CN1843995A - Antibacterial enamel and preparation method thereof - Google Patents
Antibacterial enamel and preparation method thereof Download PDFInfo
- Publication number
- CN1843995A CN1843995A CN 200610078227 CN200610078227A CN1843995A CN 1843995 A CN1843995 A CN 1843995A CN 200610078227 CN200610078227 CN 200610078227 CN 200610078227 A CN200610078227 A CN 200610078227A CN 1843995 A CN1843995 A CN 1843995A
- Authority
- CN
- China
- Prior art keywords
- enamel
- germicide
- compound
- antibacterial
- antiseptic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 210000003298 dental enamel Anatomy 0.000 title claims abstract description 61
- 230000000844 anti-bacterial effect Effects 0.000 title claims description 21
- 238000002360 preparation method Methods 0.000 title claims description 14
- 150000001875 compounds Chemical class 0.000 claims abstract description 34
- 229910052796 boron Inorganic materials 0.000 claims abstract description 29
- 150000003839 salts Chemical class 0.000 claims abstract description 17
- 229910052709 silver Inorganic materials 0.000 claims abstract description 17
- 229910052788 barium Inorganic materials 0.000 claims abstract description 15
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 15
- 229910052802 copper Inorganic materials 0.000 claims abstract description 15
- 229910052761 rare earth metal Inorganic materials 0.000 claims abstract description 15
- 150000002910 rare earth metals Chemical class 0.000 claims abstract description 15
- 229910052718 tin Inorganic materials 0.000 claims abstract description 15
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 15
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 15
- 229910052726 zirconium Inorganic materials 0.000 claims abstract description 15
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 16
- 239000004332 silver Substances 0.000 claims description 16
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 14
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 14
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 14
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 14
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 14
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 14
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 14
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 14
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 14
- 239000011575 calcium Substances 0.000 claims description 14
- 239000010949 copper Substances 0.000 claims description 14
- 239000011135 tin Substances 0.000 claims description 14
- 239000010936 titanium Substances 0.000 claims description 14
- 239000011701 zinc Substances 0.000 claims description 14
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 10
- 229910052742 iron Inorganic materials 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 239000004927 clay Substances 0.000 claims description 5
- 238000004140 cleaning Methods 0.000 claims description 5
- 239000000049 pigment Substances 0.000 claims description 5
- 238000005303 weighing Methods 0.000 claims description 5
- 229910021543 Nickel dioxide Inorganic materials 0.000 claims description 4
- 235000019402 calcium peroxide Nutrition 0.000 claims description 4
- 239000002131 composite material Substances 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 4
- 239000000758 substrate Substances 0.000 claims description 4
- 239000004615 ingredient Substances 0.000 claims description 2
- 239000003242 anti bacterial agent Substances 0.000 abstract description 4
- 239000000203 mixture Substances 0.000 abstract description 3
- 230000003115 biocidal effect Effects 0.000 abstract description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 2
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 229910052681 coesite Inorganic materials 0.000 abstract 1
- 229910052593 corundum Inorganic materials 0.000 abstract 1
- 229910052906 cristobalite Inorganic materials 0.000 abstract 1
- 238000009472 formulation Methods 0.000 abstract 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 229910052682 stishovite Inorganic materials 0.000 abstract 1
- 229910052905 tridymite Inorganic materials 0.000 abstract 1
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
- 230000000845 anti-microbial effect Effects 0.000 description 6
- 238000007792 addition Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 4
- 239000002932 luster Substances 0.000 description 3
- 229910052573 porcelain Inorganic materials 0.000 description 3
- 241000228212 Aspergillus Species 0.000 description 2
- 241000228245 Aspergillus niger Species 0.000 description 2
- 241000223678 Aureobasidium pullulans Species 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 2
- 108090000790 Enzymes Proteins 0.000 description 2
- 241001236817 Paecilomyces <Clavicipitaceae> Species 0.000 description 2
- 241000191967 Staphylococcus aureus Species 0.000 description 2
- 241001136494 Talaromyces funiculosus Species 0.000 description 2
- 230000000843 anti-fungal effect Effects 0.000 description 2
- 230000002421 anti-septic effect Effects 0.000 description 2
- 229940121375 antifungal agent Drugs 0.000 description 2
- 239000002320 enamel (paints) Substances 0.000 description 2
- 241000305071 Enterobacterales Species 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 241000191940 Staphylococcus Species 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
Landscapes
- Glass Compositions (AREA)
Abstract
The invention discloses an antibiotic enamel, wherein the glaze-making base formulation includes SiO2 30-50%, Al2O3 5-10%, B2O3 5-20%, Na2O 2-20%, K2O 2-10%, CaO 0-5%, MgO 0-5%, TiO2 0-20%, Zr02 0-10%, ZnO 0-5%, BaO 0-5%, F 1-10%, NiO 0-2%, MnO 20-4%, Fe2O3 0-4%, CuO 0-2%, the added antibacterial agents being Cu, Ag, Sn, Zr, rare earth, Ca, Zn, B, Ba, Ti and their compounds, salts or oxide compounds, the total content being 1-5%.
