供料圆筒32被设置用于提供已印刷好的第一膜10。例如,根据图1到4,第一膜10可以已经印刷有颜料层14。换句话说,图8中的供料圆筒32提供载有颜料层14的膜10。膜10经过辊34被送进清漆施用站36。在清漆施用站36中,清漆层12(参见图1)被施用到颜料层14上。清漆施用站36包括用于将清漆施用到膜上的辊36a、36b。这种施用辊子本身也是现有技术中公知的。或者,清漆施用站36可以包括例如象下面根据图9所描述的一组辊子。清漆供应装置36c也在图8中示意性的标出。A supply cylinder 32 is provided for supplying the printed first film 10 . For example, according to FIGS. 1 to 4 , the first film 10 may already be printed with a pigment layer 14 . In other words, the feed cylinder 32 in FIG. 8 provides the film 10 bearing the pigment layer 14 . The film 10 is fed to a varnish application station 36 via rollers 34 . In the varnish application station 36 , the varnish layer 12 (see FIG. 1 ) is applied onto the paint layer 14 . The varnish application station 36 includes rollers 36a, 36b for applying varnish to the film. Such application rollers are also known per se from the prior art. Alternatively, the varnish application station 36 may comprise, for example, a set of rollers as described below with respect to FIG. 9 . The varnish supply device 36c is also schematically indicated in FIG. 8 .

在该清漆施用站36中,清漆被施用到膜上以使膜被清漆完全覆盖,颜料层位于清漆层下面。通常清漆层具有在1到130μm之间的厚度。此后,膜被送进到加热站38,在该加热站中清漆被逐渐加热以使清漆更均匀的分布在膜上。为了加热,使用了红外线源38a。作为一个实例,可以在60℃至90℃将清漆加热10到15秒,不过该温度和加热时间可以根据需要变化。In this varnish application station 36 varnish is applied to the film so that the film is completely covered with varnish, the pigment layer being located underneath the varnish layer. Usually the varnish layer has a thickness of between 1 and 130 μm. Thereafter, the film is fed to a heating station 38 where the varnish is gradually heated to distribute the varnish more evenly on the film. For heating, an infrared source 38a is used. As an example, the varnish can be heated at 60°C to 90°C for 10 to 15 seconds, although the temperature and heating time can be varied as desired.

在经过加热站38之后,膜被送进到第一固化站40。第一固化站40包括更大的辊40a,在该辊上,膜按照图8中的从左手侧到右手侧被送进。紫外线源40b被径向相对于辊40a布置,用于不完全固化在膜10上的清漆。在一个优选的实施方案中,不完全固化可以通过施用50到80瓦/平方厘米的功率,或者如果清漆层足够薄时施用甚至小于50瓦/平方厘米的功率,来获得。辊40优选地通过水来冷却。After passing through the heating station 38 , the film is fed to a first curing station 40 . The first curing station 40 comprises a larger roller 40a on which the film is fed from the left hand side to the right hand side in FIG. 8 . A UV source 40b is arranged radially relative to the roller 40a for incomplete curing of the varnish on the film 10 . In a preferred embodiment, incomplete curing can be obtained by applying a power of 50 to 80 W/cm2, or even less than 50 W/cm2 if the layer of varnish is thin enough. Roller 40 is preferably cooled by water.

紫外线源被固定在滑架40c上,该滑架40c能够从在图中实线显示出的位置移动到虚线显示出的位置上。用实线显示出的左手侧位置是工作位置。The ultraviolet light source is fixed on a carriage 40c which can be moved from a position shown by a solid line to a position shown by a broken line in the figure. The left-hand position shown with a solid line is the working position.

在经过第一固化站40之后,载有不完全固化清漆的膜10a被送进到转移站44。根据使用的膜的材料,通过在辊之间施加1到2巴的压力和范围在120℃到180℃内的高温,借助于转移辊44a、44b促使清漆层和颜料层的转移。After passing through the first curing station 40 , the film 10 a loaded with partially cured varnish is fed to a transfer station 44 . The transfer of the varnish and pigment layers is induced by means of the transfer rollers 44a, 44b by applying a pressure of 1 to 2 bar between the rollers and a high temperature in the range of 120°C to 180°C, depending on the material of the film used.

