CN1778286A - Cosmetics containing silver and zinc composition and preparation thereof - Google Patents
Cosmetics containing silver and zinc composition and preparation thereof Download PDFInfo
- Publication number
- CN1778286A CN1778286A CN 200410091487 CN200410091487A CN1778286A CN 1778286 A CN1778286 A CN 1778286A CN 200410091487 CN200410091487 CN 200410091487 CN 200410091487 A CN200410091487 A CN 200410091487A CN 1778286 A CN1778286 A CN 1778286A
- Authority
- CN
- China
- Prior art keywords
- zinc
- argentiferous
- cosmetics
- composition
- silver
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 112
- 239000002537 cosmetic Substances 0.000 title claims abstract description 71
- 239000011701 zinc Substances 0.000 title claims description 141
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title claims description 55
- 229910052725 zinc Inorganic materials 0.000 title claims description 55
- 239000004332 silver Substances 0.000 title claims description 48
- 229910052709 silver Inorganic materials 0.000 title claims description 48
- 238000002360 preparation method Methods 0.000 title claims description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 28
- 238000001223 reverse osmosis Methods 0.000 claims abstract description 17
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 8
- 239000004094 surface-active agent Substances 0.000 claims abstract description 8
- 239000002562 thickening agent Substances 0.000 claims abstract description 8
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 46
- PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerol group Chemical group OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 27
- 239000002131 composite material Substances 0.000 claims description 26
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 24
- 239000000463 material Substances 0.000 claims description 22
- 150000002148 esters Chemical class 0.000 claims description 20
- 238000003756 stirring Methods 0.000 claims description 19
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 18
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims description 16
- -1 polyoxyethylene monostearate Polymers 0.000 claims description 15
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 13
- 244000173166 Pyrus ussuriensis Species 0.000 claims description 12
- 235000011572 Pyrus ussuriensis Nutrition 0.000 claims description 12
- 230000018044 dehydration Effects 0.000 claims description 12
- 238000006297 dehydration reaction Methods 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 12
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 claims description 11
- 239000002689 soil Substances 0.000 claims description 10
- 150000003751 zinc Chemical class 0.000 claims description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 9
- 229940075507 glyceryl monostearate Drugs 0.000 claims description 8
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 claims description 8
- 239000000080 wetting agent Substances 0.000 claims description 8
- 239000002202 Polyethylene glycol Substances 0.000 claims description 7
- 229920001223 polyethylene glycol Polymers 0.000 claims description 7
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 6
- 229910021536 Zeolite Inorganic materials 0.000 claims description 6
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 6
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 6
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 6
- 229940057995 liquid paraffin Drugs 0.000 claims description 6
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 6
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 6
- 239000010457 zeolite Substances 0.000 claims description 6
- CUNWUEBNSZSNRX-RKGWDQTMSA-N (2r,3r,4r,5s)-hexane-1,2,3,4,5,6-hexol;(z)-octadec-9-enoic acid Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O CUNWUEBNSZSNRX-RKGWDQTMSA-N 0.000 claims description 5
- 229920001214 Polysorbate 60 Polymers 0.000 claims description 5
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 5
- 229920001577 copolymer Polymers 0.000 claims description 5
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- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 5
- 229960005078 sorbitan sesquioleate Drugs 0.000 claims description 5
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 4
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 4
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 4
- RMJNSNPPAZENDA-UHFFFAOYSA-M C(C)(=O)[O-].[Na+].C(CCCCCCCCCCC)(=O)NC Chemical compound C(C)(=O)[O-].[Na+].C(CCCCCCCCCCC)(=O)NC RMJNSNPPAZENDA-UHFFFAOYSA-M 0.000 claims description 4
- CWNSVVHTTQBGQB-UHFFFAOYSA-N N,N-Diethyldodecanamide Chemical compound CCCCCCCCCCCC(=O)N(CC)CC CWNSVVHTTQBGQB-UHFFFAOYSA-N 0.000 claims description 4
- 239000005642 Oleic acid Substances 0.000 claims description 4
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 4
- 229920001213 Polysorbate 20 Polymers 0.000 claims description 4
- 229920002125 Sokalan® Polymers 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- 229960001631 carbomer Drugs 0.000 claims description 4
- JZKFHQMONDVVNF-UHFFFAOYSA-N dodecyl sulfate;tris(2-hydroxyethyl)azanium Chemical compound OCCN(CCO)CCO.CCCCCCCCCCCCOS(O)(=O)=O JZKFHQMONDVVNF-UHFFFAOYSA-N 0.000 claims description 4
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 4
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 4
- 239000004006 olive oil Substances 0.000 claims description 4
- 235000008390 olive oil Nutrition 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- WGIWBXUNRXCYRA-UHFFFAOYSA-H trizinc;2-hydroxypropane-1,2,3-tricarboxylate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O WGIWBXUNRXCYRA-UHFFFAOYSA-H 0.000 claims description 4
- 235000013904 zinc acetate Nutrition 0.000 claims description 4
- 239000011746 zinc citrate Substances 0.000 claims description 4
- 235000006076 zinc citrate Nutrition 0.000 claims description 4
- 229940068475 zinc citrate Drugs 0.000 claims description 4
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 3
- GWXNYJUUTVJQGU-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-(carboxymethyl)amino]acetic acid;zinc Chemical compound [Zn].OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O GWXNYJUUTVJQGU-UHFFFAOYSA-N 0.000 claims description 3
- 239000005995 Aluminium silicate Substances 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 239000004166 Lanolin Substances 0.000 claims description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 3
- 239000006004 Quartz sand Substances 0.000 claims description 3
- WHMDKBIGKVEYHS-IYEMJOQQSA-L Zinc gluconate Chemical compound [Zn+2].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O WHMDKBIGKVEYHS-IYEMJOQQSA-L 0.000 claims description 3
- CANRESZKMUPMAE-UHFFFAOYSA-L Zinc lactate Chemical compound [Zn+2].CC(O)C([O-])=O.CC(O)C([O-])=O CANRESZKMUPMAE-UHFFFAOYSA-L 0.000 claims description 3
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 claims description 3
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 3