Description
Technical field
The present invention relates to a kind of enamel, particularly have the enamel of anti-microbial effect.
Background technology
The history in existing thousand of inorganic enamel material, it is a kind of conventional art, its technical process generally is the prescription according to design, choose raw material (natural mineral, chemical materials etc.), through weighing, mix the back and in High-temp. kiln (1200 ℃～1350 ℃), be melt into glassy mass, again through shrend or compressing tablet, make the glaze piece, add an amount of mill addition with the glaze piece, as: clay, dielectric substance, pigment and water etc. are worn into certain fineness together in ball mill, make glaze slip and be coated in and handled on the various metallic surfaces of cleaning in advance, under 750 ℃～900 ℃ temperature, be fused into level and smooth, glossiness enamel layer.But the surface of this common enamel material, may adsorb various harmful bacteriums and mould, at this problem, people wish to produce the enamel with anti-microbial effect, the interpolation antiseptic-germicide is a kind of method wherein, the employed antiseptic-germicide of people is organic antibacterial agent and inorganic antiseptic now, wherein organic antibacterial agent is thermo-labile, the temperature that is suitable for the course of processing is lower than the situation of 300 degree, be not suitable for enamelware pyritous complete processing, and if after inorganic antiseptic is melt into the porcelain piece according to conventional enamel frit makeing method and material commonly used together, because redox, effects such as volatilization or generation silicate, the porcelain facing color and luster is unstable or do not play anti-microbial effect, wear into glaze slip if mix, then porcelain facing tarnish, crude, neither attractive in appearance, anti-microbial effect is also little.
Summary of the invention
At the shortcoming that above-mentioned prior art exists, the object of the present invention is to provide a kind ofly can keep the gloss on enamel layer surface, smooth, color and luster, can guarantee that again antiseptic-germicide can be present in the enamel that plays anti-microbial effect in the enamel coating snugly.The present invention also provides the preparation method of this antibacterial enamel.
For achieving the above object, the technical solution used in the present invention is:
A kind of antibacterial enamel, its enamel frit makeing basic components is: SiO
230%～50%, Al
2O
35%～10%, B
2O
35%～20%, Na
2O5%～20%, k
2O2%～10%, CaO0%～5%, MgO0%～5%, TiO
20%～20%, ZrO
20%～10%, ZnO0%～5%, BaO0%～5%, F1%～10%, NiO0%～2%, MnO
20%～4%, Fe
2O
30%～4%, CuO0%～2% adds antiseptic-germicide and is a kind of in copper, silver, tin, zirconium, rare earth, calcium, zinc, boron, barium, titanium and their compound, salt or the oxide compound or several, and its total content is 1%～5%.
Described enamel frit makeing basic components is: SiO
230%, B
2O
35%, Na
2O5%, k
2O2%～10%, F1%～10% add antiseptic-germicide and are a kind of in copper, silver, tin, zirconium, rare earth, calcium, zinc, boron, barium, titanium and their compound, salt or the oxide compound or several, and its total content is 1%.
Described enamel frit makeing basic components is: SiO
250%, Al
2O
310%, B
2O
320%, Na
2O20%, k
2O10%, CaO5%, MgO5%, TiO
220%, ZrO
210%, ZnO5%, BaO5%, F10%, NiO2%, MnO
24%, Fe
2O
34%, CuO2% adds antiseptic-germicide and is a kind of in copper, silver, tin, zirconium, rare earth, calcium, zinc, boron, barium, titanium and their compound, salt or the oxide compound or several, and its total content is 5%.
Described enamel frit makeing basic components is: SiO
240%, Al
2O
35%, B
2O
315%, Na
2O15%, k
2O6%, CaO2%, MgO2%, TiO
210%, ZrO
25%, ZnO3%, BaO3%, F5%, NiO1%, MnO
22%, Fe
2O
32%, CuO1% adds antiseptic-germicide and is a kind of in copper, silver, tin, zirconium, rare earth, calcium, zinc, boron, barium, titanium and their compound, salt or the oxide compound or several, and its total content is 2.5%.
The major ingredient of described antiseptic-germicide is silver and compound, salt or oxide compound.