用于供应第二膜16的供料圆筒42也靠近转移站44布置,以将第二膜供应至转移站。转移站44包括转移辊44a和44b以将清漆层和颜料层都从第一膜10a上转移到第二膜16上。如上文所阐明地,第二膜16比第一膜10a更柔软。由于第一膜10a具有脱膜性能,颜料层和不完全固化的清漆层可以通过脱膜技术从第一膜被转移到第二膜上。这种脱膜转移技术本身在该技术领域中公知。在转移之后,第一和第二膜都一起经由辊46和另一辊46a被送进到分离辊48。在分离辊48处,第一膜10从第二膜16a上分离,以使得载有颜料层和清漆层的第二膜16a被送进到第二固化站52,而第一膜10在收集辊50处被收集。A supply cylinder 42 for supplying the second film 16 is also arranged close to the transfer station 44 for supplying the second film to the transfer station. The transfer station 44 includes transfer rollers 44a and 44b to transfer both the varnish layer and the paint layer from the first film 10a to the second film 16 . As explained above, the second membrane 16 is more flexible than the first membrane 10a. Since the first film 10a has a release property, the pigment layer and the partially cured varnish layer can be transferred from the first film to the second film by a release technique. Such release transfer techniques are known per se in this technical field. After the transfer, both the first and second films are fed together to a separation roll 48 via roll 46 and another roll 46a. At the separation roller 48, the first film 10 is separated from the second film 16a, so that the second film 16a loaded with the pigment layer and the varnish layer is fed to the second curing station 52, while the first film 10 is on the collecting rollers. 50 were collected.

在第二固化站52内,通过紫外线灯52b提供的紫外线辐射,在第二膜16a上的清漆层被完全固化。紫外线灯被布置在滑架52c上,该滑架52c能够移动进入在图中用虚线指示的非工作位置。根据所使用的清漆,可以优选地通过施用120瓦/平方厘米来获得清漆的完全固化。作为紫外线固化的替换,在第二固化站52,第二固化步骤可以通过将热施用到膜上来完成。通常,当膜要被施用到具有复杂或不规则表面形状的物体上时采用热固化。在一个实施方案中,紫外线灯52被用于将热施加到膜16a上的红外线源替换。当然,用于将热施加到膜16a上的其他方法是在本发明的范围之内的。典型地,热源应该使膜层的温度增高到约90到140℃,不过根据膜层的成分,其它温度也可能是合适的。In the second curing station 52, the varnish layer on the second film 16a is completely cured by ultraviolet radiation provided by the ultraviolet lamp 52b. The UV lamps are arranged on a carriage 52c which can be moved into an inoperative position indicated by dotted lines in the figure. Depending on the varnish used, complete curing of the varnish may preferably be obtained by applying 120 W/cm2. As an alternative to UV curing, at the second curing station 52, a second curing step may be accomplished by applying heat to the film. Typically, thermal curing is employed when the film is to be applied to objects with complex or irregular surface shapes. In one embodiment, the ultraviolet lamp 52 is replaced by an infrared source for applying heat to the film 16a. Of course, other methods for applying heat to the film 16a are within the scope of the present invention. Typically, the heat source should raise the temperature of the film to about 90 to 140°C, although other temperatures may be suitable depending on the composition of the film.

清漆在第二固化站52内完全固化之后,完工的膜16c经由辊56被送进到收集圆筒58上。在连接圆筒58时,因为第二膜16也具有脱膜性能,所以成品可以随时装运至会使用通过脱膜技术来向物体上施用清漆和颜料的膜的消费者。After the varnish is fully cured in the second curing station 52 , the finished film 16c is fed via rollers 56 onto a collection cylinder 58 . When the cylinder 58 is attached, because the second film 16 also has release properties, the finished product is ready to ship to consumers who will use the film to apply varnishes and paints to objects by release techniques.