- 235000012211 aluminium silicate Nutrition 0.000 claims description 3
- 229940040526 anhydrous sodium acetate Drugs 0.000 claims description 3
- 229960000892 attapulgite Drugs 0.000 claims description 3
- 239000000440 bentonite Substances 0.000 claims description 3
- 229910000278 bentonite Inorganic materials 0.000 claims description 3
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 3
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 3
- 239000004202 carbamide Substances 0.000 claims description 3
- 235000013877 carbamide Nutrition 0.000 claims description 3
- 239000010439 graphite Substances 0.000 claims description 3
- 229910002804 graphite Inorganic materials 0.000 claims description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 3
- 229940039717 lanolin Drugs 0.000 claims description 3
- 235000019388 lanolin Nutrition 0.000 claims description 3
- 239000001630 malic acid Substances 0.000 claims description 3
- 235000011090 malic acid Nutrition 0.000 claims description 3
- 229910052625 palygorskite Inorganic materials 0.000 claims description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 3
- 229910052624 sepiolite Inorganic materials 0.000 claims description 3
- 235000019355 sepiolite Nutrition 0.000 claims description 3
- 239000004246 zinc acetate Substances 0.000 claims description 3
- 229960000314 zinc acetate Drugs 0.000 claims description 3
- 239000011670 zinc gluconate Substances 0.000 claims description 3
- 235000011478 zinc gluconate Nutrition 0.000 claims description 3
- 229960000306 zinc gluconate Drugs 0.000 claims description 3
- 239000011576 zinc lactate Substances 0.000 claims description 3
- 235000000193 zinc lactate Nutrition 0.000 claims description 3
- 229940050168 zinc lactate Drugs 0.000 claims description 3
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 claims description 3
- 229910000165 zinc phosphate Inorganic materials 0.000 claims description 3
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 3
- 229960001763 zinc sulfate Drugs 0.000 claims description 3
- 229910000368 zinc sulfate Inorganic materials 0.000 claims description 3
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 claims 2
- 229950007687 macrogol ester Drugs 0.000 claims 2
- 238000005406 washing Methods 0.000 claims 1
- 241000894006 Bacteria Species 0.000 abstract description 5
- 241000233866 Fungi Species 0.000 abstract description 5
- 238000002156 mixing Methods 0.000 abstract description 4
- 230000002421 anti-septic effect Effects 0.000 abstract description 3
- 239000003795 chemical substances by application Substances 0.000 abstract description 2
- 230000002147 killing effect Effects 0.000 abstract description 2
- BSWGGJHLVUUXTL-UHFFFAOYSA-N silver zinc Chemical compound [Zn].[Ag] BSWGGJHLVUUXTL-UHFFFAOYSA-N 0.000 abstract 2
- 239000003906 humectant Substances 0.000 abstract 1
- 239000011159 matrix material Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 34
- 239000010413 mother solution Substances 0.000 description 27
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- 206010000496 acne Diseases 0.000 description 10
- 239000002781 deodorant agent Substances 0.000 description 9
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- 239000000126 substance Substances 0.000 description 8
- 208000001840 Dandruff Diseases 0.000 description 7
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- BIVBRWYINDPWKA-VLQRKCJKSA-L Glycyrrhizinate dipotassium Chemical compound [K+].[K+].O([C@@H]1[C@@H](O)[C@H](O)[C@H](O[C@@H]1O[C@H]1CC[C@]2(C)[C@H]3C(=O)C=C4[C@@H]5C[C@](C)(CC[C@@]5(CC[C@@]4(C)[C@]3(C)CC[C@H]2C1(C)C)C)C(O)=O)C([O-])=O)[C@@H]1O[C@H](C([O-])=O)[C@@H](O)[C@H](O)[C@H]1O BIVBRWYINDPWKA-VLQRKCJKSA-L 0.000 description 6
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 6
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- 229940110456 cocoa butter Drugs 0.000 description 1
- 235000019868 cocoa butter Nutrition 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000002951 depilatory effect Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000001647 drug administration Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 210000002615 epidermis Anatomy 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
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- 235000019197 fats Nutrition 0.000 description 1
- 210000004905 finger nail Anatomy 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 239000001963 growth medium Substances 0.000 description 1
- 239000000118 hair dye Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- CXORMDKZEUMQHX-UHFFFAOYSA-N kermesic acid Chemical compound O=C1C2=C(O)C(O)=CC(O)=C2C(=O)C2=C1C=C(O)C(C(O)=O)=C2C CXORMDKZEUMQHX-UHFFFAOYSA-N 0.000 description 1
- 238000002372 labelling Methods 0.000 description 1
- 239000006224 matting agent Substances 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 244000052769 pathogen Species 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
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- 238000005498 polishing Methods 0.000 description 1
- 229920000053 polysorbate 80 Polymers 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 235000010232 propyl p-hydroxybenzoate Nutrition 0.000 description 1
- QELSKZZBTMNZEB-UHFFFAOYSA-N propylparaben Chemical compound CCCOC(=O)C1=CC=C(O)C=C1 QELSKZZBTMNZEB-UHFFFAOYSA-N 0.000 description 1
- 229960003415 propylparaben Drugs 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 208000029561 pustule Diseases 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 239000013558 reference substance Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 208000013223 septicemia Diseases 0.000 description 1
- 239000008257 shaving cream Substances 0.000 description 1
- 229940100890 silver compound Drugs 0.000 description 1
- 150000003379 silver compounds Chemical class 0.000 description 1
- 229910001961 silver nitrate Inorganic materials 0.000 description 1
- 229910000108 silver(I,III) oxide Inorganic materials 0.000 description 1
- 208000017520 skin disease Diseases 0.000 description 1
- 206010040882 skin lesion Diseases 0.000 description 1
- 231100000444 skin lesion Toxicity 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 208000003265 stomatitis Diseases 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 230000000475 sunscreen effect Effects 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 206010043378 tetanus neonatorum Diseases 0.000 description 1
- 230000029663 wound healing Effects 0.000 description 1
- DJWUNCQRNNEAKC-UHFFFAOYSA-L zinc acetate Chemical class [Zn+2].CC([O-])=O.CC([O-])=O DJWUNCQRNNEAKC-UHFFFAOYSA-L 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
A cosmetic containing the Ag-Zn composition for the antiseptic purpose and killing bacteria, fungi and mite contains proportionally the Ag-Zn composition prepared from H4Ag2O6 solution and soluble Zn salt through mixing and the matrix prepared from surfactant or emulsifier, humectant, thickening agent or filming agent, and reverse osmosis water.