A kind of method for preparing above-mentioned antibacterial enamel, its technical process is:
1) according to above-mentioned prescription, select raw material and after weighing, mixing, under the high temperature of 1200 ℃～1350 ℃ of High-temp. kilns, be melt into glassy mass, make the glaze piece through shrend again;
2) in the glaze piece, add the glaze slip of in ball mill, wearing into certain fineness behind an amount of mill addition;
3) glaze slip is coated in has handled on the enamel base substrate of cleaning in advance, under 750 ℃～900 ℃ temperature, be fused into level and smooth, glossiness enamel composite bed.
Described preparation method makes the glaze piece with the enamel frit makeing basic components in step 1), then in step 2) in add antiseptic-germicide and make glaze slip.
Described mill addition is clay, dielectric substance or pigment water.
The present invention adopts the form of complex antimicrobials and enamel to be fused together, form a uniform complex body, can kill effectively, bacterium and mould, its prescription and preparation method can keep the gloss on enamel layer surface, smooth, color and luster, can guarantee again that antiseptic-germicide can be present in snugly plays anti-microbial effect in the enamel coating, after measured, Chinese People's Anti-Japanese Military and Political College enterobacteria and staphylococcus reach 92%～99%, anti-comprehensive mould is a zero level, use the antibiotic enamel of the present invention and can be made into various household enamels, medical enamelware, building environmental protection enamelware is as the assembly unit plate, water chamber plate, decorative sheet or the like.
Specific embodiment
The present invention will be further described in detail below in conjunction with embodiment.
Embodiment 1
Antibacterial enamel, its enamel frit makeing basic components is: SiO
230%, B
2O
35%, Na
2O5%, k
2O2%～10%, F1%～10% add antiseptic-germicide and are a kind of in copper, silver, tin, zirconium, rare earth, calcium, zinc, boron, barium, titanium and their compound, salt or the oxide compound or several, and its total content is 1%; The preparation method is: 1) according to above-mentioned prescription, select raw material and after weighing, mixing, under the high temperature of 1200 ℃～1350 ℃ of High-temp. kilns, be melt into glassy mass, make the glaze piece through shrend again; 2) in the glaze piece, add the glaze slip of in ball mill, wearing into certain fineness behind the mill additions such as an amount of clay, dielectric substance or pigment water; 3) glaze slip is coated in has handled on the enamel base substrate of cleaning in advance, under 750 ℃～900 ℃ temperature, be fused into level and smooth, glossiness enamel composite bed.
Embodiment 2
Antibacterial enamel, its enamel frit makeing basic components is: SiO
250%, Al
2O
310%, B
2O
320%, Na
2O20%, k
2O10%, CaO5%, MgO5%, TiO
220%, ZrO
210%, ZnO5%, BaO5%, F10%, NiO2%, MnO
24%, Fe
2O
34%, CuO2% adds antiseptic-germicide and is a kind of in copper, silver, tin, zirconium, rare earth, calcium, zinc, boron, barium, titanium and their compound, salt or the oxide compound or several, and its total content is 5%, and the preparation method is the same.
Embodiment 3
Antibacterial enamel, its enamel frit makeing basic components is: SiO
240%, Al
2O
35%, B
2O
315%, Na
2O15%, k
2O6%, CaO2%, MgO2%, TiO
210%, ZrO
25%, ZnO3%, BaO3%, F5%, NiO1%, MnO
22%, Fe
2O
32%, CuO1% adds antiseptic-germicide and is a kind of in copper, silver, tin, zirconium, rare earth, calcium, zinc, boron, barium, titanium and their compound, salt or the oxide compound or several, and its total content is 2.5%, and the preparation method is the same.
Embodiment 4
Antibacterial enamel, its enamel frit makeing basic components is: SiO
230%, B
2O
35%, Na
2O5%, k
2O2%～10%, F1%～10% add antiseptic-germicide and are a kind of in copper, silver, tin, zirconium, rare earth, calcium, zinc, boron, barium, titanium and their compound, salt or the oxide compound or several, and its total content is 1%; The preparation method is: 1) according to above-mentioned prescription, select basic components after weighing, mixing, under the high temperature of 1200 ℃～1350 ℃ of High-temp. kilns, be melt into glassy mass, make the glaze piece through shrend again; 2) in the glaze piece, add the glaze slip of in ball mill, wearing into certain fineness behind the antiseptic-germicide of the dosage of filling a prescription and the mill additions such as an amount of clay, dielectric substance or pigment water; 3) glaze slip is coated in has handled on the enamel base substrate of cleaning in advance, under 750 ℃～900 ℃ temperature, be fused into level and smooth, glossiness enamel composite bed.
