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CN1818208B - Paper conveying felt and press device of paper machine with the paper conveying felt - Google Patents

Paper conveying felt and press device of paper machine with the paper conveying felt Download PDF

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Publication number
CN1818208B
CN1818208B CN2006100032402A CN200610003240A CN1818208B CN 1818208 B CN1818208 B CN 1818208B CN 2006100032402 A CN2006100032402 A CN 2006100032402A CN 200610003240 A CN200610003240 A CN 200610003240A CN 1818208 B CN1818208 B CN 1818208B
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Prior art keywords
paper
layer
press
batt
wet paper
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Expired - Fee Related
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CN1818208A (en
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大内隆司
井上健二
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Ichikawa Woolen Textile Co Ltd
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Ichikawa Woolen Textile Co Ltd
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    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21FPAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F3/00Press section of machines for making continuous webs of paper
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21FPAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F7/00Other details of machines for making continuous webs of paper
    • D21F7/08Felts
    • D21F7/083Multi-layer felts
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21FPAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F7/00Other details of machines for making continuous webs of paper
    • D21F7/08Felts
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S162/00Paper making and fiber liberation
    • Y10S162/90Papermaking press felts
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/30Woven fabric [i.e., woven strand or strip material]
    • Y10T442/3707Woven fabric including a nonwoven fabric layer other than paper
    • Y10T442/378Coated, impregnated, or autogenously bonded
    • Y10T442/3789Plural nonwoven fabric layers

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  • Paper (AREA)

Abstract

A paper transporting felt includes a base layer, a first batt layer formed on a wet paper side surface of the base layer, a second batt layer formed on a press side surface of the base layer, a polymer elastic material impregnated in the base layer, the first batt layer and the second batt layer, and a wet paper contacting layer which is formed on a wet paper side surface of the first batt layer so as to come into direct contact with a wet paper, and includes a flexible resin material. The compressibility of the wet paper contacting layer is larger than that of a layer formed of the base layer, the first batt layer and the second batt layer.

Description

纸输送毛毯及具有该纸输送毛毯的造纸机的压榨装置Paper conveying felt and press device of paper machine with the paper conveying felt

相关申请的交叉引用 Cross References to Related Applications

本申请基于并要求于2005年2月7日提交的在先日本专利申请第2005-030300号的优先权,其全部内容结合于此作为参考。 This application is based upon and claims the benefit of priority from prior Japanese Patent Application No. 2005-030300 filed on February 7, 2005, the entire contents of which are hereby incorporated by reference. the

技术领域technical field

本发明涉及一种纸输送毛毯及具有该纸输送毛毯的造纸机的压榨装置。The invention relates to a paper conveying felt and a press device of a paper machine provided with the paper conveying felt.

背景技术Background technique

通常,造纸机包括金属网部、压榨部、及干燥部。该金属网部、压榨部、及干燥部以沿湿纸输送方向的顺序排布。湿纸通过设于金属网部、压榨部、及干燥部中的湿纸传输件被顺次传输,同时将水分从湿纸中挤压出,最后湿纸在干燥部的干燥帆布(用作纸输送件)上被干燥。设置于压榨部中的压榨装置包括沿湿纸输送方向连续排列的多个压榨机构。Typically, a paper machine includes a wire section, a press section, and a dryer section. The wire mesh section, the press section, and the drying section are arranged in order along the wet paper transport direction. The wet paper is sequentially transported through the wet paper conveying parts in the wire mesh section, the press section, and the drying section. Conveyors) are dried. The pressing device arranged in the pressing section includes a plurality of pressing mechanisms arranged continuously along the wet paper conveying direction.

每个压榨机构包括:一对纸输送毛毯,其具有环形带状;以及一对辊(即辊式压榨)或者辊与靴形件(即靴形压榨),其作为彼此纵向相对的压榨件,从而将该对纸输送毛毯的一部分夹持在其间。通过使得该对辊或者辊与靴形件压榨与纸输送毛毯一起以相同的速度沿相同的方向由纸输送毛毯输送行进的湿纸,水分从湿纸中 被挤出并且由纸输送毛毯吸收。造纸机分为辊式压榨型造纸机和靴形压榨型造纸机,其中,辊式压榨型造纸机中,在压榨部设置有压榨装置,该压榨装置在辊与辊之间夹持和压榨夹持湿纸的纸输送毛毯的一部分。而靴形压榨型造纸机中,在压榨部设置有压榨装置,该压榨装置在辊与靴形件之间夹持和压榨夹持湿纸的纸输送毛毯的一部分。特别地,由于靴形压榨型造纸机与应用更为广泛的辊式压榨型造纸机相比,具有更大的压榨件的压榨部分(即压区)的压榨区,由此可延长压榨时间。因此,靴形压榨型造纸机可以具有更优良的脱水性。Each press mechanism comprises: a pair of paper conveying felts, which have an endless belt shape; and a pair of rollers (i.e., a roll press) or a roller and shoe (i.e., a shoe press) as press members longitudinally opposed to each other, A part of the pair of paper conveying felts is thereby sandwiched therebetween. By having the pair of rollers or rollers and shoes press the wet paper traveling by the paper conveying felt at the same speed and in the same direction as the paper conveying felt, moisture is squeezed out of the wet paper and absorbed by the paper conveying felt. The paper machine is divided into a roll press type paper machine and a shoe press type paper machine. Among them, in the roll press type paper machine, a pressing device is provided in the press section, and the pressing device clamps and presses the nip between the rolls. Part of the paper transport felt that holds the wet paper. On the other hand, in the shoe press type papermaking machine, a press device is provided in the press section, and the press device pinches and presses a part of the paper conveying felt that pinches the wet paper between the roll and the shoe. In particular, since the shoe press type papermaking machine has a larger press area of the press section (ie the nip) of the press elements than the more widely used roll press type papermaking machine, the press time can thus be extended. Therefore, the shoe press type paper machine can have more excellent dewatering properties.

在造纸机中,由压榨装置的纸输送毛毯输送的湿纸通过连续布置的多个压榨机构的纸输送毛毯被顺次输送,同时从中挤压出水,然后湿纸表面被平滑化。由此,纸输送毛毯须具有传送湿纸的功能,从湿纸中压挤出水的功能,将湿纸从纸输送毛毯上平滑地分离以将湿纸送至下一工序(换句话说,使湿纸容易从纸输送毛毯剥离)的纸分离功能,以及平滑湿纸表面的湿纸表面平滑化功能。尤其是,由于大量的水分通过设置于沿压榨部的湿纸输送方向的上游侧的压榨机构从湿纸中被挤出,因此对于设置于沿湿纸输送方向的下游侧的压榨机构的纸输送毛毯来说,更为重要的功能是湿纸表面平滑化功能,而非从湿纸挤压水的功能。In the paper machine, the wet paper conveyed by the paper conveying felt of the press device is sequentially conveyed through a plurality of paper conveying felts of the press mechanism arranged in succession, while water is squeezed out therefrom, and then the surface of the wet paper is smoothed. Therefore, the paper conveying felt must have the function of conveying the wet paper, the function of squeezing water out of the wet paper, and smoothly separating the wet paper from the paper conveying felt to send the wet paper to the next process (in other words, The paper separation function to make the wet paper easy to peel off from the paper conveying felt, and the wet paper surface smoothing function to smooth the surface of the wet paper. In particular, since a large amount of moisture is squeezed out from the wet paper through the press mechanism arranged on the upstream side in the wet paper conveying direction of the press section, the paper conveyance of the press mechanism arranged on the downstream side in the wet paper conveying direction For felts, the more important function is the smoothing function of the wet paper surface than the function of squeezing water from the wet paper.

在覆盖压榨机构的压榨部的中央到其出口的部分上,由于施加于湿纸及纸输送毛毯上的压力突然地释放,因而在该部分上纸输送毛毯及湿纸的体积急剧膨胀。结果是,在纸输送毛毯及湿纸上产生负压,并且由于湿纸由微细纤维构成,会发生毛细管现象,由此导致被纸输送毛毯吸收的水分再次向湿纸转移的再湿现象。这样,覆盖压榨机构的压榨部的中央到其出口的部分成为造纸机的压榨装置的脱水性能下降的重要因素。On the portion covering the center of the press section of the press mechanism to its outlet, since the pressure applied to the wet paper and paper conveying felt is released suddenly, the volume of the paper conveying felt and wet paper expands rapidly at this portion. As a result, a negative pressure is generated on the paper conveying felt and the wet paper, and since the wet paper is composed of fine fibers, capillary phenomenon occurs, thereby causing a rewetting phenomenon in which moisture absorbed by the paper conveying felt is transferred to the wet paper again. In this way, the portion covering the center of the press section of the press mechanism to the outlet thereof becomes an important factor for dehydrating the dewatering performance of the press device of the paper machine.