Description
Technical field
The present invention relates to cosmetics and preparation method thereof, particularly relate to cosmetics of a kind of argentiferous Zn composition and preparation method thereof.
Background technology
Along with improving constantly of social life level, cosmetics in people's life in occupation of considerable status, people are also more and more higher to the requirement of cosmetics quality and function, have the welcome that multi-functional compound cosmetics such as scrubbing, nursing, sterilization, acaricide more and more are subjected to people.But,, be easy to become the good place of microorganism existence owing to contain nutritional labelings such as fat, protein, inorganic salt in the cosmetics.In a single day cosmetics are polluted by Institute of Micro-biology, product quality is descended, and can cause the infringement to human body, pathogenic and poisoning to some extent.The microbial contamination of cosmetics early has report abroad, and as far back as the forties, New Zealand just the incident of tetanus neonatorum occurred being caused by microbial contamination owing to Pulvis Talci in the talcum powder; The sixties, the U.S. also took place owing to the vanishing cream that has used the lanoline that has added by microbial contamination causes that 6 people suffer from the incident of septicemia, 1 people's death.
In order to solve cosmetics by the problem of microbial contamination, people are normal some antiseptic and the antibacterial of adding in cosmetics, but these antiseptic and antibacterial all are organic chemicalss, and human body skin is had certain stimulation, and antibacterial also has drug resistance.
Silver is used relatively extensively as antibacterial, and such as in Japan, silver has the time of decades in the application in fields such as pottery, coating; In the U.S., the application of silver in wound dressing obtained the approval of FDA (U.S. food Drug Administration); In China, the applied research of silver also presents good trend.But Yin application in the prior art is to adopt silver nitrate, simple substance silver, silver oxide, collargol, argentoproteinum etc. mostly.Along with the further investigation of people to silver-colored anti-microbial property, find that the anti-microbial property of silver and the valence state of silver have very confidential relation, the high more antibacterial ability of valence state of silver is strong more, wherein bivalence silver and trivalent silver bactericidal effect is 50～200 times of the silver-colored and argent of monovalence, and the sterilization speed of trivalent silver compound is than silver-colored fast 240 times of (the Soap/Cosmetics/Chemical Specialties of monovalence, March, 1994, page52).In the prior art, H
4Ag
2O
6Solution is a kind of chemical compound that contains high valence state silver preferably, the disclosed H of Chinese patent ZL97108681.8
4Ag
2O
6The preparation method of solution is as follows: (1) gets the oxide (comprising silver oxide or silver peroxide) of silver, adds distilled water; (2) after the stirring, add concentrated sulphuric acid, adjust pH value; (3) pour out clear liquor after the clarification, obtain precipitate; (4) in precipitate, add hydrogen peroxide, obtain argentiferous hydrate H
4Ag
2O
6Solution.
Zinc element is confirmed already in application pharmaceutically, as all effective in cure to wound healing, stomatitis, skin lesion type pimple, pustule, erosive dermatitis etc.Zinc also is a kind of traditional inorganic fungicide.Zinc is as anti-biotic material, and it is inchoate in recent years being paid attention to by people.Though the too late any silver of the antibacterial ability of zinc, zinc antifungal energy force rate silver is strong, and zinc is eager to excel to the more independent silver of the sterilization effect of fungus and mycete with the silver-colored back of making up.
In recent years, also relevant for the report that silver is used for cosmetics, but all only relate to application with the silver of lower valencies such as collargol, argentoproteinum, its bactericidal effect has certain limitation, and the addition of silver is also bigger.
Summary of the invention
The purpose of this invention is to provide a kind of cosmetics with argentiferous Zn composition of anticorrosion and anti-microbial property.
Another object of the present invention provides a kind of method for preparing argentiferous Zn composition cosmetics.
For achieving the above object, the present invention takes following technical scheme: a kind of cosmetics of argentiferous Zn composition, form by silver-colored Zn composition and base material of cosmetics basically; Described silver-colored Zn composition is H
4Ag
2O
6The argentiferous zinc composite solution that solution and soluble zinc salt mix, wherein silver accounts for 0.001%～10% of cosmetics gross weight, and zinc accounts for 0.001%～10% of cosmetics gross weight; Described base material of cosmetics comprises the following material that accounts for the cosmetics total weight percent: surfactant or emulsifying agent 0.1%～80%, wetting agent 0.1%～60%, thickening agent or film former 0.1%～60%, reverse osmosis water 1%～90%.
Described argentiferous zinc composite solution can be attached on the inorganic mineral carrier.
Described soluble zinc salt is selected from one or more in zinc sulfate, zinc nitrate, zinc acetate, zinc lactate, zinc gluconate, ethylenediaminetetraacetic acid zinc, zinc phosphate, malic acid zinc or the zinc citrate.
Described inorganic mineral carrier is selected from one or more in graphite, bentonite, Kaolin, zeolite, Montmorillonitum, meerschaum, Gypsum Fibrosum, white carbon, quartz sand, attapulgite, kieselguhr or the chalky soil.
Described cosmetics comprise that skin protection applies some make up, hair-dressing cosmetics, cosmetics and special cosmetics.
Described surfactant or emulsifying agent are selected from sodium laurylsulfate, lauryl sulfate triethanolamine salt, lauric acid diethyl amide, distearyl acid polyethylene glycol ester (400), lauroyl methylamine sodium acetate, anhydrous lanolin, glyceryl monostearate, monostearate Polyethylene Glycol (400) ester, olive oil, liquid paraffin, lanoline, sesquialter oleic acid dehydration Pyrusussuriensis ester, monostearate dehydration Pyrusussuriensis ester, polyoxyethylene monostearate dehydration Pyrusussuriensis ester, the polyoxyethylene sorbitan lanoline, paraffin, polyoxyethylene 20 sorbitan monolaurate (5EO), polyoxyethylene (15) glyceryl monostearate, sorbitan sesquioleate, soil temperature-80 or soil temperature-20.
Described wetting agent is selected from glycerol, propylene glycol, carbamide or ethanol.