如图9所示,涉及将清漆层施用到如同上面所描述的膜上的替换实施方案包括涂料辊10和压紧辊112。压紧辊有时也称为“反作用辊(counter rollers)”。压紧辊112是不用操纵的;也就是说它不是动力驱动的并且可以自由旋转。定量给料辊114邻近涂料辊10布置,用于将清漆从供给源(未示出)传送到涂料辊110上。平面116与涂料辊110和压紧辊112都相切,也就是说,平面116在互相邻近的辊之间通过。在本发明的一个优选实施方案中,涂料辊110具有由例如象橡胶或类似的人造合成材料或天然聚合物等弹性材料制成的表面。在一个更优选地实施方案中,该弹性表面具有在大约30和80之间的肖氏A级硬度。As shown in FIG. 9 , an alternative embodiment involving the application of a varnish layer to a film as described above includes a coating roller 10 and a pinch roller 112 . The pinch rollers are also sometimes referred to as "counter rollers". The pinch roller 112 is hands-free; that is, it is not powered and is free to rotate. A dosing roller 114 is disposed adjacent to the applicator roller 10 for transferring varnish onto the applicator roller 110 from a supply (not shown). The plane 116 is tangent to both the coating roller 110 and the pressure roller 112 , that is to say, the plane 116 passes between mutually adjacent rollers. In a preferred embodiment of the invention, the applicator roller 110 has a surface made of an elastic material such as rubber or similar man-made synthetic material or natural polymer, for example. In a more preferred embodiment, the resilient surface has a Shore A hardness of between about 30 and 80.

具有脱膜性能的膜118在图中被从右手侧送进到左手侧。在一个实施方案中,脱膜性能可以被限定为膜具有在约30和42达因之间,或者更优选地在约35和40达因之间,以及最优选在约39和40达因之间的表面张力(或表面能)。这种表面张力可以通过选用天然具有这种表面张力的材料或者通过改变该表面张力的方法,例如通过电晕处理方法,来获得。如图中箭头146所标出的,涂料辊110绕其轴线120在逆时针方向上转动。压紧辊112绕其轴线122转动并以膜118被送进的速度被驱动。如图8中所示,涂料辊110和压紧辊112用常规驱动机构驱动。通常,涂料辊110和压紧辊112被布置为当膜118在辊之间通过时能够在膜118上施加一给定的压力。在优选实施方案中,涂料辊110和压紧辊112会施加给膜118约1至4巴之间的压力。The film 118 with release properties is fed from the right hand side to the left hand side in the figure. In one embodiment, the release properties may be defined as a film having a film of between about 30 and 42 dynes, or more preferably between about 35 and 40 dynes, and most preferably between about 39 and 40 dynes. The surface tension (or surface energy) between them. This surface tension can be obtained by selecting a material that naturally has this surface tension or by changing the surface tension, such as by corona treatment. Applicator roller 110 rotates about its axis 120 in a counterclockwise direction, as indicated by arrow 146 . The pinch roller 112 rotates about its axis 122 and is driven at the speed at which the film 118 is fed. As shown in FIG. 8, the applicator roll 110 and pinch roll 112 are driven using conventional drive mechanisms. Typically, applicator roller 110 and pinch roller 112 are arranged to exert a given pressure on film 118 as it passes between the rollers. In a preferred embodiment, applicator roll 110 and pinch roll 112 will apply a pressure to film 118 of between about 1 and 4 bars.

膜118经由辊124和126被导向为使得其在涂料辊和压紧辊之间被送进之前,膜118没有定位在切面116上,而是如图中所示地在膜118和切面116之间限定了一个角度α。该角度α是锐角,并且优选地在约10°至30°的范围内。Film 118 is directed via rollers 124 and 126 such that film 118 is not positioned on cut surface 116 but between film 118 and cut surface 116 as shown, before it is fed between the applicator roller and pinch roller. An angle α is defined between them. This angle α is acute and preferably in the range of about 10° to 30°.