作为用于防止在压榨时纸输送毛毯的再湿现象及起泡(blowing)现象的纸输送毛毯,已知有一种纸输送毛毯,其用乳化树脂浸渍且对其湿纸侧部分进行了集中研究(参见美国专利第4,500,588号)。更具体而言,在纸输送毛毯中,通过用乳化树脂浸渍在基层的表面上形成的毛层(batt layer),同时对该毛层的湿纸侧表面进行压延加工以形成麂皮状的致密且平滑的表面从而形成阻挡层,或者用乳化树脂浸渍在基层的表面上形成的粗纤维层,以在该粗纤维层上形成阻挡层(无纺布纤维层),且在该阻挡层(无纺布纤维层)上形成细纤维层。因此,由于该阻挡层阻止了乳化树脂浸透到纸输送毛毯的湿纸侧表面,故可防止纸输送毛毯的再湿及起泡,并且由此可提高造纸速度。另外,当纸输送毛毯与湿纸一起在压榨机构的压榨部中被压榨时,可以减少阻碍湿纸表面平滑化的因素,其中,包含在纸输送毛毯内的空气从湿纸侧表面被挤出以粗糙化湿纸表面。As a paper conveying felt for preventing the rewetting phenomenon and the blowing phenomenon of the paper conveying felt at the time of pressing, there is known a paper conveying felt which is impregnated with an emulsified resin and whose wet paper side portion has been intensively studied (See US Patent No. 4,500,588). More specifically, in a paper conveying felt, a batt layer formed on the surface of a base layer is impregnated with an emulsified resin, while calendering is performed on the wet paper side surface of the batt layer to form a suede-like dense and a smooth surface to form a barrier layer, or to impregnate the thick fiber layer formed on the surface of the base layer with an emulsified resin to form a barrier layer (non-woven fabric fiber layer) on the thick fiber layer, and to form a barrier layer (non-woven fiber layer) on the barrier layer (without A fine fiber layer is formed on the spun fiber layer). Therefore, since the barrier layer prevents the emulsified resin from permeating to the wet paper side surface of the paper conveying felt, rewetting and foaming of the paper conveying felt can be prevented, and thus the papermaking speed can be increased. In addition, factors hindering the smoothing of the surface of wet paper can be reduced when the paper conveying felt is pressed together with wet paper in the press section of the press mechanism, in which air contained in the paper conveying felt is squeezed out from the wet paper side surface To roughen the surface of wet paper.

另外,还已知有一种在其表面上设置有液体不渗透层的纸输送毛毯(参见德国实用新型申请公开第DE 29706427 U1号)。该纸输送毛毯具有包括热塑性纤维或熔融纤维的纤维层,通过对纤维层的表面加热,使热塑性纤维或熔融纤维熔融以形成液体不渗透层。In addition, a paper conveying felt provided with a liquid-impermeable layer on its surface is also known (see German Utility Model Application Publication No. DE 29706427 U1). The paper conveying felt has a fiber layer including thermoplastic fibers or fused fibers which are melted by heating the surface of the fiber layer to form a liquid-impermeable layer.

另外,已知有一种纸输送毛毯,其中,面向湿纸的树脂层表面上具有向上开口的间隙(参见专利文献3)。在纸输送毛毯中,为了改善耐磨性、隔离性、及耐压强度,通过溶剂去除性物质(具体说是溶剂去除性纤维)的溶解而在面向湿纸的聚合物树脂层中形成多个开口槽,从而通过多个开口槽利用形成于面向湿纸的聚合物树脂层(更具体说是固化聚合物树脂层)中的间隙而获得水渗透性。In addition, there is known a paper conveying felt in which the surface of the resin layer facing the wet paper has gaps opening upward (see Patent Document 3). In paper conveying felts, in order to improve abrasion resistance, release properties, and compressive strength, a plurality of layers are formed in the polymer resin layer facing the wet paper by dissolving solvent-removable substances (specifically, solvent-removable fibers). Open grooves, whereby water permeability is obtained by utilizing gaps formed in the wet paper-facing polymer resin layer (more specifically, the cured polymer resin layer) through the plurality of open grooves.

美国专利第4,500,588号、德国实用新型申请公开第DE29706427 U1号、以及JP-A-62-21895号作为现有技术被参照。US Patent No. 4,500,588, German Utility Model Application Publication No. DE29706427 U1, and JP-A-62-21895 are referred to as prior art.

安装于顺序排布的多个压榨机构上的纸输送毛毯具有不同的主要功能。对于在多个压榨机构中安装在设置于沿湿纸输送方向的上游侧的压榨机构上的纸输送毛毯主要要求从湿纸挤压水的功能,而对于安装在设置于沿湿纸输送方向的下游侧的压榨机构上的纸输送毛毯主要要求平滑化湿纸表面的功能。即,湿纸的表面平滑度主要取决于安装在设置于多个压榨机构中沿湿纸输送方向的下游侧的压榨机构上的纸输送毛毯。由此,安装在设置于多个压榨机构中沿湿纸输送方向的下游侧的压榨机构上的纸输送毛毯须具有面向湿纸的光滑表面。然而,由于输入到设置在多个压榨机构中沿湿纸输送方向的下游侧的压榨机构中的湿纸中含有少许水分,因此优选地,安装在设置于下游侧的压榨机构上的纸输送毛毯须具有或多或少的脱水性。Paper transport felts mounted on multiple press units arranged in series have different primary functions. The function of squeezing water from the wet paper is mainly required for the paper conveying felt installed on the press mechanism arranged on the upstream side along the wet paper conveying direction among the plurality of press mechanisms, while for the paper conveying felt installed on the press mechanism arranged on the upstream side along the wet paper conveying direction The paper conveying felt on the press mechanism on the downstream side mainly requires the function of smoothing the wet paper surface. That is, the surface smoothness of the wet paper mainly depends on the paper conveying felt installed on the press mechanism disposed on the downstream side in the wet paper conveying direction among the plurality of press mechanisms. Thus, the paper conveying felt installed on the press mechanism disposed on the downstream side in the wet paper conveying direction among the plurality of press mechanisms must have a smooth surface facing the wet paper. However, since the wet paper input to the press mechanism arranged on the downstream side in the wet paper conveying direction among the plurality of press mechanisms contains a little moisture, it is preferable that the paper conveying felt installed on the press mechanism arranged on the downstream side Must be more or less dehydrating.

湿纸中所含的水分通过在压榨机构的压榨部中被压缩和复原的纸输送毛毯所吸收及挤出。即,为了有效地挤压出水,纸输送毛毯需要有适当的透气性、压缩性、及复原性。The moisture contained in the wet paper is absorbed and squeezed out by the paper conveying felt which is compressed and restored in the press section of the press mechanism. That is, in order to effectively squeeze out water, the paper transfer felt needs to have appropriate air permeability, compressibility, and recovery.

在造纸机的压榨装置中,尤其是在靴形压榨型造纸机或单压区型造纸机的压榨装置中,由于压榨件的压榨部(即,压区)对纸输送毛毯实施了非常大的压力以挤压水,所以直接接触压榨件的压榨部的纸输送毛毯的毛层容易损伤并且由此纸输送毛毯的寿命(即纸输送毛毯的可使用时间)缩短。由此,需要定期更换纸输送毛毯的维护。In the press arrangement of a paper machine, especially in a shoe press type paper machine or a single nip type paper machine, due to the press section (i.e. the nip) of the press element exerts a very large force on the paper transport felt. The pressure is to squeeze the water, so the batt layer of the paper conveying felt directly in contact with the press section of the press is easily damaged and thus the life of the paper conveying felt (ie, the usable time of the paper conveying felt) is shortened. For this reason, the maintenance of periodic replacement|exchange of a paper conveyance felt is required.

另外,在造纸机的压榨装置中,由于压榨部(即压区)的高压力和高摩擦,直接接触湿纸的纸输送毛毯的毛层上的纤维严重脱落(纤维损失)或者断落。这些脱落或者断落的纤维的大多数通过诸如喷水器及吸水箱的清扫单元而排出压榨装置,然而,一些纤维可能粘附在湿纸的表面。由于脱落或断落的纤维比湿纸的纤维粗而且硬,所以由粘附脱落或断落纤维的湿纸而制成的纸(即纸产品)的 印刷性差(具体地说,是印刷时会造成脱色)。由此,由于从直接与湿纸接触的纸输送毛毯的毛层的表面上脱落的纤维的原因,造成诸如印刷品的纸制品的品质恶化。另外,由于脱落的纤维使得湿纸侧毛层的表面变得粗糙,所以其成为湿纸表面平滑度降低的因素。In addition, in the press device of the paper machine, due to the high pressure and high friction of the press section (ie, the nip), the fibers on the batt layer of the paper conveying felt that directly contacts the wet paper are seriously shed (fiber loss) or broken off. Most of these shed or broken fibers exit the press through cleaning units such as water jets and suction boxes, however, some fibers may adhere to the surface of the wet paper. Since the fibers that fall off or fall off are thicker and harder than those of wet paper, paper (i.e., paper products) made of wet paper to which fibers fall off or fall off is adhered has poor printability (specifically, when printing cause discoloration). As a result, the quality of paper products such as printed matter deteriorates due to the fibers that come off from the surface of the batt layer of the paper conveying felt that directly contacts the wet paper. In addition, since the detached fibers roughen the surface of the wet paper side batt, it becomes a factor of lowering the smoothness of the wet paper surface.

