CN1891045A

CN1891045A - Insecticidal compositions

Info

Publication number: CN1891045A
Application number: CN 200610093461
Authority: CN
Inventors: C·艾尔德伦; W·克雷梅尔; K·－U·布如根
Original assignee: Bayer AG
Current assignee: Bayer AG
Priority date: 1995-05-24
Filing date: 1996-05-13
Publication date: 2007-01-10
Also published as: CN1788560A; CN1943351A

Abstract

The invention relates to an insecticidal compositions containing chloro-nicotinamide acyl pesticide of formula (I) and one or more synergistic agents described in the specification, wherein the groups are as defined in the specification.

Description

Insecticides

The application is to be on May 13rd, 1996 applying date, and application number is 200310114246.3, and denomination of invention is divided an application for the application for a patent for invention of " insecticides ".

The present invention relates to chloro nicotine acyl group (chlornicotinyl) insecticide and insecticidal synergist is the insecticides of main component.

Chloro nicotine acyl group insecticide is known, for example learns from EP-OS192 060.

Insecticidal synergist is the inhibitor of oxidase or Cytochrome P450, or strengthens the cell permeability of the membrane.This insecticides synergist is known, for example learns from the 3rd～5 page of Chemie derpflanzenschutz-und Schadlingsbekampfungsmittel volume 7kNaumann Chemie der Synthetischen Pyrethroid-InsektizideSpringer Verlag 1981.

The present invention relates to the chloro nicotine acyl group insecticide of general formula (I) and the mixture of one or more synergist:

R wherein ¹Expression C ₁-C ₅-alkyl,

R ²Expression hydrogen or C ₁-C ₅-alkyl, or

R ¹And R ²Common expression-CH ₂-CH ₂-,-CH ₂-CH ₂-CH ₂Or

X represents NH, NCH ₃Or expression sulphur,

Y represent nitrogen or CH base and

Z represents cyano group or nitro,

Described synergist is selected from:

O, O-dimethyl-S-(4-oxo-1,2,3-phentriazine-3-methyl) phosphorodithioate [M-gusathion m],

O-ethyl-O-(4-bromo-2-chlorphenyl)-S-#N-rosickyite base phosphate (bromine rosickyite),

3,5-dimethyl-4-methyl mercapto phenyl-N-methyl carbamate (mercaptodimethur),

4-bromo-2-(4-chlorphenyl)-2-(ethoxyl methyl)-5-(trifluoromethyl)-1H-pyrroles-3-nitrile (AC 303.630),

O, O,S-dimethylphosphoroamidothioate (acephatemet),

(2,6-two (1-Methylethyl)-4-Phenoxyphenyl)-N '-(1, the 1-dimethyl ethyl)-(CGA 106 630 for thiocarbamide for N-; Polo), Olivomitecidin,

Ethyl-(the 3-tert-butyl group-1-formyl-dimethylamino-1H-1,2,4-triazole-5-base sulfenyl)-acetic acid esters (Triazuron),

6,7,8,9,10,10-chlordene-1,5,5A, 6,9,9A-six hydrogen-6,9-methylene-2,4,3-benzo (e) two  thiophene frequency-3-chlorides (5a,6,9,9a-hexahydro-6,9-methano-2,4),

Trans-5-(4-chlorphenyl)-N-cyclohexyl-4-methyl-2-oxo-3-thiazolidine-3-carboxylic acid amides (Hexythiazox),

3,6-two-(2-chlorphenyl)-1,2,4,5-tetrazine (four mite piperazines),

Ethyl-(2-(4-phenoxy group phenoxy group)-ethyl) carbamate (ABG-6215),

2-(1-methyl-2-(4-phenoxy group phenoxy group) ethyoxyl) pyridine (pyriproxyfen),

N-cyclopropyl-1,3,5-triazines-2,4,6-triamine (fly eradication amine),

Benzoic acid-(2-benzoyl-1-(1, the 1-dimethyl)) hydrazides (RH5849),

5-amino-3-cyano group-1-(2,6-dichlor-4-trifluoromethyl phenyl)-4-trifluoromethyl thion pyrazoles (Fipronil),

Suitable-(2,3,5,6-tetrafluoro-4-aminomethyl phenyl) methyl-3-(2-chloro-3,3,3-three fluoro-1-acrylic)-2,2-dimethyl-cyclopropane-carboxylate (tefluthrin),