Described thickening agent or film former are selected from sodium carboxymethyl cellulose, acrylate copolymer, polyvinyl alcohol or carbomer.
A kind of method for preparing the cosmetics of argentiferous Zn composition may further comprise the steps: a, at H
4Ag
2O
6Add an amount of soluble zinc salt in the solution, make argentiferous zinc composite solution, in the argentiferous zinc composite solution composition of silver account for the cosmetics gross weight 0.001%～10%, the composition of zinc accounts for 0.001%～10% of cosmetics gross weight; B, stirring argentiferous zinc composite solution make its mix homogeneously; C, argentiferous zinc composite solution is spiked in the acceptable base material of cosmetics of skin, makes the cosmetics of argentiferous Zn composition; Described base material of cosmetics comprises the following material that accounts for the cosmetics total weight percent: surfactant or emulsifying agent 0.1%～80%, wetting agent 0.1%～60%, thickening agent or film former 0.1%～60%, reverse osmosis water 1%～90%.。
In the method for described a kind of cosmetics that prepare the argentiferous Zn composition, can be with the composite solution of argentiferous zinc attached on the inorganic mineral carrier, its step is as follows: the inorganic mineral carrier is sieved, then it is joined in the argentiferous zinc composite solution, wherein, the ratio of weight and number of inorganic mineral carrier and argentiferous zinc composite solution is: the inorganic mineral carrier; Stirred 0.5 hour～1 hour argentiferous zinc composite solution=1: 1～20, filters then, washes, filters, and dry under 50 ℃～80 ℃ again, final powder is broken to 0.50 μ m～100 μ m.
It is that those are used for handling or the product of nursing, moistening, improvement or cleaning skin that described skin protection applies some make up, and it comprises adhesive, binder, anhydrous isolation wetting agent, antiperspirant, deodorizer, detergent, fabric sofetening towel, isolated drug release patch, fingernail polishing agent, powder, fabric, wiping thing, solid emulsified body compressor, anhydrous conditioner for hair etc.; Described hair-dressing cosmetics are those articles for use that are used for having one's hair wash, taking care of hair and shave etc., and it mainly acts on is the cleaning hair, promotes the eubolism of hair; The effect of hair care articles is lubricated hair and fixing hair style; The effect of shaving product is soft palpus hair.Hair-dressing cosmetics comprise shampoo, hair oil, pomade, suppurative mastitis, hair cream, flood, send out slurry, shaving cream, water etc. shaves; Described cosmetics are those products that are used for modifying and beautifying appearance, and it comprises color make-up, foundation cream, XIANGFEN, perfume, kermes, lip pomade, eyebrow pencil, informer, eye black pigment used by women in ancient times to paint their eyebrows, nial polish, epidermis remover, matting agent etc.; Described extraordinary cosmetics are those products with certain effect or effect, and it comprises hair dye, setting lotion, depilatory, antiperspirant deodorizer, sunscreen, freckle cream, white skin oil, acne ointment, facial film, bath oil, foam bath agent, articles for babies etc.
The silver-colored Zn composition composite solution that the present invention relates to, its preparation method is as follows: the oxide of silver is mixed with silver-containing solution, regulates pH value to 1～5; In silver-containing solution, add hydrogen peroxide, be mixed with the aqueous solution that contains the high price silver ion; Again soluble zinc salt is joined in the aqueous solution that contains the high price silver ion, promptly become silver-colored Zn composition composite solution.
The cosmetics of argentiferous Zn composition of the present invention, silver-colored zinc composition in its compositions has dual function, at first being antisepsis, secondly is that pathogen such as the antibacterial in skin or the hair, fungus, acarid are played killing action, and various dermatosiss are also had treatment and preventive effect.
Active component argentiferous Zn composition in the cosmetics of the present invention is as shown in table 1 to the in-vitro antibacterial effect of common bacteria:
Table 1: argentiferous Zn composition in-vitro antibacterial effect data table
| Test strain | Compositions silver and zinc concentration μ g/L | Different time (min) sterilizing rate (%) | |||
| 1 | 3 | 5 | 10 | ||
| Golden yellow Fructus Vitis viniferae ball | 200 | 99.86％ | 99.89％ | 99.97％ | 100％ |
| Bacterium ATCC 6538 | 100 | 97.9％ | 99.83％ | 99.97％ | 100％ |
| 50 | 94.5％ | 99.74％ | 99.94％ | 99.94％ | |
| Contrast (notes) | 84.7％ | 95.33％ | 96.37％ | 97.18％ | |
| Bacillus subtilis ATCC 6633 | 200 | 92.33％ | 92.61％ | 92.94％ | 92.96％ |
| 100 | 90.97％ | 91.43％ | 91.43％ | 91.54％ | |
| 50 | 90.82％ | 91.18％ | 91.32％ | 91.61％ | |
| Contrast | 91.0％ | 91.32％ | 91.36％ | 91.90％ | |
| Candida albicans ATCC10231 | 200 | 99.76％ | 99.84％ | 99.84％ | 100％ |
| 100 | 99.27％ | 99.66％ | 99.84％ | 99.92％ | |
| 50 | 95.3％ | 94.73％ | 98.31％ | 96.11％ | |
| Contrast | 76.62％ | 84.0％ | 90.08％ | 93.71 |
(notes) reference substance is that 5% benzene is pricked smelly amine
Active component argentiferous Zn composition in the cosmetics of the present invention is as shown in table 2 to the external MIC measurement result of 12 kinds of pathomycetes of common 5 genus:
Table 2: the argentiferous Zn composition is to the external MIC measurement result of 12 kinds of pathomycetes of common 5 genus
| The bacterium name | The concentration (ppm/ml) of culture medium silver and zinc complexes | MIC (ppm/ ml) | |||||||||
| 256 | 128 | 64 | 32 | 16 | 8 | 4.0 | 2.0 | 1.0 | 0.5 | ||
| Trichophyton | - | - | - | - | - | - | - | + | + | + | 4.0 |
| Alpha fungus | - | - | - | - | - | - | + | + | + | + | 8 |
| Trichophyton | - | - | - | - | - | - | + | + | + | + | 8 |
| Trichophyton violaceum | - | - | - | - | - | - | - | + | + | + | 4.0 |
| Trichophyton | - | - | - | - | - | - | + | + | + | + | 8 |
| Sabouraudites lanosus | - | - | - | - | - | - | + | + | + | + | 8 |
| Microsporon gypseum | - | - | - | - | - | - | + | + | + | + | 8 |
| Acrothesium floccosum | - | - | - | - | - | - | - | - | + | + | 2.0 |
| Candida albicans | - | - | - | - | - | - | + | + | + | + | 8 |
| Malassezia furfur | - | - | - | - | - | + | + | + | + | + | 16 |
| Contain a horse | - | - | - | - | + | + | + | + | + | + | 32 |
| Draw the color bacterium | |||||||||||
| Spherical chlosma | - | - | - | - | - | + | + | + | + | + | 16 |
The present invention is owing to take above technical scheme, and it has the following advantages: 1, the cosmetics of argentiferous Zn composition of the present invention, and silver-colored zinc composition wherein has anticorrosion and antimicrobial dual function; 2, the cosmetics of argentiferous Zn composition of the present invention can be strengthened the sterilization effect to fungus and mycete after wherein zinc makes up with silver; 3, the cosmetics of argentiferous Zn composition of the present invention, its preparation method is simple, is convenient to implement.