然而,很难仅仅将构成与湿纸直接接触的纸输送毛毯的毛层的表面的纤维替换为细纤维。特别地,作为制造纸输送毛毯的一道工序,当细纤维在针刺工序的前一个工序被切割时(在针刺工序前执行切割操作,在切割操作后通过针刺生成纤维网片),容易生成纤维块(即纤维的块)。由此,通过在切割操作后立即针刺,会在毛毯上形成纤维块,这样就在纸输送毛毯的表面上形成相对较大的凹凸不匀,从而使湿纸的表面平滑度下降。However, it is difficult to replace only the fibers constituting the surface of the batt layer of the paper conveying felt which is in direct contact with wet paper with fine fibers. In particular, as a process for manufacturing a paper conveying felt, when fine fibers are cut in a process preceding the needling process (cutting operation is performed before the needling process, and a fiber web is generated by needling after the cutting operation), it is easy Fibrous clumps (ie clumps of fibers) are generated. Thus, fiber lumps are formed on the felt by needling immediately after the cutting operation, so that relatively large irregularities are formed on the surface of the paper conveying felt, thereby degrading the surface smoothness of the wet paper.

美国专利第4,500,588号公开了一种其湿纸侧表面被处理的纸输送毛毯,这种纸输送毛毯具有优良的表面平滑度和不渗水性(即,使得水不从湿纸侧表面进入到压榨侧表面的能力),但从湿纸挤压水的性能较差。因此,不能期望这样的纸输送毛毯具有从湿纸脱水的高性能,所以最好使用湿纸的脱水是完全通过设置于沿湿纸输送方向的上游侧的压榨机构来进行的纸输送毛毯。换句话说,美国专利第4,500,588号中公开的湿纸侧表面进行过压延工序的纸输送毛毯可优选地安装于连续排布的多个压榨机构中的设置于沿湿纸输送方向的下游侧的压榨装置上。然而,由于作为下道工序的在干燥部中的加热和干燥工序需要大量的热能,所以在压榨部中把湿纸中的水尽可能的去除掉很重要。因此,安装在设置于多个压榨机构中沿湿纸输送方向的下游侧的压榨机构上的纸输送毛毯更加优选地具有或多或少的从湿纸挤压出水的功能。在美国专利第4,500,588号中公开的纸输送毛毯(其中,在面向基层的粗纤维层与面向湿纸的细纤维之间夹设有无纺纤维层,并具有纤维块)不适于用作这样的造纸机的压榨装置,其中对纸输送毛毯要求具有很高从湿纸挤压水的能力。U.S. Patent No. 4,500,588 discloses a paper conveying felt whose wet paper side surface is treated. side surface), but poor performance in squeezing water from wet paper. Therefore, such a paper conveying felt cannot be expected to have high performance of dewatering from wet paper, so it is preferable to use a paper conveying felt in which dewatering of wet paper is performed entirely by a pressing mechanism arranged on the upstream side in the wet paper conveying direction. In other words, the paper conveying felt disclosed in U.S. Patent No. 4,500,588, in which the calendering process is performed on the wet paper side surface, may be preferably installed in a plurality of press mechanisms arranged in series on the downstream side in the wet paper conveying direction. on the pressing device. However, it is important to remove as much water as possible from the wet paper in the press section because the heating and drying process in the dryer section as a subsequent process requires a large amount of thermal energy. Therefore, the paper conveying felt installed on the press mechanism disposed on the downstream side in the wet paper conveying direction among the plurality of press mechanisms more preferably has a function of squeezing water from the wet paper more or less. The paper conveying felt disclosed in U.S. Patent No. 4,500,588 (wherein a non-woven fiber layer is interposed between a coarse fiber layer facing the base layer and fine fibers facing the wet paper, and has fiber masses) is not suitable for use as such Press units of paper machines where a high capacity to squeeze water from wet paper is required on the paper transfer felt.

在德国实用新型申请公开第DE 29706427 U1中公开的纸输送毛毯中,通过加热含有热塑性纤维或者熔融纤维的纤维层表面以熔融热塑性纤维或熔融纤维而形成液体不渗透层。纸输送毛毯具有通过调节从纤维层表面施加的热量,从而可在一定程度上控制液体不渗透层的厚度的特征。然而,由于需要在不会使加热表面,即,液体不渗透层的表面的纤维特性恶化的范围内加热,通过加热,纸输送毛毯的深度(即液体不渗透层的厚度)受考虑到热塑性纤维或熔融纤维的热劣化或热分解而受限。由此,液体不渗透层的厚度会自动受到限制从而不会太厚。另外,由于湿纸侧表面包括纤维层,通过压榨部,非常大的压力或摩擦力施加于该纤维上,从而纤维层表面的纤维的脱落或断落(即纤维损失)显著发生。纸输送毛毯中与湿纸直接接触的纤维层的表面的纤维损失使诸如印刷品的纸制品的品质恶化。另一方面,由于纤维损失,纤维层表面变得粗糙,所以湿纸的表面平滑度显著降低。In the paper conveying felt disclosed in German Utility Model Application Publication No. DE 29706427 U1, the liquid-impermeable layer is formed by heating the surface of the fiber layer containing thermoplastic fibers or molten fibers to melt the thermoplastic fibers or molten fibers. Paper transport felts are characterized by the ability to control the thickness of the liquid impermeable layer to some extent by adjusting the amount of heat applied from the surface of the fibrous layer. However, since it is necessary to heat within a range that does not deteriorate the fiber properties of the heated surface, that is, the surface of the liquid-impermeable layer, the depth of the paper conveying felt (i.e., the thickness of the liquid-impermeable layer) is limited by heating in consideration of the thermoplastic fiber Or the thermal deterioration or thermal decomposition of the molten fiber is limited. Thereby, the thickness of the liquid-impermeable layer is automatically limited so as not to be too thick. In addition, since the wet paper side surface includes a fiber layer, very large pressure or frictional force is applied to the fibers by the press section, so that detachment or breaking of fibers on the surface of the fiber layer (ie, fiber loss) occurs significantly. Fiber loss at the surface of the fibrous layer in the paper transport felt that is in direct contact with the wet paper deteriorates the quality of paper products such as printed matter. On the other hand, due to fiber loss, the surface of the fiber layer becomes rough, so the surface smoothness of the wet paper is significantly reduced.

在专利文献3中公开的纸输送毛毯中,因为通过溶剂除去性物质(具体为溶剂除去性纤维)的溶解而在面向湿纸的聚合物树脂层的表面上形成有细长间隙,所以脱水的性能没有变化。然而,当增加溶剂除去性物质的用量时,会影响湿纸的表面平滑度。另外,在溶剂除去性物质溶解后,由于用作加强物质的溶剂除去性物质从面向湿纸的聚合物树脂层中被去除,所以耐压缩性恶化。In the paper conveying felt disclosed in Patent Document 3, since elongated gaps are formed on the surface of the polymer resin layer facing wet paper by the dissolution of solvent-removable substances (specifically, solvent-removable fibers), the dehydration There is no change in performance. However, when the amount of the solvent-removing substance is increased, the surface smoothness of the wet paper is affected. In addition, since the solvent-removable substance serving as a reinforcing substance is removed from the polymer resin layer facing the wet paper after the solvent-removable substance is dissolved, compression resistance deteriorates.

发明内容Contents of the invention

本发明的目的在于提供一种纸输送毛毯,其由压榨机构的压榨件的压榨引起的损坏小,并且具有优良的耐久性、合适的脱水性、以及优良的湿纸表面平滑性能,本发明的目的还在于提供一种具有该纸输送毛毯的造纸机的压榨装置。An object of the present invention is to provide a paper conveying felt which is less damaged by the pressing of the pressing member of the pressing mechanism and has excellent durability, suitable dehydration, and excellent wet paper surface smoothness. It is also an object to provide a press arrangement of a paper machine having such a paper transport felt.

本发明提供了一种纸输送毛毯,其为设置于造纸机的压榨部中的压榨装置中的一对纸输送毛毯中的至少一个纸输送毛毯,其与压榨装置中的压榨件一起构成了压榨机构,在夹持湿纸并通过所述压榨件对其加压的同时进行输送,其具有:基层;第一毛层,其形成于基层的湿纸侧表面上;第二毛层,其形成于基层的压榨侧表面上;聚合物弹性材料,浸渍在基层、第一毛层、以及第二毛层中;以及湿纸接触层,形成于第一毛层的湿纸侧表面以便与湿纸直接接触,而且其包括柔软性树脂材料,其中,湿纸接触层的可压缩性大于由基层、第一毛层、以及第二毛层所形成的层的可压缩性。The present invention provides a paper conveying felt, which is at least one of a pair of paper conveying felts arranged in a press device in a press section of a paper machine, which together with a press member in the press device constitutes a press A mechanism for conveying wet paper while clamping and pressing it by the pressing member, having: a base layer; a first batt layer formed on the wet paper side surface of the base layer; a second batt layer formed on the press side surface of the base layer; a polymer elastic material impregnated in the base layer, the first batt layer, and the second batt layer; and a wet paper contact layer formed on the wet paper side surface of the first batt layer so as to contact the wet paper direct contact, and comprising a flexible resinous material, wherein the wet paper contact layer is more compressible than the layer formed by the base layer, the first batt layer, and the second batt layer.

在纸输送毛毯中,树脂材料包括发泡树脂或者中空的颗粒状树脂。In the paper conveying felt, the resin material includes foamed resin or hollow granular resin.

在纸输送毛毯中,在10kg/cm2的压力下,湿纸接触层的可压缩性与由基层、第一毛层、以及第二毛层形成的层的可压缩性之间的差值大于或等于5%。In a paper conveying felt, under a pressure of 10 kg/cm 2 , the difference between the compressibility of the wet paper contact layer and the layer formed by the base layer, the first batt layer, and the second batt layer is greater than Or equal to 5%.