Embodiment 5
Antibacterial enamel, its enamel frit makeing basic components is: SiO
250%, Al
2O
310%, B
2O
320%, Na
2O20%, k
2O10%, CaO5%, MgO5%, TiO
220%, ZrO
210%, ZnO5%, BaO5%, F10%, NiO2%, MnO
24%, Fe
2O
34%, CuO2% adds antiseptic-germicide and is a kind of in copper, silver, tin, zirconium, rare earth, calcium, zinc, boron, barium, titanium and their compound, salt or the oxide compound or several, and its total content is 5%, and the preparation method is the same.
Embodiment 6
Antibacterial enamel, its enamel frit makeing basic components is: SiO
240%, Al
2O
35%, B
2O
315%, Na
2O15%, k
2O6%, CaO2%, MgO2%, TiO
210%, ZrO
25%, ZnO3%, BaO3%, F5%, NiO1%, MnO
22%, Fe
2O
32%, CuO1% adds antiseptic-germicide and is a kind of in copper, silver, tin, zirconium, rare earth, calcium, zinc, boron, barium, titanium and their compound, salt or the oxide compound or several, and its total content is 2.5%, and the preparation method is the same.
Antibacterial enamel product of the present invention and common enamel entrust " data behind the building material industry environment measuring " center " monitoring analysis are as follows:
Common enamel: 1) antifungal performance, experimental strain is comprehensive mould, comprises aspergillus niger, goes up aspergillus, paecilomyces varioti, penicillium funiculosum, Aureobasidium pullulans, ball hair shell, the long enzyme grade of sample is 3 grades; 2) sample is 60.75% to the bacteriostasis rate of streptococcus aureus, is 57.32% to colibacillary bacteriostasis rate, does not meet the requirement of JC/T897-2002 standard index.
Antibacterial enamel: 1) antifungal performance, experimental strain is comprehensive mould, comprises aspergillus niger, goes up aspergillus, paecilomyces varioti, penicillium funiculosum, Aureobasidium pullulans, ball hair shell, the long enzyme grade of sample is 0 grade; 2) sample is 92.52% to the bacteriostasis rate of streptococcus aureus, is 91.55% to colibacillary bacteriostasis rate, meets the requirement of JC/T897-2002 standard index.
The present invention is not limited to above-mentioned specific embodiment; anyone can draw other various forms of variations under enlightenment of the present invention; no matter substitute or improve but what kind of is done, every identical with the application or akin technical scheme all drops within protection scope of the present invention.
Claims (8)
1, a kind of antibacterial enamel is characterized in that, the enamel frit makeing basic components is: SiO
230%～50%, Al
2O
35%～10%, B
2O
35%～20%, Na
2O5%～20%, k
2O2%～10%, CaO0%～5%, MgO0%～5%, TiO
20%～20%, ZrO
20%～10%, ZnO0%～5%, BaO0%～5%, F1%～10%, NiO0%～2%, MnO
20%～4%, Fe
2O
30%～4%, CuO0%～2% adds antiseptic-germicide and is a kind of in copper, silver, tin, zirconium, rare earth, calcium, zinc, boron, barium, titanium and their compound, salt or the oxide compound or several, and its total content is 1%～5%.
2, antibacterial enamel according to claim 1 is characterized in that, described enamel frit makeing basic components is: SiO
230%, B
2O
35%, Na
2O5%, k
2O2%～10%, F1%～10% add antiseptic-germicide and are a kind of in copper, silver, tin, zirconium, rare earth, calcium, zinc, boron, barium, titanium and their compound, salt or the oxide compound or several, and its total content is 1%.
3, antibacterial enamel according to claim 1 is characterized in that, described enamel frit makeing basic components is: SiO
250%, Al
2O
310%, B
2O
320%, Na
2O20%, k
2O10%, CaO5%, MgO5%, TiO
220%, ZrO
210%, ZnO5%, BaO5%, F10%, NiO2%, MnO
24%, Fe
2O
34%, CuO2% adds antiseptic-germicide and is a kind of in copper, silver, tin, zirconium, rare earth, calcium, zinc, boron, barium, titanium and their compound, salt or the oxide compound or several, and its total content is 5%.
4, antibacterial enamel according to claim 1 is characterized in that, described enamel frit makeing basic components is: SiO
240%, Al
2O
35%, B
2O
315%, Na
2O15%, k
2O6%, CaO2%, MgO2%, TiO
210%, ZrO
25%, ZnO3%, BaO3%, F5%, NiO1%, MnO
22%, Fe
2O
32%, CuO1% adds antiseptic-germicide and is a kind of in copper, silver, tin, zirconium, rare earth, calcium, zinc, boron, barium, titanium and their compound, salt or the oxide compound or several, and its total content is 2.5%.