如上所述,膜118按图中从右到左的方向送进。用于在方向142上牵引膜的牵引装置没有示出,不过在图中它们通常布置在涂料辊110和压紧辊112的左边。例如,一常规从动(driven)收集辊适于在方向142上牵引膜。As mentioned above, film 118 is fed in a direction from right to left in the drawing. The pulling means for pulling the film in direction 142 are not shown, but they are generally arranged to the left of coating roller 110 and pinch roller 112 in the figure. For example, a conventional driven collection roll is adapted to pull the film in direction 142 .

如图所示,清漆通过涂料辊110转移到膜118上,具体而言,是转移到膜118的上表面上。优选地,清漆是可通过通常所说的交联作用固化的,这本身是现有技术所公知的。例如,固化装置(未示出)可以布置在涂料辊110和压紧辊112的左边。As shown, the varnish is transferred by applicator roller 110 onto film 118 , and specifically, onto the upper surface of film 118 . Preferably, the varnish is curable by so-called crosslinking, which is known per se from the prior art. For example, a curing device (not shown) may be disposed on the left side of the coating roller 110 and the pinch roller 112 .

一清漆容器128被布置在压紧辊112的下面来收集没有用于涂在膜118上的多余清漆,例如,施用在膜118边缘的清漆。A varnish container 128 is disposed below pinch roller 112 to collect excess varnish not intended to be applied to film 118 , eg, varnish applied to the edges of film 118 .

一支座130,其支撑压紧辊112和涂料辊110,允许涂料辊110和压紧辊112在箭头132方向上转动,也就是说,涂料辊110和压紧辊112都能够绕在两个辊的中间处穿过轴线120和122的轴线A转动。由于图中显示了一穿过辊的中心横截面,所以轴线A也处在附图所示的平面中。通过绕轴线A在箭头方向132上的转动,在辊和膜118之间的相对布置和定位可以被调整从而避免褶皱。压紧辊112总是如图用箭头所示的逆时针方向转动。A support 130, which supports the pinch roller 112 and the paint roller 110, allows the paint roller 110 and the pinch roller 112 to rotate in the direction of the arrow 132, that is, the paint roller 110 and the pinch roller 112 can be wound around two The middle of the rollers rotates on axis A passing through axes 120 and 122 . Since the figure shows a central cross-section through the roller, the axis A also lies in the plane shown in the figure. By rotation about the axis A in the direction of the arrow 132, the relative arrangement and positioning between the roller and the film 118 can be adjusted so as to avoid wrinkles. The pinch roller 112 always rotates counterclockwise as indicated by the arrow.

如在该技术领域中本身已知的,可以布置涂料刀136、138,其可以是由聚烯烃材料制成的“软”刀,以用于控制清漆从定量给料辊到涂料辊的转移。如用箭头146、148所标出地,涂料辊110和定量给料辊114一般在相反的方向上转动。如该技术领域中所知的,传输到膜的清漆的量可以通过在涂料刀和辊之间的距离以及由涂料辊110和压紧辊112施加到膜上的压力来调整。Coating knives 136, 138, which may be "soft" knives made of polyolefin material, may be arranged, as known per se in the art, for controlling the transfer of varnish from the dosing roll to the coating roll. As indicated by arrows 146, 148, applicator roll 110 and doser roll 114 generally rotate in opposite directions. As is known in the art, the amount of varnish delivered to the film can be adjusted by the distance between the coating knife and the roller and the pressure applied to the film by the coating roller 110 and pinch roller 112 .

辊的典型尺寸如下:涂料辊110可以具有在180和300毫米之间的典型直径,优选地为约240毫米。压紧辊112可以具有相同的尺寸。定量给料辊114可以具有在100到200毫米的范围内的直径,优选地为约160毫米。定量给料辊114小于涂料辊。膜的宽度一般为160到180厘米。Typical dimensions of the roll are as follows: The coating roll 110 may have a typical diameter of between 180 and 300 mm, preferably about 240 mm. The pinch rollers 112 may have the same size. The dosing roller 114 may have a diameter in the range of 100 to 200 mm, preferably about 160 mm. The dosing roller 114 is smaller than the applicator roller. The width of the film is generally 160 to 180 cm.