本发明也提供了具有上述纸输送毛毯的造纸机的压榨装置。The present invention also provides a press apparatus for a paper machine having a paper transport felt as described above.

本发明也提供了造纸机的压榨装置,其具有多个压榨机构,每个压榨机构具有纸输送毛毯,其中多个压榨机构沿由纸输送毛毯输送的湿纸输送方向连续设置。The present invention also provides a press device of a paper machine, which has a plurality of press mechanisms each having a paper conveying felt, wherein the plurality of press mechanisms are continuously arranged along a wet paper conveying direction conveyed by the paper conveying felt.

在造纸机的压榨装置中,前述纸输送毛毯设置于多个压榨机构中的沿输送方向的下游侧设置的压榨机构中。In a press apparatus of a paper machine, the aforementioned paper conveying felt is provided in a press mechanism provided on a downstream side in a conveying direction among a plurality of press mechanisms.

造纸机的前述压榨装置可以是靴形压榨型造纸机的压榨装置,其中压榨装置的压榨件是靴形压榨件,其具有压榨纸输送毛毯的辊及靴形件。The aforementioned press of the paper machine may be a press of a shoe press type paper machine, wherein the press of the press is a shoe press having a roll of a press paper conveying felt and a shoe.

造纸机的前述压榨装置可以是辊形压榨型造纸机的压榨装置,其中压榨装置的压榨件是辊形压榨件,其具有一对辊形压榨件以压榨纸输送毛毯。The aforementioned press of the paper machine may be a press of a roll press type paper machine, wherein the press of the press is a roll press having a pair of roll presses to press the paper delivery felt.

在纸输送毛毯中,基层、第一毛层、以及第二毛层包括聚合物弹性材料,并且湿纸接触层由柔软性树脂材料形成。由此,由于基层、第一毛层、以及第二毛层包括如合成树脂的聚合物弹性材料,所以基层及第二毛层具有很高的机械强度以对抗压榨机构的压榨件的压榨。因此,即使纸输送毛毯由压榨件的压榨部强力地压榨时,纸输送毛毯也很少受损,从而纸输送毛毯具有优良的耐久性。结果是由于纸输送毛毯的寿命延长,更换纸输送毛毯的频率可以减少。另外,由于由柔软性树脂材料制成的湿纸接触层具有比由基层、第一毛层、以及第二毛层形成的层更大的可压缩性,与由基层、第一毛层、以及第二毛层形成的层相比,湿纸接触层具有适当的压缩、复原性,故可以从湿纸中吸收水分。另外,由于湿纸接触层完全不产生纤维脱落现象,因此改善了湿纸的表面平滑度。另外,由于湿纸接触层不会脱落纤维,纸输送毛毯的使用寿命(即纸输送毛毯的使用期)延长,并且可以减少更换的频率。In the paper conveying felt, the base layer, the first batt layer, and the second batt layer include a polymer elastic material, and the wet paper contact layer is formed of a flexible resin material. Thus, since the base layer, the first batt layer, and the second batt layer include polymer elastic material such as synthetic resin, the base layer and the second batt layer have high mechanical strength against being pressed by the pressing member of the pressing mechanism. Therefore, even when the paper conveying felt is strongly pressed by the press portion of the press member, the paper conveying felt is rarely damaged, so that the paper conveying felt has excellent durability. As a result, the frequency of replacement of the paper transfer felt can be reduced due to the extended life of the paper transfer felt. In addition, since the wet paper contact layer made of flexible resin material has greater compressibility than the layer formed by the base layer, the first batt layer, and the second batt layer, it is different from the layer formed by the base layer, the first batt layer, and the Compared with the layer formed by the second batt layer, the wet paper contact layer has appropriate compression and recovery properties, so it can absorb moisture from the wet paper. In addition, since the wet paper contact layer does not generate fiber shedding at all, the surface smoothness of the wet paper is improved. In addition, since the wet paper contact layer does not shed fibers, the service life of the paper conveying felt (ie, the lifespan of the paper conveying felt) is extended, and the frequency of replacement can be reduced.

在纸输送毛毯中,由于形成湿纸接触层的树脂材料包含发泡树脂或中空的颗粒状树脂,湿纸接触层具有平滑且有多孔的内部组织。这样,纸输送毛毯适度地缓冲而且具有脱水的能力,从而可以使湿纸的表面平滑。In the paper conveying felt, since the resin material forming the wet paper contact layer contains foamed resin or hollow granular resin, the wet paper contact layer has a smooth and porous internal structure. In this way, the paper conveying felt is moderately cushioned and has the ability to dewater, so that the surface of the wet paper can be smoothed.

在纸输送毛毯中,在10kg/cm2的压力下,由于纸输送毛毯的湿纸接触层的可压缩性与由基层、第一毛层、以及第二毛层形成的层的可压缩性之间的差值大于或等于5%,所以湿纸接触层具有适度的压缩、复原性。另外,该纸输送毛毯更适合用于压榨装置的输送方向的下游上。In a paper conveying felt, under a pressure of 10 kg/cm 2 , due to the difference between the compressibility of the wet paper contact layer of the paper conveying felt and the compressibility of the layer formed by the base layer, the first batt layer, and the second batt layer The difference between them is greater than or equal to 5%, so the wet paper contact layer has moderate compression and recovery. In addition, the paper transport felt is more suitable for use downstream in the transport direction of the press.

聚合物弹性材料可以是如水性聚氨脂树脂、水性丙烯酸树脂、水性环氧树脂、以及水性合成橡胶(即水性乳化树脂)的合成树脂。这样的聚合物弹性材料浸渍在基层、第一毛层、以及第二毛层,然后被加热以及固化。The polymer elastic material may be a synthetic resin such as water-based polyurethane resin, water-based acrylic resin, water-based epoxy resin, and water-based synthetic rubber (ie, water-based emulsified resin). Such a polymer elastic material is impregnated in the base layer, the first batt layer, and the second batt layer, and then heated and cured.

由于造纸机的压榨装置包括造纸输送带,故可获得上述的优良操作优点。The above-mentioned good operating advantages are obtained because the press unit of the paper machine includes a paper machine belt.

另外,当包括多个具有前述纸输送毛毯的压榨机构的造纸机的压榨装置、多个压榨机构沿由纸输送毛毯输送湿纸的方向连续设置时,水可从湿纸中高效脱出,并且湿纸表面可被适度地平滑,从而可高速地进行造纸作业。In addition, when the press apparatus of the paper machine including a plurality of press mechanisms having the aforementioned paper conveying felt, the plurality of press mechanisms are successively arranged in the direction in which the wet paper is conveyed by the paper conveying felt, water can be extracted from the wet paper efficiently, and the wet The paper surface can be moderately smoothed, so that papermaking can be performed at high speed.

另外,当纸输送毛毯在多个压榨机构中沿输送方向下游侧设置的压榨机构中设置时,可以考虑渗水性稍稍小于具有更小含量的聚合物弹性材料的纸输送毛毯,但由于有更优良的湿纸表面平滑化功能,所以可提高湿纸的表面平滑度,而且可高速进行造纸作业。In addition, when the paper conveying felt is provided in a press mechanism disposed on the downstream side in the conveying direction among a plurality of press mechanisms, it is considered that the water permeability is slightly lower than that of a paper conveying felt having a smaller content of polymer elastic material, but since there is a more excellent Excellent wet paper surface smoothing function, so the surface smoothness of wet paper can be improved, and papermaking can be performed at high speed.

在所示的压榨型造纸机的压榨装置中,由于通过使用靴形压榨型造纸机的压榨装置,压榨部的压榨区域(即辊与靴形件之间形成的压区)被加宽,从而可延长压榨时间,因此可以改善脱水性能以及湿纸表面的平滑度。In the press apparatus of the press type paper machine shown, since the press area of the press section (i.e., the nip formed between the roll and the shoe) is widened by using the press apparatus of the shoe press type paper machine, thereby The pressing time can be extended, so the dewatering performance and the smoothness of the wet paper surface can be improved.

在辊形压榨型造纸机的压榨装置中,即使使用辊压榨型造纸机的压榨装置,也可以获得与前述一样的优良的操作优点。In the press apparatus of the roll press type papermaking machine, even if the press apparatus of the roll press type papermaking machine is used, the same excellent operational advantages as described above can be obtained.

因此,可以提供一种由压榨机构的压榨件的压榨引起的损伤小,并且具有优良的耐久性、适当的脱水性、且湿纸的表面平滑性能优良的纸输送毛毯,以及具有该纸输送毛毯的造纸机的压榨装置。Therefore, it is possible to provide a paper conveying felt that causes little damage due to the pressing of the pressing member of the pressing mechanism, has excellent durability, appropriate dehydration, and has excellent surface smoothness of wet paper, and has the paper conveying felt. The press device of the paper machine.

以上对本发明进行了简洁的说明。通过参照附图对用于实施本发明的最佳方式的描述,本发明将会更加明了。The present invention has been briefly described above. The present invention will be more apparent by describing the best mode for carrying out the invention with reference to the accompanying drawings.