According to the arbitrary described antibacterial enamel of claim 1 to 4, it is characterized in that 5, the major ingredient of described antiseptic-germicide is silver and compound, salt or oxide compound.
6, a kind of method for preparing the described antibacterial enamel of claim 1, its technical process is:
1) according to above-mentioned prescription, select raw material and after weighing, mixing, under the high temperature of 1200 ℃～1350 ℃ of High-temp. kilns, be melt into glassy mass, make the glaze piece through shrend again;
2) in the glaze piece, add the glaze slip of in ball mill, wearing into certain fineness behind an amount of mill addition;
3) glaze slip is coated in has handled on the enamel base substrate of cleaning in advance, under 750 ℃～900 ℃ temperature, be fused into level and smooth, glossiness enamel composite bed.
7, antibacterial enamel preparation method according to claim 6 is characterized in that, described preparation method makes the glaze piece with the enamel frit makeing basic components in step 1), then in step 2) in add antiseptic-germicide and make glaze slip.
8, antibacterial enamel preparation method according to claim 7 is characterized in that, described mill addition is clay, dielectric substance or pigment water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200610078227 CN1843995A (en) | 2006-05-12 | 2006-05-12 | Antibacterial enamel and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200610078227 CN1843995A (en) | 2006-05-12 | 2006-05-12 | Antibacterial enamel and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1843995A true CN1843995A (en) | 2006-10-11 |
Family
ID=37062966
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200610078227 Pending CN1843995A (en) | 2006-05-12 | 2006-05-12 | Antibacterial enamel and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1843995A (en) |
Cited By (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090104459A1 (en) * | 2007-02-20 | 2009-04-23 | Microban Products Company | Ceramic glaze having antimicrobial property |
| CN101066837B (en) * | 2007-05-24 | 2010-08-04 | 江苏奥博晶瓷科技有限公司 | Environment friendly heat resistant opal crystalline glass and its preparation process |
| RU2417168C1 (en) * | 2010-01-11 | 2011-04-27 | Юлия Алексеевна Щепочкина | Glase |
| CN102086091A (en) * | 2010-07-08 | 2011-06-08 | 石家庄正中科技有限公司 | Surface glaze, white enamel and preparation method thereof |
| CN102223801A (en) * | 2008-11-24 | 2011-10-19 | 西门子公司 | Component with an antimicrobial surface and use thereof |
| RU2446116C1 (en) * | 2010-11-30 | 2012-03-27 | Юлия Алексеевна Щепочкина | Enamel coating |
| CN102795893A (en) * | 2012-09-10 | 2012-11-28 | 山东电盾科技有限公司 | Antistatic antimicrobial ceramic glaze |
| CN104876646A (en) * | 2015-05-26 | 2015-09-02 | 绥阳县华夏陶瓷有限责任公司 | Anti-bacterial glaze and preparation method thereof |
| CN104876645A (en) * | 2015-05-26 | 2015-09-02 | 绥阳县华夏陶瓷有限责任公司 | Glass fiber containing antibacterial glaze and manufacture method thereof |
| CN105152683A (en) * | 2015-08-25 | 2015-12-16 | 山东建筑大学 | Method for manufacturing nanometer antibacterial ceramic glaze layers |
| CN105601113A (en) * | 2015-12-29 | 2016-05-25 | 广东美的厨房电器制造有限公司 | Antibacterial enamel material and preparation method and application thereof |
| WO2016094484A1 (en) * | 2014-12-10 | 2016-06-16 | Microban Products Company | Biocidal glazing composition, method, and article |
| CN105925151A (en) * | 2016-04-29 | 2016-09-07 | 宁波高新区夏远科技有限公司 | Composite anti-bacterial paint |
| CN106430958A (en) * | 2016-08-30 | 2017-02-22 | 无锡上工搪化工设备有限公司 | Ceramic glaze for glass lining |
| CN107384388A (en) * | 2017-07-28 | 2017-11-24 | 成都理工大学 | A kind of metatitanic acid calcium material and preparation method with antibacterial and luminous complex function |
| CN107935392A (en) * | 2017-11-30 | 2018-04-20 | 南宁市生润科技有限公司 | A kind of celeste glaze with anti-pollution function |
| US9974310B2 (en) | 2016-03-09 | 2018-05-22 | Microban Products Company | Ceramic additive formulation and method of making |