1,5-two-(2, the 4-3,5-dimethylphenyl)-3-methyl isophthalic acid, 3,5-three azepines penta-1,4-diketone (amitraz),

3,5-mesitylenic acid-1-(1, the 1-dimethyl ethyl)-2-(4-ethylamino benzonitrile acyl group) hydrazides (RH5992),

N-((2,5-two chloro-4-(1,1,2,3,3,3-hexafluoro propoxyl group) phenyl)-amino carbonyl)-2,6-difluorobenzamide (Match),

(4-ethoxyl phenenyl)-(3-(4-fluoro-3-Phenoxyphenyl) propyl group) dimethylsilane (FHOE 498) and

(E)-4,5-dihydro-6-methyl-4-((3-pyridine radicals methylene) amino)-1,2,4-triazine-3 (2H)-ketone (Chess).

Preferably list the new blend of the chloro nicotine acyl group insecticide of above synergist and following general structure:

Especially preferably list the new blend of the chloro nicotine acyl group insecticide of above synergist and following general structure:

The new active compound combinations of chloro nicotine acyl group insecticide and above-mentioned synergist can change into regular dosage form; as solution, emulsion, suspension, pulvis, foaming agent, slurry, granule, gaseous solvents, with microcapsules and seed coating composition in the natural material of reactive compound dipping and synthetic material, the polymer; and in the preparation of band cigarette; as stifling cylinder, fumigation tank, stifling coil pipe or the like, also have cold mist agent of ULV and the agent of hot mist type.

These preparations can be produced in a known manner, for example with reactive compound with filler, be that liquid flux, pressurized liquefied vapour and/or solid carrier mix, the optional surfactant that uses, be emulsifier and/or dispersant, and/or foaming agent, mix, under the situation that makes water as filler, for example also available organic solvent is made cosolvent.The liquid flux that is fit to has substantially: aromatic compound, as dimethylbenzene, toluene or Fluhyzon, chlorinated aromatic compound or chlorinated aliphatic hydrocarbon, as the chlorobenzene class, polyvinyl chloride-base or carrene, aliphatic hydrocarbon, as cyclohexane or paraffin, mineral oil fraction for example, alcohols, as butanols or ethylene glycol and ether and ester, ketone, as acetone, MEK, methyl iso-butyl ketone (MIBK) or cyclohexanone, intensive polar solvent, as dimethyl formamide and methyl-sulfoxide and water, so-called liquefaction vapour filler or carrier are meant it is the fluid of gaseous state at normal temperatures and pressures, aerosol propellant for example is as halogenated hydrocarbons and butane, propane, nitrogen and carbonic acid gas; The solid-state carrier that is fit to has: the natural mineral matter that for example grinds, as kaolin, clay, talcum, chalk, quartz, Attagel, imvite or diatomite and the synthetic mineral matter that grinds, as silica in small, broken bits, alumina and silicate; Be used for suitable the having of solid carrier of granule: for example pulverize the also natural rock of classification, as calcite, marble, float stone, sepiolite and dolomite, and synthetic inorganic particle and organic powder and organic granular, as wood sawdust, cocoa husk, corncob rod and tobacco stem; The emulsifier and/or the foaming agent that are fit to have: for example nonionic and anion emulsifier, as the hydrolysate of polyoxyethylene fatty acid ester, polyoxyethylene aliphatic alcohol ether, for example alkaryl polyglycol ether, alkylsulfonate, alkyl sulfate, arylsulphonate and protein; The dispersant that is fit to has: for example lignin sulfurous acidity liquid and methylcellulose.

Can use the carboxymethyl cellulose and the natural and synthetic polymer of adhesive such as powdery, particle or latex form in the preparation, as gum Arabic, polyvinyl alcohol and polyvinyl acetate and natural phosphide, as kephalin and lecithin, and synthetic phospholipid.Other additive can be mineral oil and vegetable oil.

Also may use dyestuff, as inorganic pigment, for example iron oxide, titanium oxide and Pu Lu soil are blue, and organic dyestuff, as the salt of alizarin dyes, azo dyes and metal phthalocyanine dyestuff and micronutrient such as iron, manganese, boron, copper, cobalt, molybdenum and zinc.

Usually contain the reactive compound of 0.1 to 95% (weight) by weight in the preparation, preferred 0.5 to 90%.