附图说明Description of drawings

图1是示出根据本发明实施例的纸输送毛毯的纵向截面图;以及1 is a longitudinal sectional view showing a paper conveying felt according to an embodiment of the present invention; and

图2是示意性示出根据本发明实施例的造纸机的压榨装置的结构的平面图。Fig. 2 is a plan view schematically showing the structure of a press device of a paper machine according to an embodiment of the present invention.

具体实施方式Detailed ways

下面,参照附图对根据本发明的多个优选实施例进行详细说明。Hereinafter, several preferred embodiments according to the present invention will be described in detail with reference to the accompanying drawings.

图1是示出根据本发明实施例的纸输送毛毯的纵向截面图(纸输送毛毯100),图2是示意性示出根据本发明实施例的纸输送毛毯的结构的平面图。1 is a longitudinal sectional view (paper conveying felt 100) showing a paper conveying felt according to an embodiment of the present invention, and FIG. 2 is a plan view schematically showing the structure of the paper conveying felt according to an embodiment of the present invention.

如图1所示,纸输送毛毯100包括基层11、毛层13(第一毛层13A以及第二毛层13B),以及湿纸接触层25。具体而言,在基层11的湿纸侧表面上形成第一毛层13A,在基层11的压榨件侧表面(具体为朝向一对辊中的一个或者辊及靴形件中的一个的表面)上形成第二毛层13B,并且湿纸接触层25形成于第一毛层13A的湿纸侧表面上,从而湿纸接触层25直接与湿纸接触。基层11及毛层13(第一毛层13A以及第二毛层13B)通过针刺操作彼此缠结以形成一体。As shown in FIG. 1 , the paper conveying felt 100 includes a base layer 11 , a batt layer 13 (a first batt layer 13A and a second batt layer 13B), and a wet paper contact layer 25 . Specifically, the first batt layer 13A is formed on the wet paper side surface of the base layer 11, and the press member side surface of the base layer 11 (specifically, the surface facing one of the pair of rollers or one of the roller and the shoe) The second batt layer 13B is formed on the first batt layer 13A, and the wet paper contact layer 25 is formed on the wet paper side surface of the first batt layer 13A so that the wet paper contact layer 25 directly contacts the wet paper. The base layer 11 and the batt layer 13 (the first batt layer 13A and the second batt layer 13B) are entangled with each other by a needling operation to be integrated.

基层11用于对纸输送毛毯100赋予强度并且其可适当地由织布制成,该织布由诸如具有优良的耐磨性、耐疲劳性、拉伸性、及防火性的尼龙6(即N6)及尼龙66(即N66)的合成纤维,或者诸如羊毛、由线材料重叠而非纺织制成的布、或者制成薄片形布等的天然纤维组成。在本实施例中,织布被用于基层11。The base layer 11 is used to impart strength to the paper conveying felt 100 and it may suitably be made of a woven fabric such as Nylon 6 (i.e. N6) and nylon 66 (ie N66) synthetic fibers, or natural fibers such as wool, cloth made of overlapping thread materials rather than woven, or made into sheet-shaped cloth. In this embodiment, woven cloth is used for the base layer 11 .

毛层13(第一毛层13A以及第二毛层13B)是由大小为6分特或更大(一般为17分特左右)的人造纤维17形成的非分隔纤维层(non-split fiber layer)。形成毛层13的材料可适当包含与基层11相同的材料。第二毛层13B可以取决于纸输送毛毯100所需要的特性而予以省略。The wool layer 13 (the first wool layer 13A and the second wool layer 13B) is a non-split fiber layer (non-split fiber layer) formed by artificial fibers 17 with a size of 6 decitex or more (generally about 17 decitex). ). The material forming the batt layer 13 may suitably include the same material as that of the base layer 11 . The second batt layer 13B may be omitted depending on the desired properties of the paper transfer felt 100 .

基层11、第一毛层13A、以及第二毛层13B在其纤维中或在人造纤维17之间的空间中包含有聚合物弹性材料23。聚合物弹性材料23的实例可以包括如水性聚氨脂树脂、水性丙烯酸树脂、水性环氧树脂、以及水性合成橡胶(即水性乳化树脂)等的合成树脂。通过辊子或涂布机刮刀的使用或者通过喷射器的使用在其上喷射聚合物弹性材料而在第二毛层13B的表面(在图1中为下表面)上涂抹聚合物弹性材料23,从而将这样的聚合物弹性材料23渗到第二毛层13B、基层11、以及第一毛层13A中,然后通过使用热风使其干燥和固化。由于基层11、第一毛层13A、以及第二毛层13B包含有聚合物弹性材料23,构成基层11、第一毛层13A、及第二毛层13B的纤维的交织点相互之间和聚合物弹性材料23结合,从而稳定了形状并且提高了机械强度。即,甚至当纸输送毛毯100在压榨机构的压榨部压榨时,也不会长时间扁平并且其密度及透气性随时间的变化小,趋于稳定。The base layer 11 , the first batt layer 13A, and the second batt layer 13B contain a polymer elastic material 23 in the fibers thereof or in spaces between the artificial fibers 17 . Examples of the polymer elastic material 23 may include synthetic resins such as water-based polyurethane resin, water-based acrylic resin, water-based epoxy resin, and water-based synthetic rubber (ie, water-based emulsion resin). The polymer elastic material 23 is spread on the surface (lower surface in FIG. 1 ) of the second batt layer 13B by use of a roller or a coater blade or by spraying the polymer elastic material thereon by use of a sprayer, thereby Such a polymer elastic material 23 is impregnated into the second batt layer 13B, the base layer 11, and the first batt layer 13A, and then dried and cured by using hot air. Since the base layer 11, the first wool layer 13A, and the second wool layer 13B contain the polymer elastic material 23, the interlacing points of the fibers constituting the base layer 11, the first wool layer 13A, and the second wool layer 13B are mutually compatible with each other. The bioelastic material 23 is combined, thereby stabilizing the shape and improving the mechanical strength. That is, even when the paper conveying felt 100 is pressed in the press section of the press mechanism, it is not flattened for a long time and its density and air permeability tend to be stable with little change over time.

湿纸接触层25由形成于第一毛层13A的湿纸侧表面上的柔软性树脂层形成。形成树脂层的树脂材料例如是包括发泡树脂、中空微小颗粒状树脂等的树脂材料,并使得树脂层柔软。湿纸接触层25的可压缩性大于由基层11、第一毛层13A、及第二毛层13B形成的纸输送毛毯100的部分(层)的可压缩性。The wet paper contact layer 25 is formed of a flexible resin layer formed on the wet paper side surface of the first batt layer 13A. The resin material forming the resin layer is, for example, a resin material including foamed resin, hollow fine particle resin, etc., and makes the resin layer soft. The compressibility of the wet paper contact layer 25 is greater than that of the portion (layer) of the paper transfer felt 100 formed by the base layer 11, the first batt layer 13A, and the second batt layer 13B.

更具体地说,湿纸接触层25的可压缩性在25%至40%范围之间,并且优选地在30%至35%之间。另一方面,由基层11、第一毛层13A、及第二毛层13B形成的纸输送毛毯100的该部分(层)的可压缩性范围从20%到35%之间,并且优选地在25%到30%。More specifically, the compressibility of the wet paper contact layer 25 ranges between 25% and 40%, and preferably between 30% and 35%. On the other hand, the compressibility of the portion (layer) of the paper conveying felt 100 formed by the base layer 11, the first batt layer 13A, and the second batt layer 13B ranges from 20% to 35%, and is preferably between 25% to 30%.

可压缩性由使用压板测试机(未示出)获得,纸输送毛毯100的测试件在2kg/cm2的初始压力下加压然后压力增加到10kg/cm2,同时每经过一次加压通过光学显微镜的图像输出测量湿纸接触层25以及由基层11、第一毛层13A、及第二毛层13B形成的纸输送毛毯100的该部分(层)的每一次厚度。然后通过把测量的厚度代入如下的表达式而得到可压缩性。对纸输送毛毯100的多个测试件中的每一个都进行前述的同样测试。另外,在前述测试中,初始压力施加于测试件上,从而通过使测试件的表面平滑,测量厚度不会出错。Compressibility was obtained using a platen tester (not shown), a test piece of the paper conveying felt 100 was pressurized at an initial pressure of 2 kg/cm 2 and then the pressure was increased to 10 kg/cm 2 while passing through the optical The image output of the microscope measures each thickness of the wet paper contact layer 25 and the portion (layer) of the paper conveying felt 100 formed by the base layer 11, the first batt layer 13A, and the second batt layer 13B. The compressibility is then obtained by substituting the measured thickness into the following expression. Each of the plurality of test pieces of the paper transfer felt 100 was subjected to the same tests as previously described. In addition, in the foregoing test, an initial pressure is applied to the test piece so that by smoothing the surface of the test piece, the measurement of thickness will not be erroneous.

计算可压缩性的表达式如下。The expression for calculating the compressibility is as follows.