软刀140被靠近清漆收集容器128布置以便于从压紧辊112上清除过量或未使用的清漆。A soft knife 140 is disposed adjacent to the varnish collection container 128 to facilitate removal of excess or unused varnish from the pinch roll 112 .

如上文所描述的,膜118在箭头142的方向上送进。膜118穿过在涂料辊110和压紧辊112之间的间隙144。Film 118 is advanced in the direction of arrow 142 as described above. Film 118 passes through gap 144 between applicator roller 110 and pressure roller 112 .

在一个实施方案中,涂料辊110的旋转方向146和旋转速度被控制为使得邻近膜118的涂料辊110的圆周,即实际上将清漆转移到膜上的涂料辊的圆周,在相对于膜的运动相反的方向上运动。因此,涂料辊110的圆周表面具有一个相对于膜118的速度沿相反方向上的速度。也就是说,在一个(运动)坐标系统中,其中膜118是静止的,传送清漆到膜上的涂料辊110的圆周表面相对于膜以一不为零的速度运动。最优选地,在一个静止(不运动)的坐标系统(即图中的坐标系统)内,涂料辊110具有在图中用箭头146标示的逆时针方向转动的圆周表面。定量给料辊114在与涂料辊110的转动方向相反的方向上转动,即定量给料辊114沿顺时针方向转动。In one embodiment, the direction of rotation 146 and the speed of rotation of the coating roller 110 are controlled such that the circumference of the coating roller 110 adjacent to the film 118, i.e. the circumference of the coating roller that actually transfers the varnish to the film, Movement in the opposite direction of movement. Accordingly, the peripheral surface of the applicator roller 110 has a velocity in the opposite direction relative to the velocity of the film 118 . That is, in a (moving) coordinate system in which the film 118 is stationary, the peripheral surface of the applicator roller 110 delivering the varnish onto the film moves at a non-zero velocity relative to the film. Most preferably, in a stationary (non-moving) coordinate system (ie, the coordinate system in the figure), applicator roller 110 has a circumferential surface that rotates in a counterclockwise direction, indicated by arrow 146 in the figure. The dosing roller 114 rotates in a direction opposite to that of the applicator roller 110, ie, the dosing roller 114 rotates in a clockwise direction.

速度的典型实例如下:膜118在方向142上的送进的速率(速度)可以在1-50米/分钟的范围内,且更优选地在10-20米/分钟的范围内。如果膜118的送进速率(速度)是20米/分钟,涂料辊10的优选转动速度是使其表面速度为110米/分钟的速度。一般而言,如果膜118的速度X相对较快,例如超过约15米/分钟,则涂料辊的转动速度是使其表面速度在X的30-70%范围内的速度。当膜的速度相对较快时,则辊筒和膜的速度在同一方向上,即膜在方向142上被送进而且涂料辊沿顺时针方向旋转。另一方面,如果膜118的送进速率(速度)相对较慢,例如在1-5米/分钟的范围内,则涂料辊可以以5-10米/分钟的表面速度在箭头146的方向上逆时针旋转。根据拟被施用到膜上的清漆涂层的具体需要,特别是清漆的厚度和清漆的性能,调整该速度。Typical examples of speeds are as follows: The rate (speed) of feeding of the film 118 in direction 142 may be in the range of 1-50 m/min, and more preferably in the range of 10-20 m/min. If the feed rate (velocity) of the film 118 is 20 m/min, the preferred rotational speed of the coating roller 10 is such that its surface speed is 110 m/min. In general, if the film 118 velocity X is relatively fast, eg, greater than about 15 m/min, the applicator roll is rotated at such a velocity that its surface velocity is in the range of 30-70% of X. When the film speed is relatively fast, then the roll and film speeds are in the same direction, ie the film is fed in direction 142 and the applicator roll rotates in a clockwise direction. On the other hand, if the feed rate (velocity) of the film 118 is relatively slow, for example in the range of 1-5 m/min, the coating roller can be moved in the direction of arrow 146 at a surface speed of 5-10 m/min. Anticlockwise rotation. This speed is adjusted according to the specific needs of the varnish coating to be applied to the film, in particular the thickness of the varnish and the properties of the varnish.