Active compound combinations is suitable for preventing and treating animal pest; special control appears at insect, acarian and the nematode on agricultural, forest, storage product and material protection and the health aspect, and has good plant drug resistance and the toxicity favourable to warm blooded animal.They have activity to normal sensitivity and resistance kind with to all or some growth and development stages.Above-mentioned insect comprises: wait sufficient guiding principle, for example, damp worm (Oniscus asellus), pillworm (Armadillidium vulgare) and spot pillworm (Porcellio scaber).

Diplopoda, for example, Blaniulus guttulatus.

Chilopoda, for example, DIWUGONG (Geophilus carpophagus) and common house centipede (Scutigeraspec).

Symphyla, for example, clean symphilid (Scutigerella immaculata).

Thysanoptera, for example, silverfiss (Lepisma saccharina).

Collembola, for example, Onychiurus arcticus (Onychiurus armatus).

Orthoptera, for example, oriental cockroach (Blatta orientalis), American cockroach (Periplanetaamericana), leucophaea maderae (Leucophaea maderae), Groton bug (Blattellagermanica), acheta domestica (Acheta domesticus), Gryllotalpa spp (Gryllotalpa spp.), tropical migratory locusts (Locusta migratoria migratorioids), very plant grasshopper (Melanoplusdifferentialis) and desert locust (Schistoeerca gregaria).

Dermaptera, for example, European earwig (Forficula auricularia).

Isoptera, for example, Reticulitermes (Reticulitermes spp.).

Anoplura, for example, body louse (Pediculus humanus corporis), Haematopinus (Haematopinus spp.) and jaw lice belong to (Linognathus spp.).

Mallophaga, for example, Trichodectes (Trichodectes spp.) and Damalinea spp..

Thrips, for example, greenhouse Hercinothrips spp (Hercinothrips femoralis) and cotton thrips (Thripstabaci).

Semiptera, for example, Eurygasterspp genus (Eurygaster spp.), middle red cotton bug (Dysdercusintermedius), beet plan lace bug (Piesma quadrata), the smelly stinkbug in temperate zone (Cimexlectularius), red abdomen are hunted stinkbug (Phodnius prolixus) and Triatoma (Triatomaspp.).

Homoptera, for example, wild cabbage aleyrodid (Aleurodes brassicae), sweet potato whitefly (Bemisiatabaci), greenhouse whitefly (Trialeurodes vaporariorum), cotten aphid (Aphisgossypii), cabbage aphid (Brevicoryne brassicae), the tea deer conceals knurl aphid (Cryptomyzusribis), aphis fabae (Aphis fabae), apple aphid (Aphis pomi), wooly aphis (Eriosoma lanigerum), mealy plum aphid (Hyalopterus arundinis), English grain aphid (Macrosiphum avenae), knurl volume Aphis (Myzus spp.), the goitre woolly aphid belongs to (Pemphigusspp.), phorodon aphid (Phorodon humili), U.S. walnut radicola (Phylloxeravastatix), rhopalosiphum padi (Rhopalosiphum padi), Empoasca spp belongs to (Empoascaspp.), Euscelis bilobatus, rice leafhopper (Nephotettix cincticeps), the hard a red-spotted lizard (Lecanium corni) of water and soil, oil lam black helmet kuwana (Saissetia oleae), small brown-back rice plant-hopper (Laodelphax striatellus), brown plant-hopper (Nilaparvata lugens), Red Garden a red-spotted lizard (Aonidiella aurantii), sweet-scented oleander garden a red-spotted lizard (Aspidiotus hederae), mealybug belongs to (Pseudococcus spp.) and Psylla spp (Psylla spp.).

Lepidoptera, for example, cotton red sandfly insect (Pectinophora gossypiella), pine sphinx moth (Bupaluspiniarius), winter geometrid moth (Cheimatobia brumata), Lithocolletisblancardella, apple ermine moth (Hyponomeuta padella), diamond-back moth (Plutellamaculipennis), tent caterpillar (Malacosoma neustris), pornography and drug moth (Euproctischrysorrhoea), Euproctis (Lymantria spp.), cotton lyonetid (Bucculatrixthurberiella), tangerine leaf miner (Phyllocnistis citrella), Agrotis spp., Euxoaspp., Feltia spp., the real moth (Earias insulana) of cotton spot, genus heliothis (Heliothisspp.), beet armyworm ((Spodoptera exigua), tomato moth (Mamestrabrassicae), small noctuid (Panolis flammea), prodenia litura (Prodenia litura), mythimna separata belongs to (Spodoptera spp.), cabbage looper (Trichoplusia ni), the moth-eaten moth (Carpocapsa pomonella) of apple, Pier (Pieris spp.), straw borer spp (Chilospp.), Pyrausta nubilalis, Ephestia kuehniella, galleria mellonella waxmoth (Galleriamellonella), curtain casemaking clothes moth (Tineola bisselliella), bag casemaking clothes moth (Tinea pellionella), brownly knit moth (Hofmannophila pseudospretella), Cacoecia podana, Capua reticulana, spruce bunworm (Choristoneura fumiferana), grape codling moth (Clysia ambiguella) (Clysia ambiguella), tea long paper moth (Homona magnanimna) and the green volume of oak moth (Tortrix viridana).