| EP3326987A1 (en) * | 2016-11-24 | 2018-05-30 | Duravit Aktiengesellschaft | Ceramic object and method for producing same |
| CN105565670B (en) * | 2016-01-12 | 2018-08-14 | 曹文 | A kind of ceramics or enamel sterilization glazing type material and preparation method thereof and its application |
| CN108439797A (en) * | 2018-06-27 | 2018-08-24 | 沙冰娟 | A kind of composite antibacterial ceramic glaze |
| CN108585495A (en) * | 2018-07-05 | 2018-09-28 | 沙冰娟 | A kind of preparation method of antibacterial ceramic glaze |
| CN109970341A (en) * | 2019-04-23 | 2019-07-05 | 廖祥胜 | Antifouling and antibiosis ceramic glaze and preparation method thereof |
| CN110255905A (en) * | 2019-07-02 | 2019-09-20 | 浙江开尔新材料股份有限公司 | The preparation method of antibacterial enamel glaze slip, preparation method and antibacterial enamel plate |
| CN110759642A (en) * | 2018-07-03 | 2020-02-07 | 佛山欧神诺陶瓷有限公司 | Rare earth antibacterial ceramic glaze |
| CN111393026A (en) * | 2020-02-25 | 2020-07-10 | 广东沃尔姆斯电器有限公司 | Preparation method of enamel product with antibacterial property and enamel product with antibacterial property |
| US10899657B1 (en) | 2016-03-09 | 2021-01-26 | Microban Products Company | Ceramic additive formulation and method of making |
| CN113402169A (en) * | 2021-07-14 | 2021-09-17 | 佛山市陶莹新型材料有限公司 | Easy-to-clean polished glaze and preparation method thereof |
| CN113526873A (en) * | 2021-09-17 | 2021-10-22 | 佛山市三水区康立泰无机合成材料有限公司 | A kind of glass ceramic antibacterial powder and its preparation method and application |
| CN115504665A (en) * | 2022-10-21 | 2022-12-23 | 格力电器（武汉）有限公司 | Antibacterial agent for borosilicate glass and antibacterial enamel liner |
| US11844351B2 (en) | 2016-10-31 | 2023-12-19 | Microban Products Company | Method of treating a glazed ceramic article |
| CN119430656A (en) * | 2025-01-08 | 2025-02-14 | 德化县坤航陶瓷有限公司 | Antibacterial and antiviral ceramic glaze and method for preparing ceramic product |
-
2006
- 2006-05-12 CN CN 200610078227 patent/CN1843995A/en active Pending
Cited By (56)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20150030863A1 (en) * | 2007-02-20 | 2015-01-29 | Microban Products Company | Ceramic glaze having antimicrobial property |
| US20150030696A1 (en) * | 2007-02-20 | 2015-01-29 | Microban Products Company | Ceramic glaze having antimicrobial property |
| US10863745B2 (en) | 2007-02-20 | 2020-12-15 | Microban Products Company | Ceramic glaze having antimicrobial property |
| US10856549B2 (en) | 2007-02-20 | 2020-12-08 | Microban Products Company | Ceramic glaze having antimicrobial property |
| US10856550B2 (en) | 2007-02-20 | 2020-12-08 | Microban Products Company | Ceramic glaze having antimicrobial property |
| US9446980B2 (en) * | 2007-02-20 | 2016-09-20 | Microban Products Company | Ceramic glaze having antimicrobial property |
| US20090104459A1 (en) * | 2007-02-20 | 2009-04-23 | Microban Products Company | Ceramic glaze having antimicrobial property |
| US10045537B2 (en) | 2007-02-20 | 2018-08-14 | Microban Products Company | Ceramic glaze having antimicrobial property |
| US9434638B2 (en) * | 2007-02-20 | 2016-09-06 | Microban Products Company | Ceramic glaze having antimicrobial property |
| US10045539B2 (en) | 2007-02-20 | 2018-08-14 | Microban Products Company | Ceramic glaze having antimicrobial property |
| US20150030861A1 (en) * | 2007-02-20 | 2015-01-29 | Microban Products Company | Ceramic glaze having antimicrobial property |
| US10045538B2 (en) | 2007-02-20 | 2018-08-14 | Microban Products Company | Ceramic glaze having antimicrobial property |
| US9446981B2 (en) * | 2007-02-20 | 2016-09-20 | Microban Products Company | Ceramic glaze having antimicrobial property |
| EP2118038A4 (en) * | 2007-02-20 | 2015-11-04 | Microban Products | CERAMIC ENAMEL WITH ANTIMICROBIAL PROPERTY |
| CN101066837B (en) * | 2007-05-24 | 2010-08-04 | 江苏奥博晶瓷科技有限公司 | Environment friendly heat resistant opal crystalline glass and its preparation process |