The specific embodiment
At first the method by following examples 1 and embodiment 2 prepares argentiferous, Zn composition mother solution, and then prepares the cosmetics of various argentiferous, Zn composition.
Embodiment 1: the preparation of argentiferous, Zn composition mother solution 1.
1000 gram silver peroxides are put in the reaction pot, added 100 kilograms of deionized waters again, be mixed with silver-containing solution; Stir silver-containing solution after 15 minutes, add 125 milliliters in perchloric acid again, regulate the pH=2 of silver-containing solution; Continue to stir then 2 hours, and when pH value is stabilized in 2, dropwise added concentration again and be 600 milliliters of 15% hydrogen peroxide, restir 30 minutes; Add this moment contain the zinc nitrates that zinc is 4400 grams (zinc nitrate that is added is chloride ion-containing not, can not contain other can with the anion of the biochemical reaction of silver hair), restir 30 minutes promptly is mixed with argentiferous, the Zn composition mother solution of high concentration.In argentiferous, the Zn composition mother solution argentiferous weight account for mother solution weight 4%, zinciferous weight account for 4% of mother solution weight.Carry out concentration dilution during application as required, also can be when making carry out concentration proportioning between the silver-colored zinc by the needs of using.
Embodiment 2: the preparation of argentiferous, Zn composition mother solution 2.
500 gram silver peroxides are put in the reaction pot, added 100 kilograms of deionized waters again, be mixed with silver-containing solution; Stir silver-containing solution after 100 minutes, add citric acid 4000 grams again, regulate the pH=2 of silver-containing solution; Continue to stir then 2 hours, and when pH value is stabilized in 2, dropwise added concentration again and be 1000 milliliters of 20% hydrogen peroxide, restir 30 minutes; Add this moment contain the zinc acetates that zinc is 1100 grams (zinc nitrate that is added is chloride ion-containing not, can not contain other can with the anion of the biochemical reaction of silver hair), restir 30 minutes promptly is mixed with argentiferous, the Zn composition mother solution of high concentration.In argentiferous, the Zn composition mother solution argentiferous weight account for mother solution weight 1%, zinciferous weight account for 1% of mother solution weight.Carry out concentration dilution during application as required, also can be when making carry out concentration proportioning between the silver-colored zinc by the needs of using.
Embodiment 3: the preparation of argentiferous, Zn composition anti-dandruff shampoo.
Press the prescription of the listed argentiferous of table 3, Zn composition anti-dandruff shampoo, adopt conventional method to prepare argentiferous, Zn composition shampoo.
Table 3: argentiferous, Zn composition anti-dandruff shampoo prescription
| The formula material of shampoo | The weight percentage of each composition in the prescription | |||
| 1 #Prescription | 2 #Prescription | 3 #Prescription | 4 #Prescription | |
| Argentiferous, Zn composition mother solution 1 (silver, zinc is content separately) | 0.001％ | 0.01％ | 0.1％ | 0.5％ |
| AES | 16％ | 15％ | ||
| Sodium laurylsulfate | 30％ | 2.7％ | ||
| Lauryl sulfate triethanolamine salt | 50％ | 20％ | ||
| Lauric acid diethyl amide | 4％ | |||
| Soil temperature-80 | 10％ | |||
| Distearyl acid polyethylene glycol ester (400) | 5％ | 5％ | ||
| Lauroyl methylamine sodium acetate | 1％ | |||
| Propylene glycol | 2％ | |||
| EDTA | 0.05％ | |||
| Pigment, essence | In right amount | In right amount | In right amount | In right amount |
| Reverse osmosis water | Surplus | Surplus | Surplus | Surplus |
Embodiment 4: the preparation of argentiferous, Zn composition anti-dandruff suppurative mastitis.
The prescription of argentiferous, Zn composition anti-dandruff suppurative mastitis is as shown in table 4.
Table 4: argentiferous, Zn composition anti-dandruff suppurative mastitis prescription
| The formula material of suppurative mastitis | The weight percentage of each composition in the prescription | |||
| 1 #Prescription | 2 #Prescription | 3 #Prescription | 4 #Prescription | |
| Argentiferous, Zn composition mother solution 2 (silver, zinc is content separately) | 0.001％ | 0.01％ | 0.1％ | 0.5％ |
| Liquid paraffin | 40％ | 15％ | 40％ | 30％ |
| Sodium laurylsulfate | 7.5％ | |||
| Stearic acid | 3.5％ | 5.0％ | ||
| Cera Flava | 3.0％ | |||
| Anhydrous lanolin | 2％ | |||
| Propylene glycol | 4.0％ | |||
| Glyceryl monostearate | 0.2％ | |||
| Triethanolamine | 1.5％ | 1.8％ | ||
| Cocoa butter | 5.0％ | |||
| Ester cerotin | 2.0％ | |||
| Glycerol | 4.5％ | 0.1％ | ||
| Monostearate Polyethylene Glycol (400) ester | 0.2％ | 6.0％ | ||
| Pigment, essence | In right amount | In right amount | In right amount | In right amount |
| Reverse osmosis water | Surplus | Surplus | Surplus | Surplus |
The preparation method of argentiferous, Zn composition anti-dandruff suppurative mastitis is as follows:
A) aqueous phase substance is dissolved in the water pot, stirs;
B) oil phase substance is placed in the oil phase pot, heats 90 ℃ of dissolvings, be cooled to 60 ℃ then.