可压缩性(%)=(t1-t2/t1)×100Compressibility (%)=(t1-t2/t1)×100

(其中t1是在10kg/cm2的压力下测试件的厚度,而t2是在2kg/cm2的压力测试件的厚度)(where t1 is the thickness of the test piece under a pressure of 10kg/ cm2 , and t2 is the thickness of the test piece under a pressure of 2kg/ cm2 )

另外,在上述测试中,即使是纸输送毛毯100本身的测试件作为测试件,也很难测量出湿纸接触层以及由基层11、第一毛层13A、及第二毛层13B形成的纸输送毛毯100的该部分(层)的单独的厚度。更具体地说,仅仅对纸输送毛毯100分层,对于湿纸接触层25以及由基层11、第一毛层13A、及第二毛层13B形成的纸输送毛毯100的部分(层),很难分别得到具有均匀厚度的测试件。In addition, in the above test, even if the test piece of the paper conveying felt 100 itself is used as a test piece, it is difficult to measure the wet paper contact layer and the paper formed by the base layer 11, the first batt layer 13A, and the second batt layer 13B. The individual thickness of the portion (layer) of the felt 100 is conveyed. More specifically, only layering the paper conveying felt 100 is very difficult for the wet paper contact layer 25 and the portion (layer) of the paper conveying felt 100 formed by the base layer 11, the first batt layer 13A, and the second batt layer 13B. It is difficult to respectively obtain a test piece having a uniform thickness.

发泡树脂由如水性聚氨脂树脂、水性丙烯酸树脂、以及水性环氧树脂等发泡或通过在树脂中混合发泡剂从而使树脂内混合多个 微细的气泡而形成。湿纸接触层25含有多个微细的气泡27,从而具有高度的柔软性以及平滑的表面。The foamed resin is formed by foaming such as water-based polyurethane resin, water-based acrylic resin, and water-based epoxy resin, or by mixing a foaming agent in the resin to mix a plurality of fine bubbles in the resin. The wet paper contact layer 25 contains a large number of fine air cells 27 and has a high degree of flexibility and a smooth surface.

含有中空微小颗粒状树脂的树脂通过在包含水性聚氨脂树脂、水性丙烯酸树脂、以及水性环氧树脂的树脂中混合如热膨胀性微胶囊等中空微小颗粒状树脂而形成。热膨胀性微胶囊是在包含有液态气体的聚合物壁壳中所产生的微小塑性球体(例如平均粒径为10~17μm),并且是中空球状微粒,通过加热到80~190℃,其体积膨胀大致40倍左右。由此,湿纸接触层25含有多个气泡27。含有热膨胀性微胶囊的湿纸接触层25具有改善的柔软性、表面平滑性、以及尺寸稳定性。“EXPANCEL”(商标;由日本ferrite有限公司制造)可以作为热膨胀性微胶囊的示例。The resin containing the hollow fine particle resin is formed by mixing a hollow fine particle resin such as thermally expandable microcapsules with a resin containing water-based polyurethane resin, water-based acrylic resin, and water-based epoxy resin. Thermally expandable microcapsules are tiny plastic spheres (for example, with an average particle size of 10-17 μm) produced in a polymer shell containing liquid gas, and are hollow spherical particles that expand in volume when heated to 80-190 °C About 40 times or so. Thus, the wet paper contact layer 25 contains a plurality of air cells 27 . The wet paper contact layer 25 containing heat-expandable microcapsules has improved softness, surface smoothness, and dimensional stability. "EXPANCEL" (trademark; manufactured by Nippon Ferrite Co., Ltd.) can be exemplified as heat-expandable microcapsules.

测量具有上述结构的纸输送毛毯100的典型实例的各构成要件的基重:湿纸接触层25的基重为200g/m2,第一毛层13A的基重为400g/m2,基层11的基重为650g/m2,第二毛层13B的基重为100g/m2。聚合物弹性材料23分别向基层11、第一毛层13A、以及第二毛层13B浸渍5wt%,并且不向湿纸接触层25浸渍。The basis weights of the constituent elements of the typical example of the paper conveying felt 100 having the above-mentioned structure were measured: the basis weight of the wet paper contact layer 25 was 200 g/m 2 , the basis weight of the first batt layer 13A was 400 g/m 2 , the base layer 11 The basis weight of the second batt layer 13B is 650 g/m 2 , and the basis weight of the second batt layer 13B is 100 g/m 2 . The polymer elastic material 23 impregnates the base layer 11 , the first batt layer 13A, and the second batt layer 13B by 5 wt % respectively, and does not impregnate the wet paper contact layer 25 .

测量纸输送毛毯100的一个轻质实例的各构成要件的基重:湿纸接触层25的基重为100g/m2,第一毛层13A的基重为200g/m2,基层11的基重为200g/m2,而第二毛层13B省略。聚合物弹性材料23分别向基层11及第一毛层13A浸渍1wt%,并且不向湿纸接触层25浸渍。The basis weights of the constituent elements of a lightweight example of the paper delivery felt 100 were measured: the basis weight of the wet paper contact layer 25 was 100 g/m 2 , the basis weight of the first batt layer 13A was 200 g/m 2 , the basis weight of the base layer 11 was The weight is 200g/m 2 , and the second batt layer 13B is omitted. The polymer elastic material 23 impregnates 1 wt % into the base layer 11 and the first batt layer 13A respectively, and does not impregnate into the wet paper contact layer 25 .

测量纸输送毛毯100的一个重质实例的各构成要件的基重:湿纸接触层25的基重为300g/m2,第一毛层13A的基重为800g/m2,基层11的基重为1500g/m2,且第二毛层13B的基重为300g/m2。聚合物弹性材料23分别向基层11、第一毛层13A、以及第二毛层13B浸渍10wt%,并且不向湿纸接触层25浸渍。The basis weight of each constituent element of a heavy example of the paper transfer felt 100 was measured: the basis weight of the wet paper contact layer 25 was 300 g/m 2 , the basis weight of the first batt layer 13A was 800 g/m 2 , the basis weight of the base layer 11 was The weight was 1500 g/m 2 , and the basis weight of the second batt layer 13B was 300 g/m 2 . The polymer elastic material 23 impregnates 10 wt % into the base layer 11 , the first batt layer 13A, and the second batt layer 13B respectively, and does not impregnate into the wet paper contact layer 25 .

简要说明制造纸输送毛毯100的方法。首先,在织布基层11的两面通过针刺等方法与毛层13整体地形成。在使用用于形成湿纸接触层25的发泡树脂的情况下,湿纸接触层25(即树脂层)通过在第一毛层13A的湿纸侧表面上涂覆发泡树脂然后干燥而形成。其间,在使用包含用于形成湿纸接触层25的热膨胀性微胶囊的树脂的情况下,湿纸接触层25(即树脂层)通过在第一毛层13A的湿纸侧表面上涂覆包含热膨胀性微胶囊的树脂,通过加热及干燥而膨胀该热膨胀性微胶囊而形成。A method of manufacturing the paper conveying felt 100 will be briefly described. First, both sides of the woven base layer 11 are integrally formed with the fleece layer 13 by methods such as needle punching. In the case of using a foamed resin for forming the wet paper contact layer 25, the wet paper contact layer 25 (ie, resin layer) is formed by coating the foamed resin on the wet paper side surface of the first batt layer 13A and then drying . Meanwhile, in the case of using a resin containing heat-expandable microcapsules for forming the wet paper contact layer 25, the wet paper contact layer 25 (i.e., resin layer) is coated on the wet paper side surface of the first batt layer 13A containing The resin of the heat-expandable microcapsules is formed by expanding the heat-expandable microcapsules by heating and drying.

其次,通过辊子或涂布机(涂覆机)刮刀的使用或者通过喷射器的使用而在其上喷射聚合物弹性材料将聚合物弹性材料23涂抹到第二毛层13B的表面(在图1中的底表面)上,因此,聚合物弹性材料23浸渍到第二毛层13B、基层11、以及第一毛层13A中,然后通过使用热风使其干燥和固化。在基层11、第一毛层13A、及第二毛层13B中浸渍的聚合物弹性材料23的量根据装配有纸输送毛毯100的压榨机构所需的特性而加以适当选择。Next, the polymer elastic material 23 is applied to the surface of the second batt layer 13B (in FIG. On the bottom surface in), therefore, the polymer elastic material 23 is impregnated into the second batt layer 13B, the base layer 11, and the first batt layer 13A, and then dried and cured by using hot air. The amount of the polymer elastic material 23 impregnated in the base layer 11, the first batt layer 13A, and the second batt layer 13B is appropriately selected according to the required characteristics of the press mechanism equipped with the paper conveying felt 100.

因此,形成了具有优良的耐久性、较小压缩性和复原性的基层11、第一毛层13A、以及第二毛层13B;以及与基层11、第一毛层13A、以及第二毛层13B相比具有更大的压缩性和复原性的湿纸接触层25。Therefore, the base layer 11, the first batt layer 13A, and the second batt layer 13B having excellent durability, less compressibility, and recovery are formed; The wet paper contact layer 25 has greater compressibility and recovery than 13B.

为了获得对于要被制造的不同种类的纸张,具有最佳性能纸输送毛毯100,形成基层11及毛层13的纤维的各自种类、形成湿纸接触层25的树脂材料的种类及量、以及聚合物弹性材料23的种类及浸渍量,要在考虑到对于各种情况或其组合时的特性而适当地加以选择。In order to obtain optimum performance for the different types of paper to be manufactured, the respective types of fibers forming the base layer 11 and the batt layer 13, the type and amount of the resin material forming the wet paper contact layer 25, and the polymerization The type and impregnation amount of the bioelastic material 23 are appropriately selected in consideration of characteristics for each case or a combination thereof.