Coleoptera, for example, tool spot death watch beetle (Anobium punctatum), lesser grain borer (Rhizoperthadominica), common bean weevil (Acanthoscelides obtectus), Bruchidiusobtectus, house longhorn beetle (Hylotrupes bajulus), the purple flea beetle (Agelasrticaalni) of alder, colorado potato beetle (Leptinotarsa decemlineata), horseradish ape chrysomelid (Phaedoncochleariae), the chrysomelid genus of bar (Diabrotica spp.), rape blue flea beetle (Psylliodeschrysocephala), Mexico's beans first (Epilachna varivestis), latent wing first belongs to (Atomaria spp.), saw-toothed grain beetle (Oryzaephilus surinamensis), Anthonomus spp belongs to (Anthonomus spp.), Sitophilus (Sitophilus spp.), vine black ear beak resembles (Otiorrhynchus sulcatus), banana root weevil (Cosmopolites sordidus), wild cabbage pod weevil (Ceuthorrhynchus assimilis), alfalfa weevil (Hyperapostica), khapra beetle belongs to (Dermestes spp.), the spot khapra beetle belongs to (Trogoderma spp.), Anthrenus (Anthrenus spp.), moth-eaten belong to (the Attagenus spp.) of hair, moth-eaten belong to (Lyctusspp.) of powder, pollen beetle (Meligethes aeneus), Ptinus (Ptinus spp.), golden yellow ptinid (Niptus hololeucus), globose spider beetle (Gibbium psylloides), Tribolium (Tribolium spp.), yellow mealworm (Tenebrio molitor), Agriotes spp., Conoderus spp., the melolonthid (Melolontha melolontha), cockchafer in June (Amphimallon sostitialis) and Costelytra zealandica.

Hymenoptera, for example, Diprion spp., Hoplocampa spp., field ant belong to (Lasiusspp.), MonomoriumMayr (Monomorium pharaonis) and wasp (Vespa spp.).Diptera, for example, Aedes (Aedes spp.), Anopheles (Anopheles spp.), Culex (Culex spp.), drosophila yellow gorilla (Drosophila melanogaster), fly belongs to (Muscaspp.), Fannia (Fannia spp.), calliphora erythrocephala (Callophora erythrocephala), Lucilia (Lucilia spp.), Carysomyia (Chrysomyia spp.), cuterbrid belongs to (Cuterebraspp.), Gasterophilus (Gastrophilus spp.), Hippobosca (Hyppobosca spp.), Genus Stomoxys (Stomoxys spp.), Oestrus (Oestrus spp.), Hypoderma (Hypodermaspp.), Gadfly (Tabanus spp.), Tannia spp., Bibio hortulanus, Sweden's wheat stem chloropid fly (Oscinella frit), Phorbia spp., spinach leaf mining flowerfly (Pegomyiahyoscyami), Mediterranean fruitfly (Ceratitis capitata), oil olive trypetid (Dacus oleae) and marsh daddy-longlegs (Tipula paludosa).

Siphonaptera, for example, Xanthopsyllacheopis (Xenopsylla cheopis) and hair row flea belong to (Ceratophyllusspp.), flea belongs to (Pulex spp.) and Ct (Ctenocephalides spp.).Arachnids, for example, scorpion (Scorpio maurus) and black widow (Latrodectus mactans).Acarina, for example, Acarus siro (Acarus siro), latent beak tick belongs to (Argas spp.), blunt beak tick belongs to (Ornithodoros spp.), the perverse mite of cock skin (Dermanyssus gallinae), tea deer goitre mite (Eriophyes ribis), citrus rust mite (Phyllocoptruta oleivora), Boophilus (Boophilus spp.), Rh (Rhipicephalus spp.), Amblyomma (Amblyommaspp.), glass eye tick belongs to (Hyalomma spp.), hard tick belongs to (Ixodes spp.), the scabies mite belongs to (Psoroptes spp.), Chorioptes (Chorioptes spp.), itch mite belongs to (Sarcoptesspp.), tarsonemid belongs to (Tarsonemus spp.), Bryobia praetiosa (Bryobia praetiosa), Panonychus citri belongs to (Panonychus spp.) and Tetranychus (Tetranychus spp.).