C) oil phase liquid is joined in the aqueous phase liquid stir, become mixed solution.
C) at last argentiferous, Zn composition mother solution 2 are joined in the mixed solution of step c), carry out emulsifying, be incubated 55 ℃, get final product to 30 minutes.
Embodiment 5: the preparation of argentiferous, Zn composition emollient cream.
Press the prescription of the listed argentiferous of table 5, Zn composition emollient cream, adopt conventional method to prepare argentiferous, Zn composition emollient cream.
Table 5: argentiferous, Zn composition emollient cream prescription
| The formula material of emollient cream | The weight percentage of each composition in the prescription | |||
| 1 #Oil/water frost | 2 #Water/bloom | 3 #Water/bloom | 4 #Water/bloom | |
| Argentiferous, Zn composition mother solution 1 (silver, zinc is content separately) | 0.001％ | 0.01％ | 0.01％ | 0.05％ |
| Liquid paraffin | 35％ | 17％ | 15％ | 25％ |
| Olive oil | 15％ | 30％ | ||
| Lanoline | 10％ | 1.0％ | 2.0％ | |
| Cera Flava | 17％ | 5.0％ | ||
| Stearic acid | 0.6％ | |||
| Monostearate dehydration Pyrusussuriensis ester | 2.0％ | 2.0％ | ||
| Sesquialter oleic acid dehydration Pyrusussuriensis ester | 3.0％ | |||
| Polyoxyethylene monostearate dehydration Pyrusussuriensis ester | 3.0％ | |||
| The polyoxyethylene sorbitan lanoline | 4.0％ | |||
| Vaseline | 20％ | 35％ | 2.0 | |
| Paraffin | 4.5％ | 0.1％ | ||
| Glycerol | 0.2％ | 4.0％ | 2.5％ | |
| Borax | 0.3％ | |||
| Magnesium sulfate | 0.2％ | 0.2％ | ||
| Pigment, essence | In right amount | In right amount | In right amount | In right amount |
| Reverse osmosis water | 33％ | 32％ | 30％ | 35％ |
Embodiment 6: the preparation of argentiferous, Zn composition cleansing cream.
The prescription of argentiferous, Zn composition cleansing cream is as shown in table 6.
Table 6: argentiferous, Zn composition cleansing cream prescription
| The formula material of cleansing cream | The weight percentage of each composition in cleansing cream dosage form and the prescription | |||
| 1 #Anhydrous non-oil-in-water type | 2 #The no ion-type of water/oil | 3 #Oil/water nonionic | 4 #Oil/aqueous emulsion | |
| Argentiferous, Zn composition mother solution 2 (silver, zinc is content separately) | 0.1％ | 0.01％ | 0.01％ | 0.05％ |
| Vaseline | 36.5％ | 11％ | 18.0％ | 5.0％ |
| Paraffin | 10％ | 5.0％ | ||
| Liquid paraffin | 50％ | 41％ | 28.0％ | 11.0％ |
| Cera Flava | 3.0％ | |||
| Hexadecanol | 1.5％ | 1.2％ | ||
| Polyoxyethylene 20 sorbitan monooleate (20EO) | 0.8％ | |||
| Stearic acid | 2.0％ | |||
| Triethanolamine | 1.0％ | |||
| Polyoxyethylene sorbitan ether (2EO) | 1.8％ | |||
| Polyoxyethylene 20 sorbitan monolaurate (5EO) | 0.4％ | |||
| Glyceryl monostearate | 3.0％ | |||
| Polyoxyethylene laurate (20EO) | 3.0％ | |||
| Sorbitan sesquioleate | 4.0％ | |||
| Propylene glycol | 4.0％ | 4.0％ | ||
| Ethanol | 2.0％ | |||
| Glycerol | 1.0％ | |||
| Spice | 0.4 | 0.69 | 0.25％ | |
| Reverse osmosis water | 34.1％ | 40.3％ | 75.3％ | |
More than 1
#Formula material when mixing except that spice and argentiferous, Zn composition mother solution 2, other various compositions after heating for dissolving, perfuming and argentiferous, Zn composition mother solution 2, cooling then again.
1
#, 2
#, 3
#Prescription is made by general emulsifying manner:
A) aqueous phase substance is dissolved in the water pot, stirs;
B) oil phase substance is placed in the oil phase pot, heats 90 ℃ of dissolvings, be cooled to 60 ℃ then.
C) oil phase liquid is joined in the aqueous phase liquid stir, become mixed solution.
D) at last argentiferous, Zn composition mother solution 2 are added in the mixed solution of step c), carry out emulsifying, be incubated 55 ℃, get final product to 30 minutes.
Embodiment 7: the preparation of argentiferous, Zn composition acne ointment.
The prescription of argentiferous, Zn composition acne ointment is as shown in table 7.
Table 7: argentiferous, Zn composition acne ointment prescription
| The formula material of acne ointment | The weight percentage of each composition (%) in the prescription |
| Argentiferous, Zn composition mother solution 2 (silver, zinc is content separately) | 1.2 |
| Hexadecanol | 10.0 |
| White oil | 10.0 |
| Glyceryl monostearate | 1.5 |
| Polyoxyethylene (15) glyceryl monostearate | 2.0 |
| Glycerol | 5.0 |
| Retinoic acid | 0.05 |
| Essence | In right amount |
| Reverse osmosis water | 71.45 |
Manufacture method is as follows: aqueous phase substance and oil phase substance are heated to 85 ℃ respectively, mix stirring and emulsifying again, when being cooled to 65 ℃ then, retinoic acid is joined in the emulsion, it is uniformly dispersed, continues to make emulsion to be cooled to 45 ℃, again essence and argentiferous, Zn composition mother solution 2 are joined in the emulsion, stop when continuing to make emulsion to be cooled to 40 ℃ stirring, be cooled to room temperature and get final product.