根据拟施用到膜118上的清漆层的厚度,涂料辊110也可以以小于膜118在箭头142的方向上的送进速度的圆周速度沿顺时针方向(即与箭头146相反)转动。例如,如果膜118在箭头142方向上的送进速度是10米/分钟,则通过将涂料辊110在顺时针方向上(与箭头146相反)的圆周速度调整到3米/分钟和7米/分钟之间、以使得涂料辊的圆周和膜之间以相应的更低相对速度的方式施用更厚的层。Depending on the thickness of the varnish layer to be applied to the film 118, the applicator roller 110 may also rotate in a clockwise direction (ie opposite to the arrow 146) at a peripheral speed that is less than the feed speed of the film 118 in the direction of arrow 142. For example, if the feeding speed of the film 118 in the direction of the arrow 142 is 10 m/min, then by adjusting the peripheral speed of the coating roller 110 in the clockwise direction (opposite to the arrow 146) to 3 m/min and 7 m/min Thicker layers are applied between minutes, in such a way that there is a correspondingly lower relative speed between the circumference of the coating roller and the film.

如附图中示出的,通过在涂料辊110和定量给料辊114之间如何供给清漆150,可以控制施用到膜118上的清漆的量。通过调整在定量给料辊114和涂料辊110之间的压力和/或在涂料辊110和定量给料辊114之间的相对速度,能够可变地控制通过涂料辊110施用到膜118上的清漆量。如果只有非常少量的清漆将被施用到膜上,即相对较薄的清漆层被施用到膜118上,则定量给料辊114可以在与涂料辊110相反的方向上旋转。这用双箭头148标出。As shown in the figures, by how the varnish 150 is fed between the applicator roll 110 and the dosing roll 114, the amount of varnish applied to the film 118 can be controlled. By adjusting the pressure between the dosing roller 114 and the applicator roller 110 and/or the relative speed between the applicator roller 110 and the dosing roller 114, the amount of water applied to the film 118 by the applicator roller 110 can be variably controlled. Amount of varnish. If only a very small amount of varnish is to be applied to the film, ie a relatively thin layer of varnish is applied to the film 118 , the dosing roller 114 may rotate in the opposite direction to the coating roller 110 . This is marked with double arrow 148 .

使用上面描述的设备,清漆层能够被施用膜118上,该清漆层比用现有技术的机器能够施用的厚度更厚,例如,可沿膜118的宽度和长度等厚度地施用具有在120μm到130μm范围内厚度的清漆层。具有脱膜性能和涂有具有在上述范围内的厚度的清漆层的膜118是非常适于以清漆层极度均匀的方式将清漆施用到一物体上,特别是在边缘区域。清漆层内的裂纹和类似的缺陷被消除到大大好于在现有技术的程度。Using the equipment described above, a varnish layer can be applied on the film 118 that is thicker than can be applied with prior art machines, e.g. Varnish layer with a thickness in the range of 130 μm. A film 118 having release properties and coated with a varnish layer having a thickness within the above-mentioned range is very suitable for applying varnish to an object in an extremely uniform manner of the varnish layer, especially in edge regions. Cracks and similar defects in the varnish layer are eliminated to a much better extent than in the prior art.