接下来,将参照图2对装配有环形带状的纸输送毛毯100的造纸机(靴形压榨型造纸机)的压榨装置300进行说明。Next, a press device 300 of a paper machine (shoe press type paper machine) equipped with an endless belt-shaped paper conveying felt 100 will be described with reference to FIG. 2 .

如图2所示,压榨装置300被称作封闭牵引式压榨装置300,其中两个机构,即第一压榨机构51及第二压榨机构53沿湿纸W的输送方向(箭头A所示的方向)连续地排列。通过使用封闭牵引式造纸机,其中湿纸W以夹入两对纸输送毛毯100之间的状态被输送并且被压榨,其可以1200到1400m/min的高速稳定地输送湿纸W。由此,与开放牵引式造纸机相比,可以有更高的效率。As shown in Figure 2, the press device 300 is called a closed traction press device 300, in which two mechanisms, namely the first press mechanism 51 and the second press mechanism 53, are aligned along the conveying direction of the wet paper W (the direction shown by the arrow A). ) are arranged consecutively. By using a closed-draw type paper machine in which wet paper W is conveyed in a state sandwiched between two pairs of paper conveying felts 100 and pressed, it can stably convey wet paper W at a high speed of 1200 to 1400 m/min. Thereby, higher efficiencies are possible compared to open-draw paper machines.

第一压榨机构51包括一对纸输送毛毯100以及第一靴形件55和第一辊57(换句话说,第一靴形压榨件),其彼此相对以在其间形成第一压区(换句话说,第一压榨部)。第二压榨机构53包括一对纸输送毛毯100以及第二靴形件59和第二辊61(换句话说,第二靴形压榨件),其彼此相对以在其间形成第二压区(换句话说,第二压榨部)。The first press mechanism 51 includes a pair of paper conveying felts 100 and a first shoe 55 and a first roll 57 (in other words, a first shoe press), which are opposed to each other to form a first nip therebetween (in other words, a first nip). In other words, the first press section). The second press mechanism 53 includes a pair of paper conveying felts 100 and a second shoe 59 and a second roll 61 (in other words, a second shoe press), which are opposed to each other to form a second nip therebetween (in other words, a second press). In other words, the second press section).

如图2所示,纸输送毛毯100可分别作为第一压榨机构51及第二压榨机构53的上、下纸输送毛毯使用,但也可以作为第一压榨机构51及第二压榨机构53的上、下纸输送毛毯中的任何一个而使用。当纸输送毛毯100作为第一压榨机构51及第二压榨机构53的上、下纸输送毛毯中的任何一个而装配时,根据造纸特性,任何纸输送毛毯都可以作为其他纸输送毛毯使用。另外,通常地,其表面平滑性胜于脱水性的纸输送毛毯被用作设置于下游侧的第二压榨机构53上所安装的一对纸输送毛毯。因此,优选地,该对纸输送毛毯100用作第二压榨机构53的纸输送毛毯。As shown in Figure 2, the paper conveying felt 100 can be used as the upper and lower paper conveying felts of the first press mechanism 51 and the second press mechanism 53 respectively, but it can also be used as the upper and lower felts of the first press mechanism 51 and the second press mechanism 53. Use any one of the lower paper conveying felts. When the paper conveying felt 100 is assembled as any one of the upper and lower paper conveying felts of the first press mechanism 51 and the second press mechanism 53, any paper conveying felt can be used as the other paper conveying felt according to papermaking characteristics. In addition, generally, a paper conveying felt whose surface is smoother than dehydrating is used as a pair of paper conveying felts mounted on the second press mechanism 53 provided on the downstream side. Therefore, preferably, the pair of paper conveying felts 100 are used as the paper conveying felts of the second press mechanism 53 .

如图2所示,从网部(未示出)传输到第一压榨机构51的湿纸W被夹入一对纸输送毛毯100之间并且在其间被输送,通过用第一靴形件55以及第一57挤压湿纸,水从湿纸中被挤出,所挤出的水被吸入到纸输送毛毯100的湿纸接触层25中。接下来,湿纸W被传送到第二压榨机构53,并且夹入一对纸输送毛毯100之间并在其间输送,通过用第二靴形件59以及第二辊61挤压湿纸,水 进一步从湿纸中被挤出,所挤出的水被吸入到纸输送毛毯100的湿纸接触层25中。As shown in FIG. 2 , the wet paper W conveyed from the wire section (not shown) to the first press mechanism 51 is sandwiched between a pair of paper conveying felts 100 and conveyed therebetween, by using the first shoe 55 And the first 57 squeezes the wet paper, water is squeezed out of the wet paper, and the squeezed water is sucked into the wet paper contact layer 25 of the paper delivery felt 100 . Next, the wet paper W is conveyed to the second pressing mechanism 53, and is sandwiched between a pair of paper conveying felts 100 and conveyed therebetween, by squeezing the wet paper with the second shoe 59 and the second roller 61, the water Further squeezed from the wet paper, the squeezed water is sucked into the wet paper contact layer 25 of the paper transport felt 100 .

纸输送毛毯100的湿纸接触层25由柔软性树脂材料形成,而且其朝向湿纸的表面致密且平滑。由此,形成具有平滑表面的湿纸W被传输到干燥部(未示出),然后在其中被干燥。由于与第一靴形件55与第一辊57之间或第二靴形件59与第二辊61之间的压榨部相接触的纸输送毛毯100的第二毛层13B、基层11、以及第一毛层13A包含聚合物弹性材料23,因此其机械强度得以提高,这些部件不会由于压榨部中的强烈的压力而损坏。因此,纸输送毛毯具有优良的耐久性。The wet paper contact layer 25 of the paper conveying felt 100 is formed of a flexible resin material, and its surface facing the wet paper is dense and smooth. Thus, the wet paper W formed to have a smooth surface is conveyed to a drying section (not shown), and then dried therein. Due to the second batt layer 13B, the base layer 11 , and the A batt 13A contains polymer elastic material 23, so that its mechanical strength is increased and these parts are not damaged by the intense pressure in the press section. Therefore, the paper conveying felt has excellent durability.

如上所述,具有双级压榨机构51及53的靴形压榨型造纸机的压榨装置300已经作为根据本发明的造纸机的压榨装置的实例而进行了说明,然而本发明当然也可以应用于具有一个压榨机构的压榨装置或具有连续排列的多个压榨机构的压榨装置。As mentioned above, the press device 300 of the shoe press type paper machine having the two-stage press mechanism 51 and 53 has been described as an example of the press device of the paper machine according to the present invention, but the present invention can of course also be applied to the press device having A pressing device with one pressing mechanism or a pressing device with a plurality of pressing mechanisms arranged in series.

在此,为了更容易地理解本发明,对根据本发明的一个实施例的纸输送毛毯的结构以及具有该纸输送毛毯的造纸机的压榨装置的结构进行简要地描述。Here, for easier understanding of the present invention, the structure of a paper conveying felt according to an embodiment of the present invention and the structure of a press apparatus of a paper machine having the paper conveying felt will be briefly described.

纸输送毛毯100是一对纸输送毛毯中的至少一个,该对纸输送毛毯配置于造纸机的压榨部中所设置的压榨装置300中,在压榨装置中,与压榨件(辊57或61以及靴形件55或59)一起形成压榨机构51或53,其夹持湿纸W进行输送并且通过所述压榨件加压。纸输送毛毯100包括基层11;第一毛层13A,其形成于基层11的湿纸侧表面上;第二毛层13B,其形成于基层11的湿纸侧表面上;聚合物弹性材料23,其浸渍于基层11、第一毛层13A、以及第二毛层13B中;以及湿纸接触层25,其形成于第一毛层13A的湿纸侧表面上从而与湿纸W直接接触,并且具有柔软的树脂材料。湿 纸接触层25的压缩性大于由基层11、第一毛层13A、以及第二毛层13B形成的层的压缩性。The paper conveying felt 100 is at least one of a pair of paper conveying felts arranged in a press device 300 provided in a press section of a paper machine, and in the press device, it is connected with a press member (roll 57 or 61 and The shoe 55 or 59) together form a press mechanism 51 or 53 which holds the wet paper W for conveyance and is pressed by said press. The paper conveying felt 100 includes a base layer 11; a first batt layer 13A formed on the wet paper side surface of the base layer 11; a second batt layer 13B formed on the wet paper side surface of the base layer 11; a polymer elastic material 23, which is impregnated in the base layer 11, the first batt layer 13A, and the second batt layer 13B; and the wet paper contact layer 25 formed on the wet paper side surface of the first batt layer 13A so as to be in direct contact with the wet paper W, and Features soft resin material. The compressibility of the wet paper contact layer 25 is greater than that of the layer formed by the base layer 11, the first batt layer 13A, and the second batt layer 13B.

另外,湿纸接触层25的柔软树脂材料包含发泡树脂或颗粒状树脂。In addition, the soft resin material of the wet paper contact layer 25 contains foamed resin or granular resin.

另外,在10kg/cm2的压力下,湿纸接触层25的压缩性与由基层11、第一毛层13A、及第二毛层13B形成的层的压缩性的差值最好大于或等于5%。In addition, under the pressure of 10 kg/cm 2 , the difference between the compressibility of the wet paper contact layer 25 and the compressibility of the layer formed by the base layer 11, the first batt layer 13A, and the second batt layer 13B is preferably greater than or equal to 5%.