Plant nematode comprises for example meadow Tylenchida (Pratylenchus spp.), radopholus (Radopholus spp.), Ditylenchus Ditylenchus spp., Tylenchulus spp., Heterodera (Heterodera spp.), capsule nematode (Globodera spp.), Meloidogyne spp., aphelenchoides (Aphelechoides spp.), Longidorusspp., Tylenchida belongs to sword nematode (Xiphinema spp.), bangs root nematode (Trichodorusspp.).

Active compound combinations of the present invention can be present in its commercially available preparation and the type of service by these formulation preparation, be form of mixtures with other reactive compound, other reactive compound such as insecticide, attractant, bactericide, miticide, nematocide, fungicide, growth regulator or insecticide.Insecticide comprises: for example phosphate, carbamate, carboxylate, chlorohydrocarbon, phenylurea and particularly by the material of microorganism preparation.

Content by the reactive compound of the type of service of commercial preparation preparation can change in very wide scope.The concentration of the reactive compound of type of service can be 0.0000001～95%, preferred 0.0001～1% (weight).

These compounds use with the usual manner that is fit to type of service.

In the following embodiments, the imidacloprid of following general formula is as the insecticidal active compound that is selected from chloro nicotine acyl group insecticide.

Embodiment A

The chrysomelid larva test of horseradish ape

Solvent: the dimethyl formamide of 7 parts of weight

Emulsifier: the alkaryl polyglycol ether of 1 part of weight

During the appropriate formulation of preparation reactive compound,, and this missible oil is diluted with water to desired concn with the reactive compound of 1 part of weight and the solvent and the emulsifier of described amount.

Wild cabbage (Brassica oleracea) blade pass crossed in the active agent preparations that immerses desired concn handle, when blade is still moistening, put into horseradish ape chrysomelid (Phaedoncochleariae) larva.

Through after the required time, the chrysomelid larval feeding of horseradish ape that plant is placed into.After 7 days, determine to kill %.100% is meant that all larvas all are killed; 0% is meant do not have larva to be killed.

In each case, 0.02% synergist is sneaked in the imidacloprid of each experimental concentration.In this test, the effect of synergist demonstrates with for example following mixture:

Table A

(insect of harm plant)

The chrysomelid larva test of horseradish ape

Reactive compound	The concentration of reactive compound (%)	Kill % after 7 days
Reactive compound	The concentration of reactive compound (%)	Kill % after 7 days	Imidacloprid	0.0008	5
The M-gusathion m	0.0008	40	Imidacloprid	0.0008	5
The M-gusathion m	0.0008	40	Imidacloprid+M-gusathion m	0.0008 +0.0008	95
HOE 498	0.008	35	Imidacloprid+M-gusathion m	0.0008 +0.0008	95
HOE 498	0.008	35	Imidacloprid+HOE 498	0.0008 +0.0008	100 bromines, third phosphorus
Bromine third phosphorus	0.0008	15	Imidacloprid+HOE 498	0.0008 +0.0008	100 bromines, third phosphorus
Bromine third phosphorus	0.0008	15	Imidacloprid+bromine third phosphorus	0.0008 +0.0008	70

Embodiment B

Diamond-back moth test (BLT resistance)

Solvent: the dimethyl formamide of 7 parts of weight

Emulsifier: the alkaryl polyglycol ether of 1 part of weight

Wild cabbage (Brassica Oleracea) blade pass crossed in the active agent preparations that immerses desired concn handle, when blade is still wetting, put diamond-back moth (Plutella maculipennis, BLT-resistance) caterpillar.

After having passed through the required time, determine to kill %.100% is meant that all diamond-back moth caterpillars all are killed; 0% is meant do not have the diamond-back moth caterpillar to be killed.