虽然就施用清漆层描述了本发明,但除清漆之外,本发明的范围还可包括施用其他涂覆材料。同样,如本文所使用的,术语“速度”是一个具有大小和方向的矢量。因此,如果膜118在第一方向上以5米/分钟的速度运动,并且在第二方向上的涂料辊110的圆周速率是5米/分钟,则膜118和涂料辊110的速度应当被认为是不同的。Although the invention has been described in terms of applying a layer of varnish, the scope of the invention also includes the application of other coating materials in addition to varnish. Also, as used herein, the term "velocity" is a vector having magnitude and direction. Thus, if the film 118 is moving at a speed of 5 m/min in a first direction, and the peripheral velocity of the applicator roller 110 in a second direction is 5 m/min, the speeds of the film 118 and applicator roller 110 should be considered is different.

Claims (28)

1. one kind is used to make the equipment that can be used to varnish and pigment are administered to the film on the object, and described equipment comprises:
A. be used for the varnish that layer of varnish is administered on first film is used the station, described first film has demoulding performance;
B. be used for solidifying by halves first curing station of described layer of varnish;
C. be used to supply with the feed cylinder of second film, described second film is more soft than described first film;
D. be used for described at least layer of varnish being transferred to transfer station on second film from described first film by the demoulding technology; With
E. be used for further solidifying second curing station of described layer of varnish.
2. according to the equipment of claim 1, it is characterized in that described first film comprises coat of colo(u)r.
3. according to the equipment of claim 1 or 2, it is characterized in that a heating station is disposed in described varnish and uses between station and described first curing station.
4. according to the equipment of claim 1, it is characterized in that described first film is made by polypropylene.
5. according to the equipment of claim 1, it is characterized in that described second film is made by polyolefin, polypropylene or polyvinyl chloride (PVC).
6. according to the equipment of claim 1, it is characterized in that described first curing station comprises ultraviolet source.
7. according to the equipment of claim 1, it is characterized in that described second curing station comprises ultraviolet source.
8. a manufacturing can be used in the method that varnish and pigment is administered to the film on the object, and described method comprises step:
A. coat of colo(u)r is administered on first film, described first film has demoulding performance;
B. layer of varnish is administered on the described coat of colo(u)r on described first film;
C. solidify described layer of varnish by halves;
D. by the demoulding technology described layer of varnish and coat of colo(u)r are transferred to from described first film on second film with demoulding performance, wherein said second film is more soft than described first film; And
E. further be solidificated in the layer of varnish that has been transferred on described second film.
9. method according to Claim 8 is characterized in that, described first film is made by polypropylene.
10. method according to Claim 8 is characterized in that, described second film is made by polyolefin, polypropylene or polyvinyl chloride (PVC).
11. method according to Claim 8 is characterized in that, described incomplete curing is implemented by ultraviolet source.
12. method according to Claim 8 is characterized in that, described further curing is implemented by ultraviolet source.
13. method according to Claim 8 is characterized in that, described step is to implement on the continuous length of film as a continuous process.
14. method according to Claim 8 is characterized in that, described layer of varnish and coat of colo(u)r are applied on described first film and second film, and do not use remover.
15. method according to Claim 8 is characterized in that, described first film has the surface energy of about 35 to 40 dyne.
16. method according to Claim 8 is characterized in that, before using described coat of colo(u)r, adhesive layer is administered on described first film.
17. the method according to claim 16 is characterized in that, bottom is applied to described adhesive layer.
18. one kind is administered to equipment on the film with varnish, described equipment comprises:
A. be used for varnish is transferred to coating roll on the film from coating roll;
B. the hold-down roller that contiguous described coating roll is arranged;
C. be used for sending the device of described film to by the gap between described coating roll and described hold-down roller with first speed; With
D. be used to rotate described coating roll so that the device that the circumference of the coating roll of contiguous described film moves with the second speed that is different from described first speed.
19. equipment according to claim 18, it is characterized in that, the described device that is used to send to described film is sent described film to by the slit on first direction, and the described device that is used to rotate described coating roll rotates this coating roll so that the coating roll of adjacent membrane moves upward in the second party opposite with first direction.
20. the equipment according to claim 18 or 19 is characterized in that, before entering described slit, a described film and a plane limit a non-vanishing angle (α), and described plane and coating roll and hold-down roller are all tangent.
21. each the equipment according in the claim 18 to 20 is characterized in that described coating roll comprises elastic surface.
22. each the equipment according in the claim 18 to 21 is characterized in that, is provided with to be used for moving at least one device of described hold-down roller or coating roll on the direction that is parallel to a plane, described plane and coating roll and hold-down roller are all tangent.
23. one kind is administered to equipment on the film with coating material, described equipment comprises:
A. be oriented to the coating roll that contacts with the coating material source;
B. close on the hold-down roller that described coating roll is arranged;
C. advance by the film in the gap between described coating roll and described hold-down roller with first speed; And
D. wherein the circumference of the described coating roll of contiguous described film moves with the second speed that is different from described first speed.
24. the equipment according to claim 23 is characterized in that, described first speed and described second speed are created in the relative velocity between about 10 and 20 meters/minute.
25. the equipment according to claim 21 is characterized in that, the described elastic surface of described coating roll has the hardness of the Shore A level between about 30 and 80.
26. the equipment according to claim 21 is characterized in that, described elastic surface comprises elastomeric material.
27., it is characterized in that described coating roll and described hold-down roller are at the pressure that is applied on the described film between about 1 and 4 crust according to the equipment of claim 18.
28. one kind is used for varnish is administered to method on the film, described method comprises the steps:
A. the coating roll that provides contiguous hold-down roller to arrange;
B. use a certain amount of varnish to described coating roll;
C. between described coating roll and described hold-down roller, send film with first speed to;
D. rotate the circumference of described coating roll with the second speed that is different from described first speed;
E. be used to rotate described coating roll so that the device that the circumference of the coating roll of contiguous described film moves with the second speed that is different from described first speed.
CNA2005800127730A 2004-02-23 2005-02-22 Apparatus and process for manufacturing a film for applying varnish and colour onto an object Pending CN1946571A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US54673604P 2004-02-23 2004-02-23
US60/546,736 2004-02-23
PCT/US2005/005522 WO2005081915A2 (en) 2004-02-23 2005-02-22 Apparatus and process for manufacturing a film for applying varnish and colour onto an object