Embodiment 8: the preparation of argentiferous, Zn composition lotion for pimples.
The prescription of argentiferous, Zn composition lotion for pimples is as shown in table 8.
Table 8: argentiferous, Zn composition lotion for pimples prescription
| The formula material of lotion for pimples | The weight percentage of each composition (%) in the prescription |
| Argentiferous, Zn composition mother solution 1 (silver, zinc is content separately) | 1.2 |
| Glycyrrhizic acid dipotassium | 0.2 |
| Acrylate copolymer | 0.2 |
| Ethanol | 10.2 |
| Diisopropanolamine (DIPA) | 0.2 |
| Halocarbon | 0.1 |
| Essence | In right amount |
| Reverse osmosis water | 88.8 |
Manufacture method is as follows: at first glycyrrhizic acid dipotassium is dissolved in one-tenth glycyrrhizic acid dipotassium solution in the reverse osmosis water, under agitation acrylate copolymer is joined glycyrrhizic acid dipotassium solution, make it homodisperse; Other is dissolved in halocarbon in the ethanol and with it and adds in the above-mentioned glycyrrhizic acid dipotassium dispersion liquid, diisopropanolamine (DIPA) and argentiferous, Zn composition mother solution 1 is joined in the glycyrrhizic acid dipotassium dispersion liquid at last again, fully stirs to get final product.
Embodiment 9: the preparation of argentiferous, Zn composition deodorant liquid.
The prescription of argentiferous, Zn composition deodorant liquid is as shown in table 9.
Table 9: the prescription of argentiferous, Zn composition deodorant liquid
| The formula material of deodorant liquid | The weight percentage of each composition (%) in the prescription |
| Argentiferous, Zn composition mother solution 2 (silver, zinc is content separately) | 2.0 |
| Glycerol | 8 |
| Propylene glycol | 1 |
| Sodium carboxymethyl cellulose | 5 |
| Essence | In right amount |
| Reverse osmosis water | 83.5 |
Manufacture method is as follows: glycerol, propylene glycol and essence are mixed into uniform mixed liquor, when mixing liquid sodium carboxymethyl cellulose is joined wherein, add argentiferous, Zn composition mother solution 2 again, the limit mixes liquid limit adding reverse osmosis water then, and stirring gets final product.
Embodiment 10: the preparation of argentiferous, Zn composition deodorant frost.
The prescription of argentiferous, Zn composition deodorant frost is as shown in table 10.
Table 10: argentiferous, Zn composition deodorant frost prescription
| The formula material of deodorant frost | The weight percentage of each composition (%) in the prescription |
| Argentiferous, Zn composition mother solution 1 (silver, zinc is content separately) | 2.0 |
| Mineral oil | 20.0 |
| Vaseline | 8.5 |
| Ceresin | 6.0 |
| Lanoline | 4.5 |
| Sorbitan sesquioleate | 4.0 |
| Magnesium sulfate | 0.15 |
| Essence | In right amount |
| Reverse osmosis water | 54.1 |
Manufacture method is as follows: oil-phase component is mixed and heated to 80 ℃, magnesium sulfate is dissolved in becomes Adlerika in the reverse osmosis water, be heated to 80 ℃ then; When stirring Adlerika it is joined and become mixed solution in the oil-phase solution, continue to mix solution, when treating that its temperature is reduced to 50 ℃, slowly argentiferous, Zn composition mother solution 1 are joined in the mixed solution, and continue slowly to be chilled to 40 ℃, continue to stir again and add essence simultaneously, stir evenly and be cooled to room temperature and get final product.
Embodiment 11: argentiferous, Zn composition prepare zeolite.
A, at H
4Ag
2O
6Add an amount of soluble zinc salt in the solution, make argentiferous zinc composite solution, the weight percentage of silver is 10% in the argentiferous zinc composite solution, the weight percentage of zinc is 10%; B, stirring argentiferous zinc composite solution make its mix homogeneously; C, zeolite is sieved, then it is joined in the argentiferous zinc composite solution, the mixed by 1: 20 stirred 1 hour, filtered then, washes, refiltered, and then less than 60 ℃ of dryings down, final powder is broken to about 30 μ m.
Embodiment 12: the preparation of argentiferous, Zn composition deodorant gel.
Get the zeolite 5.0g of embodiment 11 preparations
Zinc citrate 2.0g
Polyethylene Glycol 40.0g
Carbomer 30.0g
Sodium carboxymethyl cellulose 15.0g
Nipasol 0.1g
Add reverse osmosis water to 1000.0g
Mentioned component is mixed fill behind the mixing.
Claims (10)
1, a kind of cosmetics of argentiferous Zn composition are made up of silver-colored Zn composition and base material of cosmetics basically, and described silver-colored Zn composition is H
4Ag
2O
6The argentiferous zinc composite solution that solution and soluble zinc salt mix, wherein silver accounts for 0.001%～10% of cosmetics gross weight, and zinc accounts for 0.001%～10% of cosmetics gross weight; Described base material of cosmetics comprises the following material that accounts for the cosmetics total weight percent: surfactant or emulsifying agent 0.1%～80%, wetting agent 0.1%～60%, thickening agent or film former 0.1%～60%, reverse osmosis water 1%～90%.
2, the cosmetics of a kind of argentiferous Zn composition as claimed in claim 1 is characterized in that: described argentiferous zinc composite solution is attached on the inorganic mineral carrier.
3, the cosmetics of a kind of argentiferous Zn composition as claimed in claim 2 is characterized in that: described inorganic mineral carrier is selected from one or more in graphite, bentonite, Kaolin, zeolite, Montmorillonitum, meerschaum, Gypsum Fibrosum, white carbon, quartz sand, attapulgite, kieselguhr or the chalky soil.
4, the cosmetics of a kind of argentiferous Zn composition as claimed in claim 1 is characterized in that: described soluble zinc salt is selected from one or more in zinc sulfate, zinc nitrate, zinc acetate, zinc lactate, zinc gluconate, ethylenediaminetetraacetic acid zinc, zinc phosphate, malic acid zinc or the zinc citrate.