| US10159255B2 (en) | 2008-02-16 | 2018-12-25 | Microban Products Company | Biocidal glazing composition, method, and article |
| CN102223801B (en) * | 2008-11-24 | 2015-11-25 | 西门子公司 | Components with antimicrobial surfaces and uses thereof |
| US9492812B2 (en) | 2008-11-24 | 2016-11-15 | Siemens Aktiengesellschaft | Component with an antimicrobial surface and use thereof |
| CN102223801A (en) * | 2008-11-24 | 2011-10-19 | 西门子公司 | Component with an antimicrobial surface and use thereof |
| RU2417168C1 (en) * | 2010-01-11 | 2011-04-27 | Юлия Алексеевна Щепочкина | Glase |
| CN102086091A (en) * | 2010-07-08 | 2011-06-08 | 石家庄正中科技有限公司 | Surface glaze, white enamel and preparation method thereof |
| RU2446116C1 (en) * | 2010-11-30 | 2012-03-27 | Юлия Алексеевна Щепочкина | Enamel coating |
| CN102795893B (en) * | 2012-09-10 | 2013-12-11 | 山东电盾科技有限公司 | Antistatic antimicrobial ceramic glaze |
| CN102795893A (en) * | 2012-09-10 | 2012-11-28 | 山东电盾科技有限公司 | Antistatic antimicrobial ceramic glaze |
| WO2016094484A1 (en) * | 2014-12-10 | 2016-06-16 | Microban Products Company | Biocidal glazing composition, method, and article |
| CN104876645A (en) * | 2015-05-26 | 2015-09-02 | 绥阳县华夏陶瓷有限责任公司 | Glass fiber containing antibacterial glaze and manufacture method thereof |
| CN104876646A (en) * | 2015-05-26 | 2015-09-02 | 绥阳县华夏陶瓷有限责任公司 | Anti-bacterial glaze and preparation method thereof |
| CN105152683A (en) * | 2015-08-25 | 2015-12-16 | 山东建筑大学 | Method for manufacturing nanometer antibacterial ceramic glaze layers |
| CN105601113A (en) * | 2015-12-29 | 2016-05-25 | 广东美的厨房电器制造有限公司 | Antibacterial enamel material and preparation method and application thereof |
| CN105601113B (en) * | 2015-12-29 | 2019-02-19 | 广东美的厨房电器制造有限公司 | Antibacterial enamel material and preparation method and application thereof |
| CN105565670B (en) * | 2016-01-12 | 2018-08-14 | 曹文 | A kind of ceramics or enamel sterilization glazing type material and preparation method thereof and its application |
| US10899657B1 (en) | 2016-03-09 | 2021-01-26 | Microban Products Company | Ceramic additive formulation and method of making |
| US11767256B1 (en) | 2016-03-09 | 2023-09-26 | Microban Products Company | Ceramic additive formulation and method of making |
| CN109071353A (en) * | 2016-03-09 | 2018-12-21 | 美可帮产品公司 | Ceramic additive preparation and preparation method |
| US9974310B2 (en) | 2016-03-09 | 2018-05-22 | Microban Products Company | Ceramic additive formulation and method of making |
| US10299483B2 (en) | 2016-03-09 | 2019-05-28 | Microban Products Company | Ceramic additive formulation and method of making |
| CN105925151A (en) * | 2016-04-29 | 2016-09-07 | 宁波高新区夏远科技有限公司 | Composite anti-bacterial paint |
| CN106430958A (en) * | 2016-08-30 | 2017-02-22 | 无锡上工搪化工设备有限公司 | Ceramic glaze for glass lining |
| US12376593B2 (en) | 2016-10-31 | 2025-08-05 | Microban Products Company | Method of treating a glazed ceramic article |
| US11844351B2 (en) | 2016-10-31 | 2023-12-19 | Microban Products Company | Method of treating a glazed ceramic article |
| EP3326987A1 (en) * | 2016-11-24 | 2018-05-30 | Duravit Aktiengesellschaft | Ceramic object and method for producing same |
| CN107384388B (en) * | 2017-07-28 | 2020-06-23 | 成都理工大学 | A kind of calcium titanate material with antibacterial and luminescent composite functions and preparation method |
| CN107384388A (en) * | 2017-07-28 | 2017-11-24 | 成都理工大学 | A kind of metatitanic acid calcium material and preparation method with antibacterial and luminous complex function |
| CN107935392A (en) * | 2017-11-30 | 2018-04-20 | 南宁市生润科技有限公司 | A kind of celeste glaze with anti-pollution function |
| CN108439797A (en) * | 2018-06-27 | 2018-08-24 | 沙冰娟 | A kind of composite antibacterial ceramic glaze |
| CN110759642A (en) * | 2018-07-03 | 2020-02-07 | 佛山欧神诺陶瓷有限公司 | Rare earth antibacterial ceramic glaze |
| CN108585495A (en) * | 2018-07-05 | 2018-09-28 | 沙冰娟 | A kind of preparation method of antibacterial ceramic glaze |