Publications (1)

Publication Number Publication Date
CN1946571A true CN1946571A (en) 2007-04-11

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CN (1) CN1946571A (en)
WO (1) WO2005081915A2 (en)

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CN102555415A (en) * 2011-12-30 2012-07-11 西安交通大学 Method for coating protective film on grating scale for machine tool measurement
CN110895355A (en) * 2018-08-22 2020-03-20 通用汽车环球科技运作有限责任公司 Intelligent multifunctional lens coating

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CN115497371B (en) * 2022-10-17 2024-11-26 福建省三源兴纺织科技有限公司 A micro-prismatic holographic anti-counterfeiting film and its preparation process

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DK0455849T3 (en) * 1990-05-08 1993-03-22 Polytrend Ges Fuer Polymere We Method and apparatus for applying a color decoration to a plastic substrate and a decorated plastic substrate
EP0573676B1 (en) * 1992-05-19 1998-07-29 MZI/ M. ZAHER Institut für Oberflächensysteme und Verfahrenstechnik Use of a carrier with release properties for the application of lacquer and dyestuff to a substrate
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CN102555415A (en) * 2011-12-30 2012-07-11 西安交通大学 Method for coating protective film on grating scale for machine tool measurement
CN102555415B (en) * 2011-12-30 2014-08-06 西安交通大学 Method for coating protective film on grating scale for machine tool measurement
CN110895355A (en) * 2018-08-22 2020-03-20 通用汽车环球科技运作有限责任公司 Intelligent multifunctional lens coating

Also Published As

Publication number Publication date
WO2005081915A3 (en) 2006-04-06
EP1732769A4 (en) 2009-07-01
WO2005081915A2 (en) 2005-09-09
EP1732769A2 (en) 2006-12-20

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