压榨装置300包括多个具有纸输送毛毯100的压榨机构,并且多个压榨机构51及53沿湿纸输送方向A连续排列,其中湿纸由纸输送毛毯100输送。The press device 300 includes a plurality of press mechanisms having the paper conveying felt 100 , and the plurality of press mechanisms 51 and 53 are arranged in series along the wet paper conveying direction A, wherein the wet paper is conveyed by the paper conveying felt 100 .

如上所述,根据本发明,纸输送毛毯100、基层11、第一毛层13A、以及第二毛层13B包含聚合物弹性材料23并且湿纸接触层25由柔软性树脂材料构成。由此,由于基层11、第一毛层13A、以及第二毛层13B包括诸如合成树脂的聚合物弹性材料23,基层以及第二毛层具有很高的机械强度以对抗由压榨机构51及53的压榨件的压力。因此,即使当纸输送毛毯100由压榨件的压榨部分强烈地压榨时,纸输送毛毯也很少被损伤并且因此纸输送毛毯具有优良的耐久性。结果,由于纸输送毛毯100的寿命延长,可以减少纸输送毛毯的更换频率。另外,由于由柔软性树脂材料制成的湿纸接触层25与由基层11、第一毛层13A、以及第二毛层13B构成的层相比,具有较大的压缩性,并且与由基层11、第一毛层13A、以及第二毛层13B构成的层相比具有适当的压缩性和减压性,故可以从湿纸中吸收水分。另外,由于不会发生纤维从湿纸接触层25上脱落,所以湿纸表面的平滑度得以改善。另外,如上所述,由于纤维不会从湿纸接触层25上脱落,纸输送毛毯100的寿命(即纸输送毛毯100的可使用期间)可以延长,并且更换频率可以减少。As described above, according to the present invention, the paper conveying felt 100, the base layer 11, the first batt layer 13A, and the second batt layer 13B comprise the polymer elastic material 23 and the wet paper contact layer 25 is composed of a flexible resin material. Thus, since the base layer 11, the first batt layer 13A, and the second batt layer 13B include the polymer elastic material 23 such as synthetic resin, the base layer and the second batt layer have high mechanical strength against the force of the pressing mechanism 51 and 53. The pressure of the press piece. Therefore, even when the paper conveying felt 100 is strongly pressed by the press portion of the press member, the paper conveying felt is rarely damaged and thus the paper conveying felt has excellent durability. As a result, since the life of the paper conveying felt 100 is extended, the frequency of replacement of the paper conveying felt can be reduced. In addition, since the wet paper contact layer 25 made of a flexible resin material has greater compressibility than a layer composed of the base layer 11, the first batt layer 13A, and the second batt layer 13B, and is more compact than the layer composed of the base layer 11. The layer composed of the first batt layer 13A and the second batt layer 13B has appropriate compressibility and decompression properties, so it can absorb moisture from wet paper. In addition, since fiber detachment from the wet paper contact layer 25 does not occur, the smoothness of the wet paper surface is improved. In addition, as described above, since fibers do not come off from the wet paper contact layer 25, the life of the paper conveying felt 100 (ie, the usable period of the paper conveying felt 100) can be extended and the frequency of replacement can be reduced.

另外,因为在10kg/cm2的压力下,湿纸接触层25的压缩性与由基层11、第一毛层13A、及第二毛层13B构成的层的压缩性之间的差值大于或等于5%,所以纸输送毛毯100具有合适的压缩性和复原性。In addition, because under the pressure of 10 kg/cm 2 , the difference between the compressibility of the wet paper contact layer 25 and the compressibility of the layer composed of the base layer 11, the first batt layer 13A, and the second batt layer 13B is greater than or is equal to 5%, so the paper transport felt 100 has suitable compressibility and recovery.

根据本发明的造纸机的压榨装置300,当多个具有纸输送毛毯100的压榨机构51及53沿由造纸输送带100输送湿纸W的湿纸输送方向连续排列时,水从湿纸W中被高效地挤出,并且湿纸表面可适当地平滑化,从而使得造纸作业高速进行。当纸输送毛毯100设置于多个压榨机构51、53中的配置于沿纸输送毛毯100输送湿纸W的湿纸输送方向的下游侧的压榨机构53中时,考虑到渗水性虽然比含有较少聚合物弹性材料23的纸输送毛毯的渗水性稍小,但由于具有更优良的平滑湿纸表面的功能,所以可以改善湿纸W的表面平滑度并且使得造纸作业高速进行。另外,由于纸输送毛毯100具有脱水功能,即使当纸输送毛毯装配到布置于下游侧的压榨机构53上时,纸输送毛毯也可以从湿纸W吸收水分,并且可以传输湿纸到进行下一工序的干燥部,从而减少使用热风的干燥工序中所消耗的热量。According to the press device 300 of the paper machine of the present invention, when a plurality of press mechanisms 51 and 53 having the paper conveying felt 100 are arranged continuously along the wet paper conveying direction in which the wet paper W is conveyed by the papermaking conveying belt 100, the water from the wet paper W are efficiently extruded, and the surface of wet paper can be properly smoothed, so that the papermaking operation can be carried out at high speed. When the paper conveying felt 100 is provided in the pressing mechanism 53 arranged on the downstream side in the wet paper conveying direction in which the paper conveying felt 100 conveys the wet paper W among the plurality of press mechanisms 51, 53, although water permeability is considered relatively The paper conveying felt of the polymer-less elastic material 23 has slightly lower water permeability, but since it has a better function of smoothing the surface of the wet paper, it can improve the surface smoothness of the wet paper W and enable high-speed papermaking operations. In addition, since the paper conveying felt 100 has a dehydrating function, even when the paper conveying felt is attached to the press mechanism 53 arranged on the downstream side, the paper conveying felt can absorb moisture from the wet paper W and can convey the wet paper to the next step. The drying part of the process, thereby reducing the heat consumed in the drying process using hot air.

本发明并不限于上述的实施例,其可进行适当地修改和形式上的变化。此外,上述实施例中的各构成要件的材质、形状、尺寸、数值、形式、数量、配置位置等可以是任意的并且不受限制,只要能够实现本发明即可。The present invention is not limited to the above-mentioned embodiment, and it can be appropriately modified and changed in form. In addition, the material, shape, size, numerical value, form, quantity, arrangement position, etc. of each constituent element in the above-mentioned embodiments may be arbitrary and not limited, as long as the present invention can be realized.

例如,当根据本发明的纸输送毛毯被安装在输送过程中具有独立输送湿纸W的部分的开放式牵引的靴形压榨型造纸机的压榨装置上时,也可以同样有效地获得相同的优点。另外,当根据本发明的纸输送毛毯安装在具有封闭式牵引或开放式牵引的辊压榨型造纸机的压榨装置上时,也可以获得以上所述的本发明的操作优点。For example, when the paper conveying felt according to the present invention is installed on a press device of an open-draw shoe press type paper machine having a section for independently conveying wet paper W during conveying, the same advantages can be equally effectively obtained . Furthermore, the operational advantages of the invention described above can also be obtained when the paper transport felt according to the invention is installed on a press of a paper machine of the roll press type with a closed draw or an open draw.

Claims (6)

1. paper transporting felt, be at least one in a pair of paper transporting felt, described paper transporting felt is disposed in the pressing device set on the press section of paper machine, squeezing part in described pressing device forms press mechanism, its clamping that l Water Paper is carried and by described squeezing part it is pressurizeed, and comprising:
Basic unit;
First batt, it is formed on the wet paper surface of described basic unit;
Second batt, it is formed on the squeezing part side surface of described basic unit;
The polymer elasticity material, it impregnated in described basic unit, described first batt, reaches in described second batt; And
The l Water Paper contact layer, thus it is formed on the wet paper surface of described first batt and directly contacts with described l Water Paper, and comprise the flexibility resin material;
Wherein, the compressibility of described l Water Paper contact layer than by described basic unit, described first batt, and described second batt forms layer compressibility big.
2. paper transporting felt according to claim 1, wherein, described flexibility resin material comprises the particulate resins of Foamex or hollow.
3. paper transporting felt according to claim 1, wherein, at 10kg/cm 2Pressure under, the compressibility of described l Water Paper contact layer and by described basic unit, described first batt, and described second batt forms layer compressibility between difference more than or equal to 5%.
4. the pressing device of a paper machine comprises paper transporting felt according to claim 1.
5. the pressing device of a paper machine, comprise a plurality of each all have the press mechanism of paper transporting felt according to claim 1, wherein, described a plurality of press mechanisms are along carrying the throughput direction of l Water Paper to arrange continuously by described paper transporting felt.
6. the pressing device of a paper machine, wherein, described pressing device comprises a plurality of press mechanisms, and paper transporting felt according to claim 1 is set on the press mechanism in the downstream that is arranged at described throughput direction in described a plurality of press mechanism.
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WO2003091498A1 (en) * 2002-04-26 2003-11-06 Tamfelt Oyj Abp Press felt

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TW200639294A (en) 2006-11-16
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JP2006214058A (en) 2006-08-17
CN1818208A (en) 2006-08-16
AU2006200518A1 (en) 2006-08-24
EP1688536B1 (en) 2008-06-25
US20060175032A1 (en) 2006-08-10
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EP1688536A1 (en) 2006-08-09
BRPI0600252A (en) 2006-10-03

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