CN1888878B - Non-combustible dye check cleaning liquid and preparation method thereof - Google Patents
Non-combustible dye check cleaning liquid and preparation method thereof Download PDFInfo
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- CN1888878B CN1888878B CN2006100289534A CN200610028953A CN1888878B CN 1888878 B CN1888878 B CN 1888878B CN 2006100289534 A CN2006100289534 A CN 2006100289534A CN 200610028953 A CN200610028953 A CN 200610028953A CN 1888878 B CN1888878 B CN 1888878B
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- cleaning liquid
- dye check
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- raw material
- dye
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- 238000004140 cleaning Methods 0.000 title claims abstract description 24
- 239000007788 liquid Substances 0.000 title claims abstract description 22
- 238000002360 preparation method Methods 0.000 title claims description 13
- 239000003795 chemical substances by application Substances 0.000 claims description 20
- 238000002485 combustion reaction Methods 0.000 claims description 16
- 239000012530 fluid Substances 0.000 claims description 15
- 239000002994 raw material Substances 0.000 claims description 15
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 10
- 229910052757 nitrogen Inorganic materials 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 6
- PTKIBFRLTHBANB-UHFFFAOYSA-N 2-methylpropyl 2-aminoacetate Chemical compound CC(C)COC(=O)CN PTKIBFRLTHBANB-UHFFFAOYSA-N 0.000 claims description 5
- GIIJTDXSACMUEI-UHFFFAOYSA-N carbonic acid;propane-1,1-diol Chemical compound OC(O)=O.CCC(O)O GIIJTDXSACMUEI-UHFFFAOYSA-N 0.000 claims description 5
- 238000005303 weighing Methods 0.000 claims description 5
- 239000000443 aerosol Substances 0.000 claims description 4
- 239000003380 propellant Substances 0.000 claims description 3
- 238000009288 screen filtration Methods 0.000 claims description 3
- 238000001514 detection method Methods 0.000 abstract description 18
- 230000000149 penetrating effect Effects 0.000 abstract description 7
- 238000002474 experimental method Methods 0.000 abstract description 2
- 239000000975 dye Substances 0.000 description 24
- 239000003063 flame retardant Substances 0.000 description 12
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 10
- 239000000047 product Substances 0.000 description 8
- 238000007689 inspection Methods 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 239000001569 carbon dioxide Substances 0.000 description 5
- 229910002092 carbon dioxide Inorganic materials 0.000 description 5
- 230000035515 penetration Effects 0.000 description 5
- 239000002904 solvent Substances 0.000 description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- -1 phenixin Substances 0.000 description 3
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000004079 fireproofing Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
- 238000005493 welding type Methods 0.000 description 1
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- Investigating Materials By The Use Of Optical Means Adapted For Particular Applications (AREA)
Abstract
The non-inflammable dye check cleaning liquid comprises the following components in percentage by weight:
Description
Technical field
The present invention relates to the engineering flaw detection, belong to fine chemistry industry prescription and preparation technology, particularly a kind of non-combustion dye check cleaning liquid and preparation method thereof.
Background technology
The employed penetrant flaw detection agent of liquid penetration test, the product of many kinds of models has appearred in world at present.But all there are some common weakness in they: flammable.
As everyone knows, burning has three fundamentals: flammable material, oxygen and high temperature, if block one of them among the key element, just can avoid burning.The most of compositions of existing dye check agent all are inflammable Organic Ingredients, and do not take the obstruct measure.
For the problem in the site operation that solves the shipbuilding engineering, need to survey defectives such as weld crack.When surveying, all unavoidably there is the naked light of one type of welding, gas cutting to exist on every side, at this time adopt the dye-penetrant inspection operation, be easy to breaking out of fire, so must a kind of fire-retardant type dye-penetrant inspection liquid of development.
In the past, at other one type penetrant flaw detection agent---in the fluorescent penetrant inspection agent, though " flame retardant type " fluorescent penetration flaw detection liquid also occurred; But just fire-retardant, be not fire fully, if dangerous situation takes place; Though the fluorescent penetrant of flame retardant type has certain flameproof effect, act on limited.In addition the fluorescent penetration flaw detection liquid great majority are to use in indoor special place, and comparatively speaking, the place fireproofing installation is more complete.
Different therewith is, the dye check agent that another kind of range of application is extremely wide, internal field, outfield, high-altitude, down-hole etc. many with other work post and the situation of depositing under use, the building site of naked light is arranged like welding, gas cutting, husky mill etc.As to carry out dye-penetrant inspection, and necessarily require others to stop work, this is uneconomic on producing.