Table B

(insect of harm plant)

Diamond-back moth test (resistance)

Reactive compound	The concentration of reactive compound (%)	Kill % after 7 days
Reactive compound	The concentration of reactive compound (%)	Kill % after 7 days	Imidacloprid	0.004	0
The M-gusathion m	0.0008	0	Imidacloprid	0.004	0
The M-gusathion m	0.0008	0	Imidacloprid+M-gusathion m	0.004 +0.0008	100
HOE 498	0.0008	0	Imidacloprid+M-gusathion m	0.004 +0.0008	100
HOE 498	0.0008	0	Imidacloprid+HOE 498	0.004 +0.0008	100
Bromine third phosphorus	0.0008	40	Imidacloprid+HOE 498	0.004 +0.0008	100
Bromine third phosphorus	0.0008	40	Imidacloprid+bromine third phosphorus	0.004 +0.0008	100
Mercaptodimethur	0.004	0	Imidacloprid+bromine third phosphorus	0.004 +0.0008	100
Mercaptodimethur	0.004	0	Imidacloprid+mercaptodimethur	0.004 +0.004	100
Acephatemet	0.004	0	Imidacloprid+mercaptodimethur	0.004 +0.004	100
Acephatemet	0.004	0	Imidacloprid+acephatemet	0.004 +0.004	100
Match	0.0000064	0	Imidacloprid+acephatemet	0.004 +0.004	100
Match	0.0000064	0	Imidacloprid+Match	0.004 +0.0000064	65

Embodiment C

Meadow mythimna separata test

Solvent: the dimethyl formamide of 7 parts of weight

Emulsifier: the alkaryl polyglycol ether of 1 part of weight

Wild cabbage (Brassica oleracea) blade pass crossed in the active agent preparations that immerses desired concn handle, when blade is still moistening, put meadow mythimna separata (Spodopterafrugiperda) caterpillar.

Through after the regular hour, determine to kill %.100% is meant that all caterpillars all are killed; 0% is meant do not have caterpillar to be killed.

Table C

(insect of harm plant)

Meadow mythimna separata test

Reactive compound	The concentration of reactive compound (%)	Kill % after 7 days
Reactive compound	The concentration of reactive compound (%)	Kill % after 7 days	Imidacloprid	0.004 0.0008	50 0
AC 303.603	0.0008	0	Imidacloprid	0.004 0.0008	50 0
AC 303.603	0.0008	0	Imidacloprid+AC 303 630	0.004 +0.0008	100
RH 5992	0.0008	0	Imidacloprid+AC 303 630	0.004 +0.0008	100
RH 5992	0.0008	0	Imidacloprid+RH 5992	0.004 +0.0008	100
Acephatemet	0.004	0	Imidacloprid+RH 5992	0.004 +0.0008	100
Acephatemet	0.004	0	Imidacloprid+acephatemet	0.004 +0.004	100
Match	0.0000064	15	Imidacloprid+acephatemet	0.004 +0.004	100
Match	0.0000064	15	Imidacloprid+Match	0.004 +0.0000064	100

Embodiment D

The black peach aphid test

Solvent: the dimethyl formamide of 3 parts of weight

Emulsifier: the alkaryl polyglycol ether of 1 part of weight

To be crossed in the active agent preparations that immerses desired concn by wild cabbage (BrassicaOleracea) blade pass that black peach aphid (Myzus persicae) seriously infects and handle.

After having passed through the required time, determine to kill %.100% is meant that all aphids all are killed; 0% is meant do not have aphid to be killed.

Table D

(insect of harm plant)

The black peach aphid test

Reactive compound	The concentration of reactive compound (%)	Kill % after 6 days
Reactive compound	The concentration of reactive compound (%)	Kill % after 6 days	Imidacloprid	0.00016	10
Mercaptodimethur	0.004	0	Imidacloprid	0.00016	10
Mercaptodimethur	0.004	0	Imidacloprid+mercaptodimethur	0.00016 +0.004	70
Acephatemet	0.004	0	Imidacloprid+mercaptodimethur	0.00016 +0.004	70
Acephatemet	0.004	0	Imidacloprid+acephatemet	0.00016 +0.004	80

Claims

1. insecticides, it is the chloro nicotine acyl group insecticide of following structural

Imidacloprid or

Thiophene worm quinoline

With synergist 3,5-mesitylenic acid-1-(1, the 1-dimethyl ethyl)-2-(4-ethylamino benzonitrile acyl group) hydrazides.

2. the method for the insecticides in the preparation claim 1 is characterized in that reactive compound is mixed with filler, the optional surfactant that uses.

3. the insecticides of claim 1 is characterized in that they contain the active compound combinations of 0.1-95 weight %.

4. the insecticides of claim 1 is used to prevent and treat the application of insect, acarian and nematode.