5, the cosmetics of a kind of argentiferous Zn composition as claimed in claim 1 is characterized in that: described surfactant or emulsifying agent are selected from sodium laurylsulfate, lauryl sulfate triethanolamine salt, lauric acid diethyl amide, distearyl acid polyethylene glycol ester, lauroyl methylamine sodium acetate, anhydrous lanolin, glyceryl monostearate, the monostearate macrogol ester, olive oil, liquid paraffin, lanoline, sesquialter oleic acid dehydration Pyrusussuriensis ester, monostearate dehydration Pyrusussuriensis ester, polyoxyethylene monostearate dehydration Pyrusussuriensis ester, the polyoxyethylene sorbitan lanoline, paraffin, polyoxyethylene 20 sorbitan monolaurate, the polyoxyethylene glyceryl monostearate, sorbitan sesquioleate, soil temperature-80 or soil temperature-20; Described wetting agent is selected from glycerol, propylene glycol, carbamide or ethanol; Described thickening agent or film former are selected from sodium carboxymethyl cellulose, acrylate copolymer, polyvinyl alcohol or carbomer.
6, as claim 1 or 2 or 3 or the cosmetics of 4 or 5 described a kind of argentiferous Zn compositions, it is characterized in that: described cosmetics comprise that skin protection applies some make up, hair-dressing cosmetics, cosmetics and special cosmetics.
7, a kind of method for preparing the cosmetics of argentiferous Zn composition may further comprise the steps: a, at H
4Ag
2O
6Add an amount of soluble zinc salt in the solution, make argentiferous zinc composite solution, in the argentiferous zinc composite solution composition of silver account for the cosmetics gross weight 0.001%～10%, the composition of zinc accounts for 0.001%～10% of cosmetics gross weight; B, stirring argentiferous zinc composite solution make its mix homogeneously; C, argentiferous zinc composite solution is spiked in the acceptable base material of cosmetics of skin, makes the cosmetics of argentiferous Zn composition; Described base material of cosmetics comprises the following material that accounts for the cosmetics total weight percent: surfactant or emulsifying agent 0.1%～80%, wetting agent 0.1%～60%, thickening agent or film former 0.1%～60%, reverse osmosis water 1%～90%.
8, a kind of method for preparing the cosmetics of argentiferous Zn composition as claimed in claim 7, it is characterized in that, the composite solution of described argentiferous zinc is attached on the inorganic mineral carrier, its preparation process is as follows: the inorganic mineral carrier is sieved, then it is joined in the argentiferous zinc composite solution, wherein, the ratio of weight and number of inorganic mineral carrier and argentiferous zinc composite solution is: the inorganic mineral carrier: argentiferous zinc composite solution=1: 1～20, stirred 0.5 hour～1 hour, filter then, washing, filter, dry under 50 ℃～80 ℃ again, final powder is broken to 0.50 μ m～100 μ m.
9, a kind of method for preparing the cosmetics of argentiferous Zn composition as claimed in claim 8, it is characterized in that: described inorganic mineral carrier is selected from one or more in graphite, bentonite, Kaolin, zeolite, Montmorillonitum, meerschaum, Gypsum Fibrosum, white carbon, quartz sand, attapulgite, kieselguhr or the chalky soil.
10, as claim 7 or 8 described a kind of methods that prepare the cosmetics of argentiferous Zn composition, it is characterized in that: described soluble zinc salt is selected from one or more in zinc sulfate, zinc nitrate, zinc acetate, zinc lactate, zinc gluconate, ethylenediaminetetraacetic acid zinc, zinc phosphate, malic acid zinc or the zinc citrate; Described surfactant or emulsifying agent are selected from sodium laurylsulfate, lauryl sulfate triethanolamine salt, lauric acid diethyl amide, distearyl acid polyethylene glycol ester, lauroyl methylamine sodium acetate, anhydrous lanolin, glyceryl monostearate, the monostearate macrogol ester, olive oil, liquid paraffin, lanoline, sesquialter oleic acid dehydration Pyrusussuriensis ester, monostearate dehydration Pyrusussuriensis ester, polyoxyethylene monostearate dehydration Pyrusussuriensis ester, the polyoxyethylene sorbitan lanoline, paraffin, polyoxyethylene 20 sorbitan monolaurate, the polyoxyethylene glyceryl monostearate, sorbitan sesquioleate, soil temperature-80 or soil temperature-20; Described wetting agent is selected from glycerol, propylene glycol, carbamide or ethanol; Described thickening agent or film former are selected from sodium carboxymethyl cellulose, acrylate copolymer, polyvinyl alcohol or carbomer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410091487 CN1778286A (en) | 2004-11-25 | 2004-11-25 | Cosmetics containing silver and zinc composition and preparation thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410091487 CN1778286A (en) | 2004-11-25 | 2004-11-25 | Cosmetics containing silver and zinc composition and preparation thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1778286A true CN1778286A (en) | 2006-05-31 |
Family
ID=36768826
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200410091487 Pending CN1778286A (en) | 2004-11-25 | 2004-11-25 | Cosmetics containing silver and zinc composition and preparation thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1778286A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104055694A (en) * | 2013-03-18 | 2014-09-24 | 恒源祥（集团）有限公司 | Lanolin-containing household chemical additive and preparation method thereof |
| CN115485033A (en) * | 2020-05-04 | 2022-12-16 | 联合利华知识产权控股有限公司 | Antibacterial composition |
| CN116548434A (en) * | 2022-01-28 | 2023-08-08 | 南京银宽医药技术有限公司 | High-valence silver-loaded zeolite antibacterial liquid and preparation method thereof |
-
2004
- 2004-11-25 CN CN 200410091487 patent/CN1778286A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104055694A (en) * | 2013-03-18 | 2014-09-24 | 恒源祥（集团）有限公司 | Lanolin-containing household chemical additive and preparation method thereof |
| CN104055694B (en) * | 2013-03-18 | 2016-04-06 | 恒源祥（集团）有限公司 | A kind of lanolated daily chemical products additive and preparation method thereof |
| CN115485033A (en) * | 2020-05-04 | 2022-12-16 | 联合利华知识产权控股有限公司 | Antibacterial composition |
| CN116548434A (en) * | 2022-01-28 | 2023-08-08 | 南京银宽医药技术有限公司 | High-valence silver-loaded zeolite antibacterial liquid and preparation method thereof |
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