Summary of the invention
The objective of the invention is to overcome the deficiency of above-mentioned prior art; A kind of fire-retardant type permeation flaw detection cleaning fluid and preparation method thereof is provided; It and the Incombusitible dye check developer that matches, non-combustion dye check penetrating fluid constitutes one group of fire-retardant type permeation flaw detection reagent.
Make fire-retardant type flaw detection agent, adopting non-flame properties raw material is the problem of at first expecting, has many solvents not fire really, like water, phenixin, methylene chloride etc.; All there is more shortcoming in they: though water is nontoxic, cheap and easy to get; But the surface tension coefficient of monomer water is big, seepage force is poor, poor to the dissolving power of organic dyestuff, and monomer water is run into metal and also will be got rusty, and does not meet the requirement of making dye penetrant basically; The solvent of dichlorodifluoromethan hydro carbons such as phenixin, liquid properties on the contrary meet the requirement of preparation dye penetrant inspection agent, but they all are high poison, and be bigger to environmental destruction, and some has stopped producing and having banned use of.
The present invention adopts frothing agent TSHG, modified water compound auxiliary agent, the carbon dioxide bubble release agent, and the measure of inorganic, organic mixing powder can accomplish that the length of flame (weighing the index of burning degree) of dye penetrant inspection agent is zero, reaches and does not fire requirement.Hydrate is nontoxic basically, emits tie water during high temperature earlier, reduces temperature, decomposes and emits carbon dioxide; In a single day bubble release agent is met fire and is heated, and discharges nitrogen immediately.Carbon dioxide, nitrogen all are the gas that does not fire, and they will be applied to, and the dye penetrant inspection agent covers on the workpiece, and itself and the blocking-up of airborne oxygen are isolated.Like this, the oxygen condition in the burning three elements has been removed, and temperature conditions is affected greatly.Even the base solvent of dye check agent has part can burn vapor evolution to peripheral aerial, also be mixed in wherein because of non-flame properties carbon dioxide, nitrogen, watered down the concentration of flammable steam, reduced the possibility of burning.Moreover, water vapor, carbon dioxide, nitrogen, they are principal ingredients of air, nonhazardous does not destroy ecologic environment yet.
Technical scheme of the present invention is following:
A kind of non-combustion dye check cleaning liquid, its composition and percentage by weight are following:
The preparation method of described non-combustion dye check cleaning liquid comprises the following steps:
1. select for use glycine isobutyl ester, carbonate propanediol, the frothing agent TSHG of chemical pure or the above purity of chemical pure to make raw material;
2. select the percentage by weight of each raw material, and take by weighing each raw material in this ratio;
3. at normal temperatures, each raw material is mixed, seals stirring at middle agitated reactor, the time is not less than 2 hours;
4. after stirring end,, promptly obtain the cleaning fluid finished product through 200 purpose screen filtrations.
The preparation method of described non-combustion dye check penetrating fluid is characterized in that also in steps:
5. the cleaning fluid finished product of gained is packed into and do in the head tank of propellant, process aerosol jar product with nitrogen.
Technique effect of the present invention is following:
Non-combustion dye check cleaning liquid of the present invention and Incombusitible dye check developer (separate case invention application) and the supporting use of non-combustion dye check penetrating fluid (separate case application invention).Experiment showed, on engineering and can not only accomplish the flaw detection task, and can prevent effectively that pyrophoricity accident from taking place.The flaw detection agent of the present invention and other kind use that matches though also can accomplish the flaw detection task, can not prevent the generation of pyrophoricity accident; Because permeation flaw detection needs three kinds of reagent; Though only having a kind of is fire-retardant type, other is flammable, does not then reach to prevent the purpose of burning.
The composition and the percentage by weight of described fire-retardant type penetration defects detection developer are following:
The composition and the percentage by weight of described fire-retardant type permeation flaw detection penetrating fluid are following:
Embodiment
Below in conjunction with specific embodiment the present invention is described in further detail.
Non-combustion dye check cleaning liquid of the present invention is formulated by glycine isobutyl ester, carbonate propanediol and frothing agent TSHG.
Embodiment 1
The composition proportioning of described non-combustion dye check cleaning liquid is following:
Its preparation steps is following:
1. screen raw material, the purity of described each raw material is chemical pure purity;
2. raw materials weighing takes by weighing each raw material consumption by above-mentioned formula rate;
3. at normal temperatures, each raw material is mixed, seals stirring at middle agitated reactor, the time is 2 hours;
4. after stirring end, promptly get the cleaning fluid finished product through 200 purpose screen filtrations;
5. gained penetrating fluid finished product is packed into and do in the head tank of propellant, process aerosol jar product with nitrogen.