| CN109970341A (en) * | 2019-04-23 | 2019-07-05 | 廖祥胜 | Antifouling and antibiosis ceramic glaze and preparation method thereof |
| CN110255905B (en) * | 2019-07-02 | 2022-06-03 | 浙江开尔新材料股份有限公司 | Antibacterial enamel glaze slurry, preparation method and preparation method of antibacterial enamel plate |
| CN110255905A (en) * | 2019-07-02 | 2019-09-20 | 浙江开尔新材料股份有限公司 | The preparation method of antibacterial enamel glaze slip, preparation method and antibacterial enamel plate |
| CN111393026A (en) * | 2020-02-25 | 2020-07-10 | 广东沃尔姆斯电器有限公司 | Preparation method of enamel product with antibacterial property and enamel product with antibacterial property |
| CN113402169A (en) * | 2021-07-14 | 2021-09-17 | 佛山市陶莹新型材料有限公司 | Easy-to-clean polished glaze and preparation method thereof |
| CN113526873A (en) * | 2021-09-17 | 2021-10-22 | 佛山市三水区康立泰无机合成材料有限公司 | A kind of glass ceramic antibacterial powder and its preparation method and application |
| CN115504665A (en) * | 2022-10-21 | 2022-12-23 | 格力电器（武汉）有限公司 | Antibacterial agent for borosilicate glass and antibacterial enamel liner |
| CN119430656A (en) * | 2025-01-08 | 2025-02-14 | 德化县坤航陶瓷有限公司 | Antibacterial and antiviral ceramic glaze and method for preparing ceramic product |
| CN119430656B (en) * | 2025-01-08 | 2025-06-27 | 德化县坤航陶瓷有限公司 | Antibacterial and antiviral ceramic glaze and method for preparing ceramic product |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1843995A (en) | Antibacterial enamel and preparation method thereof | |
| US11066338B2 (en) | Antimicrobial glaze and porcelain enamel via double layer glaze with high zinc content | |
| US5807641A (en) | Anti-bacterial and anti-fungal glaze composition for ceramic products | |
| CN101580342B (en) | Self-cleaning antibacterial ceramic glaze and preparation method and ceramic product thereof | |
| RU2010135771A (en) | GLASS FRITS | |
| CN110790505B (en) | Composite antibacterial ceramic glaze and preparation method thereof | |
| CN102086091A (en) | Surface glaze, white enamel and preparation method thereof | |
| DE69408096T2 (en) | ANTIBACTERIAL AND MOLD-REPELLENT GLAZE COMPOSITION FOR CERAMIC PRODUCTS | |
| CN115677219B (en) | Antibacterial glaze, ceramic tile with high hardness, smooth glaze and antibacterial function and preparation method thereof | |
| CN101880177A (en) | A self-cleaning and antibacterial glaze for sanitary ceramics | |
| CN108929117A (en) | It is a kind of with super-hydrophobic and antibacterial functions glazed tiles and preparation method thereof | |
| TW201628990A (en) | Antimicrobial chemically strengthened glass and method for the manufacture thereof | |
| EP1845073A1 (en) | Compositions comprising nanoparticles of zirconium hydroxide and/or glass frits for coating ceramic products | |
| WO2021006680A1 (en) | Antimicrobial glass composition and production method thereof | |
| CN110759642A (en) | Rare earth antibacterial ceramic glaze | |
| CN1887812A (en) | Decoration glaze for inner wall tile and its prepn and detection method | |
| JP3104578B2 (en) | Antibacterial and antifungal additive for glaze | |
| JP3098387B2 (en) | Antibacterial additives for glaze, antibacterial porcelain or enamel products | |
| JP3894246B2 (en) | Glaze composition having conductivity and antibacterial properties | |
| KR102658178B1 (en) | Eco-friendly antibacterial glaze and its manufacturing method | |
| CN114804929B (en) | Ceramic tile with antibacterial function and preparation method thereof | |
| CN111574060A (en) | Transmutation glaze overglaze, preparation method thereof and porcelain | |
| CN1331059A (en) | Antibacterial daily ceramic product | |
| JP2961892B2 (en) | Method for producing antibacterial glaze for ceramics and method for producing antibacterial ceramics | |
| JP3051019B2 (en) | Antibacterial and antifungal glaze composition and antibacterial and antifungal composition for adding glaze |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Open date: 20061011 |