Embodiment 2
The compositing formula of said non-combustion dye check cleaning liquid is following:
Composition: wt%
Glycine isobutyl ester (base solvent) 30
Carbonate propanediol (hydrate auxiliary agent) 40
Frothing agent TSHG (bubble release agent) 30
Embodiment 3
The compositing formula of said non-combustion dye check cleaning liquid is following:
Composition: wt%
Glycine isobutyl ester 65
Carbonate propanediol 22
Frothing agent TSHG 13
The preparation steps of embodiment 2 and embodiment 3 is identical with embodiment 1 with method of application, and each proportioning components amount is different when just disposing, and wherein each raw material is also selected chemical pure raw material.
Use by the fire-retardant type permeation flaw detection cleaning fluid of the composition proportion amount of embodiment 1, embodiment 2 and embodiment 3 preparation with fire-retardant type penetration defects detection developer and non-combustion dye check penetrating fluid.
Operating position is tested according to following standard:
1. GB/T 14449-93 aerosol products method of testing
2. Q/UCAB008-1999 standard form dye check agent
3. ASTM-E165 permeates the detecting operation method
Test result is as shown in the table:
Can be known by last table data: the length of flame of the cleaning fluid of three embodiment of the present invention is zero, and does not change the flaw detection sensitivity of cleaning fluid.
Claims (3)
1. non-combustion dye check cleaning liquid is characterized in that its composition and percentage by weight are following:
2. the preparation method of the described non-combustion dye check cleaning liquid of claim 1 is characterized in that comprising the following steps:
1. select for use glycine isobutyl ester, carbonate propanediol, the frothing agent TSHG of chemical pure or the above purity of chemical pure to make raw material;
2. select the percentage by weight of each raw material, and take by weighing each raw material in this ratio;
3. at normal temperatures, will mix, seal stirring to pulp, the time is not less than 2 hours;
4. after stirring end,, promptly obtain the cleaning fluid finished product through 200 purpose screen filtrations.
3. the preparation method of non-combustion dye check cleaning liquid according to claim 2 is characterized in that also in steps:
5. the cleaning fluid finished product of gained is packed into and do in the head tank of propellant, process aerosol jar product with nitrogen.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2006100289534A CN1888878B (en) | 2006-07-14 | 2006-07-14 | Non-combustible dye check cleaning liquid and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2006100289534A CN1888878B (en) | 2006-07-14 | 2006-07-14 | Non-combustible dye check cleaning liquid and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1888878A CN1888878A (en) | 2007-01-03 |
| CN1888878B true CN1888878B (en) | 2012-05-30 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2006100289534A Active CN1888878B (en) | 2006-07-14 | 2006-07-14 | Non-combustible dye check cleaning liquid and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1888878B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104330416A (en) * | 2014-10-28 | 2015-02-04 | 南京佳业检测工程有限公司 | Dyeing flaw detection penetrating fluid convenient to wash and preparation method of dyeing flaw detection penetrating fluid |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1414610A (en) * | 2001-10-23 | 2003-04-30 | Ums有限公司 | Method and equipment of removing organic film |
| US20050096250A1 (en) * | 2003-10-31 | 2005-05-05 | Resource Development L.L.C. | Cleaning and multifunctional coating composition containing an organosilane quaternary compound and methods of using |
| CN1644766A (en) * | 2004-12-17 | 2005-07-27 | 沪东中华造船(集团)有限公司 | Flaw detecting cleansing liquid and production thereof |
-
2006
- 2006-07-14 CN CN2006100289534A patent/CN1888878B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1414610A (en) * | 2001-10-23 | 2003-04-30 | Ums有限公司 | Method and equipment of removing organic film |
| US20050096250A1 (en) * | 2003-10-31 | 2005-05-05 | Resource Development L.L.C. | Cleaning and multifunctional coating composition containing an organosilane quaternary compound and methods of using |
| CN1644766A (en) * | 2004-12-17 | 2005-07-27 | 沪东中华造船(集团)有限公司 | Flaw detecting cleansing liquid and production thereof |
Non-Patent Citations (1)
| Title |
|---|
| 丁晓萍.荧光渗透探伤水基预清洗方法.《无损探测》.2001,第23卷(第12期),全文. * |
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| Publication number | Publication date |
|---|---|
| CN1888878A (en) | 2007-01-03 |
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